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United States International Trade Commission

SYNTHETIC ORGANIC CHEMICALS United States Production and Sales, 1991 USITC PUBLICATION 2607 February 1993

Seventy-Fifth Annual Edition

UNITED STATES INTERNATIONAL TRADE COMMISSION

COMMISSIONERS Don E. Newquist, Chairman Peter S. Watson, Vice Chairman David B. Rohr Anne E. Brunsdale Carol T. Crawford Janet A. Nuzum

Office of Operations Robert A. Rogowsky, Director Office of Industries Vern Simpson, Director

This report was prepared principally by Cynthia B. Foreso, Jesse Lawrence Johnson, Dr. Aimison Jonnard, Eric Land, Edward Matusik, David Michels, Denby L. Misurelli, Elizabeth R. Nesbitt, James Raftery, Robert Randall, and Cynthia Trainor. Assistance in the preparation of the report was provided by Kenneth R. Kozel, Gwen L. Bennett, Brenda Carroll, Elaine T. Freeman, Lemuel Shields, and Darlene Smith. Data Processing was provided by James Gill, and Annie Sams. Electronic publishing and design was provided by Pamela Chase, Keven Blake, Joyce Bookman, and Paulette Henderson.

Address all communications to Secretary to the Commission United States International Trade Commission Washington, DC 20436

UNITED STATES INTERNATIONAL TRADE COMMISSION

SYNTHETIC ORGANIC CHEMICALS United States Production and Sales, 1991

USITC Publication 2607

Synthetic Organic Chemicals, 1991

CONTENTS Page

Introduction

1

Summary

3

General

5

Sections 1. Coal tar, tar crudes, and pitches 2. Primary products from petroleum and natural gas for chemical conversion 3 Cyclic intermediates 4. Dyes 5. Organic pigments 6. Medicinal chemicals 7. Flavor and perfume materials 8. Plastics and resin materials 9. Rubber-processing chemicals 10. Elastomers 11. Plasticizers 12. Surface-active agents 13. Pesticides and related products 14. Miscellaneous end-use chemicals and chemical products 15. Miscellaneous cyclic and acyclic chemicals

1-1 2-1 3-1 4-1 5-1 6-1 7-1 8-1 9-1 10-1 11-1 12-1 13-1 14-1 15-1

Appendixes A. Directory of manufacturers B. Cyclic intermediates: Glossary of synonymous names C. Synthetic Organic Chemicals, U.S. production and sales, 1991, harmonized system basis Alphabetical chemical index D.

A-1 B-1 C-1 D-1

Synthetic Organic Chemicals, 1991

Introduction This is the 75th annual report of the U.S. International Trade Commission on domestic production and sales of synthetic organic chemicals and the raw materials from which they are made. The report. along with the quarterly report titled Preliminary Report on U.S. Production of Selected Synthetic_Organic Chemicals (Including Synthetic Plastics and Resin Materials), is prepared under investigation No. 332-135, Synthetic Organic Chemicals Reports. This investigation is conducted under the authority of section 332(g) of the Tariff Act of 1930 (19 U.S.C. 1322(g)). for the purpose of collecting data and preparing public reports on synthetic organic chemicals, plastics materials. medicinal chemicals, pesticides, and other organic chemical products. The annual report consists of 15 sections, each covering a specified group (based principally on use) of organic chemicals as follows: Tar and tar crudes; primary products from petroleum and natural gas for chemical conversion; cyclic intermediates; dyes; organic pigments; medicinal chemicals; flavor and perfume materials; plastics and resin materials; rubber-processing chemicals; elastomers; plasticizers; surface-active agents; pesticides and related products; miscellaneous end-use chemicals and chemical products; and miscellaneous cyclic and acyclic chemicals. Data have been supplied by approximately 698 producers. Each of the 15 sections is headed by a summary of the statistical data The first table in each section gives statistics on products and groups of products in as great detail as is possible without revealing the operations of individual producers. Statistics for an individual chemical or group of chemicals are given only when there are three or more producers, no one or two of which may be predominant. Moreover, even when there are three or more producers, statistics are not given if there is any possibility that their publication would violate the statutory provisions relating to unlawful disclosure of information accepted in confidence by the Commission.' Data are reported by producers for only those items where the volume of production or sales or value of sales exceeds certain minimums. Those minimums are 450 kilograms of production or sales or $1,000 of value of sales for organic pigments, medicinal chemicals, flavor and perfume materials, rubber-processing chemicals, elastomers, and those chemicals whose end-use is not readily determinable; 2,250 kilograms or $5,000 for tar and tar crudes, petroleum and natural gas products. dyes, plasticizers, surface-active agents, and pesticides; 4,500 kilograms or $10,000 for cyclic intermediates and miscellaneous cyclic and acyclic chemicls; 9,000 kilograms or $20,000 or miscellaneous end-use chemicals and products; and 22,500 kilograms or $50,000 or plastics materials, Data are usually supplied in terms of undiluted materials; however, for reporting purposes, products of 95 percent or greater purity are considered to be 100 percent pure Commercial concentrations are applicable for dyes, certain plastics and resins, and a few solvents; such concentrations are specifically noted. 1

U.S.C. § 1905 and 44 U.S.C. §3508.

The statistics given in this report include data from all known domestic producers of the items covered and include the total output of each company's plants, i.e., the quantities produced for consumption within the producing plant, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, therefore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to changes in inventory. The second table in each section lists all items for which data on production or sales have been reported. by primary manufacturers, identified by manufacturers' codes. Each code consists of not more than three capital letters and is assigned on a permanent basis. The third table in each section is a directory, alphabetized by the codes of the manufacturers reporting in that section. Appendix A is a directory, alphabetized by the names of the manufacturers reporting in all sections and which includes their general corporate phone numbers and office addresses. Appendix B lists synonymous names for cyclic intermediates. Information on synonymous names of the organic chemicals included m this report may be found in the SOCMA Handbook: Commercial Organic Chemical Names. published by the Chemical Abstracts Service of the American Chemical Society, or the Colour Index (Revised Third Edition), published jointly by the Society of Dyes and Colourists and the American Association of Textile Chemists and Colorists. Appendix C presents the data in this report aggregated in the format of the Harmonized System (HS) nomenclature on a 6-digit HS basis. Appendix D is an alphabetical index of all the products in this edition of the report. Data contained in this report are compiled primarily from Commission questionnaires sent to domestic producers and represent the best data available to the Commission. While the data supplied in the questionnaires are checked against data previously supplied by the submitting firm and with data supplied by other domestic producers, data are not independently verified by direct Commission examination of the books of companies furnishing information. Data contained in this report should not be used for investment and other purposes without independent verification. As specified in the reporting instructions sent to manufacturers, production and sales (unless otherwise specified) are defined as follows: Production is the total quantity of a commodity made available by original manufacturers only within the customs territory of the United States (includes the 50 states, the District of Columbia, and Puerto Rico). It covers synthetic organic chemicals. specified crudes from petroleum and coal tar, and certain chemically described natural products, such as alkaloids, enzymes, and perfume isolates. It is the sum—expressed in terms of 100% active ingredient unless otherwise specified in the reporting instructions—of the quantities:

Introduction Produced, separated, and consumed in the same plant or establishment. A commodity is considered separated either when it is isolated from the reactive system or when it is not isolated, but weighed, analyzed, or otherwise measured. This includes by-products and co-products that are not classifiable as waste materials; . Produced and not isolated, but directly converted to a finished or semifinished item not included in this report (e.g., polyester film, polyurethane tires, nylon fiber, bar soap, etc.). (See specific instructions in individual sections); Produced and transferred to other plants or establishments of the same fine or 100% owned subsidiaries or affiliates; Produced and sold to. or bartered with, other firms (including less than 100% owned subsidiaries); Produced for others under toll agreements (see general instructions); and Produced and held in stock. PRODUCTION EXCLUDES: Purification of a commodity, which is purchased by. or transferred from within, the company, unless inclusion of such processing is specifically requested in the reporting instructions for individual sections; Intermediate products which are formed in the manufacturing process, but are not isolated from the reaction system—that is, not weighed, analyzed, or otherwise measured;

2

except such products as described above as being produced and not isolated, but directly converted to a finished or semifinished item. Materials that are used in the process but which are recovered for re-use or sale; Waste products having no economic significance. SALES are actual quantifies of commodities sold by original manufacturers only. Sales include the quantity and value of: Shipments of a commodity for domestic use or for export, or segregation in a warehouse when title has passed to the purchaser in a bona fide sale; Shipments of a commodity produced for a company by others under toll agreement; Shipments to subsidiary or affiliated compajnies, provided the ownership is less than 100%. SALES EXCLUDE: All intra-company transfers within a corporate entity; All shipments to 100% owned subsidiary or affiliated companies; All resales of imported or purchased material, including materials obtained by barter; All shipments of commodity produced for others under toll agreements. VALUE OF SALES is the net dollar receipts of sales f.o.b. plant or warehouse, or delivered. F.o.b. values were preferred, but if they are not readily available from company records, delivered values were acceptable.

Synthetic Organic Chemicals, 1991

Summary Combined production of all synthetic organic chemicals, coal tar and crudes, and primary products from petroleum and natural gas in 1991 was 177,828 million kilograms-a decrease of 1.0 percent from the output in 1990. Sales of these materials in 1991, which totaled 101,236 million kilograms, valued at $85,464 million, were 0.4 percent less than in 1990 in terms of quantity and 8.2 percent less in terms of value. These figures include data on production and sales of chemicals measured at several successive steps in the manufacturing process, and, therefore, they necessarily reflect some duplication. During 1987-91, the total output of these products rose each year since 1987 (figure 1). During that period the output of these products generally followed the trend of the Federal Reserve Board Index of U.S. Production, except for 1989. In 1991, production of all synthetic organic chemicals, including cyclic intermediates and finished products totaled 122,971 million kilograms, or 3.2

percent less than the output in 1990. Three sections showed an increase in production in 1991 over 1990: medicinal chemicals (184 million kilograms) increased by 27.8 percent; flavor and perfume materials (69 million kilograms) increased by 15.0 percent; cyclic intermediates (24,103 million kilograms) increased by 0.5 percent; of the remaining sections, pesticides and related products (452 million kilograms) showed a decreased of 19.9 percent; rubber-processing chemicals (155 million kilograms) decreased 13.4 percent; surface-active agents (3,379 million kilograms) decreased 11.0 percent; miscellaneous end-use chemicals and chemical products (13,467 million kilograms) decreased 10.2 percent; plasticizers (828 million kilograms) decreased 7.1 percent; plastics and resin materials (28,253 million kilograms) decreased 6.0 percent; dyes (111 million kilograms) decreased 5.3 percent; elastomers (synthetic rubber) (2,166 million kilograms) decreased 3.0 percent; organic pigments (51 million kilograms) decreased 2.4 percent; and miscellaneous cyclic and acyclic chemicals (49,754 million kilograms) decreased 0.4 percent in 1991 from that in 1990.

Table 1 Synthetic organic chemicals and their raw materials: U.S. production and sales, 1990 and 1991 Sales Production

Value

Quantity Or

Decrease (-),1991

Over

Over

Chemical

Grand total Coal tar and crudes Primary products from petroleum and natural gas Synthetic organic chemicals, total 3 Cyclic intermediates Dyes Organic pigments Medicinal chemicals Flavor and perfume materials Plastics and resin materials Rubber-processing chemicals Elastomer (synthetic rubber) Plasticizers Surface-active agents Pesticides and related products Miscellaneous end-use chemicals and chemical products Miscellaneous cyclic and acyclic chemicals

Increase or decrease (-),1991 over 19901

Increase or decrease (-),1991

Increase

1990

1991

19901

1990

1991

19901

1990

1991

Million kilograms

Million kilograms

Percent

Million kilograms

Million kilograms

Percent

Million dollars

Million dollars Percent

179,546

177,828

-1.0

101,624

101,236

-0.4

93,092

85,464

-8.2

843

759

-10.0

(2)

(2)

(2)

(2)

(2)

(2)

51,722

54,098

4.6

26,914

27,640

2.7

11,206

9,634 -14.0

126,981 23,996 117 53 144

122,971 24,103 111 51 184

-3.2 0.4 -5.3 -2.4 27.8

74,710 11,866 104 45 107

73,596 11,494 107 39 133

-1.5 -3.1 2.8 -11.9 24.3

81,886 10,981 775 717 2,169

75,830 -7.4 7,588 -30.9 761 -1.8 644 -10.3 9.5 2,376

60

69

15.0

37

39

5.4

992

925

-6.8

30,053

28,253

-6.0

25,729

24,787

-3.7

30,529

28,141

-7.8

179

155

-13.4

136

114

-16.2

458

457

-0.2

2,233 891 3,795

2,166 828 3,379

-3.0 -7.1 -11.0

1,555 827 1,930

1,529 810 2,028

-1.7 -2.1 5.1

3,128 967 2,193

2,979 1,052 2,257

-4.8 8.8 2.9

557

452

-19.9

442

445

0.7

4,774

4,019 -15.8

14,992

13,467

-10.2

10,737

10,712

-0.2

9,711

9,938

2.3

49,912

49,754

-0.4

21,197

21,359

0.7

14,492

14,690

1.3

I Percentage calculated from figures rounded to thousands. 2 Not available 3 Because of rounding, figures may not add to the totals shown. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

3

Summary

Figure 1-1 Synthetic organic chemicals and their raw materials, total production, vs FRB Industrial production index Billions of kilograms •• 120

200-

100

160-

80 120-

60 80Chemical production

40

0— FRB index (1987=100)

4020

1987

1988

1989

1990

Source: Production, U.S. International Trade Commission, Synthetic Organic Chemicals: United States Production and Sales; FRB Industrial Production index, The Board of Governors of the Federal Reserve System.

4

1991

0

Synthetic Organic Chemicals, 1991

General In this report, synthetic organic chemicals are classified on the basis of their principal use as follows: Cyclic intermediates, dyes, organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic rubber), plasticizers, surface-active agents, pesticides and related products, miscellaneous end-use chemicals and chemical products, and miscellaneous cyclic and acyclic chemicals. Most of these groups are further subdivided either by use or by chemical composition. As intermediates, chemicals are used in the manufacture of fmished products. Aggregate figures that cover both intermediates and finished products, therefore, necessarily include considerable duplication. Total production of synthetic organic chemicals (intermediates and finished products combined) in 1991 was 122,971 million kilograms, or 3.2 percent less than the output of 126,981 million kilograms reported for 1990, and 55.3 percent more than the output of 79,144 million kilograms reported in 1977 (table 2). Sales of synthetic organic chemicals in 1991

amounted to 73,596 million kilograms, valued at $75,830 million, compared with 74,711 million kilograms, valued at $81,886 million, in 1990, and 44,378 million kilograms, valued at $32,434 million, in 1977. Production of all cyclic (ring chemical structure) products (intermediates and finished products combined) in 1991 totaled 38,789 million kilograms, or 0.01 percent less than the 38,823 million kilograms reported for 1990, and 122.2 percent more than the 17,451 million kilograms reported for 1977; however, the transfer of eight items, in 1979, from the primary products from petroleum and natural gas section to the section on cyclic intermediates has caused the output of cyclic products to appear much higher in relation to 1977 than would otherwise have resulted. Production of all acyclic (linear or branch chemical structure) products in 1991 totaled 82,016 million kilograms, or 4.6 percent less than the 85,925 million kilograms reported for 1990, and 38.8 percent more than the 59,057 million kilograms reported for 1977. Differences in trends between cyclic and acylic products reflect the aggregation of changes in usage of individual chemicals rather than preferences for cyclic versus acyclic chemicals.

Table 2 Synthetic organic chemicals: Summary U.S. production and sales of intermediates and finished products, 1977, 1990, and 1991 (Production and sales in thousands of kilograms; sales value in thousands of dollars) Increase or decrease (-) Chemicals

19771

1990

1991 over 1977

1991

1991 over 1990

Organic chemicals, cyclic and acyclic, total:

Production

79,144,460

Sales Sales value Cyclic, total:2

44,378,105 32,434,301

126,980,989 74,710,337 81,885,632

122,970,963 73,596,362 75,829,690

55.3 65.8 133.7

-3.2 -1.5 -7.4

Production Sales Sales value Acyclic, total: 2

17,451,083 10,833,542 13,410,029

38,823,382 23,567,459 37,221,177

38,788,700 23,143,961 33,433,914

122.2 113.6 149.3

-0.01 -1.8 -10.2

Production

59,056,510 31,649,694 17,084,012

85,924,531 49,587,756 41,536,592

82,016,099 48,923,274 39,416,469

38.8 54.5 130.7

-4.6 -1.4 -5.2

8,493,888 3,622,331 2,596,627

23,995,795 11,865,617 10,980,553

24,103,470 11,494,041 7,588,484

183.8 217.3 192.2

0.4 -3.1 -30.9

119,917 115,448 689,992

117,135 103,897 775,352

110,961 106,813 761,415

-7.5 -7.5 10.4

-5.3 2.8 -1.8

31,165 26,052

52,551 44,773

267,747

717,194

Sales Sales value 1. Cyclic intermediates

Production Sales Sales value 2. Dyes

Production Sales Sales value 3. Organic Pigments Production Sales

Sales value

51,311

64.6

-2.4

39,426 643,561

51.3 140.4

-11.9 -10.3

See footnotes at end of table.

5

General

Table 2-Continued Synthetic organic chemicals: Summary U.S. production and sales of intermediates and finished products, 1977, 1990, and 1991 (Production and sales in thousands of kilograms; sales value in thousands of dollars)

Increase or decrease (-) 1990

Chemicals 4. Medicinal Chemicals Cyclic: Production Sales Sales value Acyclic: Production Sales Sales value 5. Flavors and Perfume Materials Cyclic: Production Sales Sales value Acydic: Production Sales Sales value 6. Plastics and Resin Materials Cyclic: Production Sales Sales value Acydic: Production Sales Sales value 7. Rubber-Processing Chemicals Cyclic: Production Sales Sales value Acyclic: Production Sales Sales value 8. Elastomers (Synthetic Rubber) Production Sales Sales value 9. Plasticizers Cyclic: Production Sales Sales value Acydic: Production Sales Sales value 10. Surface-Active Agents Cyclic:3 Production Sales Sales value Acydic: Production Sales Sales value See footnotes at end of table.

6

1991 over 1977

1991

1991 over 1990

69,819 37,914 718,392

119,726 65,847 1,867,993

136,971 68,947 2,077,635

96.2 81.9 189.2

14.4 4.7 11.2

39,377 35,743 75,626

24,615 41,400 301,351

46,934 64,116 298,758

19.2 79.4 295.1

90.7 54.9 -0.9

26,514 21,232 134,628

39,514 27,867 909,620

42,291 27,881 826,627

59.5 31.3 514.0

7.0 0.1 -9.1

41,715 27,559 72,473

20,417 8,647 81,992

26,552 10,813 98,851

-36.4 -60.8 36.4

30.1 25.1 20.6

4,899,932 4,284,062 4,275,111

8,925,713 7,512,789 12,394,918

8,391,008 7,237,785 11,425,177

71.2 68.9 1672

-6.0 -3.7 -7.8

10,804,977 9,232,677 6,606,712

21,127,193 18,215,939 18,134,437

19,861,543 17,549,151 16,715,652

83.8 90.1 153.0

-6.0 -3.7 -7.8

152,204 91,740 248,756

138,426 104,280 413,253

139,796 99,434 427,997

-8.2 8.4 72.1

1.0 -4.7 3.6

21,076 16,254 29,009

40,181 32,131 44,399

14,800 14,379 29,340

-29.8 -11.5 1.1

-63.2 -55.3 -33.9

2,636,867 1,894,869 1,940,260

2,233,076 1,555,122 3,127,863

2,166,164 1,529,127 2,979,307

-17.9 -19.3 53.6

-3.0 -1.7 -4.8

638,249 630,645 474,781

640,099 644,104 665,385

604,042 604,433 708,491

-5.4 -4.2 49.2

-5.6 -6.2 6.5

174,615 125,784 157,549

250,619 182,423 301,132

223,889 205,494 343,973

28.2 63.4 118.3

10.7 12.7 14.2

448,863 212,933 200,244

1,263,291 1,018,716 813,759

1,356,258 1,033,713 841,648

itt

1,691,285 927,674 674,778

2,531,363 911,544 1,379,089

2,022,904 994,110 1,415,398

{41

4

7.4 1.5 3.4 -20.1 9.1 2.6

Synthetic Organic Chemicals, 1991 Table 2-Continued Synthetic organic chemicals: Summary U.S. produCtion and sales of intermediates and finished products, 1977, 1990, and 1991

(Production and sales in thousands of kilograms; sales value in thousands of dollars) Increase or decrease (-) 1991 over 1990

Chemicals

1991

1977

1991 over 1990

11. Pesticides and Related Products Cyclic: Production Sales Sales value Acyclic: Production Sales Sale value 12. Miscellaneous End-Use Chemicals and Chemical Product Cyclic: Production Sales Sales value Acydic: Production Sales Sales value 13. Miscellaneous Cyclic and Acyclic Chemicals Cyclic: Production Sales Sales value Acyclic: Production Sales Sales value

376,276 313,520 1,664,008

361,202 280,112 3,366,910

300,146 242,171 2,834,941

-20.2 -22.8 70.4

-16.9 -13.5 -15.8

253,099 259,376 1,144,265

195,673 161,453 1,407,435

151,357 203,165 1,184,282

-40.2 -21.7 3.5

-22.7 25.8 -15.9

1,252,527 1,004,105 1,479,800

1,469,599 1,126,028 2,831,664

1,781,761 1,465,992 3,772,391

42.3 46.0 154.9

21.2 30.2 33.2

7,523,638 3,919,801 1,067,681

13,522,424 9,610,721 6,879,700

11,685,032 9,245,939 6,165,975

55.3 135.9 477.5

-13.6 -3.8 -10.4

941,729 473,560 659,943

1,700,331 773,429 1,484,576

1,770,685 723,325 1,525,547

88.0 52.7 131.2

4.1 -6.5 2.8

38,506,728 17,104,826 7,255,919

48,212,046 20,423,498 13,007,057

47,983,088 20,636,107 13,164,240

24.6 20.6 81.4

-0.5 1.0 1.2

1 Standard reference base period for Federal Government general-purpose index numbers. 2 Does not indude data for elastomers. 3 Includes ligninsuffonates. 4 The data for 1977 are not comparable with current data as a result of a change in accounting

procedures. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

The following tabulation shows, by chemical groups, the number of companies that reported production in 1991 of one or more of the chemicals included in each group. Chemical group Cyclic intermediates Dyes Organic pigments Medicinal chemicals Flavor and perfume materials Plastics and resins materials Rubber-processing chemicals

Number of companies 157 30 29 78 26 242 20

Chemical group Elastomers (synthetic rubber) Plasticizers Surface-active agents Pesticides and related products Miscellaneous end-use chemicals and chemicals products Miscellaneous cyclic and acydic chemicals

Number of companies 35 40 135 62 143 240

7

Synthetic Organic Chemicals, 1991

Section 1 Coal Tar, Tar Crudes, and Pitches Coal tar is produced chiefly by the steel industry as a by-product of the manufacture of coke; water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas tars have properties intermediate between those of petroleum asphalts and coal tar. Petroleum asphalts are not usually considered to be raw materials for chemicals. The U.S. International Trade Commission began collecting data on crude coal tar for the 1986 reporting year. In 1991, U.S. production of crude coal tar was 536 million liters. Production of crude light oil was 204 million liters in 1991. Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and oil-gas tar. The most important tar crudes are benzene, toluene, xylene, creosote oil, and pitch of tar. Some of these products

are identical with those obtained from petroleum. Data for materials obtained from petroleum are included, for the most part, with the statistics for like materials obtained from coke-oven gas and tars, and are shown in table 1-1. The domestic production by coke-oven operators of industrial and specification grades of benzene, toluene, and xylene cannot be published since to do so would disclose the operations of individual companies Some of the products obtained from tar and included in the statistics in table 1-1 are obtained from other products for which data are also included in the table. The statistics, therefore, involve considerable duplication, and for this reason no group totals or grand totals are given. Table 1-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 1-3. Data for 1991 tar crudes were supplied by 23 companies and company divisions. Cynthia B. Foreso 202-205-3348

Figure 1-1 Crude Coal tar: U.S. production, 1987-91 Millions of liters 800 700 600 500 400 300 200 100 0

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

1-1

Section 1

Table 1-1 Coal tar, tar crudes, and pitches: U.S. production and sales, 1991

Coal tar, tar crudes and pitches

Crude coal tar (coke-oven operators) Crude light oil: (coke-oven operators) Light-oil distillates: Benzene, all grades, total 2 Coke-oven operators Petroleum refiners Toluene, all grades, total2 Coke-oven operator Petroleum refiners Xylene, all grades, total 2 Coke-oven operator Petroleum refiners Other tar distillate Crude naphthalene (solidifying at 76 ° C to less than 79 ° C) Crude tar acid oils (having a tar acid content of 5% to less than 24%) Creosote oil (Dead oil) (100 percent creosote basis): Distillate as such (100 percent creosote basis) Creosote in coal tar solution (100 percent solution basis) Tar and tar pitches: Pitch of tar - hard

Unit of Quantity

Sales Production

Quantity

Average Unit valuer

Value 1,000 Dollars

1,000 liters

535,885

430,307

48,048

$0.11

1,000 liters

203,741

200,836

27,351

.14

1,000 liters 1,000 liters 1,000 liters 1,000 liters 1,000 liters 1,000 liters 1,000 liters 1,000 liters 1,000 liters 1,000 liters 1,000 liters

(3)

(3)

( 3)

( 3)

(3 )

(3 )

(3)

5,926,290 (3) (3) 3,295,099 (3) (3) 3,138,691 387,790 110,254

4,216,494 (3)

1,397,618

.33

( 3)

( 3)

(3)

(3 )

(3)

1,662,345

405,686

.24

(3)

(3 )

(3)

(3 )

(3 )

(3)

1,352,582 237,975

326,280 41,824

.24 .18

(3)

(3)

( 3)

1,000 liters

9,126

8,145

2,292

.28

1,000 liters

183,713

106,231

21,437

.20

1,000 liters

84,697

123,600

18,095

.15

717

607

1,000 metric ton

(3 )

137,639 226.73

1 Unit value per liter or metric ton as specified.

Includes data for material produced for use in blending motor fuels. The annual production statistics for petroleum refiners on benzene, toluene, and xylene are not comparable with the combined monthly production figures because of fiscal year revisions. 3 Statistics cannot be published; to do so would disclose the operations of individual companies. Note.-Statistics for materials produced in tar and petroleum refineries are compiled by the U.S. International Trade Commission. Data for all other tars and tar crudes are not included in the 1991 report because publication would disclose the operations of individual companies. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 2

Synthetic Organic Chemicals, 1991 Table 1-2 Coal tar, tar crudes, and pitches for which U.S. production and/or sales were reported, identified by Coal tar, tar crudes and pitches Light oil, light oil distillates, and tar bases: Crude light oil: Crude coal tar Crude light oil

Separate statistics1

Manufacturers' identification codes (according to list in table 1-3)

Yes

ABP, ALS, CGU, EKO, GSS, ILI, INL, KPT, LW, NBC, NTS, SGO, TWD, USX, WPS Yes ABP, ALS, BTS, CGU, EKO, GSS, ILI, INL KPT, LTV, NBC, NTS, SGO, TWD, USX, WPS.

Pyridine, tar bases: Benzene (benzol): Tar bases: crude bases (dry basis) All other: All other light-oil distillates Other tar distillates: Naphthalene, crude: Methylnaphthalene Naphthalene, crude, solidifying at less than 74° Naphthalene, crude, solidifying at 76° C to less than 79° C Crude tar acid oils: Crude tar acid oils having a tar acid content of: 5 percent to less than 24 percent Creosote oil (Dead oil): Creosote oil (Dead oil): creosote content in solution (100 percent basis) Creosote oil (Dead oil): creosote in coal tar solution (100 percent solution basis) Creosote oil (Dead oil): distillate as such (100 percent creosote basis) All other distillate products: Crude coal tar solvent Priming and refractory oil All other tar distillates Tar and tar pitches: Tar, road: Tar, road Tar for other uses: Tar for other uses: crude Tar for other uses: refined Pitch of tar: Pitch of tar: hard (M.P. 161° F and over) Pitch of tar: medium (M.P. 110° To 160° F) Pitch of tar: soft (M.P. 80° To 109° F.) All other: All other pitch of tar

No

KPT, USX.

No

LYP.

No No

KPT. BTS, COP, GSS.

Yes

ACS, ART, KPT.

Yes

ACS, INL, KPT.

No

RIL.

Yes

ACS, ART, COP, KPT, RIL.

Yes

ACS, ART, KPT, RIL.

No No No

KPT. BTS, KPT. ACS, GIV.

No

ACS, RIL.

No No

BTS. ACS, KPT, RIL.

Yes No No

ACS, COP, KPT, RIL. ART, COP, RIL. ART, COP.

No

WPS.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Section 1

Table 1-3 Coal tar, tar crudes and pitches: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ABP ACS

Drummond Co Inc Allied Signal, Inc., Engineered Materials Sector Armco, Inc. Aristech Chemical Corp. Bethlehem Steel Corp Citizen Gas And Coke Utility Coopers Creek Chemical Corp Empire Coke Co. Givaudan Corp. Gulf States Steel, Inc. Acme Steel Co Inland Steel Co.

KPT LTV LYP NBC NTS RIL SGO TWD USX

Kopper Industries, Inc. LTV Steel Co., Inc. Lyondell Petrochemical Co. New Boston Coke Corp. National Steel Corp., Great Lakes Div. Reilly Industries, Inc. Shenango, Inc. Tonawanda Coke Corp. U.S. Steel, Div. of USX Clairton Plant Gary Works Wheeling-Pittsburg Steel Corp.

ALS ART BTS CGU COP EKO GIV GSS ILI INL

.

.

WPS

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

1-4

Synthetic Organic Chemicals, 1991

Section 2 Primary Products from Petroleum and Natural Gas for Chemical Conversion Primary products that are derived from petroleum and natural gas are related to the intermediates and finished products made from such primary materials in much the same way that crude products derived from the distillation of coal tars are related to their intermediates and finished products. Many of the primary products derived from petroleum are identical with those derived from coal tar (e.g., benzene, toluene, and mixed xylenes). Considerable duplication exists in the statistics on the production and sales of primary petroleum products because some of these primary chemicals are converted to other primary products derived from petroleum and because data on some production and sales are reported at successive stages in the conversion process. The statistics are sufficiently accurate, however, to indicate trends in the industry. Many of the primary products for which data are included in the statistics may be used either as fuel or as basic materials from which other chemicals are derived. In this report every effort has been made to exclude data on materials that are used as fuel; however, data are included on toluene and mixed xylenes, which may be used in blending aviation and motor fuel. 1 Statistics on chemicals from coal tar are given in Section 1 (Coal tar, tar crudes, and pitches) of this report.

The total production of primary products derived from petroleum and natural gas during 1987-91 is shown in figure 2-1. Beginning in 1988, production and sales data no longer are collected for ethane propane, and butane. Total production for primary products during 1991 amounted to 54,098 million kilograms. The output of aromatic and naphthenic products from petroleum amounted to 12,469 million kilograms in 1991, compared with 12,974 million kilograms in 1990. Sales amounted to $2,362 million in 1991 down from $2,889 million in 1990. In 1991, production of benzene was 5,209 million kilograms; production of toluene was 2,857 million kilograms; and production of mixed xylenes was 2,866 million kilograms (table 2-1). Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas was 41,629 million kilograms in 1991. Sales of these products were valued at $7,272 million. Production of ethylene was 18,123 million kilograms in 1991. The output of 1,3-butadiene was 1,385 million kilograms and propylene production was 9,774 million kilograms during 1991 (table 2-1). Table 2-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. The codes are identified by company name in table 2-3. Data for 1991 primary products from petroleum and natural gas for chemical conversion were supplied by 61 companies or company divisions. James Raftery 202-205-3365

Figure 2-1 Primary products from petroleum and natural gas for chemical conversion U.S. production, 1987-91

Billions of kilograms 60

Note.—Data for 1988-91 do not indude ethane, propane, and butane production. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commision. 2-1

Section 2 Table 2-1 Primary products from petroleum and natural gas for chemical conversion: U.S. production and sales, 1991

Production

Quantity

Value

Average Unit valuer

1,000 kilograms

1,000 kilograms

1,000 dollars

kilogram

Grand total

54,097,917

27,640,421

9,633,676

$0.35

Aromatics and naphthenes2 Total

12,469,213

7,439,511

2,361,625

.32

5,209,209 2,856,521 2,866,253 1,537,230

3,706,298 1,441,087 1,235,178 1,056,948

1,379,618 405,686 326,280 250,041

.37 .28 .26 .24

Aliphatic hydrocarbons Total

41,628,704

20,200,910

7,272,051

.36

C2 Hydrocarbons, totals

18,260,049

6,994,081

2,831,794

.40

Acetylene? (for chemical use only) Ethylene

136,595 18,123,454

63,806 6,930,275

47,197 2,784,597

.74 .40

C3 Hydrocarbons, total8

9,774,421

5,587,526

2,026,443

.36

Propylene9

9,774,421

5,587,526

2,026,443

.36

C4 Hydrocarbons, total .")

6,339,764

4,131,838

1,072,332

.26

Butadiene and butylene fractions 1,3-Butadiene, grade for rubber (elastomers) 1-Butene Isobutane Isobutylene All other C4 hydrocarbons11

1,046,777 1,385,318 425,457 499,319 440,829 2,542,064

693,111 1,387,608 211,628 458,547 201,982 1,178,962

139,031 432,999 92,425 102,503 83,031 222,343

.20 .31 .44 .22 .41 .19

C5 Hydrocarbons, total

1,696,591

904,597

242,277

.27

Isoprene (2-Methyl-1,3-butadiene) Pentenes, mixed All other C5 hydrocathons13

214,070 188,536 1,293,985

163,566

58,213 (12)

(12)

741,031

184,064

.25

All other aliphatic hydrocarbons, derivatives, and mixtures, total

5,557,879

2,582,868

1,099,205

.43

469,025 392,001 157,390

220,439 214,795 142,894 171,827 55,889 77,228 467,294 1,232,502

173,160 168,054 65,950 50,324 18,863 35,506 140,509 446,839

.79 .78 .46 .29 .34 .46 .30 .36

Primary products from petroleum and natural gas for chemical conversion

Benzene, all grades Toluene, all grades3 4 Xylenes, mixed All other aromatics and naphthenes 5

Alpha olefins, C6-C10 Alpha olefins, C11 and higher Dodecene (Tetrapropylene) Hexane n-Heptane Nonene (Tripropylene) n-Paraffins14 All other15 See footnotes at end of table.

2-2

Sales

(12)

52,416 253,756 673,177 3,560,114

(12)

Per

.36

Synthetic Organic Chemicals, 1991 Table 2-1--Continued Primary products from petroleum and natural gas for chemical conversion: U.S. production and sales, 1991

Calculated from rounded figures. The chemical raw materials designated as aromatics are in some cases identical with those obtained from the distillation of coal tar; however, the statistics given in the table above relate only to such materials as are derived from petroleum and natural gas. Statistics on production and/or sales of benzene, toluene, and xylene from all sources are given in table 1-1 of the report on "Coal tar, tar crudes, and pitches." 3 Includes toluene, solvent grade, 90 percent. 4 Includes toluene and xylene used as solvents; may include that which is blended in aviation and motor gasolines. 5 Includes data for alkyl aromatics, crude cresylic acid, cydopentane, naphthalene, naphthenic acid, carbon black feedstock, distillates, solvents, and miscellaneous cyclic hydrocarbons. 6 Ethane production and sales data are no longer collected. 7 Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of the Census. 8 Propane production and sales data are no longer collected. 9 Includes data for refinery propylene. 10 Butane production and sales data are no longer collected. 11 Includes production and/or sales data for 2-butene, mixtures of 1-butene and 2-butene, and mixed C4 streams. 12 Reported data are accepted in confidence and may not be published, or no data were reported. 13 Includes data for mixtures of C5 hydrocarbons, isopentane, n-pentane, 1-pentene, 2-pentene, mixed pentenes, and piperylene. 14 Includes data for the following chain lengths: C6-C9, C9-C15, C10 - C14, C12-C18 and others. 15 Includes production and/or sales data for methane, isoheptanes, isohexane, iso-octane, neohexane, methylcyclopentadiene, mixed hexenes, mixed heptenes, mixed octanes, n-octane, di-isobutylene, mixtures of C2 and C3, C5-C6, C5-C7, C6-C7 hydrocarbons, hydrocarbon derivatives, and other hydrocarbons. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 1

2

Section 2 Table 2-2 Primary products from petroleum and natural gas for chemical conversion for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Primary products from petroleum and natural gas for chemical conversion Aromatics and naphthenes: Alkyl aromatics: Cyclosols All other alkyl aromatics Benzene: Benzene high purity (98-100%)

Separate statisticsi

No No Yes No

Manufacturers' identification codes (according to list in table 2-3)

CXI. SHC. AMO, ASH, CGO, CNE, CSD, CSP, DOW, ENJ, GRS, HES, KHI, LYP, MOC, PLC, PPR, SHC, SIO, SM, SOC, SOG, SUN, SWR, TX, USI, UVN, VST, (2).

All other benzene Cresylic acid (less than 75 percent distilling over 215° C) Cyclopentane Methylcyclopentane Naphthalene Naphthenic acid: Naphthenic acid, acid number 150-199 Naphthenic acid, acid number 200-224 Naphthenic acid, acid number less than 150 Toluene: Toluene high purity (98-100%)

No No No No

KHI. PLC. CNE. CXI, TX.

No No No Yes No

CPS, HEC, MER. MER. HEC, SHC.

All other toluene Xylenes, mixed: Xylene high purity (98-100%)

No Yes No

All other xylene All other aromatics and naphthene: Benzene, toluene, xylene, mixtures Carbon black feedstock All other products from petroleum and natural gas, cyclic

No Yes No No

Aliphatic hydrocarbons: C1 Hydrocarbons: Methane C2 Hydrocarbons: Acetylene (for chemical use only) Ethylene

Yes

C3 Hydrocarbons:

No

No

AMO, ASH, BAS, BFG, CSD, EKX, ELP, ENJ, LYP, OMC, SHC, SOG, UCC, UPM, UTP, VST, (2).

Yes Yes

BCP, RH, UCC, USI. AMO, BAS, BFG, CNE, DOW, DUP, EKX, ELP, ENJ, GE, JVL, KHI, LYP, OMC, PLC, SHC, SM, SOC, SUN, TX, UCC, USI, UTP, VST, WLK.

C4 Hydrocarbons: Butadiene and butylene fractions

Yes Yes

2-4

ATR, ELP. ENJ.

SHO.

Yes No Yes

See footnotes at end of table.

AMO, ASH, CSD, CSP, ENJ, GRS, HES, PLC, PPR, SHC, SOG, SUN, SWR, UNV. AMO, MOC.

No

Hydrocarbons, C2-C3 mixtures Propylene

1,3-Butadiene, grade for rubber (Elastomers) 1-Butene 2-Butene 1-Butene and 2-butene, mixed

ASH, CNE, CSD, ENJ, GRS, HES, KHI, LYP, MOC, PLC, PPR, PPX, SC, SHC SIO, SM,SOC, SOG, SUN, SWR, TX, UVN. ATR, GE, LYP.

Yes Yes No No

CGO, SM. AMO, ASH, BAS, BFG, CCP, CGO, CLK, CNE, CSD, DA, DOW, DUP, EKX, ELP, ENJ, EPC, KHI, LYP, MOC, PLC, SHC, SIO, SM, SOC, SOG, SUN, TX, UCC, UTP, VLR, VST. BAS, CNE, DA, DOW, EKX, PLC, SOC, TX, UCC, USI, UTP, VST. AMO, CNE, ENJ, LYP, SHC, SM, TPC, TX. CNE, ENJ, SHC, SM, SOC, TNA, TPC. TPC. LYP, SHC.

Synthetic Organic Chemicals, 1991 Table 2-2-Continued Primary products from petroleum and natural gas for chemical conversion for which U.S. production and/or sales were reported, Identified by manufacturer, 1991 Primary products from petroleum and natural gas for chemical conversion

Separate statistic&

Manufacturers' identification codes (according to list in table 2-3)

Aliphatic hydrocarbons—Continued C4 Hydrocarbon—Continued Hydrocarbons, C4 fraction Hydrocarbons, C4 mixtures

Isobutane (2-Methyipropane) lsobutylene (2-Methylprqoene) All other hydrocarbons, C4, C5 Hydrocarbons: Hydrocarbons, C5 mixtures

Hydrocarbons, C5-C7 mixtures Isopentane (2-Methylbutane) Isoprene (2-Methyl-1,3-butadiene) n-Pentane 1-Pentene 2-Pentene Pentenes, mixed Piperylene (1,3-Pentadiene) All other hydrocarbons, C5 All other aliphatic hydrocarbons, derivatives, and mixtures: C6 Hydrocarbons: Hexane 1-Hexene Hexenes, mixed Hydrocarbons, C5-C6 mixtures Isohexane Methylcyclopentadiene Neohexane (2,2-Dimethylbutane All other hydrocarbons, C6 C7 Hydrocarbons: n-Heptane Heptenes, mixed Isoheptanes All other hydrocarbons, C7, C8 Hydrocarbons: Di-isobutylene (Di-isobutene) n-Octane Octenes, mixed 2,2,4-Trimethylpentane (Iso-octane) All other hydrocarbons. C8 Cg and above hydrocarbons (except alpha olefins): Dodecene Nonene (Tripropylene) Alpha olefins: Alpha olefins, C6-C10 Alpha olefins, C11 and higher N-paraffins n-Paraffins, C10 -C14 n-Paraffins, C12 - C18 n-Paraffins, C6-C16 n-Paraffins, C6-C9 n-Paraffins, C9-C15 All other n-paraffins Hydrocarbon derivatives: n-Butyl mercaptan (1-Butanethiol) sec-Butyl mercaptan(2-Butanethiol) tert-Butyl mercaptan (2-Methyl-2-propanethiol) Decyl mercaptans Di-tert-butyl disulfide Diethyl sulfide (Ethyl sulfide) Dimethyl sulfide Ethyl mercaptan (Ethanethiol) Isopropyl merman (2-Propanethiol) Methyl ethyl sulfide

No No Yes Yes Yes

TX LYP, PPR, SOG. CSP, DA, MOC, PLC, SHO, SM, SUN, TX. AMO, ATR, ENJ, SHC, TPC, TX. GE, SM, TNA, TX.

Yes No No No Yes No No No Yes No No

LYP. CNE. PLC, SHO. CNE, DOW, ENJ, GYR, LYP, SHC, SOC. CNE, PLC, SHO. DOW. BFG. CSP, CXI, ENJ, PLC, SHO, TX. CXI, LYP. CNE, DOW, ENJ, SHC.

Yes Yes No No No No No No No

ENJ, PLC, SOG, TX, (2). PLC, (2). ENJ. PLC. PLC. ENJ. PLC. DA, PLC, SHC, SM, TNA.

Yes No No No

ENJ, PLC, SOG, TX. ENJ, TX. PLC. EKX, PPR, SHC.

No No No No No

EKT, TPC. SOG. ENJ. LYP, PLC. SHC, TX.

Yes Yes

ATR, CSP, ENJ, SOC, SUN. ATR, CSP, ENJ, SOC, TX.

Yes Yes Yes No No No No No No

SHC, SOC, TNA, TX. SHC, SOC, TNA.

No No No No No No No No No No

PAS, PLC. HAP, PLC. HAP, PAS, PLC. PAS. PLC. HAP, PAS. GAY, PAS. HAP, PAS, PLC. HAP, PAS, PLC. HAP.

SHC. VST. ENJ. SOG. ENJ, SOG, TX. ENJ, SOG, VST.

See footnotes at end of table.

2-5

Section 2 Table 2-2-Continued Primary products from petroleum and natural gas for chemical conversion for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Primary products from petroleum and natural gas for chemical conversion

All other aliphatic hydrocarbons, derivatives, and mixtures:—Continued Methyl mercaptan (Methanethiol) n-Propyl mercaptan (1-Propanethiol) Thiophane (Tetrahydrothiophene) All other hydrocarbon derivatives All other hydrocarbons, C9 and above, including mixtures

Separate statistics

Manufacturers' identification codes (according to list in table 2-3)

No No No No

PAS. PAS, PLC. HAP. PAS, PLC, SHC.

Yes

ENJ, PLC, SOC, TNA.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

2-6

Synthetic Organic Chemicals, 1991 Table 2-3 Primary products from petroleum and natural gas for chemical conversion: Directory of manufacturers, alphabetical by code, 1991

Code

Name of company

Code

Name of company

AMO ASH

Amoco Corp. Ashland Oil, Inc., Ashland Petroleum Co. Atlantic Richfield Co., Arco Chemical Co. BASF Corp. Borden Chemical & Plastics Delaware Limited B. F. Goodrich Co., B. F. Goodrich Chemical Group Crown Central Petroleum Corp. Citgo Petroleum Corp. Clark Oil & Refining Corp. Oxy Petrochemicals, Inc. CPS Chemical Co., Inc. Fina Oil & Chemical Co., Coastal Refining & Marketing, Inc. Chemical Exchange Industries, Inc. Diamond Shamrock Refining & Marketing Dow Chemical Co. E. I. duPont de Nemours & Co., Inc. Eastman Kodak Co.: Tennessee Eastman Co. Div. Texas Eastman Co. Div. Rexene Products Company Exxon Chemical Americas EPC Partners, Ltd. Gaylord Chemical Corp. General Electric, Specialty Chemical Group Citgo Refining & Chemicals, Inc. Goodyear Tire & Rubber Co Helmerich & Payne Inc., Natural Gas Odorizing, Inc. Hew, Inc

HES

Amerada Hess Corp. (Hess Oil Virgin Islands Corp.) Javelin Co. Koch Refining Co. Kalama Chemical, Inc. Lyondell Petrochemical Co. Merichem Co. Marathon Oil Co. Olin Corp. Atochem North America, Inc. Phillips 66 Co. Phillips Puerto Rico Core, Inc. Phillips Paraxylene, Inc. Rohm & Haas Co. Sterling Chemicals, Inc. Shell Oil Co., Shell Chemical Co. Shell Oil Co. BP Oil Company Mobil Oil Corp.: Gas Liquids Dept. Petrochemicals Div. Chevron Corp., Chevron Chemical Co. Phibro Refining Sun Company, Inc. Southwestern Refining Co., Inc. Ethyl Corp. Texas Petrochemicals Corp. Texaco Chemical Co. Union Carbide Corp., Industrial Chemical Div. UOP, Inc. Quantum Chemical Corp., USI Div. Union Texas Product Corp. UNO-VEN Co. Valero Refining & Marketing Co. Vista Chemical Co. Westlake Corp.

ATR BAS BCP BFG CCP CGO CLK CNE CPS CSD CSP CXI DA DOW DUP EKT EKX ELP ENJ EPC GAY GE GRS GYR HAP HEC

JVL KHI KLM LYP MER MOC OMC PAS PLC PPR PPX RH SC SHC SHO SIO SM

SOC SOG SUN SWR TNA TPC TX UCC UPM USI UTP UVN VLR VST WLK

Note—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission

2-7

Synthetic Organic Chemicals, 1991

Section 3 Cyclic Intermediates Cyclic intermediates are synthetic organic chemicals derived principally from petroleum and natural gas and from coal-tar crudes produced by destructive distillation (pyrolysis) of coal. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic chemicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic rubber), pesticides, and plastics and resin materials. Some intermediates, however, are sold as end products without further processing. For example, ethylbenzene may be used as a raw material in the manufacture of styrene. In 1991, about 48 percent of the total output of cyclic intermediates was sold; the rest was consumed chiefly in the producing plants in the manufacture of more advanced intermediates and finished products. The total annual production of cyclic intermediates during 1987-91 is shown in figure 3-1. Total production of cyclic intermediates in 1991 amounted to 24,104 million kilograms, an increase of 1 percent compared with production reported to the Commission

in 1990. Reported sales of cyclic intermediate chemicals in 1991 were 11,494 million kilograms, valued at $7,588 million compared with 11,866 million kilograms, valued at $10,981 million, in 1990. Intermediates that were produced in excess of 500 million kilograms in 1991 were ethylbenzene (4,024 million kilograms). styrene (3.681 million kilograms), terephthalic acid and terephthalic acid, dimethyl ester (3,466 million kilograms), p-xylene (2.427 million kilograms), cumene (1,890 million kilograms). phenol (1,632 million kilograms), cyclohexane (1.047 million kilograms). and bisphenol A (553 million kilograms). Intermediate chemicals produced in excess of 1 billion kilograms accounted for about 75 percent of the total output of cyclic intermediate chemicals produced in 1991. Table 3-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 3-3.

Ed Matusik 202-205-3356

Figure 3-1 Cylic Intermediates: U.S. production, 1987-91 Billions

of kilograms 30

.

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 3-1

Section 3

Table 3-1 Cyclic intermediates: U.S. production and sales, 1991 Sales Cyclic intermediates

Grand total Aniline (Aniline oil) Biphenyl Chlorobenzene, monoCumene Cyclohexane Cyclohexanone o-Dichlorobenzene p-Dichlorobenzene Dicyclohexylamine Dicyclopentadiene (including cydopentadiene) Ethylbenzene Isocyanic acid derivatives, total Toluene-2,4- and 2,6-diisocyanate (80/20 mixture) All other isocyanic acid derivatives 4,4'-lsopropylidenediphenol (Bisphenol A) a-Methylstyrene Nonylphenol Phenol, total From cumene All other phenol Phthalic anhydride Styrene Terephthalic acid, dimethyl ester 3 Tetrahydrofuran o-Xylene p-Xylene All other cyclic intermediates

Production

Quantity

Value

Average Unit value 1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

24,103,470

11,494,041

7,588,484

$0.66

436,021 (2)

285,682 8,143

181,834 5,617

.64 .69

95,315 1,890,456 1,046,505 462,199 19,657 36,664 (2) 65,911 4,023,827

(2)

(2)

1,510,477 935,618 44,718 17,050 42,754 1,344 47,923 159,941

682,426 392215 43,483 15,020 35,013 2,728 19,676 68,089

.45 .42 .97 .88 .82 2.03 .41 .43

462,317

405,610

716,441

1.77

255,471 206,846

217,049 188,561

393,920 322,521

1.81 1.71

552,801 82,116

191,341 18,956 51,311

200,437 11,172 47,497

1.05 .59 .93

1,631,620

889,262

348,059

.39

1,119,556 512,064

558,790 330,472

170,737 177,322

.31 .54

266,277 3,680,516 3,465,695 96,584 347,768 2,426,663 3,014,558

165,764 1,634,357

109,964 951,662

.66 .58 (2) 1.97 .34 .44 .86

(2)

(2)

(2)

48,742 275,874 1,203,450 3,555,724

1 Calculated from unrounded figures. 2 Reported data were accepted in confidence and may not be published, or no data 3 The figure for terephthalic acid, dimethyl ester (DMT) includes both the acid itself

(2)

96,027 92,500 526,315 3,042,309

were reported. and the dimethyl ester without double counting. The acid production figure was multiplied by the factor 1.16 to convert it to equivalent DMT. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Synthetic Organic Chemicals, 1991 Table 3-2 Cyclic intermediates for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Cyclic intermediates Cyclic: p-Acetanisidide Acetoacetanilide o-Acetoacetanisidide o-Acetoacetotoluidide 2',4'-Acetoacetoxylidide Acetoguanamine Acetophenone, tech p-Acetotoluidide 2-Acetylpyridine Aldadiene Alkylbenzenes: Alkylbenzene straight-chain (except dodecyl and tridecyl) Dodecylbenzene (including tridecylbenzene): Dodecylbenzene, straight-chain Dodecylbenzene, other All other alkylbenzene (except dodecyl, tridecyl and straight-chain) Alkylphenols, mixed Alkylpyridines, mixed 4'-Aminoacetanilide (Acetyl-p-phenylenediamine) 3'-Amino-p-acetanisidide p-Aminobenzamide 1-Amino-5-benzamidoanthraquinone o-Aminobenzenethiol p-Aminobenzoic acid, tech 2-Amino-6-benzothiazolesulfonic acid 2-Amino-1 -bromo-3-chloroanthraquinone 7-Aminocephalosporanic acid 1 Amino 2 chlorobenzene 4-Amino-6-chloro-m-benzenedisulfonamide 5-Amino-2-chlorobenzenesulfonic acid 3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 6-Amino-5-chloro-m-toluenesulfonic acid [SO3H=1] (2B acid) 4-Amino-5-methoxy-2-methylbenzenesulfonic acid (5-methyl-o-anisidinesulfonic acid) 4-Amino-4'-(3-methyl-5-oxo-2-pyrazolin-1-y1)-Z2'stilbenedisulfonic acid 2-Amino-2-inethylpropyl 8-bromotheophyllinate 2-Amino-3-methylpyridine 2-Amino-4-methylpyridine 2-Amino-5-methylpyridine 2-Amino-6-methylpyridine 3-Amino-2,7-naphthalenedisulfonic acid 2-Amino-4-nitroacetanilide 2-Amino-5-nitrothiazole 5-Amino-2-[(2-oxo-5-benzimidazolinyl)aminojbenzenesulfonic acid p-Aminophenol p[(p-Aminophenyl)azo]benzenesulfonic acid 3-Aminophenylphosphonic acid 2-Aminopyridine 3-Aminopyridine 4-Aminopyridine 4-Amino-m-toluenesulfonic acid [SO3H=1] 6-Amino-m-toluenesulfonic acid [SO3H=1] 4-Amino-1,2,4-triazole Aniline (Aniline oil) 2-Anilinoethanol Anilinomethanesulfonic acid and salt Anisole, tech -

-

-

Separate statistics's

No No No No No No No No No No

EKT. BRD. BRD, EKT. BRD, EKT. BRD, EKT, PFZ. DIX. S. EK. RIL. SRL.

No No No

Manufacturers' Identification codes (according to list in table 3-3)

MON, PLC. .

MON, VST. MON.

No No No No No No No No No No No No. No No No No

SCN. RIL HCL BUC. NSC. NSC. FMT. NSC, WYK. VPC. PLC. BRS. LMC. MRF. LMC. CWN.

No

DUP, PHC.

No

(2)-

VPC.

No No No No No No No No No

DUP. CHT. RIL RIL RIL RIL. NES. SDC. PCW, SAL

No No No No No No No No No No Yes No No No

BRS, PFZ. MAL. VPC. ICI. RIL RIL. REG, RIL DUP. DUP, PHC. RIL. ART, DUP, FST, ICI, MA1_, RUC, USR. SCP. VPC. CHF.

See footnotes at end of table.

3-3

Section 3 Table 3-2—Continued Cyclic intermediates for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Separate statistics 1

Cyclic intermediates =

Manufacturers' identification Codes (according to list In tabiC 3-3)

Cyclic—Continued: Anisoyl chloride No , Anthranilic acid (o-Aminobenzoic acid) No N,N'-(1,5-Anthraquinonylene)dianthrartilic acid , No Benzaldehyde, tech No , Benzanilide No 1,2,4,5-Benzenetetracarboxylic acid No 1,2,4-Benzenetricarboxylic acid, 1,2-dianhydride (Trimellitic anhydride) No Benzhydrol (Diphenylmethanol) No Benzimidazole No 1,3-Benzodioxole No Benzoic acid, methyl ester No Benzoic acid, tech No Benzonitrile No Benzophenone No T. 2-Benzothiazolethiol, sodium salt No 1 H-Benzotriazole No , , 2-Benzoxazolethiol No Benzoyl chloride No Benzylamine No , 2-(Benzylamino)ethanol NO 2-Benzy1-2'-hydroxy-5,9-dimethy1-6,7benzomorphanhydrobromide No 1-Benzy1-4-phenylisonipecotonitrila No Benzyltrimethylammonium hydroxide No Biphenyl Yes 3'-[Bis(2-hydroxyethypamino]benzanilide, diacetate , ester No N,N-Bis(2-hydroxyethy1)-p-toluidine No 1,2-Bis(tribromophenoxy)ethane No ,, 3-Bromoacetophenone No Bromobenzene,moNo No o-Bromobenzoic acid No 2-Bromo-4,6-dinitroaniline No , Bromoethylbenzene No , p-Bromofluorobenzene No 2-Bromopyridine No 4-Butoxyacetophenone No p-tert-Butylbenzaldehyde No n-Butylbenzene No 2-tert-Butyl-p-cresol No , o-sec-Butylphenol No o-tert-Butylphenol No , p-sec-Butylphenol , No p-tert-Butylphenol No Butylphenols, mixed No p-tert-Butyltoluene No 4,4'-Carbonylbis[phthalic anhydride] No t• N-Carboxy-N-methylanthranilic anhydride No , 2-Chloro-4-aminotoluene No o-Chloroaniline No p-Chloroaniline No Chlorobenzene, mono - Yes 4'-Chloro-2',5'-dimethoxyacetoacetanilide No 2-Chloro-1,4-dimethoxybenzene No 1-Chloro-2,4-dinitrobenzene (Dinitrochiorobenzene) No 4-Chloro-3,5-dinitrobenzenesulfonic acid, potassium salt No 3-Chlorodiphenylamine No p-[(2-Chloroethyl)methylamino]benzaldehyde No 4-Chloro-N-methyl-3-nitrobenzenesulfonamide No 1-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene) No P i

See footnotes at end of table.

3-4

SD. PSG. SDC. GIV, KLM. EK. AMO. AMO. PD. EK. AMB. HCF. KLM, PFZ. PSG. CWN. BFG, USR. PSG. EK. HK, VET.. HXL, KLM. HXL SD. SDW. RSA. KHI, MON. SOC. SCP. RSA. GIL (2). DAZ. PD. HCL. GIL (2)DAZ. BUC. GIV. PLC. PSG. SCN VCC. TNA. SCN. SCN. FMC, (2), GIV. ACH. (2). LMC. DUP. DUP. MON, PPG, SCC. BRD. CHF. SDC. LMC. SK. VPC. REG. DUP, MON.

Synthetic Organic Chemicals, 1991 Table 3-2--Continued Cyclic intermediates for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Cyclic intermediates Cyclic—Continued: 1-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene) 2-Chiorophenothiazine 1-(3-ChloropropyI)-4-methylpiperazine 3-Chloropropyl-2,5-xylyl ether 2-Chioropyridine a-Chlorotoluene (Benzyl chloride) 3-Chloro-p-toluidine [NH2=1] 3-(2-Chloro-4-trifluoromethylphenoxy)toluene 4-Chloro-3,5-xylend Cresols: m-Cresol 0-cresol: o-Cresol, from petroleum p-Cresol Cresols, mixed: (m,p)-cresol: (m,p)-Cresol, from petroleum Cresylic acid, refined: Cresylic acid, refined, from petroleum Cumene (Isopropyl benzene) 4-(Cyanoacetyl) morpholine N-Cyanoethyl-N-acetoxyethylaniline 3-Cyanopyridine Cyclohexane 1,2-Cyclohexanedicarboxylic acid anhydride Cyclohexanol Cyclohexanone Cyclohexanone oxime Cyclohexene 4-Cyclohexene-1,2-dicarboxylic anhydride Cyclohexene oxide 0-(1-Cyclohexenyl)ethylamine Cyclohexylamine Cyclooctadiene 2-Cyclopropylmethylamino-5-chlorobenzophenone 2-(N-Cyclopropylmethyl-N-phthalimidoacetyl) -amino-5-chlorobenzophenone p-Cymene Decyldiphenyl oxide Dialkylbenzene 1,3 Diaminocydohexane 2,6-Diaminopyridine 2,5-Dianilinoterephthalic acid Dibenzyl oxalate p-Dibromobenzene 2,6-Dibromo-4-nitroaniline Dibromostyrene p-Dibutoxybenzene (DBB) 2,5-Dibutoxy-4-morpholinobenzenediazonium sulfate salt (DBB Sulfate) 2,5-Dibutoxy-4-morpholinonitrobenzene 2,6-Di-tert-butyl-alpha-dimethylamino-p-cresol Dibutyl-p-cresol 2,6-Di-t-butyl-p-cresol 2,4-Di-tert-butylphenol 2,6-Di-tert-butylphenol 2,6-Di-tert-butyiphenol 2,6-Di-tert-4-sec-butylphenol 3,4-Dichloroaniline o-Dichlorobenzene

Separate statistics1

Manufacturers' identification codes (according to list In table 3-3)

No No No No No No No No No

DUP, MON. SK. SK. PD. OMC. MON. DUP. (2). FER.

No

MER.

No No

GE, MER. MER, PSG.

No No Yes

MER.

No No No Yes No No Yes No No No No No No No No

MER. ART, ASH, BTL, GGC, GRS, KHI, SHC, SOC, TX DUP, PCW. SCP. RIL. GRS, PLC, PPR, SOC, SUN, TX. HK. ACS, BAS, DUP, MON. ACS, BAS, CNP, DUP, MON. CNP. USR. DKA. USR. HXL. AIP. DUP. PD.

No No No No No No No No No No No No

PD. HPC. TCC. VST. DUP. REG, RIL. VPC. MRF. DAZ. HCL. GTL. ALL

No No No No No No No No No No Yes

ALL ALL TNA. PSG: PLC. SCN, TNA. SCN. TNA. SCN. DUP. MON, PPG, SCC, SOI.

See footnotes at end of table. 3-5

Section 3

Table 3-2-Continued Cyclic intermediates for which U.S. production andfor sales were reported, identified by manufacturer, 1991 Cyclic intermediates

Separate statistics1

Manufacturers' identification codes (according to list in table 3-3)

Cyclic-Continued:

m-Dichiorobenzene p-Dichiorobenzene 3,3'-Dichlorobenzidine base and salts 3,4-Dichlorobenzotrifluoride 3,3'-Dichloro-4,4'-biphenyl Dichiorodiphenylsilane 2,6-Dichloro-3-methylaniline Dichloromethylphenylsilane 2,6-Dichloro-4-nitroaniline Dicyclohexylamine Dicyclohexylamine, nitrate salt Dicyclopentadiene (includes Cydopentadiene) a,a-Diethoxyacetophenone p-(Diethylamino)benzaldehyde 3'-[2-(Diethylamino)ethyl]-4'-hydroxyacetanilide N-(3-Diethylamino-1,4-methoxyphenyl)acetamide N,N-Diethylaniline 2,6-Diethylaniline Diethylbenzene N,N-Diethylcyclohexylamine 3,5-Diethyl-1 ,2-dihydro-1 -pheny1-2-propylpyridine 3,5-Diethyltoluene-2,4-diamine N,N-Diethyl-m-toluidine N,N-Diethyl-p-toluidine 6,11-Dihydrodibenz(b,e)oxepin-11-one 2-2-(2,3-Dihydro-1, 3-dioxo-1 H-inden-2y1)-(quinolinyl)]6-methylbenzothiazole-7-sulfonic acid 2,4-Dihydroxybenzaldehyde 6,7-Dihydroxy-2-naphthalenesulfonic acid m-Diiodobenzene 2,6-Diisopropylphenol 2,6-Diisopropy1-4-phenoxyaniline 2,5-Dimethoxybenzaldehyde m-Dimethoxybenzene 3,3'-Dimethoxybenzidine hydrochloride 2[4-(Dimethylamino)benzoyl]benzoic acid N,N-Dimethylaniline N,N-Dimethylbenzylamine N-(1,3-Dimethylbuty1)-N-phenyl-1, 4-benzenediamine Dimethy1-1,4-cyclohexanedicarboxylate N,N-Dimethylcydohexylamine 5,5-Dimethylhydantoin 2,6-Dimethylnaphthalene N,N'-Dimethyl-3,4,9, 10-perylenetetracarboxylic acid 3, 4:9,10-diimide 3,5-Dimethylpiperidine N,N-Dimethyl-o-toluidine N,N-Dimethyl-m-toluidine N,N-Dimethyl-p-toluidine 3,5-Dinitro-N4,N4-dipropylsulfanilamide 2,4-Dinitroacetanilide m-Dinitrobenzene 2,4-Dinitrobenzenesutfonic acid, sodium salt 3,5-Dinitrobenzoic acid 2,6-Dinitro-4-isopropylphenol 3,5-Dinitrosalicylic acid, methyl ester p-Dinitrosobenzene 2,4-Dinitrotoluene 2,4(and 2,6)-Dinitrotoluene See footnotes at end of table. 3-6

No Yes No No No No No No No Yes No Yes No No No No No No No No No No No No No

MON. MON, PPG, SCC, SOI. LMC. HK, (2). LMC. DCC. SDC. DCC. ASL. AIP, HK, VEL OMC. CX1, DOW, ENJ, LYP, SHC, (2). CWN. VPC. VPC. SCP. BCC, DUP. TNA. UPM. AIP. RIL. TNA. DUP, FST. RSA. PFZ.

No No No No No No No No No No No No

VPC. EK. CCC. GGC. TNA. TNA. CWN. ACY. BRI. EK. BCC, DUP. HXL.

No No No No No

VPC. EKT. AIP, BAS. BRD. UPM.

No No No No No No No No No No No No No No No

VPC. RIL RSA. RSA. FST, RSA. LMC. SDC. FST. EK. SAL. SDC. SAL LC. DUP. RUC, (2).

Synthetic Organic Chemicals, 1991 Table 3-2—Continued Cyclic intermediates for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Cyclic intermediates Cyclic—Continued: Dinonylphenol Di-para-benzoquinone dioxime 2,4-Di-tert-pentylphenol Diphenylamine 9,10-Diphenylanthracene Diphenyldisulfide Diphenyl phthalate 1,3-Di-4-piperidylpropane 2,5-Di-p-toluidinoterephthalic acid 1,5-Diureidonaphthalene Divinylbenzene 1,1-Di-3,4-xylylethane Dodecyldiphenyl oxide p-Dodecylphenol 2-Ethanolpyridine 5-Ethanoxy-3-trichloromethy1-1,2,4-thiadiazole Ethisterone o-Ethylaniline N-Ethylaniline, refined 2-(N-Ethylanilino)ethanol 3-(N-Ethylanilino)propionitrile Ethylbenzene 2-(N-Ethyl-N,6-cyanoethyl)-4-acetaminoanisole Ethyl 4-dimethylaminobenzoate N-Ethyl-N-(2-hydroxyethyl)-m-toluidine 6-Ethyl-2-methylaniline 2-[Ethyl(3-methylphenyl)aminoiethanol 1-Ethylpiperidine N-Ethyl-m-toluidine 3-(N-Ethyl-m-toluidino)propionitrile o-Fluorobenzoyl chloride 1-Formylpiperidine Furan Furfuryl alcohol Guanine 1,4,5,6,7,7-Hexachloro-5-norbornene-2, 3-dicarboxylic anhydride (Chiorendic anhydride) (Hexadecylphenoxy)benzene Hexahydro-1[(2-aminophenypsulfonyl]-1h-azepine . . . Hexahydro-1-[(2-nitrophenypsutfony1]-1h-azepine Hexamethyleneimine Hydroquinone, tech p-Hydroxybenzoic acid 4-Hydroxy-2H-1,2-benzothiazine-3-carboxylic acid, methyl ester, 1,1-dioxide 2'-Hydroxy-5,9-dimethy1-6,7-benzomorphan 3-[N-(2-Hydroxyethyl)anilino]propionitrile N-6-Hydroxyethy1-2,4-dihydroxybenzamide 4-Hydroxy-2-methyl-2H-1, 2-benzothiazine-3-carboxylic acid, methyl ester, 1,1-dioxide 2-Hydroxymethylene-17a-ethinylandrost-17 (3-o1-4-en-3-one 3-Hydroxy-N-(3-N-morpholino-y-propyl) -2-naphthimide 1-Hydroxy-2-naphthoic acid 3-Hydroxy-2-naphthoic acid (B.0 N) 3-Hydroxy-2-naphthoic acid, methyl ester p-lodotoluene Isobutylbenzene Isobutylbiphenyl

Separate statistics',

No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No

No No

Manufacturers' identification codes (according to list In table 3-3)

TX. LC. PAS, SCN. ART, RUC, USR. PAH. PAH. EK. RIL. VPC. S01. DLT, DOW, TCC. ACH. TCC. MON, SCN. RIL OMC. SRL. TNA. BCC, FST. SCP. SCP. AMO, ATR, CSD, DOW, ELP, GE, KHI, SC, SOC, S, SOC, SCP (2). FST. SCP. TNA. FST. BAS. DUP, FST. SCP. OMC. RIL QKO. QKO. LLI. OMC, VEL. TCC. SAL. SAL CXI, DUP. EKT, GYR. LEM.

No No No No

PFZ. SD. SCP. PCW.

No

PFZ.

No

SD.

No No No No No No No

PCW. PCW. PCW. PCW. RSA. PLC, TNA. TCC.

See footnotes at end of table.

3-7

Section 3 Table 3-2—Continued Cyclic intermediates for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Cyclic intermediates

Separate statistics1

Manufacturers' identification codes (according to list in table 3-3)

Cyclic--Continued: Isobutyrophenone Isocyanic acid derivatives: Bitolylene diisocyanate (TODI) Diphenylmethane-4,4'-diisocyanate (MDI) Polymethylene polyphenylisocyanate Toluene 2,4-and 2,6-diisocyanate (80/20 mixture) p-Toluenesulfonyl isocyanate All other isocyanic acid derivatives Isonicotinic acid Isonicotinonitrile Isophthalic acid (Benzene-1,3-dicarboxylic acid) Isophthalic acid, dimethyl ester Isophthalonitrile Isophthaloyl chloride Isopropylbiphenyl 4,4'-lsopropylidenediphenol (Bisphenol A) 4,4'-lsopropylidenediphenol, ethoxylated 4,4'-lsopropylidenediphenol, propoxylated o-lsopropylphenol 2,6-Lutidine 3,4-Lutidine 3,5-Lutidine Melamine p-Mentha-1 ,4(8)-diene dl-p-Mentha-1,8-diene (Umonene) 4-Methoxyacetophenone 4-Methoxybenzyl alcohol N-(4-Methoxy-3-nitrophenyl)acetamide 2-(N-Methylanilino)ethanol 3-(N-Methylanilino)propionitrile 5-Methyl-o-anisidine [NH2=1] 2-Methylanthraquinone 4-Methylbenzotriazole o-Methylbenzoyl chloride N-Methylbenzylamine 2-Methyl-1 , 1 -biphenyl(n-3-y1) methanol Methylcyclohexane Methyl-3-(D-a-dihydrocarboxybenzylamino)crotonate, sodium salt 4,4-Methylenebis(2,6-di-tert-butylphenol) 2,2'-Methylenebis(4-methyl-6-nonyl-p-cresol) 4,4'-Methylenedianiline 5,5'-Methylenedisalicylic acid Methyl p-formylbenzoate Methylhydroquinone 1 -Methyl-(2-hydroxyethyl)piperidine 6-Methy1-2-(2-methy1-6-quinolyI)-7benzothiazolesulfonic acid N-Methyl-p-nitroaniline 4-Methyl-2-nitroanisole 1 -(2-Meth y1-4-nitrophenyl)pyrrolidine 2-Methyl-5-norbomene-2,3-dicarboxylic anhydride 4-(1 -Methyl-1 -phenyl)ethylphenol 4-Methylphthalic acid 1-Methylpiperidine 2-Methylpiperidine p-Methylstyrene a-Methylstyrene ar-Methylstyrene (Vinyltoluene) 2,6-Naphthalenedicarboxylic acid 2-Naphthalenesulfonic acid Naphthalimide See footnotes at end of table.

3-8

No

ARS.

No No No Yes No Yes No No No No No No No Yes No No No No No No No No - No No No No No No No No No No No No No

CWN. BAS, ICI, RUC. BAS, ICI, RUC. BAS, DOW, ICI, OMC, RUC. VCM. CWN. RIL. RIL. AMO. UTC. DUP, PSG. DUP, TLC. TCC. ART, DOW, GE, SHC. ICI, SCP. ICI, SCP. FMC. RIL. RIL. RIL. ACY, MLC. NCI. ARZ, NCI. BUC. BUC. SDC. SCP. SCP. PSG. ACY. VPC. TLC. HXL. NES. PLC.

No No No No No No No No No No No No No No No No No No Yes No No No No

KAN. TNA. PSG. AUS, RUC, USR. KLM. EKT. EKT. RIL. VPC. ACY. PSG. ALL. BCC. SCN. EK. BAS. RIL. DLT. ART, BTL, GGC, TX. DLT. AMO. ACY. VPC.

Synthetic Organic Chemicals, 1991 Table 3-2—Continued Cyclic intermediates for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Cyclic intermediates Cyclic—Continued: p-(2-Naphthylamino)phenol (N-(p-HydroxyphenyI)-2naphthylamine) Nicotinonitrile (3-Cyancpyridine) o-Nitroaniline p-Nitroaniline 5-Nitroanthranilic acid p-Nitrobenzamide Nitrobenzene m-Nitrobenzenesuffonic acid, sodium salt o-Nitrobenzoic acid m-Nitrobenzoic acid p-Nitrobenzoic acid m-Nitrobenzoic acid, sodium salt 2-Nitro-N-benzoylaniline 2-Nitro-p-cresol 5-Nitrodimethylisophthalate Nitrodiphenylamine 5-Nitroisophthaiic acid p-Nitrophenethyl alcohol p-Nitrophenol p-Nitrophenol, sodium salt p-Nitrophenoxyethanol 3(and 5)-Nitrosalicylic acid p-Nitrosophenol 4-Nitrosophenol, sodium salt o-Nitrotoluene m-Nitrotoluene p-Nitrotoluene Nitrotoluene mixtures Nonylphenol (-)Octamandelate Octyiphenol Octyiphenoxydiethoxy chloride 3-0xo-1,2-benzisothiazoline-2-acetic acid, methyl ester,1 ,1 -dioxide 4,4'-Oxydianiline Parahydroxyphenylglycine potassium methyl dane salt o-Pentylphenol (o-Amylphenol) p-tert-Pentylphenol 3,4,9,10-Perylenetetracarboxylic-3,4:9, 10-dianhydride 3,4,9,10-Perylenetetracarboxylic-3,4:9, 10-diimide 1,10-Phenanthroline 2-Phenethylamine p-Phenetidine Phenol: Natural: From petroleum: Phenol, natural, from petroleum, U.S.P Synthetic: By caustic fusion: Phenol, synthetic, by caustic fusion, all other Phenol, styrenated Phenol, synthetic, from cumene by oxidation, U.S.P. Phenoxathiin All other phenol Phenolsulfonic acid Phenolsulfonic acid, sodium salt Phenoxyacetic acid, sodium salt m-Phenoxytoluene

Separate statistics!

Manufacturers' identification codes (according to list in table 3-3)

No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No

SDC. NEP. MON. MON. SAL PD. FST, ICI, RUC. USM. SAL SAL. DUP. SAL. SAL. PSG. SAL ACY, MON. RIL, SAL PCW. MON. DUP. SCP. SAL LC, SDC. SDC. DUP, FST. . FST. DUP, FST. FST. GE, KLM, MON, SCN, TX. W. PSG, SCN. RH.

No No No No No

PFZ. CHT, DUP. KAN. PAS, SCN. PAS.

No

VPC.

No No No No

VPC. (2). HXL MNA.

No

MER.

No No

ISP. PSG.

Yes No Yes No No No No

ACS, ART, STL, DOW, GE. C1GC. PAH. GGC, KLM, SHC, TX. SAL SAL NCC. MER.

See footnotes at end of table.

3-9

Section 3

Table 3-2—Continued Cyclic intermediates for which 04. production and/or sales were reported, identified by manufacturer, 1991 Cyclic intermediates' Cyclic—Continued: 4-(Phenylazo)diphenylamine 2-Phenyibenzimide m-Phenylenebismaleimide o-Phenylenediamine m-Phenylenediamine p-Phenylenediamine Phenyl ether (Diphenyl oxide) d(9)a-Phenylethylamine N-Phenyiglycine Phenyiglycine, potassium salt Phenyiglycine, sodium salt 2,2'-[(Phenypimino]diethanol (N-Phenyidiethanoiamine) 2,2'-[(Phenyl)imino]diethanol, diacetale ester o-Phenylphenol p-Phenylphenol o-Phenylphenol, sodium salt Phenyl-2-propanone 4-Phenyipropylpyridine N-Phenylurea Phthalic acid Phthalic anhydride Phthalimide , [Phthalocyaninato(2-)]copper Phthalocyaninetetrasulfonyl chloride, copper derivative Phthaioyl chloride (Phthalyl chloride) Picolines: Picoline (3,4-mixture) 2-Picoline (a-Picoline) 3-Picoline (8-Picoline) 4-Picoline (y-Picoline) Picolinonitrile (2-Cyanopyricine) 3-Picolylamine Picric acid (Trinitrophenol) Pipecolic acid Piperidine Polyethylbenzene (80 percent diethybenzene) Propiophenone Pyridine hydrochloride Pyridine, refined: 2° Pyridine, refined Pyridine, refined all other grades 2 Pyridinethio1-1-oxide, sodium salt 2 Pyridinethiol-l-oxide, zinc salt Pyromellitic dianhydride 2-Pyrrolidinone (2-Pyrrolidone) Pyrvinium pamoate Quinaldine Quinone dioxime Resorcinol, tech, 8-Resorcylic acid Salicylaldehyde oxime Salicylic acid, tech Sodium p-sulfophenylmethallyl ether Styrene (Vinylbenzene) Sulfanilic acid (p-Aminobenzenesulfonic acid) and salt 5-Suifoisophthalic acid, 1,3-dimethyl ester, sodium salt 5-Sulfoisophthalic acid, sodium salt See footnotes at end of table.

Separate statistics1

Manufacturers' identification codes (according to list in table 3-3)

No No No No No No No No No No No

EK. SAL NES. DUP, PSG. DUP, FST. DUP. DOW, MON. HXL EK. KAN. BCC, LIL

No No No No No No No No No Yes No No

MIL SCP. SCP. DOW. DOW. DOW, USR. SK. RIL RSA. EK. ART, BAS, ENJ, STP, USR. PSG. PC, PHC.

No No

S, VPC. TLC.

No No No No No No No No No No No No

RIL. RIL NEP, RIL RIL NEP. RIL SDC. RIL AIP, RIL ELP. ARS, ORT. HXL

No No No No No No No No No No No No No No Yes

NEP. RIL OMC. OMC. ACH. GAF. (2). CIC. LC. ISP. ISP. EK. DOW, KIM. SAL AMO, ATR, CSD, DLT, DOW, ELP, HMN, PLC,

No

RMI.

No No

DUP. EKT, PCW.

