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SYNTHETIC ORGANIC CHEMICALS

United States Production and Sales, 1987

(Investigation No. 332-135)

USITC PUBLICATION 2118 SEPTEMBER 1988

United States International Trade Commission • Washington, DC 20436

RECENT REPORTS OF THE UNITED STATES INTERNATIONAL TRADE COMMISSION ON SYNTHETIC ORGANIC CHEMICALS

1 Synthetic

Organic Chemicals, United States Production and Sales, 1980 (USITC Publication 1183, 1981), $9.00 1 Synthetic Organic Chemicals, United States Production and Sales, 1981 (USITC Publication 1292, 1982), $8.50 1 Synthetic Organic Chemicals, United States Production and Sales, 1982 (USITC Publication 1422, 1983), $7.50 1 Synthetic Organic Chemicals, United States Production and Sales, 1983 (USITC Publication 1588, 1984), $9.50 1 Synthetic Organic Chemicals, United States Production and Sales, 1984 (USITC Publication 1745, 1985), $12.00 2 Synthetic Organic Chemicals, United States Production and Sales, 1985 (USITC Publication 1892, 1986), $19.00 2 Synthetic Organic Chemicals, United States Production and Sales, 1986 (USITC Publication 2009, 1987), $16.00

1 Report is out of print. 2 Report may be purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington,

DC 20402. All U.S. International Trade Commission reports produced by the Government Printing Office may be consulted in offical depository libraries throughout the United States.

UNITED STATES INTERNATIONAL TRADE COMMISSION

SYNTHETIC ORGANIC CHEMICALS United States Production and Sales, 1987

U.S. Government Printing Office Washington, 1987 USITC Publication 2118

For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, DC 20402

UNITED STATES INTERNATIONAL TRADE COMMISSION

COMMISSIONERS Anne E. Brunsdale, Acting Chairman Alfred E. Eckes Seeley G. Lodwick Susan Liebeler David B. Rohr Ronald A. Cass

Office of Industries Erland Heginbotham, Director

This report was prepared principally by Cynthia B. Foreso, Jesse Lawrence Johnson, Dr. Aimison Jonnard, Eric Land, Edward Matusik, David Michels, Elizabeth R. Nesbitt, James Raftery, Edward J. Taylor, Cynthia Trainor, and Steve Wanser. Assistance in the preparation of the report was provided by Kenneth R. Kozel, Gwen L. Bennett, Brenda Carroll, Sharon Greenfield, Chris Romett, Lemuel Shields, and Wanda Tolson. Automatic Data Processing input was provided by Barbara Bobbitt, James Gill, and Marie Jagannathan. Electronic publishing and design was provided by Pamela Chase, Joyce Bookman, Betsy Davis-Nichols and Fredericka Ross.

Address all communications to Kenneth R. Mason, Secretary to the Commission United States International Trade Commission Washington, DC 20436

Synthetic Organic Chemicals, 1987

CONTENTS Page Introduction

1

Summary

3

General

5

Sections 1.

Coal tar, tar crudes and pitches

1-1

2.

Primary products from petroleum and natural gas for chemical conversion

2-1

3 Cyclic intermediates

3-1

4.

Dyes

4-1

5.

Organic pigments

5-1

6. 7.

Medicinal chemicals

6-1

Flavor and perfume materials

8.

Plastics and resin materials

7-1 8-1

9. Rubber-processing chemicals 10. Elastomers

10-1

11. Plasticizers

11-1

12. Surface-active agents 13. Pesticides and related products

12-1

14. Miscellaneous end-use chemicals and chemical production 15. Miscellaneous cyclic and acyclic chemicals

9-1

13—i 14-1 15—i

Appendixes A.

Directory of manufacturers

A-1

B.

Cyclic intermediates: Glossary of synonymous names

B-1

C.

U.S. production and sales, 1985 harmonized system basic

C-1

D. Alphabetical chemical index

D-1

III

iii

Synthetic Organic Chemicals, 1987

Introduction This is the 71st annual report of the U.S. International Trade Commission on domestic production and sales of synthetic organic chemicals and the raw materials from which they are made. The report, along with the quarterly report titled Preliminary Report on U.S.

Production of Selected Synthetic Organic Chemicals (Including Synthetic Plastics and Resin Materials), is prepared under investigation No. 332-135, Synthetic Organic Chemicals Reports. This investigation is conducted under the authority of section 332(g) of the Tariff Act of 1930 (19 U.S.C. 1322(g)), for the purpose of collecting data and preparing public reports on synthetic organic chemicals, plastics materials, medicinal chemicals, pesticides, and other organic chemical products. The annual report consists of 15 sections, each covering a specified group (based principally on use) of organic chemicals as follows: Coal tar, tar crudes and pitches; primary products from petroleum and natural gas for chemical conversion; cyclic intermediates; dyes; organic pigments; medicinal chemicals; flavor and perfume materials; plastics and resin materials; rubber-processing chemicals; elastomers; plasticizers; surface-active agents; pesticides and related products; miscellaneous end-use chemicals and chemical products; and miscellaneous cyclic and acyclic chemicals. Data have been supplied by approximately 742 producers. Each of the 15 sections is headed by a summary of the statistical data. The first table in each section gives statistics on products and groups of products in as great detail as is possible without revealing the operations of individual producers. Statistics for an individual chemical or group of chemicals are given only when there are three or more producers, no one or two of which may be predominant. Moreover, even when there are three or more producers, statistics are not given if there is any possibility that their publication would violate the statutory provisions relating to unlawful disclosure of information accepted in confidence by the Commission. 1 Data are reported by producers for only those items where the volume of production or sales or value of sales exceeds certain minimums. Those minimums for all sections are 5,000 pounds of production or sales or $5,000 of value of sales with the following exceptions: Plastics and resin materials-50,000 pounds or $50,000; pigments, medicinal chemicals, flavor and perfume materials, and rubber-processing chemicals1,000 pounds or $1,000. They are usually given in terms of undiluted materials; however, products of 95 percent or greater purity are considered to be 100 percent pure. Commercial concentrations are applicable for dyes, certain plastics and resins, and a few solvents; such concentrations are specifically noted. 18 U.S.C. u 1905 and 44 U.S.C. u 3508.

