Iron Oxide Tube-in-Tube Nanostructures - The Journal of Physical [PDF]

Aug 10, 2007 - Single-crystalline hematite tube-in-tube nanostructures were prepared by a facile one-step hydrothermal m

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Iron Oxide Tube-in-Tube Nanostructures Article Options

Chun-Jiang Jia† , Ling-Dong Sun*† , Zheng-Guang Yan† , Yu-Cheng Pang† , Li-Ping You‡ , and Chun-Hua Yan*† Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications & PKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistry, and Electron Microscopy Laboratory, Peking University, Beijing 100871, China

Abstract

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J. Phys. Chem. C, 2007, 111 (35), pp 13022–13027 DOI: 10.1021/jp073837q Publication Date (Web): August 10, 2007 Copyright © 2007 American Chemical Society

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Single-crystalline hematite tube-in-tube nanostructures were prepared by a facile one-step

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hydrothermal method. The structure, shape, and formation mechanism of the tube-in-tube

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nanostructures were investigated. The results disclosed that the hematite tube-in-tube

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nanostructures were formed through a multisite dissolution process of the ellipsoid precursors.

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What is more, the tube-in-tube nanostructure is a single crystal in nature, and a simple

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combination of a small tube filling into a big one can be excluded. Single-crystalline magnetite and maghemite tube-in-tube nanostructures were also obtained via a simple reduction or

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reduction and reoxidation process with the hematite as the precursor. The facile and mild reaction route could be useful for the fabrication of complex tubular nanostructures.



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Received 18 May 2007 Published online 10 August 2007 Published in print 1 September 2007 Learn more about these metrics

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