Synthetic Organic Chemicals, 1991 Table 3-2—Continued Cyclic intermediates for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Cyclic intermediates Cyclic—Continued: Terephthalic acid Terephthalic acid, dimethyl ester Terephthaloyl chloride Terphenyl (Phenylbiphenyl) (m-,o-,and p-isomers) Tetrabromophthalic anhydride 1,2,3,4-Tetrachlorobenzene Tetrachlorophthalic anhydride Tetrahydrofuran 1,2,4,5-Tetramethylbenzene (Durene) p-(1,1,3,3-Tetramethylbutyl)phenol 4,4'-Thio-bis(6-t-butyl-o-cresol) 4,4'-Thiobis(6-t-butyl-m-cresol) Thiodiphenol Toluene-2,3-(and 3,4)-diamine (35/65 mixture) Toluene-2,4-diamine (4-m-Tolylenediamine) Toluene-2,4-(and 2,6)-diamine (80/20 mixture) Toluene-3,4-diamine Toulenesuffonamide p-Toluenesulfonic acid, aniline salt p-Toluenesulfonic acid monohydrate m-Toluic acid p-Toluic acid, methyl ester o-Toluidine m-Toluidine p-Toluidine 2,2'-(m-Tolylimino)diethanol Tolyltriazole 2,4,6-Trbromophenol 1,2,3-Trichlorobenzene 1,2,3(and 1,2,4)-Trichlorobenzene 1,2,4-Trichlorobenzene 3-Trichloromethy1-1,2,4-thiadiazole 1,2,4-Trichloro-5-nitrobenzene Trichlorophenylsilane a,a,a-Trichlorotoluene (Benzotrichloride) 2,4,6-Trichloro-s-triazine (Cyanuric chloride) Tri(dimethylaminomethyl)phenol Trimellitic anhydride, acid chloride Trimeilitic trichloride 1,2,4-Trimethylbenzene (Pseudocumene) 1,3,5-Trimethylbenzene (Mesitylene) 1,3,3-Trimethy1-92 , a-indolineacetaldehyde Trioxane Triphenylmethane a,a',a"-Tris(dimethylamino)mesitol 1,1,1-Tris(p-hydroxyphenyl)ethane Tris(2-methyl-1-aziridinyl)phosphine oxide 7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid] (J-Acid urea) Veratraldehyde (3,4-Dimethoxybenzaldehyde) 5-Vinyl-2-picoline (MVP) 2-Vinylpyridine 4-Vinylpyridine o-Xylene (90-100% of o-xylene isomer) m-Xylene (90-100% of m-xylene isomer) p-Xylene (90-100% Of p-xylene isomer) 2,4-Xylenesulfonic acid Xylenesulfonic acid, mixed isomers 2,6-Xylenol Xylenol crystals

Separate statistics

Manufacturers' Identification codes (according to list in table 3-3)

Yes Yes No No No No No Yes No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

AMO, DUP, HCF. DUP, EKT, HCF. DUP, TLC. MON. GTL. SCC. MON. ATR, BAS, DUP, GAF, QKO. KHI. GAF. TNA. AUS. AUS. OMC. RUC, (2). OMC, BAS, DOW, ICI. (2). UTC. NES. TEN. WTC. HCF. DUP, FST. DUP, FST. DUP, FST. MIL SCP. PSG. GTL SCC. PPG, SCC. SCC. OMC. PCW. DCC. HK. DGC. PEL (2). TLC KHI. ABB. VPC. UTF. EK. RH. SAL ARS.

No No No No No Yes No Yes No No No No

S. GIV. HK, PD. RIL. RIL. ENJ, KHI, LYP, PLC, PPR. AMO, PLC. AMO, ENJ, KHI, LYP, PPX, SOC, STX. PLC. NES. GE. BRS, HXL.

See footnotes at end of table.

3-11

Section 3 Table 3-2—Continued Cyclic intermediates for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Cyclic intermediates

Separate statistic&

Manufacturers' identification codes (according to list in table 3-3)

No No

MER. GE.

No No Yes

FST. DUP. ACY, AMD, AUS, BRS, BUC, CWN, DUP, EKT, FST, HCF, HCL, HXL, LC, MRX, OMC, PCW, PD, PFZ, PIL, PRC, PSG, RAY, RIL, SAL, SCP, SDC, SDW, SK, TNA, UCC, VPC, (2).

Cyclic—Continued: Xylenols: Xylenol, low boiling point Xylenols, not classified as to boiling point Xylidines: 2,4-Xylidine (m-4-Xylidine) Xylidine, original mixture All other cyclic intermediates

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Synthetic Organic Chemicals, 1991 Table 3-3 Cyclic intermediates: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ABB ACH ACS

Abbott Laboratories Allco Chemical Corp. Allied Signal Inc., Engineered Material Sector American Cyanamid Co Air Products & Chemicals, Inc. Alliance Chemical, Inc. American Bio-Synthetics Corp. Cyclo Products, Inc. Amoco Corp. Arsynco, Inc., Sub. Div. of Aceto Corp. Aristech Chemical Corp Arizona Chemical Co Ashland Oil, Inc., Ashland Petroleum Co. Specialtychem Products, Corp. Atlantic Richfield Co., Arco Chemical Co. Ausimont N.V. BASF Corp. Buffalo Color Corp. B. F. Goodrich Co B. F. Goodrich Chemical Group Lonza, Inc. Burlington Industries Bristol-Myers Co. BTL Specialty Resin Corp. Synalloy Corp., Blackman Uhler Chemical Div. C.N.C. International, Inc. Kincaid Enterprises, Inc Chattem, Inc. Color Chem International Corp DSM Chemicals North America Fine Oil & Chemicals Co Upjohn Co. Fine Chemicals Chemical Exchange Industries, Inc. Diaz Chemical Corp. Dow Coming Corp Degussa Corp. Dixie Chemical Co., Inc. Miles, Inc. Deltech Corporation Dow Chemical Co E. I. duPont de Nemours & Co., Inc. Chemicals and Pigments Dept. Petrochemicals Dept. Eastman Kodak Co.* Tennessee Eastman Co Div. Rexene Products Company Exxon Chemical Americas

FER

Ferro Corp.: Bedford Chemical Div. FMC Corp., Nitro Div. Fairmount Chemical Co., Inc. First Chemical Corp. ISP Chemicals, Inc. General ELectric Co., Speciality Chemical Group Georgia-Gulf Corp.: Houston Div. Plaquemine Div. Givaudan Corp Citgo Refining & Chemicals, Inc. Great Lakes Chemical Corp. Goodyear Tire & Rubber Co. Cape Industries Hoechst Celanese Corp.: Sou-Tex Works Specialty Chem Group Occidental Chemical Corp., ED & S Div. Huntsman Chemical Corp. Hercules, Inc. Hexcel Corp., Hexcel Chemical Products ICI Americas, Inc., Polyurethanes Group Specialty Chem Div. Indspec Chemical Corp. Kanasco, Ltd Koch Refining Co. Kalama Chemical, Inc. Lord Corp., Chemical Products Group Napp Chemicals, Inc. Eli Lilly & Co. Lee Laboratories, Inc. Lomac, Inc. Lyondell Petrochemical Co. Mallinckrodt, Inc. Merichem Co. Milliken & Co., Milliken Chemical Div. Melamine Chemicals, Inc. Monsanto Co., Agricultural Group Monsanto Co. Morflex, Inc. Johnson Matthey, Materials Technology Div. Niacet, Corp. Union Camp Corp., B B A Div. Nepera, Inc. Ruetgers-Nease Chemical Co. National Starch & Chemical Corp.

ACY AIP ALL AMB AMD AMO ARS ART ARZ ASH ASL ATR AUS BAS BCC BFG BRD BRI BRS BTL BUC CCC CHF CHT CIC CNP CSD CWN CXI DAZ DCC DGC DIX DKA DLT DOW DUP

EK EKT ELP ENJ

.

.

.

FMC FMT FST GAF GE GGC

GIV GRS GTL GYR HCF HCL

HK HMN HPC HXL ICI

ISP KAN KHI KLM LC LEM LIL LLI LMC LYP MAL MER MIL MLC MNA MON MRF MRX NCC NCI NEP NES NSC

See footnotes at end of table. 3-13

Section 3 Table 3-3—Continued Cyclic intermediates: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

OMC ORT

Olin Corp. Roehr Chemicals, Inc., Div. of Aceto Corp. Parish Chemical Co Elf Atochem North America, Inc. PCI, Inc. Pfister Chemical, Inc. Parke-Davis Div. of Warner-Lambert Co. Peiron Corp. Pfizer, Inc., & Pfizer Pharmaceuticals, Inc. Phthalchem, Inc. Pilot Chemical Co. Phillips 66 Co. PPG Industries, Inc. Phillips Puerto Rico Core, Inc. Phillips Paraxylene, Inc. Products Research & Chemical Corp. PMC, Inc., PMC Specialty Group, Inc. QO Chemicals, Inc. ITT Rayonier Uguin Products, Inc. Regis Chemical Co. Rohm & Haas Co. Reilly Industries, Inc. R-M Industries, Inc. R.S.A. Corp. Rubicon, Inc. Sandoz Chemicals Corp. Salsbury Chemicals, Inc Sterling Chemicals, Inc. Standard Chlorine of Delaware, Inc Schenectady Chemical, Inc

SCP SD

Henkel Corp. Sterling Drug, Inc., Sterling Pharmaceuticals, Inc. Sandoz Chemicals Corp. Sterling Drug, Inc., Organic Div. Shell Oil Co., Shell Chemical Co. Smithidine Beecham Chemicals Chevron Corp., Chevron Chemical Co. Phibro Refining Specialty Organics, Inc. G. D. Searle & Co. Stepan Co. St. Croix Petrochemical Corp. Sun Company, Inc. Sybron Chemicals, Inc. BIT Manufacturing, Inc. Twin Lake Chemical, Inc. Ethyl Corp. Texaco Chemical Co. Union Carbide Corp., Industrial Chemicals Div. Upjohn Co UOP, Inc. Crown Metro, Inc. Uniroyal Chemical Co., Inc. Unitex Chemical Corp. Vanchem, Inc. Velsicol Chemical Corp. Miles, Inc. Vista Chemical Co. Witco Corp.

PAH PAS PC PCW PD PEL PFZ PHC PIL PLC PPG PPR PPX PRC PSG QKO RAY REG RH RIL RMI RSA RUC S SAL SC SCC SCN

SDC SDW SHC SK SOC SOG SOI SRL STP STX SUN TCC TEN TLC TNA TX UCC UPJ UPM USM USR UTC VCM VEL VPC VST WTC

Note—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

3-14

Synthetic Organic Chemicals, 1991 Total domestic production of dyes in 1991 amounted to 111 million kilograms, or 5 percent less than the 117 million kilograms produced in 1990 (table 4-1). Sales of dyes in 1991 amounted to 107 million kilograms, valued at $761 million, compared with 104 million kilograms, valued at $775 million, in 1990. In terms of quantity, sales of dyes in 1991 was 3 percent greater, and in terms of value 2 percent lower. The average unit value of sales of all dyes in 1991 was $7.13 per kilogram, compared with $7.46 per kilogram in 1990. Production of four classes of dyes decreased in 1991, while the production of two classes increased. Statistics on four classes - fibers reactive dyes, mordant dyes, flouorescent brightening agents, and food, drug, and cosmetic colors - were not publishable. Changes in U.S. production of synthetic dyes followed overall changes in U.S. economic activity during 1987-91 (see figure 4-1). Table 4-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 4-3. Rob Randall 202-205-3366

Section 4 Dyes Synthetic dyes are derived in whole or in part from cyclic intermediates. Approximately two-thirds of the dyes consumed in the United States are used by the textile industry to dye natural and synthetic fibers or fabrics: about one-sixth is used for coloring paper; and the rest is used chiefly in the production of organic pigments and in dyeing leather and plastics. Of the several thousand different synthetic dyes that are known, more than seven hundred are manufactured by domestic producers, collectively. The large number of dyes results from the many different types of materials to which dyes are applied, the different conditions of service for which dyes are required. and the cost that a particular use can bear. Commercial dyes are formulated products which are sold in a variety of physical forms (e.g.. granular, powders, liquids, and pastes) containing concentrations of colorant ranging from 5 percent (approximately) to 100 percent. In the statistical tables, production and sales quantities are expressed in terms of a standard strength of product (based on dyeing performance) and not in terms of the amount of actual colorant.

Figure 4-1 Dyes: U.S. production, 1987-91

Millions of kilograms

180 160 140 120 100 80 60 40 20 0

4441

-) 1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 4-1

Section 4

Table 4-1 Dyes: U.S. production and sales, 1991

Production

Quantity

Value

Average Unit value1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Sales Dyes

110,961

106,813

761,415

$7.13

5,655

5,346

70,788

13.24

612

559

6,514

11.66

1,493

1,512

23,648

15.64

536 957

551 961

10,306 13,342

18.72 13.88

3,550

3,275

40,626

12.40

3,983

3,862

55,394

14.34

- 1,102 761 846 643 631

1,147 755 765 598 597

15,560 13,949 10,112 8,938 6,835

13.56 18.47 13.22 14.95 11.46

18,454

17,866

138,724

7.76

7,332 3,315

7,403 3,072

41,320 39,411

5.58 12.83

849 2,466

785 2,287

4,983 34,428

6.34 15.06

Direct violet dyes Direct blue dyes, total

123 3,287

96 3,176

1,469 28,090

15.36 8.84

Direct Blue 86 All other direct blue dyes All other direct dyes

332 2,955 4,397

347 2,829 4,119

2,456 25,634 28,434

7.08 9.06 6.90

Grand total Acid dyes Total Acid yellow dyes Acid blue dyes, total Acid Blue 324 All other acid blue dyes All other acid dyes Basic dyes (classical and modified) Total Basic yellow dyes Basic red dyes Basic violet dyes Basic blue dyes All other basic dyes Direct dyes Total Direct yellow dyes Direct red dyes, total Direct Red 254 All other direct red dyes

See footnotes at end of table.

4-2

Synthetic Organic Chemicals, 1991 Table 4-1-Continued Dyes: U.S. production and sales, 1991 Sales Production

Quantity

Value

Average Unit valuer

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

20,363

20,311

113,040

$5.57

Disperse yellow dyes Disperse orange dyes Disperse red dyes, total

2,319 2,159 2,650

2,086 2,590 1,937

9,400 9,681 24,493

4.51 3.74 12.64

Disperse Red 153 Disperse Red 177 All other disperse red dyes Disperse blue dyes, total

120 158 2,372 9,861

112 133 1,692 10,741

1,895 1,802 20,796 52,316

16.91 13.57 12.29 4.87

Disperse blue 79 All other disperse blue dyes Disperse black, brown, green and violet dyes, total

7,033 2,828 3,374

7,164 3,577 2,957

12,991 39,325 17,150

1.81 10.99 5.21

324

282

2,599

9.21

- 3,050

2,675

14,551

5.00

5,144

3,372

41,660

12.36

377

402

7,280

18.09

15 362

15 387

330 6,950

21.16 17.97

140 1,406 36 2,033 1,152

142 1,327 26 427 1,048

3,102 15,318 1,335 7,650 6,975

21.90 11.54 51.97 17.91 6.65

14,203

13,973

57,007

4.08

88 14,115

102 13,871

2,083 54,924

20.45 3.96

43,159

42,083

284,802

6.77

Disperse dyes Total

Disperse Brown 1 All other disperse black, brown, green and violet dyes Solvent dyes Total Solvent yellow dyes, total Solvent yellow 13 All other solvent yellow dyes Solvent orange dyes Solvent red dyes Solvent violet dyes Solvent blue dyes All other solvent dyes Vat dyes Total Vat orange dyes All other vat dyes All other dyes Total4

1 Calculated from unrounded figures. 2 Reported data were accepted in confidence and may not be published, or no data were reported. 3 The data include external drug and cosmetic dyes. 4 The data include azoic compositions, azoic coupling components, azoic diazo components (bases

and salts), fiber reactive dyes, fluorescent brightening agents, food, drug and cosmetic colors, mordant dyes, sulfur dyes, and miscellaneous dyes. Statistics for those groups of dyes may not be published separately because publication would disclose information received in confidence. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

4-3

Section 4

Table 4-2 Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Dyes Acid dyes: Acid yellow dyes: Acid Yellow 5 Acid Yellow 17 Acid Yellow 19 Acid Yellow 23 Acid Yellow 34 Acid Yellow 36 Acid Yellow 49 Acid Yellow 59 Acid Yellow 65 Acid Yellow 135 Acid Yellow 137 Acid Yellow 151 Acid Yellow 159 Acid Yellow 199 Acid Yellow 200 Acid Yellow 216 Acid Yellow 219 Acid Yellow 226 Acid Yellow 239 All other acid yellow dyes Acid orange dyes: Acid Orange 7 Acid Orange 8 Acid Orange 10 Acid Orange 24 Acid Orange 60 Acid Orange 64 Acid Orange 89 Acid Orange 116 Acid Orange 128 Acid Orange 152 Acid Orange 156 Acid Orange 161 Acid red dyes: Acid Red 1 Acid Red 14 Acid Red 18 Acid Red 26 Acid Red 33 Acid Red 57 Acid Red 73 Acid Red 88 Acid Red 119 Acid Red 151 Acid Red 182 Acid Red 201 Acid Red 226 Acid Red 266 Acid Red 278 Acid Red 296 Acid Red 299 Acid Red 337 Acid Red 350 Acid Red 364 Acid Red 384 Acid Red 388 Acid Red 396 Acid Red 400 Acid Red 418 See footnotes at end of table. 4-4

Separate statistics1 Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' identification codes (according to list in table 4-3)

BAS. CK. CK. BAS, LVR, WJ. CK. CK. CK, FAB. BAS, CK. CK. ICI. CK. CK. CK. CK. CK. VPC. CK. BAS. DGO. CK. BAS, CK, LVR, WJ. CK. CK, ROM. CK. CK. CK. BAS. CK. CK. CK. CK. CK. CK. CK. CK. CK. FAB. CK. PSC. FAB. CK. CK. CK, VPC. CK. BAS. CK, FAB, VPC. CK. BAS. CK. CK, FAB, VPC. CK. CK. CK. CK. ICI. CK. CK.

Synthetic Organic Chemicals, 1991 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Dyes

Separate statisticsi

Acid dyes-Continued Acid red dyes-Continued Acid Red 419 All other acid red dyes Acid violet dyes: Acid Violet 3 Acid Violet 7 Acid Violet 12 Acid Violet 17 Acid blue dyes: Acid Blue 9 Acid Blue 15 Acid Blue 25 Acid Blue 40 Acid Blue 41 Acid Blue 50 Acid Blue 62 Acid Blue 67 Acid Blue 104 Acid Blue 113 Acid Blue 145 Acid Blue 231 Acid Blue 281 Acid Blue 298 Acid Blue 321 Acid Blue 324 Acid Blue 330 All other acid blue dyes Acid green dyes: Acid Green 1 Acid Green 5 Acid Green 16 Acid Green 20 Acid Green 25 All other acid green dyes Acid brown dyes: Acid Brown 14 Acid Brown 19 Acid Brown 50 Acid Brown 96 Acid Brown 97 Acid Brown 98 Acid Brown 147 Acid Brown 159 Acid Brown 160 Acid Brown 161 Acid Brown 165 Acid Brown 188 Acid Brown 189 Acid Brown 227 Acid Brown 239 Acid Brown 264 Acid Brown 439 Acid black dyes: Acid Black 1 Acid Black 2 Acid Black 52 Acid Black 60 Acid Black 63 Acid Black 92

Yes No No No No No No No No Yes No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

See footnotes at end of table.

Manufacturers' identification codes (according to list in table 4-3)

CK. BAS. FAB. CK, FAB. CK, FAB. BAS. BAS, LVR, WJ. BAS. VPC. CK. CK. BAS. CK. BAS. CK. CK. CK. CK. CK CK. CK. CK, S, VPC. CK. CK. LVR. WJ. LVR. CK. CK. CK. CK, FAB, LVR. CK. BAS. FAB. BAS, FAB. FAB. CK. BAS. BAS. BAS. BAS. CK. CK. BAS. CK. BAS. CK. CK, LVR. CK, LVR. CK, S. CK. BAS. FAB.

Section 4

Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, Identified by manufacturer, 1991 Separate statisticsi

Dyes Acid dyes-Continued Acid black dyes-Continued

Acid Black 107 Acid Black 172 Acid Black 194 Acid Black 210 All other acid black dyes

Azoic dyes and components: Azoic compositions: Azoic yellow compositions:

Azoic Yellow 1

Azoic red compositions:

Azoic Red 1 Azoic Red 2 Azoic Red 6 Azoic Red 32 All other azoic red compositions

Azoic violet compositions:

All other azoic violet compositions Azoic blue compositions:

Azoic Blue 3 Azoic Blue 6 Azoic Blue 20

Azoic brown compositions:

Azoic Brown 9

Yes

No No No No No No No No No No No No No No No No No No No No No No No No

Azoic black compositions:

Azoic Black 4 Azoic Black 48 All other azoic black compositions

Azoic diazo components, bases:

Azoic Diazo Component 5, base Azoic Diazo Component 13, base Azoic Diazo Component 32, base All other azoic diazo components, base Azoic diazo components, salts:

Azoic Diazo Component 1, salt Azoic Diazo Component 3, salt Azoic Diazo Component 5, salt Azoic Diazo Component 8, salt Azoic Diazo Component 9, salt Azoic Diazo Component 10, salt Azoic Diazo Component 12, salt Azoic Diazo Component 13, salt

Azoic coupling components:

Azoic Coupling Component 2 Azoic Coupling Component 4 Azoic Coupling Component 12 Azoic Coupling Component 14 Azoic Coupling Component 17 Azoic Coupling Component 18 Azoic Coupling Component 20 Azoic Coupling Component 34 Azoic Coupling Component 43 Basic dyes (classical and modified) Basic yellow dyes

Basic Yellow 15 Basic Yellow 28 Basic Yellow 29 Basic Yellow 53 Basic Yellow 58 Basic Yellow 65 Basic Yellow 78 Basic Yellow 79 See footnotes at end of table. 4-6

Manufacturers' identification codes (according to list in table 4-3)

No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No

CK. CK. BAS. BAS. BAS.

BUC. BUC. BUC. BUC. CK. BUC. BUC. BUC. CK. CK. BUC. BUC. CK. BUC. ALL ALL. ALL ALL BUC. ALL BUC. ALL BUC. BUC. BUC. BUC. ALL BUC. BUC. ALL ALL. ALL ALL ALL ALL ALL ALL ALL CK. BAS, VPC. BAS. CK. VPC. BAS. BAS. CK.

Synthetic Organic Chemicals, 1991 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Dyes Basic dyes (classical and modified)-Continued Basic yellow dyes-Continued Basic Yellow 11 Basic Yellow 83 Basic Yellow 94 Basic Yellow 96 Basic Yellow 98 Basic Yellow 102 All other basic yellow dyes Basic orange dyes: Basic Orange 1 Basic Orange 2 Basic Orange 21 Basic Orange 26 All other basic orange dyes Basic red dyes: Basic Red 12 Basic Red 14 Basic Red 15 Basic Red 17 Basic Red 29 Basic Red 46 Basic Red 49 Basic Red 73 Basic Red 104 Basic Red 111 All other basic red dyes Basic violet dyes: Basic Violet 1 Basic Violet 3 Basic Violet 4 Basic Violet 16 All other basic violet dyes Basic blue dyes: Basic Blue 1 Basic Blue 3 Basic Blue 6 Basic Blue 7 Basic Blue 21 Basic Blue 41 Basic Blue 60 Basic Blue 77 Basic Blue 94 and 94:1 Basic Blue 140 Basic Blue 152 All other basic blue dyes All other basic blue dyes, modified Basic green dyes: Basic Green 4 All other basic green dyes Basic brown dyes: Basic Brown 1 Basic Brown 4 All other basic brown dyes Basic black dyes: All other basic black dyes All other basic black dyes, modified

Separate statistics' Yes Yes No No No No No No No Yes No No No No No Yes No No No No No No No No No No No Yes No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' Identification codes (according to list in table 4-3)

CK. CK. S. BAS. BAS. BAS. ALL BAS, CK. BAS, CK, PSC. CK, VPC. CK. BAS. CK, VPC. BAS, CK, VPC. BAS, CK. CK. BAS. CK. BAS. CK. CK. S. BAS. BAS, DSC. CK, DSC. DSC. CK, VPC. BAS. BAS. BAS, CK. BAS. DSC. CK. BAS. BAS. CK. CK. S, VPC. BAS. BAS. BAS. BAS. BAS. PSC. BAS, PSC. BAS. BAS. BAS, CK.

See footnotes at end of table.

4-7

Section 4 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Dyes Direct dyes: Direct yellow dyes: Direct Yellow 4 Direct Yellow 5 Direct Yellow 6 Direct Yellow 11 Direct Yellow 34 Direct Yellow 44 Direct Yellow 51 Direct Yellow 105 Direct Yellow 106 Direct Yellow 107 Direct Yellow 118 Direct Yellow 119 Direct Yellow 127 Direct Yellow 131 Direct Yellow 132 Direct Yellow 133 Direct Yellow 137 Direct Yellow 147 Direct Yellow 148 All other direct yellow dyes Direct orange dyes: Direct Orange 15 Direct Orange 26 Direct Orange 34 Direct Orange 39 Direct Orange 72 Direct Orange 80 Direct Orange 102 Direct Orange 118 All other direct orange dyes Direct red dyes: Direct Red 2 Direct Red 9 Direct Red 16 Direct Red 24 Direct Red 26 Direct Red 72 Direct Red 73 Direct Red 79 Direct Red 80 Direct Red 81 Direct Red 83 Direct Red 224 Direct Red 227 Direct Red 236 Direct Red 238 Direct Red 239 Direct Red 243 Direct Red 254 Direct Red 263 All other direct red dyes Direct violet dyes: Direct Violet 9 Direct Violet 35 Direct Violet 66 Direct Violet 99 Direct Violet 195 All other direct violet dyes See footnotes at end of table.

4-8

Separate statistics1 Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No Yes No No Yes No No No No No No

Manufacturers' identification codes (according to list In table 4-3)

BAS, CK, LVR, VPC. BAS. BAS, VPC. BAS, VPC. CK. CK. S. CK. CK. CK. CK. VPC. BAS, CK, S, VPC. VPC. S. S. VPC. BAS, CK, FAB, VPC. S. BAS, CK, VPC. FAB, VPC. CK. CK, FAB. CK, FAB. CK. CK. BAS, CK, VPC. S. BAS. CK. CK. CK, FAB. CK, FAB. CK. CK. CK. CK. CK. CK, LVR, VPC. CK, FAB. CK. CK. BAS, VPC. VPC. BAS, CK, S. CK. BAS, CK, VPC. BAS. BAS, CK, VPC. CK. S. CK. VPC. CK. BAS.

Synthetic Organic Chemicals, 1991 Table 4-2--Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Dyes Basic dyes (classical and modified)-Continued Basic yellow dyes-Continued Basic Yellow 11 Basic Yellow 83 Basic Yellow 94 Basic Yellow 96 Basic Yellow 98 Basic Yellow 102 All other basic yellow dyes Basic orange dyes: Basic Orange 1 Basic Orange 2 Basic Orange 21 Basic Orange 26 All other basic orange dyes Basic red dyes: Basic Red 12 Basic Red 14 Basic Red 15 Basic Red 17 Basic Red 29 Basic Red 46 Basic Red 49 Basic Red 73 Basic Red 104 Basic Red 111 All other basic red dyes Basic violet dyes: Basic Violet 1 Basic Violet 3 Basic Violet 4 Basic Violet 16 All other basic violet dyes Basic blue dyes: Basic Blue 1 Basic Blue 3 Basic Blue 6 Basic Blue 7 Basic Blue 21 Basic Blue 41 Basic Blue 60 Basic Blue 77 Basic Blue 94 and 94:1 Basic Blue 140 Basic Blue 152 All other basic blue dyes All other basic blue dyes, modified Basic green dyes: Basic Green 4 All other basic green dyes Basic brown dyes: Basic Brown 1 Basic Brown 4 All other basic brown dyes Basic black dyes: All other basic black dyes All other basic black dyes, modified

Separate statistic& Yes Yes No No No No No No No Yes No No No No No Yes No No No No No No No No No No No Yes No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' identification codes (according to list in table 4-3)

CK. CK. S. BAS. BAS. BAS. ALL. BAS, CK. BAS, CK, PSC. CK, VPC. CK. BAS. CK, VPC. BAS, CK, VPC. BAS, CK. CK. BAS. CK. BAS. CK. CK. S. BAS. BAS, DSC. CK, DSC. DSC. CK, VPC. BAS. BAS. BAS, CK. BAS. DSC. CK. BAS. BAS. CK. CK. S, VPC. BAS. BAS. BAS. BAS. BAS. PSC. BAS, PSC. BAS. BAS. BAS, CK.

See footnotes at end of table.

4-7

Section 4 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Dyes

Separate statistics

Direct dyes: Direct yellow dyes: Direct Yellow 4 Direct Yellow 5 Direct Yellow 6 Direct Yellow 11 Direct Yellow 34 Direct Yellow 44 Direct Yellow 51 Direct Yellow 105 Direct Yellow 106 Direct Yellow 107 Direct Yellow 118 Direct Yellow 119 Direct Yellow 127 Direct Yellow 131 Direct Yellow 132 Direct Yellow 133 Direct Yellow 137 Direct Yellow 147 Direct Yellow 148 All other direct yellow dyes Direct orange dyes: Direct Orange 15 Direct Orange 26 Direct Orange 34 Direct Orange 39 Direct Orange 72 Direct Orange 80 Direct Orange 102 Direct Orange 118 All other direct orange dyes Direct red dyes: Direct Red 2 Direct Red 9 Direct Red 16 Direct Red 24 Direct Red 26 Direct Red 72 Direct Red 73 Direct Red 79 Direct Red 80 Direct Red 81 Direct Red 83 Direct Red 224 Direct Red 227 Direct Red 236 Direct Red 238 Direct Red 239 Direct Red 243 Direct Red 254 Direct Red 263 All other direct red dyes Direct violet dyes: Direct Violet 9 Direct Violet 35 Direct Violet 66 Direct Violet 99 Direct Violet 195 All other direct violet dyes

Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No Yes No No Yes No No No No No No

See footnotes at end of table.

4-8

Manufacturers' identification codes (according to list in table 4-3)

BAS, CK, LVR, VPC. BAS. BAS, VPC. BAS, VPC. CK. CK. S. CK. CK. CK. CK. VPC. BAS, CK, S, VPC. VPC. S. S. VPC. BAS, CK, FAB, VPC. S. BAS, CK, VPC. FAB, VPC. CK. CK, FAB. CK, FAB. CK. CK. BAS, CK, VPC. S. BAS. CK. CK. CK, FAB. CK, FAB. CK. CK. CK. CK. CK. CK, LVR, VPC. CK, FAB. CK. CK. BAS, VPC. VPC. BAS, CK, S. CK. BAS, CK, VPC. BAS. BAS, CK, VPC. CK. S. CK. VPC. CK. BAS.

Synthetic Organic Chemicals, 1991 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Dyes

Separate statistics

Direct dyes-Continued Direct blue dyes: Direct Blue 14 Direct Blue 15 Direct Blue 25 Direct Blue 75 Direct Blue 76 Direct Blue 80 Direct Blue 86 Direct Blue 98 Direct Blue 100 Direct Blue 108 Direct Blue 160 Direct Blue 189 Direct Blue 191 Direct Blue 199 Direct Blue 218 Direct Blue 261 Direct Blue 269 Direct Blue 273 Direct Blue 279 Direct Blue 281 Direct Blue 283 Direct Blue 285 Direct Blue 286 All other direct blue dyes Direct green dyes: Direct Green 92 All other direct green dyes Direct brown dyes: Direct Brown 44 Direct Brown 154 All other direct brown dyes Direct black dyes: Direct Black 22 Direct Black 80 Direct Black 163 Direct Black 165 Direct Black 170 Direct Black 179 All other direct black dyes Disperse dyes: Disperse yellow dyes: Disperse Yellow 3 Disperse Yellow 23 Disperse Yellow 34 Disperse Yellow 42 Disperse Yellow 54 Disperse Yellow 64 Disperse Yellow 77 Disperse Yellow 86 Disperse Yellow 88 Disperse Yellow 108 Disperse Yellow 114 Disperse Yellow 126 Disperse Yellow 198 Disperse Yellow 219 Disperse Yellow 238 Disperse Yellow 239 All other disperse yellow dyes

Yes No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes No No No No No No No No No No No No No No No No No

See footnotes at end of table.

Manufacturers' Identification codes (according to list In table 4-3)

FAB. VPC. CK, FAB. CK, S. CK. CK, FAB. CK, S, VPC. CK, FAB. FAB. CK. CK. CK. CK. BAS, S, VPC. CK, FAB, VPC. S. VPC. S. VPC. VPC. CK. CK. CK. BAS, CK, VPC. CK. CK, FAB. FAB. CK. FAB, VPC. CK, FAB. CK, FAB. S. CK. CK. CK. BAS, CK, FAB, VPC. CK. CK. EKT. S. BAS. BAS, HCL. VPC. CK, EKT. EKT. EKE HCL ICI. BAS. S. CK. CK. BAS, ICI, VPC.

Section 4 Table 4-2--Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Dyes Disperse dyes-Continued Disperse orange dyes: Disperse Orange 3 Disperse Orange 25 and 25:1 Disperse Orange 29 Disperse Orange 30 Disperse Orange 37 Disperse Orange 41 Disperse Orange 44 and 44:1 Disperse Orange 73 Disperse Orange 89 Disperse Orange 138 Disperse Orange 153 Disperse red dyes: Disperse Red 1 Disperse Red 5 Disperse Red 9 Disperse Red 13 Disperse Red 17 Disperse Red 30 Disperse Red 50 Disperse Red 55 Disperse Red 60 Disperse Red 65 Disperse Red 73 Disperse Red 74 Disperse Red 86 Disperse Red 88 Disperse Red 91 Disperse Red 117 Disperse Red 135 Disperse Red 136 Disperse Red 137 Disperse Red 145 Disperse Red 153 Disperse Red 159 Disperse Red 167 and 167:1 Disperse Red 177 Disperse Red 179 Disperse Red 273 Disperse Red 274 Disperse Red 278 Disperse Red 305 Disperse Red 307 Disperse Red 311 Disperse Red 313 Disperse Red 316 Disperse Red 325 Disperse Red 333 Disperse Red 338 Disperse Red 339 Disperse Red 340 Disperse Red 345 Disperse Red 358 All other disperse red dyes See footnotes at end of table.

4-10

Separate statistics1

Yes No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No Yes No No Yes No No No No No No No No No No No No No No No No No

Manufacturers' Identification codes (according to list in table 4-3)

CK. CK, ICI. CK. BUC, CK, S, SDC. CK, EKT. S. CK, EKT. BAS, CK. CK. EKT. CK. CK. CK. CK. CK. CK. EKT. CK. BAS. BAS, CK. CK. CK, S. S. CK, S, SDC. EKT. BAS. EKT. CK. EKT. EKT. CK. CK, FAB, S. VPC. CK, S. CK, ICI, S. S. S. CK, S. ICI. Err EKT. ICI. S. S. CK. S. EKT. EKE EKT. CK. HCL. BAS, SDC.

Synthetic Organic Chemicals, 1991 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Dyes Disperse dyes-Continued Disperse violet dyes: Disperse Violet 1 Disperse Violet 17 Disperse Violet 28 Disperse Violet 33 Disperse Violet 36 Disperse Violet 48 Disperse Violet 60 All other disperse violet dyes Disperse blue dyes: Disperse Blue 1 Disperse Blue 3 Disperse Blue 14 Disperse Blue 27 Disperse Blue 56 Disperse Blue 60 Disperse Blue 62 Disperse Blue 64 Disperse Blue 73 Disperse Blue 79 Disperse Blue 95 Disperse Blue 102 Disperse Blue 118 Disperse Blue 148 Disperse Blue 175 Disperse Blue 183 Disperse Blue 200 Disperse Blue 281 Disperse Blue 284 Disperse Blue 291 Disperse Blue 333 Disperse Blue 337 Disperse Blue 359 All other disperse blue dyes Disperse green dyes: Disperse Green 9 Disperse brown dyes: Disperse Brown 1 Disperse Brown 18 Disperse Brown 22 Disperse Brown 26 Disperse Brown 27 Disperse black dyes: Disperse Black 9 All other disperse black dyes Fiber-reactive dyes: Reactive yellow dyes: Reactive Yellow 7 Reactive Yellow 15 Reactive Yellow 18 Reactive Yellow 42 Reactive Yellow 86 Reactive Yellow 135 Reactive Yellow 160 Reactive Yellow 165 All other reactive yellow dyes

Separate statistics1

Manufacturers' identification codes (according to list in table 4-3)

Yes No No No No No No No No

CK. CK. CK. ICI, S. S. HCL. S. EKT.

No No No No No No No No No Yes No No No No No No No No No No No No No No Yes No Yes Yes No No No No Yes No No No No No No No No No No No No No

CK. CK, EKT. CK. EKT. CK. BAS. EKT. EKT. S. BAS, BUC, CK, EKT, ICI, S. HCL. CK, EKT. EKT. BAS. CK. S. ICI. S. ICI. CK, S. HCL. EKT. CK. BAS, BUC, ICI, SDC. ICI. BUC, CK, S, SDC. S. EKE CK. CK. CK, EKT, FAB. BAS, SDC. ICI. HCL ICI. HCL. ICI. ICI. HCL. S. HCL.

See footnotes at end of table.

4-11

Section 4

Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Dyes

Separate statistical

Fiber-reactive dyes-Continued Reactive orange dyes: Reactive Orange 1 Reactive Orange 4 Reactive Orange 12 Reactive Orange 13 Reactive Orange 16 Reactive Orange 20 Reactive Orange 72 Reactive Orange 84 Reactive Orange 86 All other reactive orange dyes Reactive red dyes: Reactive Red 2 Reactive Red 11 Reactive Red 21 Reactive Red 24 Reactive Red 31 Reactive Red 33 Reactive Red 35 Reactive Red 43 Reactive Red 49 Reactive Red 94 Reactive Red 120 Reactive Red 141 Reactive Red 180 All other reactive red dyes Reactive violet dyes: Reactive Violet 1 Reactive Violet 5 All other reactive violet dyes Reactive blue dyes: Reactive Blue 3 Reactive Blue 4 Reactive Blue 5 Reactive Blue 7 Reactive Blue 19 Reactive Blue 21 Reactive Blue 28 Reactive Blue 38 Reactive Blue 41 Reactive Blue 71 Reactive Blue 89 Reactive Blue 199 Reactive Blue 214 All other reactive blue dyes Reactive green dyes: Reactive Green 19 Reactive brown dyes: Reactive Brown 1 Reactive Brown 17 Reactive Brown 18 Reactive black dyes: Reactive Black 5 Reactive Black 9 All other reactive black dyes

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

See footnotes at end of table.

4-12

Manufacturers' identification codes (according to list in table 4-3)

ICI. ICI. ICI. ICI. CK. CK. CK. ICI. ICI. HCL ICI. ICI. HCL. BAS. ICI. ICI. HCL. CK, ICI. HCL. HCL. ICI, S. ICI. HCL CK, HCL. ICI. HCL. HCL, ICI. ICI. ICI. ICI. CK. HCL HCL CK. HCL S. ICI. ICI. ICI. S. HCL, ICI. ICI. ICI. ICI. HCL. CK, HCL ICI. HCL.

Synthetic Organic Chemicals, 1991 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Dyes

Fluorescent brighteners: Fluorescent Brightener 28 Fluorescent Brightener 49 Fluorescent Brightener 52 Fluorescent Brightener 61 Fluorescent Brightener 71 Fluorescent Brightener 130 Fluorescent Brightener 205 Fluorescent Brightener 231 Fluorescent Brightener 232 Fluorescent Brightener 290 Flourescent Brightener 315 Flourescent Brightener 339 All other fluorescent brighteners Food, drug, and cosmetic colors: Food, drug, and cosmetic dyes: Food, Drug, and Cosmetic Blue 1 Food, Drug, and Cosmetic Blue 2 Food, Drug, and Cosmetic Green 3 Food, Drug, and Cosmetic Red 2 Food, Drug, and Cosmetic Red 3 Food, Drug, and Cosmetic Red 40 Food, Drug, and Cosmetic Yellow 5 Food, Drug, and Cosmetic Yellow 6 Drug and cosmetic dyes: Drug and Cosmetic Red 57:1 Drug and Cosmetic Red 1 1 Drug and Cosmetic Green 5 Drug and Cosmetic Orange 5 Drug and Cosmetic Red 6 Drug and Cosmetic Red 7 Drug and Cosmetic Red 17 Drug and Cosmetic Red 21 Drug and Cosmetic Red 22 Drug and Cosmetic Red 27 Drug and Cosmetic Red 30 Drug and Cosmetic Red 33 Drug and Cosmetic Red 34 Drug and Cosmetic Red 36 Drug and Cosmetic Yellow 5 Drug and Cosmetic Yellow 8 Drug and Cosmetic Yellow 10 Drug and cosmetic dyes, external: External Drug and Cosmetic Orange 3 Mordant dyes: Mordant yellow dyes: Mordant Yellow 16 Mordant orange dyes: Mordant Orange 1 Mordant Orange 3 Mordant Orange 6 Mordant brown dyes: Mordant Brown 1 Mordant Brown 33 Mordant Brown 70 Solvent dyes: Solvent yellow dyes: Solvent Yellow 3 Solvent Yellow 13 Solvent Yellow 14 Solvent Yellow 16 Solvent Yellow 18

Separate statistics1

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes No Yes No No No

Manufacturers' identification codes (according to list in table 4-3)

VPC. S. S. BAS. VPC. BAS. VPC. S. S. S. CK. CK. S, VPC. WJ. WJ. WJ. WJ. WJ. WJ. WJ. CK, WJ. SNA. SNA. CK, WJ. CCG, SNA. CCG, SNA. CCG, SNA. WJ. CCG, SNA. WJ. CCG, SNA, WJ. CCG, SNA. CCG, CK, SNA, WJ. CCG, SNA. CCG, SNA. CCG. WJ. CCG, CK, WJ. CK, WJ. CK. FAB. FAB. FAB. FAB. FAB. FAB. PSC. BAS, CK, FAB. PSC. PSC. CK.

See footnotes at end of table. 4-13

Section 4

Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Dyes Solvent dyes—Continued: Solvent yellow dyes—Continued: Solvent Yellow 33 Solvent Yellow 40 Solvent Yellow 42 Solvent Yellow 43 Solvent Yellow 56 Solvent Yellow 72 Solvent Yellow 96 Solvent Yellow 131 Solvent Yellow 135 Solvent Yellow 143 Solvent Yellow 160 Solvent Yellow 161 Solvent Yellow 167 All other solvent yellow dyes Solvent orange dyes: Solvent Orange 2 Solvent Orange 3 Solvent Orange 7 Solvent Orange 20 Solvent Orange 23 Solvent Orange 31 Solvent Orange 60 Solvent Orange 77 Solvent Orange 97 All other solvent orange dyes Solvent red dyes: Solvent Red 1 Solvent Red 23 Solvent Red 24 Solvent Red 26 Solvent Red 27 Solvent Red 49 Solvent Red 68 Solvent Red 111 Solvent Red 164 Solvent Red 166 Solvent Red 168 Solvent Red 169 Solvent Red 175 Solvent Red 179 Solvent Red 207 Solvent Red 208 Solvent violet dyes: Solvent Violet 8 Solvent Violet 9 Solvent Violet 11 Solvent Violet 13 Solvent Violet 38 All other solvent violet dyes Solvent blue dyes: Solvent Blue 3 Solvent Blue 5 Solvent Blue 23 Solvent Blue 35 Solvent Blue 36 Solvent Blue 38 Solvent Blue 58 Solvent Blue 59 Solvent Blue 98 See footnotes at end of table. 4-14

Separate statistics Yes Yes No No No No No No No No No No No No No No Yes No No No No No No No No No No Yes No No No No No No No No No No No No No No No No Yes No No No No No No Yes No No No No No No No No No

Manufacturers' identification codes (according to list in table 4-3)

BAS, CIC, MRT. CK. CK. HCL. PSC. CIC, FAB, PSC, UCM. MRT. DGO. DGO. MRT. (2). MRT. CIC. CK, MRT, (2). PSC. PSC. CK, PSC. BAS, CK, FAB. CK. PSC. CIC. MRT. MRT. (2). PSC. PSC. PSC. PSC. PSC. BAS. CK, MRT MRT. MRT, (2), (2). MRT. MRT. MAT. MRT. CIC. MRT. MRT BAS, DSC. DSC. CK. CK. MRT. CK. PSG. DSC. BAS. MRT MRT TNI. VPC. MRT, VPC. MRT

Synthetic Organic Chemicals, 1991 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Dyes Solvent blue dyes—Continued:

Solvent Blue 99 Solvent Blue 100 Solvent Blue 102 Solvent Blue 128 Solvent Blue 129 Solvent green dyes:

Solvent Green 3 Solvent brown dyes:

Solvent Brown 12 Solvent Brown 20 Solvent Brown 22 Solvent Brown 38 Solvent Brown 52

Solvent black dyes:

Solvent Black 5 Solvent Black 7 Solvent Black 13 Solvent Black 26 Solvent Black 46 Solvent Black 47 Solvent Black 49 Sulfur dyes: Sulfur yellow dyes:

Leuco Sulfur Yellow 21 Leuco Sulfur Yellow 22 All other sulfur yellow dyes Sulfur orange dyes:

All other sulfur orange dyes Sulfur red dyes:

Leuco Sulfur Red 14 Sulfur Red 10 Sulfur blue dyes:

Leuco Sulfur Blue 7 Leuco Sulfur Blue 11 Leuco sulfur blue 20 Sulfur green dyes:

Leuco Sulfur Green 2 Leuco Sulfur Green 16 Leuco Sulfur Green 34 Leuco Sulfur Green 35 Leuco Sulfur Green 36 Solubilized Sulfur Green 11 Sulfur brown dyes:

Leuco Sulfur Brown 1, 1:1 Leuco Sulfur Brown 3 Leuco Sulfur Brown 37 Leuco Sulfur Brown 52 Leuco Sulfur Brown 96 Sulfur Brown 37 Sulfur Brown 96 Sulfur black dyes:

Leuco Sulfur Black 1 Leuco Sulfur Black 2 Leuco Sulfur Black 11, 11:1 Leuco Sulfur Black 18 Solubilized Sulfur Black 2 Sulfur Black 2 Sulfur Black 11, 11:1

See footnotes at end of table.

Separate statistics

Yes No No No No No No No No No No No No No No No No No No No No No No No No No No - No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' identification codes (according to list in table 4-3)

MRT. MRT. MRT. MRT. MRT. CK, MRT. PSC. CK, MRT. PSC. FAB. MRT. LVR. BAS, CK, OCC, PSC. CK. FAB. MRT. MRT. MRT. SDC. SDC. SDC. SDC. SDC. SDC. S, SDC. SDC. S. SDC. SDC. SDC. SDC. SDC. S. SDC. SDC. S, SDC. SDC. SDC. SDC. SDC. SDC. S, SDC. SDC. SDC. SDC. SDC. SDC.

Section 4 Table 4-2—Continued Dyes for which U.S. production and/or sales were reported, identified by manufacturer, 1 991 Dyes

Separate statistics

Vat dyes: Vat orange dyes: Vat Orange 1, 20% Vat Orange 2, 12% Vat Orange 7, 11% Vat Orange 9, 12% Vat red dyes: Vat Red 10,18% Vat Red 15,10% All other vat red dyes Vat violet dyes: Vat Violet 13, 6-1/4% Vat blue dyes: Vat Blue 1, 20% Vat Blue 6, 8-1/3% Vat Blue 16, 16% Vat Blue 19 Vat Blue 29 Vat Blue 43 Vat Blue 66 All other vat blue dyes Vat green dyes: Vat Green 1, 6% Vat Green 3, 10% Vat Green 7 Vat brown dyes: Vat Brown 57, 12.8% Vat black dyes: Vat Black 22, 19% Vat Black 25, 12-12% Miscellaneous dyes: All other dyes

Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes

Manufacturers' identification codes (according to list in table 4-3)

SDC. BAS. HCL. BAS. BAS. HCL HCL BAS, SDC. BCC. BAS, SDC. BAS. BAS. BAS. SDC. BAS. SDC. BAS, SDC. BAS, SDC. SDC. HCL. SDC. BAS, SDC. MRT, RIL SDC.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to his identification with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

4-16

Synthetic Organic Chemicals, 1991 Table 4-3 Dyes: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ALL BAS BCC BUC

Alliance Chemical, Inc. BASF Corp. Buffalo Color Corp Synalloy Corp., Blackman Uhler Chemical Div. Warner-Jenkinson Cosmetic Colors Color Chem International Corp. Crompton & Knowles Corp. Day-Glo Color Corp. Dye Specialties, Inc. Eastman Kodak Co., Tennessee Eastman Co. Div. Fabricolor Manufacturing Corp. Hoechst Celanese Corp.' Sou-Tex Works Specialty Chem Group

ICI LVR MRT

ICI Americas, Inc., Specialty Chem Div. C. Lever Co., Inc. Morton International, Inc., Specialty Chemicals Orient Chemical Corp. Passaic Color & Chemical Co. PMC, Inc., PMC Specialities Group, Inc. Reilly Industries, Inc. Roma Color, Inc. Sandoz, Inc. Sandoz Chemicals Corp. Sun Chemical Corp., Pigments Div. Gillette Chemical Co. United Color Manufacturing Co. Miles, Inc. Wamer-Jenkinson Co.

CCG CIC CK DGO DSC EKT FAB HCL

.

OCC PSC PSG RIL ROM S& SDC SNA TNI UCM VPC WJ

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaire of the U.S. International Trade Commission.

Synthetic Organic Chemicals, 1991 Production of toners in 1991 accounted for over 99 percent of total pigment production. Changes in toner production and sales mirrored changes in production and sales of total pigments. The individual toners listed in the report which were produced in the largest quantities in 1991 were Pigment Yellow 12, Pigment Yellow 14, Pigment Red 48:2 calcium toner, Pigment Red 53:1 barium toner, and Pigment Green 7.

Section 5 Organic Pigments Organic pigments are toners and lakes 1 derived in whole or in part from benzenoid chemicals and colors. Statistics on production and sales of all organic pigments in 1990 are given in table 5-1 Individual toners and lakes are identified in this report by the names used in the third edition of the Colour Index. Total production of organic pigments in 1991 was 51 million kilograms, 2.4 percent less than the 52 million kilograms produced in 1990. Total sales of organic pigments in 1991 amounted to 39 million kilogams, valued at $644 million, compared with 45 million kilograms, valued at $717 million, in 1990. In terms of quantity, sales of organic pigments in 1991 were 11.9 percent lower than in 1990; in terms of value, sales in 1991 were 10.3 percent lower than in 1990. Changes in U.S. production of pigments have followed overall changes in U.S. economic activity during 1987-91 (see figure 5-1).

Table 5-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 5-3. Jesse Lawrence Johnson 202-205-3351

Figure 5-1 Organic pigments: U.S. production, 1987-91 Millions of kilograms

60

1987

1988

1989

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 1 Toners and lakes are essentially the same in their final form; they differ in the method of preparation. A lake is an organic pigment produced by the interaction of a soluble dye, a precipitant, and an absorptive inorganic substrate. A toner is an insoluble dye produced as a powder; some toners are extended by the indusion of a solid diluent. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

5-1

Section 5 Table 5-1 Organic pigments: U.S. production and sales, 1991

Production

Quantity

Value1

Average Unit value2

1,000 Kilograms

1,000 Kilogtams

1,000 dollars

Per kilogram

Sales Organic pigments

dry basis 3

dry basis 3

51,311

39,426

643,561

$16.32

14,548

10,602

135,156

12.75

1,498

1,040

18,875

18.15

135 531 832

146 500 394

2,697 9,350 6,828

18.52 18.69 17.33

9,040 285 2,963 147 537 78

5,828 207 2,792 143 518 74

63,684 3,285 30,973 2,271 13,812 2,256

10.93 15.84 11.09 15.87 26.78 30.49

1,217

1,104

18,233

16.52

392 58 382 41 344

342 51 344 43 324

4,165 1,201 5,275 1,066 6,526

12.19 23.74 15.32 24.79 20.14

15,959

12,470

224,549

18.01

1,000 25 210 103 662 14,959 251 72 777 955 854 74 1,391 157 10,428

985 26 199 101 659 11,485 219 72 609 886 815 72 1,249 141 7,422

27,946 56 4,149 2,866 20,875 196,603 3,810 1,848 8,012 11,946 9,049 1,168 9,870 3,571 147,329

28.38 21.16 20.88 28.48 31.68 17.12 17.41 25.51 13.17 13.49 11.10 16.16 7.90 25.27 19.85

Violet toners, total

2,288

1,628

76,773

47.15

Blue toners, total

15,569

12,070

155,348

12.87

Grand Total Toners Yellow toners, total Acetoacetarylide yellows, total Pigment Yellow 65, C.I. 11 740 Pigment Yellow 74, C.I. 11 741 All other acetoacetarylide yellows Diarylide: Pigment Yellow 12, C.I. 21 090 Pigment Yellow 13, C.I. 21 100 Pigment Yellow 14, C.I. 21 095 Pigment Yellow 17, C.I. 21 105 Pigment Yellow 83, C.I. 21 108 All other yellow toners Orange toners, total Pigment Orange 5, C.I. 21 075 Pigment Orange 13 Pigment Orange 16, C.I. 21 160 Pigment Orange 34 All other Orange toners Red toners, total Naphthol reds, total Pigment Red 2, C.I. 12 310 Pigment Red 22, C.I. 12 315 Pigment Red 23, C.I. 12 355 All other naphthol reds Other red toners, total Pigment Red 3, C.I. 12 120 Pigment Red 38, C.I. 12 120 Pigment Red 48:1, barium toner, C.I. 15 865 Pigment Red 482, calcium toner, C.I. 15 865 Pigment Red 52:1, calcium toner, C.I. 15 860 Pigment Red 52:2, manganese toner, C.I. 15 860 Pigment Red 53:1, barium toner, C.I. 15 585 Pigment Ned 81, PMA, C.I. 45 160 All other red toners

See footnotes at end of table.

52 -

Synthetic Organic Chemicals, 1991 Table 5-1—Continued Organic pigments: U.S. production and sales, 1991 Sales Organic pigments

Green toners, total Pigment Green 7, C.I. 74 260 Pigment green 36 • All other green toners

Production

Quantity

Values

Average Unit value2

1,000 Kilograms dry basis3

1,000 Kilogtams dry basis3

1,000 dollars

Per kilogram

1,393 1,350 0 43

1,344 1,290 38 16

30,202 28,089 1,377 736

22.47 21.77 36.31 46.00

9 24

12 23

391 609

32.58 26.48

304

173

2,300

13.29

Lakes Pigment Red 83, C.I. 58 000 Pigment Violet 5:1, C.I. 58 055 All other lakes and toners

1 The value of sales for toners is reported on a dry-full strength basis and the value of sales for lakes is reported on a dry form basis. All sales value data exclude the additional cost of processing or packaging in commercial forms other than the dry full-strength or dry form. 2 Calculated from unrounded figures. 3 Quantities for toners are reported as dry full-strength toner content, excluding the weight of any dispersing agent, vehicle, or extender. Quantities for lakes are reported as dry lake content, excluding the weight of any dispersing agent or vehicle. Note.—The C.I. (Colour Index) number shown in this report are the identifying number given in the third edition of the Colour Index. The abbreviation PMA stands for phosphomolybdic acids.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Section 5

Table 5-2 Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Organic pigments

Separate statistics1

Manufacturers' identification codes (according to list in table 5-3)

Yes Yes No No No No Yes No Yes No No No No No Yes

BAS, DUP, HSH, MAX, SNA. KCW. HEU, HSH, KCW, MAX, SNA, VPC. HSH. HCL, HEU, HSH, SNA, VPC. HCL, HSH, SNA, VPC. BAS, HCL, HEU, HSH, ROM, SNA, VPC, HCL, HSH, SNA. HCL. HCL. BAS. HCL. KCW.

Toners: Yellow toners: Acetoacetarylide yellows: Pigment Yellow 1 Pigment Yellow 2 Pigment Yellow 3 Pigment Yellow 60 Pigment Yellow 65 Pigment Yellow 73 Pigment Yellow 74 Pigment Yellow 75 Pigment Yellow 97 Pigment Yellow 98 Pigment Yellow 119 Pigment Yellow 194 All other acetoacetarylide yellows Diarylide yellows: Pigment Yellow 12 Pigment Yellow 13

Yes

Pigment Yellow 14

Yes

Pigment Yellow 17

Yes

Pigment Yellow 83

Yes

Pigment Yellow 124 Pigment Yellow 176 Yellow pigments, other: (Basic Yellow 2), fugitive Pigment Yellow 16 Pigment Yellow 139 All other pigment yellow toners Orange toners: Pigment Orange 1 Pigment Orange 2 Pigment Orange 5 Pigment Orange 13 Pigment Orange 15 Pigment Orange 16 Pigment Orange 34 Pigment Orange 38 Pigment Orange 46 Pigment Orange 48 All other pigment orange toners Red toners: Naphthol reds: Pigment Red 2 Pigment Red 5 Pigment Red 13 Pigment Red 17 Pigment Red 21 Pigment Red 22 Pigment Red 23

See footnotes at end of table. 5-4

Yes

No No No No No Yes Yes No No Yes Yes No Yes Yes No No No Yes Yes Yes Yes No No No No Yes Yes

APO, BAS, CDR, HCL, HSH, IDC, IND, POP, ROM, SNA. APO, BAS, CDR, GLX, HCL, IDC, IND, ROM, SNA. BAS, CDR, FAB, GLX, HCL, HSH, IDC, IND, ROM, SNA, VPC. APO, BAS, FAB, GLX, HCL, HSH, IDC, IND, ROM. BAS, FAB, GLX, HCL, IDC, IND, ROM, SNA. GLX. SNA. MAX. HCL VPC. HSH, VPC. MAX. UHL BAS, HCL, HSH, SNA. BAS, HSH, SNA. IND. FAB, GLX, HSH, IND, ROM, SNA. BAS, HCL, ROM, SNA. CDR, HCL BAS, SNA. CGY. GLX, UHL GLX, HCL, HSH, MAX. FAB, GLX, HSH. KCW. ROM, SNA, UHL IND. FAB, GLX, HEU, IND, MAX, ROM, SNA. DUP, FAB, GLX, HEU, HSH, IND, KCW, ROM, SNA, UHL.

Synthetic Organic Chemicals, 1991 Table 5-2—Continued Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Organic pigments Toners-Continued Red toners-Continued Naphthol reds—Continued Pigment Red 31 Pigment Red 112 Pigment Red 146 Pigment Red 147 Pigment Red 170 Pigment Red 210 All other naphthol reds Red toners, other: Pigment Red 1, (light) Pigment Red 3 Pigment Red 4 Pigment Red 38 Pigment Red 41 Pigment Red 48:1, (barium)

Separate statistics

Manufacturers' identification codes (according to list in table 5-3)

Yes Yes No No No No No No Yes

GLX. HCL, VPC. HCL. HCL, HSH. GLX, HCL, HEU. SNA. BUC, FAB, GLX, MGR, ROM, (2).

No Yes No Yes No Yes

Pigment Red 48:2, (calcium)

Yes

Pigment Red 48:3, (strontium) Pigment Red 48:4, (manganese) Pigment Red 49:1, (barium) Pigment Red 49:2, (calcium) Pigment Red 52:1, (calcium) Pigment Red 52:2, (manganese) Pigment Red 53:1, (barium)

No No No No Yes Yes Yes

Pigment Red 57:1, (calcium)

No

Pigment Red 63 Pigment Red 81, (PMA) Pigment Red 81, (PTA) Pigment Red 101 Pigment Red 122 Pigment Red 123 Pigment Red 135 Pigment Red 149 Pigment Red 168 Pigment Red 169 Pigment Red 176 Pigment Red 179 Pigment Red 181 Pigment Red 188 Pigment Red 190 Pigment Red 194 Pigment Red 195 Pigment Red 200 Pigment Red 202 Pigment Red 206 Pigment Red 207 Pigment Red 209 Pigment Red 214 Pigment Red 224 Pigment Red 238 Pigment Red 63:1, calcium All other pigment red toners

No Yes No No No No No No No No No No No No No No No No No No No No No No No No Yes

HSH. BAS, HSH, MAX, SNA, UHL. HSH, MAX, SNA, UHL. FAB, HCL, HSH, SNA, VPC. VPC. APO, BAS, CDR, HEU, HSH, MGR, SNA, UHL. APO, BAS, CDR, HCL, HEU, HSH, MGR, SNA, UHL, VPC. HSH. HEU, HSH, SNA. BAS, IDC, MGR, SNA, UHL. CDR, IDC, MAX, MGR, SNA, UHL. APO, BAS, CDR, HSH, MGR, SNA, UHL. BAS, CDR, HSH, UHL APO, BAS, CDR, HSH, IDC, MAX, MGR, SNA, UHL. APO, BAS, CDR, FAB, HSH, IDC, MGR, POP, PS, SNA, UHL. HSH. BAS, MGR, SNA, UHL BAS, MAX, UHL. HCL. SNA, VPC. VPC. HCL HCL. VPC. MAX. HCL HEU, SNA, VPC. HCL. HCL. VPC. HCL. HCL BAS. CGY, SNA, VPC. COY. CGY. SNA. HCL. VPC. FAB. SNA. HCL, SNA, VPC.

See footnotes at end of table.

5-5

Section 5

Table 5-2—Continued Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Organic pigments

Separate statIsticsi

Manufacturers' Identification codes (according to list in table 5-3)

Toners-Continued Violet toners: Pigment Violet 1, (fugitive) Pigment Violet 1, (PMA) Pigment Violet 1, (PTA) Pigment Violet 3, (fugitive) Pigment Violet 3, (PMA) Pigment Violet 3, (PTA) Pigment Violet 4, (fugitive) Pigment Violet 19 Pigment Violet 23 Pigment Violet 27 Pigment Violet 29 Pigment Violet 39, (PMA) All other pigment violet toners Blue toners: Pigment Blue 1, (PMA) Pigment Blue 1, (PTA) Pigment Blue 2, (PMA) Pigment Blue 14, (PMA) Pigment Blue 15, (a form) Pigment Blue 15:1, (a form) Pigment Blue 15:2, (a form) Pigment Blue 15:3, (l form)

Yes No No No No No No No No No No No No No Yes No No No No No No No No

Pigment Blue 15:4, (0 form) Pigment Blue 19 Pigment Blue 25 Pigment Blue 61 Pigment Blue 62 All other pigment blue toners Green toners: Pigment Green 1, (PMA) Pigment Green 2, (PMA) Pigment Green 2, (PTA) Pigment Green 4, (PMA) Pigment Green 7

No No No No No No Yes No No No No Yes

Pigment Green 10 Pigment Green 36 All other pigment green toners Brown toners: Pigment Brown 5 Black toners: Pigment Black 7 All other pigment black toners

No Yes Yes

MAX, UHL. MAX. MAX. UHL. ALG, BAS, BFC, HCL, MGR, POP, SNA, VPC. HEU. ALG, SNA, VPC. UHL.

No

GLX.

No No

HCL. UHL.

Lakes: Yellow lakes: (Acid Yellow 23) All other pigment yellow lakes Orange lakes: Pigment Orange 17

Yes

See footnotes at end of table.

5-6

KCW, UHL. BAS, MAX, MGR, UHL MGR, SNA, UHL UHL. MAX, MGR, UHL. FAB, MAX, UHL. KCW. CGY, SNA, VPC. HCL, IPP, RMI, SNA. MAX. SNA, VPC. BAS. BUC, UHL, VPC. MGR, UHL MAX. UHL. BAS, HSH, MGR, UHL. BAS, CGY, HEU, SNA. CGY, HCL, HEU, SNA, VPC. CGY, HEU, SNA, VPC. ALG, APO, BAS, BFC, CDR, CGY, HCL, HEU, IDC, IPP, MGR, POP, PS, SNA. BFC, CGY, HEU, POP, SNA, VPC. BAS, PSG. FAB, GLX. BAS. MAX. BAS, FAB.

No No

MAX. LVR.

No

KCW.

Synthetic Organic Chemicals, 1991 Table 5-2—Continued Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Organic pigments

Separate statistics1

Manufacturers' identification codes (according to list in table 5-3)

Lakes-Continued

Red lakes: (Acid Red 26) (Basic Red 81, PMA) Pigment Red 60:1 Pigment Red 83 Violet lakes: Violet 5:1 Blue lakes: (Basic Blue 14, PMA) Green lakes: (Basic Green 1, PMA) (Basic Green 1, PMA)

No No No Yes

KCW. LVR. HSH. HSH, MAX, UHL.

Yes

HSH, MAX, UHL, VPC.

No

LVR.

No No

LVR. LVR.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

5-7

Section 5 Table 5-3 Organic pigments: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

ALG APO BAS BFC BUC

Allegheny Chemical Corp Apollo Colors, Inc. BASF Corp. Baker Fine Color, Inc. Synalloy Corp., Blackman Uhler Chemical Div. CDR Pigments & Dispersions Ciba-Geigy Corp. E.I. duPont de Nemours & Co., Inc., Chemicals and Pigments Dept. Fabricolor Manufacturing Corp. Galrode Chemical Corp. Hoechst Celanese Corp.: Specialty Chem Group Cookson Pigment, Inc. Engelhard Corporation

CDR CGY DUP FAB GLX HCL HEU HSH

.

Code

Name of company

IDC IND IPP ..... KCW LVR MAX , MGR POP PS PSG RMI ROM SNA UHL VPC

Industrial Color, Inc. Indol Color Co., Inc. Spectrachem Corp. Keystone Color Works, Inc. C. Lever Co., Inc. Max Marx Color Corp. Magruder Color Co., Inc. Daicolor-Pope, Inc. CPS Corp. PMC, Inc. Specialities Group, Inc. R-M industries Roma Color, Inc. Sun Chemical Corp., Pigment Div. Paul Uhlich & Co., Inc. Miles, Inc.

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

5-8

Synthetic Organic Chemicals, 1991

Section 6 Medicinal Chemicals

as an intermediate in the manufacture of other antibiotics. All quantities are given in terms of 100 percent content of the pure bulk drug. Table 6-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 6-3. Total U.S. production of bulk medicinal chemicals in 1991 amounted to 183.9 million kilograms. Total sales of bulk medicinal chemicals in 1991 amounted to 133 1 million kilograms, valued at $2,376.4 million Beginning in 1980, methionine and most other amino acids and their salts are reported in the section on Miscellaneous End-Use Chemicals and Chemical Products. Section totals are not, therefore. comparable with years prior to 1980. Production of the larger groups of medicinal chemicals in 1991 was as follows (see table 6-1): Antibiotics, 23.2 million kilograms, 6 percent lower than in 1990; anti-infective agents other than antibiotics, 11.4 million kilograms, 39.6 percent higher than in 1990; central nervous system depressants and stimulants, 39.0 million kilograms, 3.3 percent lower than in 1990; gastrointestinal agents and therapeutic nutrients. 47 1 million kilograms, 88.6 percent higher than in 1990; and vitamins, 40.2 million kilograms, 6.9 percent higher than in 1990. Elizabeth R. Nesbitt 202-205-3355

Medicinal chemicals include the medicinal and feed grades of all organic chemicals having therapeutic value, whether obtained by chemical synthesis, by fermentation, by extraction from naturally occurring plant or animal substances, or by refining a technical grade product. They include antibiotics and other anti-infective agents, antihistamines, autonomic drugs, cardiovascular agents, central nervous system depressants and stimulants, hormones and synthetic substitutes, vitamins, and other therapeutic agents for human or veterinary use, and for animal feed supplements. Data for the production of these products during 1987-91 are shown in figure 6-1. Table 6-1 shows statistics for production and sales of medicinal chemicals grouped by pharmacological class. The statistics shown are for bulk chemicals only. Finished pharmaceutical preparations and products put up in pills, capsules, tablets, or other measured doses are excluded. 1 The reported levels of production and sales reflects inventory changes, processing losses, and captive consumption of medicinal chemicals processed into ethical (i.e., available by prescription) and proprietary pharmaceutical products by the primary manufacturer. in some instances, the difference may also include quantities for medicinal grade products used as intermediates; for example, penicillin V used

Figure 6-1 Medicinal Chemicals: U.S. production, 1987-91 Millions of kilograms 200 180 160 140 120 100 80 60

40 20 0

1987

1988

1989

1990

1991

1 Complementary statistics on the dollar value of manufacturers' shipments of finished pharmaceutical

preparations, except biologicals, are published annually by the U.S. Department of Commerce, Bureau of the Census, in Current Industnal Reports, Series MA-28G. Many pharmaceutical manufacturers that report to the Bureau of the Census are exduded from the U.S. International Trade Commission report because they are not primary producers of medicinal chemicals; that is, they do not themselves produce the bulk drugs which go into their pharmaceutical products, but purchase their drug requirements from domestic or foreign producers. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 6-1

Section 6 Table 6-1 Medicinal chemicals: U.S. production and sales, 1991

Production 1

Quantity

Veto

Average Unit value2

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Sales Medicinal chemicals

183,905

133,063

2,376,403

$17.86

23,231 135 11,414

6,863 90 6,462

644,876 24,297 52,065

93.96 269.97 8.06

( 3)

( 3)

(3)

4,453 39,019

6,462 29,043

52,065 501,417

8.06 17.26

35,409 3,610

26,568 2,475

212,044 289,373

7.98 116.92

933

824

11,346

13.77

Gastrointestinal agents and therapeutic nutrients 6

47,072

63,907

88,120

1.38

Vitamins?

40,179

17,556

189,916

10.82

Miscellaneous medicinal chemicals8

21,922

8,318

864,366

103.92

Grand total Antibiotics Antihistamines Anti-infective agents (except antibiotics), total Anthelmintics All other anti-infective agents (except antibiotics)4 Central depressants and stimulants, total Analgesics, antipyretics, and nonhormonal antiinflammatory agents, total All other central depressants and stimulants 5 Expectorants and mucolytic agents

6,961

1 The data on production and sales are for bulk medicinal chemicals only. Methionine and most other amino acids and their salts are now reported in the section on Miscellaneous End-Use Chemicals and Chemical Products. Section totals are not, therefore, comparable with years prior to 1980. 2 Calculated from rounded figures. 3 Reported data were accepted in confidence and may not be published, or no data were reported. 4 Includes production and sales of antiprotozoan agents, sulfonamides, and urinary antiseptics; includes sale of anthelminties; does not include production of sulfaguanidine used as an intermediate in the production of anti-infective sulfonamides. 5 Includes production and sales of amphetamines; general anesthetics; respiratory and cerebral stimulants; skeletal muscle relaxants; tranquilizers; anticonvulsants, hypnotics, and sedatives; aspirin; antidepressant; and antitussives. 6 Methionine and its salts are reported in the section in Miscellaneous End-Use Chemicals and Chemical Products under amino acids. 7 Includes production and sales of vitamin A, vitamin B, vitamin C, vitamin D, vitamin E, and vitamin K. 8 Includes production and sales of antineoplastic agents, cardiovascular agents, diagnostic agents, hematological agents, renal-acting and edema-reducing agents, autonomic drugs, dermatological agents and unclassified medicinal chemicals. Also includes production and sales of local anesthetics, smooth muscle relaxants (including theophylline derivatives), and hormones and synthetic substitutes.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

6-2

Synthetic Organic Chemicals, 1991 Table 6-2 Medicinal chemicals for which US. production and/or sales were reported, identified by manufacturer, 1991 Medicinal chemicals

Antibiotics: Cephalosporins: Cefador Cefamandole Cefazolin, sodium Cefoxitin Cephalexin Cephalothin, sodium Cephradine Penicillins, semisynthetic: Amoxicillin: Amoxicillin (trihydrate) Amoxicillin (anhydrous) Ampicillin: Ampicillin (anhydrous) Ampicillin (trihydrate) Other semisynthetic penicillins: Ampicillin, sodium Cloxacillin, sodium Dicloxacillin, sodium Hetacillin, potassium Methicillin, sodium Nafcillin, sodium Oxacillin, sodium Piperacillin Ticarcillin, disodium All other semisynthetic penicillins Penicillins (except semisynthetic): For medicinal use: Penicillin V Penicillin G, benzathine Penicillin 0, potassium Penicillin V, potassium Penicillin G, procaine (medicinal grade) For nonmedicinal uses . Penicillin G, procaine (animal feed grade) Tetracyclines For medicinal use: Chlortetracycline (medicinal grade) Minocydine Tetracycline For nonmedicinal uses: Chlortetracycline (animal feed grade) Oxytetracycline (animal feed grade) Other antibiotics: For medicinal use • Antifungal antibiotics: Amphotericin B Nystatin (medicinal grade) Antitubercular antibiotics: Cycloserine Dihydrostreptomycin Other antibiotics for medicinal use: Apramycin Aztreonam Cefonicid Ceftiofur Cefuroxime

Separate statistics"'

Yes No No No No No No No No No No No No No No

No No No No No No No No NO No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' Identification codes (according to list in table 6-3)

LIL. LIL LIL. MRK. KAN, LIL. LIL BRS, KAN. BEE, BOC, KAN. BEE, BRS. BRS, KAN. BOC, KAN. WYT. BEE, BOC, KAN. BEE, BOC. BRS. WYT. BEE. BEE, BOC. BRS. BEE. BEE. BRS. WYT. PFZ. BRS. WYT. PFZ. ACY. ACY. ACY. ACY, PFZ. PFZ. No BRS, PEN. ACY, BRS. LIL PFZ. PFZ. BRS. SIC UPJ. LIL.

See footnotes at end of table.

6-3

Section 6

Table 6-2--Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Medicinal chemicals Antibiotics-Continued Other antibiotics-Continued For medicinal use-Continued Clindamycin Erythromycin Erythromycin estolate Gentamycin , Kanamycin Lincomycin (medicinal grade) , Moxalactam Neomycin (medicinal grade) Netilmicin Novobiocin, sodium Polymyxin B Sisomycin Spectinomycin (medicinal grade) Thiostrepton Vancomycin All other antibiotics, for medicinal use For nonmedicinal uses: Bacitracin (animal feed grade) Cydoheximide Hygromycin B Lasalocid, sodium Lincomycin (animal feed grade) Monesin Neomycin (animal feed grade) Spectinomycin (animal feed grade) Streptomycin Tylosin All other antibiotics, for nonmedicinal uses Antihistamines: Antinauseants: Dimenhydrinate Diphenidol Diphenidol hydrochloride Meclizine hydrochloride Metodopramide hydrochloride Other antihistamines Brompheniramine maleate Chlorpheniramine Chlorpheniramine maleate Cyproheptadine hydrochloride Dexbrorripheniramine maleate Dimethindene maleate Diphenhydramine citrate Diphenhydramine hydrochloride Diphenylpyraline hydrochloride Phenyltoloxamine citrate Terfenadine Trimeprazine Tripelennamine Tripelennamine hydrochloride Triprolidine hydrochloride Triprolidine oxalate See footnotes at end of table.

6-4

Separate statistical

No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' identification codes (according to list in table 6-3)

ABB, UPJ. ABB, UPJ. UPJ. SCH. BRS. UPJ. LIL UPJ. SCH. UPJ. PFZ, WYK. SCH. ABB, UPJ. BRS. ABB, ACY, LIL ABB, MRK. IMC. UPJ. LIL. HOF. UPJ. LIL PFZ, UPJ. UPJ. PFZ. LIL LLI. GAN. SK. SK. PFZ. W. LLI. SK, UPJ. SK MRK. (2). Y. WYK. PD, WYK. SK. GAN. GAN. SK. COY. COY. AMD, BUR. AMD.

Synthetic Organic Chemicals. 1991 Table 6-2—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Medicinal chemicals Anti-infective agents (except antibiotics): Anthelmintics: Diethylcarbamazine citrate Piperazine Piperazine dihydrochioride Piperazine hydrochloride Piperazine sulfate Thiabendazole All other anthelmintic agents Antiprotozoan agents: Arsenic and bismuth compounds Arsanilic acid Nitarsone Roxarsone Roxarsone, sodium Other antiprotozoan agents Amprolium Dinitolmide Ethopabate Hydroxychloroquine sulfate lodochlorhydroxyquin Metronidazole Sulfonamides Mafenide acetate Suifacetamide, sodium Sulfadiazine, silver Sulfamethizole Sulfamethoxazole Sulfapyridine Sulfasalazine Sulfisoxazole, acetyl Urinary antiseptics: Methenamine Methenamine mandelate Other anti-infective agents Antifungal agents: Benzoic acid Calcium undecylenate Fluconazole Flucytosine Sodium caprylate Zinc undecylenate All other antifungal agents Antileprotic and antitubercular agents: Aminosalicylic acid Sulfoxone, sodium Antiviral agents: Acyclovir Azidothymidine General antiseptics and antibacterial agents Bismuth formic iodide Ceftazidime Ceftazidime dihydrochloride Cetylpyridinium chloride Cinoxacin lodoform Magnesium salicylate Mitotane Ormetoprim Oxyquinoline benzoate (benoxiquine) Oxyquinoline citrate Oxyquinoline sulfate Pentamidine isethionate

Separate sta6stics1 Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' Identification codes (according to list in table 6-3)

SI( TX, UCC. FLM. FLM. FLM. MRK. MRK. No FLM. SAL. SAL SAL MRK. SAL MRK. SD. CGY. SRL SDW. SCH. BOT, LEM. ACY. HOF. ACY. SAL HOF. ARN. ARN, PD. KLM. WTL PFZ. HOF. LEM. PAS, WTL ARN. HXL ABB. R. RSA. LIL SK. HXL LIL. MAL ARN. (2). HOF. LEM. LEM. LEM. MRX.

See footnotes at end of table. 6-5

Section 6

Table 6-2—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Medicinal chemicals

Separate statistics"'

Anti-infective agents (except antibiotics)-Continued Other anti-infective agents-Continued General antiseptics and antibacterial agents-Continued Povidone - iodine No Resorcinol No Trimethoprim No Autonomic drugs: No Sympathomimetic agents No Albuterol sulfate No Dobutamine No Naphazoline hydrochloride No Phenylephrine bitartrate No Phenylephrine hydrochloride No Phenylpropanolamine bitartrate No Phenylpropanolamine hydrochloride No Propylhexedrine No Pseudoephedrine hydrochloride No Pseudoephedrine sulfate No Terbutaline sulfate No Tetrahydrozoline hydrochloride No Other autonomic drugs: No Parasympatholytic quatemary ammonium compounds (except tropane derivatives): No Glycopyrrolate No Parasympatholytic tertiary amines (except tropane derivatives): No Oxybutynin chloride No Parasympathomimetic agents: No Bethanechol chloride No Pyridostigmine bromide No Sympatholytic agents: limolol maleate No Central depressants and stimulants: Yes Analgesics, antipyretics, and nonhormonal antiinflammatory agents: Yes Acetaminophen No Aspirin No Butorphanol tartrate No Choline magnesium salicylate No Difiunisal No Fenoprofen No Fentanyl citrate No Flunixin meglumine No Hydromorphone hydrochloride No Ibuprofen No Indomethacin No Ketoprofen No Meclofenamate, sodium No Meclofenamic acid No Mefenamic acid No Meperidine hydrochloride No Mesalamine No Methadone hydrochloride No Morphine sulfate No Oxycodone hydrochloride No Oxycodone terephthalate No Pentazocine No Pentazocine hydrochloride No Piroxicam No Potassium salicylate No Propoxyphene hydrochloride No

See footnotes at end of table.

6-6

Manufacturers' identification codes (according to list in table 6-3)

GAF. ISP. BUR. SCH. LIL. CGY. GAN. GAN, SDW. ARS. ARS, ORT. SK. GAN, WYK. GAN, WYK. CGY. PFZ.

LLI. ABB. GAN. HOF. MRK.

MAL, SDW, SK. DOW, NOR. BRS. ARN, LEM. MRK. LIL, M EN. TNA. MRK. WYK. PD, WYK. PD. PD. PEN, SDW. SAL. MAL. MAL. MAL, PEN. PEN. SD. SD. PFZ. KLM. GAN.