The statistics given in this report include data from all known domestic producers of the items covered and include the total output of each company's plants, i.e., the quantities produced for consumption within the producing plant, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, therefore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to changes in inventory. The second table in each section lists all items for which data on production or sales have been reported, by primary manufacturers, identified by manufacturers' codes. Each code consists of not more than three capital letters and is assigned on a permanent basis. The third table in each section is a directory, alphabetized by the codes of the manufacturers reporting in that section. Appendix A is a directory, alphabetized by the names of the manufacturers reporting in all sections and which includes their general corporate phone numbers and office addresses. Appendix B lists synonymous names for cyclic intermediates. Information on synonymous names of the organic chemicals included in this report may be found in the SOCMA Handbook: Commercial Organic Chemical Names, published by the Chemical Abstracts Service of the American Chemical Society, or the Colour Index (Revised Third Edition), published jointly by the Society of Dyes and Colourists and the American Association of Textile Chemists and Colorists. Appendix C presents the data in this report aggregated in the format of the Harmonized System (HS) nomenclature on a 6-digit HS basis. Appendix D is an alphabetical index of all the products in this edition of the report. Data contained in this report are compiled primarily from Commission's questionnaires sent to domestic producers and represent the best data available to the Commission. While the data supplied in the questionnaires are checked against data previously supplied by the submitting firm and with data supplied by other domestic producers, data are not independently verified by direct Commission examination of the books of companies furnishing information. Data contained in this report should not be used for investment and other purposes without independent verification. As specified in the reporting instructions sent to manufacturers, production and sales (unless otherwise specified) are defined as follows: PRODUCTION is the total quantity of a commodity made available by Original Manufacturers Only within the customs territory of the United States (includes the 50 states, the District of Columbia, and Puerto Rico). It covers synthetic organic chemicals, specified crudes from petroleum and coal tar, and certain chemically described natural 1 products, such as, alkaloids, enzymes, and 1

Introduction perfume isolates. It is the sum—expressed in terms of 100% active ingredient unless otherwise specified in the reporting instructions—of the quantities: Produced, separated, and consumed in the same plant or establishment. A Commodity is considered separated either when it is isolated from the reactive system or when it is not isolated, but weighed, analyzed, or otherwise measured. This includes by-products and co-products that are not classifiable as waste materials; Produced and not isolated, but directly converted to a finished or semifinished item not included in this report (e.g., polyester film, polyurethane tires, nylon fiber, bar soap, etc.). (See specific instructions in individual sections); Produced and transferred to other plants or establishments of the same firm or 100% owned subsidiaries or affiliates; Produced and sold to, or bartered with, other firms (including less than 100% owned subsidiaries); Produced for others under toll agreements (see general instructions); Produced and held in stock. PRODUCTION EXCLUDES: Purification of a commodity, which is purchased by, or transferred from within, the company, unless inclusion of such processing is specifically requested in the reporting instructions for individual sections; Intermediate products which are formed in the manufacturing process, but are not isolated from the reaction system—that

is, not weighed, analyzed, or otherwise measured; except such products as described above as being produced and not isolated, but directly converted to a finished or semifinsihed item. Materials that are used in the process but which are recovered for re-use or sale; Waste products having no economic significance. SALES are actual quantities of commodities sold by Original Manufacturers Only. Sales include the quantity and value of: Shipments of a commodity for domestic use or for export, or segregation in a warehouse when title has passed to the purchaser in a bona fide sale; Shipments of a commodity produced for you by others under toll agreement; Shipments to subsidiary or affiliated companies, provided the ownership is less than 100%. SALES EXCLUDE: All intra-company transfers within a corporate entity; All shipments to 100% owned subsidiary or affiliated companies; All resales of imported or purchased material, including materials obtained by barter; All shipments of commodity produced for others under toll agreements. VALUE OF SALES is the net dollar receipts of sales f.o.b. plant or warehouse, or delivered. F.o.b. values are preferred, but if they are not readily available form your records, delivered values are acceptable.

