of Hydrogen Deficiency - Index of [PDF]

for each atom of a Group 5 element (N, P), add one hydrogen. Problem: isopentyl acetate has a molecular formula of. C7H1

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Idea Transcript


CH 310 N

The index of hydrogen deficiency (IHD): the sum of the number of rings and pi bonds in a molecule To determine IHD, compare the number of hydrogens in an unknown compound with the number in a reference hydrocarbon of the same number of carbons and with no rings or pi bonds the molecular formula of the reference hydrocarbon is CnH2n+2

IH D =

(H

re fe re n c e

- H

m o le c u le )

2

• for each atom of a Group 7 element (F, Cl, Br, I), add one H • no correction is necessary for the addition of atoms of Group 6 elements (O,S) to the reference hydrocarbon • for each atom of a Group 5 element (N, P), add one hydrogen

Problem: isopentyl acetate has a molecular formula of C7H14O2. Calculate its IHD • reference hydrocarbon C7H16 O O • IHD = (16-14)/2 = 1 Isopentyl acetate

Problem: calculate the IHD for niacin, molecular formula C6H6N2O • reference hydrocarbon C6H16 O • IHD = (16 - 6)/2 = 5 N H2 N Niacin 1

Revision on:1/29/2008

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