Synthetic Organic Chemicals, 1991 Thble 6-2—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Medicinal chemicals Central depressants and stimulants-Continued Analgesics, antipyretics, and nonhormonal antiinflammatory agents-Continued Propoxyphene napsylate Salsalate Sodium salicylate Sufentanil citrate Sulindac Anticonvulsants, hypnotics, and sedatives: Anticonvulsants (except barbiturates): Ethosuximide Ethotoin Methsuximide Phensuximide Phenytoin Phenytoin, sodium Valproic acid Barbiturates: Amobarbital, sodium Butabarbital Butalbital Pentobarbital Phenobarbital Phenobarbital, sodium Poly(oxy-1,2-ethanediyI)-a-carboxyrnethyl, omega(tridecyloxy), potassium salt Secobarbital, sodium Thiamylal, sodium Thiopental, sodium All other barbiturates Hypnotics and sedatives (except barbiturates): Alprazolam Dichloralphenazone Ethchlorvynol Glutethimide Antidepressants: Amitriptyline hydrochloride Bupropion Doxepin hydrochloride Imipramine hydrochloride Maprotiline hydrochloride Nortriptyline hydrochloride Sertraline Antitussives Benzonatate Caramiphen edisylate Codeine Dextromethorphan hydrobromide Hydrocodone bitartrate Noscapine Thebaine Tranquilizers: Phenothiazine derivatives: Chlorpromazine Chlorpromazine hydrochloride Fluphenazine hydrochloride Prochlorperazine Prochlorperazine edisylate Prochlorperazine maleate See footnotes at end of table.

Separate statistics1

Manufacturers' identification codes (according to list in table 6-3)

No No No No No No No No No No No No No No No No No No No No No

ABB, GAN. (2). KLM. MRX. MRK.

No No - No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

GAN. GAN. PD. ABB. (2).

PD. ABB. PD. PD. PD. PD. ABB. GAN. GAN. GAN. GAN. GAN. GAN.

UPJ, (2). ARN. ABB. GAN. GAN, MRK. BUR. PFZ, SK. COY. ABB. LIL, WYK. PFZ. CGY, WYK. SK. MAL, PEN. AMD, HOF. MAL, PEN. MAL, PEN. MAL, PEN. SK. SK. BRS. SK. SK. SK.

Section 6 Table 6-2—Continued Medicinal chemicals for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Medicinal chemicals Central depressants and stimulants-Continued Tranquilizers-Continued

Other tranquilizers: Chlorprothixene Halazepam Hydroxyzine pamoate Molindone hydrochloride Other central depressants and stimulants: Amphetamines Amphetamine Amphetamine sulfate Dextroamphetamine Dextroamphetamine sulfate Methamphetahrine Methamphetamine hydrochloride Tranylcypromine All other amphetamines General anesthetics: Enflurane Isoflurane Ketamine hydrochloride Respiratory and cerebral stimulants: Caffeine (natural and synthetic): Caffeine, natural Caffeine, synthetic Other respiratory and cerebral stimulants: Doxapram hydrochloride Methylphenidate hydrochloride Pemoline Phentermine Skeletal muscle relaxants: Chlorphenesin carbamate Cydobenzaprine hydrochloride Methocarbamol Orphenadrine citrate Succinylcholine chloride Tubocurarine Dermatological agents: Ammonium phenoludfonate Salicylic acid Zinc phenolsulfonate Expectorants and mucolytic agents: rynediamine dihydriodide Guaifenesin Iodinated glycerol Gastrointestinal agents and therapeutic nutrients: Gastrointestinal agents: Choline chloride (all grades): Choline chloride (animal feed grade) Choline chloride (medicinal grade) Other gastrointestinal agents: Betaine hydrochlonde Calcium polycarbophil Choleretics and hydrocholeretics Choline Choline bicarbonate Choline bitartrate Choline citrate Choline dihydrogen citrate CdestOol hydrochloride Dihydroxyaluminum aminoacetate Diphenoxylate Docusate, potassium

See footnotes at end of table. 6-8

Separate statistics

No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No Yes No No No No No No No No No No No No No No No No No

Manufacturers' identification codes (according to list In table 6-3)

HOF. SCH. LEM. PD. ARN, SK. AMD. ARN, SK. ARN, SK. ARN. ARN. SK. ARN. OH. OH. PD. GNF. AMB, PFZ. LLI. COY. ABB. GAN, SDW. UPJ. MRK. LLI. WYK. ABB, BUR. ABB. SAL DOW, KLM. MAL. MY, DPW. LLI. (2).

CHO, HFT, NUT, TMH. CHO, HFT. CHO, HFT. LLI. UPJ. HFT, RSA. CHO, HFT. CHO, HFT. CHO, HFT CHO, HFT. UPJ. CHT. MAL ACY.

Synthetic Organic Chemicals, 1991 Table 6-2—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Medicinal chemicals Central depressants and stimulants-Continued Gastrointestinal agents and therapeutic nutrientsContinued Other gastrointestinal agents-Continued: Docusate, sodium Famotidine Gemfibrozil Methscopolamine bromide Nizatidine Sitosterols Sucralfate All other gastrointestinal agents Therapeutic nutrients Calcium gluceptate Zinc gluceptate Hormones and synthetic substitutes: Anabolic agents and androgens: Fluoxymesterone Methyltestosterone Stanozolol Testosterone Testosterone cypionate Testosterone propionate Zeranol Corticosteroids: Aclomethasone Betamethasone Betamethasone dipropionate Betamethasone sodium phosphate Betamethasone valerate Cortisone acetate Dexamethasone Dexamethasone sodium phosphate Diflorasone diacetate Fludrocortisone acetate Fluorometholone Halcinonide Hydrocortisone Hydrocortisone acetate Isoflupredone, acetate Medrysone Methylprednisolone Mometasone Prednisolone Prednisolone acetate Prednisone Triamcinolone Triamcinolone acetonide Triamcinolone diacetate Triamcinolone hexacetonide Estrogens and progestogens: Estrogens: Estradiol cypionate Estrogens, conjugated Estrogens, esterified All other estrogens Progestogens: Alprostadil Dinoprostone Hydroxyprogesterone Hydroxyprogesterone caproate Medroxyprogesterone acetate Megestrol acetate Melengestrol acetate

Separate statistics'

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

Manufacturers' identification codes (according to list in table 6-3)

ACY, MAL. MRK. PD. UPJ. LIL. UPJ. SK. MRK. PFN. PFN. UPJ. UPJ. SD. UPJ. UPJ. UPJ. IMC. SCH. SCH. SCH, SCH, SCH, MRK, UPJ. MRK, SCH, (2). MRK, (2). UPJ. UPJ. UPJ. BRS. UPJ. UPJ. UPJ. UPJ. ABB, SCH, UPJ. SCH. MRK, UPJ. UPJ. UPJ. BRS, ) BRS, BRS. BRS. UPJ. ORG. ORG. ORG. (2). UPJ. CWN. UPJ. (2). UPJ. (2).

See footnotes at end of table. 6-9

Section 6 Table 6-2--Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Medicinal chemicals Hormones and synthetic substitutes-Continued Progestogens-Continued Progesterone All other progestins Synthetic hypoglycemic agents: Acetohexamide Glipizide Tolazamide Tolbutamide Thyroid hormone and antithyroid agents: Levothyroxine, sodium Methimazole Thyroglobulin Thyroid Other hormones and synthetic substitutes: Calcitonin Corticotropin Danazol Glucagon Gonadorelin, acetate Humatrope Insulin Local anesthetics: Benzocaine Butacaine hydrochloride Butamben Butamben picrate Cocaine Dibucaine Lidocaine Lidocaine hydrochloride Pramoxine hydrochloride Prilocaine hydrochloride Tetracaine hydrochloride All other local anesthetics Renal-acting and edema-reducing agents: Benzothiadiazine derivatives: Chlorothiazide Cyclothiazide Hydrochlorothiazide Methyclothiazide Trichlormethiazide Other renal-acting and edema-reducing agents: Amiloride hydrochloride Canrenoate, potassium Dichlorphenamide Ethacrynic acid Metolazone Probenecid Spironolactone Triamterene Smooth muscle relaxants: Atracurium besylate Flavoxate hydrochloride Oxtriphylline Papavenne hydrochloride Theophylline Vitamins: Vitamin A: Beta carotene (provitamin A) Vitamin A alcohol Vitamin A palmitate (medicinal grade) All other vitamin A

See footnotes at end of table. 6-10

Separate statistic&

No No No No No No No No No No No No No No No No No No No No No No No No - No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No

Manufacturers' Identification codes (according to list In table 6-3)

UPJ. UPJ. LIL. PFZ. UPJ. UPJ. BOT. LIL. NEP. ARP. ARP. ARP, ORG. SD. LIL. ABB. LIL. LIL. WYK. HOF. ABB, WYK. HOF. MAL. CGY. LEM, WYK. LEM, WYK. ABB. WYK. WYK. EK, (2). M RK. _

COY, MRK. ABB. SCH. MRK. SRL. MRK. MRK. EK. MRK, SAL. SRL. SK. BUR. SK. PD. CHT. AMB. (2). HOF HOF. EK.

Synthetic Organic Chemicals, 1991 Table 6-2--Continued Medicinal chemicals for which U.S. production and/or sales were reported, Identified by manufacturer, 1991 Medicinal chemicals Vitamins-Continued Vitamin B-complex: Niacin and derivatives Niacin (medicinal grade) Niacinamide (medicinal grade) Pantothenic acid derivatives Dexpanthenol Panthenol Other B-complex vitamins: Biotin Cyanocobalamin (medicinal grade) Pyridoxine Riboflavin (animal feed grade) Thiamine hydrochloride Thiamine mononitrate M other vitamin B-complex Vitamin C: Ascorbic acid Calcium ascorbate Sodium ascorbate Vitamin D: Cholecalciferol (vitamin D3) Ergocalciferol (vitamin D2) Vitamin E: . . DI-alpha tocopheryl acetate (all grades): dl -a Tocopheryl acetate (animal feed grade) dl -a Tocopheryl acetate (medicinal grade) Other vitamin e: d-a Tocopherol d-a Tocopheryl acetate d -a Tocopheryl acid succinate Miscellaneous medicinal chemicals: Antineoplastic agents: Azathioprine Carboplatin Carmustine Cisplatin ' Cytarabine . Gallium nitrate Leuprolide acetate Ormapiatin Streptozocin Cardiovascular agents: Antihypertensive agents: Gaptopril , Guanethidine sulfate Hydralazine hydrochloride Lisinopril Methyldopa Minoxidil Nadolol Phenoxybenzamine Prazosin Sodium nitroprusside Terazosin Enalapril maieate Vasodilators: Amlodipine Nifedipine Lovastatin Other cardiovascular agents: Acecainide Disopyramide phosphate Procainamide hydrochloride

Separate slatisdcsi No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No No . No No.. No No No No No No No No No No No No No No No No No No No No

Manufacturers' Identification codes (according to list in table 6-3)

RIL. HOF, NEP, RIL. HOF. HOF. AMD. MRK. HOF. ZGN. HOF. TKD. HOF. TKD. HOF. (2). VTM. VTM. BAS, BAS,

0. (9.

EKT, SCP. EKT, SCP. EKT, SCP. BUR. MRX. MRX. MRX. PFN, UPJ. MRX. ABB. MRX. PFN. BRS. CGY. COY. MRK. CGY, MRK. UPJ. BRS. SK. ABB. ABB. ABB. MRK. PFZ. PFZ. MRK. ARN. SRL PD, WYK.

See footnotes at end of table. 6-11

Section 6 Table 6-2—Continued Medicinal chemicals for which U.S. production andfor sales were reported, Identified by manufacturer, 1991 Separate statistical

Medicinal chemicals Miscellaneous medicinal chemicals; Other cardiovascular agents: Propranolol hydrochloride Simvastatin Sodium tetradecyl sulfate All other cardiovascular agents Diagnostic agents: Roentgenographic contrast media: Diatrizoate, sodium , „ lohexol lothalamate, rneglumine Other diagnostic agents: Albumin Aminohippuric acid Edrophonium chloride Metyrapone Xylose (intestinal malabsorption test) All other diagnostic agents, other than roentgenographic contrast media Hematological agents: Anticoagulants: Ammonium heparin Benzalkonium heparin Lithium heparin Potassium warfarin Sodium heparin Other hematological agents: Cellulose, oxidized Dextran Unclassified medicinal chemicals: Allopurinol Aminobenzoic acid, potassium salt , Carbidopa Copper glycinate Deferoxamine mesylate Deprenyl hydrochloride Disulfuram Etidronate, disodium , Levodopa Melatonin Nicotine polacrilex ? Selegiline hydrochloride Tacrine Trioxsalen All other medicinal chemicals

,•

Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No , No No No No No No No No No No No No NO No No

Manufactureri' Identification codes (according to list in table 6-3)

WYK. MRK. MRX. MRK. SDW. SD. MAL SPR. AZ. CGY. PFN.

PFZ. SPR. RIK. SPR. DR. EKT. PHR. BUR. WYK. MRK. ARN. 2 N. A05. NOR. SRL REG.

WYK.

WK.

PD.

R5G.

Aag, BIB.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' ChemiCals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

6-12

Synthetic Organic Chemicals, 1991 Table 6-3 Medicinal chemicals: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ABB ACY AJY AMB AMD ARN ARP ARS BAS BEE BIB BOC BOT BRS BUR CGY CHO CHT CWN DOW DPW EK EKT FLM GAF GAN GNF HFT HOF HXL

Abbott Laboratories American Cyanamid Co. Ajay Chemicals, Inc. American Bio-Synthetics Corp . Cyclo Products, Inc. Arenoi Chemical Corp. Armour Pharmaceutical Co. Arsynco, Inc., Sub. Div. of Aceto Corp. BASF Corp. SmithKline Beecham Pharmaceuticals Beckman Instruments, Inc. Biocraft Laboratories, Inc. Boots Pharmaceuticals, Inc. Bristol-Myers Squibb Co. Burroughs Wellcome Co. Ciba-Geigy Corp. Ducon Chattem, Inc. Upjohn Co., Fine Chemicals Dow Chemical Co. Deepwater, Inc. Eastman Kodak Co.: Tennessee Eastman Co. Div. Fleming Laboratories, Inc. ISP Chemicals, Inc. Ganes Chemicals, Inc. Maxwell House Coffee Co. Syntex Agribusiness, Inc. Hoffmann-LaRoche, Inc. Hexcel Corp., Hexcel Chemical Products IMC Pitman-Moore, Inc. Inspec Chemical Corp. Kanasco, LTD Kalama Chemical, Inc. Napp Chemicals, Inc. Eli Lilly & Co. Lee Laboratories, Inc. Mallinckrodt, Inc. Merck & Co., Inc. Johnson Matthey, Materials Technology Div.

NEP NOR NUT OH ORG ORT

Nepera Inc. Norwich Eaton Pharmaceutical, Inc. Bioproducts, Inc. Anaquest Organics/LaGrange, Inc. Roehr Chemicals, Inc., Div. of Aceto Corp. ELF Atochem North America, Inc. Parke-Davis Div. of Warner-Lambert Co. Penick Corp. Pfanstiehl Laboratories, Inc. Pfizer, Inc. & Pfizer Pharmaceuticals, Inc. Pharmachem Corp. Regis Chemical Co. Riker Laboratories, Inc., Sub. of 3M Co. Reilly Industries, Inc. R.S.A. Corp. Salsbury Chemicals, Inc. Schering Corp. Henkel Corp. Sterling Drug, Inc.: Sterling Organics Div. SmithKline Beecham Chemicals Scientific Protein Laboratories G.D. Searle & Co. Takeda Chemical Product USA, Inc. Harcros Chemicals, Inc. Ethyl Corp. Texaco Chemical Co. Union Carbide Corp., Industrial Chemical Div. Upjohn Co. Vitamins, Inc. ELF Atochem North America, Inc., Organic Peroxides Div. Wyckoff Chemical Co., Inc. Wyeth Laboratories, Inc., Wyeth Laboratories Div. of American Home Products Corp.

IMC ISP KAN KLM LEM LIL LLI MAL MRK MRX

PAS PD PEN PFN PFZ PHR REG RIK RIL RSA SAL SCH SCP SD SDW SK SPR SRL TKD TMH TNA TX UCC UPJ VTM WTL WYK WYT

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Synthetic Organic Chemicals, 1991

Section 7 Flavor and Perfume Materials

amounted to 27.9 million kilograms, valued at $826.6 million. Individual publishable chemicals in the cyclic group produced in the greatest volume in 1991 were anethole (1.6 million kilograms), and a-terpineol (1.1 million kilograms).

Flavor and perfume materials are organic chemicals used to impart flavors and aromas to foods, beverages, cosmetics, and soaps. These aroma chemicals are also utilized to neutralize or mask unpleasant odors in industrial processes and products, as well as in consumer products. Total domestic production of flavor and perfume materials in 1991 amounted to 68.8 million kilograms (see figure 7-1). Sales of these materials in 1991 amounted to 38.7 million kilograms, valued at $925.5 million, compared with 36.5 million kilograms, valued at $991.6 million. in 1990. U.S. production of flavor and perfume materials in 1991 increased by 14.9 percent from the level in 1990 while the value of sales decreased by 6.7 percent. Production of cyclic flavor and perfume materials in 1991 amounted to 42 3 million kilograms; sales

U.S. output of acyclic flavor and perfume materials in 1991 amounted to 26.6 million kilograms; sales of these materials amounted to 10.8 million kilograms, valued at $98.9 million. Individual publishable acyclic flavor and perfume chemicals produced in the greatest volume in 1991 were citronellol (1.5 million kilograms). tetrahydrogeraniol (222,000 kilograms) and geranyl acetate (106,000 kilograms). Table 7-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 7-3.

Eric Land 202-205-3349

Figure 7-1 Flavor and perfume materials: U.S. production, 1986-91

Millions of kilograms 100 90 80 70 60 50 40 30 20 10 0

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 7-1

Section 7 Table 7-1 Flavor and perfume materials: U.S. production and sales, 1991 Sales Flavor and perfume materials

Grand total

Production

Quantity

Value

Average Unit value

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

68,843

38,694

925,478

$23.92

42,291

27,881

826,627

29.65

30,116

21,736

751,809

34.59

9 287 17 1,641 28,162

9 311 (2) 1,105 20,311

89 913 (2) 7,673 743,134

9.88 2.94 (2) 6.94 36.59

12,175

6,145

74,818

12.18

92 749 1,088

49 394 714

587 8,281 1,420

12.04 21.01 1.99

10,246

4,988

64,530

12.94

26,552

10,813

98,851

9.14

51 11

38 4

54 121

14.18 27.76

14

11

128

11.63

222 1,542 106 24,606

45

416

9.14

90 10,625

911 97,221

10.11 9.15

Cyclic Total Benzenoid and Naphthalenoid Total 4-Allyl-2-methoxyphenol (Eugenol) Benzyl benzoate Phenethyl isobutyrate p-Propenylanisole (Anethde) All other benzenoid and naphthalenoid materials Terpenoid, Heterocyclic, and Alicydic Total Cedryl acetate y-Methylionone a-Terpineol All other terpenoid, heterocyclic, and alicydic materials Acyclic Total Citronellyl acetate Citronellyl formate 3,7-Dimethyl-cis-2,6-octadienoi, acetate (Neryl acetate) 3,7-Dimethyloctano1-1 (Tetrahydrogeraniol) 3,7-Dimethy1-6-octen-1-ol (Citronellol) Geranyl acetate All other acyclic materials 1 Calculated from unrounded figures. 2 Reported data are accepted in confidence

and may not be published, or no data were reported.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

7-2

Synthetic Organic Chemicals, 1991 Table 7-2 Flavor and perfume materials for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Flavor and perfume materials

Separate statistics1

Manufacturers' Identification codes (according to list in table 7-3)

Cyclic: Benzenoid and naphthalenold: 2'-Acetonaphthone (0-Methyl naphthyl ketone) 1-Acetoxy-2-sec-butyl-1-ethenylcyclohexane p-Allylanisole 4-AllyI-1,2-dimethoxybenzene (4-Allylveratrole) 4-Allyl-2-methoxyphenol (Eugenol) a-Amyl cinnamic aldehyde Amyl cinnamyl alcohol Anisyl acetate Benzaldehyde glyceryl acetal Benzophenone Benzyl acetate Benzyl benzoate Benzyl butyrate Benzyl isobutyrate Benzyl isopentyl ether Benzyl isovalerate 1-(Benzyloxy)-2-methoxy-4-propenylbenzene (Benzyl isoeugenyl ether) Benzyl phenylacetate Benzyl propionate Benzyl salicylate p-tert-Butyl-a-methylhydrocinnamaiehyde N-(3-(p-tert-butylpheny1)-2-methylpropylidene)anthrantlic acid, methyl ester Carvacrol Cineole [eucalyptol] Cinnamaldehyde Cinnamyl acetate Cinnamyl butyrate Cinnamyl nitrite Cinnamyl propionate Cuminyl acetate trans-Decahydro-0-naphthol Dihydrocoumarin 1,2-Dimethoxy-4-propenylbenzene (4-Propenylveratrole) 0,4, Dimethy1-3-cyclohexene-1 -propanal 3,7-Dimethyl-1, 6-octadien-3-yl formate 3,7-Dimethyl-2,6-octadienyl phenylacetate (Geranyl phenylacetate) a,a-Dimethylphenethyl acetate 2-Ethoxynaphthalene Ethyl anthranilate Ethyl cinnamate Ethyl-a,f3-epoxy-p-methylhydrocinnamate 2-Ethylhexyl-p-methoxy cinnamate 2-Ethyl hexyl salicylate Ethyl phenylacetate cis-3-Hexenyl salicylate Hydratropaldehyde,dimethyl acetal Hydrocinnamic acid Hydrocoumarin a-Hexylcinnamaldehyde

No No No No Yes No No No No No No Yes No No No No

GIV. GIV. NCI, SCM. Cl. BDS, CI, ELN, GIV. KLM. IFF. ELN, GIV. GIV. CWN, PD. HAR. HAR, KLM, MRF. ELN. ELN. GIV. ELN.

No No No No No

GIV. ELN, GIV. ELN. HAR. GIV.

No No No No No No No No No No No

GIV. GIV. SCM. ELN, KLM. ELN. ELN. IFF. ELN. IFF. IFF. ARS.

No No No

Cl. Cl. GIV.

No No No No No No No No No No No No No No

GIV. IFF. GIV. AMB. ELN. ELN. IV. HAR. ELN. BDS, 1FF. IFF. ELN. ELN, GIV. CI, KLM.

See footnotes at end of table. 7-3

Section 7

Table 7-2—Continued Flavor and perfume materials for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Flavor and perfume materials

Separate statistics

Manufacturers' identification codes (according to list in table 7-3)

Cyclic—Continued: Benzenoid and naphthalenoid: Hydroxycitronellal methyl anthranilate 4-Hydroxy-3-methoxybenzaldehyde [Vanillin] 4(4-Hydroxy-3-methoxyphenyl)-2-butanone (Vanillyacetone) p-Hydroxy phenylbutanone Isoamyl phenylacetate Isobutylquinoline Isohexenyl tetrahydrobenzaldehyde (Myrac aldehyde) Isopentyl benzoate I-Limonene p-Mentha-1,8-diene (Limonene) 4,7-Methano-1 H-indene-2-methanol octahydro acetate o-Methoxy benzaldehyde p-Methoxybenzyl alcohol (Anisyl alcohol) 3-(4-Methoxypheny0-2-methyl propanal 1-p-Methoxyphenyl penten-1-one-3 (a-Methylanisalacetone) 3-(2-Methoxyphenyl)-2-propenal 2-Methoxy-4-propenylphenol (Isoeugenol) 2-Methoxy-4-propenylphenol,acetate 2-Methoxy-4-propylphenol 4'-Methylacetophenone p-Methylanisole Methyl anthranilate a-Methylbenzene propanal Methyl benzoate a-Methylbenzyl acetate (Styralyl acetate) a-Methylcinnamaldehyde 1,2-Methylenedioxy-4-propylene benzene (isoSafrole) Methyl N-methylanthranilate a-methyl-3,4-methylene dioxyhydrocinnamaldehyde Methyl phenylacetate 3-Methyl-5-phenyl-1-pentanol Methyl salicylate Octahydro-5-methoxy-4,7-methano-1 H-indene, 2-carboxaldehyde 1,1,3,3,5-Pentamethy1-4,6-dinitroindan (Moskene) a-Pentylcinnamaldehyde Phenethyl acetate Phenethyl alcohol Phenethyl formate Phenethyl isobutyrate Phenethyl isovalerate 2-Phenethyl phenylacetate Phenethyl propionate 2-Phenoxyethyl isobutyrate Phenylacetaldehyde Phenylacetaldehyde,dimethyl acetal See footnotes at end of table.

7-4

No No

GIV, IFF. RAY.

No No No No

GIV. GIV. ELN. ELN, IFF.

No No No No

IFF. GIV. SCM. IFF.

No No No No

Cl. Cl. ELN. Cl.

No No No No No No No No No No No No

GIV. Cl. Cl. ELN. Cl. CWN. GIV. PSG. Cl. HCF, MRF. IFF. IFF.

No No

AMB. AMB.

No No No No

GIV. GIV. IFF. KLM.

No

Cl.

No No No No No Yes No No No No No No

GIV. Cl. BDS, IFF. ATR, 1FF. ELN, IFF. ELN, GIV, IFF. ELN. BDS, ELN, IFF. ELN. IFF. GIV, (2). CI, ELN, GIV.

Synthetic Organic Chemicals, 1991 Table 7-2—Continued Flavor and perfume materials for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Flavor and perfume materials

Separate statistics1

Manufacturers' identification codes (according to list in table 7-3)

Cyclic—Continued: Benzenoid and naphthalenoid: Phenylethyl 2-methyl butyrate 3-Phenyipropyl acetate Piperonal (Heliotropin) p-Propenylanisole (Anethole) p-Propylanisol (Dihydroanethole) Phenylethyl benzoate p-Tolyl acetate p-Tolyl isobutyrate p-Tolyl octanoate p-Tolylphenylacetate a-(Trichloromethyl)benzyl acetate (Rosetone) Trimethyl benzyl dioxane Trimethylcyclohexyl salicylate Sweeteners, synthetic: Cyclohexanesulfamic acid (Cydamic acid) Cyclohexanesulfamic acid, sodium salt (Sodium cyclamate) Saccharin (1,2-Benzisothiazolin-3-one,-1,1-dioxide) Saccharin,sodium salt Tetramethyl, octahydro acetophenone Tetramethyl octahydro acetyl naphthalene All other synthetic sweetner material All other benzenoid or naphthalenoid chemicals Terpenoid, heterocyclic, and alicydic: Acetyl cedrene (Vertoflex) Allo-ocimene Allyl cyclohexyl propionate Amyl cyclohexyl acetate Amyris acetate Beta methyl ionone coevr 2-tert-Butyl cydohexanol 2-sec-Butylcyclohexanone o-tert-Butylcydohexyl acetate Cadinene a-Campholenic aldehyde Canrenoate, potassium I-Catvone p-Caryophyllene a-Cedrene epoxide (An:Irene) Cedrenol Cedrol Cedryl acetate Cedryl formate Cydohexyl ethyl acetate p-Cymene Dihydronordicyclopentacfienyl acetate (Cydacet) Dihydronordicyclopentadienyl propionate (Cyclaprop) (Verdyl propionate extra) Dihydro terpineol Dimethyl cyclohexane methanol 2, 6-Dimethylheptan-2-ol

No No No Yes No No No No No No No No No

SCM. ELN, GIV. AMB. ARZ, HPC, NCI, SCM. GIV. IFF. ELN. IFF. IFF. GIV. ARS. IFF. ARS.

No

ABB.

No

ABB.

No No No No No No

PSG. PSG. IFF. IFF. NSW. CI, IFF, PFZ.

No No No No No No No No No No No No No No No No No No Yes No No

BDS. SCM, (2). GIV. IFF. GIV. IFF. IFF. GIV. CI, IFF. GIV. SCM. IFF. SCM. BDS, GIV. BDS. BDS, ELN, IFF. ELN, IFF. BDS, ELN, IFF. IFF. IFF. SCM.

No

Cl.

No No No No

Cl. SCM. IFF. GIV.

See footnotes at end of table.

7-5

Section 7

Table 7-2—Continued Flavor and perfume materials for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Flavor and perfume materials

Separate statistics1

Manufacturers' identification codes (according to list in table 7-3)

Cyclic—Continued: Benzenoid and naphthalenoid: Dimethy1-3-oxo-2-pentylcyclopentane propanedioate Ethyl furoate Gaiaxolide (1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8hexamethyl-cyclopenta-y-2-benzopyran) Guaiacwood acetate 2-Heptylcyciopentanone Hexadecanolide 3-Hydroxy-2-ethyl-4-pyrone (Ethylmaltol) 4-(4-Hydroxy-4-methyl penty1)-3-cyclohexene-10carboxaldehyde (Lyra!) 3-Hydroxy-2-methyl-4-pyrone (Maltol) 4-Hydroxynonanic acid, y-lactone (y-Nonaiactone) .. 2-(1-HydroxypentyI)-cyclopentanone 4-Hydroxyundecanoic acid,y-lactone (y-Undecalactone) lonone(a- and 0-) a-lonone Isobomyl acetate Isobomyl methyl ether Isobomyl propionate Isolongifolene epoxide Isomenthone 2-Isopropylcyclohexanol 6-isopropyldecalone Isopulegyl acetate p-Mentha-1,3-diene (a-Terpinene) p-Mentha-1,4-diene (y-Terpinene) p-Menth-8-en-3-ol (Isopulegol) p-Menth-1-en-3-one (Piperitone) p-Menth-4-(8)-en-3-one (Pulegone) dl-Menthol, synthetic I-Menthol, synthetic Menthyl acetate Methylionone(a- and f3-) y-Methylionone 6-Methyl-a-ionone Methyl-3-oxo-2-pentane acetate Nopyl acetate 3-0xo-2-pentylcyclopropane acetic acid 2-Pentyl-cydopenten-1-one a-Pinene oxide Plinol Rose oxide Terpinene-ol a-Terpineol a-Terpinyi acetate a-Terpinyl propionate 3,3,5-Trimethyl cyclohexanol (m-Homomenthol) Trimethyl cyclohexenyl butenone 1-(2,6,6-Trimethyl-2-cyc.lohexen-1-y1)-1, 6-heptadien-3-one (Allyl-a-ionone) Trimethyl norbornane methanol See footnotes at end of table. 7-6

No No

(2). IFF, SCM.

No No No No No

IFF. ELN. IFF. IFF. PFZ.

No No No No

IFF. PFZ. ELN. (2).

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No

ELN. ELN, GIV, NCI, SCM. GIV, IFF, SCM. SCM. SCM. ELN. GIV. GIV. GIV. GIV. GIV. SCM. SCM. GIV. GIV. GIV. HAR, NCI, SCM. HAR. SCM. BDS, GIV, IFF, NCI. GIV, IFF, NCI. BDS, GIV. Cl. NCI. (2). (2). SCM. SCM. GIV. SCM. HPC, NCI, SCM. NCI, SCM. ELN. ARS. IFF.

No No

IFF. IFF.

Synthetic Organic Chemicals, 1991 Table 7-2--Continued Flavor and perfume materials for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Flavor and perfume materials

Separate statistics1

Manufacturers' identification codes (according to list in table 7-3)

Cyclic—Continued: Benzenoid and naphthalenoid: 5-(2,2,3-Trimethyl(yclopent-3-en-1-yI)-3methylpentan-2-ol Vetivenol Vetivenyl acetate All other terpenoid,hetercyclic, or alicyclic flavor and perfume chemicals Acyclic: Allyl disulfide Allyl heptanoate Allyl hexanoate Ammonium isovalerate Butanoic acid, 1-cyclohexylethyl ester Butyl butyrl lactate Citral dimethyl acetal Citronellyl acetate Citronellyl formate Citronellyl isobutyrate Citronellyl nitrite Citronellyl propionate Decanal (Capraldehyde) Decyl acetate Diethyl sebacate Diethyl succinate Dihydrocarvone Dihydrolinalod Dihydro myrcenol Dihydro pentamethyl indanone Dihydroterpinyl acetate 1,1-Dimethoxy octane Dimethyl hexanediol 2,5-Dimethyl-3-hexyne-2,5-diol 3,7-Dimethyl-cis-2,6-octadienal (Citral B) (Neral 3,7-Dimethyl-trans-2,6-octadienal (Citral A, geranial) 3,7-Dimethyl-2,6-octadienal (Citral a & b) 3,7-Dimethyl-2,6-octadienenitriie 3,7-Dimethyl-cis-2,6-octadien-1-ol (Nerol 3,7-Dimethyl-trans-2,6-octadien-1-ol (Geranid) 3,7-Dimethyl-1,6-octadien-3-ol (Unalool) (Linalyl alcohol) 3,7-Dimethyl-cis-2,6-octadienol, acetate (Neryl acetate) 3,7-Dimethyl-1,6-octadien-3-ol,acetate (Linalyl acetate) 3,7-Dimethyl-1,6-octadien-3-y1 isobutyrate (Linalyl isobutyrate) 3,7-Dimethyl-1,6-octadien-3-y1 propionate (Unalyl propionate) 3,7-Dimethyloctanol-1 (Tetrahydrogeraniol) 3,7-Dimethyl-3-octanol Dimethyloctanyl acetate 3,7-Dimethyl-6-octen-1-al (Citronellal)

No No No

GIV. GIV. BDS, ELN, GIV, IFF.

No

CI, GIV, IFF, SCM.

No No No No No No No Yes Yes No No No No No No No No No No No No No No No No

IFF. ELN. ELN. RSA. (2). ELN. IFF. BDS, ELN, GIV, IFF, SCM. BDS, ELN, GIV, IFF. ELN, GIV, IFF. SCM. IFF. Cl. GIV. ELN. MRF. SCM. SCM. SCM. IFF. IFF, NCI. IFF. (2). (2). NCI.

No No No No No

BDS, NCI. SCM. Cl. GIV, NCI, SCM. ELN, GIV, NCI, SCM.

No

ELN, IFF, SCM.

Yes

ELN, GIV, IFF, SCM.

No

GIV, SCM.

No

GIV.

No Yes No No No

GIV. GIV, 1FF, SCM, (2). NCI, SCM. GIV. GIV, SCM.

See footnotes at end of table. 7-7

Section 7

Table 7-2—Continued Flavor and perfume materials for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Flavor and perfume materials Acyclic—Continued: 3,7-Dimethy1-6-octen-1-ol (Citronellol) 3,7-Dimethyl-7-octenol 70%, 6-octenol isomer 30% Ethyl butyrate Ethyl heptanoate Ethyl hexanoate Ethyl isovalerate Ethyl laurate Ethyl-2-methyl butyrate Ethyl myristate Ethyl propionate Ethyl trimethyl cyclopentenyl buterol Ethyl valerate Geranyl acetate Geranyl butyrate Geranyl formate Geranyl isobutyrate Geranyl nitrite (Citralva) Geranyl propionate N-Hexanal 2-Hexenal cis-3-Hexen-1-y1 acetate cis-3-Hexenyl butyrate cis-3-Hexenyl methyl carbonate cis-3-Hexenyl tiglate Hexyl 2-methylbutyrate Hydroxycitronellol 7-Hydroxy-3,7-dimethyl-1-octanal (Hydroxycitronellal) 7-Hydroxy-3,7-dimethyl octane!, dimethyl acetal (Hydroxycitronellal, dimethyl acetal Isobutyl acetate Isopentyl acetate (Isoamyl acetate) Isopentyl butyrate Isopentyl formate Isopentyl isovalerate 3-Methyl-2-butenyl acetate 2-Methylbutyl isovalerate Methyl butynol 2-Methylene undecanal Methyl hexyl ether Methyl isobutyrate Methyl-2-methyl butyrate 3-Methyl-2-[and 3]nonene nitrite Methyl-2-nonenoate Methyl pentynol 2-Methylundecanal Myrcenyl acetate Myristaldehyde Nonanal 1,3-Nonanediol acetate Ocimene Ocimenyl acetate Octane! N-Octyl acetate See footnotes at end of table.

7-8

Separate statistics

Manufacturers' identification codes (according to list in table 7-3)

No

ELN, GIV, IFF, NCI, SCM.

No No No No No No No No No No No No Yes No No No No No No No No No No No No

GIV. ELN, HPC, NW. ELN. ELN, NW. ELN. ELN. SCM. ELN. NW. IFF. ELN. BDS, CI, ELN, GIV, IFF, NCI, NW, SCM. ELN. BDS, ELN, GIV. IFF. IFF, SCM. ELN. Cl. GIV. BDS. SCM. IFF. BDS. SCM. SCM.

No

GIV, IFF, SCM.

No No No No No No No No No No No No No No No No No No No No No No No No No

GIV. NW. ELN, NW. ELN, GIV, NW. ELN. ELN. IFF. SCM. (2). (2). SCM. HPC. SCM. GIV. HPC. (2). CI, GIV. IFF. GIV. Cl. ELN, GIV. IFF. IFF. Cl. SCM.

Synthetic Organic Chemicals, 1991

Flavor and perfume materials

Separate statisticsi

Manufacturers' identification codes (according to list In table 7-3)

Acyclic—Continued: Octyl isovalerate Pseudo linalyl acetate (Neobergamate) Rhodinol Tepyl acetate Tetrahydrolinalyl acetate Tetrahydromyrcenol 2,4,6,8-Tetramethylnonan-1-y1 acetate Trimethyl-cydododeca-trienyl ethanone 3,5,5-Trimethyl hexane! Undecanal All other acyclic flavor and perfume materials

FF FF FFFF F FF

Table 7-2—Continued Flavor and perfume materials for which U.S. production and/or saes were reported, identified by manufacturer, 1991

GIV. IFF. GIV, IFF. ELN. SCM. SCM. Cl. IFF. 1FF. CI, GIV. IFF, SCM.

Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. 1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

7-9

Section 7

Table 7-3 Flavor and perfume materials: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ABB AMB ARS ARZ ATR

Abbott Laboratories American Bio-Synthetics Corp. Arsynco, Inc., Sub. Div., of Aceto Corp. Arizona Chemical Co Atlantic Richfield Co., ARCO Chemical Co. Fragrance Resources, Inc. Firmenich, Inc. Upjohn Co., Fine Chemicals Elan Chemical Co Givaudan Corp. Haarmann & Reimer Corp. Cape Industries Hercules, Inc.

IFF KLM MRF NCI NSW NW PD

International Flavors & Fragrances, Inc. Kalama Chemical, Inc. Morflex Inc. Union Camp Corp., BBA Div. Nutrasweet Co. Northwestern Flavors, Inc. Parke-Davis, Div. of Wamer-Lambert Co. Pfizer, Inc. PMC Inc., Specialities Group, Inc. ITT Rayonier Uguin Products, Inc. R.S.A. Corp. SCM Corp., Glidco Organics

BDS CI CWN ELN GIV HAR HCF HPC

PFZ PSG RAY RSA SCM

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

7-10

Synthetic Organic Chemicals, 1991

Section 8 Plastics and Resin Materials

compared with 25,729 million kilograms, valued at $30,529 million, in 1990. Thermosetting materials are those which harden in composition in the final treatment so that in their final state they are substantially infusible and insoluble; that is, they cannot again be softened by heat or solvents. U.S. production of thermosetting materials totaled 4,542 million kilograms in 1991 compared with 4,309 million kilograms in 1990. Production of the most important products in 1991 included phenolic (1,201 million kilograms); amino (urea and melamine) resins (1,262 million kilograms); polyester resins, unsaturated (513 million kilograms); and alkyd resins (356 million kilograms). Thermoplastic materials are those which in their final state can be repeatedly softened by heat and hardened by a decrease in temperature. U.S. production of thermoplastic materials totaled 23,711 million kilograms in 1991 (or 84 percent of the total plastics and resin materials output for 1991), compared with 25,743 million kilograms. in 1990. Production of the most important products in 1991 included polyethylene (9,429 million kilograms), polypropylene (2,664 million kilograms), vinyl resins (4,231 million kilograms), and styrene type materials (3,310 million kilograms). In 1991, production of saturated polyester resins reached 1.689 million kilograms (polyethylene terephthalate alone reached 1,442 million kilograms). Production of engineering plastics, in the aggregate, amounted to 488 million kilograms in 1991. Table 8-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 8-3. Denby L. Misurelli

Plastics and resin materials are high molecular weight polymers which, at some stage in their manufacture, exist in such physical condition that they can be shaped or otherwise processed by the application of heat and pressure. The terms "plastics," "resin," and "polymers, ,, can be (and often are) used interchangeably by the trade. Depending on the chemical composition, manufacturing process, or intended use, the commercial products may contain plasticizers, fillers, extenders, stabilizers, coloring agents, or other additives. There are about 40 to 50 basic plastics and resins which are available commercially. These basic materials are available in literally thousands of individual compounds each with its distinct properties depending on the molecular weight of the resin, chemical structure; and the types and amounts of the additives present. Plastics materials may be molded, cast, or extruded into semifinished or finished solid forms. Resin materials may be in the form of solutions, pastes. or emulsions for applications such as protective coatings, adhesives, or paper and textile treatment. Statistics on U.S. production and sales of synthetic plastics and resin materials for 1991 are given in table 8-1. U.S. production of plastics and resin materials in 1991 totaled 28,253 million kilograms, or 6 percent less than the 30,053 million kilograms produced in 1990. From 1987-91, the production of plastics and resin materials increased irregularly from 26,980 million kilograms in 1987 to 28,253 million kilograms in 1991, or at an average, animal rate of growth of 1 percent (see figure 8-1). Sales in 1991 totaled 24,787 million kilograms, valued at $28;141 million,

202-205-3362

Figure 8-1 Plastics and resin materials: U.S. production, 1987-91 Billions of kilograms

30

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 8-1

Section 8 Table 8-1 Plastics and resin materials: U.S. Production and sales, 1991

Production Quantity

Value

Average Unit valuer

1,000 kilograms dry basis2

1,000 kilograms dry basis2

1,000 dollars

Per kilogram

28,252,551

24,786,936

28,140,829

$1.14

4,541,889

3,142,434

3,928,123

1.25

355,636

279,546

334,921

1.20

5,605 313,918 7,098 6,448 12,374 10,193

2,699 250,962 4,114 1,737 11,747 8,287

6,327 274,303 6,997 4,828 20,529 21,937

2.34 1.09 1.70 2.78 1.75 2.65

Sales Plastics and resin materials

Grand total Thermosetting resins Total Alkyd resins, total Alkyd-acrylate copolymer resins Phthalic anhydride type Polybasic aad type Styrenated-alkyds or copolymer alkyds Vinyl toluene alkyds All other alkyd resins Dicyandiamide resins (an amino resin) Epoxy resins, total3 4 Unmodified Advanced

1,281

1,267

2,564

2.02

254,467 (121,031)

180,443 (69,507)

528,610 (203,326)

2.93 (2.97)

Melamine formaldehyde resins (an amino resin) Phenolic and other tar acid resins Polyester resins, unsaturated 5 Polyether and polyester polyols for urethanes 6

115,523 1,200,624 512,608 789,059

95,238 552,008 453,562 690,152

223,990 593,052 643,865 848,265

2.35 1.07 1.42 1.23

Polyurethane elastomers and plastics products, total

95,127

80,577

323,700

4.02

66,667 28,460

53,079 27,498

240,464 83,236

4.53 3.03

1,146,510 71,054

756,183 53,458

268,180 160,976

.35 3.01

23,710,662 21,644,502

24,212,706

1.12

Elastomers7 Plastics Urea-formaldehyde resins (an amino resin) 8 All other thermosetting revile Thermoplastic resins Total Acrylic resins, total 18 Homopolymer resins, except PMMA, of acrylic or methacrylic acid esters Polymethyl methacrylate (PMMA) resins Thermosetting acrylic resins All other acrylic resins Engineering plastics, totalli Polyimides and amide-imide polymers All other engineering plastics Fluorocarbon resins Petroleum hydrocarbon resins

,

Polyamide resins, total 10 13 Nylon Non-nylon type Polyester resins, saturated, total 18 14 Polyethylene terephthalate (PET) All other saturated polyesters, induding polybutylene terephthalate, (PBT) resins See footnotes at end of table. 8-2

,

743,366

622,002

1,553,033

2.50

23,251 280,833 40,821 398,461

19,268 177,086 27,420 398,228

55,795 413,862 84,143 999,233

2.90 2.34 3.07 2.51

488,495

350,749

1,295,014

3.69

8,778 479,717

5,466 345,283

124,318 1,170,696

22.74 3.39

23,180 174,224

163,'121 1

(12) 183,464

(12) 1.12

316,144

323,765

974,026

3.01

272,414 43,730

280,646 43,119

902,080 71,946

3.21 1.67

1,688,506

1,161,988

2,048,364

1.76

1,441,972

971,425

1,496,722

1.54

246,534

190,563

551,642

2.90

Synthetic Organic Chemicals, 1991

Table 8-1-Continued Plastics and resin materials: U.S. Production and sales, 1991 Sales Plastics and resin materials

Thermoplastic resins-Continued Polyethylene resins, total

Production Quantity

Value

Average Unit valuer

1,000 kilograms dry basis2

1,000 dollars

Per kilogram

1,000 kilograms dry basis2

9,429,407

9,387,443

7,284,639

$.78

242,056

226,710

239,170

1.05

Specific gravity 0.940 and below, total Low density polyethylene (LDPE) resins Linear low density polyethylene (LLDPE) resins

5,236,044 3,006,174

5,193,087 2,923,696

3,964,623 2,322,145

.76 .79

2,229,870

2,269,391

1,642,478

.72

Specific gravity over 0.940 All other ethylene copolymers

3,850,976 100,331

3,881,484 86,162

2,949,937 130,909

.76 1.52

2,664,063

2,403,391

1,792,668

.75

(12)

163,142

218,999

1.34

1 33,856

49,570 80,497 33,075

62,427 111,939 44,633

1.26 1.39 1.35

3,310,464

2,978,314

3,795,324

1.27

487,596

439,396

858,733

1.95

2,189,752 313,902 807,956 1,067,894

1,898,378 229,074 770,442 898,862

1,883,640 251,565 790,028 842,047

.99 1.10 1.03 .94

Styrene latexes, total Styrene-butadiene latexes All other styrene latexes

303,227 281,681 21,546

335,008 314,667 20,341

428,599 396,154 32,445

1.28 1.26 1.60

Methyl methacrylate-butadiene styrene (MBS) All other styrene plastics materials 15

51,336 278,553

44,907 260,625

102,678 521,674

2.29 2.00

4,230,895

3,827,554

3,433,149

.90

243,905 3,455,220 90,487 261,338 37,423 142,522

191,918 3,273,328 83,798 138,124 24,839 115,547

314,197 2,361,277 158,757 264,000 60,409 274,509

1.64 .72 1.89 1.91 2.43 2.38

533,011

262,438

1,634,026

6.23

Ethylene-vinyl acetate (EVA) resins

Polypropylene resins Rosin modifications, total Modified rosin (unesterified) Modified rosin esters Rosin esters, unmodified (Ester gums) Styrene plastics materials, total Acrylonitrile-butadiene-styrene terpolymer (ABS) resins Polystyrene homopolymers, total Expandable polystyrene beads Rubber modified polystyrene Straight polystyrene

Vinyl resins, total" Polyvinyl acetate 17 Polyvinyl chloride homopolymers Polyvinyl chloride copolymers Vinyl acetate-acrylate copolymers Polyvinylidene chloride, latex and solid types All other vinyl resins18 All other thermoplastic resins 18

75,S152

1 Calculated from unrounded figures. 2 Dryl.iveight basis unless otherwise specified.

Dry weight basis is the total weight of the materials including resin and coloring agents, extenders, fillers, plasticizers, and other additives, but excluding water and other liquid diluents unless they are an integral part of the materials. 3 Includes reactive diluents which are an integral part of the resin. Excludes the weight of hardeners sold in association with the resin as part of a two-component system. 4 Data shown for advanced epoxy resins are that part of the unmodified epoxy resins which is further processed; therefore, the total in parentheses are not included in the grand total. 5 Polyester resins are unsaturated alkyd resins, later to be copolymerized with a monomer (Such as styrene or methyl methacrylate), and polyallyl resins (such as did)/ phthalate and diglycol carbonate). Data are on an "as sold" ncluding monomer if part of the resin system. including 6 In addition to the polyols, the other principal starting materials used in the production of urethane products are the isocyanic acid derivatives, mainly the 80/20 mixture of toluene-2,4- and 2,6-diisocyanate. Statistics for the isocyanic acid derivatives are reported in the "Cyclic Intermediates" section of the Synthetic Organic Chemicals report. 8-3

Section 8 Footnotes for table 8-1—Continued 7 The data on urethane elastomers are believed to be not fully representative of the total urethane market in view of the very large number of urethane elastomer producers. The commission has begun reporting statistics for urethane elastomers in two sections, section VIII, Plastics and resin materials, and section X, Elastomers (synthetic rubber). Henceforth those polyurethane products classified as "thermoplastic" urethane elastomers will be reported in SOC section X; all other urethane elastomers will remain in SOC section VIII. 8 Includes thiourea resins. 9 Includes acetone-formaldehyde resins, glyoxal-formaldehyde resins, furfuryl resins, polybutadiene resins, silicone resins, and certain other thermosetting resins. 10 Does not include production or sales for fiber use. 11 Engineering plastics: Includes acetal, polycarbonate, polyetheretherketone (PEEK) resinspolyphenylene oxide, polyphenylene sulfide, and polysulfone. Engineering plastics are defined in Whittington's Dictionary of Plastics., as "All plastics, with or without fillers or reinforcements, which have mechanical, chemical and thermal properties suitable for use in construction, machine components and chemical processing equipment." The above list of plastics (all of which are thermoplastic) was selected from a larger group in this source. Certain other plastics named in Whittington's Dictionary as engineering plastics, such as ABS resins, acrylic resins, and nylon resins, are not included in the above list as they are published separately. 12 Reported data did not meet the disclosure criteria. 13 Statistics for nylon 6 and nylon 6/6 which are used in plastics applications (e.g., molding, etc.) are induded here. 14 Statistics are included here for polyethylene terephthalate used in plastics applications (e.g., molding, etc.) Statistics also are included here for production only when the starting materials are converted directly to a finished product(i.e., In situ" production); polyester film and tape are examples of such a conversion. 15 Includes data for a-methyl styrene polymers, styrene acrylonitrile (SAN) copolymer resins, styrene-allyl alcohol copolymer resins, styrene-divinylbenzene copolymer resins, styrene-maleic anhydride copolymer resins, styrene-methyl methacrylate copolymer resins, and other styrene resins. 16 Data are reported on the basis of dry resin content, excluding the weight of plasticizers, extenders, fillers coloring agents, stabilizers, or impact modifiers, unless otherwise noted. 17 Data for polyvinyl acetate produced and sold in latex form includes the weight of any protective colloids which are used as emulsion stabilizers and form an integral part of the resin system. Production and sales do not include polyvinyl acetate used as a reactive intermediate for polyvinyl alcohol or other vinyl resins. 18 Includes polyvinyl alcohol, polyvinyl butyral, polyvinyl formal, polyvinylidene chloride, and other vinyl resins. 19 Includes cellulose plastics, coumarone-indene resins, phenoxy resins, polybutylene type resins, polyphenyl aromatic ester resins, polyterpene phenol, chlorinated polyolefins, acrylonitrile modified rosin (unesterfied) (production only); fluorocarbon resins (sales only) and certain other thermoplastic materials. Note.—Data reported to the U.S. International Trade Commission do not necessarily coincide with that reported to the Society of the Plastics Industry (SPI) because of differences in both the reporting instructions and in the coverage of certain resins. Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

8-4

Synthetic Organic Chemicals, 1991 Table 8-2 Plastics and resin materials for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Plastics and resin materials

Separate statistics

Thermosetting resins: Acetone-formaldehyde resins Alkyd resins: Acrylate-alkyd copolymer resins Phthalic anhydride type alkyd resins

No Yes Yes Yes

Polybasic acid type alkyd resins

Yes

Styrenated-alkyds, or copolymer alkyds

Yes

Vinyl toluene alkyds

Yes

All other alkyd copolymers Amino resins: Melamine-formaldehyde resins

Yes Yes

Urea-formaldehyde resins

Dicyandiamide resins Epoxy resins: Epoxy resins, advanced

Epoxy resins, unmodified Furfuryl type resins Glyoxal-formaldehyde resins Phenolic and other tar acid resins

Polybutadiene resins Polyester resins, unsaturated, and ally! resins: Allyl resins Diallyl isophthaiate Polyester resins, unsaturated

Yes Yes Yes

Yes No No Yes

No Yes No No No

Polyether and polyester polyols for urethanes

Yes

Polyurethane elastomer and plastic products: Polyurethane elastomers

Yes Yes

Polyurethane resins

Yes

Manufacturers' identification codes (according to list in table 8-3)

BAS, FLH, GP. CKC, CPV, DRR, MNP, PPG, REL, ( 2). ACO, AKZ, BAS, BLC, CGL, CJO, CKC, BRU, JOB, CPV, DRC, DUP, ECC, EW, FOC, OLD, GRG, GRV, IMI, LIC, MMM, MNP, NCP, PPG, PRT, QCP, RCI, REL, REZ, SRY, TCC, UNO, USP,( 2), (2). CJO, CKC, EW, FOC, GLD, IMI, 10y, MID, PPG, REL, SCN, (2). CJO, CKC, CPV, EW, IMI, MNP, MRT, REL, SCN, (2). BLC, CGL, CKC, CPV, GLD, GRV, IMI, JOB, MNP, REL, (2). BLC, CGL, CJO, DUP, MNP. ACY, AUX, BOR, CBD, COL CKC, DGO, DRC, GP, GRG, HCL, MID, MNP, MON, PLS, PMC, PPL, PST, RCI, REL, REZ, RSN, SQA, TCC, WRD. ACY, AUX, BOR, CBD, CGL, CKC, CPV, GP, MMM, MNP, PMC, PPL, PST, REL, REZ, SAC, SPU, SQA, SYT, SOR, WCL. ECC, HCL, S, SYT, TCC. AIP, AKZ, CNI, BAS, CGL, CGY, CJO, CKC, CPV, DOW, EW, GE, GLD, GRG, GRV, HXL, MID, MIL MMM, MRT, OCF, PPG, RCI, REZ, SMO, (2). ASH, BAS, CGY, CKC, CLU, CMS, CPV, DAN, DOW, HYA, MNP, PRT, RCI, REZ, SHC, UCC, (2). CLU, DRR, HVG, UNO. AUX, HCL, SQA, TCC, WPG. ADC, ASH, BAS, BME, BOR, BSC, BTL, CBD, CKC, DRR, EW, GP, GRV, HCL, HER, HKP, HPC, HVG, IRI, ISP, LII, MCA, MID, MMM, OCF, PLS, PSG, PSL, RH, SCN, SPL, UCC, UNO, USR, VSV, WPG, WTH, (2), (2), (2), (2). CCS, CNI, PAS, LC. ATR, CMS, IMI. CMS. ADC, APH, ART, ASH, BAS, CGL, CKC, CMS, EW, GLD, GRG, IMI, IPC, JOB, LII, MID, MMM, MRT, NCP, OCF, PPG, PPL, RCI, SCN, SIC. ATR, BAS, BMC, BPT, CHC, CXI, DOW, GRG, HCF, ICI, MRT, OMC, PPG, PPL, RCI, RUO, SLC, SYT, UCC, WM, (2). ACY, ADC, ARO, BAS, BPT, CAS, CGY, CNI, DNS, HXL, HYC, INP, MRT, PPG, PRC, QUN, RSN, RUO, SCN, SLC, SMO, SYT, USM, USR. CGL, DUP, EW, GLD, GRD, HVG, HYC, INP, JOB, LC, OMC, PEL, SHX, SIF, ( 2).

See footnotes at end of table. 8-5

Section 8 Table 8-2--Continued Plastics and resin materials for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Plastics and resin materials

Separate statistics1

Manufacturers' identification codes (according to list in table 8-3)

Thermosetting resins—Continued: Silicone resins All other thermosetting resins, benzenoid

No Yes

CJO, DCC, MID, PEL, SPD. ACY, AKZ, BAS, GLD, GRV, PRC, GRV, PRC, MID, REL, RTC, RUO, S, TCC, WPG, ( 2), (2). (2), (2)-

Thermoplastic resins: Acrylic resins: Copolymer resins of acrylic and/or methacrylic acid resins: Butyl acrylate ethyl acrylate copolymer resins Butyl methacrylate-ethyl methylacrylate copolymer resins 2-Ethylhexyl acrylate-methy acrylate copolymer resins Other copolymer resins of acrylic and/or methacrylic acid esters

Yes

No

AIP, BFG, ICI, MIL RH, TCC, UOC.

No

UOC.

No

UOC, AIP.

Yes

ACO, AIP, BAS, CHP, CKC, CPV, DRB, DRC, ESS, FLH, GGI, GLD, ICI, JNS, KMP, MON, NES, NSC, PPG, PRA, PYI, RAS,2IRCI, RH, SCN, SYT, TCC, UCC, ( AIP, AKZ, BAS, CGY, CKC, CPV, DRC, DUP, GRV, MID, MNP, PPG, PRA, REL, REZ, SCP, SM.

Thermosetting acrylic resins

Yes

Homopolymer resins of acrylic and/or methacrylic acid resins: Other homopolymer resins of acrylic and/or methacrylic acid esters

Yes

Polymethyl methacrylate (PMMA)

Yes

Cellulose plastics and resins: Cellulose acetate Cellulose acetate butyrate Cellulose acetate propionate Ethyl cellulose Chlorinated polyolefins, thermoplastic Coumarone-indene resins Acrylonitrile resin

AIP, CKC CPV, DUP, RH, SAR, SCP, UOC, 0). ART, DUP, ICI, JOB, MRT, PKL, PYI, RH, CYR, SAR, SQA, TCC.

No No No No No No No

EKT, MIL EKT. EKT. AQU, (2). EKT. CKC. (2).

Engineering plastics: Acetal resins Polycarbonate resins Polyimides and amide-imide polymers Polyphenylene oxide type resins Polyphenylene sulfide resins

Yes Yes No Yes No No

DUP, HCL, PRT, UTF, WPG. DOW, GE, SQA. DUP, EW, GE, GRG, PDI, SCN. GE . HCL, PLC.

Fluorocarbon resins: Ethylene/chlorotrifluoro ethylene copolymer Polytetrafluoroethylene (PTFE) Polyvinyl fluoride Polyvinylidene fluoride All other fluorocarbon resins Nylon 6,6-acrylonitrile-butadiene-styrene Petroleum hydrocarbon resins

Yes No No No No No No Yes

Phenol polymers Phenoxy (R) resin (other than for coating and adhesives)

No

AUS. AUS, DUP, ICI. DUP. AUS, PAS. DUP. MON. ARZ, BAS, CFX, CXI, EKX, ENJ, GYR, HPC, LII, NEV, (2), (2). ARZ.

No

NEV, UCC.

See footnotes at end of table. 8-6

Synthetic Organic Chemicals, 1991 Table 8-2--Continued Plastics and resin materials for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Plastics and resin materials

Separate statistic&

Thermoplastic resins—Continued: Polyamide resins: Non-nylon type, polyamide resins

Yes Yes

Nylon type, polyamide resins Polybutylene type resins Polyester resins, saturated: Polybutylene terephthalate(PB1) Polyethylene terephthalate (PET)

Yes No Yes No Yes

Manufacturers' identification codes (according to list in table 8-3)

ARZ, COO, DXA, EFH, GP, LII, S, SCP, SQA, USM, WTH. ACS, AGI, BAS, BCM, CTR, DGO, DUP, GRG, HCL, MON, NYL, PAS, RSN, SCP, SKID, USM. AMO, ENJ, SHC. BAS, GE, HCL. ACS, DUP, EKT GE, GYR, HCL, ICI, TRY, WLM, YKK, ACS, AUS, BAS, CGY, CKC, CPV, DUP, EKT, GLD, GRG, GYR, HCL, ICI, IMI, MID, MNP, PPG,REL, SCN, USM. (2).

All other polyester resins, saturated

Yes

Polyethylene and copolymers resins: Ethylene-vinyl acetate (EVA) resins Other ethylene copolymer resins

Yes Yes Yes

Specific gravity 0.940 and below (LDPE)

Yes

Specific gravity 0.940 and below, linear (LLDPE) Specific gravity over 0.940

Yes Yes

Polypropylene polymer and copolymer resins

Yes

Polyterpene resins Rosin modifications: Modified rosin (unesterified) Modified rosin esters

No Yes Yes Yes

Rosin esters, unmodified (Ester gums) Styrene type plastics materials: Acrylonitrile-butadiene-styrene (ABS) terpolymer resins a-Methyl styrene polymers Styrene-ac rylonitrile copolymer resins (SAN) Polystyrene: Expandable polystyrene beads Rubber modified polystyrene

Yes Yes

Straight polystyrene Styrene latexes: Styrene-butadiene latexes All other styrene latexes Other styrene copolymers: Acrylic-styrene-ac rylonitrile Methyl methacrylate-butadiene styrene (MBS) resins Styrene-acrylonitriie-a-methyl styrene Styrene-ally) alcohol copolymer resins Styrene-divinylbenzene copolymer resins Styrene-maleic anhydride copolymer resins Styrene-maleic anhydride, glass filled Styrene-maleic anhydride-isobutanol terpolymer . Styrene-methyl methacrylate copolymer resins All other styrene copolymers

Yes No No Yes Yes Yes Yes Yes Yes Yes Yes No Yes No No No No No No No Yes

ENJ, NSC, RCI, RSN, USI, WLK. DOW, EKX, ENJ, EVL, HXL, tax, SQA, (2). DOW, DUP, EKX, ELP, ENJ, LYP, SM, SOC, SQA, UCC, USI, WLK. DOW, ENJ, SM, SOC, UCC, USI. DOW, ENJ, HCL, HIM, HKP, PAX, PLC, SLT, SOC, UCC, USI. AMO, ART, BAS, CSD, EKX, ELP, ENJ, HIM, LYP, MIL, PLC, SHC, SLT, USI, WYK. ARZ. ARZ, CJO, HPC, WTH, WVA. ARZ, BAS, CKC, EW, FRP, GP, GRV, HCL, HPC, LII, WTH, WVA, ARZ, CKC, FRP, HPC, H. DOW, GE, GRD, MON. AIP, AMO, CKC, CPV, JNS. DOW, ICI, MON. ATR, BAS, DPI, HMN, TXS. AMO, API, CSD, DOW, DPI, HMN, PLR, SM. AEP, AMO, API, ATR, CSD, DLT, DOW, DPI, HMN, HPC, KTP, PLR, SM, SOC, TXS. DOW, GRD, GYR, PYI, RCI, UOC. ADC, GCS, FRS, GRD, SPO, UCC, UOC. MON. CYR, KTX, RH. MON. HPC, MON. EK, RH, TCC. ATR, DIX, JNS, MON, PAS. MON. MON. ADC, PLR, ZNC, (a). AIP, ATR, CKC, CPV, EW, FLH, GAF, GE, GGI, GYR, HPC, JNS, MON, PLC, SCN, SQA, TCC, (2).

See footnotes at end of table. 8-7

Section 8 Table 8-2--Continued Plastics and resin materials for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Plastics and resin materials

Separate statistics

Manufacturers' Identification codes (according to list in table 8-3)

No

FER, ICI.

Thermoplastic resins—Continued:

All other styrene type plastics materials Vinyl resins: Polyvinyl acetate resins

Yes Yes

Polyvinyl alcohol resins Polyvinyl butyral resins Polyvinyl formal resin Vinyl acetate-acrylate copolymers

No No No Yes

Polyvinyl chloride and copolymer resins: All other polyvinyl chloride copolymer resins Polyvinyl chloride homopolymer resins

Yes Yes Yes

Polyvinylidine chloride resins: Latex type polyvinylidene chloride resins Solid type polyvinylidene chloride resins All other vinyl resins All other thermoplastic resins, benzenoid

No No Yes Yes

AIP, CGL, DAN, FLH, FLN, GLD, GRD, JOB, MNP, MON, PYI, RCI, SQA, NSC, TCC, UCC, UOC, (2). AIP, DUP. MON. GRG, MON. ACO, DAN, FLH, FLN, GLD, KMP, NCJ, NTC, PRA, RCI, RH, SPC, SQA, UCC, UOC. BCP, BFG, KYS, UCC, VYN. BCP, BFG, CNT, FOR, GGC, GYR, HKP, KYS, PLC, SHT, VST, VYN. BFG, DOW, GRD, UOC. DOW. DIX, EW, FLH, GLD, NCJ, RH, UCC. BRD, FER, HCL, LII, NES, UOC, (2).

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

8-8

Synthetic Organic Chemicals, 1991 Table 8-3 Plastics and resin materials: Directory of manufacturers, alphabetical by code, 1991 Code ACO ACS

ACY ADC AEP AES AGI AIP AKZ AMO APH API AQU ARO ART ARZ ASH ATR AUS AUX BAS BCM BCP BFG BLC BMC BME BOR BPT BRD BRU BSC BTL CAS CBD GCS CFX CGL CGY CHC CHP CJO CKC CLU CMP CMS

Name of company Adco Chemical Co. Allied Signal, Inc. Engineered Materials Sector. Engineered Plastic Div. American Cyanamid Co Anderson Development Co Packaging Corp. of America Advanced Elastomer Systems, LP. EMS-American Grilon, Inc. Air Products & Chemicals, Inc. Akzo Coating, Inc. Amoco Corp. Alpha Resins Corp. American Polymers, Inc. Aqualon Co. Arnco Aristech Chemical Corp. Arizona Chemical Co. Ashland Oil, Inc. Atlantic Richfield Co., Arco Chemical Co Ausimont N.V. Auralux Corp. BASF Corp. Belding Heminway Co. Borden Chemical & Plastics Delaware • Limited Partnership B. F. Goodrich Co Ranbar Technology, Inc Brin-Mont Chemicals, Inc. Allied Signal, Inc Friction Materials Div. Borden, Inc., Packaging & industrial Products Div. Permuthane Coatings, Inc. Lonza, Inc. M. A. Bruder & Sons, Inc. Cascade Resins, Inc. BTL Specialty Resin Corp. CasChem, Inc. Neste Resins Corp. Advanced Resins, Inc. Chemfax, Inc. Cargill, Inc. Ciba-Geigy Corp . Carpenter Chemical Co C. H. Patrick & Co., Inc C. J. Osbom Chemicals, Inc. Cook Composites and Polymers Co. CL Industries, Inc Commercial Products Co., Inc. Cosmic Plastics, Inc.

Code CNI CNT COO CPV CSD CTR CXI CYR DAN DCC DGO DIX DLT DNS DOW .... DPI DRB DRC DRR DUP

DXA ECC EFH EK EKT EKX ELP ENJ ESS EVL EW FER FLH FLN FOC FOR FRP FRS

GAF GE

Name of company Conap, Inc. Certainteed Corp. H.B. Fuller Co. Cook Paint & Varnish Co. Fina Oil & Chemical Co. Custom Resins Div. of Bemis Co., Inc. Chemical Exchange Industries, Inc. CYRO Industries Hickson Danchem Corp. Dow Corning Corp. Day-Glo Color Corp. Dixie Chemical Co., Inc. Deltech Corp. Dennis Chemical Co. Dow Chemical Co. Dart Polymers, Inc., Sub of Dart Container Corp. Rohm Tech, Inc. Dock Resins Corp. Delta Resins & Refractories, Inc. E. I. duPont de Nemours & Co., Inc.: Automotive Product Dept. Chemicals and Pigments Dept. ED/IMG Dept. Petrochemicals Dept. Polymer Products Dept. Dexter Corp., Automotive Div. . Eastern Color & Chemical Co. E. F. Houghton & Co. Eastman Kodak Co.: Tennessee Eastman Co. Div. Texas Eastman Co. Div. Rexene Products Company Exxon Chemical Americas Essential Industries, Inc. Eval Company of America Westinghouse Electric Corp., Electrical Ferro Corp., Keil Chemical Div. H. B. Fuller Co. Franklin International, Inc. Handschy Industries, Inc., Ink & Chemicals Div. Formosa Plastics Corp. Akzo Coatings, Inc. Firestone Tire & Rubber Co., Firestone Synthetic Rubber & Latex Co. Div. ISP Chemicals Corp. General Electric Co.: Electromaterials Div. Specialty Chemical Group

See footnotes at end of table. 8-9

Section 8 Table 8-3—Continued Plastics and resin materials: Directory of manufacturers, alphabetical by code, 1991 Code GGC

GGI GLD GP GRD GRG .... GRV GYR HCF HCL

HER HIM HKP HMN .... HPC HVG HXL HYA HYC ICI

IMI INP 10V IPC IRI ISP JNS JOB KMP KTP KTX KYS LC LIC LII LYP MCA .....

Name of company Georgia-Gulf Corp.,: PVC Compound Div. Plaquemine Div. Grow Group, Inc., Cello Corp. Div. Glidden Co. Georgia-Pacific Corp Resins, Inc. W. R. Grace & Co., Organic Chemicals Div., P. D. George Co. Guardsman Products, Inc. Goodyear lire & Rubber Co Cape Industries Hoechst Celanese Corp: Bayport Works Fibers Industrial Div. Sou-Tex Works Heresite Protective Coatings, Inc. Himont U.S.A., Inc. Occidental Chemical Corp., Polymers and Plastics Group Huntsman Chemical Corp. Hercules, Inc. Ametek, Inc., Haveg Div. Hexcel Corp. Hexcel Chemical Products Dexter Corp: Aerospace Material Div. Dexter Electronic Materials Div. ICI Americas: Film Group Div. ICI Acrylic, Inc. Resin Div. Rubicon, Inc. Specialty Chemical Div. Insulating Materials, Inc. Synair Corp. Akzo Resins & Vehicles Interplastic Corp Stuart-Ironsides, Inc. lndspec Chemical Corp S.C. Johnson & Son, Inc. Jones-Blair Kelly-Moore Paint Co., Inc Kama Corp Kaneka Texas Corp. Keysor Century Corp Lord Corp. Chemical Products Group Lilly Industrial, Inc. Lawter International, Inc. Lyondell Petrochemical Co Masonite Corp., Alpine Resin Div. .

.

.

See footnotes at end of table. 8-10

Code

.

MID MIL MMM .... MNP MON .... MRT NCJ NCP NES NEV NSC NTC NYL OCF OMC PAS PAX PDI PEL PKL PLC PLR PLS PMC PPG PPL PRA PRC PRT PSG PSL PST PYI QCP QUN RAS RCI REL REZ RH RSN RTC RUO

S SAC SAR

Name of company Dexter Corp., Dexter Specialty Coatings Milliken & Co., Milliken Chemical Div. Minnesota Mining & Manufacturing Co, McWhorther, Inc. Monsanto Co. Morton International Inc., Morton Chemical Div. National Casein of New Jersey Niles Chemical Paint Co. Ruetgers-Nease Chemical Co. Neville Chemical Co. National Starch & Chemical Corp. National Casein Co. Nylon Corp. of America Owens-Corning Fiberglas Corp. Olin Corp. ELF Atochem North America, Inc. Paxon Polymer Co., LP. Phelps Dodge Industries, Inc., Phelps Dodge Magnet Wire Co. Div. Pelron Corp. Plaskolite, Inc. Phillips 66 Co. Novacor Chemicals, Inc. Plastics Engineering Co. Plastics Manufacturing Co. PPG Industries, Inc. Pioneer Plastics Corp. Para-Chem Southern, -Inc. Products Research & Chemical Corp. Pratt & Lambert, Inc. PMC, Inc., PMC Specialites Group, Inc. Plaslok Corp. Perstorp Compounds, Inc. Morton International, Inc., Morton Chemical Div. Quaker Chemical Corp. K. J. Quinn & Co., Inc. Surface Coatings, Inc. Reichhold Chemicals, Inc. Akzo Coatings, Inc. Rhone-Poulenc, Inc. Rohm & Haas Co. ELF Atochem North America, Polymers Div. Mount Vernon Mills, Inc. Ruco Polymer Corp. Sandoz Chemicals Corp., Color and Chemicals Div. Southeastern Adhesives Co. Esschem, Inc.

Synthetic Organic Chemicals, 1991 Table 8-3—Continued Plastics and resin materials: Directory of manufacturers, alphabetical by code, 1991 Code SCN SCP SHC SHT SHX SIC SIF SKP SLC SLT SM

SMO SOC SOR SPC SPD SPL SPO SPU SQA SRY SYT

Name of company Schenectady Chemicals, Inc. Henkel Corp Shell Oil Co. Shell Chemical Co. Shintech, Inc. Sherex Chemical Co., Inc. BP Chemicals, Inc., Silmar Div. BP Chemicals, Inc., Filon Div. Shakespeare Co. Monofilament Div. Soluol Chem Co., Inc. Solvay Polymer Corp. Mobil Oil Corp.: Mobil Chemical Co.: Chemical Products Div. Petrochemicals Div. Polystyrene Business Group Smooth-On, Inc. Chevron Corp., Chevron Chemical Co. Southern Resin, Inc. Insilco Corp., Sinclair Paint Co. Div. General Electric Co., Silicone Products Dept. Spaulding Composites Co., Industrial Plastics Div. Ameripol Synpol Co. Div. of Uniroyal Goodrich Tire Co. Spulock Adhesives, Inc. Sequa Chemicals, Inc. Synray Corp Synthron, Inc. .

.

Code TCC TNA TRY TXS UCC UNO UOC USI USM USP USR UTF VST VSV VYN WCL WLK WLM WM WPG WRD WTH WVA WYK YKK ZNC

Name of company Sybron Chemicals, Inc. Ethyl Corp. Toray Plastics America, Inc. Scott Polymers, Inc. Union Carbide Corp., Industrial Chemical Div. United-Erie, Inc. Union Oil Co. of California Quantum Chemical Corp., USI Division Emhart Corp., Bostik Div. U.S. Polymers, Inc. Uniroyal, Chemical Co., Inc. Ultraform Co. Vista Chemical Co. Valentine Sugars, Inc. Vygen, Inc. Wright Chemical Corp. Westlake Corp. Wellman, Inc. Inolex Chemical Co. West Point-Pepperell, Inc. Grifftex Chemical Co., Sub. Weyerhaeuser Co. Union Camp Corp., Chemical Div. Westvaco Corp. Wyckoff Chemical Co., Inc. YKK Corp. Zeon Chemicals, Inc.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

8-11

Synthetic Organic Chemicals, 1991

Section 9 Rubber-Processing Chemicals

valued at $413 million, in 1990. Of the total production of cyclic rubber-processing chemicals in 1991, antioxidants, antiozonants, and stabilizers accounted for 61 percent, and accelerators, activators, and vulcanizing agents for 37 percent. Production of antioxidants, antiozonants, and stabilizers, which amounted to 85 million kilograms in 1991, included 54 million kilograms of amino compounds and 31 million kilograms of phenolic and phosphite compounds. Sales of amino antioxidants, antiozonants, and stabilizers in 1991 amounted to 40 million kilograms, valued at $165 million; sales of phenolic and phosphite compounds were 30 million kilograms, valued at $130 million

Rubber-processing chemicals are organic compounds that are added to natural and synthetic rubber to give them qualities necessary for their conversion into fmished rubber goods. In this report, statistics are given for cyclic and acyclic compounds by use—such as accelerators, antioxidants, and vulcanizing agents. Data on production and sales of rubber-processing chemicals in 1991 are given in table 9-1. Data on production of rubber-processing chemicals during 1987-91 are given in figure 9-1. Production of rubber-processing chemicals as a group in 1991 amounted to 155 million kilograms, or 14 percent less than the 179 million kilograms produced in 1990. Sales of rubber-processing chemicals in 1991 amounted to 114 million kilograms, valued at $457 million, compared with 136 million kilograms, valued at $458 million, in 1990. The production of cyclic rubber-processing chemicals in 1991 amounted to 140 million kilograms, or 1 percent more than the 138 million kilograms produced in 1990. Sales of cyclic rubber-processing chemicals in 1991 totaled 99 million kilograms, valued at $428 million, compared with 104 million kilograms,

Production of acyclic rubber-processing chemicals in 1991 amounted to 15 million kilograms. or 63 percent less than the 40 million kilograms produced in 1990. Sales in 1991 totaled 14 million kilograms, valued at $29 million, compared with 32 million kilograms, valued at $44 million, in 1990. Table 9-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 9-3. Cynthia Trainor 202-205-3354

Figure 9-1 Rubber-processing chemicals: U.S. production, 1987-91

Millions of kilograms 200 180 160 140 120

100 80 60 40 20 0

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 9-1

Section 9 Figure 9-1 Rubber-processing chemicals: U.S. production, 1987-91 Sales Rubber-processing chemicals

Grand Total

Production

Quantity

Value

Average Unit value1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

154,596

113,813

457,337

$4.02

139,796

99,434

427,997

4.30

51,030

25,441

103,641

4.07

Thiazole derivatives, total

49,160

23,685

86,645

3.66

N-tert-Butyl-2-benzothiazolesulfenamide 2,2'-Dithiobis[benzothiazolej All other thiazole derivatives All other accelerators, activators, and vulcanizing agents2 3

10,821 4,419 33,920

9,238 5,153 9,294

39,186 13,900 33,559

4.24 2.70 3.61

1,870

1,756

16,996

9.68

84,735

70,164

295,242

4.21

54,085 33,946 20,139 30,650 2,653

39,753 23,950 15,803 30,411

165,350 112,758 52,592 129,892

4.16 4.71 3.33 4.27

27,997 4,031

630,411

6 129,892

6 4.27

3,829

29,114

7.60

14,800

14,379

29,340

2.04

Cyclic Total Accelerators, activators, and vulcanizing agents total

Antioxidants, antiozonants, and stabilizers, total Amino compounds, total Substituted p-phenylenediamines All other amino compounds4 Phenolic and phosphite compounds, tote Polyphenolics All other phenolic and phosphite compounds All other cydid rubber-processing chemicals? Acyclic Total 1 Calculated from unrounded figures. 2 Includes aldehyde-amine reaction products,

dithiocarbamates, and other accelerators, activators, and vulcanizing agents. 3 Data on dithiocarbamates induded in this table are for materials used chiefly in the processing of natural and synthetic rubber. Data on dithiocarbamates, which are used chiefly as fungicides, are included in the section on `Pesticides and Related Products." 4 Includes aldehyde- and acetone-amine reaction products and other amines. 5 Also includes other antioxidants, antiozonants, and stabilizers. 6 Includes sales quantity and value figures for polyphenolics. 7 Includes blowing agents and other cyclic rubber-processing chemicals. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Synthetic Organic Chemicals, 1991 Table 9-2 Rubber-processing chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Rubber-processing chemicals Cyclic: Accelerators, activators, and vulcanizing agents: Aldehyde-amine reaction products: Heptaldehyde-aniline condensate Triethyltrimethylenetriamine All other aldehyde-amine reaction products, cyclic Dithiocarbamic acid derivatives: Dibenzyldithiocarbamic acid, sodium salt Dibenzyldithiocarbamic acid, zinc salt All other dithiocarbamic acid derivatives, cyclic Guanidines: Dicatechol borate, di-o-tolylguanidine salt All other guanidines, cyclic Thiazole derivatives: N-tert-Butyl-2-benzothiazolesulfenamide N-Cyclohexy1-2-benzothiazolesulfenamide 2,2'-Dithiobis[benzothiazole] 2-Mercaptobenzothiazole 2-Mercaptobenzothiazole, copper salt 2-Mercaptobenzothiazoie, zinc salt N-Morpholinyl-2-benzothiazolyl disulfide N-Oxydiethyl ene-2-benzothiazdesuffenamide All other thiazole derivatives, cyclic All other cyclic accelerators, activators, and vulcanizing agents: Bis(morpholinothiocarbamoyl) disulfide ....... 1,3-Dihydro-4(or 5)-methy1-2H-benzimidazole-2thione Dimethylammonium hydrogen isophthalate Di-N,N'-pentamethylenethiuram tetrasulfide 4,4'-Dithiodimorpholine 2-Mercaptotololuimidazole, zinc salt m-Phenylenebismaleimide All other accelerators, activators, and vulcanizing agents, cydic Antioxidants, antiozonants, and stabilizers : Amino antioxidants, antiozonants, and stabilizers: Aldehyde- and acetone-amine reaction products: Diphenylamine-acetone aldehyde Diphenylamine-acetone condensate All othr aldehyde and acetone-amine reaction products, cyclic Substituted p-phenylenediamines: Alkylaryl-p-phenylenediamines N,N'-Bis(1,4-dimethylpentyI)-pphenylenediamine N,N'-Bis(1 -ethy1-3-methylpenty1)-pphenylenediamine N,N'-Bis(1-methylhepty1)-p-phenylenediamine N-Cyclohexyl-N'-phenyl-p-phenylenediamine Diarylenediamines, mixed N-(1,3-Dimethylbuty1)-N'-phenyl-pphenylenediamine N,N1-Di-2-naphthyl-p-phenylenediamine

Separate Manufacturers' identification codes statistics1 (according to list in table 9.3)

No No

USR. USR.