2

2

Synthetic Organic Chemicals, 1987

Summary Combined production of all synthetic organic chemicals and primary products from petroleum and natural gas in 1987 was 378,465 million pounds-an increase of 7.9 percent from the output in 1986 (which also included data on tars) (table 1). Sales of these materials in 1987, which totaled 206,049 million pounds, valued at $74,012 million, were 11.7 percent larger than in 1986 in terms of quantity and 13.0 percent more in terms of value. These figures include data on production and sales of chemicals measured at several successive steps in the manufacturing process, and, therefore, they necessarily reflect some duplication. During 1983-87, the total output of these products rose each year except for 1985 (figure 1). During that period the output of these products generally followed the trend of the Federal Reserve Board Index of U.S. Production. In 1987, production of all synthetic organic chemicals, including cyclic intermediates and finished products totaled 253,055 million pounds, or 7.6 percent more than the output in 1986. Ten

sections showed an increase in production in 1987 over 1986. Rubber-processing chemicals (382 million pounds) increased by 17.9 percent; plasticizers (1,998 million pounds) increased by 16.0 percent; elastomers (synthetic rubber) (4,690 million pounds) increased by 14.9 percent; plastics and resin materials (59,481 million pounds) increased by 13.4 percent; cyclic intermediates (55,196 million pounds) increased by 10.0 percent; miscellaneous end-use chemicals and chemical products (25,223 million pounds) increased by 9.5 percent; dyes (255 million pounds) increased by 8.3 percent, surface-active agents (6,269 million pounds) increased by 6.3 percent; organic pigments (94 million pounds) increased by 6.1 percent; miscellaneous cyclic and acyclic chemicals (98,040 million pounds) increased by 2.5 percent; of the remaining sections, pesticides and related products (1,040 million pounds) showed a decreased of 11.9 percent; flavor and perfume materials (126 million pounds) decreased 9.7 percent and medicinal chemicals (261 million pounds) also decreased 1.3 percent in 1987 from that in 1986.

Table 1 Synthetic organic chemicals and their raw materials U.S.production and sales, 1986 and 19867 Sales Production

Chemical

Grand total

Quantity

1986

1987

Million pounds

Million pounds

Increase or decrease (-), 1987 over 1986 1 or Percent

Value

1986

1987

Million pounds

Million pounds

Increase or decrease (-),1987 over 1986 1

1986

1987

Percent

Million dollars

Million dollars

11.7

65,486

74,012

Increase or decrease (-),1987 over 1986' Percent

350,859

378,465

7.9

Tars 2,046 Primary products from petroleum and natural gas 113,545 Synthetic organic chemicals, total2 235,267

2,291

12.0

(3)

(3)

(3)

(3)

(3)

123,119

8.4

53,035

59,677

12.5

6,020

7,620

26.6

253,055

7.6

131,419 146,371

11.4

59,466

66,392

11.6

Cyclic intermediates Dyes Organic pigments Medicinal chemicals Flavor and perfume materials Plastics and resin materials Rubber-processing chemicals Elastomer (synthetic rubber) Plasticizers Surface-active agents Pesticides and related product Miscellaneous end-use chemicals and chemical products Miscellaneous cyclic and acyclic chemicals

184,454 206,049

13.0 ( 3)

50,193 236 89 264

55,196 10.0 255 8.3 94 6.1 261 -1.3

22,333 226 77 158

23,206 230 83 167

3.9 1.8 8.6 5.1

7,150 652 513 1,518

7,562 677 586 1,534

5.8 3.9 14.3 1.1

138

126 -8.7

96

81

-15.5

623

726

16.5

13.4

45,144

51,170

13.3

20,355

26,066

28.1

324

382 17.9

235

289

22.8

297

359

21.1

4,081 1,722 5,895

4,690 14.9 1,998 16.0 6,269 6.3

2,489 1,624 3,567

3,109 1,876 3,923

24.9 15.5 10.0

2,213 765 1,606

2,714 896 1,713

22.7 7.1 6.6

1,180

1,040-11.9

940

911

-3.2

4,234

4,171

-1.5

7,355 -15.8

52,447

59,481

23,033

25,223

9.5

16,600

21,010

26.6

8,731

95,666

98,040

2.5

37,930

40,317

6.3

10,809

12,032

11.3

Percentage calculated from figures rounded to thousands. 2 Because of rounding, figures may not add to the totals shown. 3 Not available 1

3

Source: Compiled from data received in response to questionnaire of the U.S. International Trade Commission.

3

Summary Figure 1 Synthetic organic chemicals and their raw materials, total, vs FRB index

Billions of pounds

500 450 400 350 300 250 200 150 100 50

1983

1984

1985

1986

1987

Source: Production, U.S. International Trade Commission, Synthetic Organic Chemicals: United States Production and Sales; FRB index, The Board of Governors of the Federal Reserve System.



4

4

Synthetic Organic Chemicals, 1987

General In this report, synthetic organic chemicals are classified on the basis of their principal use as follows: Cyclic intermediates, dyes, organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic rubber), plasticizers, surface-active agents, pesticides and related products, miscellaneous end-use chemicals and chemical products, and miscellaneous cyclic and acyclic chemicals. Most of these groups are further subdivided either by use or by chemical composition. As intermediates, chemicals are used in the manufacture of finished products, aggregate figures that cover both intermediates and finished products necessarily include considerable duplication. Total production of synthetic organic chemicals (intermediates and finished products combined) in 1987 was 253,055 million pounds, or 7.6 percent more than the output of 235,267 million pounds reported for 1986, and 141.7 percent more than the output of 104,711 million pounds reported in 1967 (see table 2). Sales of synthetic organic chemicals in 1987 amounted to

146,371 million pounds, valued at $66,392 million, compared with 131,419 million pounds, valued at $59,466 million, in 1986, and 55,177 million pounds, valued at $10,438 million, in 1967. Production of all cyclic (ring chemical structure) products (intermediates and finished products combined) in 1987 totaled 84,979 million pounds, or 9.4 percent more than the 77,674 million pounds reported for 1986, and 172.5 percent more than the 31,182 million pounds reported for 1967; however, the transfer of eight items, in 1979, from the primary products from petroleum and natural gas section to the section on cyclic intermediates has caused the output of cyclic products to appear much higher in relation to 1967 than would otherwise have resulted. Production of all acyclic (linear or branch chemical structure) products in 1987 totaled 163,386 million pounds, or 6.5 percent more than the 153,462 million pounds reported for 1986, and 134.4 percent more than the 69,707 million pounds reported for 1967. Differences in trends between cyclic and acylic products reflect the aggregation of changes in usage of individual chemicals rather than preferences for cyclic versus acyclic chemcials.

