SAFETY DATA SHEET according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
Section 1
MOL-LUB Ltd.
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
Date of issue: 20. 02. 2009
Page: 1/(14)
Identification of the mixture/substance and of the company/undertaking
1.1
Product identifier: MOL ThermoFluid HTF industrial heat transfer fluid concentrate
1.2
Relevant identified uses of the mixture or substance and uses advised against Relevant identified uses: industrial heat transfer fluid concentrate Uses advised against: no data
1.3 Details of the supplier of the safety data sheet: MOL-LUB Lubricant Production Trade and Service Limited Liability Company H-2931 Almásfüzitő, Fő út 21., Hungary Phone / Fax: +36 34 526 330 / +36 34 526 391 E-mail:
[email protected] Request SDS of: MOL-LUB Lubricant Production Trade and Service Limited Liability Company Customer Service Center H-2931 Almásfüzitő, Fő út 21., Hungary Phone / Fax: +36 80 201 296 / +36 34 348 010 Responsible for SDS: MOL-LUB Ltd. Csaba Horváth, head of SD, HSE & Business Support Phone: +36 34 526 343; Mobile: +36 20 474 2644 e-mail:
[email protected]
1.4 Emergency telephone number Emergency telephone (07-1520 h): +36 34 526 210 (CET) on workdays Health Toxicological Information Service (ETTSZ 1096 Budapest, Nagyvárad tér 2.) Tel.: 36 80 201 199 (0-24 h, free number). National Health Toxicological Information Service:
SAFETY DATA SHEET according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
MOL-LUB Ltd.
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
Section 2
Date of issue: 20. 02. 2009
Page: 2/(14)
Hazards identification
2.1
Classification of the mixture or substance Hazard Class and Category: Hazard statement: Acute Tox. 4 H302 Harmful if swallowed. STOT RE 3 H373 May cause damage to kidneys through prolonged or repeated exposure. Repr. 2 H361d Suspected of damaging fertility. Suspected of damaging the unborn child. Eye Irrit. 2 H319 Causes serious eye irritation.
2.2
Label elements Product identification: Trade name: Hazardous substance(s):
MOL ThermoFluid HTF concentrate
industrial heat transfer fluid
Ethanediol (CAS No: 107-21-1) 2-ethylhexanoic acid, sodium salt (CAS No: 19766-89-3) Disodium tetraborate pentahydrate (CAS No: 12179-04-3)
GHS Pictogram:
Signal word: Hazard statement: H302 H373 H361d H319
Warning Harmful if swallowed May cause damage to kidneys through prolonged or repeated exposure. Suspected of damaging fertility. Suspected of damaging the unborn child. Causes serious eye irritation.
Supplemental hazard information: Precautionary statements – General: -
SAFETY DATA SHEET MOL-LUB Ltd.
according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
Date of issue: 20. 02. 2009
Page: 3/(14)
Precautionary statements - Prevention Obtain special instructions before use. P201 Do no eat, drink or smoke when using this product. P270 Avoid release to the environment. P273 Wear protective gloves, protective clothing, eye protection. P280 Precautionary statements - Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. P337 + P313 IF SWALLOWED: Call a POISON CENTER or doctor/physician if P301+312 you feel unwell. IF exposed or concerned: Get medical advice/attention. P308 + P313 Precautionary statements – Storage: Precautionary statements - Disposal Dispose of contents/container in accordance with national regulation. P501 Other liabilities for labelling: Tactile warning of danger: Not distributed for population. Transport classification: see section 14. 2.3
Other hazards The product does not contain any PBT or vPvB substance according to annex XIII of regulation (EC) 1907/2006.
Section 3 3.2
Composition/information on ingredients
Mixtures Chemical description: Ethylene glycol with additives, colouring agent, diluted with water. Component(s) / Hazardous component(s): Name Ethanediol REACH Registr. Nr.: 01-2119456816-28 On the SVHC List: Disodium tetraborate pentahydrate 2-ethylhexanoic acid, sodium salt
EU number
CAS number
Hazard classes and cat.
Hazard statements
Conc. %(m/m)
203-473-3
107-21-1
Acute Tox. 4 STOT RE 2
H302 H373
80-98
-
12179-04-3
Eye Dam. 1 Repr. 1B
H318 H360FD
100 mg/l >100 mg/ l >100 mg/l
(Literature) (Literature) (Literature)
>1000 mg/l
(Literature)
SAFETY DATA SHEET MOL-LUB Ltd.
according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
12.2
12.3 12.4
12.5 12.6
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
Persistence and degradability Biodegradability: Bioaccumulative potential Mobility Mobility in soil: Mobility in water: Results of PBT and vPvB assessment Other adverse effects Biological oxygen demand: Chemical oxygen demand: Heavy metal content: PCT, PCB and other chlorinated hydrocarbons: Effects on activated sludge:
Environmental effects: Water hazard class (German): Section 13
Date of issue: 20. 02. 2009
Page: 10/(14)
> 70 %, DOC decrease (OECD 301 A) (28 day), readily degradable (Literature). Has low bioaccumulation (ethylene glycol). Large spills to soil can contaminate groundwater. No data available. Does not contain PBT and vPvB substances. Ethanediol: Ethanediol: None. None.
BOD: COD:
0,81 g/g 1,29 g/g
(Literature) (Literature)
The product can be disposed in wastewater treatment plant – biological stage of treatment (activation) after dilution in the ratio 1:1000 and after approval of relevant authority and manager of the sewer. Do not empty into waterways without disposal. WGK 1 (Classification by VwVwS)
Disposal considerations
13.1 Waste treatment methods Product disposal: Wastes of the product or used oil should be treated as hazardous waste. Waste Identification Code: 16 01 14* Antifreeze fluids containing dangerous substances. Recommended waste treatment method: incineration Packaging disposal: Containers with product residue should also be treated as hazardous waste according to national and local disposal regulations. Waste Identification Code: 15 01 10* Packaging containing residues of or contaminated by dangerous substances.