No

DUP.

No No No

USR. USR. VNC.

No No

VNC, (2). VNC.

Yes No Yes No No No No No No

BFG, MON, USR. MON, USR. BFG, MON, USR. MON, USR. ACY. USR, (2). GYR. BFG, USR. BFG,

No

ACY.

No No No No No No

VNC. (2). VNC. MON. VNC. DUP.

No

DUP, USR, (2).

No No

USR. BFG, USR.

No

USR.

No

MON.

No

MON, UPM.

No No No No

UPM. UPM. USR. GYR.

No No

UPM, USR. BFG.

(2).

See footnotes at end of table.

9-3

Section 9

Table 9-2—Continued Rubber-processing chemicals for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Rubber-processing chemicals

Manufacturers' identification codes Separate statistics1 (according to list In table 9-3)

Cyclic-Continued Antioxidants, antiozonants, and stabilizers -Continued Amino antioxidants, antiozonants, and stabilizers -Continued Substituted p-phenyienediamines-Continued N,N'-Diphenyl-p-phenylenediamine No N-Isopropyl-N'-phenyl-p-phenylenediamine No N-(1-MethylheptyI)-N'-phenyl-p-phenylenediamine No N-(1-Methylpenty1)-N'phenyl-p-phenylenediamine No All other p-Phenylenediamines, substituted No Other amines: p-Anilinophenol No 1,2-Dihydro-2,2,4-trimethylquinoline No Nonyldiphenylamine mixture (Mono-, di-, and tri-) No Octyldiphenylamine No Octyldiphenylamine, alkylated No p-(p-Toluenesulfonamido)diphenyiamine No Phenolic and phosphite antioxidants and stabilizers: Phosphites: Aikylaryl phosphites mixed No Nonylphenyl phosphites, mixed No Polyphenolic phosphites, polyalkylated No Triaryl phosphites No Polyphenolics (including bisphenois): Bisphenol, hindered No 4,4'-Butylidenebis(6-tert-butyl-m-cresol) No 2,5-Di-sec-butyldecylhydroquinone No 2,5-Di-(1,1-dimethylpropyphydroquinone No 2,2'-Methylenebis(6-tert-butyl-p-cresol) No 2,2'-Methylenebis(6-tert-butyl-4-ethylphenol) No All other phenolic antioxidants and stabilizers: Phenol, alkylated No Phenol, hindered No Phenol, styrenated, mixtures No N-Stearoyl-p-aminophenol No All other phenolic antioxidants No Blowing agents: p,p'-Oxybis(benzenesulfonhydrazide) No 5-Phenyltetrazole No p-Toiuenesulfonylsemicarbazide No All other cyclic rubber-processing chemicals: p-tert-Amylphenoi sulfide (Taddfier) No N-(Cydohexylthio)phthalimide No Dipheny1-4,4'-diphenylmethylenedicathamate No All other rubber-processing chemicals, cyclic No

BFG. USR. UPM. USR. KPI, UPM, USR. BFG. BFG, MON, USA. USR. BFG, USR. BFG. USR. FER, GE. GE, USR. BFG, GE. GE. USR. MON. USR. MON. ACY. ACY. ACY, BFG, GYR, NEV. GYR, USR. NEV, USR. HXL USR. USR. OMC. USR. PAS. MON. USR. FER.

Acyclic: Accelerators, activators, and vulcanizing agents: Dithiocarbamic acid derivatives: Dialkyldithiocarbamic acid derivative Dibutyldithiocathamic acid, nickel salt Dibutyldithiocarbamic acid, sodium salt Dibutyldithiocarbamic acid, zinc salt See footnotes at end of table. 9-4

No No No No

( 2).

USR, VNC. USR, VNC. VNC, (2).

Synthetic Organic Chemicals, 1991 Table 9-2--Continued Rubber-processing chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Rubber-processing chemicals

Separate Manufacturers' identification codes statisticsi (according to list in table 9-3)

Acyclic-Continued Accelerators, activators, and vulcanizing agentsContinued

Diethyldithiocarbamic acid, cadmium salt and bis(diethylthiocarbamoyl)disulfide, mixture Diethyldithiocarbamic acid, sodium salt Diethyldithiocarbamic acid, tellurium salt Diethyldithiocarbamic acid, zinc salt Dimethyldithiocarbamic acid, bismuth salt Dimethyldithiocarbamic acid, copper salt Dimethyldithiocarbamic acid, lead salt Dimethyldithiocarbamic acid, selenium salt Dimethyldithiocarbamic acid, zinc salt All other dithiocarbamic acid derivatives, acyclic Thiurams: Bis(dibutylthiocarbamoyl) disulfide Xanthates and sulfides: Di-n-butylxantho disulfide Zinc isopropyl xanthate All other acyclic accelerators, activators, and vulcanizing agents: All other accelerators, activators, and vulcanizing agents, acyclic Polymerization regulators: n-Dodecyl mercaptans tert-Nonyl mercaptan n-Octyl mercaptan tert-Octyl mercaptan All other polymerization regulators, acyclic Shortstops: Dimethyldithiocarbamic acid, potassium salt Dimethyldithiocarbamic acid, sodium salt All other acyclic rubber-processing chemicals: Waxes and paraffinic products Zinc laurate (Activator, physical property improver, and processing auxiliary) All other rubber-processing chemicals, acyclic

No No No No No No No No No No

(2). VNC, (2). (2 ).

(2). VNC. (2).

No

(2).

No No

USR. VNC.

No

DUP, (2).

No No No No No

PLC. PAS. PAS, PLC. PLC. PLC.

No No

USR. ALC, USR, VCC, VNC.

No

DUP.

No No

USR. (2).

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Section 9 Table 9-3 Rubber-processing chemicals: Directory of manufacturers, alphabetical by code, 1991 Code ACY ALC BFG DUP FER GE GYR HXL

Name of company American Cyanamid Co Alco Chemical Corp. B.F. Goodrich Co., B.F. Goodrich Chemical Group E. I. duPont de Nemours & Co., Inc. Polymer Products Dept. Ferro Corp. Bedford Chemical Div. General Electric Co., Speciality Chemical Group Goodyear Tire & Rubber Co Hexcel Corp., Hexcel Chemical Products

Code KPI MON NEV OMC PAS PLC UPM USR VCC VNC

Name of company Kenrich Petrochemicals, Inc. Monsanto Co. Neville Chemical Co. Olin Corp. ELF Atochem North America, Inc. Phillips 66 Co. UOP, Inc. Uniroyal Chemical Co., Inc. Vinings Industries, Inc. Vanderbilt Chemical Corp.

Note—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

9-6

Synthetic Organic Chemicals, 1991

Section 10 Elastomers Elastomers or synthetic rubbers are high polymer material exhibiting extensibility and elastic recovery. The term "elastomers" as used in this report pertain to substances, whether in bale, crumb, powder, latex, or other crude form, which can be vulcanized or similarly processed into materials which can be stretched to at least twice their original length and which, after having been so stretched and the stress removed, will return with force to approximately their original length. U.S. production and sales of elastomers in 1991 are shown in table 10-1. In 1991, total U.S. production' of elastomers amounted to 2,166 million kilograms, a decrease of 3.0 percent from that produced in 1990. The production of elastomers has remained stable during the past 5 year period; 1991 production showed an increase of 1.8 percent over 1987 production. Sales of elastomers also decreased slightly in 1991 compared to 1990. The sales volume decreased by 1.7 percent and sales value decreased 4.7 percent. Polyurethane type elastomers have previously been included in the section VIII "Plastids and Resin Materials." The commission reports urethane elastomers in section VIII, and section X, "Elastomers" (synthetic rubber). Henceforth those polyurethane products classified as "thermoplastic" urethane elastomers will be reported in SOC section X; all other urethane elastomers will remain in SOC section VIII.

Elastomers production was dominated by styrene-butadiene rubber (SBR) in 1991; production amounted to 902 million kilograms. Polybutadiene rubber was produced in the next largest quantity, amounting to 371 million kilograms. These two rubbers are used primarily in the production of tires. Other principle types of synthetic elastomers for which U.S. production data were reported separately are thermoplastic elastomers, production of which was 215 million kilograms in 1991; ethylene-propylene rubber, production of which was 206 million kilograms in 1991; and butadiene-acrylonitrile rubber (NBR), production of which was 73 million kilograms in 1991. Sales of styrene-butadiene rubber by U.S. producers in 1991 amounted to 603 million kilograms. In 1991, sales of polybutadiene rubber amounted to 170 million kilograms, and those of ethylene-propylene rubber to 194 million kilograms. Sales of thermoplastic elastomers amounted to 176 million kilograms and butadiene-acrylonitrile rubber amounted to 75 million kilograms. Table 10-2 lists the products reported in this section and indicates the manufacture(s) of each by code. These codes are identified by company names in table 10-3. Denby L. Misurelli 202-205-3362

Figure 10-1 Elastomers: U.S. production, 1987-91 Billions of kilograms

5 4

3

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

10-1

Section 10 Table 10-1 Elastomers (synthetic rubber): 1 U.S. production and sales, 1991

Production 2

Quantity2 Value

Average Unit value3

1,000 kilograms

1,000 1,000 kilograms dollars

Per kilogram

2,166,164

1,529,127

2,979,307

$1.95

Acrylic type elastomers Butadiene-acrylonitrile type (nitrile) (NBR-type) Ethylene-propylene type (EP-type)

4,138 72,979 206,045

5,637 74,892 193,659

26,927 163,721 394,272

4.78 2.19 2.04

Polybutadiene type (BR-type), total

370,713

170,120

159,823

.94

15,481 355,232

12,253 157,867

12,912 146,911

1.05 .93

59,993

38,455

357,927

9.31

Styrene-butadiene type (SBR)-type), total

902,038

602,787

593,101

.98

Styrene-butadiene, dry type Styrene-butadiene-vinylpyridine Styrene-butadiene, latex type and other

763,542 7,800 130,696

464,090 5,336 133,361

418,066 14,658 160,377

.90 2.75 1.20

215,319 334,939

175,783 267,794

535,243 748,293

3.04 2.79

Sales Elastomers

Grand total

Polybutadiene, emulsion-polymerized Polybutadiene, solution-polymerized Silicone (Q) type elastomers

Thermoplastic elastomers (such as styrene-block copolymers, thermoplastic olefin elastomers, thermoplastic polyurethane elastomers, and copolyesters) All other elastomers4

1 The term "elastomers" is defined as substances in bale, =nib, powder, latex, and other crude forms which can be vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original length and, after having been stretched and the stress removed, will return with force to approximately their original length. 2 Includes oil content of oil-extended elastomers. 3 Calculated from unrounded figures. 4 Includes butyl, chlorosulfonated polyethylene, epichiorohydrin, fluoroelastomers. hydrogenated nitrite, polychloroprene (neoprene) type, polyisoprene, polysulfide, and miscellaneous elastomers. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

10-2

Synthetic Organic Chemicals, 1991 Table 10-2 Elastomers for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Elastomers

Separate statistics1

Manufacturers' identification codes (according to list in table 10-3)

Cyclic

Epichlorohydrin elastomers (CO, ECO) tpye Styrene-butadiene (S or SBR) type Styrene-butadiene, dry type Styrene-butadiene, latex type Styrene-butadiene-vinylpyridine All other styrene-butadiene type elastomers, other Thermoplastic elastomers (such as styrene-block copolymers, thermoplastic olefin elastomers, thermoplastic polyurethanes elastomers, and copolyester)

No Yes Yes No Yes

ZNC.

No

ASY, LC.

Yes

All other cyclic elastomers

No

AES, BAS, BFG, DOW, DUP, EEP, EPI, FRS, GEP, HCL, ROG, SHC. TNA.

Yes No No No Yes No No No

BFG, CPY, GYR, MMM, RCI, USR, ZNC. ENJ. DUP. DUP. CPY, DUP, ENJ, USR. DUP, MMM. ZNC. ACY, ZNC.

No Yes Yes Yes No No No Yes

ASY.

CPY, FRS, DYG, GYR, RCI, SPO. BAS, BFG, GNT, GRD, GYR, MMM. BFG, FRS, GNT, GYR.

Acyclic

Butadiene-acrylonitrile type (nitrite) (NBR-type) Butyl (isobutylene-isoprene) type Chlorosulfonated polyethylene (CSM) type Ethylene acrylic elastomer Ethylene-propylene (EP) type Fluoroelastomers (CFM, FKM, FFKM) type Hydrogenated nitrite (HNBR) type Polyacrylic (ACM) type elastomers Polybutadiene acrylic acid acrylonitrile terpolymer (PBAN) Polybutadiene (BR) type Polybutadiene, emulsion-polymerized Polybutadiene, solution-polymerized Polychloroprene (Neoprene) (CR) type Polyisoprene (IR) type Polysulfide (T) type elastomers Silicone (Q) type elastomers

DYG, GNT, GYR, RCI, SPO. ASY, FRS, GYR, PLC. DUP, DKA. GYR. MRT. DCC, MRT, SPD, SWS.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

10-3

Section 10 Table 10-3 Elastomers (synthetic rubber): Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ACY AES ASY BAS BFG CPY DCC DKA DOW DUP

American Cyanamid Co. Advanced Elastomer Systems American Synthetic Rubber Corp. BASF Corp. B. F. Goodrich Co. Copolymer Rubber & Chemical Corp. Dow Coming Corp. Miles, Inc. Dow Chemical Co. E. I. duPont de Nemours & Co., Inc., Polymer Products Dept. Dynagen, Inc., Subsidary of General Tire Furon Co. Exxon Chemical Americas Eagle Pitcher Industries Inc., Orthane Div. Firestone Tire & Rubber Co., Firestone Synthetic Rubber & Latex Co. Div. General Electric Co., Speciality Chemical Group General Electric Co., Plastics Div. Gencorp Polymers Products

GRD

W. R. Grace & Co., Organic Chemicals Div. Polymers & Chemical Div. Goodyear Tire & Rubber Co. Hoechst Celanese Corp., Advanced Materials Group Lord Corp., Chemical Products Group Minnesota Mining and Manufacturing Co. Morton International, Inc., Morton Chemical Div. Phillips 66 Co. Reichold Chemicals, Inc. Rogers Corp. Shell Oil Co., Shell Chemical Co. General Electric Co., Silicone Products Dept. Ameripol Synpol Co., Div. of Uniroyal Goodrich Tire Co. Wacker Silicones Corp. Ethyl Corp Uniroyal Chemical Co., Inc. Zeon Chemicals, Inc.

DYG EEP ENJ EPI FRS GE GEP GNT

GYR HCL LC MMM MRT PLC RCI ROG SHC SPD SPO SWS TNA USR ZNC

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app A. Source: Compiled from data recieved in response to questionnaires of the U.S. International Trade Commission.

10-4

Synthetic Organic Chemicals, 1991

Section 11 Plasticizers Plasticizers are organic chemicals that are added to synthetic plastics and resin materials to (1) improve workability during fabrication, (2) extend or modify the natural properties of these materials, or (3) develop new or improved properties not present in the original material. Table 11-1 presents statistics on U.S. production and sales of plasticizers in as great detail as is possible without revealing the operations of individual producers. U.S. production of plasticizers totaled 828 million kilograms in 1991, a decrease of 7.0 percent from the 891 million kilograms reported for 1990. The trend of production of these products is shown in the graph in figure 11-1. Sales of plasticizers totaled 810 million kilograms, valued at $1,052 million in 1991, compared with 827 million kilograms, valued at $967 million in 1990. Production of cyclic plasticizers in 1991, which consisted chiefly of the esters of phthilic anhydride, phosphoric acid, and trimellitic acid, amounted to 604

million kilograms, an decrease of 5.6 percent from the 640 million kilograms reported for 1990. Sales of cyclic plasticizers in 1991 totaled 604 million kilograms. valued at $708 million, compared with 644 million kilograms, valued at $665 million, in 1990. The most important cyclic plasticizers were the dioctyl phthalates, with production of 123 million pounds, in 1991. Production of acyclic plasticizers in 1991 totaled 224 million kilograms, a decrease of 10.7 percent from the 251 million kilograms reported for 1990. Sales of acyclic plasticizers totaled 205 million kilograms, valued at $344 million in 1991, compared with 182 million kilograms, valued at $301 million, in 1990. Epoxidized esters were the most important acyclic plasticizers in 1991 with production of 62 million kilograms. Table 11-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 11-3. Jesse Lawrence Johnson 202-205-3351

Figure 11-1 Plasticizers: U.S. production, 1987-91

Millions of kilograms 1200

1000

0

1987

1988

1989

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Section 11 Table 11-1 Plasticisers: U.S. production and sales, 1991 Sales Productions

Quantity

Value

Average Unit value2

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

827,931

809,927

1,052,464

$1.30

685,480 142,451

677,074 132,853

843,139 209,325

1.25 1.58

604,042

604,433

708,491

1.17

Phthalic anhydride esters, total

546,477

537,728

603,912

1.12

Dibutyl phthalates (including diisobutyl phthalates) Diisodecyl phthalate Dioctyl phthalates4 All other phthalic anhydride esters Trimellitic acid esters All other cyclic plasticizers5

8,506 95,348 122,510 320,113 15,731 41,834

6,450 96,103 125,206 309,969 24,400 42,305

7,945 83,902 115,518 396,547 43,333 61,246

1.23 .87 .92 1.28 1.78 1.45

223,889

205,494

343,973

1.67

56,523

48,651

86,116

1.77

24,343 987 31,193

23,159 1,074 24,418

30,036 1,768 54,312

1.30 1.65 2.22

Complex linear polyesters and polymeric plasticizers

42,013

30,178

65,665

2.18

Epoxidized esters

62,383

66,687

75,445

1.13

535

517

773

1.50

3,380

3,080

16,017

5.20

245 3,135

250 2,830

895 15,122

3.58 5.34

5,145

5,240

8,791

1.68

53,910

51,141

91,166

1.78

Plasticizers

Grand total Benzenoid3 Nonbenzenoid Cyclic Total

Acyclic

Total Adipic acid esters, total Di(2-ethylhexyl) adipate Diisodecyl adipate All other adipic acid esters

Butyl oleate Sebacic acid esters, total Dibutyl sebacate All other sebadc acid esters Stearic acid esters All other acydic plasticizers 6

1 Includes data for compounds used principally (but not exclusively) as primary plasticizers. Does not include clearly defined extenders or secondary plasticizers. 2 Calculated from unrounded figures. 3 Includes benzenoid products as defined in part 1, schedule 4, of the Tariff Schedules of the United States Annotated. 4 The difference between the production reported here and that shown on the Preliminary Report on U.S. Production of Selected Organic Chemicals (including Synthetic Plastics and Resin Materials), 1991, results from a combination of incorrect reporting by some companies, end-of-year inventory adjustments, and rounding. 5 Includes data for cresyl diphenyl phosphate, dibutyl phenyl phosphate, diphenyl octyl phosphate, tricresyl phosphate, triphenyl ~ate, and other cyclic phosphoric acid esters, glycol dibenzoates, toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. 6 Includes data for azelaic acid esters, citric and acetylcitric acid esters, myristic acid esters, pelargonic acid esters, ricinoleic and acetylricinoleic acid esters, glyceryl and glycol esters, and other acyclic plasticizers. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

11-2

Synthetic Organic Chemicals, 1991 Table 11-2 Plasticizers for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Plasticizers

Separate statistics"'

Cyclic plasticizers

Yes

N-n-Butyl benzenesulfonamide Diethylene glycol dibenzoate Dipropanediol dibenzoate (Dipropylene glycol dibenzoate) N-Ethyl-p-toluenesulfonamide Phosphoric acid esters: Isodecyl diphenyl phosphate Tricresyl phosphate Triphenyl phosphate All other phosphoric acid esters Phthalic anhydride esters: Bis(2-ethylhexypterephthlate Butyl benzyl phthalate Butyl octyl phthalates Di (2-butoxyethyl) phthalate Dibutyl phthalate (including diisobutyl phthalate) Dicyclohexyl phthalate Diethylene glycol phthalate Diethyl isophthalate Diethyl phthalate Di-(heptyl, nonyl) phthlate, mixed esters Di-(heptyl, nonyl, undecyl) phthlate, mixed esters Diisodecyi phthalate Diisononyl phthalate Dimethyl isophthalate Di methyl phthalate Di-(nonyl, decyl.undecyl) phthlate, mixed esters Di nonyl phthalate Diphenyl phthalate Di-tridecyl phthalate Diundecyl phthalate Hexyl n-decyl phthalate n-Octyl n-decyl phthalate Dioctyl phthalates: Di(2-ethylhexyl) phthalate Diiso-octyl phthalate All other dioctyl phthalates Glycol phthalate esters: Butyl phthalyl butyl glycolate All other glycol phthalate esters All other phthalic anhydride esters Polyethylene glycol dibenzoate Tetrahydrofuriuryl oleate Trimellitic acid esters: Tri(2-ethylhexyl) trimellitate Tri-n-hekiltrimellitate Triisodecyl trimellitate Triisononyl trimellitate Triiso-octyl trimellitate trimethyl trimellitate Trioctyl trimellitate All other trimellitic acid esters All other cyclic plasticizers

Manufacturers' identification codes (according to list in table 11-3)

No No

UTC. KLM, VEL.

No No No No No No No Yes No No No No Yes No No No No No No Yes No No No No No No No No No No Yes No No No No No No Yes No No Yes No No No No No No No No Yes

KLM, VEL. EPI, UTC. MON. FMC. FMC, MON. FMC, MON, SCP, SM. EKT. MON. ART. ART. ART, EKT NOD, UTC, WTH. UTC, (2). CMB. (2)• EKT, MRF. BAS, ENJ, SC. BAS, SC. ART, ENJ, HCC, MON, NOD, TEK. ART, BAS, ENJ, MRF, TEK. UTC. EKT, MRF, UTC. BAS. BAS, ENJ, SC, TEK. ART ENJ, HCC, NOD, SM, TEK. ART BAS, SC, TEK. VST. ART, VST. ART, BAS, Eta, ENJ, NOD, TEK. ENJ, HAL, HCC, NOD, TEK. WTH. (2).

HAL. BAS, MON, NOD, SC, TEK, WTC. VEL. WTC. BAS, ENJ, TEK. (2).

ENJ, WM. ART, TEK. NOD. FER. ART, EKT. ART BAS, TEK, (2), (2). BOE, NEV, NOD, UTC.

See footnotes at end of table.

11-3

Section 11 Table 11-2—Continued Plasticizers for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Plasticizers Acyclic plasticizers: Adipic acid esters: Butylene glycol adipate Di(2-(2-butoxyethoxy)ethyl) adipate Dibutoxyethyl adipate Di(2-ethylhexyl) adipate

Separate statistics1 Yes Yes No No No Yes

Di-n-hexyl adipate Diisobutyl adipate Diisodecyl adipate Di isononyl adipate Diiso-octyl adipate Diisopropyl adipate Dimethyl adipate Di-n-octyl adipate Di-tridecyl adipate Ethylene glycol adipate Neopentyl glycol adipate All other adipic acid esters Azelaic acid esters: Di(2-ethylhexyl) azelate All other azelaic acid esters Citric and acetylcitric acid esters: Tributyl acetylcitrate Tributyl citrate Triethyl acetylcitrate -Methyl citrate All other citric and acetylcitric acid esters Complex linear polyesters and polymeric plasticizers: Adipic acid type complex linear polyesters and polymeric plasticizers All other complex linear polyesters and polymeric plasticizers

No No Yes No No No No No No No No Yes No No No Yes No No No No No

Epoxidized esters: Epoxidized linseed oils Epoxidized pentaerythritol tetraphthalate Epoxidized soya oils 2-Ethylhexyl epoxytallates All other epoxidized esters Glyceryl tripropionate Glutaric acid esters: Neopentyl glycol glutarate All other glutaric acid esters Lauric acid esters: All other lauric acid esters Myristic acid esters: Isopropyl myristate All other myristic acid esters Octandic aciud esters; 2-Butoxyethyl oleate Oleic acid esters: Butyl oleate Decyl oleate Glyceryl trioleate (Triolein)

Yes No No No No No No No No No No No No No No No No

See footnotes at end of table.

11-4

Manufacturers' identification codes (according to list in table 11-3)

HAL HAL, MON. HAL. ART, CAS, EKT, ENJ, HAL, MON, NOD, TEK, WTH. EKT, MON. HAL, WTC, (2). HAL, HCC, NOD. ART, TEK. HAL, HCC, SM. WTH. MRF. WTH. NOD, WM. HAL. HAL. ENJ, HAL, SCP, SM, WTC. HAL, SCP, TEK. SCP. UTC. (2)• (2) (2.)• CCL, (2).

Yes No

CMB, HAL, SCP, TEK, WTC, WTH.

No

AQU, EKX, HPC, SBC, SCP, SM, TEK, VND, WM, WTC. PAS, UCC, WTC. UCC. FER, FMB, PAS, TEK, UCC, WTC. UCC, WTC, PAS, UCC. EKT. HAL. HAL. HAL CAS, WM, WTH. CAS, WTH. HAL.

Yes No No No

CHL, SCP, WTC, WTH. SBC, VND. SCP, 1NTC.

Synthetic Organic Chemicals, 1991 Table 11-2—Continued Plasticizers for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Acyclic plasticizers-Continued Oleic acid esters-Continued Isobutyl oleate Methyl oleate Oleyl oleate Proply oleates: n-Propyl oleate All other oleic acid esters Palmitic acid esters: n-Butyl palmitate 2-Ethylhexyl palmitate Isobutyl palmitate Isopropyl palmitate All other palmitic acid esters Pelargonic acid esters: Glycol pelargonate Isodecyl pelargonate All other pelargonic acid esters Phosphoric acid esters: Tri(2-butoxyethyl) phosphate Tributyl phosphate Triethyl phosphate Trioctyl phosphate Ricinoleic and acetyiricinoleic acid esters: n-Butyl acetylricinoleate Butyl ricindeate Glyceryl monoricindeate Glyceryl tri(acetylricinoleate) Methyl rianoleate Propylene glycol monoridnoleate All other ricinoleic and acetyiricinoleic acid esters Sebacic acid esters: Dibutoxyethyl sebacate Dibutyl sebacate Di(2-ethylhexyl) sebacate Diisopropyl sebacate Dimethyl sebacate Propylene glycol sebacate All other sebacic acid ester Stearic acid esters: n-Butyl stearate 2-Ethylhexyl stearate Glyceryl triacetyl stearate Hexadecyl stearate Isobutyl stearate Isopropyl stearate Myristyl stearate Tridecyl stearate All other stearic acid esters

Separate statistics Yes Yes No No No No No No No No No No No No

EF FEfE gEEFi FE E Ei gi F FE EE F FE F E EF F EE K

Plasticizers

Manufacturers' identification codes (according to list in table 11.3)

SBC. SCR WTC. SBC. SCP. SCP. EKT. CAS, VND, WM, WTH. WTH. CAS, WM, WTH. SBC. SCP. SCP. SBC, SM, WM. FMC, MON, RDA. FMC. EKT. FMC, RDA. CAS. CAS. CAS. CAS. CAS, SCP. CAS. CAS. HAL HAL, MRF, HAL, TEK SEC, (2). HAL CHL, SCP, WM, WTC, WTH. CAS, HCL, WM. CAS. HCL SCP, WTC, WTH. CAS, WM. VND. WM. CMB, SBC, SM, VND, WM.

See footnotes at end of table.

11-S

Section 11 Table 11-2—Continued Plasticizers for which U.S. production andtor sales were reported, Identified by manufacturer, 1991

Plasticizers Acyclic plasticizers-Continued Stearic acid esters-Continued

Sucrose acetate isobutyrate Tetraethylene glycol di(2-ethylhexanoate) Triethylene glycol di(caprylate-caprate) Triethylene glycol di(2-ethylbutyrate) Triethylene glycol di(2-ethylhexanoate) 2,2,4-Trimethy1-1,3-pentanediol diisobutyrate All other acyclic plasticizers

Separate statisticsi

Manufacturers' identification codes (according to list in table 11-3)

Yes

No No No No No No No Yes

EKT. HAL, UCC, WM. HAL HAL EKT, HAL EKX. HCL, VND, WM.

Chemicals for which separate statistics are r epo rted in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

11 6 -

Synthetic Organic Chemicals, 1991 Table 11-3 Plasticizers: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

AQU ART BAS BOE CAS CCL CHL CMB EK EKT EKX ENJ EPI FER

Aqualon Co Aristech Chemical Corp. BASF Corp. Boehme Filatex, Inc. CasChem, Inc. Catawba-Charlab, Inc. Chemol Co Cambridge Industries Co Eastman Kodak Co • Tennessee Eastman Co. Div. Texas Eastman Co. Div. Exxon Chemical Americas Eagle Picher Industries, Inc. Ferro Corp.' Bedford Chemical Div. Grant Chemical Div. FMC Corp., Chemical Products Group FMC Corp., Nitro Div. C. P. Hall Co. Hatco Chemical Corp. Hoechst Celanese Corp., Sou-Tex Works

HPC KLM MON MRF NEV NOD PAS RDA SBC SC SCP SM TEK UCC

Hercules, Inc. Kalama Chemical, Inc. Monsanto Co. Morflex, Inc. Neville Chemical Co. Huls America, Inc. ELF Atochem North America, Inc. Rhone-Poulenc, Inc. Scher Chemicals, Inc. Sterling Chemical, Inc. Henkel Corp. Mobil Oil Corp. Chemical Products Div. Teknor Apex Co. Union Carbide Corp., Industrial Chemicals Div. Unitex Chemical Corp. Vesicol Chemical Corp. ISP-Van Dyk, Inc. Vista Chemical Co. Inolex Chemical Co. Witco Corp. Union Camp Corp., Chemical Div.

FMB FMC HAL HCC HCL

UTC VEL VND VST WM WTC WTH

Note—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

11-7

Synthetic Organic Chemicals, 1991

Section 12 Surface-Active Agents The surface-active agents included in this report are organic chemicals that reduce the surface tension of water or other solvents and are used chiefly as detergents, dispersing agents, emulsifiers, foaming agents, or wetting agents in either aqueous or nonaqueous systems Waxes and products used chiefly as plasticizers are excluded. Surface-active agents are produced from natural fats and oils, from silvichemicals such as lignin, rosin, and tall oil, and from chemical intermediates derived from coal tar and petroleum. A major part of the output of the bulk chemicals shown in this report is consumed in the form of packaged soaps and detergents for household and industrial use. The remainder is used in the processing of textiles and leather, in ore flotation and oil-drilling operations, and in the manufacture of agricultural sprays, cosmetics, elastomers, foods, lubricants, paint, pharmaceuticals. and many other products. The statistics for production and sales of surface-active agents (table 12-1) are grouped by ionic class and by chemical class and subclass. All quantities are reported in terms of 100-percent organic surface-active ingredients and thus exclude all inorganic salts, water, and other diluents. Sales statistics reflect sales of bulk surface-active agents only; sales of formulated products are excluded. Data for the production of surface-active agents during 1987-91 are shown in figure 12-1. Total U.S. production of surface-active agents in 1991 amounted to 3,379 million kilograms, or 11 percent less than the 3,795 million kilograms reported for 1990. Sales of bulk surface-active agents in 1991 amounted to 2,028 million kilograms, valued at $2,257 million compared with sales in 1990 of 1,930 million kilograms, valued at $2,193 million. In terms of

quantity, sales in 1991 were 5 percent greater than in 1990. Production of anionic surface-active agents in 1991 amounted to 2,223 million kilograms, or 66 percent of the total surfactant output reported for 1991. Sales of anionics in 1991 amounted to 1,064 million kilograms, valued at $779 million. Production of cationic surface-active agents in 1991 amounted to 300 million kilograms, 13 percent less than the 343 million kilograms reported in 1990. Production of nonionic surface-active agents amounted to 842 million kilograms in 1991, 0.4 percent less than the 845 million kilograms reported in 1990. Sales of cationic surface-active agents in 1991 decreased by 2 percent in terms of quantity, but increased by 1 percent in terms of value when compared with sales as reported in 1990. Sales of nonionics in 1991 increased by 3 percent in terms of quantity, but decreased by about 2 percent in terms of value when compared with sales as reported in 1990. The difference between production and sales reflects inventory changes and captive consumption of surface-active agents by synthetic rubber producers, and by manufacturers of cosmetics, packaged detergents, bar soaps, and other formulated consumer products. In some instances the difference may also reflect quantities of surface-active agents used as chemical intermediates, e.g., nonionic alcohol and allcylphenol ethoxylates, which may be converted to anionic surface-active agents by phosphation or sulfation. Table 12-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 12-3. Eric Land 202-205-3349

Section 12 Figure 12-1 Surface-active agents: U.S. production, 1987-91 Billions of kilograms 5

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

12-2

Synthetic Organic Chemicals, 1991 Table 12-1 Surface-active agents: U.S. production and sales, 1991 Sales2 Production1

Quantity

Value

Average Unit value3

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

3,379,162

2,027,823

2,257,046

$1.11

14,633

12,125

31,375

2.59

4,421 284 9,928

3,078 260 8,787

8,056 722 22,597

2.62 2.78 2.57

1,064,222 •

779,180

.73

755,420

235,974

153,148

.65

Amine salts of fatty, rosin, and tall oil acids, Carboxylic acids having amide, ester, or ether linkages Coconut oil acids, potassium salt Coconut oil acids, sodium salt Oleic acid, sodium salt Tall oil acids, potassium salt Tallow acids, sodium salt All other carboxylic acids (and salts thereof)

3,257 7,244 1,755 78,895 96 5,073 260,223 398,877

2,872 6,960 229 4,350 58 1,385 17,187 202,933

4,698 14,104 2,404 4,250 98 691 10,235 116,668

1.64 2.03 10.50 .98 1.68 .50 .60 .57

Phosphoric and polyphosphoric acid esters (and salts thereof), total

32,350

28,138

54,495

1.94

274 1,027 490 1,194 350 408 740

229 999 467 1,219 295 321 585

585 1,494 1,027 1,483 531 604 2,338

2.55 1.49 2.20 1.22 1.80 1.88 3.99

2,556 3,976 658 659 5,366

2,284 3,589 711 645 (4)

5,464 8,695 2,373 1,381 (4)

2.39 2.42 3.34 2.14 (4)

14,652

16,794

28,520

1.70

1,000,655

655,230

341,682

0.52

157,205 2,431 4,258 18 216,334 1,548 292,780 87,816 11,738 34,076 192,451

105,201 1,743 3,937 (4) 24,997 1,531 283,561 87,140 709 29,973 116,438

83,361 5,476 6,073 (4) 40,638 2,715 31,607 29,982 1,167 21,888 118,775

$.79 3.14 1.54 (4) 1.63 1.77 .11 .34 1.65 .73 1.02

Surface-active agents

Grand total

Amphoteric Total (Carboxymethyl)(3-(coconut oil amido)propyl] dimethylammonium hydroxide, inner salt (Mixed alkyl) sulfobetaine All other amphoteric surface active agents

Anionic Total Carboxylic acids (and salts thereof), total

Decyl alcohol, ethoxylated and phosphated Decyl and octyl phosphate Dinonylphenol, ethoxylated and phosphated 2-Ethylhexanol, ethoxylated and phosphated 2-Ethyihexyl phosphate Hexyl phosphate Mixed alkyl phosphate Mixed linear alcohols, ethoxylated and phosphated Nonylphenol, ethoxylated and phosphated 9-Octadecenyl alcohol, ethoxylated and phosphated Phenol, ethoxylated and phosphated Tridecyl alcohol, ethoxylated and phosphated All other phosphoric and polyphosphoric acid esters (and salts thereof) Suffonic acids (and salts thereof), total Dodecylbenzenesulfonic acid Dodecylbenzenesulfonic acid, calcium salt Dodecylbenzenesulfonic acid, isopropylamine salt Dodecylbenzenesulfonic acid, potassium salt Docecylbenzenesulfonic acid, sodium salt Dodecylbenzenesulfonic acid, triethanolamine salt Ugninsulfonic acid, calcium salt Ligninsulfonic acid, sodium salt Tridecylbenzenesuffonic acid, sodium salt Xylenesulfonic acid, sodium salt All other sulfonic acids (and salts thereof)

2,223,007

See footnotes at end of table.

12-3

Section 12 Table 12-1-Continued Surface-active agents: U.S. production and sales, 1991 Sales2 Surface-active agents

Production1

Quantity

Value

Average Unit value3

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

415,629

125,936

195,346

1.55

261 2,199

247 1,744

346 2,446

1.40 1.40

550

395

1,415

3.58

7,578 8,724 49 12,659 1,805 1,746

6,795 5,861 50 12,004 1,083 1,733

19,417 12,813 278 33,930 3,580 3,476

2.86 2.19 5.60 2.83 3.30 2.01

65,966 217 548 303 313,024

(4) 199 516 228 95,081

(4) 661 559 199 116,226

(4) 3.32 1.08 .87 1.22

18,953

18,944

34,509

1.82

299,908

186,928

400,744

2.14

181,231

88,994

178,251

2.11

1,684 1,286 2,217 3,296 443

1,614 535 1,371 527 2,131 1,536 323

3,399 1,358 2,539 1,494 5,412 2,163 1,095

2.11 2.54 1.85 2.84 2.54 $1.41 3.39

768 (4) 2,341 687 2,909 1,412 (4) 895 1,961 1,802 159,530

320 168 2,244 463 1,732 1,227 473 880 1,367 1,214 70,869

2,407 236 3,473 1,606 3,223 2,300 1,241 2,730 3,604 1,669 138,302

7.52 1.40 1.55 3.48 1.86 1.88 2.62 3.10 2.64 1.37 1.95

114,284

97,169

219,984

2.26

818 6,312 366

796 4,519 271

1,734 17,544 1,391

2.18 3.88 5.14

Anionic-Continued Sulfuric acid esters (and salts thereof), totals Butyl oleate, sulfated, sodium salt Castor oil, sulfated, sodium salt Dodecyl alcohol, ethoxylated and sulfated, ammonium salt Dodecyl alcohol, ethoxylated and sulfated, sodium salt Dodecyl sulfate, ammonium salt Dodecyl sulfate, magnesium salt Dodecyl sulfate, sodium salt Dodecyl sulfate, triethanolamine salt 2-Ethylhexyl sulfate sodium salt Mixed linear alcohols, ethoxylated and sulfated, sodium salt Octyl sulfate, sodium salt Tall oil, sulfated, sodium salt Tallow, sulfated, sodium salt All other sulfuric acid esters (and salts thereof) All other anionic surface active agents Cationic Total Amines and amine oxides, total N,N-Bis(2-hydroxyethyl)(tallow alkyl)amine, ethoxylated (Coconut oil alkyl) amine (Coconut oil alkyl)amine, ethoxylated N,N-Dimethylhexadecylamine N,N-Dimethyloctadecylamine (Hydrogenated tallow alkyl)amine 1-(2-Hydroxyethyl)-2-nony1-2-imidazoline 1-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2imidazoline N-Methylbis(coconut oil alkyl)amine Mixed alkyl)amine (Mixed alkyl)amine, ethoxylated (9-Octadecenylamine (9-Octadecenyl)amine, ethoxylated Octadecylamine (Soybean oil alkyl)amine, ethoxylated (Tallow alkyl)amine, ethoxylated N-(Tallow alkyl) trimethylene diamine, ethoxylated All other amines and amines oxides

Quaternary ammonium salts total Benzyl(coconut oil alkypdimethylammanium chloride Benzyldimethyl(mixed alkyl)ammonium chloride Benzyldimethyl octadecyl ammonium chloride See footnotes at end of table.

12-4

Synthetic Organic Chemicals, 1991 Table 12-1-Continued Surface-active agents: U.S. production and sales, 1991 Sales2 Surface-active agents

Cationic-Continued Quaternary ammonium salts-Continued Benzyl(hydrogenated tallow alkyl)dimethylammonium chloride Bis(coconut oil alkyl)dimethylammonium chloride Bis(hydrogenated tallow alkyl)dimethylannonium chloride Hexadecyltrimethylammonium chloride Trimethyl(tallow alkyl)ammonium chloride All other quaternary ammonium salts All other cationic surface-active agents Nonionic Total Carboxylic acid amides, total Coconut oil acids, diethanolamine condensate, amine acid ratio = 2/1 Coconut oil acids, diethanolamine condensate, amine acid ratio = 1/1 Lauric acid, diethanolamine condensate, amine acid ratio = 1/1 Lauric and myristic acids, diethanolamine condensate, amine acid ratio = 1/1 Oleic acid, diethanolamine condensate, amine acid ratio = 2/1 Oleic acid, diethanolamine condensate, amine acid ratio = 1/1 Soybean oil acids, diethanolamine condensate, amine acid ratio =1/1 Stearic acid, diethanolamine condensate amine acid ratio = 1/1 Tall oil acids diethanolamine condensate amine acid ratio = 2/1 Tall oil acids diethanolamine condensate amine acid ratio = 1/1 Tallow acids, diethanolarnine condensate, amine acid ratio = 2/1 All other carboxylic acid amides Carboxylic acid esters, total Anhydrosorbitol monolaurate Anhydrosorbitol mono-oleate Anhydrosorbitol monostearate Castor oil, ethoxylated Diethylene glycol mono-oleate Ethoxylated anhydrosorbitol monolaurate Ethoxylated anhydrosorbitol mono-oleate Ethoxylated anhydrosorbitol monostearate Ethoxylated anhydrosorbitol tristearate Ethoxylated sorbitol monostearate Ethylene glycol distearate Ethylene glycol monostearate Glycerol diester of lard acids

Productionl

Quantity

Value

Average Unit values

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

1,454 1,805

770 1,572

1,693 4,186

2.20 2.66

38,043 806 1,093 63,587

34,692 532 1,045 52,972

55,136 2,337 2,981 132,982

1.59 4.39 2.85 2.51

4,393

765

2,509

3.28

841,614

764,548

1,045,747

1.37

53,646

44,489

70,590

1.59

1,398

1,416

2,385

1.94

11,279

11,313

14,907

1.32

6,621

6,667

7,940

1.19

670

872

1,985

$2.28

73

85

189

2.21

111

63

182

2.88

1,069

2,115

1.98

327

323

554

1.72

548

(4)

(4)

(4)

73

(4)

(4)

(4)

122 32,424

74 22,607

160 40,173

2.16 1.78

155,949

119,417

226,239

1.89

3,590 5,056 8,553 12,371 405 3,337 4,302 4,480 298 88 1,849 1,896 453

2,627 2,705 7,063 10,095 469 2,968 4,225 4,442 252 85 1,954 2,009 (4)

5,215 4,787 11,437 16,290 832 7,626 8,750 9,656 598 201 3,235 3,685 (4)

1.99 1.77 1.62 1.61 1.77 2.57 2.07 2.17 2.37 2.37 1.66 1.83 (4)

See footnotes at end of table.

12-5

Section 12 Table 12-1-Continued Surface-active agents: U.S. production and sales, 1991 Sales2 Surface-active agents

Nonionic-Continued Carboxylic acid esters-Continued Glycerol mono-deate Glycerol monostearate Hydrogenated castor oil, ethoxylated Lanolin, ethoxylated Polyethylene glycol diester of tall oil acids Polyethylene glycol dilaurate Polyethylene glycol dioleate Polyethylene glycol distearate Polyethylene glycol monolaurate Polyethylene glycol mono-oleate Polyethylene glycol monopalmitate Polyethylene glycol monopelargonate Polyethylene glycol monostearate Polyethylene glycol sesquiester of tall oil acids Polyglycerol mono-oleate Tall oil acids, ethoxylated All other carboxylic acid esters Ethers, total Decyl alcohol, ethoxylated Dinonylphenol, ethoxylated Dodecyl alcohol, ethoxylated Dodecylphend, ethoxylated Hexadecyl alcohol, ethoxylated Isodecyl alcohol, ethoxylated Mixed alcohols, ethoxylated (Mixed alkyl)phenol-formaldehyde, alkoxylated Mixed linear alcohols, ethoxylated Mixed linear alcohols, ethoxylated and propoxylated Nonylphenol, ethoxylated Nonylphenol, ethoxylated and propoxylated Nonylphenol-formaldehyde, alkoxylated 9-Octadecenyl alcohol, ethoxylated Octadecyl alcohol ethoxylated Oleyl alcohol, ethoxylated Phenol, ethoxylated Poly(mixed ethylene, propylene) glycol Tridecyl alcohol, ethoxylated Trimethylol propane, alkoxylated All other ether ethers and thioethers All other nonionic surface-active agents

Productions

Quantity

Value

Average Unit value3

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

4,454 4,392 1,414 505 3,884 823 1,662 910 3,786 2,383 111 1,855 3,113

4,305 3.868 1,249 400

7,257 7,368 2,017 946

1.69 1.91 1.62 2.36

758 659 856 3,584 1,956

1,168 1,304 2,764 5,560 3,067

1.54 1.98 3.23 1.55 1.57

330 391 79,258

3,039 473 304 350 58,722

5,278 1,103 945 804 114,346

1.74 2.33 3.11 2.30 1.95

622,562

594,684

735,787

1.24

3,711 1,705 1,146 2,700 668 1,385 821 9,112 313,982

3,579 1,402 961 2,753

6,009 2,768 2,379 5,385

1.68 1.97 2.48 1.96

1,215 732

1,471 809

1.21 1.11

307,589 9

306,774

1.00

13,597 178,422 1,246 2,127 1,484 1,299 728 380 4,312 3,775 1,433 78,529

12,043 176,105 1,318 1,431 1,210 701

20,081 195,210 3,132 1,872 3,431 1,973

1.67 1.11 2.38 1.31 2.83 2.82

1,829 3,048 1,433 77,335

3,880 4,741 3,266 172,606

2.12 1.56 2.28 2.23

9,457

5,958

13,131

2.20

(4)

(4)

(4) (4)

(4)

( 4)

(4)

1 All quantities are given in terms of 100 percent organic surface-active ingredient 2 Sales indude products sold as bulk surface-active agents only. 3 Calculated from unrounded figures. 4 Reported data were accepted in confidence and may not be published, or no data 5 Includes all other anionic surface-active agents.

(4)

(4) (4)

(4)

(4)

(4)

(4)

(4) (4)

(4) (4)

(4)

were reported.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

12-6

Synthetic Organic Chemicals, 1991 Table .12-2 Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents Amphoteric surface-active agents: 1,1-Bis(carboxyrnethyl)-2-undecy1-2-imidazolinium hydroxide, disodium salt 1-Carboxyethy1-1-(2-hydroxyethyl)-2-heptyl-2imidazolinium hydroxide, sodium derivative, sodium salt N42-(Carboxymethylamino)ethyli-N-(2-hydroxyethyl)coconut oil amide, sodium salt Carboxymethy1-3-cocoamidopropyl dimethyl ammonium chloride, sodium salt (Carboxymethyl)[3-(coconut oil amido)propyl]dimethylammonium hydroxide, inner salt (Carboxymethyl)dodecyldimethylammonium hydroxide, inner salt 1-Carboxymethy1-2-heptadecy1-1-(2-hydroxyethyl)-2imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxymethy1-1-(2-hydroxyethyl)-2-heptyl-2imidazoliniumhydroxide, sodium derivative, sodium salt 1-Carboxymethy1-1-(2-hydroxyethyl)-2-nonyl-2imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxymethy1-1-(2-hydroxyethyl)-2-undecyl-2- • imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxymethy1-1-(2-hydroxyethyl)-2-undecyl-2imidazoliniumhydroxide, sodium derivative, sodium , salt Cocoamidoamphoglycinate N-Cocoamido-propyl-N,N-dimethylamine oxide 3-Cocoamidopropy1-2-hydroxy-3-sulfopropyldimethyl ammonium hydroxide, inner salt Cocoamphocarboxyglycinate Cocoamphocarboxypropionate Cocoarrphopropionate 3-[(Coconut oil alkyl)amidoethylene-(2-hydriuyethyl)aminojpropionic acid N,N-di(hydroxyethyl)-n-carboxymethyl tallow ammonium quat, inner salt • N,N-Dihydroxyethyl tallow glycinate N-Dodecy1-3-iminodipropionic acid, disodium salt N-Dodecy1-3-imino-dipropionic acid, monosodium salt 1-Hydroxyethy1-1-(2-hydroxy-3-sodiumsulfonatopropyl)2-norcutilfayds-2mzolinu hydroxide 1-Hydroxyethy1-1-(2-hydroxy-3-sodiumsulionatopropyl-2oley1-2-imidazolinium hydroxide 1-(2-Hydroxyethyl)-2-undecy1-3carboxyethylimidazoline,sodium salt Isodecyloxypropyliminopropionic acid, monosodium salt Isonanylamidocaproic acid, triethanolamine salt Isostearic amphopropionate Laurylamidopropyl betaine Laurylamphoglycinate (Mixed alkyl)sulfobetaine

Separate Manufacturers' identification codes statistics1 (according to list in table 12-3)

No

PCI.

No

RDA.

No

ETC.

No

ENJ.

Yes

BRD, PPG, RDA, SBC, SCP, SHX, WM, WTC, (2).

No

RDA.

No

RDA.

No '

RDA.

• No

RDA.

No

RDA.

No No No

RDA. MOA. MOA.

No No No No

SHX. MOA. MOA. MOA.

No

RDA.

No •No No No

SHX. MOA. MOA, RDA, SCP. RDA.

No

RDA.

No

RDA.

No

RDA.

No No No No No Yes

ENJ. RDA. MOA. MOA. MOA. BRD, MOA, SBC, WTC, (2).

See footnotes at end of table.

12-7

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics (according to list In table 12-3)

Amphoteric-Continued Oleamidopropyl betaine Oleyl betaine 1-(Sodium carboxyrnethyl)-1-(sodium carboxymetbyleneoxyethylene)-2-noricoconut oil fatty acids)-2-imidazolinium lauryl sulfate N-(Tallow alkyl)-3-iminodipropionic acid, disodium salt Tridecyloxypoly(ethyleneoxy)propionic acid, potassium salt All other acyclic amphoteric surface-active agents All other cyclic amphoteric surface-active agents

No No

RDA. RDA.

No

RDA.

No

MOA, RDA, SCP.

No No No

MRV. BRD, DUP, ENJ, MOA, RDA, SCP. BRD, SBC.

No No No No No No No No No No No No No No No

RDA, SHX. SBP. SCP.

No

BRD, WVA, (2).

No

RDA

No No No

DJ, HMP.

No No No

RDA. HMP. HMP.

No

glP.

No

BRI.

No

RDA.

Anionic Carboxylic acids (and salts thereof): Amine salts of fatty, rosin, and tall oil acids: Coconut oil acids. diethanolamine salt Coconut oil acids, ethanolamine salt Coconut oil acids, triethanolamine salt Isostearic acid, mixed isopropanolamines salt Isostearic acid, triethanolamine salt Oleic acid, diethanolamine salt Oleic acid, mixed isopropanolamine salt Oleic acid, morpholine salt Oleic acid, triethanolamine salt Rosin acids, triethanolamine salt Stearic acid, triethanolamine salt Tall oil acids, diethanolamine salt (Condensate) (Tall oil fatty acids), triethanolamine salt Tallow acids, diethanolamine salt Tallow acids, triethanolamine salt All other amine salts of fatty, rosin, and tall oil acids Carboxylic acids having amide, ester, or ether linkages: Butoxyethylene oxyacetic acid, sodium salt 5(or 6)-Carboxy-4-hexy1-2-cyclohexene-1-octanoic acid, reaction products with castor oil N-(Coconut oil acyl)sarcosine, sodium salt N,N-Dimethyl capramide Dodecyloxypoly(ethyleneoxy)acetic acid, sodium salt N-Lauroylsarcosine, sodium salt N-(Mixed alkylsulfonyl)glycine, sodium salt Mixed(secondary linear alcohol)polyethylene propronic acid, sodium salt Naphthenic acid, ethoxylated Nonylphenol poly(ethyleneoxy)acetic acid, sodium salt Poly(oxy-1,2-ethanediy1), w-(2-carboxyethoxy)-w'hydroxy-a, a'-(iminodi-2, 1-ethanedryl) bis-,Ntallow alkyl dens., potassium salt Tridecyloxypoly(ethyleneoxy)acetic acid, sodium salt carboxylic acids with amide, ester or ether linkage Potassium and sodium salts of fatty, rosin, and tall oil acids: Alkoxy triacryl titanate 5(or 6)carboxy-4-hexy1-2-cyclohexene-1-octanoic acid, potassium/sodium salts See footnotes at end of table. 12-8

RDA.

um, (2). C. BRD, PCI, SBP. RDA, WPG. PNX, WPG. SBP. CPC, ENJ, SBP, (2).

PEL

No

Frx. S.

No

BRD, PCI, WM.

No

KPI.

No

(2).

Synthetic Organic Chemicals, 1991 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' Identification codes statisticsi (according to list in table 12-3)

Anionic-Continued Carboxylic acids (and salts thereof)-Continued Potassium and sodium salts of fatty, rosin, and tall oil acids-Continued Castor oil acids, potassium salt Castor oil acids, sodium salt Coconut oil acids and oleic acid, potassium salt Coconut oil adds, potassium salt

No No No Yes

Coconut oil adds, sodium salt

Yes

Corn oil acids, potassium salt Corn oil acids, sodium salt Gluconic acid, potassium and sodium salts W/20% mix of sodium bisulfite-formaldehyde Heptanoic acid, potassium salt lsostearic acid, isoproxy titanium salt Lauric acid, potassium salt Mixed vegetable fatty acids, potassium salt Mixed wool grease and tall oil fatty acids Neoalkoxy, trineodecanoyl titanate Neoalkoxy, trineodecanoyl zirconate Oleic add, potassium salt Oleic add, sodium salt Olive oil acids, potassium salt Palm oil acids, sodium salt Rosin acids, potassium salt Rosin acids, sodium salt Stearic acid, ammonium salt Stearic acid, potassium salt Stearic acid, sodium salt Tall oil acids, potassium salt

No No

Tall oil acids, sodium salt Tallow acids, potassium salt Tallow acids, sodium salt

No No Yes

Potassium and sodium salts of fatty rosin, and oil acids Other carboxylic acids: All other carboxylic acids Phosphoric and polyphosphoric acid esters (and salts thereof): Alcohols and phenols, alkoxylated and phosphated: Butyl alcohol, ethoxylated and phosphated Decyl alcohol, ethoxylated and phosphated Dinonylphenol, ethoxylated and phosphated Dodecyl alcohol, ethoxylated and phosphated Dodecylphenol, ethoxylated and phosphated 2-Ethylhexanol and ethoxylated nonylphenol, polyphosphated 2-Ethylhe xanol and ethoxylated nonylphenol, polyphosphated, sodium salt 2-Ethylhexanol, ethoxylated and phosphated 2-Ethylhexanol, ethoxylated, phosphated, potassium salt Hexylalcohol, ethoxylated and phosphated Isopentyl alcohol, ethoxylated and phosphated Lauryl alcohol, ethoxylated and phosphated

No No No No No No No No No Yes No No No No No No No Yes

GRL. DEX, LEA. HCL CON, ESS, GRL, HEW, HNT, JTM, NMC, PG, PNX. AGP, BSW, CON, CP, ENJ, HEW, LEV, NMC, PG, PNX, (2). HNT, MCP. NMC. HCL.

I. PG. CRT, GRL. SLM. KPI. KPI. BSW, PG, WBG, (2). BSW, HNT, NMC, SCP, WBG. HNT. AGP, BSW, CON, HEW, PG. ARZ, ECC, WVA, (2). ARZ, SLM, (2). BSW. CON, SCP. HEW, JTM, LEV, PNX. CON, DAN, ESS, FER, HNT, JTM, LEA, PNX, SBP, SCP, WVA NMC, PG, WVA, CRT, PG. AGP, BSW, CON, CP, HEW, LEV, NMC, PG, (2).

No

ECC, GAF, PG, SCP, WVA.

No

ARZ, BRD, BRI, MOA, SCP, TX, USR, WVA.

No Yes Yes No No

RDA. MCP, OC, RDA, VKR. CPC, ETC, GAF, RDA, WTC. CPC, ENJ, GAF, HCL, RDA, VKR. DEX, GAF, RDA.

No

CCC.

No Yes

CCC. BRD, CPC, ETC, PPG, SCP, SDC, WIC.

No No No No

BRI. RDA. RDA. RDA.

See footnotes at end of table.

12-9

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistic& (according to list in table 12-3)

Anionic-Continued Phosphoric and polyphosphoric acid esters (and salts thereof)-Continued Alcohols and phenols, alkoxylated and phosphated -Continued Mixed linear alcohols, alkoxylated and phosphated, potassium salt No Mixed linear alcohols, ethoxylated and phosphated Yes Mixed linear alcohols, ethoxylated and phosphated, sodium salt Nonylphenol, ethoxylated and phosphated

No Yes

Nonylphenol, ethoxylated and phosphated, diethanolamine salt No Nonylphenol, ethoxylated and phosphated, sodium salt No 9-Octadecenyl alcohol, ethoxylated and phosphated Yes Octylphenol, ethoxylated and phosphated No Phenol, ethoxylated and phosphated Yes Polyhydric alcohol, ethoxylated and phosphated No Polypropylene glycol, phosphated No Tridecyl alchol, ethoxylated and phosphated, polyalkylene polyamine salt No Tridecyl alcohol, ethoxylated and phosphated Yes Tridecyl alcohol ethoxylated and phosphated, potassium salt Tridecylphenol, ethoxylated and phosphated All other alcohols and phenols, alkoxylated and phospated or polyphosphated Alcohols, phosphated or polyphosphated: Butyl phosphate Butyl phosphate, potassium salt Decyl and octyl phosphate Decyl polyphosphate, sodium salt 1,2 Ethanediol phosphate Ethanol, 2,2',2"-nitrilotris-tns(dihydrogen phosphate)ester, disodium salt Ethyl alcohol, phosphated, amine salt 2-Ethylhexyl phosphate 2-Ethylhexylphosphate, potassium salt 2-Ethylhexyl phosphate, sodium salt 2-Ethylhexyl polyphosphate, sodium salt Hexadecyldiphosphate Hexadecylmonophosphate Hexyl phosphate Hexyl phosphate, potassium salt Isooctyl phosphate Isooctyl phosphate, potassium salt Isopropyl phosphate Methylbutyl pyrophosphate, ethylenedioxy titanium salt Mixed alkyl phoshate, sodium salt Mixed alkyl phosphate Mixed alkyl phosphate, alkylamine salt Mixed alkyl phosphate, diethanolamine salt Mixed alkyl phosphate, potassium salt

See footnotes at end of table. 12-10

PCI. BAS, CRD, CRT, EFH, ENJ, ESS, ETC, FER, GAF, HCL, HRT, MOA, MRV, RDA, TMH, WTC, (2). CHP. ARL, BRD, CPC, DEX, ESS, ETC, GAF, GDC, OMC. WTC. ETC, GAF, HCL, RDA, WTC. RDA, WTC. ETC, HDG, MOA, PPG, WTC. ETC, RDA. BAS, TMH.

al), CPC, DAN, DEX, ETC, GAF, MIL, RDA, VKR, WTC.

No No

DEX. TCC.

No

ETC, GAF, RDA, SCP, TCC.

No No Yes No No

HRT, TCC. DUP. ENJ, ETC, HCL, SCP. CRD. (2).

No No Yes No No No No No Yes No No No No No No Yes No No No

(jilt. CHP, ETC, FER, OC, OMC, RDA, SOS. PCI. CHP, DAN, ENJ, PAT, S. DEX, GAF. C, HCL, ICI. ICI. BRI, QCP. QCP. TCC. KPI. gbP, HCL, WTC, (2). gt1P. QCP.

Synthetic. Organic Chemicals, 1991 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 12-3)

Anionic-Continued Phosphoric and polyphosphoric acid esters (and salts thereof)-Continued Alcohols, phosphated or polyphosphated-Continued Mixed alkyl phosphate, triethanolanine salt No Neoalkoxy tris(dioctyl) pyrophosphato zirconate No Octy diphosphate, oxoethylene titanium salt No Octy phosphate No Octy phosphate, alkylamine salt No Octy phosphate, isoproxy titanium salt No Octy phosphate neoalkoxy titanium salt No Octy polyphosphate No Octy polyphosphate, potassium salt No Octy pyrophosphate, ethylenedioxy titanium salt No Qcty pyrophosphate, isoproxy titanium salt No Octy pyrophosphate neoalkoxy titanium salt No Octy pyrophosphate, oxoethylenedioxy titanium salt No N-2(C-5 to C-17)alkylamido-N-carboxyethyl,N-2hydroxyetmyl, 3-amino-2-mydroxypropyl phosphate, disodium salt No Tridecyl phosphate No All other phosphated and polyphosphated alcohols , No Other phosphoric and polyphosphoric acid esters: Blend of fatty and phosphate esters No Glycerol, ethoxylated and phosphated No Glycerol monoester of mixed fatty acids, • phosphated No Octadeclyamine, ethoxylated and phosphated, . sodium salt No All other phosphoric and polyphosphoric acid esters No Sulfonic acids (and salts thereof): Alkylbenzenesulfonates: Dodecylbenzenesulfonates: • Dodecylbenzenesulfonic acid Yes Dodecylbenzenesulfonic acid, (Mixed alkypamine salt No Dodecylbenzenesulfonic acid, ammonium salt No Dodecylbenzenesulfonic acid, calcium•aft Yes Dodecylbenzenesulfonic acid, diethanolamine salt No Dodecylbenzene sulfonic acid, DMAP salt No Dodecylbenzenesulfonic acid, isopropanolamine salt Yes Dodecylbenzenesulfonic acid, isopropylamine salt No

(2). KPI. KPI. ENJ, GAF. KPI. DEX. DEX: KPI. KPI. KPI. KPI. MOA. HCL. ETC, SOS. MIL (2).



WC. GDC. BRD, ENJ, SCP, WTC.

ENJ, JLP, LEV, NPR, PIL, SCP, STP, TEN, VST, WIC, (2). JLP, TMH, (2). (2).

I

(2.

HCL ICI, CI, RH, STP, TMH, WTC, (2). RDA. WTC. PIL ECC, ICI, KPI, NES, PPG, RDA, STP,

wrC,

(2).

Dodecylbenzenesulfonic acid, monoethanolamine salt Dodecylbenzenesulfonic acid, potassium salt Dodecylbenzenesulfonic acid, sodium salt

No Yes Yes

Dodecylbenzenesulfonic acid, triethanolamine salt

ESS, PCI. BRI, ESS, LEA, (2). BLA, BOE, BRI, CP, CPC, DOW, ECC, JTM, LEA, LEV, NES, PCI, PG, PILL PNX, RDA, STP, TEN, VST, WTC, (2).

Yes

BRD, BRI, CCC, CPC, ESS, NES, PCI, PPG, RDA, SCP, STP, WTC, (2).

See footnotes at end of table. 12-11

Section 12 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identifiCation codes statistics1 (according to list in table 12-3)

Anionic-Continued Suffonic acids (and salts thereof)-Continued Alkylbenzenesulfonates-Continued Dodecylbenesulfonates—Continued Other alkylbenzenesulfonates-Continued

See footnotes at end of table.

12-12

No

BAS, ENJ, PG.

No

WTC.

No No

DIJ.

No No

I.

DP

Yes

BI.A, CMT, CP, CPC, STR

No No No No No No No Yes

NES, SIR NES, STP. NES. NES, PG, VST. WTC. NES, STP. DUP. ICI, NES, PIL, SDC, STP, WTC.

f

All other dodecylbenzene sulfonates Other alkylbenzenesulfonates: Benzene sulfonic acid 2,4-Didodecylbenzenesulfonic acid, ammonium salt Didod lbenzenesulfonic acid, sodium salt [Monoi io-ilalkyl derivatives]benzenesulfonic acid, ammonium salt Neoalkoxy, dodecylbenzene-suffonyl titanate Oxirane, methyl-, polymer with oxirane, didodecyibenzenesulfonate Tridecylbenzenesulfonic acid Tridecylbenzenesulfonic acid, sodium salt Benzene-, cumene-, toluene-, and xylenesulfonates: Cumenesulfonic acid, ammonium salt Cumenesulfonic acid, sodium salt Toluenesulfonic acid, potassium salt Toluenesulfonic acid, sodium salt Toluene xylene sulfonic acid Xylenesulfonic acid, ammonium salt Xylenesulfonic acid, potassium salt Xylenesulfonic acid, sodium salt All other benzene-, cumene-, toluene-, and xylenesulfonates Ligninsuifonates: Ligninsulfonic acid, aluminum salt Ugninsulfonic acid, ammonium salt Ligninsulfonic acid, calcium salt Ugninsulfonic acid, chromium salt Ligninsulfonic acid, iron salt Ligninsulfonic acid, manganese salt Ligninsulfonic acid, mixed chromium and iron salts Ligninsulfonic acid, mixed salt Ugninsulfonic acid, sodium salt Ugninsulfonic acid, zinc salt All other ligninsulfates Naphthalenesulfonates: Butylnaphthalenesulfonic acid Butylnaphthalenesulfonic acid, sodium salt Di(C5-C6 alkyl)naphthalenesulfonic acid Diisopropylnaphthalenesulfonic acid, sodium salt Methylnaphthalenesulfonic acid, sodium salt Naphthalenesulfonic acid, bis(1-rnethylethyI)-, compounded with cyclohexanarnine (1:1) Naphthalene sulfonic acid, sodium sat formaldehyde condensate All other naphthalenesulfonates Sulfonic acids having amide linkages: Sulfosuccinamic acid derivatives: N-[Coconut oil alkyl]sulfosuccinamic and disodium salt N-(1,2-Dicarboxyethyp-Noctadecylsulfosuccinamic acid, tetrasodium salt

SCP.

No No Yes No No No

DUP. MAR, PSP, RAY. FPC, MAR, PSP. PSP, RAY. MAR, PSP, MAR.

No No Yes No No

PSP. LKY. ENJ, MAR, PSP. RAY, WVA. MAR, PSP. ETC.

No No No No No

DUP. ECC, SCP.

No

(2).

No No

ICI. HAL, SCP, WTC.

No

WPG.

No

ACY, DUP, MOA.

DUP, SCP. CPC, SCR

Synthetic Organic Chemicals, 1991 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistic& (according to list in table 12-3)

Anionic-Continued Sulfonic acids (and salts thereof)-Continued Sulfonic acids having amide linkages-Cont. Sulfosuccinamic acid derivatives-Cont. N-Octadecylsutfosuccinamic acid, disodium salt Oleamidosuffosuccinamic acid, disodium salt N-(Oleoyloxyisoprooypsulfosuccinamic acid All other sulfosuccinamic add derivatives Taurine derivatives: N-(Coconut oil acy1)-N-methyltaurine, sodium salt N-Methyl-N-oleoyltaurine, sodium salt N-Methyl-N-(tall oil acyl)taurine, sodium salt All other sulfonic acids having amide linkages: All other sulfonic acids having amide linkages Sulfonic acids having ester or ether linkages: Sulfosuccinic add esters: Sulfosucdnic add, bis(diisobutyl)ester, amidodisodium salt Sulfosuccinic acid, bis(2,6-dimethy1-4-hepty1)ester, sodium salt Sulfosucdnic acid, bis(2-ethylhexyl)ester, sodium salt Sulfosuccinic acid, dihexyl ester, sodium salt Sulfosuccinic acid, diisodecyl ester, sodium salt Sulfosuccinic acid, diisooctyl ester, sodium salt Sulfosuccinic acid, dioctyl ester, sodium salt Sulfosucdnic acid, dipentyl ester, sodium salt Sutfosuccinic acid, ditridecyl ester, sodium salt Sulfosuccinic acid, (lauryl polyethylene glycol ether) ester, disodium salt Sulfosucdnic acid, (coconut oil alkyI)iminoisopropanol half-ester, sodium salt Suffosucanic acid, lauramidomonoethanolamine, disodium salt Sulfosuccinic acid, monolaureth ester, disodium salt Sulfosuccinic acid myristyl ester disodium monoethanolamine salt Suffosuccinic acid, oleamidopolyethyleneglycol, disodium salt All other sulfosuccinic add esters All other sulfonic acids having ester or ether linkages: Coconut oil adds, 2-sulfoethyl ester, sodium salt Dodecyldiphenyloxidedisulfonic add Dodecyldiphenyloxidedisulfonic add, disodium salt n-Octylphenol, ethoxylated and sutfonated, sodium salt All other sulfonic acid with ester linkages All other sulfonic acids with ether linkages

No No No No

ACY, HIP. SBC. WTC. DUP, SCP.

No No No

FTX, RDA. CPC, FTX, HCL, RDA. CCC, DUP, FTX, RDA, MA.

No

HCL

No

MOA.

No

MOA, NSC.

No No

ACY, AMU, APX, BRI, CCC, CHP, ECC, ENJ, FTX, HCL, MCP, MOA, WPG, WTC. ACY, FTX, MOA.

No

FTX.

No No No

ARI, MIL SCP, SHX. MOA. ACY.

No

ACY, MOA.

No

SHX.

No

MOA.

No

RDA.

No

MOA, RDA.

No

WTC.

No No

MOA. FTX, MOA, RDA, SCP, WTC.

No No

FIX, LEV. (2).

No

PIL, RDA, (2).

No No No

APX. GAF. PG, PPG.

See footnotes at end of table.

12.13

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics1 (according to list In table 12-3)

Anionic-Continued Sulfonic acids (and salts thereof)-Continued Sulfonic acids having ester or ether linkages-Cont. Other sulfonic acids: All)/ sulfonate, sodium salt Mixed alkane sulfonic acid, sodium salt Mixed linear olefin sulfonate n-Octanesulfonic acid, sodium salt Oleyloxyethyldiamide oxypropanol sulfonic acid Petroleumsulfonic acid, water soluble (Acid layer), sodium salt All other sulfonic acids Sulfuric acid esters (and salts thereof): Acids, amides, and esters, sulfated: Coconut oil acids-ethanolamine salt, sulfated, potassium salt Mixed alkyl phenol sulfate, ethoxylated, triethandamine salt Carboxylic acid esters (except natural fats and oils), sulfated: Esters of sulfated oleic acid: Butyl deate, sulfated, sodium salt Isopropyl oleate, sulfated, sodium salt Methyl deate, sulfated, sodium salt Oleic acid, sulfated Propyl deate, sulfated, sodium salt All other esters of sulfated oleic acid Other sulfated esters: Tall oil acids, sulfated, sodium salt Alcohols, sulfated: Decyl and octyl sulfate, sodium salt Decyl sulfate, sodium salt Dodecylsulfate salts: Dodecyl sulfate, ammonium salt Dodecyl sulfate, diethanolamine salt Dodecyl sulfate, N,N-diethylcydohexylamine salt Dodecyl sulfate, magnesium salt Dodecyl sulfate, sodium salt Dodecyl sulfate, triethanolamine salt 3,9-Diethyl-6-tridecyl sulfate, sodium salt 2-Ethylhexyl sulfate, sodium salt 7-Ethyl-2-methyl-4-undecyl sulfate, sodium salt Hexadecyl sulfate, sodium salt Hexyl sulfate, potassium salt All other linear alcohols, sulfated Mixed linear alcohols, sulfated, ammonium salt Mixed linear alcohols, sulfated, diethanolamine salt Mixed linear alcohols, sulfated, sodium salt Mixed linear alcohols, sulfated, triethanolamine salt Octyl sulfate, sodium salt Oleyl sulfate, sodium salt Oxoalcohol bottoms, sulfated, sodium salt Tridecyl sulfate, sodium salt All other alcohols and phenols, sulfated See footnotes at end of table.

12-14

No No No No No

ARD. STP, WTC. RDA, STP, WVA.

No No

PIL CLU, HAL

No

ENJ.

No

MIL

Yes No No No No No

ICI, MCP, MRV, NSC. DEX. ICI. ACT. MRV. SCP.

No

ICI.

No No

DUP, STP, WTC. ARI, SCP.

Yes No

BRD, LEV, RDA, SCP, SIP, TN!. BRD, DUP, STP.

No Yes Yes Yes No Yes No No No No No

DUP. BRD, RDA, STP. BRD, DUP, RDA, SCP, SW. BRD, RDA, SCP, TNI. NCC. NCC, PCI, RDA, SCP, WTC. NCC. RDA, STP. DEX. BRD, PG, RDA, SCP. CP, S, SCP, WTC, (2).

No No

WTC. CP, DUP, PG, SCP, WTC.

No Yes No No No No

SCP, WTC. ARC, DUP, RDA, SCP, WTC. DUP, RDA. WVA. RDA. BRD, RDA.

Synthetic Organic Chemicals, 1991 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics1 (according to list in table 12-3)

Anionic-Continued Sulfuric acid esters (and salts thereof)-Continued Alcohols, sulfated-Continued Ethers, sulfated: Ally!phenols, ethoxylated and sulfated: 1-Naphthol, ethoxylated and sulfated, free acid Nonylphenol, ethoxylated and sulfated, ammonium salt Octylphenol, ethoxylated and sulfated, sodium salt All other sulfated cyclic ethers Dodecyl alcohol, ethoxylated and sulfated, ammonium salt Dodecyl alcohol, ethoxylated and sulfated, sodium salt Dodecyl and tetradecyl alcohols, ethoxylated and sulfated, ammonium salt 2-Hexyloxypropyl sulfate, sodium salt Isobutanol, ethoxylated and sulfated, ammonium salt Mixed linear alcohols, ethoxylated and sulfated, ammonium salt Mixed linear alcohols, ethoxylated and sulfated, sodium salt Tridecyl alcohol, ethoxylated and sulfated, sodium salt All other sulfated ethers Natural fats and oils, sulfated: Castor oil, sulfated, sodium salt Coconut oil, sulfated, sodium salt Cod oil, sulfated, sodium salt Cod oil, sulfated, sodium salt Grease, other than wool, sulfated, sodium salt Herring oil, sulfated Herring oil, sulfated, sodium salt Hydrogenated marine glycerides, sulfated, sodium salt Lard, sulfated, sodium salt Mixed animal and vegetable oil, sulfated, sodium salt Mixed fish oils, sulfated, ammonium salt Mixed fish oils, sulfated, sodium salt Mixed vegetable oils, sulfated, sodium salt Mixed vegetable oils, sulfated, sodium salt Neat's foot oil, sulfated, sodium salt Soybean oil, sulfated, sodium salt All other sulfated animal fats and oils All other sulfated fish and marine fat oils Synthetic fatty alcohol ester, sulfated, sodium salt Tall oil, sulfated, ammonia salt Tall oil, sulfated, sodium salt Tallow, sulfated, sodium salt All other vegetable oils, sulfated All other sulfuric acid esters Other anionic surface-active agents: Lignin, sodium salt

No

SCP.

No

GAF, RDA, STP.

No No

RDA, STP. BRD, RDA, SCP, WTC.

Yes

BRD, MOA, RDA, SCP, TNI.

Yes

BRD, RDA, SCP.

No No No

(2)-

No

PG, RDA, SCP, STP, VST, WTC, (2).

Yes

DUP, PG, PIL, RDA, SCP, SW, VST, WTC, WVA.

No No

BRD, RDA. BRD.

Yes No No No No No No

ACT, ACY, ARI, ARL, CRT, DEX, HIP, LEA, MRV, S, SCP, SLM, WHW. WHW. ARI. WHW. WHW. SLM. ARI, SLM, WHW.

No No

CRT. CIN, CRT, DUP, WHW.

No No No No No No No No No

SLM. CIN. CRT, SLM, WHW. CRT. CPC. ARI, WHW. ACT, SCP, WHW. WHW. WHW.

No No Yes Yes No No

SLM. CIN. ACT, ARI, CIN, CRT, WHW, WTC. ARI, CCC, CRT, NSC, WHW. CRT, SCP. BRD, SCP.

No

WVA.

See footnotes at end of table.

12-15

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics1 (according to list in table 12-3)

Anionic-Continued Sulfuric acid ester (and salt thereof)-Continued Mixed alpha-olefins and vegetable Mixed linear alcohols, ethoxylated and carbonated, sodium salt Nonylphenol, ethoxylated and carbonated, sodium salt Stearoyl isolactyiate Stearoyl iso-lactylate, sodium salt Stearoyl-2 lactylate, calcium salt Stearoyl lactylate, mixed sodium and calcium salt Stearoyl lactylate, sodium salt Tridecyl alcohol, ethoxylated and carbonated, sodium salt All other anionic surface-active agents Cationic surface-active agents: Amine oxides and oxygen-containing amines (except those having amide linkages):

No

SLM.

No

S.

No No No No No No

WTC. BFP. BFP. BFP. BFP. BFP.

No No

S. DUP, MOA, WVA.

No

ENJ.

No No No Yes No Yes

ENJ . ARC, SHX. ARC, ENJ, HCL, JTO, SHX.

No

SVC, WTC, (2). PG, (2).

No No No No No No

D, PPG, SCP. ARC, PPG. S.

No No No No No

KPI. DUP, ENJ. ENJ, ETC, SHX, WTC.

No

(2).

No No No No No No No No No No Yes No No

ENJ. SHX. ENJ. KPI. ENJ. ENJ. SHX. SHX. BRD, ICI. KPI. KPI.

Acyclic: 3-(C12-15 alkyloxy)-1-propanamine Amides from C-18 unsaturated fatty acid dimers and polyhexamethyienepolyamines, ethoxylated Bis-(2-hydroxyethyl)isodecyloxypropylamine oxide N,N-Bis(2-hydroxyethyl)octadecylamine N,N-Bis(2-hydroxyethyl)(tallow alkyl)amine Cocoamidopropyl dimethyl amine (Coconut oil alkyl)amine, ethoxylated (Coconut oil alkyl)amine, ethoxylated, acetate Coconut oil(alkyl)amine, ethoxylated and phosphated Diethylenetriamine, alkoxylated N,N-Dimethyldecylamine oxide N,N-Dimethyldodecylamine oxide N,N-Dimethylhexadecylamine oxide N,N-Dimethyl(mixed alkyl)amine oxide 1,2-Ethanediamine, N-(2-aminoethyl)-, ethoxylated and propoxylated Ethylenediamine, alkoxylated Ethylene diamine ethoxiated Hexyloxypropyl amine (Hydrogenated tallow alkyl)amine, ethoxylated N-(2-Hydroxyethyl)-N,N',N'-tris(2-hydroxypropy1)ethylenediamine 2-Imidazoline-1-(2-aminoethyl)-2-(tall oil alkyl), ethoxylated Isodecyloxypropylamine lsodecyloxyprcpylamine, ethoxylated 3-(3-Isodecyloxy)propylaminopropyl amine N-Isodecyloxypropyl trimethylene diamine Isopropoxy-tns(2-ethylenediamino)ethyl titanate Isotridecyloxypropylamine N-Isotridecyloxypropyl trimethylene diamine 3-(Mixed alkoxy)propylamine, ethoxylated oxides 3-(3-Mixed alkoMpropylaminopropyl amine (Mixed alkyl)amine, ethoxylated Neoalkoxy, tri(m-amino)-phenyl titanate Neoalkoxy, tris(m-amino) phenyl zirconate

See footnotes at end of table.