Table 2 Synthetic organic chemicals summary of U.S. production and sales of intermediates and finished products, 1967, 1986, and 1987 (Production and sales in thousands of pounds; sales value in thousands of dollars) Increase or decrease (-) Chemical Organic chemicals, cyclic and acyclic, grand total: Production Sales Sales value Cyclic, total: 2 Production Sales Sales value Acyclic, total: 2 Production Sales Sales value 1. Cyclic Intermediates Production Sales Sales value 2. Dyes Production Sales Sales value 3. Organic Pigments Production Sales Sales value 4. Medicinal Chemicals Cyclic: Production Sales Sales value Acyclic Production Sales Sales value

1987 over 1967

1987 over 1986

253,055,030 146,371,462 66,391,979

141.7 165.3 536.0

7.6 11.4 11.6

77,674,272 43,071,693 27,923,080

84,979,001 46,129,029 31,158,174

172.5 165.3 647.1

9.4 7.1 11.6

69,706,980 34,526,250 5,393,503

153,462,151 85,858,812 29,329,973

163,385,671 97,133,672 32,519,757

134.4 181.3 502.9

6.5 13.1 10.9

20,793,132 9,461,180 1,000,359

50,192,839 22,332,679 7,150,386

55,196,139 23,205,872 7,562,427

165.5 145.3 656.0

10.0 3.9 5.8

206,240 198,592 332,049

235,547 225,695 651,804

255,198 229,763 677,424

23.7 15.7 104.0

8.3 1.8 3.9

53,322 42,867 108,354

88,521 76,711 513,132

93,915 83,302 586,254

76.1 94.3 441.1

6.1 8.6 14.3

110,129 70,120 348,873

207,619 106,195• 1,364,394

196,029 103,833 1,364,930

78.0 48.1 291.2

-5.6 -2.2 .1

69,941 56,804 36,402

56,442 52,253 153,136

64,588 62,668 169,196

-7.7 10.3 364.8

14.4 19.9 10.5

19671

1986

104,711,357 55,176,823 10,438,453

235,267,490 131,419,041 59,465,667

31,181,832 17,388,529 4,170,713

1987

5

See notes at end of table.

5

General Table 2-Continued Synthetic organic chemicals summary of U.S. production and sales of intermediates and finished products, 1967, 1986, and 1987

(Production and sales in thousands of pounds; sales value in thousands of dollars) Increase or decrease (-) Chemical

19671

1986

1987 over 1967

1987

1987 over 1986

5. Flavors and Perfume Materials

Cyclic: Production Sales Sales value Acyclic: Production Sales Sales value 6.

-16.6 -22.3 14.2

53,558 49,311 40,495

53,312 24,108 56,502

55,414 25,225 79,081

3.5 -48.8 95.3

3.9 4.6 40.0

5,033,497 4,224,121 1,036,940

15,576,662 13,182,073 8,264,044

17,665,771 14,941,653 10,582,852

251.0 253.7 920.6

13.4 13.3 28.1

8,759,452 7,753,242 1,635,690

36,870,013 31,962,014 12,090,744

41,814,939 36,228,390 15,483,286

377.4 367.3 846.6

13.4 13.3 28.1

220,139 169,970 116,318

296,853 210,539 273,380

354,372 262,853 336,204

61.0 54.6 189.0

19.4 24.8 23.0

43,994 30,878 15,477

27,257 24,727 23,170

27,642 25,978 22,783

-37.2 -15.9 47.2

1.4 5.1 -1.7

3,822,545 3,262,044 874,237

4,081,067 2,488,536 2,212,614

4,690,358 3,108,761 2,714,048

22.7 -4.7 210.4

14.9 24.9 22.7

929,871 865,084 167,827

1,312,105 1,245,349 516,501

1,455,074 1,451,905 627,675

56.5 67.8 274.0

10.9 16.6 21.5

332,908 296,767 93,142

410,021 378,821 248,286

543,421 423,667 267,991

63.2 42.8 187.7

32.5 11.8 7.9

1,418,444 852,238 95,810

2,567,382 1,864,282 567,806

2,646,680 1,991,374 595,083

(4) (4) (4)

3.1 6.8 4.8

2,060,851 897,786 220,877

3,327,999 1,702,727 1,038,354

3,621,853 1,931,643 1,117,633

(4) (4) (4)

8.8 13.4 7.6

823,158 681,532 627,742

862,184 692,262 2,964,065

647,516 592,839 2,828,226

-21.3 -13.0 350.5

-24.9 -14.4 -4.6

226,505 215,831 159,301

317,858 248,076 1,269,605

392,021 317,756 1,342,357

73.1 47.2 742.7

23.3 28.1 5.7

(1,535,922) (775,540) (283,575)

3,534,252 1,897,205 4,050,468

3,510,100 1,904,165 3,952,458

(5) (5) (5)

-0.7 6 0.4 -2.4

Surface-Active Agents

Cyclic: 3 Production Sales Sales value Acyclic: Production Sales Sales value 11. Pesticides and Related Products Cyclic: Production Sales Sales value Acyclic: Production Sales Sale value 12. Miscellaneous End-Use Chemicals and Chemical Product Cyclic: Production Sales Sales value

See notes at end of table.

