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What is the molarity of a solution containing 0.32 moles of sodium chloride, NaCl, in 3.4 L of solution? 4. Calculate th

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Idea Transcript


Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

Name______________________________________     Date:_________________     Part  I.    Math  Skills.     1.    Convert  0.5  decimeters  to  millimeters.    Fill  in  the  blanks.       Step  1.    Convert  0.5  decimeters  to  meters.     1  𝑑𝑚 =  deci-­‐meter  =  ________  𝑚         ________ ________  ×   = ________  𝑚   ________       Step  2.    Convert  answer  from  first  step  to  millimeters.     1  𝑚𝑚 =  milli-­‐meter  =  ________  𝑚         ________ ________  ×   = ________    𝑚𝑚   ________     2.    Convert  600  centigrams  to  decigrams.    Follow  format  exactly  as  above.       Step  1.                   Step  2.                

 

1  

Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

3.    What  is  the  molarity  of  a  solution  containing  0.32  moles  of  sodium   chloride,  NaCl,  in  3.4  L  of  solution?               4.    Calculate  the  molarity  of  a  solution  that  contains  35.0  grams  of   barium  chloride,  BaCl2,  dissolved  in  0.45  L  of  solution.               5.    How  many  moles  of  lithium  chloride,  LiCl,  are  dissolved  in  3.00  L  of  a   0.200  M  solution  of  lithium  chloride?               6.    How  many  grams  of  calcium  chloride,  CaCl2,  are  needed  to  prepare   0.4  L  of  a  1.20  M  solution  of  calcium  chloride?               7.    What  is  the  molarity  of  250  mL  of  a  solution  that  contains  12.5  g  of   dissolved  zinc  bromide,  ZnBr2?  (convert  mL  to  L  first!)          

 

2  

Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

Bonus:    A  sample  of  oxygen  gas  occupies  a  volume  of  4.02  mL  at  2.5  kPa.     What  will  its  pressure  be  if  the  volume  decreases  to  1.5  mL?                 Part  II.    Definitions.    Define  each  term.       1.    Reactant.         2.    Product.         3.    Endothermic  reaction.             4.    Exothermic  reaction.         5.    Catalyst.         6.    Inhibitor.         7.    Enzyme.              

3  

Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

8.    Chemical  equilibrium.         9.    Le  Châtelier’s  principle.         10.    Solute.         11.    Solvent.         12.    Polar  compound.         13.    Nonpolar  compound.         14.    Hydrogen  bonding.         15.    Solubility.         16.    Concentration.         17.    Unsaturated.        

4  

Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

18.    Saturated.         19.    Supersaturated.         Bonus:  Define  orbital  OR  valence  electron  OR  polyatomic  ion  OR   kinetic  energy  OR  temperature  OR  radical.           Part  III.    Short  answers,  tables  and  plots.     1.   Identify  each  of  the  following  reactions  as  exothermic  or   endothermic.     CH4(s)  +  2O2(g)  →  CO2(g)  +  2H2O(l)   ΔH°  =  -­‐890  kJ         2HCl(g)  →  H2(g)  +  Cl2(g)     ΔH°  =  185  kJ           4NH3(g)  +  5O2(g)  →  4NO(g)  +  6H2O(l)     ΔH°  =  -­‐1169  kJ         2.    Balance  the  following  equations  and  indicate  the  type  of  reaction   taking  place  (synthesis,  decomposition,  combustion,  single-­‐ displacement  or  double-­‐displacement).     a.   ____  H2SO4  +  ____  NaOH  →  ____  Na2SO4  +  ____  H2O     Type  of  reaction:  ____________________       b.   ____  Fe  +  ____  S8  →____  FeS     Type  of  reaction:  ____________________      

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Intro.  to  Chem  and  Physics  

c.    

Exam  3  

Zumbo  

____  KClO3  →  ____  KCl  +  ____  O2   Type  of  reaction:  ____________________  

    d.       e.    

____  C2H6  +  ____  O2  →  ____  H2O  +  ____  CO2   Type  of  reaction:  ____________________   ____  Al  +  ____  CuCl2  →  ____  AlCl3  +  ____  Cu   Type  of  reaction:  ____________________  

    3.  Which  half-­‐equation  contains  a  reducing  agent  and  which  contains  an   oxidizing  agent?     a. Cu  →  Cu2+  +  2e–         b. 2e–  +  2Ag+  →  2Ag       4.    Name  6  factors  that  affect  the  rate  of  a  reaction.    State  how  each   factor  affects  the  rate.     a.     •       b.     •       c.     •       d.     •            

6  

Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

e.     f.      

•     •    

    5.    Consider  the  below  reaction.    The  forward  reaction  releases  energy,   whereas  the  backward  reaction  absorbs  energy.    If  the  temperature  of   the  reaction  is  increased,  which  reaction  will  be  favored  according  to  Le   Châtelier’s  principle?       N2+3H2  ↔  2NH3             ΔH°  =  -­‐22.1  k.cal         6.    Write  the  appropriate  charges  on  the  water  molecule  below,  and   explain  why  the  individual  H—O  bonds  are  very  polar.      

        7.    Explain  what  happens  when  sodium  chloride,  NaCl,  dissolves  in   water.    Why  does  this  occur?                    

 

7  

Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

8.      Which  solvent,  water  or  carbon  tetrachloride,  best  dissolves  iodine?     Why?    Water  is  polar,  while  both  iodine  and  carbon  tetrachloride  are   not.             9.    Complete  the  below  concept  map.      

mixtures   can  be  

___________  

___________  

which  can  be  

also  called  

___________   which  

___________  

___________  

___________  

which  

___________  

      10.    How  might  knowledge  of  chemical  reactions  or  the  dissolution   process  be  useful  in  everyday  life?              

 

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Intro.  to  Chem  and  Physics  

Exam  3  

Zumbo  

Bonus:    Elements  can  be  classified  into  families.     a. Complete  the  following  concept  map  (consider  part  c).   b. For  each  major  family,  list  two  defining  features.   c. For  each  major  family,  draw  an  arrow  encompassing  each   subfamily  indicating  increasing  reactivity   d. For  each  subfamily,  name  the  periodic  group  or  groups  that  are   represented.    

elements  

  ___________  

___________  

___________  

  ___________  

___________  

___________  

___________  

___________  

        End  of  Exam  Bonus:  What  did  you  find  interesting  from  chapters  6  and   7?        

 

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