12-16

AR C, BAS, ENJ, ETC, ICI, PPG, SHX,

Synthetic Organic Chemicals, 1991 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' Identification codes statistics1 (according to list in table 12-3)

Cationic-Continued Amine oxides and oxygen-containing amines (except those having amide linkages)-Continued Acyclic-Continued Neoalkoxy, tris (ethylene diamino) zirconate (9-Octadecenyl)amine, ethoxylated Octadecylamine, ethoxylated Octyldimethylamine oxide Polyalkylene polyamine, ethoxylated (Soybean oil alkyl)amine, ethoxylated

No Yes No No No Yes

(Tallow alkyl)amine, ethoxylated

Yes

(Tallow alkyl)amine, propoxylated N-(Tallow alkyl)trimethylenediamine, ethoxylated [Tallow ethyl alkyl)amine, ethoxylated, sulfate N,N,N',N'-Tetrakis(2-Hydroxyethyl)ethylenediamine, propoxylated N,N,N,N'-Tetrakis(2-hydroxypropy1)ethylenediamine, propoxylated and ethoxylated 3-(3-Tridecyloxy)propylaminopropyl amine Tridecyl-3-(trimethyleneamine), ethoxylated Triethanolamine, ethoxylated Triethanolamine phosphate ester Amine oxides and oxygen-containing amines (except those with amide linkages), acydic

No Yes No

KPI. ARC, ETC, GAF, RDA, SHX, WTC, (2). ARC, ETC, WTC. HNT. BAS. ARC, ENJ, ETC, JTO, RDA, SHX, SVC, . (2). An, BAS, ENJ, HCL, PPG, S, SCP, SHX, WT C, (2). SHX. ARC, ENJ, ETC, JTO, (2). RDA.

No

HCL.

No No No No No

BAS, ETC. SHX. JTO. MIL RSA, SCP.

No

ARC, BRD, ENJ, ETC, MOA, PG, RDA, SCP, SHX, TNA, (2).

(2).

Cyclic: Aniline, ethoxylated No 2-Butenedioic acid-41;)-diamine - 1-(2-aminoethyl)2-(tall oil alkyl)-2-imidazoline condensate No 2,5-Dimethoxyaniline, ethoxylated No N-Hexadecylmorpholine No N-(2-Hydroxyethyl)-1,2-diphenylethylenediamine No 1-(2-Hydroxyethyl)-2-nony1-2-imidazoline Yes 1-(2-Hydroxyethyl)-2-nor(coconut oil alkyl)-2imidazoline Yes 1-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2imidazoline No 1-(2-Hydroxyethyl)-2-(tall oil alkyl)imidazoline, fatty add salt No Lignin amine No Rosin amine, ethoxylated No Tall oil fatty acids, compound with polyethylenepolamine-tall oil fatty acid reaction products No All other amine oxides and oxygen-containing amines (except those having amine linkages), cydic No Amines and amine oxides having amide linkages: Carboxylic acid - diamine and polyamine condensates: Acetic acid, amides with polyalkylene polyamines, salt No Amides from C- 18 No Amidesfrom C-18 unsaturated fatty acid dimers and polyhexamethylenepolyamines No 2-Butenediamide, (E)-, N,n'-bis[2-(4,5-dihydro-2nortall oil alkyl)-0-1-imidazol-1-yl)ethyliderivatives No Caprylic acid tetraethylene-pentamine condensate No

MIL (2).

MIL BRD. BRD, RDA. MOA, RDA, SHX, VKR, WTC. BRD, FTX, MOA. HDG, MOA, RDA, (2).

IA.

HPC, (2).

(2).

BRD, RDA, (2).

j. (2). (2)-

ICI.

See footnotes at end of table. 12-17

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistic& (according to list in table 12-3)

Cationic-Continued Amines and amine oxides having amide linkages-Continued Cyclic-Continued Coconut oil acids-N,N-dimethyltrimethylenediamine condensate No C-18 Fatty acids, unsaturated compounds, with polyethylene-polyamines-tall oil fatty acid reaction products No 1H-Imidazole-1-ethanamine, 4,5-dihydro-, 2nortall-oil alkyl derivatives, acetates No N,N'-(Iminodi-2,1-ethanediAbis-tall oil fatty amides No Mixed fatty acids-polyalkylenepolyamine No condensate Naphthenic acids-polyalkylene polyamine condensate No Naphthenic acids-tall oil fatty acidspolyalicylene polyamine condensate No 2-Nor-tall oil alkyl-1-tall oil amido-ethyl imidazoline No Oleic acid-1-(2-aminoethyppiperazine No condensate Oleic acid-N,N-dimethyttrimethylenediamine No condensate Pelargonic acid-tetraethylenepentamine condensate No Stearic acid-diethylenetriamine condensate No Stearic acid-diethylenetriamine condensate, ethyl sulfate No Stearic acid - ethylenediamine condensate No Stearic acid mixed amine condensate No Stearic acid-tetraethylenepentamine condensate No Tall oil acids/aminoethylpiperazine condensate No Tail oil acids-diethylenetriamine condensate No Tall oil acids-polyalkylenepolyamine condensate No Tall oil acids-polyal ene polyamine condensate, salts, with dod enzene sulfonic acid and/or tall oil fatty acids No Tall oil fatty acids, reaction products with diethylenetriamine acetates No Tallow fatty acids-aminoethylethanolamine condensates No All other carboxylic acid-diamine and polyamine condensates No Carboxylic acid - diamine and polyamine condensates, alkoxylated: Mixed fatty acids-alkylenediamine condensate, polyethoxylate No Steanc acid-ethylenediamine condensate, monoethoxylated No All other carboxylic acid-diamine and polyamine condensates alkoxylated No Other amines and amine oxides having amide linkages: 3-Cocoarnido-N,N-dimethyl propylamine oxide No Cocoamidopropyl dimethyl dime amine oxide No N,N'-(Di-tall oil acid)amidoethylamine No 1-(2-Hydrogenated tallow amidoethyl)-2nor(hydrogenated tallow)-2-imidazoline No 3-Lauramido-N,N-dimethylpropylamine oxide No Stearamidoethyldiethylamine No See footnotes at end of table. 12-18

ENJ, SCP. (2). (2). (2). JTO. (2).

(a). SHX. ARC. CCW. ETC, ICI, OC. ARC, OC, RDA, S, SCP, SQA. GDC. CLD, SOS. HCL SCP, WTC, WVA. FER, JTO, WVA, (2).

(2).

(2).

OC. ARI, BRD, RDA,WVA,

WTC. APC, DEX, GDC, ICI. SCP, TMH. ar, SBC. (2).

SHX. DAN, SQA. S.

(2).

Synthetic Organic Chemicals, 1991 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Cationic-Continued Other amines and amine oxides having amid linkages -Continued Stearamidoethylethanolamine acetate Stearic acid-N-(2-cyanoethyl)diethylenetriamine condensate (Amine/acid ratio = 1/2) Stearic acid, diethanolamine condensate, methyl sulfate Stearylamidopropyldimethyl amine Amines, not containing oxygen (and salts thereof): Amine salts: (Coconut oil alkyl)amine acetate N,N-Dimethyl-N-alkylamine phosphate (Hydrogenated tallow alkyl)amine acetate Hydrogenated tallow diethylenetriamine condensate Mixed alkyl)amine phosphate decylamine acetate (Tallow alkyl)amine acetate N-(Tallow allryl)trimethylenediamine acetate N-(Tallow allryl)trimethylenediamine oleate All other amine salts (Not containing oxygen) Diamines and polyamines: Imidazoline derivatives: 1-(2-Aminoethyl)-2-nor(tall oil alkyl)-2imidazoline N-(Coconut oil alkyl)trimethylenediamine. N-(Dimeracidalkyl)trimethylenediamine Dimer diamine N-(Mixed alkyl)polyethylenepolyamine Mustard seed oil fatty acids diethylenetriamine, phosphate salt N-(9-Octadecenyl)trimethylenediamine Polyalicyclene polyamines and salts and quats 1-Propanamine, 3-(CirC15 alkoxy derivatives) N-(Soybean oil alkyl)tnmethylenediamine Stearamidoethyl-2-heptadecyl imidazoline N-(Tallow alkyl)dipropylenetriamine N-(Tallow alkyptrimethylenediamine All other diamines and polyamines Primary monoamines: Arachidylbehenylalkyl amine (Coconut oil alkyl)amine Dimeracidalkyl amine Dodecylamine [Erucyl alkyl)amine Hexadecylamine (Hydrogenated tallow alkyl)amine (Mixed alkyl)amine 9-Octadecenylamine Octadecylamine (Soybean oil alkyl)amine (Tallow alkyl)amine All other primary monoamines Secondary and tertiary monoamines: Bis(coconut oil alkyl)amine Bis(hydrogenated tallow alkyl)amine N,N-Didecylmethylamine See footnotes at end of table.

Separate Manufacturers' identification codes statistic& (according to list in table 12-3)

No

S.

No

ICI.

No No

DUP, PCI. RDA.

No No No

ENJ, (2). 2C.

No No No No No No No

CRT.

No No No No No

WTC, (2). ARC, JTO, SHX. ENO. SHX. CCW.

No No No No No No No No No

CRT. ARC, JTO, SHX, WTC.

AC.

( ARC, SHX. ARC. ARC. ARC, JTO.

No Yes No No No No Yes Yes Yes Yes No No No

SHX. ENO, WTC. ICI. ARC, ENJ. ARC, ENJ, JTO, SHX. ARC, ENO, JTO, (2). . ENO. ARC, ENO, JTO, SHX, WTC. ENO,WTC. ARC, JTO, SHX. ENO. ARC, ENO, WTC. ARC, ENO, JTO, SHX, WTC. ARC, JTO, SHX. ARC, ENO, JTO; SHX, WTC. ARC, ENO, JTO. ARC, ENO, JTO, WTC. ENJ, ENO, JTO, SHX. ARC, WTC.

No No No

ARC. ARC, ENO, WTC. SHX.

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics (according to list In table 12-3)

Cationic-Continued Amines not containig oxygen (and salt thereof) -Continued Secondary and tertiary monoamines-Continued N,N-Dimethyl(coconut oil alkyl)amine N,N-Dimethyldodecylamine N,N-Dimethylhexadecylamine N,N-Dimethyl(hydrogenated tallow alkypamine N,N-Dimethyl(mixed alkyl)amine N,N-Dimethyl(9-octadecenyl-alkyl)amine N,N-Dimethyloctadecenylamine N,N-Dimethyloctadecylamine N,N-Dimethyl(soybean oil alkyl)amine N,N-Dimethyltetradecylamine N-Methylbis(coconut oil alkyl)amine N-Methylbis(hydrogenated tallow alkyl)amine N-Methyldioctadecylamine Triisodecylamine Trilaurylamine Tri(mixed alkyl)amine Trioctylamine All other secondary and tertiary monoamines Oxygen-containing quaternary ammonium salts: 8-Alanine-N-(2-hydroxyethyI)-N-2,1oxococoyl amino ethyl, sodium salt 2-(C13-17 Alk14)- 1 -(C-14-18 arnidoethyl)(4,5-dimydro3-methyl)imidazolinium, methyl sulfate (2-Aminoethyl)ethyl(hydrogenated tallow alkyl)(2hydroxyethyl)ammonium ethyl sulfate Benzyl(coconut oil alkyl)bis(2-hydroxyethyl)ammonium chloride 1-Benzy1-2-heptadecy1-1-(2-hydroxyethyl)-2imidazolinium chloride 1-Benzy1-1-(2-hydroxyethyl)-2-nor(coconut oil alkyl) -2-imidazolinium chloride 1-Benzy1-1-(2-hydroxyethyl)-2-nor(tall oil alkyl)-2imidazoline Benzyl(tallow alkyl)bis(2-hydroxyethyl)ammonium chloride Bis(N-amidopropyI)-N,N-dimethyl-N-ethylammonium ethyl sulfate, dimer acid Bis(N,N1-ethyl(stearidarachidic/behenic)amide)cyanoethyl ethylammonium ethosulfate Bis(2-hydroxyethyl, ethoxylated)methyloctadecylammonium chloride Bis-2-hydroxyethyl-hydrogenated tallow-ethyl sulfate Bis-2-hydroxyethyl-octyl-methyl-p-toluene sulfonate (Coconut oil alkyl)bis(2-hydroxyethyl, ethoxylated)methylammonium chloride (Coconut oil alkyl)-bis-(hydroxyethyl)methyl ethoxylated mono-(2-carboxyethyl)ether methyl sulfate, potassium salt Distearyldimethyl ammonium methosulfate Ethoxylated(hydrogenated tallow amine), methyl ammonium chlonde Ethoxylated, quatemized(C12-18 alkyl) oxypropyl trimethylene diamine

See footnotes at end of table. 12-20

No No Yes No No No No Yes No No Yes No No No No No No No

ARC, EFH, JTO. ARC, SHX, TNA. ARC, BRD, SHX, TNA. ARC, CPC. ARC, TNA. ENO. WTC. ARC, ENO, SHX, TNA, WIC. ARC, JTO. SHX, TNA. ARC, JTO, SHX. ARC, SHX. ARC. SCP. SCP. SHX. SCP, SHX. ARC, ENO, TNA, WTC.

No

SHX.

No

DOW, SVC.

No

OC.

No

(2).

No

HDG.

No

EFH.

No

(a).

No

DUP.

No

SBC.

No

PCI.

No

SHX.

No

ICI.

No

HXL

No

ENJ, SHX.

No No

SVC. HXL.

No

ENJ.

No

ENJ.

Synthetic Organic Chemicals, 1991 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistical (according to list in table 12-3)

Cationic-Continued Oxygen-containing quaternary ammonium salts-Continued Ethoxylated, quatemized reaction product of formaldehyde and tallow diamine No N-Ethyl-N,N-bis(polyoxyethylene)tallow ammonium ethyl sulfate No 1-Ethy1-2-(8-heptadeceny1)-1-(2-hydroxyethyl)-2imidazolinium ethyl sulfate No N-Ethyl-N-hexadecylmorpholinium ethyl sulfate No N-Ethyl-N-(soybean oil alkyl)morpholinium ethyl sulfate No a-Gluconamidopropyl dimethy-2-hydroxyethyl ammonium chloride No (2-Hydroxyethypdimethyl(3-stearamidopropy1)ammonium nitrate No Hydroxyethyl-2-undecyl-2,3-imidazoline No N-2-hydroxy propyl-n-methyl-N,n-bigtallow amide ethyl] ammonium ethyl sulfate No Imidazolinium, 1-carboxymethyl)-4,5-dihydro-1(hydroxyethyl)-2-nor(cocoalkyl), hydroxides, monosodium salts No (3-Lauramidopropyl)trimethylammonium methyl sulfate No Methyl, bis-(2-hydroxyethyl) hydrogenated tallow alkylammonium chloride No Methyl, bis-(2-hydroxyethyl) isodecyloxypropylammonium chloride No Methyl, bis-(2-hydroxyethyl) isotridecyloxypropylammonium chloride No Methyl, bis-(2-hydroxyethyl) soyaalkylammonium chloride No Methyl-ditallowimidazolinium methosulfate No 1-Methy1-2-(8-heptadeceny1)-1-(9-octadecenypamido ethyl No Methyl(hydrogenated tallow alkyl)diethylamine condensate, polyethoxylated, methyl sulfate No 1-methyl-2-nor-tallow-1-[2 tallow ami oethyl]imidazoliniummethyl sulfate No N-Methyl-N-polyoxyethylene-N,N-bis(hydrogenated tallow amidoethAammonium No N-Methyl-N-polyoxyethylene-N,N-bis(tailow amidoethyl) No Methyltallowdiethylenetriamine condensate, polyethoxylated, methyl sulfate No Methyltallowdiethylenetriamine condensate, polypropoxylated, methyl sulfate No Mixed(coco and soya fatty acids), reaction products with chioromethane and diethylenetriamine, ethoxylated, quatemized No Mixed fatty acid amide with diethylene triamine/ethyl sulfate No N-Octadecyl-N,N-di(2-hydroxyethyl)-N-methylammonium chloride No Phosphonic acid, [1,2ethanediyIbignitrilobis(methylene)Dtetralds-, ammonium salt No

ENJ. SHX. ICI, SHX. BRD, ICI. ICI. VND. ACY. MOA. SHX. SHX. ACY. ENJ. ENJ. ENJ. ENJ. SVC. SHX. SVC. SHX. SHX. SHX. SVC. SVC. ENJ. EFH. SHX. (2).

See footnotes at end of table.

12-21

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

rirace-active agents

Cationic-Continued Oxygen-containing quarternary ammonium salts— Continued Quaternary ammonium salts—Continued Phosphonic acid, [nitrilotris(methylene)]-Iris-, ammonium salt Phosphonic acid, [nitrilotris(methylene)]-tris, sodium salt Polyethoxy methylstearyl ammonium chloride Poly(oxyethanyl, 2-diy1)-di-[2-[2-bis(2-aminoethyl)methylamiumethyl].. Polypropoxy diethylmethyl ammonium chloride 1-Propanaminium, N-ethyl-N,N-dimethy1-3-[(1oxooctadecyl)amino]-, ethyl sulfate Soya fatty acids, reaction products with chioromethame and diethylenetriamine, ethoxylated, quatemized Soya fatty acids, reaction products with chloromethane and diethylenetriamine, propoxylated, quatemized Stearamidopropyldimethylceterylammonium tosylate and propylene glycol Stearylamidopropyl dimethyl myristyl acetate ammonium chloride Tallow alkyl)ethoxylated, ethyl sulfate Tallow amine, ethoxylated, quartemary ammonium salt All other oxygen-containing quaternary ammonium salts (except those having amide linkages) All other quatemary ammonium salts having amide linkages Quaternary ammonium salts, not containing oxygen: Acyclic: Bis(coconut oil alkyl)dimethylammonium chloride Bis(hydrogenated tallow alkyl)dimethylammonium chloride Bis(hydrogenated tallow alkyl)dimethylammoniummethyl sulfate Bis(tallow alkyl)dimethylammonium chloride N-(Cocoamidopropyl; N,N-acetic acid) ammonium salt Cocodimethyl ethyl ammonium ethyl sulfate N-[(Coconut oil alkyl)amino]butyric acid, sodium salt Didecyldimethylammonium chloride Dimethyldi(C12-18)ammonium chloride (mixed straight and branched chains) Dimethyldioctadecylammonium choride Dodecyttrimethylammonium bromide Dodecyttnmethylammonium chloride Ethyldimethyl(mixed alkyl)ammonium ethyl sulfate Hexadecyttrimethylammonium bromide Hexadecyltrimethylammonium chloride Hexane-1,6-bis(tributylammonium bromide) (Hydrogenated tallow alkyl)trimethylammonium chloride Lauryl pyridinium chloride Methy1-1-tallowamidoethy1-2-tallowimidazoliummethyl sulfate See footnotes at end of table. 12-22

Separate Manufacturers' identification codes statistics1 (according to list in table 12-3)

No

(2).

No No

WTC.

No No

SVC. WTC.

No

SBC.

No

ENJ.

No

ENJ.

No

VND.

No No

VND. SVC.

No

DUP, VND.

No

ARC, BRD, ENJ, ETC, SBC, SCP, SDC, SHX, WTC, (2), (2).

No

BRD, ENJ, MIL

Yes

ARC, ENJ, JTO, PPG, SHX.

Yes

ARC, ENO, SHX, WTC.

No No

ARC, SHX. SHX.

No No

ax.

No No

ARC, JTO, PPG, SHX. BRD, HNT.

No No No No

SHX. SHX. RSA. ARC, BRD, SHX.

No No Yes No

BRD, DEX. ARC. ARC, BRD, SHX. HXL

No No

ARC, SHX. WTC.

No

CRD.

Synthetic Organic Chemicals, 1991 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statisficsi (according to list in table 12-3)

Cationic-Continued Quaternary ammonium salts, not containing oxygen -Continued Acyclic-Continued Methyl tri(C9-10)ammonium chloride Methyltrioctylammonium chloride Methyltris(mixed alkyl)ammonium chloride N,N,N',N',N-Pentamethyl-Nitallow alkyl)trimethylene-bis[ammonium chloride] Stearyl pyridium chloride Trihydrogenated tallow ammonium chloride Trimethyl(mixed alkyl)ammonium chloride Trimethyloctadecylammonium chloride Trimethyl(soybean oil alkyl)ammonium chloride Trimethyl(tallow alkyl)ammonium chloride All other quaternary ammonium salts, not containing oxygen acydic Benzenoid: Benzyl(alkylpyridinium)chloride Benzyl(cocoamidopropyl)dimethyl ammonium chloride Benzyl(coconut oil alkyl)dimethylammonium chloride Benzyldimethyl(mixed alkyl)ammonium chloride Benzyldimethyloctadecylammonium chloride Benzyl dimethyl oleyl ammonium chloride Benzyldimethyl(tallow alkyl)ammonium chloride Benzyldimethyttetradecylammonium chloride Benzyldodecytdimethylammonium chloride Benzylhexadecyldimethylammonium chloride Benzyl(hydrogenated tallow alkyl)dimethylammonium chloride Benzyl-methyl-bis(hydrogenated tallow)ammonium chloride Benzyl(mixed alkyppyridinium chloride Benzyl picolinium chloride Benzyltrimethylammonium chloride Butyl picolinium bromide 1-Dodecylpyridinium chloride (Ethyibenzyl)dimethyl(mixed alkyl)ammonium chloride Octadecyl-dibenzyltrimethy1-1,3-propane diammonium chloride 1-Phenethy1-2-picolinium bromide All other quaternary ammonium salts not containing oxygen cyclic Other cationic surface-active agents: All other cationic surface-active agents Nonionic surface-active agents: Carboxylic acid amides: (amine/acid ratio = 2/1): Capric acid (Ratio =2/1) Castor oil acids (Ratio = 2/1) Coconut oil acids (Ratio = 2/1)

Coconut oil and tallow acids (Ratio = 2/1) Lard oil acids

No No No

SHX. SCP. HMP.

No No No No No No Yes

SHX. WTC. ENO. ARC, BRD. ARC, SHX. JTO. ARC, ENO, JTO, SHX, WTC.

No

ARC, BRD, DUP, MOA, SHX.

No

(2).

No

(2).

Yes

ARC, ENJ, ENO, GDC, HRT, WTC, (2).

Yes Yes No No No No No

BRD, CRD, HNT, PPG, SHX, STP, TCC, (2). BRD, PPG, RDA, SHX, TNI. RDA. BOE, ENO, WTC. BRD. HIP. BKM.

Yes

ARC, ENO, SHX, WTC.

No No No No No No

ENO.

No

BRD, HNT, STP.

No No

GDC. HXL.

No

ARC, BRD, ICI, RDA, WTC, (2).

No

ARC, ARI, BRI, JTO, MOA, PPG, RDA, S, VVM, INTC, VVVA.

No No Yes

SCP. NSC, RDA. ARD, ARL, BRI, CCC, CON, CRT, ECC, EFH, ETC, HNT, MCP, MOA, MRV, NES, PPG, RDA, SBC, SCP, SHX, WPG, WTC. ENJ, MOA, SBC, UNN. FER.

(2)-

No No

C. HIP, RSA, TCC. HXL. DAN.

See footnotes at end of table. 12-23

Section 12 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Separate Manufacturers' identification codes statistical (according to list in table 12-3)

Surface-active agents

Nonionic-Continued Carboxylic acid amides-Continued Other amine/acid ratios-Continued Lauric acid (Ratio = 2/1) Lauric and myristic acids (Ratio = 2/1) Linoleic acid (Ratio = 2/1) Mixed carboxylic acids Mixed fatty acids, neutralized Oleic acid (Ratio = 2/1) Stearic acid (Ratio = 2/1) Tall oil acids (Ratio = 2/1) Tallow acids (Ratio = 2/1) All other diethanolamine condensates (Amine/acid = 2/1) Other amine/acid ratios: Capric acid (Ratio=1/1) Coconut oil acids (Ratio = 1/1)

No No No No No Yes No Yes Yes

Lard oil acids (ratio = 1/1) Lauric acid (Ratio = 1/1) Lauric and myristic acid (Ratio = 1/1) Linoleic acid (Ratio = 1/1) Mixed carboxylic acids Mixed fatty acids camine/acid ratio = 1/1 Myristic acid (Ratio = 1/1) Oleic acid (Ratio = 1/1) Palm kernel oil acids (Ratio =1/1) Rapeseed acids (ratio = 1/1) Soybean oil acids (Ratio = 1/1) Stearic acid (Ratio = 1/1) Tall oil acids Tallow acids Diethanolamine condensates, amine/acid, ratio = 1/1 All other carboxylic acid amides: All other alkanolamine condensates All other carboxylic acid - alkanolamine condensates All other carboxylic acid-diamine and polyamine condensate All other diethanolamine condensate All other ethanolamine condensates, amine/acid, ratio la 1/1 All other ethanolamine condensates, amine/acid, ratio = 2/1 Coconut oil acids (Ratio = 1/1) Coconut oil acids (Ratio = 2/1) Coconut oil acids Coconut oil acids-dimethylaminopropylamine condensate (amine/acid ratio = 1/1 Dodecylbenzenesulfonic acid, monoethanolamine condensate Hydrogenated tallow acids, (Ratio = 2/1) Hydrogenated tallow amides, ethoxylated Hydrogenated tallow glycerides diethylenediamine condensate

See footnotes at end of table.

12-24

CRD. CRD, MOA, SBC. MOA. SOS. FTX. EFH, LEA, MOA, RDA, SBC, WTC. BRD, OC, RDA. BRI, ECC, PPG, SBC, WVA. ICI, MOA.

No

ARZ, MOA, RDA, SHX.

No Yes

Yes No No No No Yes No No Yes Yes Yes No

MOA. ARD, BRD, CPC, CRT, ESS, ETC, FTX, HNT, HRT, JRG, MOA, PIL, OCP, RDA, SBC, SCP, SHX, TMH, VND, WTC, (2). FER. MOA, RDA, SBC, SCP, SHX, WTC. BRD, FTX, MOA, RDA, SBC. SBC, VND. SOS, WTC. RDA, WTC. MOA. DAN, EFH, MOA, RDA, SBC. SVC, TMH. EFH. MOA, RDA, SBC. ECC, ENJ, ETC, HIP, MRV, WTC. EFH, ESS, (2). MOA.

No

BRD, MOA.

No

SCP, (2).

No

SCP.

No No

HIP. EFH, SCP, SHX.

No

BRD.

No No No No

SHX. FTX, MOA, RDA, SOS, STP. ENJ, MOA, NSC, SCP. DAN, PAT, PPG.

No

(2)•

No No No

(2)• WPG. PCI.

No

LEA.

No Yes

Synthetic Organic Chemicals, 1991 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Surface-active agents

Nonionic-Continued Carboxylic acid amides-Continued M other carboxylic acid amides Hydrogenated tallow glycerides diethylenetriamine condensate Isonanoic acid, mono- and triethanolamine salt All other isopropanolamine condensates lsostearic acid, aminoethylethanolamide, acetate salt Lauric acid Lauric acid (Ratio = 1/1) Lauric and myristic acids Lauric and myristic acids (Ratio = 1/1) Mixed fatty acids, diethanolamine condensate Stearic acid (Ratio = 1/1) Stearic acid (Ratio = 2/1) Stearic acid aminoethanolamine (amine acid ratio = 1.0/1.65) Stearic acid-N-aminoethyl ethanolamine condensate Stearic acid-ethylenediamine condensate amine/acid ratio=1/2 Stearic acid monoethanolamine condensate Tall oil acids-dimethylamine condensate (Amine acid ratio = 1/1) Tall oil fatty acids (ratio = 1 t2) Tall oil fatty acids (ratio = 2.7/1) Tall oil fatty acids (ratio = 1.5/1) Tall oil fatty acids-triethanolamine condensate Tallow, n-(3-(dimethylamino)propyl (amine/acid ratio= 1/3) All other carboxylic acid amides Carboxylic acid esters: Anhydrosorbitol esters: Anhydrosorbitol dioleate Anhydrosorbitol monoester of tall oil acids Anhydrosorbitol monolaurate Anhydrosorbitol mono-oleate Anhydrosorbitol monopalmitate Anhydrosorbitol monostearate Anhydrosorbitol sesquioleate Anhydrosorbitol triester of tall oil acids Anhydrosorbitol trioleate Anhydrosorbitol tristearate All other anhydrosorbitol esters Diethylene glycol esters: Diethylene glycol monoester of coconut oil acids Diethylene glycol monoester of tall oil acids Diethylene glycol monoester of tallow acids Diethylene glycol monolaurate Diethylene glycol mono-oleate Diethylene glycol monostearate Diethylene glycol sesquiester of tall oil acids All other diethylene glycol esters Ethoxylated anhydrosorbitol esters: Ethoxylated anhydrosorbitol monolaurate Ethoxylated anhydrosorbitol mono-oleate

Separate Manufacturers' identification codes statisticsi (according to list In table 12-3)

No No No

HRT. HCL. SBC, VND.

No No No No No No No No

PCI. MOA, NSC. RDA. RDA. MOA, STP. WTC. MOA. ECC.

No

CHP.

No

BOE.

No No

SLC. VND, WTC.

No No No No No

BKM. EFH. EFH. EFH. (2).

No No

PAT. BRD, MOA, ( 2).

No No Yes Yes No Yes No No No No No

ICI. HDG. BRD, HDG, ICI, PPG. BRD, HDG, ICI, PPG, SCP. BRD, ICI, PPG. BRD, HDG, ICI, PPG. BRD, HDG.

No No No No Yes No No No

BRD. BKM. ENJ. ECC, HDG, PPG. BRD, SCP, SHX, (2). BRD, ECC, HDG, RDA. ECC, WVA. (2).

Yes Yes

BRD, ETC, HDG, ICI, PPG, SVC. BRD, ETC, HDG, ICI, PPG, SVC.

D, ICI, PPG. BRD, PPG. PG.

See footnotes at end of table.

12-25

Section 12

Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents Nonionic-Continued Carboxylic acid esters-Continued Ethoxyiated anhyrosorbitol esters-Continued Ethoxylated anhydrosorbitol monopalmitate Ethoxylated anhydrosorbitol monostearate Ethoxylated anhydrosorbitol trioleate Ethoxylated anhydrosorbitol tristearate M other ethoxylated anhydrosorbitol esters Ethoxylated sorbitol esters: Ethoxylated sorbitol beeswax ester Ethoxylated sorbitol hexaester of tall oil acids Ethoxylated sorbitol hexaoleate Ethoxylated sorbitol lanolin ester Ethoxylated sorbitol mono-oleate Ethoxylated sorbitol monopalmitate Ethoxylated sorbitol monostearate Ethoxylated sorbitol oleate, acetylated Ethoxylated sorbitol pentalaurate Ethoxylated sorbitol tetraester of lauric and oleic acids Ethoxylated sorbitol tetraester of tall oil acids Ethoxylated sorbitol tetraoleate Ethoxylated sorbitol tetrastearate Ethylene glycol esters: Ethylene glycol distearate Ethylene glycol monostearate Ethylene glycol sesquistearate All other ethylene glycol esters Glycerol esters: Complex glycerol esters: Glycerol mono- and diesters of mixed fatty acids Glycerol monoester of mixed fatty acids, acetylated Glycerol monoester of mixed fatty acids, succinylated All other complex glycerol esters Glycerol esters of chemically defined acids: Glycerol dilaurate Glycerol monocaprylate Glycerol monolaurate Glycerol mono-oleate Glycerol monoricinoleate Glycerol monostearate Glycerol trioctanoate/decanoate Glycerol trioleate All other glycerol esters of chemically defined acids Glycerol esters of mixed acids: Glycerol diester of lard acids Glycerol monoester of C8-C10 acids Glycerol monoester of cottonseed oil acids Glycerol monoester of hydrogenated cottonseed oil acids See footnotes at end of table.

12-26

Separate Manufacturers' Identification codes statistics1 (according to list in table 12-3)

No Yes No Yes No

ICI, PPG. BRD, ETC, HDG, ICI, PPG. BRD, ETC, HDG, ICI, PPG. BRD, ICI, PPG. BRD.

No No No No No No Yes No No

ICI. BRD, PPG. ETC, ICI. ICI. CPC, ICI. HIP. CPC, HIP, NSC. ICI. NSC.

No No No No

ICI. WTC, (2). ICI. ICI.

Yes

No No

BRD, ENJ, HDG, PPG, RDA, STP, WM, . WTC. BRD, HDG, PPG, RDA, SCP, STP, VND, WM, WTC. JTO, VND. BAS, VND.

No

ICI.

No

EKE

No No

EKT. BRD, LEV, SCP.

No No No Yes

No No

HIP, STP, VND. SVC. BRD, HDG. BRD, EFH, ETC, HAL, HDG, PPG, SCP, STP, SVC, WTC. BRD, HDG. BRD, CCC, CHL, CPC, CRT, HAL, HDG, PPG, SCP, SQA, STP, VND, WM, WTC. WM. SVC.

No

BRD, SCP, SVC, VND.

Yes No No

BRD, SVC, WPG. SVC. EKE

No

EKT.

Yes

No Yes

Synthetic Organic Chemicals, 1991 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics1 (according to list In table 12-3)

Nonionic-Continued Carboxylic acid esters-Continued Glycerol esters-Continued Glycerol esters of mixed acids—Continued Glycerol monoester of hydrogenated laid acids Glycerol monoester of hydrogenated soybean oil acids Glycerol monoester of lard acids Glycerol monoester of mixed vegetable oil acid Glycerol monoester of palm oil acids Glycerol monoester of safflower oil acids Glycerol monoester of tall oil acids Glycerol monoester of tallow acids Glycerol sesquiester of hydrogenated tallow acids Glycerol triester of mixed fatty acids All other glycerol esters of mixed acids Natural fats and oils, ethoxylated: Castor oil, ethoxylated Coconut oil, ethoxylated Hydrogenated castor oil, ethoxylated Lanolin, ethoxylated Mixed fatty acids, alkyl ether, ethoxylated Mixed tall oil and rosin acids, ethoxylated Tall oil acids, ethoxylated Tall oil acids, ethoxylated and propoxylated Tall oil, refined, ethoxylated All other natural fats and oils, ethoxylated Polyethylene glycol esters: Polyethylene glycol esters of chemically defined acids: Polyethylene glycol dilaurate Polyethylene glycol dioleate

No

EKT.

No No No No No No No

EKT. EKT. BFP. EKT. EKT. EFH, FER. EKT.

No No No

PCI. SVC. BFP, BRD, EKT, ETC.

No

CAS, CPC, CRD, ETC, GAF, HCL, HIP, ICI, MIL NSC, PPG, RDA, S, SCP, SVC, "NH, WTC, (2). SVC. ETC, ICI, MIL PPG, RDA, SCP. CRD, ETC, HCL, RDA, SVC, (2).

No Yes Yes No No Yes No No No

Yes Yes

Polyethylene glycol distearate Polyethylene glycol monocaprylate Polyethylene glycol monoiaurate

Yes No Yes

Polyethylene.glycol mono-oleate

Yes

Polyethylene glycol mono-oleate, ethoxylated Polyethylene glycol monopalmitate Polyethylene glycol monopelangonate, methoxylated Polyethylene glycol monopelargonate Polyethylene glycol monoricinoleate Polyethylene glycol monostearate

No Yes

Polyethylene glycol monotallate Polyethylene glycol sesquinoleate Polyethylene glycol terephthalate An other polyethylene glycol esters of chemically defined acids

No Yes No Yes

HC

L FER, HCL, HIP, RDA. RDA, (2). BRD, CRD, ETC, HDG, MIL, SCP.

BRD, EFH, ETC, HDG, PPG, STP, WM. BRD, EFH, HAL, HDG, OC, PPG, QCP, SCP, SOS, STP. BRD, HDG, HIP, PPG, RDA, STP. ECC. BRD, CCA, ECC, EFH, ETC, HAL, HDG, ICI, PPG, RDA, STP. BOE, BRD, CCA, ECC, EFH, ETC, GDC, HAL, HCL, HDG, MIL, MRT, MRV, OC, PPG, SHX, STP, SVC, TMH, WTC, (2). ICI. ETC, HCL, ICI, RDA.

No No No

RDA ETC, SOS. ECC. BRD, CPC, ETC, GDC, HDG, HIP, ICI OC, PPG, RDA, SCP, STP, SVC, VND, (2). CCC, PPG. SOS. BOE, PCI.

No

ARC, CCA, ETC, HCL, MIL

See footnotes at end of table.

12-27

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, Identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' Identification codes statistics1 (according to list In table 12-3)

Nonionic-Continued Carboxylic acid esters-Continued Polyethylene glycol esters-Continued Polyethylene glycol esters of chemically defined acids-Continued Polyethylene glycol esters of mixed adds: Polyethylene glycol diester of coconut oil acids Polyethylene glycol diester of coconut oil and oleic acids Polyethylene glycol diester of mixed liner acid/oleic acid Polyethylene glycol diester of tall oil acids Polyethylene glycol ester of mixed fatty acids Polyethylene glycol monoester of coconut oil acids Polyethylene glycol monoester of tall oil acids Polyethylene glycol (mixed ester) of tall oil acids Polyethylene glycol sesquiester of coconut oil acids Polyethylene glycol sesquiester of tall oil acids Polyethylene glycol sesquiester of tallow acids All other polyethylene glycol esters of mixed acids Polyglycerol esters: Decaglycerol Decaglycerol tetraoleate 1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-, polymer with methyloxirane and oxirane 1,2-Ethanedimine, N,N'-bis(2-aminoethyl)-, polymer with methyloxirane Hexaglycerol Mixed oleic, lauric, stearic, and palmitic hexaglycerol esters Polyglycerol distearate Polyglycerol mono-oleate Polyglycerol monostearate Polyglycerol tetraoleate All other polyglycerol esters Propanediol esters: 1,3-Propanediol, 2-amino-2-(hydroxymethyl)-, polymer with oxirane 1,3-Propanediol, 2-amino-2-(hydroxymethyl)-, polymer with oxirane and methyloxirane 1,2-Propanediol dioctanoate/decanoate 1,2-Propanediol monolaurate 1,2-Propanediol mono-oleate 1,2-Propanediol monostearate All other propanediol esters Other carboxylic acid esters: Cholesterol isostearate Di-isobutylene maieate Ethoxylated1,3-butylene glycol condensed with oil fatty aciEthoxylated 1,3-butylene glycol stearate

See footnotes at end of table.

12-28

No

PPG.

No

EFH.

No Yes

PCI. ARI, BRD, CCC, EFH, ETC, HIP, PPG, QCP, S. SHX, SOS

No No No

ICI. BKM, EFH, WPG.

No

CRT.

No

ENJ, SCP.

Yes

SLM, WTC, (2).

No

PAT.

No

BOE, BRD, ETC, LEA, SCP, (2).

No No

SVC. SVC.

No

(2).

No No

ac.

No No Yes No No No

SVC. BRO. BRD, HDG, PPG, SVC, WTC. BRD, HDG, SVC. PPG. BRD.

No

(2).

No No No No No No

PVC.

SBC, STP. EFH, HAL. BRD, EKT, HAL, PPG, SBC, SW, WM. SCP.

No No

HIP. RH.

No

HCL

Synthetic Organic Chemicals, 1991 Table 12-2--Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics1 (according to list In table 12-3)

Nonionic-Continued Carboxylic acid esters-Continued Other carboxylic acid ester—Continued Ethoxylated glycerol and propylene glycol esters of coco fatty acids Ethoxylated glycerol sesquiester of mixed fatty acids Ethoxylated 1,2-propanediol monostearate Linoleic acid dimers, alkoxylated Maleic anhydride, polypropylene glycol copolymer Methylglucoside laurate Mixed alkyl benzoate Mixed alkyl stearate Nonylphenol, ethoxylated, coconut oil esters Oleic acid, N-octyl ester Pentaerythritol stearate Pentaerythritol tetraoleate Pentaerythritol tetrapelargonate Polyalkylene glycol oleate Polycarboxylic acid, alkylate Polycarboxylic acid, allylphenoxyalkoxylate Propylene glycol esters of hydrogenated palm All other carboxylic acid esters Ethers: Benzenoid ethers: Alkylphenol-formaldehyde condensates alkoxylated Amylphenol-formaldehyde, alkoxylated Bisphenol A, ethadated and propoxylated Bisphenol a, ethoxylated Bisphenol-A, propoxylated P-tert-Butylphenol-formaldehyde, alkoxylated Diisobutylphenol, ethoxylated Dinonylphenol, ethoxylated

No

SVC.

No No No No No No No No No No No No No No No

BRD, SHX. HDG, ICI.

No No

PG, VND. ARI, BRD, CHP, EFH, ETC, MOA, PPG, SCP, SVC, WM, WPG, ( 2).

No No No No No No No Yes

BAS, ETC, WTC, (2),

Dodecylphenol, ethoxylated Epichlorohydrin bisphenol A, ethoxylated Furfuryl alcohol, ethoxylated lso-octylphenol, ethoxylated (Mixed alkyl)phenol epichlorohydrin-formaldehyde, alkoxylated (Mixed alkyl)phenol-formaldehyde, alkoxylated Naphthalene sulfonic acid, polymer with formaldehyde and 4,4'-dihydroxydiphenyl suffone Naphthalene sulfonic acid, polymer with formaldehyde, sodium salt 13-Naphthol, ethoxylated Nonylphenol, ethoxylated

Yes No No No

Nonylphenol, ethoxylated, phosphate esters Nonylphenol, ethoxylated and propoxylated Nonyl phenol, ethoxylated with mixed fatty acids Nonylphenol-formaldehyde, alkoxylated Nonylphenoxy ethoxycocoate Nonylphenoxypoly(ethyleneoxy)ethyl iodide n-Octylphenol, ethoxylated

No Yes No Yes No No No

HDG, PPG. APC. SOS. CRT. HIP. PPG, SCP. PPG. HIP. SOS.

(2).

PPG. PPG. CPC, ETC, GAF, NSC, PPG, RDA, S, WTC, (2). MON, RDA, SCP, TMH, WTC. O (

VC.

BAS, GAF, PPG, RH, TMH.

No Yes

HCL, WTC, (2), (2).

No

PCI.

No No Yes

PCI. BAS. ARC, BAS, BRD, CPC, DUP, ENJ, ETC, GAR HCL, HDG, ICI, MIL MOA, MON, NSC, OMC, PPG, RDA, S, SCP, STP, TMH, TX, UCC, WPG, WTC, (2), (2). OMC. ETC, RDA, STP, TMH, WTC. SOS. BAS, (2), (2). AMU. RDA. RDA, SCP, TMH, WTC.

See footnotes at end of table.

12-29

Section 12 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Separate Manufacturers' identification codes statistics' (according to list in table 12-3)

Nonionic-Continued Ethers-Continued Benzenoid ethers-Continued tert-Octylphenol-formaldehyde, ethoxylated Phenol, ethoxylated Phenol-formaldehyde resin (with lignite) p-Phenylphenol, alkoxylated Phenylstyrene, ethoxylated Poly[oxy(methy1-1,2-ethanediy1)), a-hydroTridecyiphenol, ethoxylated All other phenols, ethoxylated Nonbenzenoid ethers: Linear alcohols, alkoxylated: Butanol, ethoxylated Butyl alcohol, propoxylated Decyl alcohol, ethoxylated

No No Yes

SDW, WTC. GAF, ICI, PPG, RDA, SCP. PSP. BAS. HCL. (2)WIC. BAS, ETC, GAF, MIL RDA, RH, SCP, WTC.

Decyl alcohol, ethoxylated and propoxylated Decyloxypoly(ethyleneoxy)ethyl chloride Dodecyl alcohol, ethoxylated Hexadecyl alcohol, ethoxylated Hexadecyl alcohol, propoxylated N-Hexyl alcohol, ethoxylated Isostearyl alcohol, ethoxylated 9-Octadecenyl alcohol, ethoxylated Octadecyl alcohol, ethoxylated Oleyl alcohol, ethoxylated Stearyl alcohol, propoxylated All other chemically defined linear alcohol alkoxylated Coconut oil alcohol, ethoxylated Decyl and octyl alcohols, ethoxylated Decyl and octyl alcohols, ethoxylated and propoxylated Jojoba oil, ethoxylated Mixed linear alcohols, alkoxylated Mixed linear alcohols, ethoxylated

No No Yes Yes No No No Yes Yes Yes No

HDG. WTC. BAS, CPC, ENJ, GAF, HCL, HIP, ICI, MIL, S. HIP. GAF, RDA. ENJ, HCL, HDG, ICI, MIL (2). BRD, HIP, ICI, RDA, SVC. PPG. HIP, RDA. SHX. ETC, GAF, ICI, RDA, S. ICI, NSC, PPG, RDA, SCP, SVC. CPC, CRD, HCL, PPG, SHX. SVC.

No No No

BAS, BRD, CRD, SCP. ETC, GAF, RDA. WTC.

No No No Yes

PPG. SVC.

Mixed linear alcohols, ethoxylated, benzyl ether Mixed linear alcohols, ethoxylated and propoxylated

No

Myristyl alcohol, propoxylated Stearyl alcohol, propoxylated Tallow alcohol, ethoxylated Wool wax alcohols, ethoxylated All other mixed linear alcohols, alkoxylated Other ethers and thioethers: Bis-cumylphenyl-oxoethylene titanate 1,3-Butylene glycol, ethoxylated tert-Dodecyl mercaptan, ethoxylated 2-Ethylhexanol, ethoxylated Glycerine, alkoxylated Glycerol, alkonlated, toluene diisocyanate copolymer Isodecyl alcohol, ethoxylated

See footnotes at end of table. 12-30

No Yes No No No No No No

Yes No No No No No

S, DUP, ENJ, HDG, ICI, MIL, RDA, SCP, SHC, SHX, STP, TNA, TX, UCC,

VST, WTC, (2). (2). BAS, DUP, ENJ, ETC, MIL, OMC, PEL, PPG, RDA, S, SCP, SHX, STP, SVC, UCC, WTC. WTC. WTC. ENJ, ETC, PPG, RDA. CRD. ETC, RDA, SHC, (2). KPI. HCL ETC, RDA HIP.

No No No No No

(2)•

No Yes

ETC,

PPG, RDA, WM.

Synthetic Organic Chemicals,1991 Table 12-2—Continued Surface-active agents for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Surface-active agents

Nonionic-Continued Ethers-Continued Other ethers and thioethers—Continued lsodecyl alcohol, ethoxylated and propoxylated Iso-octyl alcohol, ethoxylated Lignin, ethoxylated Mixed alcohols, ethoxylated Phosphonic acid, (1-hydroxy eth idene)bis compounded with 2-aminomethanol Poly(epichlorhydrin Polyether diols Polyether triols Polyethoxylate/polypropoxylate dibenzyl ether Polyethylene glycol mono(nonylphenol)ether ammonium sulfate Polyethylene glycol, propoxylated Poly(mixed ethylene, propylene)glycol Poly(mixed ethylene/propylene glycol) capped with alkyl oxirone Poly(oxy-1,2-ethanediy1),a-phenylmethy1-70hydroxy,C12 C15 alkyl ethers Poly(oxy-1,2-ethanediy1),a-phenylmethy1-70hydroxy, ethoxylated nonyiphenol alkyl ether Polypropylene glycol, alkoxylated, polymer with maleic anhydride, acrylic acid, and allcylphenolformaldehyde resin, alkoxylated Polypropylene glycol, ethoxylated Polypropylene glycol glycerol triether, copolymer with epichiorhydin bisphenol epoxy resin 2,4,7,9-Tetramethy1-5-decyne-4,7-diol, ethoxylated Tridecyl alcohol, ethoxylated Tridecyl alcohol, propoxylated and ethoxylated Trimethylnonyl alcohol, ethoxylated Trimethylolpropane, alkoxylated All other ethers and thioethers Other nonionic surface-active agents: Cumyl phenolate isopropoxy titanium salt Formaldehyde, dicyandiamide, ethylene sulfate polymers (Mixed alkyl)phenol alkylenediaminealkanolamine formaldehyde Tetra-(2,2-diallyloxyrnethylene)-1-butoxy titanium bis-(ditridecyl) phosphite Tetra-isopropoxy titanium (bis di phosphite Tetra octyloxy titanium (bis-tridecyl osphite) All other nonionic surface-active agents

Separate Manufacturers' identification codes statistics1 (according to list in table 12-3)

No No No Yes

RDA. ETC. WVA. ENJ, S, TMH, WTC, (2).

No No No No No

Wf C.

WTC. (2)•

No No Yes

ETC, UCC, WTC, (2), (2).

No

(2)-

No

PCI.

No

PCI.

No No

BAS,

No

(2)•

No No Yes No Yes No

ETC, HDG, PPG, RDA, SCP, TMH, WI-C, (2).

RDA, SCP. ' BAS, CPC, DUP, ENJ, ETC, HCL, HIP, ICI, MIL PPG, RDA, S, TMH, WTC, (2). ETC, NSC, TX. UCC. BAS, ETC, RDA, SCP, WTC. BRD, ETC, HCL, OMC, RDA, SCP, SVC, WTC, (2).

No

KPI.

No

PCI.

No

(2)•

No No No No

KPI. KPI. KPI. BAS, BRD, CLU, DUP, ICI, KPI, MIL, MOA, PCI, PG, RDA,SCP, WM, ( 2), (2).

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

12-31

Section 12 Table 12-3 Surface-active agents: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ACT ACY AGP AMU APC APX ARC ARD ARI ARL ARZ BAS BFP BKM BLA BOE BRD BRI BSW CAS CCA CCC CCW CHL CHP CIN CLD CLU CMT CON CP CPC CRD CRT DAN DEX DOW DUP

Climax Performance Materials Corp. American Cyanamid Co. Dial Corp. RPM American Emulsion Co., Inc. Apollo Chemicals Corp Apex Chemical Corp. Also Chemicals, Inc. Ardmore, Inc. Atlas Refinery, Inc. Arol Chemical Products Co Arizona Chemical Co BASF Corp. American Ingredients Company Buckman Laboratories, Inc. Astor Products, Inc., Blue Arrow Div. Boehme Filatex, Inc. Lonza, Inc. Burlington Industries Original Bradford Soap Works, Inc. CasChem, Inc. Akzo Chemicals, Inc C.N.C. International, Inc. Morton International, Inc Chemol Co. C. H. Patrick & Co., Inc. Stockhausen, Inc. Rhone-Poulenc, Inc. CL Industries, Inc. Chemithon Corp Concord Chemical Co., Inc. Colgate-Palmolive Co Grant Industries, Inc. Croda, Inc Reilly-Whiteman, Inc. Hickson Danchem Corp. Dexter Chemical Corp Dow Chemical Co. E. I. duPont de Nemours &Co., Inc. Chemicals & Pigments Dept. Eastern Color & Chemical Co E. F. Houghton & Co Eastman Kodak Co., Tennessee Eastman Co. Div. Emkay Chemical, Inc. Exxon Chemical Americas Enenco, Inc. Essential Industries, Inc. Ethox Chemicals, Inc. Ferro Corp. Keil Chemical Div. Flambeau Paper Corp. Finetex, Inc.

GAF GDC GRL

ISP Chemicals, Inc. Gresco Mfg., Inc. Calgon Corp., Calgon Vestal Laboratories Div. C. P. Hall Co. Hoechst Celanese Corp., Sou-Tex Works Hodag Chemical Corp. Hewitt Soap Co., Inc. High Point Chemical Corp. W. R. Grace & Co., Hampshire Chemicals Div. and Organic Chemical Div. Huntington Laboratories, Inc. Hercules, Inc. Hart Products Corp. Hexcel Corp., Hexcel Chemical Products ICI Americas, Inc., Specialty Chemical; Div. J. L Prescott Co. Andrew Jergens Co. JIM Products, Inc. Jetco Chemicals, Inc. Kenrich Petrochemicals, Inc. Kaneka Texas Corp. Leatex Chemical Co. Lever Brothers Co. Lake States Div. of Rhinelander Paper Co. Ugnotech (U.S.), Inc. Moretex Chemical Products, Inc. Milliken & Co., Milliken Chemical Div. Mona Industries, Inc. Monsanto Co. Morton International, Inc., Morton Chemical Div. Marlowe-Van Loan Corp. Niacet Corp. Ruetgers-Nease Chemical Co. Namico, Inc. Safeway, Inc. National Starch & Chemical Co. Omega Chemicals, Inc. Olin Corp. Yorkshire Pat-Chem, Inc. Piedmont Chemical Industries, Inc. Pelron Corp. Procter & Gamble Co., Procter & Gamble Mfg. Co. Pilot Chemical Co.

ECC EFH EKT EMK ENJ ENO ESS ETC FER FPC FTX

See note at end of table.

.

.

.

HAL HCL HDG HEW HIP HMP

HNT HPC HRT HXL ICI JLP JRG JTM JTO KPI KTX LEA LEV LKY MAR MCP MIL MOA MON MRT MRV NCC NES NMC NPR NSC OC OMC PAT PCI PEL PG PIL

Synthetic Organic Chemicals, 1991 Table 12-3—Continued Surface-active agents: Directory of manufacturers, alphabetical by code, 1991

Code

Name of company

Code

Name of company

PNX PPG PSP QCP RAY RDA RH RSA S

Murphy-Phoenix Co. PPG Industries, Inc. Georgia-Pacific Corp., Bellingham Div. Quaker Chemical Corp. ITT Rayonier Liguin Products, Inc. Rhone-Poulenc, Inc. Rohm & Haas Co R.S.A. Corp. Sandoz, Chemical Corp., Colors & Chemicals Div. Scher Chemicals, Inc. SBS Products Inc. Henkel Corp. Sandoz Chemical Corp . Sterling Drug, Inc., Sterling Organics Div. Shell Oil Co., Shell Chemical Co Sherex Chemical Co., Inc. Soluol Chemical Co., Inc. Salem Oil & Grease Co. SSC Industries, Inc. Sequa Chemicals, Inc. Stepan Co

SVC TCC TEN

Karlshamns, USA Sybron Chemicals, Inc. BIT Manufacturing, Inc. Harcros Chemicals, Inc. Ethyl Corp. Gillette Chemical Co. Texaco Chemical Co. Union Carbide Corp., Industrial Chemical Div. United Aniline Co. Uniroyal Chemical Co., Inc. Unitex Chemical Corp. Wider Co. ISP-Van Dyk, Inc. Vista Chemical Inc. Dryden Oil Co., of New England Whittemore-Wright Co., Inc. lnolex Chemical Co. West Point-Pepperell, Inc., Grifftex Chemical Co. Sub. Witco Corp. Westvaco Corp.

SBC SBP SCP SDC SDW SHC SHX SLC SLM SOS SQA STP

.

TMH TNA TNI TX UCC UNN USR UTC VKR VND VST WBG WHW WM WPG

WTC WVA

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Synthetic Organic Chemicals, 1991

Section 13 Pesticides and Related Products Pesticides and related products include fungicides, herbicides, insecticides, rodenticides, and related products such as plant growth regulators, seed disinfectants, soil conditioners, soil fumigants, and synergists. The data are given in terms of 100 percent active materials; they exclude such materials as diluents, emulsifiers, and wetting agents. U.S. production of pesticides and related products in 1991 amounted to 452 million kilograms. 19 percent less than the 557 million kilograms reported for 1990 (table 13-1). Sales in 1991 were 445 million kilograms, an increase of 1 percent, as compared with 442 million kilograms reported in 1990; the value of sales was $4,019 million in 1991, compared with $4,774 million in 1990, a decrease of 16 percent. Data for production of pesticides and related products during 1987-91 are shown in figure 13-1. Production of cyclic pesticides and related products amounted to 300 million kilograms in 1991, 17 percent

less than the 361 million kilograms produced in 1990. Sales in 1991 were 242 million kilograms, valued at $2,835 million, compared with 280 million kilograms, valued at $3,367 million, in 1990. Production of acyclic pesticides and related products in 1991 amounted to 151 million kilograms, compared with 196 million kilograms reported for 1990. Sales in 1991 were 203 million kilograms, compared with 161 million kilograms reported for 1990; the value of sales was $1,184 million in 1991, compared with $1,407 million in 1990. Table 13-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 13-3. Cynthia Trainor 202-205-3354 Stephen Wanser 202-205-3363

Figure 13-1 Pesticides and related products: U.S. production, 1987-91

Millions of kilograms 700

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 13-1

Section 13 Table 13-1 Pesticides and related products: U.S. production and sales, 1991 Sales Production

Quantity

Value

Average Unit value1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

451,503

445,336

4,019,223

$9.03

300,146

242,171

2,834,941

7.49

36,504 227,278 33,241 3,123

32,340 166,594 40,275 2,962

242,187 1,814,895 761,636 16,223

7.49 10.89 18.91 5.48

151,357

203,165

1,184,282

5.83

Fungicides5 Herbicides and plant growth regulators6

7,606 48,344

5,212 84,482

39,272 773,831

7.54 9.16

Insecticides, rodenticides, soil conditioners, and fumigants, total

86,319

105,023

318,062

3.03

13,325 9,937

10,512 38,588

120,692 16,784

11.48 .43

63,057

55,923

180,586

3.23

9,088

8,448

53,117

6.29

Pesticides and related products

Cyclic Grand total Total Fungicides2 Herbicides and plant growth regulators 3 Insecticides and rodenticides4 All other cyclic pesticides Acyclic Total

Organophosphorus insecticides? N-Methyldithiocarbamic acid (Metham) All other acyclic insecticides, rodenticides, soil conditioners, and fumigants 8 All other acyclic pesticides

1 Calculated from unrounded figures. 2 Includes benomyl, captan, chlorothalonil, DMTT, folpet, pipron, and others. 3 Includes alachlor, atrazine, benefin, bensulide, 2,4-D and other 2,4-D esters

and salts, dicamba, dinitrophenol compounds, diuron, maleic hydrazide, molinate, NPA, pidoram, prometon, triazines, trifluralin, plant growth regulators, and others. 4 Includes phosphorothioates and phosphorodithioates, chlorinated insecticides (heptachlor and others), insect attractants, DEET and other insect repellents, and others. 5 Includes dithiocarbamates. 6 Includes butylate, EPTC, methanearsonic acid salts, thiocarbamates, and organophosphorus herbicides, and others. 7 Includes acephate, disulfoton, ethion, and other organophosphorus insecticides. 8 Includes, methyl bromide, soil conditioners and fumigants, small quantities of rodenticides, and others. Note.-Does not include data for the insect fumigant, p-dichlorobenzene, nor the fungicide, o-phenylphenol. These data are included in the section on "Cyclic Intermediates." It also does not include data for the fungicides, dimethyldithiocarbamic acid, sodium salt and dimethyldithiocarbamic acid, zinc salt (i.e., ziram). These data are included in the section on "Rubber-Processing Chemicals." The data for ethylene dibromide, a fumigant, are included in the "Miscellaneous End-Use Chemicals and Chemical Products" section. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

13-2

Synthetic Organic Chemicals, 1991 Table 13-2 Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Pesticides and related products Cyclic: Fungicides: 2-Bromo-4'-hydroxyacetophenone a-(2-ChlorophenyI)-a-(4-chloropheny1)-5pyrimidinemethanol a-(2-ChlorophenyI)-a-(4-fluoropheny1)-5pyrimidinemethanol 1,4-Dichloro-2,5-dimethoxybenzene (Chioroneb) 5-Ethoxy-3-(trichloromethyl)-1,2,4-thiadiazole Hexahydro-1 ,3,5-triethyl-s-triazine Hexahydro-1,3,5-tri(2-hydroxyethyI)-s-triazine 2-Mercaptobenzothiazole, sodium salt Methyl-1-(butylcarbamoyl) -2-benzimidazolecarbamate (Benomyl) 3-(2-Methylpiperidino)propy1-3,4-dichlorobenzoate (Pipron) Naphthenic acid,copper salt 2-n-Octyl-4-isothiazolin-3-one Pentachloronitrobenzene (PCNB) Pentachlorophenol,sodium salt 2,4,5,6-Tetrachloroisophthalonitrile Tetrahydro-3,5-dimethy1-2H-1,3,5-thiadiazine-2thione (DMTT) 2-(Thiocyanomethylthio)benzothiazole N-Trichloromethylthio-4-cyclohexene-1,2dicarboximide (Captan) All other cyclic fungicides Herbicides and plant growth regulators: 4-Amino-6-(1,1-dimethylethyl)-3-(methylthio) -1,2,4-triazin-5-(4H)-one 4-Amino-3,5,6-trichloropicolinic acid (Pidoram) S-Benzyl thiocarbamate 4,6-Bis(isopropylamino)-2-methoxy-s-triazine (Prometon) 2,4-Bis(isopropylamino)-6-(methylthio)-s-triazine (Prometryn) 5-Bromo-3-sec-butyl-6-methyl.uracil (Bromacil) 2-(sec-Butylamino)-4-ethylammo-6-methoxy-striazine 2-(tert-Butylamino)-4-ethylamino-6-(methylthio)-striazine 3-tert-Butyl-5-chloro-6-methyluracil N-Butyl-N-ethyl-a,a,a-trifluoro-2,6-dinitro-ptoluidine (Benefin) Butyl 244-ff5-(trifluoromettly1)-2-pyridinylloxy]phenoxylpropanoate 1-(carboethoxy)ethyl 5[2-chloro-4-(trifluoromethyl) phenoxy]-2-nitrobenzoate NiChloroacety1)-N-(2,6-diethylphenyl)glycine, ethyl ester 2-Chloro-4,6-bis(ethylamino)-s-triazine (Simazine) 2-Chloro-2',6'-diethyl-Nin-butoxymethyl)acetanilide (Butachior) 2-Chloro-2',6'-diethyl-N-(methoxymethyl)acetanilide (Alachlor) 2-Chloro-N-ethoxymethy 1-N-(2-ethyl-6-methylpheny1)-acetamide (Acctochlor) See footnotes at end of table.

Separate statistics1

Manufacturers' Identification codes (according to list in table 13-3)

No

BKM.

No

LIL.

No No No No No No

LIL. CHF. USR. VNC .

No

DUP.

No No No No No No

LIL, USR. CCA, MCI, NOD, TRO. RH. AMV, USR. FRO. SDS.

No No

BKM, MRK, RH, VCC. BKM.

No No

!CI,(2).._ FER, NOD, (2).

No No No

CHG, DUP. DOW. ICI.

No

CGY.

No No

COY. DUP.

No

CGY.

No No

COY. DUP.

No

DOW, LIL

No

(2).

No

SOC.

No No

RMI. CGY.

No

MNA.

No

MNA.

No

MNA.

P:

Section 13 Table 13-2--Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Pesticides and related products Cyclic—Continued: Herbicides and plant growth regulators—Continued: 2-Chloro-1-(3-ethoxy-4-nitrophenoxy)-4(trifluoromethyObenzene(Oxyfluorfen) 2-Chloro-4-(ethylamino)-6-(isopropylamino)-striazin (Atrazine) 214-Chloro-6-(ethylamino)-s-triazin-2-ylamino]-2methylpropionitrile (Cyanazine) 2-Chloro-N-isopropylacetaniiide (Propachlor) 2-Chloro-N-[(4-methoxy-6-methy1-1,3,5-triazin-2-y1)aminocarbonyl]benzenesulfonamide 2-(4-Chloro-2-methylphenoxy)propionic acid, dimethylamine salt 2-(2-ChlorophenyOmethy1-4,4-dimethyl-3isoxazolinone 5-[2-Chloro-4-(trifluoromethyl)phenoxy]-2nitrobenzoic acid, sodium salt 3-Cyclohexy1-6-(dimethylamino)-1-methy1-1,3,5triazine-2,4-(l H,3H)-dione 3,6-Dichloro-2-anisic acid (Dicarnba) 2,6-Dichlorobenzonitrile 2-(2,4-Dichlorophenoxy)propionic acid, dimethylamine salt 3-(3,4-Dichloropheny0-1,1-dimethylurea (Diuron) 3-(3,4-DichlorophenyI)-1-methoxy-1-methylurea (Unuron) 2-(3,4-Dichloropheny1)-4-methy1-1,2,4oxadiazolidine-3,5-dione (Methazole) 1 -[-(2,4-Dichloropheny94-propy1-1,3-dioxolan-2 ylmethyI]-1H-1,2,4-tnazole 3,6-Dichloropicolinic acid 3',4'-Dichloropropionanilide (Propanil) 3,7-Dichloro-8-quinolinic acid N-2,6-Difluoropheny1)-5-methy1-1H-1,2,4-biazolo1,5-al-pyrimidine]-2-sulfonamide S- O,O-Diisopropyl phosphorodithioate) ester of N(a-mercaptoethyl)benzenesulfonamide (Bensulide) 1,1'-Dimethy1-4,4'-bipyridinium dichloride Dimethy1-2,3,5,6-tetrachloroterephthalate (DCPA) 2,6-Dinitro-N,N-dipropyl cumidine 2-(Ethylamino)-4-(isopropylamino)-6-(methylthio)-striazine (Ametryne) Ethyl 2-E(4-chloro-6-methoxypyrimidin-211)aminolcarbonyl]amino]suffonyflbenzoate (Chlonmuron ethyl) S-Ethyl cyclohexylmethy1thiocarbamate S-Ethyl-hexahydro-1H-azepine-1-carbothioate (Molinate) N-p-(1 -Ethyl-l-methylpropy1)-5-isoxazolyg-2,6dimethoxybenzamide (Flexidor) Hexahydro-1,3,5-tris(2-hydroethyl)-5-triazine Methyl 3-ff[(4-methoxy-6-methy1-1,3,5-triazin-2yl)amino carbonyllamino]sulfony1-2-thiophenecarboxylic acid 2-Methyl-4-chlorophenoxy acid dimethylamine salt (MCPA DMA) 2-(2-Methyl-4-chlorophenoxy)propionic acid (MCPP) See footnotes at end of table.

13-4

Separate statisticsi

Manufacturers' identification c odes (according to list in table 13-3)

No

RH.

No

CGY, DUP.

No No

DUP. MNA.

No

DUP.

No

RIV.

No

FMN, (2).

No

BAS.

No No No

DUP. ZOC. USR.

No No

RIV. DUP.

No

DUP.

No

ZOC.

No No No No

ICI. DOW. CED, RH. BAS, NES.

No

(2).

No No No No

ICI. SOS. LIL.

No

CGY.

No No

DUP. ICI.

No

ICI.

No No

LIL, RIV. (2).

No

DUP.

No

DOW.

No

DOW.

Synthetic Organic Chemicals, 1991 Table 13-2—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Pesticides and related products

Separate statistics

Cyclic—Continued: Herbicides and plant growth regulators—Continued: 2-(2-Methyl-4-chlorophenoxy)propionic acid dimethylamine salt (MCPA DMA salt) No 2-(2-Methyl-4-chlorophenoxy)propionic acid, isooctyl ester No 1-(2-Methylcyclohexyl)-3-phenylurea (Siduron) No Methyl 2-aff(4,6-dimethozypyrimidin-2-y1)amino]carbonygamino]sulfonyl]methyl]benzoate (Bensulfuron) (Londax) No Methyl 2411[(4,6-dimethy1-2-pyrimidinyl)amino]carbonylaminoisulfonylibenzoate No Methyl 2-[[[[(4-methoxy-6-methyl-1,3,5,-triazin-2-y1)arnino]carWnyliaminojsuffonyllbenzoate (Metsulfuron methyl) No Methyl 2-aRN-(4-methozy-6-methyl-1,3,5-triazin-2y1)thylaminoicarbonyliaminojsuffonyl]benzoate No 1-Methyl-3-pheny1-5-[3-(trifluoromethyl)pheny1]4(1H)-pyridone (Fluridone) No N-1-Naphthylphthalamic acid (NPA) No 7-Ozabicyclo(2.2.1]-heptane-2,3-dicarboxylic acid, disodium salt (Endothall) No Tetrahydrofurfuryl (r)-2-[4-(6-chloroquinoxalin-2yloxy)phenoxy] propanoate No Phenoxyacetic acid derivatives: 4-Chloro-2-methylphenoxyacetic acid (MCPA) No 4-Chloro-2-methylphenoxyacetic acid, dimethylamine salt No 4-Chloro-2-methylphenoxyacetic acid, iso-octyl ester No 2,4-dichlorophenoxyacetic acid, esters and salts: 2,4-Dichlorophenoxyacetic acid (2,4-D) No 2,4-Dichlorophenoxyacetic acid, 2-butoxyethyl ester No 2,4-Dichlorophenoxyacetic acid, sec-butyl ester No 2,4-Dichlorophenoxyacetic acid, dimethylamine salt No 2,4-Dichlorophenoxyacetic acid, ethanolamine and isopropanolamine salts No 2,4-Dichlorophenoxyacetic acid, iso-octyl ester No 2,4-Dichlorophenoxyacetic acid, isopropyl ester No 2,4-Dichlorophenoxyacetic acid, lithium salt No Al! other 2,4-dichlorophenoxyacetic acid, esters and salts No Plant growth regulators: 2-Chloro-N-(2,6-dinitro-4-(trifluoromethyl)phenyl) -N-ethyl-6-fiuorobenzenemethanamine No 13-(4-Chlorophenyl)methyl-a-(1,1-dimethylethyl)-1, 2,4-triazole-1-ethanol No 2-Chloro-6-(trichloromethyl)pyridine No a-Cyclopropyl-a-(p-methoxyphenyI)-5-pyrirnidine methanol (Ancymidol) No 2,3-Dihydro-5,6-dimethy1-1,4-dithiln-1,1,4,4tetraoxide No 1,2-Dihydro-3,6-pyridazinedione (Maleic hydrazide) (MH) No

Manufacturers' Identification codes (according to list in table 13-3)

DOW. DOW, RIV. ADC, DUP. DUP. DUP. DUP. DUP. LIL. USR. PAS. USR. DOW. RIV. RIV. DOW. DOW. DOW. DOW, PBI, RIV. DOW. DOW, RIV. AMV. GTH. ICI. CGY. ICI. DOW. LIL. NES. DRX, USR.

See footnotes at end of table.

13-5

Section 13 Table 13-2—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Pesticides and related products Cyclic—Continued: Plant growth regulators—Continued: 1 ,1 -Dimethylpiperidinium chloride Gibberellic acid a-(1 -Methyl ethyl-x-4-trifluoro-methoxypheny1)-5pyrimidinemethanol (Flurprimidol) All other plant growth regulators, cydic 3,5,6-Trichloro-2-pyridinyloxyacetic acid a,a,a-Trifluoro-2,6-dinitro-N,N-dipropyl-ptoluidine (Trifluralin) a,a,a-Trifluoro-2,6-dinitro-N-ethyl-N-(2-methy1-2propeny1)-p-toluidine (Ethylfluralin) All other cyclic herbicides Insect attractants and repellents: N,N-Diethyftoluamide (DEET) All other insect attractants Insecticides: Bacillus thuringiensis Bis(pentachloro-2,4-dicyclopentadien-1 -y1) 2-(p-tert-Butylphenoxy)cyclohexy1-2-propynyl sulfite Cyano(4-fluoro-3-phenoxyphenyl)methy1-3-(2,2dichloroetheny1)-2,2dimethylcyclopropanecarboxylate Cyano-3-phenoxybenzyl-cis, trans-3-(2,2dichlorowny1)-2,2-dimethylcyclopropane carboxylate Cyano(3-phenoxyphenyl)methy1-4-chloro-a-(1methylethyi)benzeneacetate All other cyclic insecticides N-cyclopropy1-1,3,5-triazine-2,4,6-triamine Cypermethnn 2,3-Dihydro-2,2-dimethy1-7benzofuranyl[(dibutylamino)thio]rnethylcarbamate 2,3-Dihydro-2,2-dimethyl-7-benzofuranyl methyicarbamate 5,6-Dimethyl-2-dimethylamino -4-pyrimidinyl dimethyl carbamate Di-n-propylisocinchomeronate Hexakis(2-methyl-2-phenylpropyl), distinnaxane Methyl 3-(2,2-dichloroetheny1)-2,2-dimethy1-3-cyano3-phenoxyphenylcyclopropanecarboxylate 3-(Phenoxyphenyl) methyl-cis, trans-3-(2,2 dichloroethenyl)-2,2-dimethyl cyclopropanecarboxylate Tetrahydro-5,5-dimethyl-2(1 H)-pyrimidinone[3-[4(trifluoromethyl)pheny1]-1-[244-(trifluoromethyl)phenyflethenyl-2-propenylidene]hydrozone Chlorinated insecticides: 2-Chloro-N-M4-(trifluoromethoxy)phenyl]aminolcarbonypenzamide Heptachloro-tetrahydro-endo-methanoindene (Heptachlor) 1 , 1 ,1 -Trichloro-2,2-bis(p-methoxyphenyl)ethane (Methoxychlor) Organophosphorus insecticides: O-(2,4-Dichlorophenyl) 0-ethyl S-propyl phosphorodithioate See footnotes at end of table.

13-6

Separate statistical

Manufacturers' identification codes (according to list in table 13-3)

No No

BAS. ABB.

No No No

LIL. MMM. DOW.

No

LIL.

No No

LIL. FRI, ICI, RH, SOC, ZOC, (2).

No No

(9:

No No

ABB, DUP, ZOC. ZOC.

No

USR.

No

FMN.

No

(2).

No No No No

DUP. FMN, ZOC. CGY. FMN.

No

FMN.

No

FMN.

No No No

FSN. MGK. DUP.

No

FMN.

No

FMN, (2).

No

FMN.

No

CHG.

No

VEL.

No

CHF.

No

CHG.

Synthetic Organic Chemicals, 1991 Table 13-2—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Pesticides and related products

Separate statistics

Manufacturers' identification codes (according to list in table 13-3)

No

(2).

No

DOW.

No

DUP.

No

CHG.

No

ICI.

No No

ICI. (2).

No

MOT.

No No No No

11T. MOT. MOT.

No No

ALP. ICI.

No

MGK.

No No No

BKM. ICI.

No No

BKM. MRK.

No

VIN.

No

BKM.

No

ALC, BKM.

No

ALC, VCC.

No

DUP.

No No No No

BKM. BKM. DUP. BKM, MRK.

No No No No No

ICI.

Cyclic—Continued: Insecticides—Continued: 0-(2-(Diethylamino)-6-methyl (4-pyrimidinyl) 0,0dimethyl phosphrothioate 0,0-Diethyl 0-3,5,6-trichloro-2-pyridyl phosphorothioate 0,0-Dimethyl 0-(2,4,5-trichloropheny1)phosphorothioate (Ronne!) 0-Ethyl 0[4-(methylthio)phenyl] S-propyl phosphorodithioate N-(Mercaptomethyl)phthalimide S-(0,0dimethylphosphorodithioate) 0,0'-(Thiodi-4,1-phenylene)bis(0,0-dimethyl phosphorothioate (Temphos) All other organophosphorus insectides, cyclic Rodenticides: 3-(a-AcetonylbenzyI)-4-hydroxycoumarin (Warfarin) -biphenyi-4-y1)-1,2,3,4biphenyl' 343-(4'tetrahydro-1-naphthalenyr -4-hydroxy-2H-1benzopyran-2-one 2-Diphenylacety1-1,3-indandione and sodium salt 2-lsovalery1-1,3-indandione 2-Pivaloy1-1,3-indandione (Pindone) All other cyclic pesticides: a-[2-(2-n-Butoxyethoxy)ethoxy]-4, 5-methylenedioxy-2-propyltoluene (Piperonyl butoAde) N,N-diallyI-2,2-dichloroacetarride N-(2-Ethylhexyl)bicyclo(2.2.1)-5-heptene-2,3dicarboximide 1-Methyl-3,5,7-triaza-1-azonia tricyclodecane chlonde 2,2,5-Trimethy1-3-(dichloroacety1)-1,3-oxazolidine All other pesticides and related products, cyclic

(2).

Acyclic: Fungicides: Disodium cyanodithioimidocarbonate n-Dodecylguanidine acetate (Dodine) Methylenebis(thiocyanate) Poly[oxyethylene(dimethylimino)ethylene(dimethylimino)ethylene dichloride] Dithiocarbamic acid fungicides: Dimethyldithiocarbamic acid, potassium salt Ethylene bis(dithiocarbamic acid), disodium salt (Nabam) Ethylene bis(dithiocarbamic acid), manganese salt with zinc ions Hydroxymethyl(methyl)dithiocarbamic acid,

potassium salt N-Methyldithiocarbamic acid, potassium salt All other dithiocarbamic acid fungicides, acyclic All other acyclic fungicides Herbicides and plant growth regulators: S-Ethyl diisobutylthiocarbamate (EIL4late) S- Ethyl dipropytthiocarbamate (EP C) Methanearsonic acid,monosodium salt (MSMA) N-(Phosphonomethyl)glycine, isopropylamine salt S-Propyl butylethylthiocatbamate (Pebulate)

ICI. SDS, VIN. MNA. ICI.

See footnotes at end of table. 13-7

Section 13 Table 13-2—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Pesticides and related products Acyclic—Continued: Herbicides and plant growth regulators—Continued: S-Propyl dipropylthiocarbarnate (Vernolate) Thiocyanic acid, methylene ester S,S,S-Tributyl phosphorotrithioate Plant growth regulators: 6-benzyledenine (Bap) All other plant growth regulators, acyclic Acyclic herbicides Insecticides: Ethyl 3,7,11-trimethyldodeca-2,4-dienoate Isopropy1-11-methoxy-3,7,11-trimethyldodeca-2,4dienoate Methyl N',Ne-dimethyl-N-[(methylcarbamoyl)oxy]-1thiooxamidate S-Methyl-N-[(methylcarbamoyl)oxy]thioacetimidate (Methomyl) 2-propynyl 3,7,11-trimethyl-(2e,4e) -dodecadienoate Organophosphorus insecticides: 2-Carbomethoxy-1-propen-2-yldimethyl phosphate 1,2-Dibromo-2,2-dichloroethyl dimethyl phosphate (Naled) 0,0-Diethyl S-(2-(ethylthio)ethyl] phosphorodithioate (Disulfoton) 3-(Dimethoxyphosphinyloxy)-N,N-dimethyl-ciscrotonamide 0,S-Dimethylacetylphosphoramidothioate (Acephate) O,O-Dimethyl-O-2,2-dichlorovinyl phosphate (DDVP) O,S-Dimethyl phosphoramidothioate 0,0,0',0'-Tetraethyl S,S'-methylene bisphosphorodithioate (Ethion) All other organophosphorus insecticides, cyclic Rodenticides: Bromethelin concentrate 2-Hydroxyethyl n-octyl sulfide Sodium fluoroacetate Soil fumigants: 1,3-Dichloropropene Methyl bromide (Bromomethane) N-Methyldithiocarbamic acid,sodium salt (Metham) Trichloronitromethane (Chloropicrin) All other soil fumigants, etc All other acyclic pesticides: 3-Alkoxy-2-hydroxypropyl trimethyl ammonium chloride N-Alkyl-1-naphthylmethyl ammonium chloride Ammonium oxydiethylenebis (alkyl* dimethyl chloride) *Alkyl-40% C12, 50% C14, 10%- C16 Bromoacetic acid N-Cocoalky1-1,3-propylenediamine acetate See footnotes at end of table.

Separate statistical

Manufacturers' identification codes (according to list in table 13-3)

No No No

ICI. BKM. CHG.

No No No

ABB. USR. DUP, SLM, VIN.

No

DOW, ZOC, (2).

No

ZOC, (2),

No

DUP.

No

DUP.

No

(2).

No

AMV.

No

AMV.

No

CHG.

No

DUP.

No

SOC.

No No

AMV. CHG.

No No

FMN. (2).

No No No

DOW. PLC. SLM, TUL.

No No Yes No No

DOW. GTL, TNA. AMV, BKM, ICI. LCP, NLO. MRT.

No No

(2). (2).

No No No

BKM. VIN. (2).