6

22.0 18.9 1124.3

Elastomers (Synthetic Rubber)

Production Sales Sales value 9. Plasticizers Cyclic: Production Sales Sales value Acyclic: Production Sales Sales value 10.

70,740 56,239 647,255

Rubber-Processing Chemicals

Cyclic: Production Sales Sales value Acyclic Production Sales Sales value 8.

84,818 72,335 566,944

Plastics and Resin Materials

Cyclic: Production Sales Sales value Acyclic: Production Sales Sales value 7.

57,978 47,285 52,866

Synthetic Organic Chemicals, 1987 Table 2—Continued Synthetic organic chemicals summary of U.S. production and sales of intermediates and finished products, 1967, 1986, and 1987 (Production and sales In thousands of pounds; sales value in thousands of dollars) Increase or decrease (-) Chemical

1967'

1986

1987

1987 over 1967

1987 over 1986

12. Miscellaneous End-Use Chemicals and Chemical Product —Continued

Acyclic: Production Sales Sales value 13. Miscellaneous Cyclic and

(58,159,771) (25,225,631) (3,192,119)

19,499,122 14,702,583 4,680,944

21,713,001 19,106,276 3,402,665

( 5) ( 5) (5)

11.4 30.0 -27.3

(5) (5)

2,715,490 1,166,368 1,040,156

2,887,467 1,305,231 1,397,386

(5) (5)

6.3 11.9 34.3

92,950,127 36,763,503 9,769,232

95,152,792 39,012,069 10,634,765

(5) (5) ( 5)

2.4 6.1 8.9

Acyclic Chemicals

Cyclic: Production Sales Sales value Acyclic: Production Sales Sales value

(5)

(5) (5)

(5)

(5) Standard reference base period for Federal Government general-purpose index numbers. 2 Does not include data for elastomers. 3 Includes ligninsulfonates. 4 The data for 1967 are not comparable with current data as a result of a change in accounting procedures. 5 Items in these two sections were previously included in the section named miscellaneous chemicals. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

The following tabulation shows, by chemical groups, the number of companies that reported production in 1987 of one or more of the chemicals included in each group. Chemical group

Number of companies

Cyclic intermediates Dyes Organic pigments Medicinal chemicals Flavor and perfume materials Plastics and resins materials Rubber-processing chemicals

177 36 32 85 33 261 25

Chemical group

Elastomers (synthetic rubber) Plasticizers Surface-active agents Pesticides and related products Miscellaneous end-use chemicals and chemicals products Miscellaneous cyclic and acyclic chemicals

Number of companies

32 45 164 74 164 266

7

7

8

Synthetic Organic Chemicals, 1987

Section 1 Coal Tar, Tar Crudes and Pitches Coal tar is produced chiefly by the steel industry as a by-product of the manufacture of coke; water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas tars have properties intermediate between those of petroleum asphalts and coal tar. Petroleum asphalts are not usually considered to be raw materials for chemicals. The U.S. International Trade Commission began collecting data on crude coal tar for the 1986 reporting year. In 1987, U.S. production of crude coal tar was 189 million gallons and crude light oil amounted to 66 million gallons. Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and oil-gas tar. The most important tar crudes are benzene, toluene, xylene, creosote oil, and pitch of tar.

Some of these products are identical with those obtained from petroleum. Data for materials obtained from petroleum are included, for the most part, with the statistics for like materials obtained from coke-oven gas and tars, and are shown in table 3. The domestic production by coke-oven operators of industrial and specification grades of benzene and xylene cannot be published since to do so would disclose the operations of individual companies. Some of the products obtained from tar and included in the statistics in table 3 are obtained from other products for which data are also included in the table. The statistics, therefore, involve considerable duplication, and for this reason no group totals or grand totals are given. Table 4 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 5. Data for 1987 tar crudes were supplied by 28 companies and company divisions.

Cynthia B. Foreso 202-252-1348

Figure 2 Coal tar and tar crudes: U.S. production, 1983-87

Millions of gallons 360 320 280 240 200 160 120 -r 80 40

1983

1984

1985

1986

1987

Note.—Data for 1985 are not available.

1-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

1-1

Section 1 Table 3 Coal tar, tar crudes and pitches: U.S. production and sales, 1987

Coal tar, tar crudes and pitches

Unit of Quantity

Production

Sales Quantity

Average Unit value'

Value 1,000 dollars

Crude coal tar: Coke-oven operators Crude light oil: Coke-oven operators Light-oil distillates: Benzene, all grades, total 2 Coke-oven operators Petroleum refinery' Toluene, all grades, total 2 Coke-oven operator Petroleum refiners 5 Xylene, all grades, total 2 Coke-oven operators Petroleum refiners', Creosote oil (Dead oil) (100% creosote basis): Distillate as such (100% creosote basis) Creosote in coal tar solution (100% solution basis) Pitch of tar: Hard Medium