SAFETY DATA SHEET according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
MOL-LUB Ltd.
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
Date of issue: 20. 02. 2009
Page: 11/(14)
Disposal must be in compliance with national and local regulations. Wastewater: Quality of wastewater emitted to natural water must comply with national and local regulations. Care should be taken in any case to ensure compliance with EC, national and local regulations. It is the responsibility of the user to know all relevant national and local regulations. Section 14
Transport information
Land transport: Road/ Railway 14.1. 14.2. 14.3. 14.4. 14.5. 14.6.
ADR/RID:
UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for user:
Not classified. -
Waterways: Inland waterways/ Sea transport ADN/IMDG:
Not apply to the product.
Air transport:
Not apply to the product.
Section 15
ICAO / IATA:
Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the mixture. This safety data sheet has been prepared according to Regulation (EC) No 1907/2006 (mod.: 2015/830/EU) and to Regulation (EC) 1272/2008. 15.2 Chemical safety assessment. not available
SAFETY DATA SHEET according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
16 Section
MOL-LUB Ltd.
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
Date of issue: 20. 02. 2009
Page: 12/(14)
Other information
The information given in this data sheet is based on our best knowledge at the time of publication. The information is related only to this product and is intended to assist its safe transport, handling and use. The given physical and chemical parameters describe the product only for the purpose of safety requirements and therefore should not be construed as guaranteeing any specific property of the product or as being part of a product specification or any contract. The manufacturer or supplier shall not take responsibility for any damages from the use other than recommended or other misuse of the product. It is the responsibility of the user to keep regulatory precautions and observe recommendations for safe use of the product. Source of data presented in this material safety data sheet: Test results of this product Material safety data sheets of product’s components Hungarian lists of dangerous substances, 1272/2008/EC regulation, Annex XVII. of REACH Relevant Hungarian regulation and EU directives Classification for mixtures and used evaluation method according to regulation 1272/2008/EC (CLP) Acute Tox. 4 STOT RE 3 Repr. 2 Eye Irrit. 2
H302 H373 H361d H319
calculation method calculation method calculation method calculation method
The full text of each relevant H- phrase and Hazard classes and cat. in Section 3.: H302 H318 360FD H361d H373
Harmful if swallowed. Causes serious eye damage. May damage fertility. May damage the unborn child. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure.
SAFETY DATA SHEET according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
MOL-LUB Ltd.
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
Acute Tox. 4 Eye Dam. 1 Repr. 1B Repr. 2 STOT RE 2
Date of issue: 20. 02. 2009
Page: 13/(14)
Acute toxicity Category 4 Serious eye damage/eye irritation Category 1 Reproductive toxicity Category 1B Reproductive toxicity Category 2 Specific target organ toxicity – repeated exposure Category 2
Legend: ADN ADR ATE BCF BOD Bw C&L CAS CLP CMR COD CSA CSR DMEL DNEL ECHA Ecx ErC50 Edx EC EC number ELINCS ES ESIS IARC IATA IMDG LCx LDx LOAEC LOAEL LOEC
European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways European Agreement concerning the International Carriage of Dangerous Goods by Road Acute Toxicity Estimate Biocontrentration Factor Biological Oxygen Demand Body Weight Classification and Labeling Chemical Abstracts Service Classification, Labelling and Packaging (1272/2008/EC) Carcigonic, Mutagenic or toxic to Reproduction Chamical Oxygen Demand Chemical Safety Assessment Chemical Safety Report Derived Minimal Effect Level Derived No Effect Level European Cheamicals Agency Effective Concentration x% EC50 in terms of reduction of growth rate Effective Dose x% European Community European Community number European List of Notified Chemical Substances Exposure Scenario European Chemical Substances Information System International Agency for Research on Cancer International Air Transport Association International Maritime Dangerous Goods Lethal Concentration x% Lethal Dose x%) Halálos dózis x% Lowest Observed Adverse Effect Concentration Lowest Observed Adverse Effect Level Lowest Observed Effect Concentration
SAFETY DATA SHEET according to regulation 1907/2006/EC (REACH) and 1272/2008/EC
Trade name: Version: 4
MOL-LUB Ltd.
MOL ThermoFluid HTF industrial heat transfer fluid concentrate Latest revision: 04. 04. 2017
LOEL NOEC NOEL NLP NOAEL OECD PBT PNEC ppm REACH RID SVHC UVCB VOC vPvB
Date of issue: 20. 02. 2009
Page: 14/(14)
Lowest Observed Effect Level No observed effect concentration No observed effect level No-Longer Polymer No Observed Adverse Effect Level Organisation for Economic Cooperation and Development Persistent Bioaccumulative and Toxic Predicted No-Effect Concentration parts/million Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations concerning the International carriage of Dangerous Goods by Rail Substance of Very High Concern substance of unknown or variable composition, complex reaction products or biological materials Volatile organic compounds Very Persistent and very Bio-accumulative
Revision Indicators: Section 3 9 1-16 3 9 1 3 9 1-16
Subject of change Composition/information on ingredients Physical and chemical properties Revision modification according to 453/2010/EC and 1272/2008/EC and Composition/information on ingredients Physical and chemical properties Details of the supplier of the safety data sheet, Responsible for SDS Composition/information on ingredients Physical and chemical properties Other corrections, revision modification according to 2015/830 /EU
Date
Version
07.07.2012
2
30.10.2012
3
04.04.2017
4