Synthetic Organic Chemicals, 1991 Table 13-2 —Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Pesticides and related products

Separate statistics1

Manufacturers' identification codes (according to list In table 13-3)

Cyclic—Continued: All other acyclic pesticides—Continued: 2-1(Hydroxymethyl)amino]-2-methylpropanol 2- Hydroxymethyl)ethanol 3- odo-2-propynyl butylcarbamate All other pesticides and related products, acyclic

No No No No

TRO. TRO. TRO. USR, ZOC (2).

1 Chemicals for which separate statistics are reported in this section are incicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

13-9

Section 13 Table 13-3 Pesticides and related products: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ABB ADC ALC ALP AMV BAS BKM CCA CED CGY CHF CHG

Abbott Laboratories Anderson Development Co Alco Chemical Corp Alpha Laboratories, Inc. Amvac Chemical Corp. BASF Corp. Buckman Laboratories, Inc Akzo Chemicals, Inc. Cedar Chemical Corp Ciba-Geigy Corp. Kincaid Enterprises, Inc. Mobay Chemical Crop., Agricultural Chemicals Div. Dow Chemical Co Drexel Chemical Corp E. I. duPont de Nemours & Co., Inc. Agricultural Products Ferro Corp., Bedford Chemical Div. FMC Corp. Agricultural Chemical Group Farmland Industries, Inc. Vulcan Materials Co Chemicals Div. Nor-am Chemical Co Guth Corp. Great Lakes Chemical Corp ICI Americas, Inc. Agricultural Chemicals Div. LCP Chemicals-Maine Eli Lilly & Co.

MCI MGK MMM MNA MOT MRK MRT

Mooney Chemicals, Inc. McLaughlin Gormley IGng Co. Minnesota Mining & Manufacturing Co. Monsanto Co., Agricultural Group Motomco, Ltd. Merck & Co., Inc. Morton International, Inc., Morton Chemical Div. Ruetgers-Nease Chemical Co. Nikior Chemical Co., Inc. Huls America, Inc. ELF Atochem North America, Inc. PBI-Gordon Corp. Phillips 66 Co. Rohm & Haas Co. Riverdale Chemical Co. R-M Industries, Inc. ISK Biotech Corp. Salem Oil & Grease Co. Chevron Corp., Chevron Chemical Co. Ethyl Corp. Troy Chemical Corp. Tull Chemical Co., Inc. Uniroyal Chemical Co., Inc. \finings Industries, Inc. Velsicol Chemical Corp. Vineland Chemical Co., Inc. Vanderbilt Chemical Corp. Sandoz Crop Protection

DOW DRX DUP FER FMN FRI FRO FSN GTH GTL ICI LCP LIL

.

.

.

.

NES NLO NOD PAS PBI PLC RH RIV RMI SDS SLM SOC TNA TRO TUL USR VCC VEL VIN VNC ZOC

Note.— Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

13-10

Synthetic Organic Chemicals, 1991

Section 14 Miscellaneous End-Use Chemicals and Chemical Products

14-1). The sales quantity remained at a level nearly equal to that of 1990 with the value of sales increasing by 2.3 percent. Polymers for fibers and end uses of urea collectively accounted for 58 percent of the 1991 production of these miscellaneous end-use chemicals. The total published end-uses for urea accounted for 47 percent of the 1991 sales quantity of these chemicals. Production of end-use chemicals used in the auto and motor fuels market indicated continued upward trends. Production of fuel additives for 1991 totaled 4,058 million kilograms, a decrease of 3.9 percent from the previous year. Approximately 95 percent of production in this category was methyl t-butyl ether. Table 14-2 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 14-3. David G. Michels 202-205-3352

This section incorporates those end-use groups which are not readily classifiable within the prior sections of this report. Both cyclic and acyclic chemicals fall within this section. Production and sales of the end-use chemicals contained within this section continue to follow a general increase since 1987, although levels in 1991 indicated leveling of economic trends. In 1991, the production of miscellaneous end-use chemicals amounted to 13,467 million kilograms, a decrease of 10.2 percent from the calculated 14,992 million kilograms of production for 1990 (table 14-1). Production of these chemicals steadily increased throughout 1987-90 (figure 14-1). Sales in 1991 totaled 10,712 million kilograms, valued at $9,938 million (table

Figure 14-1 Miscellaneous End-Use Chemicals and Chemical Products: U.S. production, 1987-91

Billions of kilograms 16

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

14-1

Section 14 Table 14-1 Miscellaneous end-use chemicals and chemical products: U.S. production and sales, 1991 Sales Miscellaneous end-use chemicals and chemical products

Grand total Chelating agents, nitriloacids and salts, total (Diethylene trinitrilo)pentaacetic acid (Diethylene trinitrilo)pentaacetic acid, pentasodium salt (Ethylenedinitrilo)tetraacetic acid (EDTA) (Ethylenedinitrilo)tetraacetic acid, diammonium salt (Ethylenedinitrilo)tetraacetic acid, disodium

salt (Ethylenedinitrilo)tetraacetic acid, tetrasodium salt (N-Hydroxyethylethylenedinitrilo)triacetic acid, trisodium salt All other chelating agents, nitriloacids and salts

Production

Quantity

Value

Average Unit value1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

13,466,793

10,711,931

9,938,366

$0.93

135,979

128,995

160,449

1.24

(2)

90

310

3.44

10,438 2,945

6,748 2,178

9,800 4,377

1.45 2.01

763

732

1,063

1.45

931

730

2,977

4.01

47,191

50,734

44,003

.87

(2)

2,112

3,054

1.45

73,711

65,671

94,865

1.44

(2) (2) (2)

(2) (2) (2)

22,663 6,640 41,070

(2) (2) (2)

4,058,002

2,572,180

1,023,023

.40

3,856,456 201,546

2,497,602 74,578

826,101 196,922

.33 2.64

394,827

361,182

609,345

1.69

119,963 35,626 239,238

94,422 32,267 234,493

159,088 57,432 392,825

1.68 1.78 1.68

7,171

4,162

66,474

15.97

2,388,293

1,603,893

5,045,489

3.15

1,065,992 1,322,301

(2) 1,603,893

(2) 5,045,489

(2) 3.15

Enzymes: Bacterial amylase Other hydrolytic enzymes Rennin Fuel additives, tote Methyl t-butyl ether's 5 All other fuel additives Lubricating oil and grease additives, total Oil soluble petroleum sulfonate, calcium salt Sulfur compounds All other lubricating oil and grease additives Photographic chemicals Polymers for fibers, totals Polyethylene terephthalate for fiber All other polymers for fibers See footnotes at end of table.

14-2

Synthetic Organic Chemicals, 1991 Table 14-1-Continued Miscellaneous end-use chemicals and chemical products: U.S. production and sales, 1991 Sales Miscellaneous end-use chemicals and chemical products

Polymers, water soluble, total

Production

Quantity

Value

Average Unit value1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

343,909

286,313

853,640

$2.98

54,264 (2) 16,152 29,143

19,603 65,434 (2) 30,200

71,785 298,054

3.66 4.56

84,852

2.81

160,277

142,001

313,997

2.21

Sodium ammonium polyacrylate and copolymers All other polyacrylic acid salts All other water soluble polymers

71,457 88,820 84,073

67,112 74,889 29,075

146,451 167,546 84,952

2.18 2.24 2.92

Textile chemicals, other than surface-active agents

22,367

20,337

27,436

1.35

573,631 1,400,656 3,474,398

551,155 1,178,232 3,324,050

62,441 189,903 511,817

.11 .16 .15

667,560

681,432

1,317,976

1.93

Acrylamide polymers and co-polymers Cellulose esters and ethers Hydroxethylcellulose Sodium carboxymethyl cellulose Polyacrylic acid salts, total

Urea in compounds or mixtures: In feed compounds In liquid fertilizer In solid fertilizer All other miscellaneous end-use chemicals and chemical products

(2)

(2)

Calculated from unrounded figures. Reported data were accepted in confidence and may not be published, or no data were reported. Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given with the section on "Plasticizers." 4 The difference between theproduction reported here and that shown on the Preliminary Report on U.S. Production of Selected Organic Chemicals (including Synthetic Plastics and Resins Materials, 1991, results from a combination of incorrect reporting by some companies, end-of-year inventory adjustment, and rounding. 5 Production totals shown for this chemical include quarterly production data in instances where companies reported inaccurate annual data or failed to report annual data. Totals also include reporting by companies which failed to report on a quarterly basis. 6 Although production of nylon 6 and 6/6 are published in the Preliminary Report revised annual data are not published because disclosure might result. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 1

2 3

Section 14 Table 14-2 Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Miscellaneous end-use chemicals Amino acids and their salts: Aspartic acid N,N-Bis(2,2-acetamido)glycine Glutamic acid hydrochloride Glycine (Aminoacetic acid), non-medical Potassium glutamate Methionine and its salts: Methionine (animal feed grade) Methionine, hroxy analogue, calcium salt Protein hydrosylates Sarcosine All other amino acids and salts, acyclic All other amino acids and salts, cyclic Biological stains: Biological stains Chelating agents, nitriloacids and salts: N-Alicylamine bismethylenephosphonic acid N-Aikylaminobismethylene phosphonic acid salts (Diethylenetriamine)pentamethylenephosphonic acid (Diethylenetriamine)pentamethylenephosphonic acid, sodium salt (Diethylenetrinitrilo)pentaacetic acid (Diethylenetrinitrilo)pentaacetic acid, pentasodium salt N,N-Dihydroxyethylglycine, sodium salt Ethanoldiglycine, disodium salt Ethylenedinitrilo)tetraacetic acid Ethylenediaminetetraacetic acid) (EDTA) Ethylenedinitrilo)tetraacetic acid, calcium disodium salt (Ethylenedinitrilo)tetraacetic acid, diammonium salt (Ethylenedinitrilo)tetraacetic acid, disodium copper salt, dihydrate (Ethylenedinitrilo)tetraacetic acid, disodium salt (Ethylenedinitrilo)tetraacetic acid, disodium zinc salt, dihydrate Ethylenedinitrilltetraacetic acid, magnesium salt Ethylenedinitrilo tetraacetic acid, manganese salt Ethylsnedinitrilo tetraacetic acid, monoammonium ferric salt (Ethylenedinitrilo)tetraacetic acid, monosodium iron salt (Ethylenedinitrilo)tetraacetic acid, tetraamrnonium salt (Ethylenedinitrilo)tetraacetic acid, tetrapotassium salt Ethylenedinitrilo)tetraacetic acid, tetrasodium salt Ethylenedinitrilo)tetraacetic acid, disodium salt lucoheptonic acid, (isomer, sodium salt Glucoheptonic acid, sodium salt Hexamethylenediaminetetra(methylenephosphonic acid), potassium salt Hydroxyethane-1-diphosphonic acid (N-Hydroxyethylethylenedinitrilo) triacetic acid (N-Hydroxyethylethylenedinitrilo)triacetic acid, iron salt (N-Hydroxyethylethylenedinitrilo)triacetic acid, magnesium salt

i

See footnotes at end of table.

14-4

Separate Manufacturers' identification codes statistics (according to list in table 14-3)

No No No No No

PFZ. PIC. LEM. CHT, HMP. LEM.

No No No No No No

DGC. MNA. BRS. HMP. BRS. MI.

No Yes No No No

ALD.

No Yes

MYO. CGY, DOW, HMP.

Yes No No

CGY, DOW, HMP, MYO. HMP. HMP.

Yes

CGY, DOW, HMP.

No Yes

DAN, DOW. CGY, DOW, HMP.

No Yes

DAN, DOW, HMP. CGY, DOW, HMP.

No No No

DOW, HMP. SHC. CGY, HMP.

No

DOW.

No

CGY, FER, HMP.

No

DOW.

No Yes No No No

HMP, a W, HMP, MYO. CGY, HMP. BLZ. BLZ, PFN.

No No No

MYO. MYO. HMP.

No

DOW, HMP.

No

DOW.

DUP. (2). 1(2kA,fg.).

Synthetic Organic Chemicals, 1991 Table 14-2—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1991 Miscellaneous end-use chemicals

Separate Manufacturers' Identification codes statistics', (according to list in table 14-3)

Enzymes: Hydrolytic enzymes: Amylases: a-Amylase (pancreatic) Bacterial amylase Fungal amylases Glucoamylase All other amylases Proteases: Cellulase Papain Protease (bacterial) Rennin All other proteases Other hydrolytic enzymes: Cholesterol esterase Glucose isomerase Pectinase All other hydrolytic enzymes Non-hydrolytic enzymes: Glucose oxidase Glucose-6-phosphate dehydrogenase Glycerol kinase Urease Uricase Flotation reagents: Phosphorodithioates, used as flotation reagents: Dicresylphosphorodithioic acid Dicresylphosphorodithioic acid, ammonium salt Dicresylphosphorodithioic acid, sodium salt Rosin amines Thiocarbaniiide (Diphenyithiourea) Xanthates and sulfides used as flotation reagent: Sodium n-butylxanthate All other flotation reagents,

CGY, DOW, HMP. (2). MVO, HMP. (2). HMP, MON. HMP. BKM, MYO, (2), (2). MYO, (2).

BKM, CGY, HMP, (2), (2). ALD, GFS, NBI, VNC. ENJ, GFS, PAH, PFN, PIC L PLB, REG, REG, RSA, UPJ, UPM, (9, (2).

No Yes No No No

GNR, LEM. GBF, NBI, PMP. LEM. GNR. GBF, (2).

No No No Yes No Yes No No No No

GNR, NBI. GBF. GNR, NBI. PFZ. GBF, PMP, SPR.

No No No No No

BCK. BCK. BCK. BCK. BCK.

Fci FFFFF

Chelating agents, nitriloacids and salts-Continued (N-Hydroxyethylethylenedinitrilo)triacetic acid, trisodium salt Yes Hydroxyethylidene diphosphonic acid, potassium salt No Hydroxyethylidene diphosphonic acid, sodium salt No Nitriioacetic acid, zinc salt No Nitrilotriacetic acid No Nitrilotriacetic acid, trisodium salt No Nitrilo-tris-methylene triphosphonic acid No Nitrilo-tris-methylene triphosphonic acid, sodium salt No 2-Phosphonobutane-1,2,4-tricarboxylic acid, sodium • salt No Polyamine polymethane phosphonic acid No All other chelating agents, nitriloacids and salts No Chemical indicators: Chemical indicators No Chemical reagents and fine chemicals: Chemical reagents and fine chemicals No

ACY. ACY.

BCK, GNR. GBF.. GBF, GNR, JFR, (2).

ACY. USR. DAN.

See footnotes at end of table.

14-5

Section 14 Table 14-2--Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Miscellaneous end-use chemicals Fuel additives: Diesel fuel additives: Hexyl nitrate All other diesel fuel additives, acyclic All other diesel fuel additives, cyclic Fuel oil additives: Adipic acid-diethylenetriamine-epichlorohydrin polymer Di-tert-amyl-phenyl acid phosphate 4,4'-Di-sec-butylaminodiphenylmethane N,N-Dimethy1-1,3-propanediamine polymer with epichiorohydrin, sulfate N,N-Disalicylidene-1 ,2-propanediamine Formaldehyde polymer with ethylenediamine and nonyl phenol derivatives Imidazoline from tall oil fatty acids and diethylenetriamine Polybutylether carbamate Polyethylenepolyamine polymer with 1,4-dihyroxy-2butyne Rust preventing additives Tetrahydropyrimidine from tall oil fatty acids and propylenediamine All other fuel additives, acyclic All other fuel additives, cyclic Gasoline additivies: N,N-Di-sec-butyl-p-phenylenediamine N,N'-Diisopropyl-p-phenylenediamine Ethylene dibromide Methyl-t-butyl ether Methylcyclopentadienylmanganese tricarbonyl N-(1-Methylheptyl)ethanolamine Tetraethyl lead All other gasoline additives, cyclic Lubricating oil and grease additives: Phosphorodithioates (dithiophosphates): Alkyl imidazoline Alkyl succinic anhydride Alkyl terephthalamate Bomyl phenylamine Chlorosulfurized and suffurized compounds: Sulfurized lard oil Sulfurized sperm oil substitutes Di-2-ethylhexylphosphorodithioic acid Diisopropyl hydrogen phosphite Ethylene-propylene copolymer Fatty acid polyamine condensate Hydrocarbon amine, sulfonate acid Hydrocarbon carboxylic acid derivatives (specify) Hydrocarbon phosphorous acid, barium salt Hydrocarbon phosphoryl derivatives Oxidized hydrocarbon mixture Oil-soluble petroleum sulfonates: Oil-soluble petroleum sulfonate, barium salt Oil-soluble petroleum sulfonate, calcium salt Oil-soluble petroleum sulfonate, magnesium salt Oil-soluble petroleum sulfonate, mixed salts Oil-soluble petroleum sulfonate, sodium salt All other oil-soluble petroleum sulfonate Pentaerythritol esters

See footnotes at end of table. 14-6

Separate Manufacturers' identification codes statistics1 (according to list in table 14-3) Yes No No No

DUP. TNA SM.

No No No

W. UPM.

No No

ap, FER, SM, TNA.

No

(a).

No No

PSC.

No No

(2). ALX.

No No No

ap, PAH, UPM. TNA

No No No Yes

TNA, UPM. DUP, TNA. GTL, TNA. AMO, ASH, ATR, CGO, CCP, CNE, CO, CSD, CSP, DA, ENJ, GRS, LYP, MOC, PLC, SM, SOG, SUN, TPC, TX, VLR. TNA UPM. DUP.

No No No No No No No No

QCP.

No No No No No No No No No No No

QCP. ELC. ELC. ALW.

No Yes No No No No No

SOC.

SOC. SOC.

FER, (2), (2).

ALX, FER, (2). TNA, WTC,

SOC, TNA, TX, WTC, (2), (2). WTC, (2).

(2). PAR, WTC. DUP. MON, SOC, TX. FER.

Synthetic Organic Chemicals, 1991 Table 14-2--Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Miscellaneous end-use chemicals Lubricating oil and grease additives-Continued Phenol salts: Alkylphenol, calcium salt Alkylphenol, calcium salt, sulfurized Alkyl phenols Dodecylphenol, sulfurized, calcium salt Nonylphenol, barium salt All other phenol salts Succinimides: Alkenyl succinimide All other succinimdes Sulfur compounds: Aliphatic hydrocarbon sulfides Di-tertiary nonylpolysulfide Triisobutylene polysulfide All other sulfur compounds Polyisobutenyl succinic anhydride 1,3,4-Thiadiazole, 2,5-bis(dialkyldithio) derivatives Tributyl phosphite Trimethylol propane ester Very high molecular weight (>1000) hydrocarbons Zinc dialkyldithiophosphate Zinc dialkylphenol dithiophosphate Zinc dibutyl phosphorodithioate Zinc dihexyl phosphorodithioate Zinc hydrocarbon dithiophosphate All other phosphorodithioates used as lubricating oil and grease additives All other lubricating oil and grease additives, acyclic

Separate Manufacturers' identification codes statistic& (according to list in table 14-3)

No No No No No No

SOC, TX. DIX.

No No

SOC, TNA, TX, (2). SM, (2).

No No No No No No No No No No No No No No

ELC, FER, (2). PAS. AIP. FER, QCP, TNA, (2), (2). FER. ELC. ALW. SCP.

No

ELC, (2).

No

ALW, DUP, ELC, FER, QCP, SCP, SM, TNA, TX, (2).

All other lubricating oil and grease additives, cyclic No Paint driers, naphthenic acid salts: Barium naphthenate No Cadmium naphthenate No Calcium naphthenate No Chromium naphthenate No Cobalt naphthenate No Iron naphthenate No Lead naphthenate No Manganese naphthenate No Naphthenate driers, mixed salts No Rare earths naphthenate No Zinc naphthenate No All other paint dryers, naphthenic acid salts No Photographic chemicals: 4-Drazo-2,5-diethoxyrnorpholinobenzene No 2,5-Diethoxy-4-morpholinobenzenediazonium chloride No p-Diethylaminobenzenediazonium chloride (p-Diazo-N,Ndiethylaniline zinc chloride) No p-Dimethylaminobenzenediazonium chloride (p-Diazo-N,N-dimethylaniline zinc chloride) No N-Ethyl-N-hydroxyethyl-p-phenylenediamine sulfate No p-Morpholiny1-2,5-dibutoxybenzene diazonium chloride No Pheny1-5-mercaptotetrazole No 1-Phenyl-3-pyrazolidone No Poly(viny1-0-suifobenzal) No 4-N-(1-PyrrolidyI)-m-toluenediazonium chloride No All photographic chemicals No

SOC. CCA, FER, WTC. SOC, TNA.

a.C, SOC, TNA, TX. SOC. ELC. ELC. (2).

ENJ, FER, SM, TNA, (2), (2), (2). QCP. CCA. MCI, NOD, TRO. MCI. MCI, NOD, SHP, TRO. MCI, NOD. MCI, NOD, SHP. MCI, NOD, SHP. MCI. NOD. MCI, NOD, TRO. SHP. ALL ALL ALL ALL EKT. ALL FMT. CWN. DUP. ALL ALL, AMD, CHD, DAN, DUP, FMT, (2), (2),

See footnotes at end of table. 14-7

Section 14 Table 14-2—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, Identified by manufacturer, 1991 Miscellaneous end-use chemicals Polymers for fibers: Cellulose acetate Copolyurethane urea Nylon 6 and 6/6: Nylon 6 (Polymer for fiber, only) Nylon 6/6 Polyacrylonitrile and acrylonitrile copolymers Polyethylene terephthalate Poly-p-phenylene terephthalamide All other polymers for fibers Poly-m-phenylene isophthalamide Polymers, water soluble: Acrylamide polymers and co-polymers: Acrylamide-2-acrylamido-2-methylpropanesulfonic acid, sodium salt polymer Acrylamide-acrylic acid copolymer, sodium salt Acrylamide-trimethylaminoethyl acrylate chloride polymer Acrylamide-trimethylaminoethyl methacrylate chloride Adipic acid-crosslinked polycrylamide Polyacrylamide All other polyacrylamide copolymers Cellulose esters and ethers: Hydroxyethylcellulose Hydroxyethyl hydroxypropyl cellulose 2-Hydroxypropyl cellulose Methylcellulose Sodium carboxymethylcellulose (100%) All other cellulose ethers and esters Dimethylamine epichlorohydrin ethylenediamine copolymer Ethyl acrylate methacrylic acid copolymer Hydroxypropyl guar gum Poly(acrylic acid, ethyl ester) Poly(acrylic acid, methyl ester/ethylene/1,1dichlorosuccinic acid, methylene-) with ethyl acrylate Polyacrylic acid salts: Ammonium polyacrylate Polyacrylate methacrylate copolymers Polyacrylate poly(hydroxypropylacrylate) copolymer Polyacrylic acid Sodium ammonium polyacrylate and copolymers Sodium carboxymethyl amylose Sodium carboxymethyl starch Sodium polyacrylate Sodium polyacrylate, grafted All other polyacrylic acid salts Polyacrylonitrile, hydrolyzed Polyacrylonitrile, starch hydrolized polymer Polyamines Polydextrose Poly(diallyldimethylammonium chloride All other polymers, water soluble Polymethacrylic acid, sodium salt Poly(1,1'-(methylimino)bis(3-chloro-2-propanol)tetramethylethylenediamine 1-Vinyl-2-pyrrolidinone, copolymers with vinyl acetate

See footnotes at end of table. 14-8

Separate Manufacturers' Identification codes statistics1 (according to list in table 14-3) Yes No No

EKT. DUP.

No No No Yes No No No

ACS, BLY, CNP. DUP, MON. ACY, BKM, DUP, MON. DUP, EKT, FBI, FRF, GYR. DUP. HCL. DUP.

Yes No No

(2). BKM, (2).

No

(2).

No No No No Yes No No No No Yes No

DM, ENJ, SCP, (2),(2).

No No No No

(2). ALC. AQU. DUP.

No Yes No No No No Yes No No No No No No No No No No No

DUP.

ACY, ENJ, MRK, SOA, (2). ACY, HCL, (2).

AQU, DOW, UCC, UPJ. (2).

AQU. DOW. AQU, CBC, LCS, MAK. AQU, PAH, S.

CCL, RH, (2), (2). RH, (2). 0, (2), (2). ALC, BAS, BFG, DIX, RH, SCP, (2), (2). CCL, SOH. , MYO, SYT, (2).

No

BAS, BFG, DOW, PAH, RH, (2), (2), (2). BKM, GPC, RH. GPC. ENJ, QCP. PFZ. CPS, MRK, (2). BKM, DAN, GAF PRA, RDA, RH, SCP, mfr. (2), (I). (2). ALC.

No

BKM.

No

DAN.

(2).

(2),

Synthetic Organic Chemicals, 1991 Table 14-2—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1991

Miscellaneous end-use chemicals

Separate Manufacturers' identification codes statistic& (according to list in table 14-3)

Polymers, water soluble-Continued

1-Vinyl-2-pyrrolidinone, polymers Xanthan gum Poly-olefins: Poly-a-olefins Poly-a-olefins, sulfurized Rare sugars: I-Arabinose D-Galactose D-Glucosamine hydrochloride D-Maltose All other rare sugars Silicone greases: Silicone greases Tanning materials, synthetic: 1-Naphthalenesulfonic acid,formaldehyde condensate and salt 2-Naphthalenesulfonic acid, formaldehyde condensate and salt 1-Phenol-2-sulfonic acid, formaldehyde condensate (Phenol-formaldehyde,sulfonated) Polyoxyalkylated cyclic amines All other tanning materials, synthetic Textile chemicals, other than surface active agents: AlkylphenoVformaldehyde polymer N,N-bis-(2-Hydroxyethypoctadecanamide N,N-Dibenzylhydroxylamine Dicyanodiamide formaldehyde ammonium chloride polymer Dimethyloldihydroxyethylene urea Formaldehyde polymer with carbamate esters Hydrogenated tallow fatty acid aminoethylethandamine products Lauryl alkyl dimethylamine acetate Lauryl alkyl dimethylamine phosphate Melamine formaldehyde methanol polymer Melamine formaloehyde copolymer Melamine stearyl alcohol polymer Propoxylated starches 2,2',4,4'-Tetrahydroxybenzophenone Tri(behenoyloxymethyptrimethoxymethylmelarnine Urea polymers with formaldehyde and methanol All textile chemicals, other than surface active agents Urea, by end-use markets: Urea, primary solution (report on 100% urea-content basis) Urea in compounds or mixtures (100% basis): Urea in feed compounds (100% basis) Urea in liquid fertilizer (100% basis) Urea in plastics (100% basis) Urea in solid fertilizer (100% basis)

No No

DAN, GAF. PFZ.

No No

SM, SOC, TNA. QCP, SM.

No No No No No

PFN. PFN.

No

DCC, SPD, SWS.

No

RH, S.

No

HMP.

No No No Yes No No No

RH. MIL SCP.

No No No

CCC, DAN, S. ACY, CCC, CHP, DAN, SYT. SYT.

No No No No No No No No No No

CCC.

No

CCC, DUP. CHP, ENJ.

No

ARM, BNP, CAC, CFI, CHN, FRI, HKY, MSC, SOC, SOH, TRI, UOC, WLC, WYC.

Yes Yes

BNP, CAC, HKY, SOH, TRI, WYC. ARM, BNP, CFI, CHN, FRI, HKY, MSC, SMP, SOC, SOH, UOC, (2). BCP, BNP, SOH, TRI. BCP, CAC, CFI, FRI, HKY, SOH, TRI, UOC, WLC, WYC.

No Yes

PFN. BCK.

CC

C . CCC.

CC.

ENJ. SYT. SYT. BAS. SYT. ACY, CCC.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 14-9

Section 14 Table 14-3 Miscellaneous end-use chemicals and chemical products: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

ACS

Allied Signal, Inc. Engineered Materials Sector American Cyanamid Co Air Products & Chemicals, Inc. Ajinomoto USA, Inc. Alco Chemical Corp. Aldrich Chemical Co., Inc. Alliance Chemical, Inc. Albright & Wilson Americas, Inc. Alox Corp. Cyclo Products, Inc. Amoco Corp. Aqualon LaRoche Industries, Inc. Atlantic Richfield Co., Arco Chemical Co. BASF Corp. Beckman Instruments, Inc., Diagnostics System Group Borden Chemical & Plastics Delaware Limited B. F. Goodrich Co. Buckman Laboratories, Inc. Berldey & Co., Inc. Belzak Corp. Terra International, Inc. Bristol-Myers Co. Cominco Fertilizers, Inc. Carbose Corp. Akzo Chemicals, Inc. C.N.C. International, Inc. Catawba-Charlab, Inc. CF Industries, Inc. Citgo Petroleum, Corp. Ciba-Geigy Corp. Chemdesign, Corp. Wil-Gro Fertilizer, Inc. C. H. Patrick & Co., Inc. Chattem, Inc. Oxy Petrochemicals, Inc. DSM Chemicals, North America Conoco Specialty Products, Inc. CPS Chemical, Co., Inc. Fina Oil & Chemical Co. Coastal Refining & Marketing, Inc. Upjohn Co., Fine Chemicals Diamond Shamrock Refining & Marketing Hickson Danchem Corp. Dow Coming Corp

DGC DIX DOW DUP

Degussa Corp. Dixie Chemical Co., Inc. Dow Chemical Co E. I. duPont de Nemours & Co., Inc. ED/IMG Dept. Fibers Dept. Eastman Kodak Co.: Tennessee Eastman Co. Div. Elco Corp. Sub. of Detrex Chemical Industries, Inc. Exxon Chemical Americas Fiber Industries, Inc. Ferro Corp.: Bedford Chemical Div. Keil Chemical Div. Fairmount Chemical Co., Inc. Firestone Tire & Rubber Co., Firestone Fibers & Textiles Co. Farmland Industries, Inc. ISP Chemicals, Inc. International Bio-Synthetics, Inc. GFS Chemicals, Inc. Genencor, Inc. Grain Processing Corp. Citgo Refining & Chemicals, Inc. Great Lakes Chemical Corp. Goodyear Tire & Rubber Co. Hoechst Celanese Corp: Fibers Industrial Div. Sou-Tex Works. Arcadian Corp. W. R. Grace & Co., Organic Chemicals Div. Hampshire Chemical Div. Hercules, Inc. George A. Jeffreys & Co., Inc. Napp Chemicals, Inc. Lyondell Petrochemical Co. MAK Chemical Corp. Mooney Chemicals, Inc. Milliken & Co., Milliken Chemical Div. Monsanto Co., Agricultural Group Marathong Oil Co. Monsanto Co. Merck & Co., Inc. Mississippi Chemical Corp. Mayo Chemical Co., Inc. Novo Nordisk Biochem, Inc. Huls America, Inc.

ACY AIP AJI ALC ALD ALL ALW ALX AMD AMO AQU ARM ATR BAS BCK BCP BFG BKM BLY BLZ BNP BRS CAC CBC CCA CCC CCL CFI CGO CGY CHD CHN CHP CHT CNE CNP CO CPS CSD CSP CWN DA DAN DCC

.

EK E KT ELC ENJ FBI FE R

FMT FRF FRI GAF GBF GFS GNR GPC GRS GTL GYR HCL

HKY HMP

HPC JFR LEM LYP MAK MCI MIL MNA MOC MON MRK MSC MYO NBI NOD

Synthetic Organic Chemicals, 1991 Table 14-3--Continued Miscellaneous end-use chemicals and chemical products: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

PAH PAR PAS PFZ PIC PLB PLC PMP PRA QCP RDA REG RH RSA S

Parish Chemical Co Pennzoil Products Co., Penreco Div. ELF Atochem North America, Inc. Pfizer, Inc. Pierce Chemical Co Pharmacia P-L Biochemicals, Inc Phillips 66 Co. PMP Fermentation Products, Inc. Para-Chem Southern, Inc. Quaker Chemical Corp . Rhone-Poulenc, Inc. Regis Chemical Co Rohm & Haas Co. R.S.A. Corp. Sandoz Chemical Corp., Colors & Chemicals Div. Henkel Corp. Shell Oil Co., Shell Chemical Co. Shepherd Chemical Co. Mobil Oil Corp., Chemical Product Div. Beaumont Refinery Div. J. R. Simplot Co Chevron Corp., Chevron Chemical Co Phibro Refining

SOH SPD

BP Chemicals, Inc. General Electric Co., Silicone Products Div. Scientific Protein Laboratories Sequa Chemicals, Inc. Sun Co., Inc. Wacker Silicones, Corp. Synthron, Inc. Ethyl Corp. Texas Petrochemicals Corp. Triad Chemical Troy Chemical Corp. Texaco Chemical Co. Union Carbide Corp., Industrial Chemical Div. Union Oil Co. of California Upjohn Co. UOP Inc. Uniroyal Chemical Co., Inc. Valero Refining & Marketing Co. Vanderbilt Chemical Corp. Freeport-McMoran Resource Partners Witco Corp. Coastal Chem, Inc.

SCP SHC SHP SM SMP SOC SOG

SPR SQA SUN SWS SYT TNA TPC TRI TRO TX UCC UOC UPJ UPM USR VLR VNC WLC WTC WYC

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in table 1 of the appendix. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Synthetic Organic Chemicals, 1991

Section 15 Miscellaneous Cyclic and Acyclic Chemicals The term "miscellaneous chemicals" as it is used here comprises those synthetic organic products that are not included in the use groups covered by sections I-XIV of this report. They include products that are employed in a great variety of applications. The number of chemicals used extensively for only one purpose is not large. Among the products covered in this section are those used for refrigerants, aerosols, solvents, catalysts, corrosion inhibitors, additives in plastics and food products, and, especially, a wide range of acyclic chemical intermediates. Figure 15-1 shows the trend of production of miscellaneous chemicals during 1987-91, and shows that the substantial rate of increase after 1985 came to an end in 1991. Production in 1991 was practically the same as in 1990, as was the volume of sales. However, the value of sales decreased 3.5 percent, reflecting lower prices as well as a different product mix. U.S. production of miscellaneous cyclic' and acyclic chemicals in 1991 (Table 1-15) amounted to 49.9 billion kilograms; acyclic hemicals comprised 96.4 percent of this section's total production. Because most of the production of miscellaneous chemicals is used internally by their producers to make more advanced intermediates and other Chemical products, their sales are much smaller than their production. In 1991, sales of miscellaneous chemicals were 20.5 billion kilograms, valued at $12.5 billion, compared with 21.2 billion kilograms, valued at $14.5 billion, in 1990. The average unit value of sales in 1991, 66.0 cents per kilogram, was 3.5 percent smaller than the previous year's 68.4 cents per kilogram. Oxygenated hydrocarbons accounted for about 62 percent of the production of all acyclic miscellaneous chemicals, compared with 60 percent in 1990. Production of oxygenated hydrocarbons, which include organic acids, alcohols (the largest group), ketones, esters, ethers, aldehydes, epoxides, and other chemicals, was 30.0 billion kilograms in 1991, a significant increase over the 28.7 billion kilograms produced in 1990. Essentially the same in volume in miscellaneous acyclic chemicals are the alcohols group and the

chlorinated hydrocarbons group, the latter numbering nearly 50 chemicals. Production of chlorinated hydrocarbons was about 12.0 billion kilograms in 1991, about 1.2 billion kilograms less than in 1990. Carbon tetrachloride, dichloromethane, tetrachloroethylene, 1,1,1-trichloroethane, vinyl chloride, and perchlorethylene (among the publishable items) lost ground in production in 1991. However, chloroform, methyl chloride, and some of the smaller items held their own or increased slightly. (Production of several of these chlorinated chemicals, because of their negative effect on stratospheric ozone, is being phased out over a number of years by international agreement.) The alcohols comprise two groups—monohydric alcohols (e.g., methanol synthetic ethyl alcohol) and polyhydric alcohols (e.g., ethylene glycol). Their production in 1991, 11.8 billion kilograms, was 15 percent larger than in 1990. The greatest gain was engendered by certain of the "all other" alcohols. Of those specifically identified, methanol the leader, was up by 5 percent in production in 1991, whereas ethylene glycol, ranking second in production volume, was slightly down. Virtually in a tie for third place among the major categories of miscellaneous acyclic chemicals, each with production between 4.1 and 4.5 in kilograms in 1991, are aldehydes, nitrogenous compounds, and acids/anhydrides. All three groups declined in 1991: production of acids dropped 16 percent from the previous year, that of nitrogenous chemicals 10 percent, and aldehydes 0.8 percent. Noteworthy for increased production in 1991 were butyraldehydes, acrylic acid, dimer acid, and hydrogenated fatty acids. In the other groups in section 15, those that were produced in greater volume in 1991 than in 1990 include benzoyl peroxide, sodium acetate, methyl ethyl ketone, n-butyl acetate, butyl acrylate, vinyl acetate, diethylene glycol monobutyl ether, polyethylene glycol, chlorodifluoromethane (F-22), acyclic peroxides, and phosgene. Table 15-2 lists the products in this section individually identified by manufacturer(s) codes. Table 15-3 lists those codes alphabetically and identifies the manufacturer by name Aimison Jonnard 202-205-3350

Section 15

Figure 15-1 Miscellaneous cyclic and acyclic chemicals: U.S. production, 1987-91 &lions of kilograms

50

30

20

10

1987

1988

1989

1990

1991

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

15-2

Synthetic Organic Chemicals, 1991 Table 15-1 Miscellaneous cyclic and acyclic chemicals: U.S production and sales, 1991 Sales Miscellaneous cyclic and acyclic chemicals

Average unit

Production

Quantity

Value

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

49,753,773

21,359,432

14,689,787

$0.66

1,770,685

723,325

1,525,547

2.11

Benzoic acid esters Benzoic acid salts, total Potassium benzoate Benzoyl peroxide tert-butyl peroxybenzoate Caprolactam Hexamethylenetetramine Lactones Maleic anhydride3 Morpholine

1,615 (2) (2) 7,367 2,905 582,214 31,928 80,202 172,726 24,162

715 17,055 3,139 5,866 2,956 147,828 (2) 10,611 142,857 15,427

1,981 22,212 5,102 33,534 15,683 216,811 (2) 28,127 124,166 26,119

2.77 1.30 1.62 5.72 5.31 1.47 (2) 2.65 .87 1.69

Pinene and derivatives, total

142,645

31,520

33,908

1.08

2,254 21,539 118,852

1,668 21,375 8,477

1,136 24,288 8,484

.68 1.14 1.00

(2)

9,117

20,529

2.25

2,135 1,161 (2)

1,664 1,062 6,391

3,494 4,000 13,035

2.10 3.77 2.04

721,625

339,373

1,002,477

2.95

47,983,088

20,636,107

13,164,240

.64

4,197,068

1,835,077

1,685,961

.92

72,217

75,978

141,397

1.86

5,314 14,029 52,874

3,978 14,217 57,783

18,455 20,602 102,340

4.64 1.45 1.77

508,320

329,424

450,238

1.37

10,103 (2) 3,690 (2)

10,360 1,226 3,562 5,572

23,637 2,707 6,453 14,477

2.28 2.21 1.81 2.60

Grand total Cyclic Total

Pine oil, natural, sulfate Pine oil, synthetic All other pinene and derivatives Succinic anhydride derivatives, total Dodecenylsuccinic anhydride Octenyisuccinic anhydride All other succinic anhydride derivatives All other miscellaneous cydic chemicals Acyclic Total Nitrogenous compounds Total Amides, total Erucamide N,N'-Ethylenebis-stearamide All other amides Amines, total's Butylamines, total n-Butylamine Di-n-butylamine All other butylamines See footnotes at end of table.

Section 15 Table 15-1-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1991 Sales Miscellaneous cyclic and acyclic chemicals

Production

Quantity

Value

Average unit value1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Acyclic-Continued Nitrogenous compounds-Continued Amines-Continued Diethylenetriamine Dimethylaminopropylamine Diethylamine Ethylenediamine Triethylamine Triethylenetetramine All other amines Aminoethylethanolamine Ethanolamines, total 3 2,2'-Aminodiethanol (Diethanolamine) 2-Aminoethanol (Monoethanolamine) 2,2',2"-Nitrilotriethanol (Triethanolamine) Nitriles, total Acetonitrile Acrylonitrile3 2-Methyllactonitrile (Acetone cyanohydrin) All other nitriles All other nitrogenous compounds

32,709 6,445 7,405 41,453 (2) 13,881 396,324

25,431 4,299 2,479 26,177 9,679 9,571 241,428

59,841 9,900 4,778 47,580 18,259 17,713 268,530

$2.35 2.30 1.93 1.82 1.89 1.85 1.12

11,010

(2)

(2)

298,403

223,111

195,084

.87

89,934 122,494 85,975

75,440 69,697 77,974

60,215 60,724 74,145

.80 .87 .95

2,330,811

809,892

583,289

.72

10,243 1,200,857 536,270 583,441

(2) 768,859 (2) 41,033

(2) 508,096 (2) 75,193

(2) .66 (2) 1.83

976,307

396,672

315,953

.80

4,125,121

1,405,956

1,312,304

.93

1,639,897 (2) 511,976 18,647 13,422 195,254 (2) 2,685 1,743,240

483,010 154,145 146,457 15,345 13,644 151,805 11,553 (2) 429,997

199,868 142,236 164,942 17,370 9,367 95,718 14,344 (2) 668,459

.41 .92 1.13 1.13 .69 .63 1.24 (2) 1.55

(2)

Acids, acyl halides and anhydrides Total Acetic acid, synthetic, 100% Acetic anhydride Acrylic acid Dimer acid (C36 dibasic acid) Fatty acids Fatty acids, hydrogenated5 Fumaric acid Pivaloyl chloride All other acids, acyl halides and anhydrides See footnotes at end of table.

15-4

Synthetic Organic Chemicals, 1991 Table 15-1-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1991 Sales Miscellaneous cyclic and acyclic chemicals

Production

Quantity

Value

Average unit values

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Acyclic-Continued Salts of organic acids Total

172,829

146,856

249,581

$1.70

23,448

10,056

20,957

2.08

33 1,210 20,014 2,191

21 1,239 (2) (2)

56 1,915 (2) (2)

2.67 1.54 (2) (2)

10,047

7,584

27,499

3.63

1,459 1,640 139 469 727 5,613

1,309 1,437 128 478 207 4,025

2,857 8,214 284 1,253 730 14,161

2.18 5.72 2.22 2.62 3.53 3.52

Lactic acid salts Lauric acid salts Octanoic acid, aluminum salt Oxalic acid salts Propionic acid, calcium salt

276 577 136 23 16,378

292 154 (2) 46 14,245

959 1,190 (2) 183 14,199

3.29 7.71 (2) 3.99 1.00

Stearic acid salts, totals

64,232

62,774

93,753

1.49

(2) 184 664 (2)_. (2) 40,546 3,347 15,723 3,768

2,068 (2) 703 1,365 37 39,943 3,584 15,224 1,918

5,344 (2) 2,089 3,255 229 47,195 7,395 28,483 5,107

2.58 (2) 2.97 2.39 6.19 1.18 2.06 1.87 2.66

57,712

51,705

90,841

1.75

Acetic acid salts, total Ammonium acetate Potassium acetate Sodium acetate All other acetic acid salts 2-Ethylhexanoic acid (a-Ethylcaproic acid) salts, total Calcium 2-ethylhexanoate Cobalt 2-ethylhexanoate Lead 2-ethylhexanoate Manganese 2-ethylhexanoate Zinc 2-ethylhexanoate All other 2-ethylhexanoic acid salts

Aluminum stearates, total Aluminum monostearate Aluminum tristearate All other aluminum stearate salts Cadmium stearate Calcium stearate Magnesium stearate Zinc stearate All other stearic acid salts All other salts of organic acids See footnotes at end of table.

15-5

Section 15 Table 15-1-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1991

Production

Quantity

Value

Average unit values

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Sates Miscellaneous cyclic and acyclic chemicals

Acyclic-Continued Aldehydes Total n-Butyraldehyde Formaldehyde (37% by weight) 3 All other aldehydes

4,514,072

1,177,127

280,153

$0.24

870,437 2,999,191 644,444

31,595 979,529 166,003

16,106 127,319 136,728

.51 .13 .82

1,437,649

1,133,340

736,640

.65

1,064,701 232,761 82,049 58,138

778,430 8,803 225,565 79,923 40,619

397,225 10,793 168,574 83,933 76,115

.51 1.23 .75 1.05 1.87

8,477,026

4,376,636

1,685,521

..39

7,801,956

4,126,041

1,353,828

.33

598,641 61,226 124,835 297,975 608,656 3,948,035 78,710 2,083,878

338,502 61,232 268,035 159,846 498,258 2,494,614 47,499 258,055

186,834 32,721 139,151 119,874 270,145 379,606 38,294 187,203

.55 .53 .52 .75 .54 .15 .81 .73

96,611

(2)

(2) (2)

4,101

578,459

(2)

(2)

(2)

(2)

49,224 145,303

49,765 196,651

1.01 1.35

Ketones Total Acetone Diacetone alcohol (Hydroxymethyl pentanone) Methyl ethyl ketone (2-Butanone) 4-Methyl-2-pentanone (Methyl isobutyl ketone) All other ketones

(2)

Alcohols, monohydric, unsubstituted Total Alcohols, C11 or lower, unmixed, total n-Butyl alcohol (n-Propylcarbinol) Isobutyl alcohol (Isopropylcarbino1)3 Ethyl alcohol, synthetic? 2-Ethyl-1-hexanol Isopropyl alcohol Methanol, synthetic Propyl alcohol (Propanol) All other alcohols, C11 or lower, unmixed Alcohols, C12 and higher, unmixed, total Dodecanol (Lauryl alcohol) All other alcohols, C12 and higher, unmixed Mixtures of alcohols, total Containing C,1 and lower Containing C12 thrOUghC18 8 All other mixtures of alcohols See footnotes at end of table.

313,845 264,614

(2)

(2)

(2)

7,483 (2)

(2)

(2)

1.83 (2)

(2)

Synthetic Organic Chemicals, 1991 Table 15-1-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1991 Sales Miscellaneous cyclic and acyclic chemicals

Production

Quantity

Value

Average unit value1

1,000 kilograms

1,000

kilograms

1,000 dollars

Per kilogram

Acyclic-Continued Esters of monohydric alcohols

Total Butyiacetates, total n-Butyl acetate Isobutyl acetates Butyl acrylate sec-Butyl chloroformate Dilauryl-3,3'-thiodipropionate Disteary1-3,3'-thiodipropionate Ethyl acetate (100% basis)3 Ethyl acrylate 2-Ethylhexyl acrylate Fatty acid esters, not included with plasticizers or surface-active agents, total Methyl esters of tallow All other fatty acid esters, not included with plasticers or surface-active agents Isopropyl acetate Methyl methacrylate Phosphorus acid esters, not elsewhere specified Propyl acetate Vinyl acetate All other esters of monohydric alcohols

2,948,534

1,724,640

1,420,998

$0.82

193,736 167,956 25,780 285,169 1,013 625 2,287 117,811 138,987 48,027

120,425 95,600 24,825 118,312 841 633 2,244 108,634 63,155 41,443

94,985 76,845 18,140 144,546 2,428 2,434 8,857 82,042 69,729 56,847

.79 .80 .73 1.22 2.89 3.84 3.95 .76 1.10 1.37

9,440

2,060

4,418

2.15

(2)

240

219

.91

9,440 24,381 499,790

1,820 20,817 46,410

4,199 19,232 38,482

2.31 .92 .83

34,448 36,146 1,239,389 317,285

24,950 31,478 973,470 169,768

66,353 32,240 546,959 251,446

2.66 1.02 .56 1.48

3,343,456

2,619,154

1,608,435

.61

215,951 2,181,568 51,767 301,902 66,114 66,349 459,805

(2) 2,004,390 50,335 243,078 59,065 60,621 (2)

(2)

(2) .46 1.34 .92 .55 1.19

Polyhydric alcohols9

Total 1,4-Butanediol Ethylene glycol3 Pentaerythritol Propylene glycol Sorbitol (70%) Sorbitol, crystalline All other polyhydric alcohols

See footnotes at end of table.

925,262 67,307 224,420 32,761 72,415 (2)

(2)

Section 15 Table 15-1-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1991

Production

Quantity

Value

Average unit value1

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Sales Miscellaneous cyclic and acyclic chemicals

Acyclic-Continued Esters and ethers of polyhydric alcohols Total Polyhydric alcohol esters, total 2-Butoxyethyl acetate All other polyhydric alcohol esters Polyhydric alcohol ethers, total 2-Butoxyethanol (Ethylene glycol monobutyl ether) 2-(2-Butoxyethoxy)ethanol (Diethylene glycol monobutyl ether) 242-(2-Butoxyethoxy)ethoxyjethanol (Triethylene glycol monobutyl ether) Diethylene glycol 2-Ethoxyethanol (Ethylene glycol ethyl ether) 2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl ether) Glycol ethers derived from propylene oxide 2-(2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl ether) 242-(2-Methoxyethoxy)ethoxyJethanol (Triethylene glycol monomethyl ether) Polyether polyols based on propylene oxide, total . Polypropylene glycol Sorbitol, alkoxylated & ethoxylated Polyethylene glycol Polytetramethylene glycol ether Tetraethylene glycol Triethylene glycol All other polyhydric alcohol ethers

1,143,285

873,754

943,177

$1.08

133,005

116,429

181,739

1.56

6,173 126,832

5,676 110,753

8,693 173,046

1.53 1.56

1,010,280

757,325

761,438

1.01

156,437

164,896

110,922

.67

109,070

39,048

44,809

1.15

12,250 221,185 31,886

(2) 169,271 18,359

(2) 87,266 12,366

(2) .52 .67

12,797 79,592

10,814 47,572

14,171 49,414

1.31 1.04

15,959

15,842

14,819

.94

11,959 31,439 (2) 375 61,519 (2) 12,782 53,302 199,728

(2) 12,364 8,754 (2) 61,802 22,899 (2) 46,480 147,978

(2) 18,853 13,458 (2) 87,350 78,925 (2) 44,764 197,779

(2) 1.52 1.54 (2) 1.41 3.45 (2) .96 1.34

12,863

(2)

(2)

(2)

(2) 12,863

369 (2)

938 (2)

2.54 (2)

Brominated hydrocarbons Total 1-Bromobutane All other brominated hydrocarbons See footnotes at end of table.

Synthetic Organic Chemicals, 1991 Table 15-1--Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1991 Sales Miscellaneous cyclic and acyclic chemicals

Production

Quantity

Value

Average unit valuer

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Acyclic-Continued Chlorinated hydrocarbons

11,998,453

4,264,596

1,048,353

$.25

142,944

172,911

25,292

.15

39,637 7,694 228,901 415,297 176,648 6,220,003 108,624 292,285 4,024,514 341,906

39,243 7,609 214,119 74,624 140,897 1,439,902 165,326 241,469 1,641,925 126,571

26,103 7,727 88,692 27,703 48,679 139,592 36,248 120,256 455,996 72,065

.67 1.02 .41 .37 .35 .10 .22 .50 .28 .57

367,335

304,716

744,582

2.44

142,641 71,253 44,916

108,414 88,160 56,046

260,405 184,250 96,316

2.40 2.09 1.72

108,525

52,096

203,611

3.91

5,245,397

774,255

1,448,535

1.87

37,615

32,778

197,815

6.04

2,791 34,824

2,546 30,232

23,250 174,565

9.13 5.76

4,049,128

508,430

525,877

1.03

2,380,363 1,668,765

245,346 263,084

237,317 288,560

.97 1.10

Fats and oils, chemically modified, total 10

17,562

16,942

17,607

1.04

Hydrogenated tallow glycerides All other fats oils, chemically modified

7,756 9,806

7,329 9,613

4,638 12,969

.63 1.35

13,221

(2)

(2)

(2)

Total Carbon tetrachloride 3 Chlorinated paraffins: 35%-64% chlorine 65% or more chlorine Chloroform (Trichloromethane) Chloromethane (Methyl chloride) 3 Dichloromethane (Methylene chloride) Ethylene dichloride (1,2-Dichloroethane) 3 Tetrachioroethylene (Perchloroethylene) 1,1,1-Trichloroethane (Methyl chloroform) Vinyl chloride, monomer (Chloroethylene) 3 All other chlorinated hydrocarbons5 Fluorinated (including other fluorohalogenated) hydrocarbons

Total Chlorodifluoromethane (F-22) Dichiorodifluoromethane (F-12) Trichlorofluoromethane (F-11) All other fluorinated (including other fluorohalogenated) hydrocarbons All other miscellaneous acyclic chemicals

Total Acyclic peroxides, total 2-Butanone peroxide (MEK peroxide) All other acyclic peroxides Expoxides, ethers and acetals, total Ethylene oxide All other expoxides, ethers and acetals

Hydrocarbons See footnotes at end of table.

Section 15 Taboo 15-1--4-ontinueci Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1991

Production

Quantity

Value

Average unit valuer

1,000 kilograms

1,000 kilograms

1,000 dollars

Per kilogram

Sales

Miscellaneous cyclic and acyclic chemicals

Acyclic—Continued All other miscellaneous acyclic chemicals—Continued Organo-aluminum compounds Organo-boron compounds Organ-tin compounds Phosgene (Carbonyl chloride) Silicone fluids All other miscellaneous acyclic chemicals

49,154 (2)

15,232 359 11,400

72,623 2,615 72,655

$4.77 7.28 6.37

13,645 318,242 60,179 686,651

43,715 145,399

237,565 321,778

5.43 2.21

141,286

119,651

36,275

.30

68,111 73,175

29,532 90,119

3,171 33,104

.11 .37

(2)

(2)

(2)

Mixtures not specifically itemized Total Fatty acid residues All other mixtures not specifically itemized" 1 Calculated from unrounded figures. 2 Reported data are accepted in confidence

and may not be published, or no data were reported. The difference between the production reported here and that shown on the Preliminary Report on U.S. Production of Selected Organic Chemicals (including Synthetic Plastics and Resin Materials), 1991, results from a combination of incorrect reporting or non-reporting by some companies, and end-of-year inventory and other adjustments. 4 Statistics limited to compounds of carbon, hydrogen, and nitrogen; and exclude production and sales of fatty amines. Statistics on fatty amines are included in the section on "Surface-Active Agents." 5 Excludes minor amounts reported as "fatty acids" and 'partially hydrogenate." 6 Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are included in the section on "Surface-Active Agents." 7 Synthetic ethyl alcohol is conventionally defined as that portion made from ethylene. Bureau of Alcohol, Tobacco, and Firearms statistics give the production from "natural" sources, mainly grain. 8 Includes small amount of mixtures of alcohols on both sides of the C11-C12 dividing line. 9 Some polyols which are used as intermediates for urethanes have been included in the section on "Plastics and Resin Materials." 10 Other than esters, salts, alcohols, acids, or acyl halides, which are tabulated in preceding groups. 11 Products included here are predominately acyclic; however, unspecified amounts of mixtures containing some cyclic chemicals may also be included. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 3

15-10

Synthetic Organic Chemicals, 1991 Table 15-2 Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics )

Miscellaneous chemicals, cyclic:

Yes

6-Acetoxy-2,4-dimethy1-1,3-dioxane Acetylfuran Ally!phenol formaldehyde condensate, alkoxylated Alkylphenol formaldehyde copolymer 1-(2-Aminoethyl)piperazine (2S-trans)-3-Amino-2-methy1-4-oxo-1-azetidinesulfonic acid, inner salt 1-(3-Aminopropyl)morpholine t-Amyl peroxybenzoatS p-Amyiphenol a-Aspartyl-phenylalanane methyl ester Benzenephosphinic acid Benzenesulfonic acid, 2,5-bis [(1,2-dioxobutyl)amino].. p-Benzoquinone Benzotriazole, potassium (&) sodium salts Benzotriazole, substituted Benzoyl peroxide Benzyl alcohol Benzyl chloroformate Benzyl 4-hydroxy benzoate Benzoic acid esters: Benzoic acid, butyl ester (Butyl benzoate) Benzoic acid, C12-C15 ester Benzoic acid, isodecyl ester Methyl-4-hydroxybenzoate Resorcinol monobenzoate Sucrose benzoate All other benzoic acid esters Benzoic acid salts: Barium benzoate Cadmium benzoate Potassium benzoate Sodium benzoate All other benzoic acid salts a,a-Bis(t-butylperoxy)diiscpropylbenzene Bis[p-chlorobenzoyl]peroxide 1,2-Bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl) hydrazine Bis(2,4-dichlorobenzoyl) peroxide Bis(a,a-dimethylbenzypperoxide 1,3-Bis(2-hydroxyethy1-5,5-dimethyl)-2,4imidazolinedione 2,2-Bis(4-hydro eny1)4-methylpentane Bis(perfluoroalky bis(alpha-monochlorohydry1)pyromellitate Bisphenol epichlorohydrin Bis(triphenylsilyl)chromate Brominated diphenyl ethers Bromochloro-5,5'-dimethyl hydantoin 2-Bromo-6-methoxynaphthylene 13-Bromo-p-nitrostyrene 2-Butoxyethyl benzoate (Butyl cellosolve benzoate) tert-Butyihydroquinone 2 (and 3)-tert-Butyl-4-methoxyphenol (Butylated hydroxyanisoie, or, BHA)

Manufacturers' identification codes (according to list in table 15-3)

No No

BAK, GIV, (2). QKO.

No No No

DOW.

No No No No No No

BRS. TX. WTL (2). HXL FER.

No No No No Yes No No No Yes No No No No No No No

BRD. EKT.

PCI, UTC. FTX. VEL. CHD. EKT. VEL (2).

No . No Yes No No No No

FER. CCA. CHO, HFT, KLM, PFZ. CHO, HCP, HFT, JRC, KLM. FER. WTL. CAD.

No No No

ASL CAD. WTL.

No No

BRD. ASL

No No No No No No No

HCL BAS. TNA. BRD, GTL HFT. GIV.

No No

gkr.

No

EKT, UPM.

Y. AZT, CAD, NOC, PAS, RCI, WTL KLM. HCC, VCM. CHD.

See footnotes at end of table. 15-11

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Manufacturers' identification codes (according to list in table 15-3)

Miscellaneous chemicals, cyclic-Continued Butylmorphoiine tert-Butyl peroxybenzoate Camphene Campholenic aldehyde Caprolactam (2-0xohexamethylenimine) Caprolactam magnesium bromide Carbobenzoxy-L-azetidinone sodium salt Cellulose acetate hexahydrophthalate Cellulose acetate phthalate Centralite-1 Chlorothiaxanthone Cumene hydroperoxide a Cumyl peroxyneodecanoate a Cumyl peroxyneoheptanoate Cyanuric acid Cyclic adducted amine curing agents Cyclic silizane Cyclohexane carbonitrile 1,4-Cyclohexanedicarboxylic acid Cydohexanethiol 2-Cyclohexene-1-octanoic acid, 5 (and 6)-carboxy-4hexyl,C2i H360 4 Cydohexylamine 1,4-Cyclohexylenedimethanol Cyclohexyl methacrylate Decabromodiphenyl ether (DBDP) Diamino cyclohexane 1,1-Di(t-amylperoxy)cyclohexane 1 ,4-Diazobicyclo(2.2.2)octane Dibenzylglycerol 2,6-Di-tert-butyl-p-cresol (BHT, or, Butylated hydroxytoluene Di-t-butyl diperoxy phthalate 2,5-Di-tert-butylhydroquinone 2,6-Di-t-buty1-4-nonylphenol 1,1-Di(t-butyl peroxy) cyclohexane 1,1-Di (t-butyl peroxy) cyclohexane 1,1-Di (t-butyl peroxy)-3,3,5-trimethyl cyclohexane 1,1-Di(t-butyl peroxy)-3,3,5-trimethyl cyclohexane 2,4-Di-t-butyl phenyl 3,5-di-t-butyl hydroxybenzoate 1,3-Dichloro-5,5-dimethylhydantoin 1,3-Dichloro-5-ethyl-5-methyl-2,4-imidazolinedione Dicumyl peroxide Dicydopentadienyl acrylate Dicydopentadienylchromium (Chromocene) 3-Diethylamino-6-methyl-7-(2,4-dimethylanilino) fluoran N,N'-Diethyl-N,N'-diphenylurea 1,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline (Ethoxyquin) Dihydro-2,5-furandione 2,5-Dihydrothiophene-1,1-dioxide (Sulfolene) 1,3-Dihydroxymethy1-5,5-dimethy1-2, 4-imidazolinedione 4,4-Dihydroxymethyl-2-oxazoline Diiodomethyl-p-tolylsulfone 1,3-Diisopropylbenzene 1,4-Diisopropylbenzene -

-

See footnotes at end of table.

No No Yes No No Yes No No No No No No No No No No No No No No

TX. AZT, NOC, PAS, WTC, WTL. SCM. PAS. ACS, BAS, CNP. FER. BRS.

No No No No No No No No No

WVA. HCL EKT. CPS. GTL, TNA. HXL PAS, WTL.

No No No No No No No No No No No No No No

UCC, USR. WTL. EKT. RDA. AZT, PAS. WTL PAS. WTL. FER. BRD. BRD. PAS. RDA. (2).

No No

ESA. VCM.

No No No

MNA. BCC. PLC.

No No No No No

BRD. ANG. ANG. EKT. EKT.

g). K, WTC.

ftG.

BTL, WTL. PAS, WTC. WTL MON. VEL. PCR. DUP. EKT. PAS.

Pic

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991 .

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

,Manufacturers' identification codes (according to list in table 15-3)

No

(2).

Miscellaneous chemicals, cyclic-Continued Diisopropyl/naphthalene suN. acid amine salts ... , p-Dimethoxybenzene (Dimethyl ether of hydroquinone) 4,4-Dimethyl oxazolidene 1,2-Di-(3-methylphenoxy ethane) N,N-Dimethylphenyt urea Dimethyl piperazine Dimorpholine diethyl ether Di-tert-octyl hydroquinone Dioxane (1,4-Diethylene oxide) Dioxolanone 1,4-Dioxycydoheptadiene 1,2-Diphenoxyethane Diphenyl-t-butylhexyl phosphite Diphenyl carbonate Diphenylisodecyl phosphite Diphenylisooctyl phosphite Dipropylene glycol salicylate Di(tetrahydrofuryl)propane Dodecyl pyridinium chloride 6-Ethoxy-12-dihydro-2,2,4-trimethyl quinoline Ethylene-bis-tetrabromophthalimide Ethyleneimine (Aziridne 2-Ethylhexy1-1-p-dimethylaminobenzoate 2-Ethylhexyl-p-methoxy cinnamate 2-Ethylhexyl salicylate 4-Ethyl-4-hydroxymethyloxazoline Ethylidine norbomene 4-Ethylmorpholine o-Ethylphenol 2-(Formylamino)-L-oxo-4-thiazole acetic acid Furan derivatives: 2-Furaldehyde (Furfural) , Furanacrolein Furfuryl amine Furoi c acid Methly furan Tetrahydrofurfuryl alcohol All other furan derivatives Hexabromocyclodecane Hexabromocyclododecane Hexahydro-1,3-isobenzofurandione Hexahydro-5-methyl-1,3-isobenzofurandione Hexahydrophthalic anhydride Hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triazine Hexamethylenetetramine Homomenthol salicylate Hydrindantin Hydroquinone, di(6-hydroxyethyl) ether p-Hydroxybenzoic acid, butyl ester p-Hydroxybenzoic acid, ethyl ester (Ethyl paraben) p-Hydroxybenzoic acid, methyl ester p-Hydroxybenzoic acid, propyl ester N-(Hydroxyethyl)piperazine Hydroxyrnethyl-bis-oxazoline Hydroxymethy1-5,5-hydantoin a-D-p-Hydroxyphenylglycine methyl ester K 1,2,3-Indantrione monohydrate (Ninhydrin)

No No ‘ No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

ASL. ANG, EFH. CHD.

f-k TX.

EKT. FER. g6 P. ASL, CHD. WTC. VCM. WTC. WTC. EKT, SBC. QKO. TLC. MON. TNA. SON. • VND. VND. BDS, VND. ANG. UCC, TX.. ASL BRS.

No No No Yes No No No No

QKO. EKT. QKO. • QKO. OKO. QKO. QKO. GTL. TNA. BCC. BCC. DIX. ANG. BOR, HMP, PLS, WCL WTC. PIC. EKT. KLM.

No No No No No No No No

KLM. KLM. KLM. SCP. ANG. BRD, BOC. PIC.

No No No No

See footnotes at end of table. 15-13

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 15-3)

Miscellaneous chemicals, cyclic-Continued Isobomyl acrylate Isobomyl methacrylate Isoocty1-3,5-di-t-butyl-4-hydroxyhydrocinnamate Isophoronitrile Lactones: Butyrolactone Caprolactone Diketene Lead/copper salicylate/resorcylate Lignin amine 5-Uthiosulfoisophthalic acid Maleic anhydride p-Menthane p-Menthane hydroperoxide Methoxyethyl morpholine 4-Methoxyphenol Methylbenzene sulfonate Methyl-p-benzoquinone Methyl-N-(L-caroxyd(hydrobenzyI)-b-amino crotonate, sodium salt 2-Methylcyclohexylamine 3-(N-Methyl-N-cydohexylamino)-6-methy1-7-anilino fluoran Methyl gallate 4-Methylmorpholine 1-Methyl-2-pyrrolidone, monomer 2- and 5-Methyl resorcinol Methyl tetrahydrofuran Methyltetrahydrophthalic anhydride Methylvinyl cyclic siloxane Morpholine Morpholine salt of gluconic acid Morpholine salt of p-toluene sulfonic acid Naphthenic acid/polyamine condensates 4-(2-Nitrobutyl) morpholine N-Nitrosophenylhydroxylamine, ethanolamine salt Octabromodiphenyl oxide Pentabromodiphenyl oxide Pentaerythritol tribenzoate Phenol-sulfonated formaldehyde rosin 2-Phenoxyethanol (Ethylene glycol monophenyl ether) Phenoxyethyl acrylate 2-Phenoxypropanol Phenyl acid phosphate 1-Phenyl-2-hydroxy-2-methyl-propanone-1 Phenyipropanolamine Phosphonate ester, cyclic Phthalic acid, lead salt, (Dibasic) Picramic acid, sodium salt Pinene and derivatives: Pinane Pinane hydroperoxide 2-Pinanoi (cis and trans) Pinanols/plinol mixtures a-Pinene 13 -Pinene a-Pinene oxide

See footnotes at end of table.

15-14

No No No No Yes No No No No No No No No No No No No No

RDA. RDA ASL HMP.

No No

BRS. AIP.

No No No No No No No No Yes No No No No No No No No No No No No No No No No No No Yes No No No No No No No

ATR, BAS, GAF. UCC. BRD, EKT. SHP. ARC. EKT. AMO, ART, ASH, DKA, MON. SCM. SCM. TX. ASL, EKT. EK. EK.

GTL. BRS. TX. . ATR, BAS, GAF. INYK. WO. DIX. PCR, (2). AIP, BA,S, TX, (2). 2 B. 20 MAL. GTL GTL VEL HCL SCP, UCC. CPS. WTC. ALW. CWN. ORT. ALW. AU. SDC. SCM. SCM. SCM. SCM. NCI, SCM. NCI, SCM. PAS.

Synthetic Organic Chemicals, 1991 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, cyclic-Continued Pinene and derivatives—Continued Pinene, sulfate Pinene, wood Pine oil, natural, sulfate Pine oil, synthetic Piperonal, sodium bisulfite complex Polyglycols-toluene diisocyanate reaction product Propanedioic acid, diethyldimethyl ester, polymer with 4-hydroxy-2,2,6,6-tetramethy1-1-piperidine ethanol Propylene glycol dibenzoate Propyl gallate Rosin acid salts: Calcium resinate Calcium zinc resinate Zinc resinate All other rosin acid salts Salicylic acid, lead salt Salicylic acid magnesium salt Styrene oxide Succinic anhydride derivatives: Dodecenylsuccinic anhydride Dodecylsuccinic anhydride n-Hexadecenylsuccinic anhydride iso-Hexadecenyl succinic anhydride Iso-octadecenylsuccinic anhydride Nonenylsuccinic anhydride Octadecenyl succinic anhydride Octenylsuccinic anhydride TPSAfpolyamine condensates All other succinic anhydride derivatives Tal oil acyl chloride Tal oil, chemically modified Tal oil, diethanolamine salt Tal oil fatty acid nitrile Tal oil fatty adds, polymerized Tal oil monohydric esters Tal oil monomer Tal oil: Pentaerythritol tallate Tal oil, triethanolamine salt Tannic acid, N.F Tall oil salts (linoleic-rosin acid salts): Barium zinc tallate Cadmium tallate Calcium manganese tallate Calcium tallate Cobalt manganese tallate Cobalt tallate Copper tallate Lead tallate Manganese tallate Potassium tallate Stannous dioctyl tallate Zinc tallate All other tall oil salts,(Linoleic-rosin acid salts) Terpene hydrocarbons, monocyclic (Solvend) Tetrabromobisphenol A Tetraethylene glycol diheptanoate

Separate statistics1

Manufacturers' identification codes (according to list in table 15-3)

No No Yes Yes No

ARZ, HPC. HPC. ARZ, NCI, SCM. ARZ, NCI, SCM. VEL.

No

(2).

No No No

\%L. EKT.

No No No No No No No Yes Yes No No No No No No Yes No No No No No No No No No No No No

ARZ. ARZ. ARZ. GP. SHP. KLM. UCC.

No No No No No No No No No No No No

WVA. CCA. MCI, SHP. (2). MCI, SHP. MCI, SHP. MCI. MCI. MCI, SHP. QCP. PAS. CCA, MCI.

No No No No

CCA, QCP, SHP, (2). HPC, NCI, SCM. GTL, TNA. WM.

BCC, DIX, HMY, MIL MIL HMY. DIX. DIX, HMY. HMY. HMY, MIL DIX, HMY, MIL , TNA. CCC. FOC, (2), WVA, (2). QCP. ARZ. SHX, WVA. ARZ. WTC. EFH. QCP. MAL.

See footnotes at end of table. 15-15

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' Identification codes (according to list in table 15-3)

No No No No No No No No No No

QKO. DUP. PAS. PLC, (2). PAS.

No No No No No No No No No

MON, OMC. WTC. WPG. ARS. ENJ, UCC, (2). PAH. PAS. WTC. GAF.

No No No No

GAF. GAF. GAF. ALW, ARS, ASL, BRD, CCA, CWN, EK, EK, EK, En HXL, LYP, MCK, PAH, PAS, PIC, QCP, REG, RSA, S. SCR_ SDC SHP, TNA 'TX UCC, (2) (2) (4),

Miscellaneous chemicals, cyclic-Continued 2-Tetrahydrofurfurylamine 1,2,3,4-Tetrahydronaphthalene (Tetralin) Tetrahydrothiophene Tetrahydrothiophene-1,1-dioxide (Sulfolane) Thiophene Tolyltriazole, potassium salt Triallyl trimellitate Triazine 3,4,4'-Trichlorocarbanilide Trichloromelamine 1,3,5-Trichloro-s-triazine-2,4,6-(1H,3H,5H)trione (Trichloroisocyanuric acid) Tri(2,4-ditertiarybutylphenyl) phosphite Tri(methoxymethyl) tri(stearoxymethyl) melamine 3,3,5-Trimethylcydohexanol (m-homomenthol) 3,5,5-Trimethy1-2-cyclohexene-1-one (isophorone) Trinitrophenyl methyl nitramine (Nitramine) Triphenyl phosphine Triphenyl phosphite 1-Viny1-2-pyrrolidinone—other copolymers 1-Vinyl-2-pyrrolidinone-methylacrylic acid, dimethylamine ethyl ester, copolymer 1-Vinyl-2-pyrrolidinone, monomer 1-Vinyl-2-pyrrolidinone—vinyl acetate copolymer All other cyclic chemicals

Miscellaneous chemicals, acyclic: Yes Nitrogenous compounds: Yes Acetaldehyde dimethylhydrazone No Acetamidoethanol (N-Acetyl-ethanolamine) No Allyl ureido monomer No Amides: Yes Acrylamide monomer No 1,1'-Azobisformamide No Behenamide No Bis[2-(octadecylamido)ethyil-N-(2-cyanoethyl)-Nethyl ammonium ethyl sulfate No Chloromethylene dimethyliminium (Amide chloride) No Coconut oil amide No N,N-Dimethylacetamide No N,N-Dimethylacetoacetamide No Dimethylaminopropyl methacrylamide No N,N-Dimethylformamide No Erucamide Yes N,N'-Ethylenebis-olearnide (Oleic acidethylenediamine condensate (Amine/acid ratio = 1/2)) No N,N'-Ethylenebis(stearamide) Yes Ethylene(12)hydroxystearamide No Methane sulfonamide No N-Methylacetamide No Oleamide (Octadecene amide) No Oleic amide, N,N-bis(hydroxyethyl)-,(Z)No See footnotes at end of table.

15-16

gijA. QCP. MON. GFS.

DIX. SBC. RDA. ACY, (2). USR. ASL, WTC. SBC. VCM. ARC, FER. DUP, MON. EKT. TX. DUP. ARC, SYP, WTC. BRD, CCW, WTC. BRD, CCW, WTC. CAS. PAS. ARC, ARS, EKT. SYP, WTC. QCP.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1991 Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Nitrogenous compounds-Continued Amides-Continued Oleoylpalmitamide Oxamide n-Propylamidethanol Ricinoleamide Soya amide, N,N-bis(hydroxyethyl) Stearamide (Octadecane amide) Stearylerucamide Stearyl stearamide Tallow amide Tallow amide, hydrogenated All other amides Amines: t-Alkylamines, primary, mixed All amines: Diallylamine Triallylamine Bis-hexamethylenetriamine amine Butylamines: n-Butylamine, mono sec-Butylamine, mono tert-Butylamine, mono Di-n-butylamine Diisobutylamine Tri-n-butylamine n-Butylethylamine N-Coco-N,N-dimethylamines Di-t-butylenediamine Diethylenetriamine Di-2-ethylhexylamine Diisopropylamine Dimethylaminopropylamine N,N-Dimethylethylarnme N-Dodecyl-N,N-dimethylamine Ethylamines: Diethylamine Ethylamine, monoTriethylamine N-Ethyl-1,2-dimethylpropylamine Ethylenediamine (2-Ethylhexyl)amine, monoN-Ethyl-2-methylallylamine Fatty amines N-Hexadecyl-N,N-dimethylamine 1,6-Hexanediamine (Hexamethylenediamine) n-Hexylamine Isopropylamines: Isopropylamine, mono Methylamines: Dimethylamine Methylamine, monoTrimethyl amine tert-Octylamine n-Octylamine, mono Pentaethylenehexamine

Separate statistical

No No No No No No No No No No No Yes No

Manufacturers' identification codes (according to list in table 15-3)

HXL, WTC. HML, (2). PAS. ARC. QCP. SYP, WTC. HXL, WTC. WTC. QCP. ARC. AIP, BRD, DOW, HAL, MIL QCP, REG, SK, (2), (2). BRD, RH.

No No No

HCL HCL DUP, MON.

Yes No No Yes No No No No No Yes No No Yes No No

AIP, HCL, PAS. BAS, FER, PAS. MON. AIP, HCL, PAS. HCL AIP, HCL, PAS. AIP. BRD. HCL. DOW, TX, UCC. HCL AIP. AIP, BAS, HCL, TX. BAS. BRD.

Yes No Yes No Yes No No No No No No

AIP, HCL, PAS, UCC. AIP, HCL, PAS, UCC. AIP, HCL, PAS, UCC. BAS. DOW, TX, UCC. HCL, PAS. HCL. WTH. BRD. MON. CXI, PAS.

No

AIP, HCL, UCC.

No No No No

AIP, DUP, IMC, UCC. AIP, DUP, IMC. AIP, DUP, IMC. RH. GAF, HCL. DOW, UCC.

No

No

See footnotes at end of table.

15-17

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Nitrogenous compounds-Continued Amines—Continued Pentylamines (amylamines): Dipentylamine Pentylamine, monoTripentylamine Propylamines: Dipropylamine Propylamine, monoTripropylamine N,N,N',N'-Tetrabutylhexanediamine N-Tetradecyl-N,N-dimethylamine Tetraethylenepentamine Tetramethylethylenediamine Triethylenediamine Triethylenetetramine All other amines 5-Amino-1,3-bis(2-ethylhexy1-5-methyl)hexahydropyrimidine 2-Aminoethanol hydrochloride 2-Aminoethanol (Monoethanol amine) sulfite Aminoethoxyethanol 2-(2-Aminoethylamino)ethanol (Aminoethylethanolamine) (2-Aminoethyl)aminoethanol, reaction product with octadecanoic acid 2-Aminoethyl mercaptoacetate (Monoethanolamine thioglycolate) 2-Amino-2-ethyl-1,3-propanediol 2-Amino-2-(hydroxymethyl)-1,3-propanediol [Tris(hydroxymethyl)aminomethane] 2-Amino-2-methyl-1,3-propanediol 2-Amino-2-methyl-1-propanol tert-Butylaminoethyl methacrylate tert-Butyldiethanolamine tert-Butyl urea Carbohydrazide 3-Chioro-2-hydroxypropyl trimethyl ammonium chloride (1-Propaminium, 3-chloro-2-hydroxyN,N, N-trimethyl-, chloride) Choline Diallyldimethyl ammonium chloride Di-amine derivatives of dimer acids 2-Dibutytaminoethanol Dibutylaminomethanol Diethanolamine salt of oleic acid 2-Diethylaminoethanol (N,N-Diethylethanolarnine) 2-(2-Diethylaminoethoxy)ethanol Diethylaminoethylacrylate, dimethyl sulfate, quaternary salt 2-Diethylammoethyl methacrylate Diethylhydroxylamine 1,3-Diethyl-2-thiourea 2-Diisopropylaminoethanol (N,NDiisopropylethanolamine) Dimethylamine epichlorohydrin copolymer 2-Dimethylaminoethanol (N,NDimethylethanolamine Dimethylaminoethyl acrylate

See footnotes at end of table.

15-18

Separate statisticsi

Manufacturers' Identification Codes (according to list in table 15-3)

No No No

PAS. PAS. PAS.

No No No No No Yes No No No No

AIP, HCL, PAS. PAS. AIP, PAS. MON. BRD. DOW, UCC. BKM. TX. DOW, TX, UCC. AIP, ANG, BRD, HCL, MON, SCP, UCC.

No No No No

ANG. OMC, (2). EVN. TX.

Yes

DOW, UCC, (2).

No

BRI.

No No

EVN. ANG.

No No No No No No No

ANG, VNC. ANG. ANG, VNC. CPS, RDA. PAS. PAS. OMC.

No No No No No No No No No

DGC. RH. CPS. WTC. PAS. OCP. PAS, UCC. PAS, UCC.

No No No No

CPS. CPS, DUP. PAS. PAS.

No No

PAS, UCC. CPS.

No No

PAS, TX, UCC. CPS.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Nitrogenous compounds-Continued Dimethylaminoethyl acrylate, dimethyl sulfate, quatemary salt Dimethylaminoethylacrylate, methyl chloride, quaternary salt Dimethylaminoethyl chloride Dimethylaminoethyl methacrylate Dimethylaminoethylmethacrylate, dimethyl sulfate, quaternary salt Dimethylaminoethylmethacrylate, methyl chloride, quatemary salt Dimethylaminomethanol 1-(Dimethylamino)-2-propanol Dimethylaminopropyl chloride 3,7-Dimethyl-2,6-octadien-1-oxime 3,7-Dimethyl-6-octen-1-oxime 2,4-Dioxypyrimidine (Uracil) Ethanolamines: Diethanolamine Monoethanolamine Triethanolamine 2-Ethylaminoethanol (Ethylmonoethanolamine) 2-Ethylhexyl nitrate 5-(N-Ethyl-N-hydroxyethylamino)-2-pentanone 2-Ethyl-2-nitro-1,3-propanediol Fatty acid, allcanolamine ester Hexamethylenediamine adipate (Nylon salt) Hexylamine ethoxylate N-(2-Hydroxyethyl)-12-hydroxystearamide 2-(Hydroxymethyl)-2-nitro-1,3-propanediol (Tris(hydroxymethyl)nitromethane) Iminodiacetic acid Iscpropanolamines: Diisopropanolamine Dimethyl isopropanolamine Monoisopropanolamine Triisopropanolamine 2-Isopropylaminoethanol 3-Methoxypropylamine Methylaminoacetaldehyde dimethyl acetal (MAADMA) 2-Methylaminoethanol (N-Methylethanolamine) 2,2'-(Methylimino)diethanoi (Methyldiethanolamine) 2-Methyl-2-nitro-1-propanol Mixed higher glycol amine (MHGA) Nitrated lard oil Nitriles: Acetonitrile Acrylonitrile, monomer Adiponitrile 6-Aminocapronitrile 2,2-Azobis(dimethyl pentane nitrile) 2,2-Azobis(2-methyl butane nitrile) 2,2'-Azobisp-methylpropionitrile] (Azobisisobutyronitrile) n-Butyronitrile Coconitrile See footnotes at end of table.