1,000 gal

188,504

165,422

71,489

$0.43

1,000 gal

66,066

65,852

44,034

.67

1,000 ga 1,000 ga 1 ,000 ga 1,000 ga 1,000 ga 1,000 ga 1,000 ga 1,000 ga 1,000 ga

(3) (3) 1,575,522

(3 ) (3 ) (3 )

(3) (3)

(3) (3)

(3)

(3)

(3)

(3)

(3)

(3)

(3)

(3)

( 3)

(3)

966,692 (3) (3) 649,428

(3) (3) (3) 391,641

( 3) (3) (3) 319,152

(3) (3) (3) .82

1,000 gal

47,331

32,685

22,282

.68

1,000 gal

(3)

34,285

19,748

.58

493

459 652

100,519 31,103

218.88 47.72

1,000 tons 1,000 tons

(3)

Unit value per gallon or ton as specified. Includes data for material produced for use in blending motor fuels. The annual production statistics for petroleum refiners on benzene, toluene, and xylene are not comparable with the combined monthly production figures because of fiscal year revisions. 3 Statistics cannot be published; to do so would disclose the operations of individual companies. 4 Benzene, all grades. 5 Toluene, all grades. Mixed xylenes, high purity (98-100%).

2

Note 1.-Statistics for materials produced In tar and petroleum refineries are compiled by the U.S. International Trade Commission. Note 2.-Data for all other tars and tar crudes are not included in the 1987 report because publication would disclose the operations of individual companies. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

1-2

1 2 -

Synthetic Organic Chemicals, 1987 Table 4 Coal tar, tar crudes and pitches for which U.S. production and/or sales were reported, Identified by manufacturer, 1987

Coal tar, tar crudes and pitches

Separate statistics

Manufacturers' identification codes (according to list in table 5)

Yes

Yes

ABP, ALS, ART, CDT, CGU, DTR, EKO, GSS, ILI, INL, LTV, NBC, SGO, TWD, WPS. ABP, ALS, ART, BTS, CGU, GSS, IGC, ILI, INL, LTV, NBC, NTS, SGO, TWD, WPS.

No

ART, KPT, NTS.

No

ART.

No

LYP.

No No

KPT. BTS, GSS.

No

ACS, KPT.

No

ACS, KPT.

No

KPT.

No

RIL.

Yes

ACS, ART, KPT, RIL.

Yes

ACS, ART, COP, KPT, RIL.

No No No No

ACS. KPT. BTS, KPT. GIV.

No

ACS, RIL.

No No

BTS, IGC. ACS, KPT, RIL.

Light oil, light oil distillates, and tar bases: Crude coal tar

Crude light oil

Pyridine, tar bases: Benzene (Benzol): Tar bases: crude bases (dry basis) Xylene (Xylol): Xylene (Xyloi): 90-100% All other: All other light-oil distillates Other tar distillates: Naphthalene, crude: Methylnaphthalene Naphthalene, crude, solidifying at less than 74° C Naphthalene, crude, solidifying at 76° C to less than 79° C Crude tar acid oils: Crude tar acid oils having a tar acid content of 5 percent to less than 24 percent Cresylic acid crude: Sodium cresylate Creosote oil (Dead oil): Creosote oil (Dead oil): creosote content in solution (100 percent basis) Creosote oil (Dead oil): creosote in coal tar solution (100 percent solution basis) Creosote oil (Dead oil): distillate as such (100 percent creosote basis) All other distillate products: Carbon black oil Crude coal tar solvent Priming and refractory oil All other tar distillates Tar and tar pitches: Tar, road: Tar, road Tar for other uses: Tar for other uses: crude Tar for other uses: refined Pitch of tar: Pitch of tar: hard (M.P. 161° F and Over) Pitch of tar: medium (M.P. 110° To 160° F) Pitch of tar: soft (M.P. 80° To 109° F) All other: All other pitch of tar

Yes Yes No No

ACS, KPT, RIL. ART, COP, KPT, RIL. ART. WPS.

' Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted In confidence and may not be published are Indicated by "No." The manufacturer did not consent to his identification with the disignated products.

2

Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

1-3

1-3

Section 1 Table 5 Coal tar, tar crudes and pitches:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ABP ACS

Drummond Co. Inc Allied Signal, Inc Engineered Materials Sector Armco, Inc Eastern Steel Div. Aristech Chemical Corp.: Clairton Plant Gary Works Bethlehem Steel Corp. Carondelet Coke Corp. Citizen Gas And Coke Utility Coopers Creek Chemical Corp. Detroit Coke Corp. Empire Coke Co.

GIV GSS IGC ILI INL KPT LTV LYP NBC NTS RIL SGO TWD WPS

Givaudan Corp. Gulf States Steel Indiana Gas & Chemical Corp. Acme Steel Corp. Inland Steel Co. Koppers Co., Inc. LTV Steel Co. Lyondell Petrochemical Co. New Boston Coke Corp. National Steel Corp., Great Lakes Plant Reilly Tar & Chemical Corp. Shenango, Inc. Tonawanda Coke Corp. Wheeling-Pittsburg Steel Corp.