Separate statistics"'

Manufacturers' Identification codes (according to list in table 15-3)

No

CPS.

No No No

CPS, RDA. SK. CPS, RDA.

No

CPS.

No No No No No No No Yes Yes Yes Yes No No No No No No No No

RDA, UCC.

as. SK. SCM. SCM. PCR. CNE, DOW, OMC, TX, UCC. CNE, DOW, OMC, TX, UCC. CNE, DOW, OMC, TX, UCC. PAS. BUC. W.

gbp.

MON, (2).

CXI. CAS.

No No

ANG. HMP.

No No No No No No

DOW, UCC. PEL DOW. DOW. PAS. BAS, PAS.

No No

ASL. TX, UCC.

No No No No Yes Yes Yes No No No No

DOW, PAS, TX, UCC. ANG. AIP. SM.

No No No

DUP. EKX. ARC.

BKC, DUP, SC, (2), (2). ACY, DUP, MON, SC, SOH. DUP, MON. bUP. DUP.

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Manufacturers' Identification codes (according to list in table 15-3)

Miscellaneous chemicals, acyclic-Continued Nitrogenous compounds-Continued Nitriles-Continued Cyanoacetic acid (Malonic nitrile) 1,2-Dibromo-2,4-dicyanobutane 3-Ethoxypropionitrile Ethyl cyanoacetate Hexadecylnitrile Isobutyronitrile Lauronitrile (Dodecyl nitrile) 3-Methoxypropionitrile Methyl cyanoacetate Methyl glutaronitrile 2-Methyllactonitrile (Acetone cyanohydrin) Octadecenenitrile (Oleonitrile) Octadecylnitrile Propionitrile Soya nitrile Tallow nitrile Tallow nitrile, hydrogenated 3,3'-Thiodipropionitrile Trichloroacetonitrile All other nitriles Nitroethane Nitromethane 1-Nitropropane 2-Nitropropane Polyoxypropylene triamine Propylene imine 3-Stearylamidopropyl dimethylammonium lactate Tetraethyl ammonium bromide Tetramethylammonium chloride Triethanolamine hydrochloride Triethanolamine, sulfuric - phosphoric acid salts Triethylamine, nitric acid salt Triethylenetetramine, propoxylated Zinc bis(monoethanolamine)dichloride All other nitrogenous compounds, acyclic

No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No

Acids, acid anhydrides, and acyl halides: Acetic acid, synthetic (100%) Acetic anhydride, other than recovered acetic anhydride by the vapor-phase process (100%) D-(-)-3(Acetylthio)-2-methylpropanoyl chloride Acrylic acid Adipic acid Anhydride-acid mixture Azelaic acid Bromopropionic acid Butyric acid Butyric anhydride Butyryl chloride Castor oil fatty acids, dehydrated Chloroacetic acid, mono Citric acid Crotonic acid (2-Butenoic acid) Decanoyl chloride 2,2-Dichloroacetyl chloride

Yes Yes

AIP, EKT, HCL, SC, UCC, USI.

Yes No Yes No No No No No No No No No No No No Yes

EKT, HCL, UCC. BRS. BAS, HCL, RH, UCC. DUP, MON. HCL SCP. HFT. EKT, HCL, PEN. EKT. TLC. CAS. HAR, NCC, PFZ. ADM, PFZ. EKE SDC. WTL

See footnotes at end of table.

15-20

NOD. PCW. DIX. NOD. ARC. E KK. ARC.

N

OD.

CYR, DUP, RH, SOH. ARC. ARC. MON. ARC. ARC, SHX. ARC. EVN. OMC. HMP, HXL, WTC. ANG, VNC. ANG, VNC. ANG, VNC, (28. ANG, (2), VN . TX. ARS. WM. RSA. RSA. WPG.

a,

2, ANG, ASL, CCC, EK, HXL, NES, OMC, RDA, RSA, SK, TX, UCC, VCM, WTL, (2), (2), (2).

Synthetic Organic Chemicals, 1991 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Miscellaneous chemicals, acyclic-Continued Acids, acid anhydrides, and acyl halides—Continued No Dimer acid (036 aliphatic dibasic acid) No Dimethyl propionic acid No Dithiodiglycolic acid No Dithiodipropionic acid No Dodecanedioic acid No Dodecanoic acid (Lauric acid) No 2-Ethylhexanoic acid (a-Ethylcaproic acid) No 2-Ethylhexanoyl chloride Yes Fatty acids Yes Fatty acids, hydrogenated No Fatty acids, partially hydrogenated No Formic acid, 90% Yes Fumaric acid No Gluconic acid, technical No Glycolic acid (Hydroxyacetic acid) No Heptanoic acid No Hexadecanoic acid (Palmitic acid) No n-Hexanoic acid No Isoascorbic acid (Erythorbic acid) No Isobutyric acid No Isobutyric anhydride No Itaconic acid (Methylenesuccinic acid) No Lactic acid, 100% No Lauroyl chloride No Levulinic acid No Malic acid No Mercaptoacetic acid (Thioglycolic acid) No 3-Mercaptopropionic acid No Mercaptosuccinic acid (Thiomalic acid) No Methacrylic acid No Methanesulfonic acid No Methanesulfonyl chloride No Neo-C9-C1 acids No Neodecanoic acid No Neodecanoyl chloride No Neoheptanoyl chloride No Neopentanoic/neoheptanoic acids No Nonanoic acid (Pelargonic acid) No Octanoic acid (CaprOic acid) No Oleic acid No Oxidized Fischer-Tropsch wax Yes Pivaloyl chloride No Polyacrylic acid No Propionic acid No Ricinoleic acid (Hydroxyoleic acid) No Sebacic acid No Stearic acid (Octadecanoic acid) No Stearoyl chloride No Tetradecanoic acid (Myristic acid) No 3,3'-Thiodipropionic acid No Thiodisuccinic acid No Trifluoroacetic acid No Trifluoroacetic anhydride No Trifluoroacetyl chloride No Trimer dibasic acids No Valenc acid No All other acids, acid anhydrides, and acyl halides

Manufacturers' identification codes (according to list in table 15-3)

ARZ, SCP, WTC. IMC. EVN. EVN. DUP. ARC. EKT, UCC. PAS, PPG, WTC, WTL CAS, DRL, PG, SHX, WTC. BRD, CAS, DRL, SHX, SYP, WTC, (2). SYP, WTC. HCL HAR, MON, PFZ. PFZ, PMP. DUP. HCL. ARC. ARC. PFZ. EKX. EKT. PFZ. SC, WTL. PPG. QKO. HAR. EVN. EVN, WTC. EVN. DUP, RH. PAS. PAS. ENJ. ENJ. PAS, WTC, WTL PAS, WTC, WTL ENJ. HCL, SCP. ARC. ARC, DRL, WTC. SQA. PAS, PPG, WTC, WTL. BFG, BKM, RH. HCL, UCC. BDS. WTH. ARC. PPG. ARC. EVN. EVN. HOC. HOC. HOC. WTC. UCC. BRD, DUP, ENJ, PAH, SK, UCC, WVA.

See footnotes at end of table.

15-21

Section 15 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Salts of organic acids:

Acetic acid salts: Aluminum acetate Ammonium acetate Barium acetate Calcium acetate Chromium acetate Cobalt acetate Cobalt manganese acetate Copper acetate Hydrazine acetate Lead acetate Lead subacetate Magnesium acetate Manganese acetate Nickel acetate Potassium acetate Sodium acetate Sodium diacetate Zinc acetate Zirconium acetate All other acetic acid salts Adipic acid, ammonium salt Adipic dihydrazide 3-Allyloxy-2-hydroxypropane sulfonic acid, sodium salt 2-Butoxyethoxy acetic acid Citric acid salts: Ammonium citrate Dimethylhexanoic acid, calcium carbonate salt Potassium citrate Sodium citrate Diammonium dithiodiglycolate 2-Ethylhexanoic acid (alpha-ethylcaproic acid) salts: Barium 2-ethylhexanoate Bismuth 2-ethylhexanoate Cadmium 2-ethylhexanoate Calcium 2-ethylhexanoate Cerium 2-ethylhexanoate Chromium 2-ethylhexanoate Cobalt 2-ethylhexanoate Cobalt-potassium 2-ethylhexanoate Copper 2-ethylhexanoate Iron 2-ethylhexanoate Lead 2-ethylhexanoate Manganese 2-ethylhexanoate Molybdinum 2-ethylhexanoate Nickel 2-ethylhexanoate Potassium 2-ethylhexanoate Rare earths 2-ethyihexanoate Sodium 2-ethylhexanoate Stannous 2-ethyihexanoate Zinc 2-ethylhexanoate Zirconium 2-ethylhexanoate All other 2-ethylhexanoic acid salts Fish oil, C14-C22 menhaden, lead salts See footnotes at end of table.

15-22

Separate statistics',

Manufacturers' identification codes (according to list in table 15-3)

Yes Yes No Yes No No No No No No No No No No No No Yes Yes No No No No No No

NCC. ARC, BKC, (2). BKC. CHO, HFT, NCC. SHP. SHP. SHP. BKC. FMT. BKC. BKC. BKC, EKT, SHP. SHP. SHP. BKC, HCP, JRC, NCC, PEL. BKC, HCP, JRC, MAL, NCC, UCC, (2). HCP, JRC, NCC. BKC, SHP. TZC. SHP. ACS. FMT.

No No

RDA. SDC.

No No No No No

PCA. HAR, HXL, PFZ. BRI, HAR, HXL EVN.

Yes No No No Yes

No No No Yes No No Yes Yes No No No No No No No No No No

vac.

SHP. CCA, WTC. CCA, FER, MCI, NOD, TRO, WTC.

MCI, SHP. MCI, SHP. CCA, MCI, NOD, SHP, TRO. MCI. MCI, NOD. CCA, NOD. CCA, NOD, SHP. CCA, MCI, NOD, SHP, TRO. MCI. MCI, SHP. CCA, MCI, PEL, WTC. MCI. CCA. FER. CCA, MCI, NOD, SHP, TRO, WTC, (2). CCA, MCI, TRO. MCI, NOD. ELC.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Manufacturers' identification codes (according to list in table 15-3)

Miscellaneous chemicals, acyclic-Continued Salts of organic acids-Continued

Formic acid salts: Ammonium formate Calcium formate Sodium formate, technical Gluconic acid salts: Sodium gluconate All other gluconic acid salts Glycolic acid, potassium salt Glycolic acid, sodium salt 2-Hydroxyethane.sutlonic acid, sodium salt Isoascorbic acid, sodium salt (Sodium erythorbate) Tertiary-alpha-alkylcarboxylic acid salts (isocarboxylic acid salts): Calcium t-a-alkylcarboxylate Cobalt t-a-alkylcarboxylate Cobalt/iron alkylcarboxylate Cobalt/manganese/zirconium alkylcarboxylate Cobalt/potassium/zirconium alkylcarboxylate Cobalt/zirconium t-a-alkkyylIcarboxylate Copper t-a-alkylcarboxylate Iron t-a-alkylcarboxylate Lead t-a-alkylcarboxylate Manganese t-a-alkylcarboxylate Mixed t-a-alkylcarboxylic acid salts Zinc t-a-alkylcarboxylate Zirconium t-a-alkylcarboxylate All other t-a-alkylcarboxylic acid salts (Isocarboxylic acid salts) Isooctanoic acid salts: Isooctanoic acid, manganese salt Lactic acid salts: Ammonium lactate Potassium lactate Sodium lactate (Nalac) Lauric acid salts: Barium cadmium laurate Barium laurate Cadmium laurate Dibutyltin dilaurate Lauric acid, zinc salt Mercaptoacetic acid (thioglycolic acid) salts: Ammonium mercaptoacetate Sodium mercaptoacetate Methanesulfonic acid, zinc salt N-Methyl taurine, sodium salt (2-Methyl-2aminoethanesulic acid, sodium salt) Neodecanoic acid, diethanolamine salt Neodecanoic acid salts: Bismuth neodecanoate Calcium neodecanoate Cobalt manganese neodecanoate Cobalt-manganese-zirconium neodecanoate Cobalt neodecanoate Lead-cobalt neodecanoate Lead neodecanoate Lithium neodecanoate

No No No

RSA. IMC. BKC, PST.

No No No No No No

PFN, PFZ, PMP. JRC. HCP. HCP, JRC. RDA. PFZ.

No No No No No No No No No No No No No

MCI. MCI. MCI. MCI. MCI. MCI. MCI. MCI. MCI. MCI. MCI. MCI. MCI.

No

MCI.

No Yes No NO No Yes No No No No No

CCA. WM. ' PFN. BFP. WTC. SYP. SYP. PAS, WTC. SYP.

No No No

EVN, WTC. EVN. PCW.

No No

RDA. QCP.

No No No No No No No No

MCI, SHP. MCI, SHP. SHP. MCI. MCI, SHP. MCI. MCI. MCI.

See footnotes at end of table.

15-23

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Salts of organic acids-Continued Neodecanoic acid salts-Continued: Manganese neodecanoate Neodecanoic acid, potassium salt Rare earths neodecanoate Zinc neodecanoate Zirconium neodecanoate All other neodecanoic acid salts Octanoic-acid (caprylic acid) salts: Aluminum octanoate Oxalic acid salts: Ammonium oxalate Copper oxalate Potassium oxalate Sodium oxalate All other oxalic acid salts Palmitic acid salts: Pelargonic acid, barium salt(Barium nonoate) Pelargonic acid, calcium salt (Calcium nonoate) Phosphorodithioic acid salts (dithiophosphates): Sodium di-sec-butyl/diethyl phosphorodithioate Sodium di-sec-butyl phosphorodithioate Sodium diethyl phosphorodithioate Sodium diisobutyl phosphorodithioate Sodium diisopropyl phosphorodithioate Propionic acid salts: Ammonium propionate Calcium propionate Sodium propionate All other propionic acid salts Ricinoleic acid salts: Lithium ricinoleate Protein hydrolyzates, sodium salts Ricinoleic acid, magnesium salt Stearic acid salts Aluminum stearates: Aluminum distearate Aluminum monostearate Aluminum tristearate Barium stearate Cadmium stearate Calcium stearate Cobalt stearate Lead stearate, dibasic Lithium stearate Magnesium stearate Manganese stearate Potassium stearate Sodium stearate Strontium stearate Zinc stearate All other stearic acid salts Thioacetic acid, potassium salt All other salts of organic acids Aldehydes: Acetaldehyde Acrolein (Acrylaldehyde) Butyraldehyde Crotonaldehyde 2-Ethylhexanal (a-Ethylcaproaldehyde)

See footnotes at end of table. 15-24

Separate statistics'

Manufacturers' identification codes (according to list In table 15-3)

No No No No No No

MCI, SHP. MCI, OCR MCI, SHP. SHP. MCI, SHP. MCI.

Yes Yes No No No No No

NOC, SYP, WTC.

No No

SYP. SYP.

No No No No No

ACY. ACY, ELC. ACY, ELC. ELC. ACY.

No Yes Yes No

KMI. CHO, DVR, HFT, KMI, NCC. CHO, HFT, NCC. MCK.

No No No Yes Yes yes Yes Yes No Yes Yes

CAS. SDC. CAS.

BKC, HML. SHP. BKC, HML. HML. SHP.

No No Yes No No No No No Yes No No No

MAL, NOD, SHP, SYP. MAL, NOD, SYP. MAL, NOC, NOD, SYP, WTC, (2). NOD, SYP, WTC. FER, SYP, WTC. FER, MAL, NOC, NOD, SCP, SQA, SYP, WTC. MCI, SHP. ALI. NOC, SYP, WTC. MAL, MCI, NOD, SYP, WTC. SHE WTC. WTC. WTC. CCC, MAL, NOC, NOD, PLS, SYP, WTC. FER, MCI. RSA. BRD, CCA, EK, EKT, FER, SK, ( 2).

Yes No Yes No No

EKX, HCL, UCC. UCC. BAS, EKX, HCL, UCC. EKT. EKX, UCC.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

.Separate statisticsi

Manufacturers' identification codes (according to list in table 15-3)

Yes

AQU, BCP, BOR, CBD, DGC, DUP, GAF, GP, HCL, IMC, MON, PST, WCL UCC. ACY, BAS. BAS, EKX, HCL, UCC. HCL. EKX, HCL, UCC. UCC. ASL, UCC.

Miscellaneous chemicals, acyclic-Continued Aldehydes-Continued Formaldehyde (37% HCHO by Weight) Glutaraldehyde Glyoxal Isobutyraldehyde n-Nonyialdehyde (Nonanal) Propionaldehyde Valeraldehyde (Pentanal) All other aldehydes, acyclic Ketones: Acetone

No No No No No No No Yes Yes

5-Chloro-2-pentanone No 1-Chloropinacolone No Diisopropyl ketone (2,4-Dimethy1-3-pentanone) No 2-Heptanone (Methyl amyl ketone) No 3-Heptanone (Ethyl butyl ketone) No 4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) Yes Isovalerone (Diisobutyl ketone) No Methyl ethyl ketone Yes 5-Methyl-2-hexanone (Methyl isoamyl ketone) No Methyl isobutyl ketone Yes Methylisopropyl ketone No Methyl nonyl ketone (2-Undecanone) No 4-Methyl-3-penten-2-one (Mesityl oxide) No Methylpropyl ketone No Methylpseudoionone No 2-Octanone (Hexyl methyylI ketone) No 2,4-Pentanedione (Ac etone) No 3-Pentanone (Diethyl ketone) No Pseudoionone No 2,6,8-Trimethy1-4-nonanone (Isobutyl heptyl ketone) No All other ketones No Alcohols, monohydric, unsubstituted: Yes Alcohols, C11 or lower, unmixed (95% or Yes more pure): Ally! alcohol No Amyl alcohols: No 2-Methy1-1-butanol 3-Methy1-1-butanol (Isoamyl alcohol) No 1-Pentanol No Butyl alcohols: n-Butyl alcohol (n-Propylcarbinol) Yes sec-Butyl alcohol (Methylethylcatinol) No tart-Butylalcohol (TrimetlrAcarbinol) No Isobutyl alcohol (Isoprop*arbinol) Yes No 1-Decanol 2,2-Dimethylbutanol (Isohexyl alcohol) No Ethyl alcohol, synthetic Yes Yes 2-Ethyl-1-hexanol No n-Hexyl alcohol No alcoh l lsodecyl No lsoheptyl alcohol No lsononyl alcohol No Iso-octyl alcohol Yes Isopropyl alcohol

ACS, ART, ATR, BTL, DOW, ENJ, GE, GGC, SHC, TX, UCC. SDW. CHG. EKX. EKT. UCC. HCL, SHC, UCC. EKT, UCC. ENJ, HCL, LYP, SHC, UCC. EKT. EKT, ENJ, SHC, UCC. EKX. ARC. UCC. EKT. NCI, SCM. UPM, WTH. UCC. UCC. NCI, SCM. UCC. ASL

ATR. UCC. CPS. UCC. BAS, EKX, GAF, HCL, SHC, UCC, VST. ENJ, SHC. ATR, BAS, CPS, EKX, HCL, SHC, UCC, ( 2). TNA, VST. ENJ. DOW, EKX, HCL, SHC, UCC, USI, VST. ART, BAS, EKX, SHC, UCC. TNA, VST. ENJ. ENJ. ENJ. ENJ. ATR, ENJ, LYP, SHC, UCC PLC, TOC, (4).

See footnotes at end of table. 15-25

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statisticsi

Miscellaneous chemicals, acyclic-Continued Alcohols, monohydric, unsubstituted—Continued Alcohols, Cii or lower, unmixed (95% or more pure) -Continued Methanol, synthetic Yes 2-Methyl-1 -pentanol 4-Methyl-2-pentanol (1-Methylisobutylcarbinot) 1-Octanol 2-Octanol (sec-Capryl alcohol) Propyl alcohol (Propanol) 2-Propyn-1-ol (Propargyl alcohol) Undecanol (Linear C11 alcohol) All other alcohols, unmixed C11 or lower Alcohols Cii or higher, unmixed (95% or more pure): Dodecyl alcohol (Lauryl alcohol) Eicosyl alcohol (Arachidyl alcohols i.e., 20carbon) 1-Hexadecanol (Cetyl alcohol) Isooctadecanol 1-Octadecanol (Stearyl alcohol) cis-9-Octadecen-1-ol (Oleyl alcohol) 1-Tetradecanol (Myristyl alcohol) 1-Tridecanol All other alcohols, unmixed C11 or higher Mixtures of alcohols: Alcohol mixtures, C11 or lower only Alcohol mixtures, C12 through C18 only Fatty alcohols, C8-C30 All other mixtures of alcohols, C12 and higher Alcohol mixtures, other Esters of monohydric alcohols: C12-C15 alcohol-lactates Ally' methacrylate Amyl acetates: Amyl acetate (n-Pentyl acetate) Butyl acetates: n-Butyl acetate Isobutyl acetate Butyl acrylate sec-Butyl chloroformate Butyl lactate Butyl mercaptopropionate Butyl methacrylate Butyl oleate n-Butyl perchlorocrotonate Carboxyethyl acrylate Cetyleicosyl methacrylate Cetyl lactate Dialkyl dicarbonate Dibutyl maleate Didecyl adipate Diethyl carbonate (Ethyl carbonate) Di(2-ethyl-1 -hexyl) maleate Diethyl maleate Diethyl oxalate (Ethyl oxalate) Dilauryl-3,3'-thiodipropionate Dimethyl carbonate Dioctyl maleate Distearyl-3,3'-thiodipropionate Dithiobis(stearyl propionate)

See footnotes at end of table. 15-26

Manufacturers' Identification codes (according to list in table 15-3)

No No No No No No No No

AIP, BCP, DUP, EKT, ENJ, GGC, HCL, LYP, UCC. UCC. TNA, VST. WTH. ATR, EKX, HCL, UCC. GAF. BAS, ENJ. SHC, UCC.

Yes

PG, TNA, VST.

No No No No No No No No Yes Yes Yes No No No Yes No No

ENJ. ENJ, PG, TNA, VST. SHX. ENJ, PG, TNA, VST. SHX. PG, VST. ENJ. EKT.

No Yes Yes Yes Yes Yes No No No No No No No No No No No No No No No Yes No No Yes No

UCC.

BAS, ENJ, PG, SHC, TNA, UCC, VST. PG, SHC, SHX, TNA, VST.

VST. ENJ, VST. VND. CPS.

BAS, EKT, HCL, UCC. BAS, EKT, EKX, HCL UCC. BAS, HCL, RH, UCC, WTL PAS, PPG, VCM. CPS. EVN. DUP, RH. ELC. MAL RDA. RH. VND. SYT. ART, NOD. QCP. PPG. CHP. ACY.

Paw, EVN, WTC. PPG. NOD. ACY, CCW, EVN, WTC. EVN.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Esters of monohydric alcohols-Continued Ditridecyl maleate Di(tridecyI)-3,3'-thiodipropionate Dodecylpentadecyl methacrylate 2-Ethoxyethyl acetate Ethyl acetate (85%) Ethyl acetate (100% basis) Ethyl acetoacetate Ethyl acrylate Ethyl chloroformate Ethyl 3-ethoxy propionate 2-Ethyl-1-hexyl acetate 2-Ethyl-l-hexyl acrylate 2-Ethylhexyl chloroformate 2-Ethyl-l-hexyl methacrylate Ethyl maleate, mono Ethyl methacrylate Ethyl sulfate (Diethyl sulfate) Fatty acid esters, not included with plasticizers or surface active agents: Diisopropyl dimerate Diisostearyl dimerate Docosanyl docosenoate 2-ethyihexyl stearate Hexadecyl hexadecanoate (Palmitic paimitate) Isocetyl stearate Isodecyl mercaptoacetate Isodecyl neopentanoate Isostearyl isostearate Methyl behenate Methyl esters of cottonseed oil Methyl esters of lard oil Methyl esters of tallow Methyl 12-hydroxystearate Methyl oleate Methyl pentachlorostearate Methyl pivalate Methyl stearate Myristyl mynstate Myristyl stearate Stearyl stearate 1-Tetradecylpropionate Tridecyl stearate Fatty acid esters, not included with plasticizers surface-active agents, all other Hexyl acetate Hexyl acrylate Hexyl neopentanoate sobutyl acrylate sobutyl chloroformate sobutyl isobutyrate sobutyl methacrylate sodecyl acrylate sodecyl methacrylate so-octyl mercaptoacetate so-octyl-3-mercaptopropionate sopropyl acetate sopropyl chloroformate sostearyl neopentanoate

Separate statistics1

No No No No Yes No No No No No Yes No No No No No No Yes No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No Yes No No

Manufacturers' identification codes (according to list in table 15-3)

EFH. EVN, WTC. RH. CNE, UCC. HCL. EKX, MON, UCC. BRD, EKT. HCL, RH, UCC. PPG. EKT, TX. EKT. BAS, HCL, UCC, WTL. PAS, PPG, VCM. DUP. RDA. DUP. UCC. SBC. SBC. SBC. BRI. SCP. VND. EVN. BDS. SBC. WTC. CHL. CHL, FER. CHL, FER, WTC, (2). CAS. CHL. VCM. alL, VND, WTC. RDA, SBC. WTC. RDA. BRD. WTC. SHX. EMI. CPS. SBC. BAS. PPG, VCM. EKX. RH. CPS, RDA. EVN, RH. CCW, EVN. EVN. EKT, HCL, UCC. PPG, VCM. SBC, VND.

See footnotes at end of table.

15-27

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Esters of monohydric alcohols-Continued Lauryl acrylate Lauryl lactate Lauryl methacrylate 1-Methoxy-2-ethyl acetate 2-Methoxyethyl acrylate Methyl acetoacetate Methyl acrylate Methyl butyrate Methyl chloroformate Methyl 3,3-dimethy1-4-pentenoate Methyl formate Methyl methacrylate Methyl pivaloylacetate Methyl sulfate (Dimethyl sulfate) Myristyl lactate Octadecyl-3-mercaptopropionate Phosphorus acid esters: Alkoxylated acidrosphate Bis-(2-chloroeth )-2-chloroethylphosphonate Bis(2-ethylhexyl hydrogen phosphite Butyl acid phosphate Chloroalkyl diphosphate ester, neutral Chioroalkyl phosphate ester Dibutyl butyiphosphonate Dibutyl hydrogen phosphite Diethylhexyl phosphoric acid Diethyl phosphorochloridothionate 'Dimethyl hydrogen phosphite Dimethyl methylphosphonate 2-Ethylhexyl hydrogen phosphate Iso-octyl hydrogen phosphate Methyl dihydrogen phosphate Mixed dialkyl hydrogen phosphates, amine salts mono(2-Ethylhexyl)-2-ethyihexylphosphonic acid Stearyl acid phosphate Tetraisopropylmethylene diphosphonate Trialkyl thiwhosphite Triethyl phosphite Triethyl phosphonacetate Triisodecylphosphite Triisooctyi phosphite Triisopropyl phosphite Trimeth phosphite Tris(2-c loroethyl)phosphate Tris(2-chloroethyi) phosphite Tris-2-chloropropyl phosphate Tris(1,3-dichloro-2-propyl) phosphate All other phosphorus acid esters Propyl acetate n-Propyl chloroformate Stearyl methacrylate Tetraethyl orthosilicate (Tetraethyl silicate) Titanic acid esters: Bis[2-(bis[2-hydroxyethylJamino)ethyl] diisopropyl titanate Bis(ethy1-3-oxobutanato)bis(2-propanolato) titanium Di(hydroxy)bis(ammoniumiactato)titanium

See footnotes at end of table. 15-28

Separate statistics1

Manufacturers' Identification codes (according to list in table 15-3)

No No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No

CPS. VND. CPS, RH. EKX. CPS. BRD, EKT. HCL. PD. PPG. FMN. HCL CYR, DUP, RH. EKT. DUP, NOD. CAS, VND. EVN.

No

ELC.

No No No No No No No No No No No No No No No Yes No No No

ALW, ASL HK. ALW. GE. ALW, ICI. AMV. DVC, WTC. ALW, GE. ALW. ALW, ICI. PEL ALW. ALW, PEL ALW. AUN, DVC, (2). BAS, EKT, HCL, UCC. PAS, Wit CPS, RH, TX. UCC.

No

DUP.

No No

DUP. DUP.

ALW. ALW. ALW. ALW, HK. ALW. ALW. ALW. ALW. ALW. TNA. ALW. ALW. ALW. ALW. HK.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Manufacturers' identification codes (according to list in table 15-3)

Miscellaneous chemicals, acyclic-Continued Esters of monohydric alcohols-Continued Titanic acid esters-Continued Tetrabutyl titanate Tetraisopropyl titanate Tetrakis(2-ethylhexyl)titanate Triethanolamine titanate All other titanic acid esters Triethyl orthoacetate Triethyl orthoformate Triethyl orthopropionate Trimethyl orthoacetate Trimethyl orthoformate Vinyl acetate, monomer All other monohydric alcohol esters Polyhydric alcohols: 2,2-Bis(bromomethyl)-1,3-propanediol 2-Bromo-2-nitropropanediol 1,2(and 1,3)-Butanediol 1,4-Butanediol 2-Butene-1,4-diol 2-Butyne-1,4-diol 3-Chloro-1,2-propanediol (Glycerol a-chlorohydrin) 2,2-Dimethy1-1,3-propanediol (Neopentyl glycol) Ethylene glycol 2-Ethyl-1,3-hexanediol 2-Ethy1-2-(hydroxymethyl)-1,3-propanediol (Trimethylolpropane) Glycerol, synthetic only 1,6-Hexanediol 2-(Hydroxymethyl)-2-methyl-1,3-propanediol (Trimethylolethane) Mannitol 3-Mercapto-1,2-propanediol (Thioglycerol) 2-Methyl-2,4-pentanediol (Hexylene glycol) 2-Nitro-2-ethyl-1,3-propanediol 2-Nitro-2-methyl-1,3-propanediol Pentaerythritol 1,5-Pentanediol Propylene glycol (1,2-Propanediol) Sorbitol (70% by Weight) Sorbitol, crystalline Starch, hydrolyzed and hydrogenated 2,2,4-Trimethyl-1,3-pentanediol All other polyhydric alcohols Esters and ethers of polyhydric alcohols: Polyhydric alcohol esters: 2-(2-Butoxyethoxy)ethyl acetate 2-Butoxyethyl acetate 1,3-Butylene glycol diborate 1,3-Butylene glycol diborate/hexylene glycol boric anhydride 1,3-Butylene glycol dimethacrylate Diethylene glycol adipate Diethylene glycol chloroformate Diethylene glycol dimethacrylate Dipropylene glycol monomethyl ether acetate

No No No No No No No No No No Yes No

DUP. DUP. DUP, NOD. NOD. DUP. NOD. NOD. NOD. NOD. NOD. DUP, HCL, UCC, USI. BAS, BRD, DUP, EKT, ENJ, MON, PAH, SBC, SCP, VND, (2), (2), (2), (2).

No No No Yes No No

TNA. ANG. HCL. BAS, DUP, GAF. GAF. BAS, GAF.

No

DIX, EVN.

Yes No No

BAS, EKX. BAS, CNE, CXI, DOW, EKX, HCL, PDG, PLC, SHC, TX, UCC, (2). UCC.

No No No

HCL DOW, SYP. BAS, CXI.

No No No No No Yes No No No No No No No No Yes Yes Yes No No

1MC. ICI. EVN. ATR, SHC, UCC. ANG. ANG. AQU, HCL, PST. BAS. ATR, DOW, OMC, PLC, TX, UCC. ADM, BRD, EHC, ICI, PFZ, RQT. ICI, PFZ, RQT. RQT. EKX. BAS, BRD, ICI, (2), (2).

No No No No No

USB. CPS. HAL. PPG. CPS.

No

ATR, (2).

CNE, EKT, UCC. CNE, EKT, UCC. USB.

See footnotes at end of table.

15-29

Section 15 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Miscellaneous chemicals, acyclic-Continued Esters and ethers of polyhydric alcohols-Continued Polyhydric alcohols-Continued 2-(2-Ethoxyethoxy)ethyl acetate No Ethylene glycol diacetate No Ethylene glycol dimercaptoacetate No Ethylene glycol dimethacrylate No 2-Ethy1-2(hydroxymethyl)-1,3-propanediol trimethacrylate (TMP methacrylate No Glycerides, mixed C14- 18 and C16- 18, monoand diNo Glyceryl diacetate (Diacetin) No Glyceryl monothioglycolate No Glyceryl triacetate (Triacetin) No Hydroxyethyl acrylate No Hydroxyethyl methacrylate No Hydroxypropyl acrylate No Hydroxypropyl methacrylate No 1-Methonr-2-propyl acetate No NeopentAlycol hydroxypivalate No Neopentyl glycol oleate No Neopentyl glycol vegetable oil ester No Pentaerythritol tetrakis (3-Mercaptopropionate) No Pentaerythritol tetraoctanoate No Pentaerythritol tetrastearate No Propylene carbonate No Propylene glycol dicaprylatecaprate No Sucrose octa-acetate No Trimethylolpropane tallowate (TMP tallowate .... No Trimethylolpropane triacrylate No Trimethylolpropane trimethac ate No Trimethylolpropane trioleate P trioleate) No Trimethylolpropane tris-3-mercaptopropionate No 2,2,3-Trimethy1-1,3-pentanediol monoisobutyrate No Tripropylene glycol diacrylate No All other polyhydric alcohol esters No Polyhydric alcohol ethers: Bis(2-butoxyethyl)ether (Diethylene glycol di-nbutyl ether) Bis(2-ethoxyethyl)ether (Diethylene glycol diethyl ether) Bis[2-(2-methoxyethoxy)ethyl] ether (Tetraethylene glycol dimethyl ether) 2-Butoxyethanol (Ethylene glycol monobutyl ether 2-(2-Butoxyethoxy)ethanol (Diethylene glycol monobutyl ether) 242-(2-Butoxyethoxy)ethoxyjethanol (Triethylene glycol monobutyl ether) 1-Butoxyethoxy-2-propanol tyre aldeh ydrimer t Diethylene glycol Diethylene glycol mono-n-propyl ether Dimethoxyethane (Ethylene glycol dimethyl ether) 2-Ethoxyethanol (Ethylene glycol monoethyl ether) 2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl ether)

See footnotes at end of table.

15-30

Manufacturers' identification codes (according to list in table 15-3)

EKT. EKT. EVN. CPS. BRD. BRD, SHX, WTC. HAL EVN, WTC. EKT. DOW, RH. RDA, RH. DOW, RH. RH. ATR, (2). EKX. QCP. QCP. EVN. BRD. BRD, HPC. ATR. TX. HFT. QCP. CPS. CPS. EFH, QCP. EVN. EKX. CPS. BRD, EK, GPI, HAL, TX, UCC.

Yes No

FER.

No

FER.

No

FER.

Yes

CNE, DOW, EKX, SHC, UCC.

Yes

CNE, DOW, EKX, SHC, UCC.

Yes No No Yes

CNE, DOW, UCC. UCC.

DS, CNE, CXI, EKX, HCL, OMC, PDG,

No

SHC, TX, UCC, USI. EKX, UCC.

No

FER.

Yes

CNE, EKX, OMC, UCC.

Yes

CNE, EKX, OMC, UCC.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Polyhydric alcohol ethers-Continued 2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol monoethyl ether) Ethylene glycol di-tributyl ether Ethylene glycol di-triethyl ether Glycerol monoallyl ether 2[2-(Hexyloxy)ethoxy]ethanol 2-Methoxyethanol (Ethylene glycol monomethyl ether) 2-(2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl ether) 242-(2-Methoxyethoxy)ethoxy]ethanol (Triethylene glycol monomethyl ether) 2-(2-Methoxyethoxy)ethyl-2-methoxyethyl ether (Triethylene glycol dimethyl ether) Methoxypolyethylene glycol Paraformaldehyde Polyethylene glycol Polyethylene glycol butyl ether, propoxylated Polyethylene glycol dimethyl ether Polyglycols, ethylene glycol and glycol ether, mixed Polyoxyalkylene glycol Polyoxypropylene polyoxyethylene glycol, mixed Polytetramethylene glycol ether Poly(1,1,1-trichlorobutane-2-ol)ethylene glycol dextrose ether Glycolethers derived from propylene oxide: Dipropylene glycol Dipropylene glycol monomethyl ether (3-(3ethoxypropoxy)propanol) Ethylene glycol di-tri-propyl ether Propylene glycol t-butyl ether Propylene glycol, mixed ethers Propylene glycol monobutyl ether Propylene glycol monomethyl ether (1-Methoxy-2propanol) Tripropylene glycol Tripropylene glycol monomethyl ether (3-(3-[3Methoxypropoxy]propoxy)propanol) All other propylene glycol ethers (and propylene glycols) Polyether polyols based on propylene oxide: Polypropylene glycol Polypropylene glycol butyl ether (Polypropoxy butyl ether) Polypropylene glycol butyl ether, ethoxylated (Polypropoxy butyl ether, ethoxylated) Polypropylene glycol glycerol triether (Polypropoxyglyceryl triether) 1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-, polymer with oxirane All other polyether polyols based on propylene oxide Propoxyethanol (Ethylene glycol monopropyl ether) Propylene glycol, alkoxylated

Separate statistics1

Manufacturers' identification codes (according to list in table 15-3)

No No No No No

CNE, OMC, UCC. EKX. EKX, FER. RDA. UCC.

No

CNE, OMC, UCC.

No

CNE, DOW, OMC, UCC.

Yes

CNE, OMC, UCC.

Yes No No Yes No No

FER, OMC. PPG, RDA, UCC, (2). HCL. ABB, BAS, DOW, OMC, PPG, SCP, SHX, UCC, (2). ICI. DAN, SCP, SHX.

No No No Yes

HCL, UCC, (2). OMC. UCC. BAS, DUP, QKO.

No

DOW.

Yes No

ATR, EKX, OMC, PLC, TX.

No No No No No

ATR, OMC. EKX. ATR, (a). EKX. OMC.

No No

ATR, OMC. ATR, DOW, UCC, (2).

No

ATR, OMC.

No Yes Yes

(2).

No

PPG.

No

BAS, PPG.

No

PPG, RDA.

No

(2).

No

EKX, TX.

No No

EKX. (2).

BAS, DOW, OMC, PPG, RDA, TX, (2).

See footnotes at end of table.

15-31

Section 15 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics"'

Miscellaneous chemicals, acyclic-Continued Polyhydric alcohol ethers- Continued Sorbitol, alkoxylated Sorbitol, ethoxylated Sorbitol monooleate Sorbitol monostearate Tetraethylene glycol Tetra/penta glycols, mixed 2,2'-Thiodiethanol (Thiodiglycol) Triethylene glycol

No No No No Yes No No Yes

All other polyhydric alcohol ethers

No

Brominated, chlorinated and fluorinated hydrocarbons: Yes Brominated (including bromochlorinated) Yes hydrocarbons: Brominated hydrocarbons, C12-C1 8 No 1-Bromobutane (n-Butyl bromide) Yes Bromochioromethane No Bromodecane (Decyl bromide) No Bromodocosane No Bromoethane (Ethyl bromide) No Bromomethane (Methyl bromide) No 1-Bromo-3-methyl-2-butene No 1-Bromo-octadecane No 1-Bromopentane(n-Amyl bromide) No 1-Bromopropane (nP ropyi bromide) No 2,3-Dibromobutane No Dibromomethane (Methylene bromide) No All other brominated (Including bromochiorinated) hydrocarbons No Chlorinated (not otherwise halogenated) hydrocarbons: Yes Carbon tetrachloride Yes Yes Chlorinated paraffins (C10-C30): Chlorinated paraffins, 35-64% chlorine Yes Chlorinated paraffins, less than 35% chlorine No Chlorinated paraffins, 65% or more chlorine No 1-Chlorobutane (n-Butyl chloride) No Chloroform Yes Chloromethane (Methyl chloride) Yes 3-Chloropropene (Ally, chloride) No Decyl chloride No Yes 1,2-Dichloroethane (Ethylene dichloride) 1,2-Dichloropropane (Propylene dichloride) 2,3-Dichloropropene n-Dodecyl chloride Ethyl chloride (Chloroethane) 2-Ethylhexyl chloride Hexadecyl chloride Methylene chloride (Dichloromethane) Octadecyl chloride Octyl chloride Perchloroethylene (Tetrachioroethane) n-Tetradecyl chloride Tetrahydroalloocimenyl hydrochloride (Tetrahydrodimethylatriene hydrochloride See footnotes at end of table.

15-32

Manufacturers' identification codes (according to list in table 15-3)

ICI, (2). PPG, (2). WTC. WTC. CNE, DOW, EKX, UCC. CXI. MRT, PLC, RDA. CNE, CXI, DOW, EKX, HCL, PDG, SHC, TX, UCC. DUP, MIL, PAH, SCP, SM, UCC, (2).

DVC. DAZ, GTL, UCC. TNA. HMY. HMY. GTL TNA. SD. HMY. DAZ. DAZ, GTL HMY. TNA. FER, TNA. AKZ, DOW, FRO, HK, LCP.

No No No No No No Yes No No Yes No

DVC, FER, HK. SHC. DVC, FER, HK. ALW. DOW, FRO, HK, LCP. DCC, DOW, FRO, HK, LCP, SPD, VST. DOW, SHC. BRD. ALW, BFG, DOW, FOR, FRO, GGC, HK, PLC, PPG, SHC, VST, WLK. DOW. SHC. BRD. DOW, DUP, PPG. ALW. BRD. DOW, FRO, HK, LCP. BRD. BRD. DOW, FRO, HK, PPG. BRD.

No

NCI.

Synthetic Organic Chemicals, 1991 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals Miscellaneous chemicals, acyclic-Continued Brominated, chlorinated and fluorinated hydrocarbons-Continued Chlorinated (not otherwise halogenated) hydrocarbons-Continued 1,1,1-Trichloroethane(Methyl chloroform) 1,1,2-Trichloroethane (Vinyl trichloride) Trichloroethylene 1 ,2,3-Trichloropropane Vinyl chloride, monomer (Chioroethylene) Vinylidene chloride, monomer (1,1-Dichloroethylene) All other chlorinated (Not otherwise halogenated) hydrocarbons Fluorinated (including other fluorohalogenated) hydrocarbons: Bromochlorodifluoromethane 2-Bromo-2-chloro-1,1,1-trifluoroethane (Halothane) Bromodifluoromethane Bromotrifluoromethane 1-Chloro-1,1-difluoroethane (F-142b) Chlorodifluoromethane (F-22) 2-Chloro-1,1,1,2-tetraftuoroethane (F-124) Chlorotrifluoroethylene (Trifluorovinyl chloride) 2-Chloro-1,1,2-trifluoroethyl methyl ether Chlorotrifluoromethane (F-13) Dibromodifluoromethane 1,2-Dibromo-1,1,2,2-tetrafluoroetbane Dichlorodifluoromethane (F-12) 1,1-Dichloro-1-fluoroethane (141 b) Dichlorotetrafluoroethane (F-114) Dichloro-trifluoroethane (F-123) 1,1-Difluoroethane Hexafluoropropylene, monomer 1-lodoperfluorohexane 1,2,2,2-Tetrafluoroethane (F-134a) Tetrafluoroethylene (F-1114) Tetrafluoromethane (F-14) Trithlorofluoromethane-11) Trichlorotrifluoroethane (F-113) Trifluoropropene Vinyl fluoride, monomer Vinylidene fluoride, monomer All other fluorinated (including other fluorohalogenated hydrocarbons) Other miscellaneous acyclic chemicals: Iodinated (not otherwise halogenated) hydrocarbons: Ethylhexyl iodide (lodoethyl hexane) lodobutane lodoethane (Ethyl iodide), non-medical lodomethane (Methyl iodide) All other iodinated (Not otherwise halogenated) hydrocarbons Acetylacetonates: Aluminum acetylacetonate Titanium acetylacetonate All other acetylacetonates See footnotes at end of table.

Separate statistics1

Manufacturers' identification codes (according to list in table 15-3)

Yes No No No Yes

DOW, FRO, PPG. DOW. DOW, PPG. DOW. BCP, BFG, DOW, FOR, GGC, HK, PLC, PPG, VST, WLK.

No

DOW, PPG.

No

BRD.

Yes No No No No No Yes No No No No No No Yes No No No No No No No No No Yes No No N No No

GTL. HOC. GTL. DUP, GTL. PAS. ACS, DUP, LRO, PAS. (2). ACS. OH. DUP, GTL. GTL CS, DUP, LRO, PAS. PAS. ACS, DUP, PAS. HOC. DUP. DUP. DUP. HOC. DUP. DUP. ACS, DUP, LRO, PAS. ACS, DIX, DUP. GTL, HOC. DUP. PAS. DUP, HOC, REG, (2).

Yes No No No No

RSA. RSA. RSA. RSA.

No

RSA.

No No No

MCK. NOD. MCK.

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' Identification codes (according to list in table 15-3)

Miscellaneous chemicals, acyclic-Continued Other miscellaneous acyclic chemicals-Continued Acyclic peroxides: acetone peroxide hydroperoxide tertt-Amylperoxy acetate t-Amylperoxy neodecanoate t-Arnylperoxy pivalate 2-Butanone peroxide (MEK peroxide) n-Butyl-4,4-bis[t-butylperoxyjvalerate t-Butyl-2-ethylhexyl monoperoxycarbonate tert-Butyl hydroperoxide tert-Butyl peroxide (Di-tert-butyl peroxide) tert-Butyl peroxyacetate tert-Butyl peroxy-2-ethylhexanoate tert-Butyl peroxyisobutyrate tert-Butyl peroxyisopropylcarbonate tert-Butyl peroxy malefic acid tert-Butyl peroxyneodecanoate tert-Butyl peroxypivalate Decanoyl peroxide Di(sec-butyl)peroxydicarbonate Di-(2-ethylhexyl) peroxydicarbonate 2,5-Dihydroperoxy-2,5-dimethylhexane 2,5-Dimethyl-2,5-ditert-butylperoxylexane 2,5-Dimethyl-2,5-di tert-butylperoxy hexyne-3 2,5-Dimethyl-2,5.di 2-ethylhexano peroxy)hexane 2,5-Dimethyl-2,5-dighydroperoxy) hexane 1 ,1 -Dimethy1-3-hydroxybutylperoxyneoheptanoate 1,1-Dimethy1-3-hydroxybutylperoxyneohexanoate Di-n-propyl peroxydicarbonate Ethyl-3,3-di(t-amylperoxy)butyrate Ethyl 3,3-di(t-butyl peroxy) butyrate Lauroyl peroxide 2,4-Pentanedione peroxide Peroxyacetic acid (Peracetic acid) Succinyl peroxide Tertiary amyl per-2-ethylhexanoate An other acyclic peroxides Brominated pentaerylbritol 2-Butenediotc, monomethyl ester, polymer with methoxyethene Carbon disulfide Carboxylic acid alto Epoxides, ethers, and acetals: Bis(2-chloroethyl)ether (Dichiorodiethyl ether) Butylene oxide sec-Butyl ether Butyl vinyl ether Chloromethyl methyl ether 2,2-Dichloro-1,1-difluoroethyl methyl ether Dimethyl disulfide Dimethyl sulfide Dimethyl sulfone Epichlorohydrin Ethylene oxide Ethyl ether

See footnotes at end of table.

15-34

Yes No No No No No Yes No No No No No No No No No No No No No No No No

No

CAD, PAS. PAS, WTC, WTL WTL. WTL WTL. CAD, PAS, WTC, WTL PAS, WTL PAS, WTL ATR, NOC, PAS, WTC, INTL. PAS, WTC, WTL AZT, PAS, WTL AZT, PAS, WTC, WTL PAS, WTI. PAS, WTL. PAS, WTL. PAS, WTC, WTL AZT, PAS, WTC, WTL. PAS, WTL PAS, WTL. PAS, WTC, WTL PAS, WTI_ AZT, PAS, WM. AZT, PAS, WTL.

No No

PAS, WTC, WTL WTL

No

PAS.

No No No No No No No No No No No

WTL PAS, WTL PAS, WTL PAS, WTL PAS, WTL WTL

No No No Yes No No No No No No No No No No Yes

TNI. AKZ, PAS. (s).

No

WTL. WTC, WTL. WTL TNA.

BKM. DOW. ENJ. GAR RH. OH. PAS. PAS. AUS. DOW, SHC. BAS, CNE, DOW, EKX, HCL, OMC, SHC, SUN, TX, UCC, USI. EKX, USI.

Synthetic Organic Chemicals, 1991 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Manufacturers' Identification codes (according to list in table 15-3)

Miscellaneous chemicals, acyclic-Continued Other miscellaneous acyclic chemicals-Continued Epoxides, ethers, and acetals-Continued Ethyl vinyl ether Glycidol (2,3-Epoxy-1-propanol) Glycidyl ethers: ly-2,3-epoxypropane (Ally) glycidyl 1-(li ether) 1-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) tert-Butyl glycidyl ether All other glycidyl ethers Isopropyl ether Methylal (Dimethoxymethane) Methyl vinyl ether Poly(oxy-1,2-ethanediy1), a-(1-oxotetradecyI)Propylene oxide 1,1,3,3-Tetramethoxypropane Tri- and tetraacrylate monomers All other epoxides, ethers, acetals 2-(Ethylmercapto)ethanol Fats and oils, chemically modified: Brominated vegetable oil Castor oil, hydrogenated Castor oil, polymerized Chlorinated fatty materials Hydrogenated menhaden fish oil Hydrogenated tallow glycerides Palm oil, hydrogenated Tallow, partially hydrogenated Vegetable glycerides, hydrogenated All other fats and oils, chemically modified Glutaraldehyde bis(sodium bisulfite) Hydrocarbons: n-Decane 3,3-Dimethylbutene n-Dodecane Hexadecane Myrcene n-Octadecane n-Octane n-Tetradecane All other hydrocarbons 2-Mercaptoethanol Methylethyl sulfide Methyl sulfide (Dimethyl sulfide) Methyl sulfoxide (Dimethyl sulfoxide) Octadecanoic acid, 2-(1-carboxyethoxy)-1-methy1-2oxoethyl ester, sodium salt Organo-aluminum compounds: Aluminum di-sec-butoxide acetoacetic ester chelate Aluminum diisobutoxy ethyl acetoacetate r Aluminum diisopropoxide acetoacetic ester chelate Aluminum (1,3-butanedialato(2)-0,01(ethy1-3oxobutanoato-01 ,03-hydroxy T-4 Aluminum isooctoxide, diisopropoxide Aluminum isopropoxide (Aluminum isopropylate)

No No

GAF. DIX.

No

CPS.

No No No No No No No No No No No No Yes No No No No No Yes No No No No No Yes No No No No No No No No No No No No No

CPS, (2). CPS. gisiJ, SHC. HCL. GAF, UCC. SCP. ATR. NOD. SQA. GAF, PAS, UCC. DVC. DOM. CAS. CAS. FER. CHL, WIC. BRD, CHL, WTC. BRD. CHL. BRD, WIC. ARC, AUS, CAS, C..10, SCP, SM. FMT. HMY, PLC. PLC. HMY, PLC. HMY. SCM, (2). HMY. HMY, PLC. HMY. DUP. MRT, RDA. PAS. PLC. GAY.

No Yes

WTC.

No No

CHT. KCH.

No

CHT, KCH.

No No

CHT. KCH.

No

CHT, KCH.

See footnotes at end of table.

15-35

Section 15 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics1

Manufacturers' Identification codes (according to list in table 151)

No No No No No No No No No No No No No No No No

CHT. TNA, TSA. TNA, TSA. TNA. TNA, TSA. TSA. TSA. TNA, TSA. TNA, TSA. TSA. TNA. TSA. KCH. CHT, KCH. CHT, KCH. SQA.

No No No No No No No No No Yes No No No No No No

HXL. TNA, TSA. TNA, TSA. TNA, TSA. TNA, TSA. TNA, TSA. TNA, TSA. CHT. CHT, KCH, TNA, TSA.

Miscellaneous chemicals, acyclic-Continued Other miscellaneous acyclic chemicals-Continued Organo-aluminum compounds-Continued Aluminum tri-sec-butoxide Diethylaluminum chloride Diethylaluminum iodide Diisobutylaluminum chloride Diisobutylaluminum hydride Diisobutylaluminum oxide Di-n-propylaluminum chloride Ethylaluminum dichloride Ethylaluminum sesquichloride Isobutylaluminum Isobutylaluminum chloride lsopropenylaluminum Oxoaluminum isopropoxide Oxoaluminum stearate Oxyaluminum octanoate Polyol aluminum chelate Sodium dihydro-bis(2-methoxyethoxy) aluminate Tri-n-butylaluminum Triethylaluminum Tri-n-hexyl aluminum Triisobutylaluminum Trimethylaluminum Tri-n-octylaluminum Tri-oxyaluminum tri-isopropoxide All other organo-aluminum compounds Organo-boron compounds: Diethanolamine-borate N-Methyl-methanamine with borane (1:1) 2-Methyl-2-propanamine with borane(1:1) Mixed alcohol borates Trimethoxyboroxine Trimethyl borate N,N,N-Trimethyl methanaminium octahydrotriborate All other organo-boron compounds Organo-lithium compounds: n-Butyllithium sec-Butyllithium Lithium hydroxystearate Organo-magnesium compounds: Butyl ethyl magnesium Di-n-butylmagnesium Di-n-hexyl magnesium Magnesium methylate Organo-nickel compounds Organo-silicon compounds: N-Aminoethylaminopropyl trimethoxysilane Chloromethyldimethylchlorosilane a-Chloropropyttrichlorosilane Chloropropyltrimethoxysilane Chlorotrimethylsilane Dichlorodimethylsilane Dichloromethylsilane Dichloromethylvinylsilane Diisobutyl dimethoxychloro Wane Divinyltetramethyldisilizane

See footnotes at end of table.

EFH.

MHI.

No No

FER, HCL, TSA,

No No No

FTE. FTE. WTC.

No No No No No No No No No No No No No No No No

TSA. TSA. TSA. SOI. FER. DCC, NOD. PCR. DCC, NOD. DCC, UCC. DCC. DCC. DCC. DCC, PCR, (2). NOD. PCR.

Synthetic Organic Chemicals, 1991 Table 15-2--Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistic&

Manufacturers' identification codes (according to list in table 15-3)

Miscellaneous chemicals, acyclic-Continued Other miscellaneous acyclic chemicals-Continued Organo-silicon compounds-Continued Divinyl tetramethyldisiloxane a-Glycidoxypropyftrimethoxysilane Hexamethyldisilazane Hexamethyldisiloxane Hexyltrichlorosilane lsobutyltrimethoxysilane Mercaptopropyttrimethoxysilane a-Methacryloxypropyltrimethoxysilane Methyttrimethoxysilane and polymethyltrisiloxane N-Octyltriethoxy silane Polyoxyalkene silicones Silicone fluids Silicone resins for mold release agents Tetramethyldisiloxane Trichloromethylsilane Trichloropropylsilane Trichlorovinylsilane Tris(2-methoxyethoxy)vinyl silane Tris(pentamethyldisiloxany1)-3methacrylatopropylsilane Vinylmethyldichlorosilane Vinyttriethoxysilane Vinyl trimethoxy silane All other organo-silicon compounds

No No No No No No No No

NOD, (2). NOD, UCC. DCC, NOD, PCR. PCR. PCR. DCC, NOD. NOD, UCC. UCC.

No No No Yes No No No No No No

DCC, UCC. PCR. UCC. DCC, SPD, SWS, UCC. ALW. PCR, (2). DCC. DCC. UCC. NOD.

No No No No No

Organo-tin compounds: Yes Dbutyltin bis(butylmaleate) No Dibutyltin bistooctylmercaptoacetate) No Dibutyltin bis mercaptolaurate) No Dibutyltin ca xylates No Dbutyttin dichloride No Dibutyltin oxide No Dimethyltin dichloride No Dimethyltin-IOTG No Ester tin mercaptoesters No Monomethyl tin No Organotin mercaptides No All other organo-tin compounds No Organo-zinc compounds: Diethylzinc No All other organo-zinc compounds No Perfluoroalkyl polyether No Phosgene (Carbonyl chloride) Yes No Polyalphaolefins No Polyepichlorohydrin Polyhexafluoropropylene oxide No Polymethaaylic acid esters No Poly(oxyalkylene glycol)—polymer with polymethylene-potyphenytene isocyanate-urethane prepolymer No Potassium 2-methyl-2-butanol No Potassium 2-methyl-2-propand No Sodium methoxide (Sodium methylate) No No Trifluoroethanol Zircoaluminate compounds No

PCR, (2), NOD, UCC. NOD. DCC, NOD, PCR, PCR, SCP, UCC, (2), (2), (2). (2),

CCA, WTC. PAS, WTC. PAS. FER. PAS, WTC. PAS. WTC. WTC. CCA. WTC. CCA, CCW, PAS. PCR, (2). TSA. TSA. DUP. DUP, ICI, OMC, PPG, VDM. TNA. P. DUP, WTL GLC. H , OMC. HOC. KCH.

See footnotes at end of table. 15-37

Section 15 Table 15-2—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1991

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 15-3)

Miscellaneous chemicals, acyclic-Continued Other miscellaneous acyclic chemicals-Continued

All other miscellaneous acylic chemicals

Mixtures not specifically itemized: Alcohols, monohydric, and their esters, C8 and higher Butyl formcel Celtone Fatty acid residues Gluconic acid and salts, mixed Glycol residues Methyl formcel Oxo process bottoms Propionic blends Rosin/fatty acid mixtures Rosin/fatty acid/pitch mixtures Terpene residues All other mixtures not specifically itemized

No

AIP, ANG, BDS, BRD, DPW, EK, EKT, MCK, MRF, PAH, PAS, PIC, RSA, SCP TCC, TNA, TSA, TUL, USR, ( 2),

Yes

No No Yes No No No No No No No No No No

EKX. HCL. HCL. ARZ, BRD, DRL, SHX, SYP, WTC. PMP. OMC. HCL, NOD. CXI. HCL. ARZ. ARZ. ARZ. ARC, CNE, HCL, LYP, MON, PLC, SCP.

1 Chemicals for which separate statistics are reported in this section are indicated by 'yes.' Chemicals for which data are accepted in confidence and may not be published are indicated by 'no.' 2 The manufacturer did not consent to be identified with the designated products. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

15-38

Synthetic Organic Chemicals, 1991 Table 15-3 Miscellaneous cyclic and acyclic chemicals: Directory of manufacturers, alphabetical by code, 1991

Code

Name of company

Code

Name of company

ABB ABB ACS

Abbott Laboratories Abbott Laboratories Allied Signal Inc., Engineered Material Sector American Cyanamid Co Anderson Development Co. Archer Daniels Midland Co. Air Products & Chemicals, Inc. Akzo Chemicals, Inc. Anzon, Inc. Albright & Wilson, Americas, Inc. American Bio-Synthetics Corp. Amoco Corp. Amvac Chemical Corp. Angus Chemical Co. Aqualon Co. Akzo Chemicals, Inc. Arsynco, Inc., Sub. Div of Aceto Corp. Aristech Chemical Corp. Arizona Chemica Co. Ashland Chemical, Inc. Specialtychem Products Corp. Atlantic Industries, Inc. Arco Chemical Co. Ausimont N.V. Aztec Catalyst Co. BASF Corp. Buffalo Color Corp. Borden Chemical & Plastics Delaware Limited Fragrance Resources, Inc. B.F. Goodrich Co. American Ingredients Company J. T. Baker Chemical Co. Buckman Laboratories, Inc. Biocraft Laboratories, Inc. Borden, Inc., Packaging & Indus. Prod. Div. Lonza, Inc. Burlington Industries Bristol-Myers Squibb Co. BTL Specialty Resin Corp. Synalloy Corp., Blackman Uhler Chemical Div. Akzo Chemicals, Inc Caschem, Inc. Neste Resins Corp. Akzo Chemicals, Inc.

CCC CCW

C.N.C. International, L.P. Morton International, Inc., Speciality Chemicals Group Ciba-Geigy Corp. Chemdesign Corp. Mobay Chemical Corp., Agricultural Chemicals Div. Chemol, Inc. Ducon C. H. Patridk & Co., Inc. Chattem, Inc. C. J. Osbom Chemical, Inc. Oxy Petrochemicals, Inc. DSM Chemicals, North America, Inc. CPS Chemical Co., Inc. Upjohn Co., Fine Chemicals Chemical Exchange Industries, Inc. GYRO Industries Hickson Danchem Corp. Diaz Chemical Corp. Dow Corning Corp. Degussa Corp. Dixie Chemical Co., Inc. Miles, Inc. Dominion Products, Inc. Dow Chemical Co. Deepwater Iodides, Inc. Unicheina North America E. I. duPont de Nemours & Co., Inc. Chemicals & Pigments Dept. Petrochemicals Dept. Polymer Products Dept. Dover Chemical Corp. Sub. of ICC Industries, Inc. Diversified Technology, Inc. E. F. Houghton & Co. Ethichem Corp. Eastman Kodak Co.: Tennessee Eastman Co. Div. Texas Eastman Co. Div. Elco Corp. Sub. of Detrex Inc. Exxon Chemical Americas W. R. Grace & Co., Organic Chemicals Div. Evans Chemetics Ferro Corp.: Bedford Chemical Div. Grant Chemical Div. Keil Chemical Div.

ACY ADC ADM AIP AKZ ALI ALW AMB AMO AMV ANG AQU ARC ARS ART ARZ ASH ASL ATL ATR AUS AZT BAS BCC BCP BDS BFG BFP BKC BKM BOC BOR BRD BRI BRS BTL BUC CAD CAS CBD CCA

CGY CHD CHG CHL CHO CHP CHT CJO CNE CNP CPS CWN CXI CYR DAN DAZ DCC DGC DIX DKA DOM . DOW DPW DRL DUP .

DVC DVR EFH EHC EK EKT EKX ELC ENJ EVN

FER

See footnotes at end of table. 15-39

Section 15 Table 15-3—Continued Miscellaneous cyclic and acyclic chemicals: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

FMN

FMC Corp. Agricultural Chemical Group Fairmount Chemical Co., Inc. Handschy Industries, Inc., Ink and Chemical Div. Formosa Plastics Corporation Louisiana Vulcan Materials Co., Chemicals Div. Cyprus Foote Mineral Company Finetex, Inc. ISP Chemicals, Inc., Div. of GAF Chemicals Gaylord Chemical Corp. General Electric Co., Specialty Chemical Group GFS Chemical, Inc. Georgia-Gulf Corp.: Houston Div. Plaquemine Div. Givaudan Corp. General Latex & Chemical Corp. Georgia-Pacific Corp., Resins Operations Grindsted Products, Inc. Great Lakes Chemical Corp. C. P. Hall Co. Haarman Reimer Corp., Food Ingredients Div. Hatco Corp. Hoechst Celanese Corp: Chemical Group Inc. Fibers Industrial Division Sou-Tex Works Honig Chemical & Processing Corp. Syntex Agribusiness, Inc. Occidential Chemical Corp., ED & S Div. Hummel Crofton, Inc. W. R. Grace & Co., Hampshire Chemicals Div. & Organic Chemicals Div. Humphrey Chemical Co. Halocarbon Products Corp. Hercules, Inc. Hexcel Corp., Hexcel Chemical Products ICI Americas, Inc.. Agricultural Chemical Div. Rubicon, Inc. Specialty Chemical Div. Pitman-Moore Jarchem Industries, Inc. Rhone-Poulenc Chemicals

KLM KMI LCP

Kalama Chemical, Inc. Kemin Industries, Inc. LCP Chemicals, Hanlin Group, Inc., West Virginia, Inc. Laroche Chemicals, Inc. Lyondell Petrochemical Co. Mallinckrodt, Inc. Mooney Chemicals, Inc. MacKenzie Chemical Works, Inc. Morton International, Inc. Milliken & Co., Milliken Chemical Div. Monsanto Co., Agricultural Group Monsanto Co. Morlex, Inc. Morton International, Inc., Specialtys Chemical Niacet Corp. Union Camp Corp., BBA Div. Ruetgers-Nease Chemical Co. Norac Co., Inc. Mathe Div. Huls America, Inc. Anaquest Olin Corp. Roehr Chemicals, Inc., Div. of Aceto Corp. Parish Chemical Co. ELF Atochem North America, Inc. Piedmont Chemical Industries, Inc. PCR, Inc. Pfister Chemical, Inc. Parke-Davis, Div. of Wamer-Lambert Co. P.D. Glycol Pelron Corp. Penick Corp. Pfanstiehl Laboratories, Inc. Pfizer, Inc. Procter & Gamble Co., Procter & Gamble Mfg. Co. Pierce Chemical Co. Phillips 66 Co. Plastics Engineering Co. PMP Fermentation Products, Inc. PPG Industries, Inc. PMC, Inc., PMC Specialities Group, Inc. Perstorp Polyols, Inc. Quaker Chemical Corp. QO Chemicals, Inc. Reichhold Chemicals, Corp.

FMT FOC FOR FRO FTE FTX GAF GAY GE GFS GGC

GIV GLC GP GPI GTL HAL HAR HCC HCL

HCP HFT HK HML HMP

HMY HOC HPC HXL ICI

IMC JRC KCH

See footnotes at end of table. 15-40

LRO LYP MAL MCI MCK MHI MIL MNA MON MRF MRT NCC NCI NES NOC NOD OH OMC ORT PAH PAS PCI PCR PCW PD PDG PEL PEN PFN PFZ PG

PIC PLC PLS PMP PPG PSG PST QCP QKO RCI

Synthetic Organic Chemicals, 1991 Table 15-3—Continued Miscellaneous cyclic and acyclic chemicals: Directory of manufacturers, alphabetical by code, 1991 Code

Name of company

Code

Name of company

RDA REG RH RQT RSA

Rhone-Poulenc, Inc. Regis Chemical Co Rohm & Haas Co Roquette Corporation R.S.A. Corp . Sandoz Chemical Corp. Scher Chemicals, Inc. Sterling Chemicals, Inc. SCM Corp. Gildco Organics Schenectady Chemicals, Inc. Henkel Corp. Sterling Drug, Inc. Sandoz Chemicals Corp. Sterling Drug, Inc. Sterling Organics Div. Shell Oil Co., Shell Chemical Co. Shepherd Chemical Co Sherex Chemical Co., Inc. Smithldine Beecham Chemicals Mobil Oil Corp. Chemical Products Div. BP Chemicals, Inc. Speciality Organics, Inc General Electric Co. Silicone Products Div. Sequa Chemicals, Inc. Sun Co., Inc. Wacker Silicones Synthetic Products Co. Synthron, Inc. Sybron Chemicals, Inc. Twin Lake Chemical, Inc.

TNA TNI TOC TRO TSA TUL TX TZC UCC

Ethyl Corp. Gillette Chemical Co. Tenneco Methanol Co. Troy Chemical Corp. Akzo Chemicals, Inc. Tull Chemical Co., Inc. Texaco Chemical Co. Magnesium Elektron, Inc. Union Carbide Corp., Industrial Chemicals Div. UOP, Inc. U. S. Borax & Chemical Corp. Quantum Chemical Corp., USI Div. Uniroyal Chemical Co., Inc. Unitex Chemical Corp. Vanchem, Inc. Van De Mark Chemical Co., Inc. Velsicol Chemical Corp. Vanderbilt Chemical Corp. ISP-Van Dyk, Inc. Vista Chemical Co. Wright Chemical Corp. Westlake Corp. Inolex Chemical Co. West Point-Pepperell, Inc., Grifftex Chemical Co. Sub. Witco Corp. Union Can Corp., Chemical Division ELF Atochem North America, Inc., Organic Peroxides Div. Westvaco Corp. Wyckoff Chemical Co., Inc.

S SBC SC SCM SCN SCP SD SDC SDW SHC SHP SHX SK SM SOH SO1 SPD SQA SUN SWS SYP SYT TCC TLC

UPM USB USI USR UTC VCM VDM VEL VNC VND VST WCL WLK WM WPG WIC WTH WTL WVA WYK

Note.—Complete names, telephone number, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

15-41

APPENDIX A DIRECTORY OF MANUFACTURERS

Appendix A

Table A-1 Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1991 are listed below alphabetically, together with their identification codes as used in the 15 individelal sections of this report)

Identification code

Name of company

Telephone number

ABB

Abbott Laboratories

708-937-8343

ILI

Acme Steel Co

708-849-2500

ACO AES

Adco Chemical Co Advanced Elastomer Systems, LP.

201-589-0880 314-453-5300

CCS

Advanced Resins, Inc

303-245-8148

AIP

Air Products & Chemicals, Inc

215-4.81-4911

MY

Ajay Chemicals, Inc

404-943-6202

AKZ ARC CCA CAD TSA FRP REL AKZ lOy ALW ALC ALD

Ajinomoto USA, Inc Akzo Chemicals, Inc. Akzo Chemicals, Inc. Akzo Chemicals, Inc. Akzo Chemicals, Inc Akzo Chemicals, Inc Akzo Coatings, Inc Akzo Coatings, Inc Akzo Coatings, Inc Akzo/Resins & Vehicles Albright & Wilson, Americas, Inc Alco Chemical Aldrich Chemical Co., Inc

201-488-1212 312-906-7500 312-906-7500 312-906-7500 312-906-7500 713-479-8411 912-367-3616 502-459-9110 502-459-9110 708-481-8900 804-550-4300 615-629-1405 414-273-3850

Allco Chemical Corp Allegheny Chemical Corp Alliance Chemical, Inc Allied Signal Inc: Engineered Materials Sector Engineered Plastic Div

214-733-6841 814-772-3965 201-945-5400

Friction Materials Div Alcor Corp Alpha Laboratories, Inc Alpha Resins Corp Amerada Hess Corp. (Hess Oil Virgin Island Corp.) American Bio-Synthetics Corp American Cyanamid Co American Ingredients, Co American Polymers, Inc American Synthetic Rubber Corp

518-270-0200 716-282-1295 303-756-1338 901-853-2450 201-750-6000

Ameripol Synpol Co., Div. of Uniroyal Goodrich Tire Co Ametek Inc., Haveg Div Uniroyal Goodrich lire Co

216-762-4442

ACH ALG ALL ACS

BME ALX ALP APH HES AMB ACY BFP API ASY SPO HVG

A-2

201-455-4911 201-455-2000

414-384-7017 201-831-2768 816-561-9050 508-756-1010 502-449-8300

302-995-0400

Office address

1401 Sheridan Rd., N. Chicago, IL 60064-4000. 13500 S. Perry Ave., Riverdale, IL 60627. 49 Rutherford St., Newark, NJ 07105. 540 Maryville Centre Dr., St Louis, MO 63141. 569 24 1/4 Rd., Grand Junction, CO. 81505. 7201 Hamilton Blvd, Allentown, PA 18195-1501 1400 Industry Rd., Powder Springs, GA 30073. 4020 Ajinomoto Dr., Raleigh, NC 27610. P.O. Box 100, Axis, AL 36505. 300 S. Riverside Plaza, Chicago, IL 60606. 500 Jersey Ave, New Brunswick, NJ 08903. 2153 Lockport-Olcott Rd., Burt, NY 14028. P.O. Box 600, Deer Park, TX 77536. P.O. Box 349, Baxley, GA 31513. 4730 Crittenden Dr., Louisville, KY 40209. 1313 Windsor Ave., Columbus, OH 43211. 21625 Oak St., Matteson, IL 60443. 100 Lakeridge Pkwy., Ashland, VA 23005. 909 Mueller Dr., Chattanooga, TN 37406. 1001 W. St. Paul Ave., Milwaukee, WI 53233. 17304 N. Preston Dr., Suite 800, TX 75252. Gillis Ave., Ridgway, PA 15853. Linden Ave., Ridgefield, NJ 07657. P.O. Box 1087, Morristown, NJ 07962. Columbia Rd. & Park Ave., Morristown, NY 07960. P.O. Box 238, Troy, NY 12180. 3943 Buffalo Ave., Niagara Falls, NY14303. 1685 S. Fairfax St., Denver, CO 80222. P.O. Box 670, Collierville, TN 38017. 1 Hess Plaza, Woodbridge, NJ 07095-0961. 710 W. National Ave., Milwaukee, WI 53204. One Cyanamid Plaza, Wayne, NJ 07470. 3947 Broadway, Kansas City, MO 64111. P.O. Box 366, Oxford, MA 01540. 4500 Campground Rd., Louisville, KY 40216. 146 South High St. Akron, OH 44308-1493. 900 Greenbank Rd., Wilmington, DE 19808.

Synthetic Organic Chemicals, 1991 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

AMO

Amoco Corp

312-856-6111

AMV

Amvac Chemical Corp

213-264-3910

OH ADC ANG ALI

Anaquest Anderson Development Co Angus Chemical Co Anzon, Inc., Lead Div

608-273-0019 517-263-2121 708-498-6700 215-531-6010

APX APC APO

Apex Chemical Co Apollo Chemical Corp Apollo Colors, Inc

908-354-5420 919-226-1161 708-564-9190

AQU

Aqualon Co

302-996-2000

HKY

Arcadian Corp

901-351-6500

ARD ARN ART ARZ

Ardmore, Inc Arend Chemical Corp Aristech Chemical Corp Arizona Chemical Co

201-481-2406 201-526-5900 412-433-2747 904-785-6700

ALS ARP ARO

Armco, Steel Co Armour Pharmaceutical Co ARNCO

513-425-5000 815-932-6771 213-567-0587

ARL ARS

Arol Chemical Products Co Arsynco, Inc., Sub Div. of Aceto Corp

201-344-1510 516-627-6000

ASH

Ashland Chemical Inc Ashland Petroleum Co Astor Products, Inc., Blue Arrow Div

614-889-3333 606-329-3333 904-783-5352

Atlantic Richfield Co., Arco Chemical Co. Atlas Refinery, Inc Auralux Corp Ausimont N.V Aztec Catalyst Co.

215-359-2000

BLA ATR ARI AUX AUS AZT

201-589-2002 203-886-2616 201-292-6250 713-682-5300

TEN SOH

BASF Corp. Chemicals Div BIT Manufacturing, Inc BP Chemicals, Inc

201-316-2937 615-496-3331 216-586-4141

SIF

Commerical Composites

606-282-2623

SIC

Commerical Composites

213-757-1801

BAS

Office address

200 E. Randolph Dr., Chicago, IL 60680-0703. 4100 E. Washington Blvd., Los Angeles, CA 90023. 2005 W. Beltline Hwy., Madison, WI 53713. 1415 E. Michigan St., Adrian, MI 49221. 2211 Sanders Rd., Northbrook, IL 60085. 2545 Aramingo Ave., Philadelphia, PA 19125. 200 S. First St., Elizabeth, NJ 07206. 1105 Southeriand St., Graham, NC 27253. 3000 W. Dundee Rd., Suite 415, Northbrook, IL 60062. 2711 Centerville Rd., Wilmington, DE 19850-5417. 6750 Poplar Ave., Suite 600, Memphis, TN 38138-7419. 29 Riverside Ave., Newark, NJ 07104. 189 Meister Ave., Somerville, NJ 08876. 600 Grant St., Pittsburgh, PA 15230-0250. 1001 E. Business Hwy. 98, Panama City, FL 32401. 703 Curtis St., Middletown, OH 45044. P.O. Box 511, Kankakee, IL 60901. 5141 Firestone Place, Southgate, CA 90280. 649 Ferry St., Newark, NJ 07105. One Hollow Lane, Lake Success, NY 11042-1215. P.O. Box 2219, Columbus, OH 43216. P.O. Box 391, Ashland, KY 41114. 5244 Edgewood Ct., Jacksonville, FL 32205. 3801 West Chester Pike, Newtown Square, PA 19073. 142 Lockwood St., Newark, NJ 07105. P.O. Box 113, Yantic, CT 06389. 44 Whippany Rd., Morristown, NJ 07962. 2190 N. Loop West, Suite 400 Houston, TX 77018. 1255 Broad St., Clifton, NJ 07015. 1 Ocoee St., Copperhill, TN 37317. 200 Public Square 31-N-4105, Cleveland, OH 44114 - 2375. 7310 Turfway Rd., Suite 300, Florence, KY 41042. 12333 South Van Ness Ave., Hawthorne, CA 90250.

Appendix A

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 identification code

Name of company

Telephone number

SIO BTL BKC

BP Oil Co BTL Speciality Resin Corp J. T. Baker Chemical Co

419-226-2300 419-244-5856 908-859-2151

BFC BIB BCK

Barker Fine Color, Inc. Beckman Instruments, Inc Diagnostic Systems Group

606-261-0200 415-859-1510 619-438-9151

BCM BLZ BLY BTS BOC NUT BOE BOT

Belding Heminway Co Belzak Corp Berkley & Co., Inc. Bethlehem Steel Corp Biocraft Laboratories, Inc Bioproducts, Inc Boehme Filatex, Inc Boots Pharmaceuticals, Inc.

212-944-6040 201-773-0602 712-336-1520 215-694-4522 201-703-0400 502-962-0700 919-342-6631 708-405-7400

BOR

BMC

Borden, Inc.: Packaging & Industrial Products Div. Borden Chemical & Plastics Delaware Limited Partnership Brin-Mont Chemicals, Inc

BRS BRU BKM BCC BRI

Bristol-Myers Squibb Co M. A. Bruder & Sons, Inc Buckman Laboratories, Inc Buffalo Color Corp Burlington Industries, Inc.

212-546-4000 215-353-5100 901-278-0330 716-827-4500 919-379-2000

BUR

Burroughs Wellcome Co

919-248-3000

CDR

CDR Pigments & Dispersions

513-771-1900

CFI CLU CCC PS CPS

CF Industries, Inc CL Industries, Inc C.N.C. International, Inc CPS Corp CPS Chemical Co., Inc

708-438-9500 217-662-2136 401-769-6100 716-366-6010 908-727-3100

CYR GRL

CYRO Industries Calgon Corp., Calgon Vestal Laboratories Div. Cambridge Industries Co Cape Industries Carbose Corp Cargill, Inc Carpenter Chemical Co

201-770-3000 314-535-1390

BCP

CMB HCF CBC CGL CHC

A-4

Office address

1150 South Metcalf St., Lima, OH 45804. 2112 Sylvon Ave., Toledo, OH 43606. 222 Red School Lane, Phillipsburg, NJ 08865. 38 Elm St., Lodlov, KY 41016. 1050 Page Mill Rd., Palo Alto, CA 94304. 2470 Faraday Ave., Carlsbad, CA 92008. NJ 07424. P.O. Box 130, Hendersonville, NC 28793. 850 Bloomfield Ave., Clifton, NJ 07012. One Berkley Dr., Spirit Lake, IA 51360. 1170 8th Avenue, Bethlehem, PA 18016. 12 Industrial Park, Waldwick NJ 07463. 4820 Jennings Lane, Louisville, KY 40218. Rt. 11 Box 5, Reidsville, NC 27320. Ctr., Suite 200, 300 Tristate Lincolnshire, IL 60069-4422

614-225-4400

180 E. Broad St., Columbus. OH 43215.

504-673-6121

Box 427, Geismar, LA 70734.