ALS ART

BTS CDT CGU COP DTR EKO

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

1-4

1-4

Synthetic Organic Chemicals, 1987

Section 2 Primary Products from Petroleum and Natural Gas for Chemical Conversion Primary products that are derived from petroleum and natural gas are related to the intermediates and finished products made from such primary materials in much the same way that crude products derived from the distillation of coal tart are related to their intermediates and finished products. Many of the primary products derived from petroleum are identical with those derived from coal tar (e.g., benzene, toluene, and mixed xylenes). Considerable duplication exists in the statistics on the production and sales of primary petroleum products because some of these primary chemicals are converted to other primary products derived from petroleum and because data on some production and sales are reported at successive stages in the conversion process. The statistics are sufficiently accurate, however, to indicate trends in the industry. Many of the primary products for which data are included in the statistics may be used either as fuel or as basic materials from which other chemicals are derived. In this report every effort has been made to exclude data on materials that are used as fuel; however, data are included on toluene and mixed xylenes, which are used in blending aviation and motor fuel. The total production of primary products derived from petroleum and natural gas during 1983-87 is shown in figure 3. Between 1983-87 production increased 12 percent from 109,670 million pounds to 123,119 million pounds.

The output of primary products derived from petroleum and natural gas as a group amounted to 123,119 million pounds in 1987. Production in 1986 was 113,545 million pounds. The output of aromatic and naphthenic products from petroleum amounted to 26,762 million pounds in 1987, compared with 24,836 million pounds in 1986. Sales amounted to $1,946 million in 1987 and $ 1,404 million in 1986. In 1987, production of benzene was 11,533 million pounds; production of toluene was 6,970 million pounds; and production of high purity mixed xylenes was 4,936 million pounds (table 6). Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas was 96,358 million pounds in 1987, compared with 88,710 million pounds in 1986. Sales of these products were valued at $5,674 million in 1987, compared with $4,616 million in 1986. Production of ethylene was 34,951 million pounds in 1987. The output of 1,3-butadiene in 1987 was 2,931 million pounds. Production of propylene in 1987 was 19,019 million pounds (table 6). Table 7 lists the products reported in this section and indicates the manufacturer of each by code. The codes are identified by company name in table 8. Data for 1987 primary products from petroleum and natural gas for chemical conversion were supplied by 67 companies or company divisions. James Raftery 202-252-1365 Statistics on chemicals from coal tar are given in Section 1 (Tar and Tar Crudes) of this report.

Figure 3 Primary products from petroleum and natural gas for chemical conversion: U.S. production, 1983-87 Billions of pounds

140 120 100 80 60 40 • 20

1983

1984

1985

1986

1987

2-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

2-1

Section 2 Table 6 Primary products from petroleum and natural gas for chemical conversion: U.S. production and sales, 1987

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

123,119,361

59,677,198

7,620,039

$0.13

26,761,700

15,985,360

1,946,127

.12

11,532,819

(3)

(3)

(3)

10,587,846 944,973

5,677,064 (3 )

950,177 (3)

.17 ( 3)

Toluene, all grades, total

6,969,852

(3)

(3)

(3)

High purity (98-100%) Other (90-97.9%) 4 5

6,205,803 764,049

3,485,479 (3)

376,202

.11

( 3)

(3)

(3)

(3)

(3)

(3)

4,935,656 (3)

2,976,471 (3)

319,152 (3)

.11

3,323,373

3,846,346

300,596

.08

96,357,661

43,691,838

5,673,912

.13

Hydrocarbons, total

41,685,004

13,278,816

1,716,804

.13

Acetylene' (For chemical use only) Ethane Ethylene

260,081 6,474,13 34,950,792

117,626 2,085,681 11,075,509

36,136 90,006 1,590,662

.31 .04 .14

Hydrocarbons, total

30,143,162

18,078,433

1,900,926

.11

Propane Propylenee

11,123,860 19,019,302

8,208,244 9,870,189

489,569 1,411,357

.06 .14

Hydrocarbons, total

14,690,813

6,952,097

1,094,303

.16

Primary products from petroleum and natural gas for chemical conversion

Grand total Aromatics and naphthenes 2 Total Benzene, all grades, total High purity (98-100%) Other (90-97.9%)

Xylenes, mixed, total High purity (98-100%) Other (90-97.9%) All other aromatics and naphthenes

(3)

Aliphatic hydrocarbonse Total C2

C3

C4

C5

Butadiene and butylene fractions 1,3-Butadiene, grade for rubber (elastomers) n-Butane 1-Butene Isobutane Isobutylene All other C4 hydrocarbons9

1,240,292

951,042

114,299

.12

2,930,658 2,030,649 461,831 1,165,274 1,034,889 5,827,220

2,720,719 829,673 291,287 564,320 306,920 1,288,136

639,481 60,909 50,066 53,849 53,765 121,934

.24 .07 .17 .10 .18 .09

Hydrocarbons, total

2,434,817

1,005,834

115,988

.12

107,140 284,830 345,342 98,650 1,598,855

150,176 (3) 289,021 87,051 479,586

25,169 (3) 20,334 14,167 56,318

.17 (3) .07 .16 .12

7,403,865

4,376,658

845,891

.19

827,089

524,899

127,669

Isoprene (2-Methyl-1,3-butadiene) n-Pentane Pentenes, mixed Piperylene (1,3-Pentadiene) All other C5 hydrocarbonsle 11 All other aliphatic hydrocarbons, derivatives and mixtures, total Alpha olefins, C 6 -C 10 See footnotes at end of table.