919-292-0566

3921 Spring Garden St, Greensboro, NC 27407. 345 Park Ave., New York, NY 10154. 52nd & Grays Ave., Philadelphia, PA 19143. 1256 N. McLean Blvd., Memphis, TN 38108. P.O. Box 7027., Buffalo, NY 14240. 3330 W. Friendly Ave., Greensboro, NC 27406. 3030 Comwallis Rd., Research Triangle Park, NC 27709. 410 Glendale Milford Rd., Cincinnati, OH 45215. One Salem Lake Dr., Long Grove, IL 60047. P.O. Box 218, Georgetown, IL 61846. 20 Priviledge St., Woonsocket, RI 02895. 3257 Middle Rd d Dunkirk, NY 14048. Old Water Wofka, Rd., Old Bridge, NJ 08857. 100 Valley Rd., MT. Arlington, NJ 07856. 5035 Manchester Ave., St. Louis, MO 63110. 7-33 Amsterdam St, Newark, NJ 07103. P.O. Box 327, Wilmington, NC 28402. 100 Maple St., Somerset, PA 15501. P.O. Box 5630, Minneapolis, MN 55428. 5016 Monument Ave., Richmond, VA 23230.

201-465-4565 919-341-5500 814-443-1611 612-475-7634 804-359-0800

Synthetic Organic Chemicals, 1991 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

BSC CAS CCL

Cascade Resins, Inc Caschem, Inc Catawba-Charlab, Inc

503-343-2111 201-858-7900 704-523-4242

CED

Cedar Chemical Corp

501-572-3701

CNT CPR CHT CHD CFX CXI

Certainteed Corp Certified Processing Corp Chattem, Inc Chemdesign Corp Chemfax, Inc Chemical Exchange Industries, Inc

215-341-7000 201-923-5200 615-821-4571 508-345-9999 601-863-6511 713-526-8291

CMT

Chemithon Corp

206-937-9954

CHL

Chemol Co

919-333-3050

SOC

Chevron Corp., Chevron Chemical

415-842-5500

CGY CGO GSR

Ciba-Geigy Corp Citgo Petroleum Corp Citgo Refining & Chemicals, Inc

914-478-8131 918-495-4000 512-882-8871

CGU

Citizens Gas & Coke Utility

317-264-8802

CLK

Clark Oil & Refining Corp

314-854-9696

ACT WYC CSP CP CIC

Climax Performance Materials Corp Coastal Chem, Inc Coastal Refining & Marketing Inc Colgate-Palmolive Co Color Chem International Corp

708-458-8450 307-637-2700 713-877-1400 212-310-2000 404-396-1230

CAC

Cominco Fertilizers, Inc

509-747-6111

CNI CON CO CKC

Conap, Inc Concord Chemical Co., Inc Conoco, Inc Cook Composites and Polymers Co

716-372-9650 609-966-1526 713-293-1000 816-391-6000

CPV HEU COP CPY CMS CRD CK CCP USM

Cook Paint & Varnish Co Cookson Pigments, Inc Coopers Creek Chemical Corp Copolymer Rubber & Chemical Corp Cosmic Plastics, Inc Croda, Inc Crompton & Knowles Corp Crown Central Petroleum Corp Crown Metro, Inc

816-391-6000 201-242-1800 215-828-0375 504-355-5655 818-365-3249 201-644-4900 215-775-8000 410-539-7400 803-299-1331

Office address

11

P.O. Box 1989, Eugene, OR 97401. 40 Avenue A, Bayonne, NJ 07002. 5046 Old Pineville Rd., Charlotte, NC 28217. Highway 242 South, West Helena, AR 72390. P.O. Box 860, Valley Forge, PA 19482. U.S. Highway #22, Hillside, NJ 07205. 1715 W. 38th St., Chattanooga, TN 37409. 99 Development Rd., Fitchburg, MA 01420. 10045 Three River Rd., Gulfport, MS 39502. 3813 Buffalo Speedway, Houston, TX 77098. 5430 W. Marginal Way, SW., Seattle, WA 98106. 2410 Randolph Ave., Greensboro, NC 27406. 6001 Bollinger Canyon Rd., San Ramon, CA 94583. 444 Saw Mill River Rd., Ardsley, NY 10502. P.O. Box 1562, Lake Charles, LA 70602. 1801 Nuceces Bay Blvd., Corpus Christi, TX 78469. 3133 Southeastern Ave., Indianapolis, IN 46203. 8182 Maryland Avenue, St. Louis, MO 63105. 7666 W. 63rd St., Summit, IL 60501. P.O. Box 1287, Cheyenne, WY 82003. Nine Greenway Plaza, Houston, TX 77046. 300 Park Ave., New York, NY 10022. 5145 Meadow Creek Dr., Atlanta, GA 30338. W. 601 Riverside Ave., Spokane, WA 99201. 1405 Buffalo St., Olean, NY 14760. 17th & Federal Sts., Camden, NJ 08105. P.O Box 2197, Houston, TX 77252. 919 East 14th Ave., N. Kansas City, MO, 64141-6389. P.O. Box 419389, Kansas City, MO 64141. 256 Vanderpool St., Newark, NJ 07114. River Rd., West Conshohocken, PA 19428. P.O. Box 2591, Baton Rouge, LA 70821. 27939 Beale Court, Valencia, CA 91355. 7 Century Dr., Parsippany, NJ 07054. P.O. Box 341, Reading, PA 19603. 1 N. Charles St., Baltimore, MD 21203. Echelon Road, Donaldson Centre, Greenville, SC 29606. .

.

Appendix A

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

Office address

502-826-7641

P.O. Box 933, Henderson, KY 42420.

AMD FTE

Customs Resins Div. of Bemis Co., Inc. Cyclo Products, Inc Cyprus Foote Mineral Co

213-582-6411 215-889-9605

CNP

DSM Chemicals North America, Inc

404-849-6000

POP DPI

201-777-0200 717-656-2236

DGO DPW DGC

Daicolor Pope, Inc Dart Polymers, Inc., Sub. of Dart Container Corp. Day-Glo Color Corp Deepwater, Inc Degussa Corp

1922 E. 64th St., Los Angeles, CA 90001. 301 Lindenwood Dr., Suite 301, Malvern, PA 19355. 1 Columbia Nitrogen Rd., Augusta, GA 30903. 33 Sixth Ave., Paterson, NJ 07524. 60 E. Main St., Leola, PA 17540.

DRR

Delta Resins & Refractories, Inc

414-462-1200

DNS

Dennis Chemical Co Dexter Corp: Aerospace Material Div

314-771-1800

603-474-5541 203-627-9051 212-542-7700 708-623-4200 602-248-2800 512-641-6800

DOW

Automotive Div Dexter Electronic Material Div Dexter Chemical Corp Dexter Speciality Coatings Dial Corp Diamond Shamrock Refining & Marketing. Diaz Chemical Corp Diversified Technology, Inc. Dixie Chemical Co., Inc Dock Resins Corp Dominion Products, Inc Dover Chemical Corp. Sub. of ICC Industries, Inc. Dow Chemical Co

DCC DRX ABP WBG CHO

Dow Coming Corp Drexel Chemical Corp Drummond Co., Inc Dryden Oil Co Ducoa

517-496-4000 901-774-4370 205-945-6301 508-791-3201 618-654-2070

DUP DSC DYG AGI

E. I. duPont de Nemours & Co., Inc Dye Specialties, Inc Dynagen, Inc., Sub. of General Tire EMS-American Grilon, Inc

302-774-1000 201-866-9504 915-335-7511 803-481-9173

EPC EPI

EPC Partners, Ltd Eagle Pitcher Industries Inc., Orthane Div.

713-880-6500 817-387-0585

CTR

HYA DXA HYC DEX MID AGP DA DAZ DVR DIX DRC DOM DVC

216-391-7070 714-751-3522 201-641-6100

415-687-4201

716-638-6321 904-673-4136 713-863-1947 908-862-2351 718-499-3050 216-343-7711 517-636-6125

4515 St. Clair Ave., Cleveland, OH 44103. P.O. Box 17599, Irvine, CA 92713. 65 Challenger Rd., Ridgefield Park NJ 07660. 6263 N. Teutonia Ave., Milwaukee, WI 53209. 2700 Pepin St., St. Louis, MO 63103. 2850 Willow Pass Road, Pittsburgh, CA 94565. One Dexter Dr., Seabrook, NH 03874. 211 Franklin St., Olean, NY 14760. 845 Edgewater Rd., Bronx, NY 10474. E. Water St., Waukegan, IL 60085. 2000 Aucutt Rd., Montgomery, AL 60538. P.O. Box 696000, San Antonio, TX 78269-6000. 40 Jackson St., Holley, NY 14470. 1625 State Ave., Holly Hill, FL 32117. 300 Jackson Hill, Houston, TX 77007. 1512 W. Elizabeth Ave., Linden, NJ 07036. 882 - 3rd Ave., Brooklyn, NY 11232. W. 15th & Davis Sts., Dover, OH 44622. 2020 Willard H. Dow Center, Midland, MI 48674. P.O. Box 994, Midland, MI 48686-0994. 2487 Pennsylvania St., Memphis, TN 38109. P.O. Box 10246, Birmingham, AL 35202. 694 Millbury St., Worchester, MA 01607. 115 Executive Dr., Suite 104, Highland, IL 62249. 1007 Market St., Wilmington, DE 19898. 100 Plaza Center, Secaucus, NJ 07096. 2000 East Poole Rd., Odeessa, TX 79766. Industrial Park & Corporate Hwy., Sumter, SC 29151. P.O. Box 4324, Houston, TX 77210. P.O. Box 1389, Denton, TX 76202.

Synthetic Organic Chemicals, 1991 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

ECC EK EKT EKX ESA ELN ELC

Name of company

Telephone number

Office address

401-331-9000 716-724-4000 615-229-2000 903-237-5122 616-726-3106 201-344-8014 216-749-2605

35 Livingston St., Providence, RI 02904. 343 State St., Rochester, NY 14650. P.O. Box 511, Kingsport, TN 37662. P.O. Box 7444, Longview, TX 75607. 1221 E. Barney Ave., Muskegon, MI 49443. 268 Doremus Ave., Newark, NJ 07105. 1000 Beltline Rd., Cleveland OH 44109.

PAS RSN WTL USM EKO

Eastern Color & Chemical Co Eastman Kodak Co Tennessee Eastman Co. Div Texas Eastman Co Div East Shore Chemical Co. Elan Chemical Co Elco Corp. Sub. of Detrex Chemical Industries, Inc. Elf Atochem North America Polymer Div Organic Peroxides Div Emhart Corp., Bostik Div Empire Coke Co

215-587-7000 215-587-7000 716-877-1740 508-777-0100 205-323-2400

ENO

Enenco, Inc

901-684-7000

HSH SAR ESS EHC ETC

Engelhard Corp Esschem, Inc Essential Industries, Inc Ethichem Corp Ethox Chemicals, Inc

201-632-6000 215-521-3800 414-538-1122 201-933-7880 803-277-1620

TNA EVL

Ethyl Corp Eval Company of America

804-788-5537 708-719-4610

ENJ

Exxon Chemical Americas FMC Corp: Agricultural Chemical Group Chemical Products Group Nitro Div Fabricolor Manufacturing Corp Fairmount Chemical Co., Inc Farmland Industries, Inc

713-870-6000

Three Parkway. Philadelphia, PA 19102. 1112 Lincoln Rd., Birdsboro, PA 19508. 1740 Military Rd., Buffalo, NY 14240. Boston St., Middleton, MA 01949. 1927 1st Ave., N., Suite 900, Birmingham, AL 35203. 755 Crossover Lane, Suite 216, Memphis, TN 38117. 3400 Band Street, Louisville, KY 40212. Governor Printz Blvd., Essington, PA 19029. 28391 Essential Rd., Merton, WI 53056. 150 Grand St., Carlstadt, NJ 07072. P.O. Box 5094, Station B, Greenville, SC 29606. 330 S. 4th St., Richmond, VA 23217. 1001 Warrenville Rd., Suite 201, Lisle, IL 60532. P.O. Box 3272, Houston, TX 77253-3272.

FMN FMB FMC FAB FMT FRI

215-299-6000 215-299-6000 215-299-6000 201-742-3900 201-344-5790 816-459-6000 816-238-8111

1735 Market St., Philadelphia, PA 19103. 1735 Market St., Philadelphia, PA 19103. 1735 Market St., Philadelphia, PA 19103. 24-1/2 Van Houten St., Paterson, NJ 07509. 117 Blanchard St., Newark, NJ 07105. P.O. Box 308, Lawrence, KS 66044. 1417 Lower Lake Rd., St. Joseph, MO 64502.

FBI

Ferro Corp.: Bedford Chemical Div Grant Chemical Div Keil Chemical Div Fiber Industries, Inc

216-641-8580 504-654-6801 219-931-2630 704-357-2000

CSD

Fina Oil & Chemical Co

214-750-2400

FTX

Finetex, Inc

201-797-4686

7050 Krick Rd., Walton Hills, OH 44146. P.O. Box 263, Baton Rouge, LA 70821. 3000 Sheffield Ave., Hammond, IN 46320. 5146 Parkway Plaza Blvd., Charlotte, NC 28217. 8350 N. Central Expressway, Dallas, TX 75206. P.O. Box 216, Elmwood Park, NJ 07407.

FRF FRS

Firestone Tire & Rubber Co.: Firestone Fibers & Textile Co Firestone Synthetic Rubber & Latex Co. Div.

216-379-7000 216-379-7495

FER

P.O. Box 450, Hopewell, VA 23860. P.O. Box 26611, Akron, OH 44319-0006.

Appendix A

Table A-1--Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

CI FST FPC FLM FOR BDS FLN WLC COO FLH EEP GFS GLX GAN GAY GNT GNR GE SPD GEP GLC GRG GGC

Name of company

TNI GIV GLD BFG GYR EVN GRD HMP GON

Office address

Firmenich, Inc First Chemical Corp Flambeau Paper Corp Fleming Laboratories, Inc Formosa Plastics Corp-USA Fragrance Resources, Inc Franklin International, Inc Freeport-McMoran Resource Partners. H.B. Fuller Co H.B. Fuller Co Furon Co GFS Chemicals, Inc Galaxie Chemical Corp Ganes Chemicals, Inc Gaylord Chemical Corp Gencorp Polymers Products Latex Unit. Genencor, International Inc General Electric Co.: Electromaterials Div Silicone Products Div

609-452-1000 601-762-0870 715-762-5235 704-372-5613 201-992-2090 908-264-6767 614-443-0241 504-582-4000

P.O. Box 5880, Princeton, NJ 08543. P.O. Box 1427, Pascagoula, MS 39581. 200 N. First Ave., Park Falls, WI 54552. 2215 Thrift Rd., Charlotte, NC 28234. P.O. Box 271, Baton Rouge, LA 70821. 275 Clark St., Keyport, NJ 07735. 2020 Bruck St., Columbus, OH 43207. 1615 Poydras St, New Orleans, LA 70112.

508-694-5421 612-645-3401 714-831-5350 614-881-5501 201-279-0558 201-507-4336 504-649-5464 216-869-4200

820 Woburn St., Wilmington, MA 01887. 4450 Malsbary Rd., Blue Ash, OH 45242. Main & Orchard Sts., Mantua, OH 44255. P.O. Box 245, Columbus, OH 43065. 26 Piercy St., Paterson, NJ 07524. 630 Broad St., Carlstadt, NJ 07072 P.O. Box 1209, Slidell, LA 70459-1209 165 S. Cleveland Ave., Mogadore, OH 44260. 4 Cambridge Place, Rochester, NY 14618.

Speciality Chemicals Group General Latex and Chemical Corp P.D. George Co Georgia Gulf Corp' Houston Div

413-448-6681 617-576-8000 314-621-5700

Plaquemine Div

GP

Telephone number

PVC Compound Div Georgia-Pacific Corp.: Bellingham Div Resins, Inc Gillette Chemical Co Givaudan Corp Glidden Company B. F. Goodrich Co Goodyear Tire & Rubber Co W. R. Grace & Co.: Organic Chemicals Div., Evans Chemetics. Organic Chemicals Div., Chemicals & Polymers Div. Organic Chemicals Div., Hampshire Chemicals Div. Organic Chemicals Div., Nitroparafins.

716-256-5200 614-622-5310 518-233-3377

713-920-4306

1350 S. Second St., Coshocton, OH 43812. 260 Hudson River Rd., Waterford, NY 12188. One Plastic Ave., Pittsfield, MA 01201. P.O. Box 498, Ashland, OH 44805. 5200 N. Second St., St. Louis, MO 63147.

404-395-4500

3503 Pasadena Freeway, Pasadena, TX 77503. 400 Perimeter Center Terrace, Suite 595, Atlanta, GA 30348. P.O. Box 629, Plaquemine, LA 70765-0624.

206-733-4410 404-521-4000 617-421-7000 201-365-8000 216-344-8000 216-447-7802 216-796-2121

P.O. Box 1236, Bellingham, WA 98227. 133 Peachtree St. NE., Atlanta, GA 30303. 3500 W. 16th St., N. Chicago, IL 60064. 100 Delawanna Ave., Clifton, NJ 07014. 925 Euclid Ave., Cleveland OH 44115. 6100 Oak Tree Blvd., Cleveland, OH 44131. 1144 E. Market St., Akron, OH 44316.

617-861-6600

55 Hayden Ave., Lexington, MA 02173.

617-861-6600

55 Hayden Ave., Lexington, MA 02173.

617-861-6600

55 Hayden Ave., Lexington, MA 02173.

617-861-6600

55 Hayden Ave., Lexington, MA 02173.

404-395-4500

Synthetic Organic Chemicals, 1991 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification

code

Name of company

Telephone number

GPC

Grain Processing Corp

319-264-4211

CPC GTL GDC

Grant Industries, Inc Great Lakes Chemical Corp Gresco, Mfg. Inc

201-791-6700 317-497-6100 919-475-8101

GPI

Grinstead Products, Inc

913-764-8100

GGI

410-939-1234

GRV

Grow Group, Inc Cello Corp Div. Guardsman Products, Inc

GSS

Gulf States Steel, Inc

205-543-6201

GTH HAR

Guth Corp Haarmann & Reimer Corp Food Ingredients Div. C. P. Hall Co Halocarbon Products Corp

414-644-6461 201-467-5600 219-262-6916 708-594-5952 201-262-8899 708-597-7990 913-321-3131 201-433-6632 908-738-3000 713-424-5568

SCP

Handschy Industries, Inc Ink and Chemical Div. Harcros Chemicals, Inc Hart Products Corp Hatco Chemical Co Helmerich & Payne, Inc., Natural Gas Odorizing Div. Henkel Corp

HPC HER

Hercules, Inc Heresite Protective Coating, Inc

302-594-5000 414-684-6646

HTN HEC HEW HXL

Heterene Chemical Corp Hew, Inc Hewitt Soap Co., Inc Hexcel Corp: Chemical Products Div Resin Products Div

201-278-2000 601-863-6600 513-253-1151 510-828-4200 818-882-3022

DAN HIP HIL

Hickson Danchem Corp High Point Chemical Corp Hilton Davis Chemical Co

804-797-8105 919-884-2214 513-841-4000

HIM HDG

Himont, USA, Inc Hodag Chemical Corp

302-996-6000 708-675-3950

HCL

Hoechst Celanese Corp: Advanced Materials Group Bayport Works, SP & W Div Chemical Group Div

201-635-2600 713-474-6737 214-689-4000

HAL HOC FOC TMH HRT HCC HAP

.

616-452-5181

215-270-8100

Office address

1600 Oregon Street, Muscatine, IA 52761-0349. P.O. Box 360, Elmwood Park NJ 07407. U.S. Hwy. 52 NW., Lafayette, IN 47906. 216 E. Holly Hill Rd., Thomasville, NC 27360. 200 Industrial Parkway Industrial Airport, KS 66031. 1354 Old Post Rd., Havre De Grace, MD 21078. 1350 Steele Ave. SW., Grand Rapids, MI 49507. 174 South 26th St., Gadsden AL 35904-1935. P.O. Box 347, Slinger, WI 53086. 70 Diamond Rd., Springfield, NJ 07081. 1127 Myrtle St., Elkhart, IN 46515. 7300 S. Central Ave., Chicago, IL 60638. 887 Klnderkamack Rd., River Edge, NJ 07661. 13601 S. Ashland Ave., Riverdale, IL 60627-1099. 5200 Speaker Rd., Kansas City, KS 66110. 173 Sussex St., Jersey City, NJ 07302. IGng George Post Rd., Fords, NJ 08863. 3601 Decker Dr., Baytown, TX 77522-1429. 2200 Renaissance Blvd., Gulpn Mills, PA 19406. Hercules Plaza, Wilmington, DE 19894. 822 S. 14th St., Manitowoc, WI 54221-0250. 790 - 21st Ave., Paterson, NJ 07513. 14405 Seaway Rd., Gulfport, MS 39502. 333 Linden Ave., Dayton, OH 45403. 215 N. Centennial St, Zeeland, MI 49464. 20701 Nordhoff Street, Chatsworth, CA 91311. P.O. Box 400, Danville, VA 24543. 243 Woodbine St., High Point, NC 27261. 2335 Langdon Farm Rd., Cincinnati, OH 45237. P.O. Box 15439, Wilmington, DE 19894. 7247 N. Central Park Ave., Skokie, IL 60076. 26 Main St., Chatham, NJ 07928. P.O. Box 58160, Houston, TX 77258. 1250 W. Mockingbird Lane, Dallas, TX 75247. A-9

Appendix A

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

Hoechst Celanese Corp-Continued Fibers Industrial Div

201-231-2000 201-231-2000 201-231-2000

HOF HCP EFH

Sou-Tex SpecialityChem Group Coventry Plant. Hoffmann-LaRoche, Inc Honig Chemical & Processing Corp E. F. Houghton & Co

NOD

Huls America, Inc

201-981-5000

HML

Hummel Croton, Inc

908-754-1800

HMY HNT HMN

Humphrey Chemical Co Huntington Laboratories, Inc Huntsman Chemical Corp

201-804-3220 219-356-8100 801-532-5200

ICI

ICI Americas, Inc: Agricultural Products Div

302-886-8000

201-235-5000 201-344-0881 215-666-4100

Films Group Div

302-886-3000

ICI Acrylic, Inc

314-966-3111

Polyurethanes Group

609-423-8300

Resin Div Speciality Product Div

508-658-6600 302-886-3000

ISP SDS GAF VND RAY

INDSPEC Chemical Corp ISK Biotech Corp ISP Chemicals, Inc ISP-Can Dyk, Inc ITT Rayonier Liguin Products, Inc

412-765-1200 216-357-4100 201-628-3000 201-450-3206 203-348-7000

IND I DC I NL WM

Indol Color Co., Inc Industrial Color, Inc Inland Steel Co Index Chemical Co

201-242-1300 815-722-7402 312-346-0300 215-271-0800

SPC

Insilco Corp., Sinclair Paint Co. Div

213-888-8888

IMI GBF

Insulating Materials, Inc International Bio-Synthetics, Inc

518-395-3300 704-527-9000

IFF

International Flavor & Fragrances Inc

908-264-4500

IPC

Interplastic Corp

612-481-6860

JTM CRZ

JTM Products, Inc James River II, Inc

216-831-0404 804-644-5411

A 10 -

Office address

P.O. Box 5887, Spartanburg, SC 29304-5887. P.O. Box 2500, Mt. Holly, NC 28120. 500 Washington St., Coventry, RI 02816. 340 Kingsland St., Nutley, NJ 07110. 414 Wilson Ave., Newark, NJ 07105. Madison & Van Buren Avenues, Forge, PA 19482. 80 Contennial Ave., Piscataway, NJ 08855-0456. 10 Harmich Rd., S. Plainfield, NJ 07080-4899. 45 Divine St., N. Haven, CT 06473-0325. 970 E. Tipton St., Huntington, IN 46750. 2000 Eagle Gate Tower, Salt City, UT 84111. Delaware Corp. Center, Wilmington, DE 19897. Concord Pike & Murphy Rd., Wilmington, DE 19897. 10091 Manchester Rd., St. Louis, MO 63122. 286 Mantua Grove Rd., W. Deptford, NJ 08066-1732. 730 Main St., Wilmington, MA 01887. Concord Pike & Murphy Rd., Wilmington, DE 19897. 411 Seventh Ave., Pittsburgh, PA 15219. 5966 Heisley Rd., Mentor, OH 44060. 1361 Apls Rd., Wayne, NJ 07470. Main & Willian Sts., Belleville, NJ 07109. 18000 International Blvd., Suite 900, Seatac, WA 98188. 1029 Newark Ave., Elizabeth, NJ 07201. 50 Industry Ave., Joliet, IL 60435. 3210 Watling, St., E. Chicago, IL 46312. Jackson & Swanson Sts., Philadelphia, PA 19148. 6100 South Garfield Ave., Los Angeles, CA 90040. 1 Campbell Rd., Schenectady, NY 12306. 8720 Red Oak Blvd., Charlotte, NC 28224-1068. 1515 Highway #36, Union Beach, NJ 07735. 1225 Walters Blvd., Vadnois Heights, MN 55110. 9505 Cassius Ave., Cleveland, OH 44105. 4th & Adams Sts., Camas, WA 98607.

Synthetic Organic Chemicals, 1991

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

JRC JVL JFR JRG

Jarchem Industries, Inc Javelina Co George A. Jeffreys & Co., Inc Andrew Jergens Co

201-344-0600 713-877-7510 703-389-8220 513-421-1400

JTO MRX JNS JOB KLM

Jetco Chemicals, Inc Johnson Matthey, Inc S. C. Johnson & Son, Inc Jones-Blair Co Kalama Chemical, Inc

214-872-3011 609-384-7001 414-631-3388 214353-1600 206-682-7890

KTP KAN

Kama Corp Kanasco, Ltd

717-455-2022 301-789-7800

KTX

Kaneka Corp

713-840-1751

SVC KMP KMI KPI KYS KCW CHF KHI KPT

Karlshamns USA Kelly-Moore Paint Co., Inc Kemin Industries, Inc Kenrich Petrochemicals, Inc Keysor Century Corp Keystone Color Works, Inc IGncaid Enterprises, Inc Koch Refining Co Koppers Industries, Inc

614-299-3131 415-592-8337 515-266-2111 201-823-9000 805-259-2360 717-854-9541 304-755-3377 316-832-5500 412-227-2001

LCP

LCP Chemicals: Maine Div. of Hanlin Group, Inc West Virginia, Div. of Hanlin Group, Inc. LTV Steel Co., Inc

LTV

414 Wilson Ave., Newark, NJ 07105. Nine Greenway Plaza, Houston, TX 77046. 528 Chapman St., Salem, VA 24153. 2535 Spring Grove Ave., Cincinnati, OH 45214. P.O. Box 1898, Corsicana, TX 75110. 2002 Nolte Dr., W. Deptford, NJ 08066. 1525 Howe St., Racine, WI 53403. 2728 Empire Central, Dallas, TX 75235 Bank of California Center, Suite 1110, Seattle, WA 98164. 666 Dietrich Ave., Hazelton, PA 18201. 6118 Robinwood Rd., Baltimore, MD 21225. 175 S. Briar Hollow Lane, Suite 307, Houston, TX 77027. 525 W. First St., Janesville, WI 53547. 987 Commercial St., San Carlos, CA 94070. 2100 Maury St., Des Moines, IA 50301. 140 E. 22nd St., Bayonne, NJ 07002-0032. P.O. Box 924, Santa Clarita, CA 91380. 151 W. Gay Ave., York, PA 17403. P.O. Box 549, Nitro, WV 25143. P.O. Box 2256, Wichita, KS 67201. 436 Seventh Ave., Pittsburgh, PA 15219-1800.

201-225-4840 304-843-1310

P.O. Box 149, Orrington, ME 04474. P.O. Box 484, Linden, NJ 07036.

216-622-5000

LTV Steel Bldg., 25 W. Prospect Ave., Cleveland, OH 44115. 515 W. Davenport St, Rhinelander, WI 54501. 1200 Airline Hwy., Baton Rouge, LA 70821. 1100 Johnson Ferry Rd., Alanta GA 30342. 990 Skokie Blvd., Northbrook IL 60062. 2722 N. Hancock St., Philadelphia, PA 19133. P.O. Box 82727, Baton Rouge, LA 70884-2727. 2820 N. Normandy Dr., Petersburg, VA 23805. 736 Dunks Ferry Rd., Bensalem, PA 19020. 390 Park Ave., New York, NY 10022. 81 Holly Hill Lane, Greenwich, CT 06830. Lilly Corporate Center, Indianapolis, IN 46285.

715-369-4217

LRO

Lake States Div. of Rhinelander Paper Co. LaRoche Chemical, Inc

ARM LII LEA

LaRoche Industries Inc Lawter International, Inc Leatex Chemical Co

404-851-0475 708-498-4700 215-739-6324

LCS

Lechem, Inc

504-767-0452

LLI

Lee Laboratories, Inc

804-862-2534

LVR LEV MAR LIL

C. Lever Co., Inc Lever Brothers Co Lignotech (U.S.), Inc. Eli Lilly & Co

215-639-8640 212-688-6000 203-625-0701 317-276-6448

LKY

Office address

504-356-8421

Appendix A

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

Office address

317-634-8512 616-788-2341 201-794-2671 814-868-3611

LYP

Lilly Industries, Inc Lomac, Inc Lonza, Inc Lord Corp., Chemical Products Group. Lyondell Petrochemical Co

MGK

McLaughlin Gormley King Co

612-544-0341

MNP

McWhorter, Inc

312-428-2657

RIK

3M Pharmaceuticals

818-341-1300

MAK

MAK Chemical Corp

317-288-4464

MCK TZC

MacKenzie Chemical Works, Inc Magnesium Elektron, Inc

504-886-2173 908-782-5800

MGR MAL MOC MRV MCA MAX GNF MVO MLC

Magruder Color Co., Inc Mallinckrodt, Inc • Marathon Oil Co Marlowe-Van Loan Corp Masonite Corp., Alpine Resin Div Max Marx Color Corp Maxwell House Coffee Co Mayo Chemical Co., Inc Melamine Chemicals, Inc

201-242-1300 314-530-2000 419-422-2121 919-886-7126 601-649-6000 201-373-7801 201-420-3432 404-696-6711 504-473-3121

MRK MER DKA CHG VPC MIL MMM

Merck & Co., Inc Meridiem Co Miles Inc Agricultural Chemicals Div Dyes & Pigments Div Milliken & Co., Milliken Chemical Div Minnesota Mining & Manufacturing Co. Mississippi Chemical Corp Mobil Oil Corp.: Beaumont Refinery Div Chemical Products Div Gas Liquids Dept Petrochemicals Div

201-574-4000 713-455-1311 412-777-2000 816-242-2345 412-777-2000 803-472-9041 612-733-1110

733 S. West St., Indianapolis, IN 46225. 5025 Evanston Ave., Muskegon, MI 49443. 17-17 Route 208, Fair Lawn, NJ 07410. 2000 W. Grandview Blvd., Erie, PA 16514-0038. 1221 McIGnney, Suite 1600, Houston, TX 77253-3646. 8810 - 10th Ave. N., Minneapolis, MN 55427-4372. 400 E. Cottage Place, Carpentersville, IL 60110. 19901 Nordhoff St., Northridge, CA, 91324. 1200 Rochester Ave., Muncie, IN 47302. 78015 Chemical Rd., Bush, LA 70431. 500 Point Breeze Road, Flemington, NJ 08822. 1029 Newark Ave., Elizabeth, NJ 07208. 3600 N. Second St., St. Louis, MO 63147. 539 S. Main St., Findlay, OH 45840. 1224 Ward St., High Point, NC 27260. P.O. Box 1048, Laurel, MS 39441. 1200 Grove St., Irvington, NJ 07111. 1125 Hudson St., Hoboken, NJ 07030. 5544 Oakdale Rd. S.E., Smyrna, GA 30082. 9041 Highway 81, Donaldsonville, LA 70346. P.O. Box 2000, Rahway, NJ 07065. 1914 Haden Rd., Houston, TX 77015. Mobay Rd., Pittsburgh, PA 15205-9741. Hawthorn Rd., Kansas City, MO 64120. Mobay Rd., Pittsburgh, PA 15205-9741. P.O. Box 817, Inman, SC 29349. 3M Center 224-6S-04, St. Paul, MN 55144.

601-746-4131

P.O. Box 388, Yazoo City, MS 39194.

703-846-3000 201-321-6000 703-849-3000 713-590-7700

MOA MON

Polystyrene Business Group Mona Industries, Inc Monsanto Co

201-321-6000 201-345-8220 314-694-1000

MNA

Monsanto Agricultural Group

314-694-1000

3225 Gallows Rd., Fairfax, VA 22037. P.O. Box 250, Edison, NJ 08818. P.O. Box 900, Dallas, TX 75221. World Towers One, 15600 Kennedy Blvd., Houston, TX 77032. P.O. Box 3029, Edison, NJ 08818. 76 E. 24th St., Paterson, NJ 07544. 800 N. Lindbergh Blvd., St. Louis, MO 63167. 800 N. Lindbergh Blvd., St. Louis, MO 63167. 2301 Scranton Rd., Cleveland, OH 44113.

LIC LMC BRD LC

MSC SM

MCI

Mooney Chemicals, Inc

713-652-7200

216-781-8383

Synthetic Organic Chemicals, 1991 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

MCP MRF

Moretex Chemical Products, Inc Morflex, Inc

803-583-8441 919-292-1781

MHI MRT PYI

Morton International, Inc Morton Chemical Div Morton Chemical Div

508-774-3100 312-807-2000 312-807-2000

CCW MOT RTC

Industrial Chemical & Additives Motomco, Ltd Mount Vernon Mills, Inc

513-733-2100 608-244-2904 803-233-4151

PNX

The Murphy-Phoenix Co

216-349-7179

NMC LEM NTC NCJ NSC NTS NEP CBD

NAMICO, Inc Napp Chemicals, Inc National Casein Co National Casein of New Jersey National Starch & Chemical Corp National Steel Corp., Great Lakes Div. Nepera, Inc Neste Resins Corp

215-482-6600 201-773-3900 312-846-7300 312-846-7300 201-685-5000 313-297-2100 914-782-1200 503-687-8840

NEV NBC NCC NLO NCP NOC FSN

Neville Chemical Co New Boston Coke Corp Niacet Corp NiWor Chemical Co., Inc Niles Chemical Paint Co The Norac Co , Inc Maths Div NOR-AM Chemical Co

412-331-4200 614-456-4154 716-285-1474 213-830-2253 616-683-3377 818-334-2908 818-334-2908 302-477-3000

NW

Northwestern Flavors, Inc

708-231-6111

NOR PLR NBI NSW NYL

Norwich Eaton Pharmaceutical, Inc Novacor Chemicals, Inc Novo Nordisk Biochem, Inc. The Nutrasweet Co Nylon Corp. of America Occidential Chemical Corp.: ED &S Div Polymers-Plastic Group Olin Corp Omega Chemicals, Inc Organics/LaGrange, Inc Orient Chemical Corp Original Bradford Soap Works, Inc C. J. Osbom Chemicals, Inc Owens-Corning Fiberglas Corp Oxy Petrochemicals, Inc

607-335-2049 508-537-1111 919-494-2014 708-940-9800 603-627-5150

314 W. Henry St., Spartanburg, SC 29301. 2110 High Point Rd., Greensboro, NC 27403. 150 Andover St., Danvers, MA 01923. 100 N. Riverside Plaza, Chicago, IL 60606. 130 Montain Creek Church Rd., Greenville, SC 29602. 2000 West St., Reading, OH 45215. 3699 IGnsman Blvd., Madison, WI 53704. One Shaffer Place, Suite 700, Greenville, SC 29602. 6550 Davis International Pkwy, Solon, OH 44139. 4601 Flat Rock Rd., Philadelphia, PA 19127. 199 Main St., Lodi, NJ 07644. 601 W. 80th St., Chicago, IL 60620. 601 W. 80th St, Chicago, IL 60620. 10 Findeme Ave., Bridgewater, NJ 08807. 1 Quality Dr., Ecorse, MI 48229. Route #17, Harriman, NY 10926. 1600 Valley River, Suite 390, Eugene, OR 97401. 2800 Neville Rd., Pittsburgh, PA 15225. 600 River Ave., New Boston, OH 45662. 400 - 47th St., Niagara Falls, NY 14304. 2060 E. 220th St., Long Beach, CA 90810. P.O. Box 307, Niles, MI 49120. 405 S. Motor Ave., Azusa, CA 91702. 169 Kennedy Dr., Lodi, NJ 07644-0230. 3509 Silverside Road, Wilmington, DE 19810: 120 N. Aurora St., W. Chicago, IL 60185. 17 Eaton Ave., Norwich, NY 13815. 690 Mechanic St., Leominster, MA 01453. State Road 1003, Franklinton, NC 27525. 1751 Lake Cook Rd., Deerfield, IL 60015. 333 Sundial Ave., Manchester, NH 03103.

214-404-3300 214-404-3800 203-356-2000 803-582-5346 312-764-6700 908-355-4010 401-821-2141 609-662-0128 419-248-8000 713-623-2246

5005 LBJ Freeway, Dallas, TX 75244. 5005 LBJ Freeway, Dallas, TX 75244. 120 Long Ridge Rd., Stamford, CT 06904. P.O. Box 1723, Spartanburg, SC 29304 7125 N. Clark St., Chicago, IL 60626. 121 Tyler St., Port Newark, NJ 07114. 200 Providence St., W. Warwick, RI 02893. 820 Sherman Ave., Pennsauken, NJ 08110. Fiberglas Tower, Toledo, OH 43659. P.O. Box 809050, Dallas, TX 75380.

HK HKD OMC OC ORG OCC BSW CJO OCF CNE

.

.

Office address

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

PC PBI

PCI, Inc PBI-Gordon Corp

606-836-3660 816-421-4070

PCR PDG PSG

PCR, Inc PD Glycol PMC Inc., PMC Specialities Group, Inc. PMP Fermentation Products, Inc

904-376-8246 409-838-4521 216-356-0700

PPG Industries, Inc Packaging Corp. of America Para-Chem Southern, Inc Parish Chemical Co Parke-Davis Div., of Warner Lambert, Inc. Passaic Color & Chemical Co Div. of Royce Associates, ALP. C. H. Patrick & Co., Inc Paxon Polymer Co., Inc Pelron Corp Penick Corp Pennzoil Products Co., Penreco Div Permuthane Coatings, Inc Perstorp Compounds, Inc Perstorp Polyols, Inc Pfanstiehl Laboratories, Inc Pfister Chemical, Inc Pfizer, Inc Pfizer Pharmaceuticals, Inc Pharmachem Corp

412-434-3131 818-968-3801 803-967-7691 801-226-2018 616-392-2375 201-279-0400

414-227-3600 219-456-4444

SOG PLC PPX PPR PHC PCI PIC PIL

Pharmacia P-L Biochemicals, Inc Phelps Dodge Industries, Inc Phelps Dodge Magnet Wire Co. Phibro Refining Phillips 66 Co Phillips Paraxylene, Inc Phillips Puerto Rico Core, Inc Phthalchem, Inc Piedmont Chemical Industries, Inc Pierce Chemical Co Pilot Chemical Co

PPL IMC

Pioneer Plastics Corp Pittman-Moore, Inc

PKL PSL PLS PMC PRT JLP

Plaskolite, Inc Plaslok Corp Plastics Engineering Co Plastics Manufacturing Co Pratt & Lambert, Inc J. L. Prescott Co

207-784-9111 812-232-0121 708-615-3700 614-294-3281 716-681-7755 414-458-2121 214-330-8671 716-873-6000 708-331-8800

PMP PPG AEP PRA PAH PD PSC CHP PAX PEL PEN PAR BPT PST PST PFN PCW PFZ PHR PLB PDI

A-14

708-928-0050

803-244-4831 504-775-4330 708-442-9100 201-621-2804 713-337-1534 508-531-1880 413-584-2472 419-729-5448 708-623-0370 201-945-5400 212-573-2323 809-846-4300 215-867-4654

203-661-4770 918-661-6600 809-864-1515 809-864-1515 513-681-0099 919-885-5131 815-968-0747 213-723-0036

Office address

266 W. Mitchell Ave., Cincinnati, OH 45232. 1217 W. 12th St., Kansas City, MO 64101-1407. P.O. Box 1466, Gainsville, FL 32609. P.O. Box 3785, Beaumont, TX 77704. 20525 Center Ridge Rd, Rocky River, OH 44116. 9525 W. Bryn Mawr Ave., Suite 725, Rosemont, IL 60018. One PPG Place, Pittsburgh, PA 15272. 14505 Proctor Ave., Industry, CA 91749. P.O. Box 127, Simpsonville, SC 29681. 145 N. Geneva Rd., Orem, UT 84057. 188 Howard Ave., Holland, MI 49424. 28-36 Paterson St., Paterson, NJ 07501. P.O. Box 2526, Greenville, SC 29602. P.O. Box 53006, Baton Rouge, IA 70807. 7847 W. 47th St., Lyons, IL 60534. 158 Mount Olive Ave., Newark NJ 07714 4401 Park Ave., Dickinson, TX 77539. 13 Corwin St., Peabody, MA 01960. 238 Nonotuck St, Florence, MA 01060. 600 Matzinger Rd., Toledo, OH 43612. 1219 Glen Rock Ave., Waukegan, IL 60085. Linden Ave., Ridgefield, NJ 07657. 235 E. 42nd St., New York, NY 10017. P.O. Box 628, Barceloneta, PR 00617. 719 Stefko Blvd., Bethlehem, PA 18016-1035. 2202 N. Bartlett Ave., Milwaukee, WI 53202. 4300 New Haven Ave., Fort Wayne, IN 46803. P.O. Box 5038, Houston, TX 77262-5038. Phillips Bldg., Bartlesville, OK 74004. P.O. Box 1162, Guayama, PR 00655. P.O. Box 1166, Guayama, PR 00655. 266 W. Mitchell Ave., Cincinnati, OH 45232. P.O. Box 2728, High Point, NC 27261. 3747 N. Meridan Rd., Rockford, IL 61103. 11756 Burke St., Santa Fe Springs, CA 90670. 1 Pionite Rd., Auburn, ME 04210. 1401 S. 3rd St., Terre Haute, IN 47808, and 421 E. Hawley St., Mundelein, IL 60060. P.O. Box 1497, Columbus, OH 43216. 3155 Broadway, Buffalo, NY 14227. 3518 Lakeshore Rd., Sheboygan, WI 53081. 2700 S. Westmoreland, Dallas, TX 75233. P.O. Box 22, Buffalo, NY 14240. 16750 S. Vincennes Rd., S. Holland, IL 60473.

Synthetic Organic Chemicals, 1991

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

PG

Name of company

Telephone number

513-627-6386

QKO QCP

Procter & Gamble Co., Procter & Gamble Mfg. Co. Products Research & Chemical Corp. Q0 Chemicals, Inc Quaker Chemical Corp

USI QUN RMI

Quantum Chemical Corp., USI Div. K. J. Quinn & Co., Inc R-M Industries, Inc

513-530-6500 603-474-7177 803-548-3210

AMU RSA

RPM, American Emulsions Co., Inc RSA Corp

404-226-7028 914-693-1818

BLC

Ranbar Technology, Inc

412-486-1111

REG RCI

Regis Chemical Co Reichhold Chemicals, Inc

708-967-6000 914-682-5700

RIL

Reilly Industries, Inc

317-247-8141

CRT

Reilly-Whiteman, Inc

215-423-5300

ELP

Rexene Products Co

214-450-9000

RDA CLD REZ

Rhone-Poulenc, Inc Rhone-Poulenc, Inc Rhone-Poulenc, Inc

201-821-1000 404-422-1250 502-499-4011

KCH RIV

Manchem, Inc Riverdale Chemical Co

215-837-1808 708-754-3330

ORT ROG RH

Roehr Chemicals, Inc, Div. of Aceto Corp Rogers Corp Rohm & Haas Co

718-784-8473 203-774-9605 215-592-3000

DRB ROM RQT

Rohm Tech, Inc Roma Color, Inc Roquette Corp

508-342-5831 617-676-3481 708-249-5950

RUC RUO NES SBP SCM SOS NPR

Rubicon, Inc Ruco Polymer Corp Ruetgers-Nease Chemical Co SBS Products Inc SCM Corp., Glidco Organics SSC Industries, Inc Safeway, Inc

504-673-6141 516-931-8100 814-238-2424 517-799-4941 904-768-5800 404-762-9651 510-632-7373

PRC

818-702-8900 317-497-6110 215-828-4250

Office address

Spring Grove & June St., St. Bernard, OH 45217. 21800 Burbank Rd., Woodland Hills, CA 91367. 2801 Kent Ave., W. Lafayette, IN 47906. Elm & Lee Sts., Conshohocken, PA 19428-0809. 11500 Northlake Dr., Cincinnati, OH 45249. 135 Folly Mill Rd., Seabrook NH 03874. 2300 Banks St. Extension, Fort Mill, SC 29715. 1202 Dozier St., Dalton, GA 30721. 690 Saw Mill River Rd., Ardsley, NY 10502. 1114 William Flinn Highway, Glenshaw, PA 15116. 8210 Austin Ave., Morton Grove, IL 60053. 800 Calitola Dr., Research Triangle Park, Durham, NC 27713. 1510 Market Square Center, Indianapolis, IN 46204. 801 Washington St., Conshohocken, PA 19428. 5005 LBJ Freeway, Occidental Tower, Dallas, TX 75244. CN 5266, Princeton, NJ 08543-5266. P.O. Box 769, Marietta, GA 30061. 9808 Bluegrass Parkway, Louisville, KY 40299. 275 Keystone Dr., Bethlehem, PA 18017. 220 E. 17th St., Chicago Heights, IL 60411-3699. 52-20 37th St., Long Island City, NY 11101. One Technology Dr., Rogers, CT 06263. Independence Mall West., Philadelphia, PA 19105. 83 Authority Dr., Fitchburg, MA 01420. 749 Quequechan St., Fall River, MA 02723. 1550 Northwestern Ave., Gurnee, IL 60031-2392. P.O. Box 517, Geismar, LA 70734. New South Rd., Hicksville, NY 11802. 201 Struble Rd., State College, PA 16801. 302 Waller St., Saginaw, MI 48602. P.O. Box 389, Jacksonville, FL 32201. 1550 E. Taylor Ave., East Point, GA 30344. 1100 77th Ave., Oakland, CA 94621.

Appendix A

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

STX

St. Croix Petrochemical Corp

809-778-6450

SLM SAL

508-745-0585 515-257-1000

SDC ZOC SCN

Salem Oil & Grease Co Salsbury Chemicals, Inc Sandoz Chemical Corp.: Sandoz Chemical Corp Sandoz Chemical Corp Sandoz Corp. Protection Schenectady Chemicals, Inc

SBC SCH SPR TXS

Scher Chemicals, Inc Schering Corp Scientific Protein Laboratories Scott Polymers, Inc

201-471-1300 201-298-4000 608-849-5944 817-831-3541

SRL SQA SKP

G. D. Searle & Co Sequa Chemicals, Inc Shakespeare Monofilament Div

708-982-7000 803-385-5181 803-754-7011

SHO SHC SGO SHP SHX SHT

Shell Oil Co Shell Chemical Co Shenango, Inc Shepherd Chemical Co Sherex Chemical Co., Inc Shintech, Inc

713-241-9548 713-241-9548 412-771-4400 513-731-1110 614-764-6500 713-965-0713

SMP UPF SK BEE

J. R. Simplot Co Sloss Industries Inc SmithKline Beechman Chemicals SmithKline Beecham Pharmaceuticals

208-336-2110 205-254-7801 215-751-4000 908-469-5200

SMO SLC SLT SAC SOR SWR SPL

201-647-5800 401-821-8100 713-522-1781 704-754-3493 919-475-1348 512-884-8863 716-692-2000

ASL SOI IPP SPU SCC STP SC

Smooth-On, Inc Soluol Chemical Co., Inc Solvay Polymers, Inc. Southeastern Adhesives Southern Resin, Inc Southwestern Refining Co., Inc Spaulding Composites Co Industrial Plastics Div. SpecialtyChem Products Corp Specialty Organics, Inc Spectrachem Corp Spurlock Adhesives, Inc Standard Chlorine of Delaware, Inc Stepan Co Sterling Chemicals, Inc

715-735-9033 818-962-2008 201-595-8181 804-834-3113 201-997-1700 708-446-7500 713-650-3700

SD SDW CIN IRI SUN

Sterling Drug, Inc Sterling Organics Div Stockhausen, Inc Stuart-Ironsides, Inc Sun Company, Inc

212-907-2000 212-907-2000 919-333-3500 708-655-4595 215-977-6358

S

A-16

704-331-7016 704-331-7016 312-699-1616 518-370-4200

Office address

P.O. Box 6801, Sunny Isle, St. Croix, U.S. VI 00823-6801. 60 Grove St., Salem, MA 01970. 2000 Rocl•port Rd., Charles City, LA 50616. 4000 Monroe Rd., Charlotte, NC 28205. 4000 Monroe Rd., Charlotte, NC 28205. 1300 E. Touity Ave., Des Plaines, II 60018. Congress & 10th Ave., Schenectady, NY 12306. Industrial West, Clifton, NJ 07012. 1011 Morris Ave., Union, NJ 07081. 700 E. Main St., Waunakee, WI 53597. 3607 N. Sylvania Ave., Fort Worth, TX 76111. 5200 Old Orchard Rd., Skokie, IL 60077. P.O. Box 70, Chester, SC 29706. 6111 Shakespeare Rd., Columbia, SC 29223. P.O. Box 3105, Houston, TX 77253. P.O. Box 3105, Houston, TX 77253. 200 Neville Rd., Pittsburgh, PA 15225-1690. 4900 Beech St., Cincinnati, OH 45212. 5777 Frantz Rd., Dublin, OH 43017. 24 Greenway Plaza, Suite 811, Houston, TX 77046. P.O. Box 912 Pocatello, ID 83204. 3500 N. 35th Ave., Birmingham, AL 35207. 900 River Rd., Consnonocken, PA 19428. 101 Possumtown Rd., Piscataway, NJ 08854. 1000 Valley Rd., Gillette, NJ 07933. Green Hill & Market Sts., W. Warwick, P.O. Box 1000, Deer Park, TX 77536. 815-D Virginia St., Lenoir, NC 28645. 1510 Denton Rd., Thomasville, NC 27360. P.O. Box 9217, Corpus Christi, TX 78469. 310 Wheeler St., Tonawanda, NY 14150. 2 Stanton St., Marinette, WI 54143. 5623 N. 4th St, Irwindale, CA 91706. 200 Sheridan Ave., Paterson, NJ 07512. P.O. Box 8, Waverly, VA 23890. 1035 Belleville Turnpike, Kearny, NJ 07032. 22 West Frontage Rd., Northfield, IL 60093. 1200 Smith, Suite 1900, Texas City, TX 77592-1311. P.O. Box 11247, Barcelonita, PR 00617. 33 Riverside Ave., Rensselaer, NY 12144. 2408 Doyle St., Greensboro, NC 27406. 7575 Plaza Court, Willowbrook, IL 60521 1801 Market St., Philadelphia, PA 19103.

Synthetic Organic Chemicals, 1991

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

SNA RAS TCC I NP

Sun Chemical Corp., Pigments Div Surface Coatings, Inc Sybron Chemical, Inc Synair Corp

212-986-5500 617-933-4200 609-893-1100 615-698-8801

BUC

Synalloy Corp., Blackman Uhler Chemical Div. Synray Corp

803-585-3661

417-866-7291 216-531-6010 704-437-8611 919-762-8666 401-725-8000 408-637-6536

TOC TER

Syntex Agribusiness, Inc Synthetic Products Co Synthron, Inc Takeda Chemical Products USA, Inc Teknor Apex Co Teledyne Industries, Inc., Teledyne McCormick Selph. Tenneco Methanol Co Terra International, Inc

BNP TX TPC TWD TRY TRI

Terra International, Inc Texaco Chemical Co Texas Petrochemicals Corp Tonawanda Coke Corp Toray Plastics Americas, Inc Triad Chemical

712-277-1340 713-432-3734 713-477-9211 716-876-6222 401-294-1550 504-473-9231

TRO TUL TLC UPM

Troy Chemical Corp Tull Chemical Co., Inc Twin Lake Chemical, Inc UOP, Inc

201-589-2500 205-831-3845 716-433-3824 708-391-2000

UHL

Paul Uhlich & Co., Inc

914-478-2000

UTF

Ultraform Co

205-443-1600

DRL NCI NCI WTH UCC UOC UTP

Unichema North America Union Camp Corp.: BBA Div Chemical Div Union Carbide Corp., Union Oil Co. of California Union Texas Products Corp

312-376-9000

USR UNN UCM

Uniroyal Chemical Co., Inc United Aniline Co United Color Manufacturing, Inc.

203-573-3886 617-762-4057 215-860-2165

UNO USB

United Erie, Inc U.S. Borax & Chemical Corp

814-456-7561 213-251-5400

SRY HFT SYP SYT TKD TEK TLI

201-245-2600

713-757-2131 712-277-1340

201-628-2000 201-628-9000 304-747-3825 213-977-7746 713-623-6544

Office address

411 Sun Ave., Cincinnati, OH 45232. 100 Eames St., Wilmingon, MA 01887. Birmingham Rd., Birmingham, NJ 08011. 2003 Amnicola Hwy., Chattanooga, TN 37406. Croft Industrial Park, Spartanburg, SC 29304. 209 N. Michigan Ave., Kenilworth, NJ 07033. P.O. Box 1246, Springfield, MO 65801. 1000 Wayside Rd., Cleveland, OH 44110. P.O. Box 1111, Morganton, NC 28655. P.O. Box 2577, Wilmington, NC 28402. 505 Central Ave., Pawtucket, RI 02861. 3601 Union Rd., Hollister, CA 95023-0006. 1010 Milan St., Houston, TX 77252. Terra Centre, 600 - 4th St., Sioux City, IA 51101. 1000 Terra Dr., Woodward, OK 73801. 3040 Post Oak Rd., Houston, TX 77056. 8600 Park Place Blvd., Houston, TX 77017. 3875 River Rd., Tonawanda, NY 14150. 50 Beluer Ave., N. Kingstown, RI 02852. 39041 Highway 18 West, Donaldsonville, LA 70346. One Avenue L, Newark, NJ 07105. 130 Burton St., Oxford, AL 36203. 520 Mill St., Lockport, NY 14095. 25 E. Algonguin Road, Des Plaines, IL 60017-5017. 1 Railroad Ave., Hastings-on-Hudson, NY 10706. Theodore Industrial Park, Theodore, AL 36582. 4650 S. Racine Ave., Chicago, IL 60609. 1600 Valley Rd., Wayne, NJ 07470. 1600 Valley Rd., Wayne, NJ 07470. P.O. Box 8361, Charleston, WV 25303. 1201 W. Fifth St., Los Angeles, CA 90017. 1330 Post Oak Blvd. Houston TX 77252-2120. Benson Rd., Middlebury, CT 06749 Endicott St., Norwood, MA 02062. 638 Newtown-Yardley Rd., Suite 1 E, Newton, PA 18940. 438 Huron St., Erie, PA 16502. 3075 Wilshire Blvd., Los Angeles, CA 90010.

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1991 Identification code

Name of company

Telephone number

Office address

UTC UPJ CWN VSV VLR VCM VDM VNC

U.S. Steel, Div. Of USX: Clairton Plant Gary Works Unitex Chemical Corp The Upjohn Co Fine Chemicals Valentine Sugars, Inc Valero Refining & Marketing Co Vanchem, Inc Van De Mark Chemical Co., Inc Vanderbilt Chemical Corp

VND VEL VIN VCC.

Van Dyk, Div. of Mallinckrodt, Inc Velsicol Chemical Corp Vineland Chemical Co., Inc Vinings Industries, Inc

412-433-4980 219-888-4657 919-378-0965 616-323-4000 203-281-2700 504-532-2541 512-246-2000 716-433-6764 716-433-6764 203-744-3900 203-853-1400 201-450-3206 708-698-9700 609-691-3535 404-436-1542

VKR

Virkier Co

704-588-8500

VIM FRO VYN SWS WJ CCG WLM

Vitamins, Inc Vulcan Materials Co., Chemicals Div Vygen Corporation Wacker Silicones Corp Warner-Jenldnson Co Warner-Jenkinson Cosmetic Colors Wellman, Inc

312-861-0700 205-877-3000 216-998-1120 517-264-8500 314-889-7600 908-757-4500 908-542-7300

EW

Westinghouse Electric Corp., Electrical Materials Div. Westlake Group

412-864-8200

404-645-4753 212-688-5000 715-384-2141 304-234-2400 617-242-1180 918-825-3383 201-573-2800 919-251-0234 616-637-8474 215-341-3867

299 Park Ave., NY, NY 10171. 1401 E. 4th St., Marshfield, WI 54449. 1134 Market St, Wheeling, WV 26003. 62 Alford St., Charlestown, MA 02129. P.O. Box 429, Pryor, OK 74361. 155 Tice Blvd., Woodcliff Lake, NJ 07675. 102 Orange St., Wilmington, NC 28401. 1421 Kalamazoo St, S. Haven, MI 49090. P.O. Box 13745, Philadelphia,

YKK

WestPoint Pepperell, Inc Grifftex Chemical Co. Sib. Westvaco Corp Weyerhauser Co Wheeling-Pittsburgh Steel Corp Whittemore-Wright Co., Inc WiI-Gro Fertilizer, Inc Witco Corp Wright Chemical Corp Wyckoff Chemical Co., Inc Wyeth Laboratories, Inc., Wyeth Ayerst Laboratories Div. of American Home Products Corp. YKK Corp

Westlake Center, 2801 Post Oak Blvd., Houston, TX 77056. 1900 Cunningham Dr., Opelika, AL 36801.

201-935-0003

PAT ZNC

Yorkshire Pat-Chem, Inc. Zeon Chemicals, Inc

1251 Valley Brook Ave., Lyndhurst, NJ 07071. 11 Worley Rd., Greenville, SC 29602. 3 Continental Towers, Suite 1012, 1701 Gulf Road, Rolling Meadows, IL 60008.

USX

WLK WPG WVA WRD WPS WHW CHN WTC WCL WYK WYT

713-960-9111

803-233-3941 708-437-9770

600 Grant St., Pittsburgh, PA 15219. 1 N Broadway, Gary, IN 46402. 520 Broome Rd., Greensboro, NC 27406. 7000 Portage Rd., Kalamazoo, MI 49001. 41 Styles Lane, North Haven, CT 06473. Rt 2, Box 625, Lockport, LA 70374. 530 McCullough, San Antonio, TX 78292. 1 N. Transit Rd., Lockport, NY 14094. 1 N. Transit Rd., Lockport, NY 14094. 31 Taylor Ave., Bethel, CT 06801. and Rt. #2, Box 54, Murray, KY 42071. Main & William Sts., Belleville, NJ 07109. 10400 W. Higgins Rd., Rosemont, IL 60018. 1611 Wheat Rd., Vineland, NJ 08360. 3950 Cumberland Pkwy., Atlanta, GA 30339-4501. 12345 Steele Creek Rd., Charlotte, NC 28273. 200 E. Randolph Dr., Chicago, IL 60601. P.O. Box 530390, Birmingham, AL 35233. Middle Road, Ashtabula, OH 44004. 3301 Sutton Rd., Adrian, MI 49221. 2526 Baldwin St., St. Louis, MO 63106. 155 Helen St., S. Plainfield, NJ 07080. 1040 Broad St., Suite 302, Shrewsbury, NJ 07702. Route 993, Manor, PA 15665.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

A-18

APPENDIX B CYCLIC INTERMEDIATES; GLOSSARY OF SYNONYMOUS NAMES

Appendix B

Table B-1 Cyclic Intermediates: Glossary of synonymous names Common name

Standard (chemical abstracts) name

A acid Acetyl-p-phenylenediamine 1,2,4-acid

3,5-Dihydroxy-2,7-naphthalenedisulfonic acid. 4'-Aminoacetanilide. 4-Amino-3-hydroxy-1-naphthalenesulfonic acid (1-Amino-2-naphthol-4-sulfonic acid).

Acid yellow 9 p-Aminobenzenesulfonic acid m-Aminobenzoyl J acid

6-Amino-3,4'-azodibenzenesulfonic acid. Sulfanilic acid and salt. 4-Hydroxy-7-(m-aminobenzamido)2-naphthalenesulfonic acid.

Aminoepsilon acid Amino G acid Amino J acid Amino R salt Aniline oil Anthraflavic acid Anthrarufin Armstrong & Wynne's acid

8-Amino-1,6-naphthalenedisulfonic acid. 7-Amino-1,3-naphthalenedisulfonic acid. 6-Amino-1,3-naphthalenedisulfonic acid. 3-Amino-2,7-naphthalenedisulfonic acid. Aniline. 2,6-Dihydroxyanthraquinone. 1,5-Dihydroxyanthraquinone. 4-Hydroxy-2-naphthalenesulfonic acid.

B acid

5-Amino-4-hydroxy-1,7-naphthalenedisulfonic acid.

2B acid 4B acid Benzal chloride Benzanthrone Benzotrichloride Bisphenol A B.O.N. Broenner's acid Bromamine acid Bromobenzanthrone

6-Amino-4-chloro-m-toluenesullonic acid. 6-Amino-m-toluenesulfonic acid. a,a-Dichlorotoluene.

7H-Benz[cle]anthracen-7-one.

a,a,a-Ttichlorotoluene.

4,4'-lsopropylidenediphenol. 3-Hydroxy-2-naphthoic acid. 6-Amino-2-naphthalenesulfonic acid. 1-Amino-4-bromo-2-anthraquinonesulfonic acid. 3-Brom0-7H-benz[de]anthracen-7-one.

C acid C.A. acid C-Amine (Lake Red C acid) Cassella acid Chicago Acid (SS acid)

3-Amino-1,5-naphthalenedisulfonic acid. 3-Amino-6-chloro-4-sulfobenzoic acid. 2-Amino-5-chloro-p-toluenesulfonic acid. 5-Hydroxy-1-naphthalenesulfonic acid. 4-Amino-5-hydroxy-1,3-naphthalenedisulfonic acid.

Chlorobenzanthrone Chromotropic acid Chrysazin 1,6-Cleve's acid 1,7-Cleve's acid Crocein acid 2-Cyanopyridine 3-Cyanopyridine Cyanuric chloride

Chloro-7H-benz[de]anthracen-7-one. 4,5-Dihydroxy-2,7-naphthalenedisulfonic acid. 1,8-Dihydnwanthraquinone. 5-Amino-2-naphthalenesulfonic acid. 8-Amino-2-naphthalenesulfonic acid. 7-Hydroxyl-naphthalenesulfonic acid. Picolinonitrile, Nicotinonibile. 2,4,6-Trichloro-s-triazine.

D acid DADI DDB Decacyclene Dehydrothio-p-toluidine Developer Z o-Dianisidine 1,1'-Dianthrirnide Dibenzanthrone Dichlone 4,4'-Dihydrocydiphenylsulfone Dimethyl POPOP 4,5-Dinitrochrysazin Dioxy S acid Diphenyl epsilon acid Durene

6-Amino-1 -naphthalenesulfonic acid. Dianisidine diisocyanate. p-Dibutoxybenzene. Diacenaphtho[1 .2-j:1 ',2'4)fluoranthene. 2-(p-ArninophenyI)-6-:nethylbenzothiazole. 3-Methyl-1 ,,pheny1-2-pyrazolin-5-one. 3 ,3'- DimethOxYbenzidine. 1,1'-lminodianthraquinone. Violanthrone, 2,3-Dichloro-1,4-naphthoquinone. 4,4'-Sulfonyldiphenol. 1,4-Bis[2-(4(4-5-phenyloxazolgbenzene. 1,8-Dihyclroxy-4,5-dinitroanthraquinone. 4,5-Dihydroxy-1-naphthalenesulfonic acid. 6,8-Dianilino-1 -naphthalenesulfonic acid. 1,2,4,5-Tetramethylbenzene.

Epsilon acid (Andresen's acid)

8-Hydroxy-1,6-naphthalenedisulfonic acid.

B-2

Synthetic Organic Chemicals, 1991

Table B-1—Continued Cyclic Intermediates: Glossary of synonymous names Common name

Standard (chemical abstracts) name

F acid Fast Red G base Fast Scarlet R base Fischer's aldehyde Fischer's base Freund's acid

7-Hydroxy-2-naphthalenesulfonic acid. 2-Nitro-p-toluidine [N2=1]. 5-Nitro-o-anisidine [NH2=1]. 1,3,3-Trimethy1-62,a-indolineacetakiehyde. 1,3,3-Trimethy1-2-methyleneindoline. 4-Amino-2,7-naphthalenedisulfonic acid.

G salt Gamma acid

7-Hydroxy-1,3-naphthalenesulfonic acid, sodium salt 6-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodium salt. 9,1 O-Dihydro-9,1 0-dioxo-1 -anthracenesulfonic acid and salt.

Gold salt H acid

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid, (8-Amino-1-naphthol-3,6-disulfonic acid).

Hellimellitene

1,2,3-Trimethylbenzene.

Indoxyl Isodurene

3(2H)-Indolone. 1,2,3,5-Tetramethylbenzene.

J acid J acid urea

7-Amino-4-hydroxy-2-naphthalenesuffonic acid, sodium salt. 7,7'-Ureylenebis[4-hydroxy-2naphthalenesulfonic acid]

K acid Koch's acid

4-Amino-5-hydroxy-1,7-naphthalenedisulfonic acid. 8-Amino-1,3,6-naphthalenetrisulfonic acid.

L acid Lake Red C amine Laurent's acid

5-Hydroxy-1-naphthalenesulfonic acid. 2-Amino-5-chloro-p-toluenesulfonic acid. 5-Amino-l-naphthalenesulfonic acid.

M acid MEP Mesitylene Methane base Michler's hydro! Michler's ketone MOCA MVP

8-Amino-4-hydroxy-2-naphthalenesulfonic acid. 5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine). 1,3,5-Trimethylbenzene. 4,4'-Methylenebis[N,N-dimethylaniline]. 4,4'-Bis[dimethylamino]benzhydrol. 4,4'-Bis[dimethylamino]benzophenone. 3,3'-Dichloro-4,4'-diaminodiphenylmethane. 5-Vinyl-2-picoline.

Naphthionic acid o-Naphthionic acid

4-Amino-1-naphthalenesulfonic acid. 1 -Amino-2-naphthalenesulfonic acid. 2-Naphthol, tech 3-Hydroxy-2-naphthanilide. 1 -Naphthylamine. 4-Hydroxy-1-naphthalenesulfonic acid. 4-Hydroxy-7-(m-nitrobenzamido)-2naphthalenesulfonic acid.

p-Naphthol

Naphthol AS

a-Napthylamine Neville & Winther's acid m-Nitrobenzoyl J acid Oxy Koch's acid

1 -Naphthol-3,6,8-trisulfonic acid.

Pentaanthrimide

1 ,4,5,8-Tetralds(1 -anthraquinonylamino) anthraquinone.

Peri acid Phenylbiphenyl N-Phenyldiethanolamine Phenyl gamma acid Phenyl J acid Phenyl pen acid Picric acid POPOP Pseudocumene Pyrazoleanthrone

8-Amino-1-naphthalenesulfonic acid. Terphenyl. 2,2'-[(Phenyl)imino]diethanol. 6-Anilino-4-hydroxy-2-naphthalenesulfonic acid. 7-Anilino-4-hydroxy-2-naphthalenesulfonic acid. 8-Anilino-1-naphthalenesulfonic acid. 2,4,6-Trinitrophenol. 1,4-Bis[2-(5-phenyloxazolyl)benzene. 1,2,4-Trimethylbenzene. Anthra[1,9-cd]pyrazol-6(2H)-one. B-3

Appendix B

Table B-1—Continued Cyclic intermediates: Glossary of synonymous names Common name Pyrazoleanthrone yellow Pyrazolone T Quinizarin 2-Quinizarinsulfonic acid Quinoline yellow base R salt RG acid (Violet acid) Rhoduline acid (J Acid Imide) RR acid S acid Schaffer's acid Silver salt

Standard (chemical abstracts) name [3,3'-131anthral[1,9-cd]-pyrazole]-6,6'(2H,2'H)dione 5-0xo-1 -(p-suffophenyI)-2-pyrazoline-3carboxylic acid. 1,4-Dihydroxyanthraquinone. 9,10-Dihydro-1,4-dihydroxy-9,10-dioxo-2anthracenesulfonic acid. Quinophthalone. 3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt. 4-Hydroxy-2,7-naphthalenedisulfonic acid. 7,7'-lminobis[4-hydroxy-2-naphthalenesulfonic acid]. 3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid. 4-Amino-5-hydroxy-1-naphthalenesulfonic acid. 6-Hydroxy-2-naphthalenesulfonic acid. 9,10-Dihydro-9,10-dioxo-2-anthrazenesulfonic acid and salt.

Solvent Yellow 1 Solvent Yellow 3 SS acid (Chicago acid)

p-Phenylazoaniline and hydrochloride. 4-(o-Tolylazo)-o-toluidine. 4-Amino-5-hydroxy-1,3-naphthalenedisulfonic acid.

Sulfanilic acid o-Suffobenzaldehyde

p-Aminobenzenesulfonic acid. o-Formylbenzenesulfonic acid.

Tetralin Thiolindoxyl Thiosalicylic acid Tobias acid TODI o-Tolidine a-Toluic acid a Tolunitrile 4-m-Tolylenediamine Trimellitic anhydride Trimethyl base Trinitrophenol

1,2,3,4-Tetrahydronaphthalene. 3(2H)-Thianaphthenone. o-Mercaptobenzoic acid. 2-Amino-1-naphthalenesulfonic acid. Bitolylene diisocyanate. 3,3'-Dimethylbenzidine. Phenylacetic acid. Phenylacetonitrile. Toluene-2,4-diamine. 1,2,4-Benzenetricarboxylic acid, 1,2-anhydride. 1,3,3-Trimethy1-2-methyleneindoline. Picric acid.

Urea J acid (J acid urea)

7,7'Ureylenebis[4-hydroxy -2-naphthalenesulfonic add].

Veratraldehyde Veratrole Vinyltoluene Violet acid (RG acid)

3,4-Dimethoxybenzaldehyde. o-Dimethoxybenzene. ar-Methylstyrene. 4-Hydroxy-2,7-naphthalenedisulfonic acid.

-

B-4

APPENDIX C SYNTHETIC ORGANIC CHEMICALS, U.S. PRODUCTION AND SALES, 1991, HARMONIZED SYSTEM BASIS

Appendix C

Synthetic Organic Chemicals, U.S. Production and Sales, 1991, Harmonized System Basis The following table contains 1991 U.S. production and sales data for synthetic organic chemicals in the 6-digit Harmonized System (HS) format. The Commission decided to compile such data in this format in response to the decision by the U.S. Bureau of the Census to publish Standard Industrial Classification (SIC) data which will be convertible to the HS beginning with the 1987 Census of Manufactures. The U.S. Bureau of the Census has historically referred to the Synthetic Organic Chemicals, United States Production and Sales (SOC) report in the chemicals section of the Census of Manufactures, which permits them to omit collecting synthetic organic chemicals production and shipments data from its respondents. Because of this situation. the SOC data will now also be compiled on an HS basis to provide comparablility with the new SIC format. The table provides production and sales data on a 6-digit HS basis only where publication would not violate the statutory provisions relating to unlawful disclosure of information accepted in confidence by the Commission. It includes only the 6-digit item numbers with publishable data from a number of HS chapters in which these chemicals are classified, but does not provide totals by chapter or overall total figures.

Synthetic Organic Chemicals, 1991

Table C-1 Synthetic organic chemicals: U.S. production and sales, 1991, harmonized system basis HS/

Production

Sales

number Description

Quantity 1,000 Kilograms

Quantity 1,000 Kilograms

499,319 18,123,454 9,774,421 440,829 1,046,505 5,209,209 2,856,521 2,866,253 3,680,516 4,023,827 1,890,456 176,648 228,901 142,944 6,220,003 4,024,514

458,547 6,930,275 5,587,526 201,982 935,618 3706,298 1,441,087 1,235,178 1,634,357 159,941 1,510,477 140,897 214,119 172,911 1,439,902 1,641,925

102,503 2,784,597 2,026,443 83,031 392,215 1,379,618 405,686 326,280 951,662 68,089 682,426 48,679 88,692 25,292 139,592 455,996

151,637 3,948,035

2,494,614

379,606

687,366 598,641 2,181,568 301,902 51,767 132,463 1,631,620

545,758 338,502 2,004,390 243,078 50,335 119,687 889,262

308,439 186,834 925,262 224,420 67,307 105,177 348,059

552,801 221,185

191,341 169,271

200,437 37,266

265,507 2,380,363 3,199,191 870,437 1,064,701 232,761 82,049 462,199

203,944 245,346 1,179,529 31,595 778,430 225,565 79,923 44,718

155,731 237,317 127,319 16,106 397,225 168,574 83,933 43,483

8,803 483,010

10,793 199,868 142,236 82,042 546,959 276,845 18,140 164,942 7,945 115,518 109,964

271113 290121 290122 290123 290211 290220 290230 290244 290250 290260 290270 290312 290313 290314 290315 290321 290361 290511 290512 290513 290531 290532 290542 290544 290711 290723 290941 290943 291010 291211 291213 291411 291412 291413 291422 291441 291521 291522 291524 291531 291532 291533 291534 291611 291731 291732 291735

Butanes, liquefied Ethylene Propene (Propylene) Butene (Butylene) and isomers thereof Cyclohexane Benzene Toluene Mixed xylene isomers Styrene Ethylbenzene Cumene Dichloromethane (Methylene chloride) Chloroform (Trichloromethane) Carbon tetrachloride 1,2-Dichloroethane (Ethylene dichloride) Vinyl chloride (Chloroethylene) Chlorobenzene, o-dichlorobenzene, and p-dichlorobenzene Methanol (Methyl alcohol) Propan-1-ol (Propyl alcohol) and propan-2-ol (Isopropyl alcohol) Butan-1-ol (n-Butyl alcohol) Ethylene glycol (Ethanediol) Propylene glycol (Propane-1,2-diol) Pentaerythritol D-glucitol (Sorbitol) Phenol (Hydroxybenzene) and its salts 4,4'-lsopropylidenediphenol (Bisphenol A, Diphenylolpropane) and its salts 2,2'-Oxydiethanol (Diethylene glycol, Digol) Monobutyl ethers of ethylene glycol or of diethylene glycol Oxirane (Ethylene oxide) Methanal (Formaldehyde) Butanal (Butyraldehyde, normal isomer) Acetone Butanone (Methyl ethyl ketone) 4-Methylpentan-2-one (Methyl isobutyl ketone) Cyclohexanone and methylcyclohexanones 4-Hydroxy-4-methylpentan-2-one (Diacetone alcohol) Acetic acid Sodium acetate Acetic anhydride Ethyl acetate Vinyl acetate n-Butyl acetate Isobutyl acetate Acrylic acid and its salts Dibutyl orthophthalates Dioctyl orthophthalates Phthalic anhydride

1,639,897 20,014 117,811 1,239,389 167,956 25,780 511,976 8,506 122,510 266,277

154,145 108,634 973,470 95,600 24,825 146,457 6,450 125,206 165,764

Value 1,000 Dollars

C-3

Appendix C

Table C-1-Continued Synthetic organic chemicals: U.S. production and sales, 1991, harmonized system basis HS/

Production

Sales

number Description

Quantity 1,000 Kilograms

Quantity 1,000 Kilograms

292141 Aniline and its salts 293211 Tetrahydrofuran 293371 Caprolactam 310210 Urea, whether or not in aqueous solution 320411 Disperse dyes and preparations based thereon 320413 Basic dyes and preparations based thereon 320414 Direct dyes and preparations based thereon 320417 Pigments and preparations based thereon 390110 Polyethylene having a specific gravity of less than 0.94 390120 Polyethylene having a specific gravity of 0.94 or more 390130 Ethylene-vinyl acetate copolymers 390210 Polypropylene 390311 Polystyrene, expandable 390319 Polystyrene, other than expandable 390330 Acrylonitrile-butadiene-styrene (ABS) copolymers . 390421 Polyvinyl chloride, mixed with other substances, nonplasticized 390519 Polymers of vinyl acetate, other than in aqueous dispersion 390610 Polymethyl methacrylate 390730 Epoxide resins 390750 Alkyd resins 390760 Polyethylene terephthalate 390920 Melamine resins 390950 Polyurethanes 400219 Styrene-butadiene rubber (SBR) 400270 Ethylene-propylene-nonconjugated diene rubber (EPDM)

436,021 96,584 582,214 5,448,685 20,363 3,983 18,454 51,311

285,682 48,742 147,828 5,053,437 20,311 3,862 17,866 39,426

181,834 96,027 216,811 764,161 113,040 55,394 138,724 643,561

5,236,044 3,850,976 242,056 2,664,063 313,902 1,875,849 487,596

5,193,088 3,881,484 226,710 2,403,391 229,074 1,669,304 439,396

3,964,623 2,949,937 239,170 1,792,668 251,565 1,632,076 858,733

3,455,220

3,273,328

2,361,277

243,905 280,833 375,498 355,636 1,441,972 115,523 95,127 763,542 206,045

191,918 177,086 249,950 279,546 971,425 95,238 80,577 464,090 193,659

314,197 413,862 731,936 334,921 1,496,722 223,990 323,700 418,066 394,272

C-4

Value 1,000 Dollars

APPENDIX D ALPHABETICAL CHEMICAL INDEX

Appendix D

Alphabetical Chemical Index The alphabetical index of chemicals contained in this appendix table is an outgrowth of the processing of data by the U S International Trade Commission for its annual report, Synthetic Organic Chemicals, United States Production and Sales. This index will aid those who have an interest in the report, either as users of the published data or as suppliers of individual company data to the Commission, principally by showing the section number and line item number of specific chemicals. This information can be used to assist in locating a chemical in the report and to provide respondents to the Commission's questionnaire with information on where to list their production and sales data. The index shows only those chemicals for which production or sales were reported to the Commission for this edition of the report. The index, initially designed for Commission use in computer processing of data for the annual report, has certain characteristics that should be noted to increase its usefulness. For example. superior headings for individual entries are not shown in the index. Thus, understanding the contents of the first item in the index, "accelerators, activators, and vulcanizing agents, acyclic, other," necessitates that the index user turn to the individual section (in the report) and item number (in the questionnaire) to find those acyclic accelerators, activators, and vulcanizing agents already specified. Similarly, the index entry "specific gravity 0.940 and below" does not by itself identify the chemical product. The index user will need to turn to the indicated section number and item number to determine the chemical referred to—in this case, polyethylene. The chemical names used in this report and in the questionnaires sent to U.S. producers to obtain the data aggregated in the report are listed alphabetically in the first column of each listing in the index The second column refers to the section in the report and questionnaire containing the chemical, and the third column shows the appropriate item number in that section in the questionnaire.

• Synthetic Organic Chemicals, 1991

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D-15





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D-17





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Appendix D

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D-34

• Synthetic Organic Chemicals, 1991

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D-35

Appendix D

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D-41

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D-42

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• Synthetic Organic Chemicals, 1991

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D-43



••



Appendix D

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D-45

• Appendix D

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D-47

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• Appendix D

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D-49

Appendix D

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D-51

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Synthetic Organic Chemicals, 1991

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D-57





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synthetic organic chemicals - USITC

United States International Trade Commission SYNTHETIC ORGANIC CHEMICALS United States Production and Sales, 1991 USITC PUBLICATION 2607 February 199...

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