2-2

2-2

.24

Synthetic Organic Chemicals, 1987 Table 6—Continued Primary products from petroleum and natural gas for chemical conversion: 1987

Primary products from petroleum and natural gas for chemical conversion

Aliphatic hydrocarbons—Continued All other aliphatic hydrocarbons, derivatives and mixtures—Continued Alpha olefins, C„ and higher Dodecene (Tetrapropylene) n-Heptane Hexane Nonene (Tripropylene) n-Paraffins 12 All other 13

U.S. production and sales,

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pgund

602,782 317,552 178,497 852,035 519,663 2,298,247 1,808,000

( 3) 248,483 127,085 383,310 268,753 1,621,986 1,202,142

(3)

(3)

46,090 20,768 52,884 53,411 209,604 335,465

$.19 .16 .14 .20 .13 .28

Calculated from rounded figures. The chemical raw materials designated as aromatics are In some cases identical with those obtained from the distillation of coal tar; however, the statistics given in the table above relate only to such materials as are derived from petroleum and natural gas. Statistics on production and/or sales of benzene, toluene, and xylene from all sources are given in table 1 of the report on "Tar and Tar Crudes." 3 Reported data are accepted in confidence and may not be published, or no data were reported. Includes toluene, solvent grade, 90 percent. Includes toluene and xylene used as solvents; may Include that which is blended in aviation and motor gasolines. 6 Includes data for alkyl aromatics, crude cresylic acid, cyclopentane, naphthalene, naphthenic acid, carbon black feedstock, distillates, solvents and miscellaneous cyclic hydrocarbons. Also includes production and/or sales data for the other than high purity grades of benzene, toluene, and mixed xylenes. 7 Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of the Census. 8 Includes data for refinery propylene. 9 Includes production and/or sales data for 2-butene, mixtures of 1-butene and 2-butene, and mixed C4 streams. 10 Includes data for mixtures of C5 hydrocarbons, isopentane, and 2-pentene. 11 Includes sales data only for n-pentane. 12 Includes data for the following chain lengths: C 9-C9 , C9-C 15 , C l0-C 14 , C 10-C 18 , C12- C18 and others. 13 Includes production and/or sales data for methane, isoheptanes, isohexane, iso-octane, mixed hexenes, mixed heptenes, mixed octenes, n-octane, di-isobutylene, eicosane, mixtures of C2 and C3 , C5-05, C5- C7, Ce-C7 hydrocarbons, hydrocarbon derivatives, and other hydrocarbons. 2

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

2-3

2-3

Section 2 Table 7 Primary products from petroleum and natural gas for chemical conversion for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Primary products from petroleum and natural gas for chemical conversion

Separate statistics

Manufacturers' Identification codes (according to list In table 8)

Aromatics and naphthenes

Alkyl aromatics: Cyclosols All other alkyl aromatics Benzene: Benzene, high purity (98-100%)

No No Yes Yes

CXI. SHC.

Benzene, other Cresylic acid (Less than 75 percent distilling over 215°C) Cyclopentane Naphthalene Naphthenic acid: Naphthenic acid, acid number 150-199 Naphthenic acid, acid number 200-224 Naphthenic acid, acid number less than 150 Toluene: Toluene, high purity (98-100%)

Yes

AMO, ASH, CCP, CNE, CRP, CSD, CSP, DOW, ENJ, GRS, HES, LYP, MOC, PLC, PPR, SHC, SIO, SM, SOC, SOG, SUN, SWR, TOC, TX, UOC, USI. AMO, KHI, KLM, UTP.

No No No

KHI. PLC. CXI, TX.

No No No

CPS, HEC, MER. MER. HEC, SHC.

Yes

Toluene, other Xylenes, mixed: Xylenes, high purity (98-100%)

Yes

ASH, CNE, CSD, DOW, ENJ, GRS, HCL, HES, KHI, LYP, MNA, MOC, PLC,SHC, SIO, SM, SOG, SUN, SWR, TOC, TX, UOC. PPR, SHC, SOC, SOG, SUN.

Xylenes, other All other aromatics and naphthenes: Aromatics, C9 Carbon black feedstock All other products from petroleum and natural gas, cyclic

No Yes No No

Aliphatic hydrocarbons C1 Hydrocarbons: Methane C2 Hydrocarbons: Acetylene (For chemical use only) Ethane

C3

Yes

AMO, ASH, CSD, ENJ, HES, LYP, PLC, PPR, SHC, SOG, SUN, SWR, UOC. AMO, MOC, TOC. MOC. ENJ.

No

AMO, ASH, BAS, BFG, EKX, ELP, ENJ, LYP, SHC, TX, UCC, UPM, VST.

No

SHO.

Yes Yes

BOR, RH, UCC. AMO, CGO, DA, ENJ, LYP, PLC, SHO, USI, UTP. AMO, ART, BAS, BFG, CNE, DOW, DUP, EKX, ELP, ENJ, HKO, KHI, LYP, MCB, PLC, PPS, SHC, SM, SNO, SOC, TX, UCC, USI, UTP, VST.

Ethylene

Yes

Hydrocarbons: Hydrocarbons, C2-C3 , mixtures Propane (Commercial and hd-5)

No Yes

CGO, TU. AMO, ASH, CCP, CGO, CSD, CSP, DA, ENJ, GRS, KHI, LYP, MOC, PLC, PPS, SHO, SM, SOG, SUN, TCR, TUS, UOC, USI, VLR.

See footnotes at the end of table.

2-4

2-4

Synthetic Organic Chemicals, 1987 Table 7—Continued Primary products from petroleum and natural gas for chemical conversion for which U.S. production and/or sales were reported, identified by manufacturer, 1987—continued Primary products from petroleum and natural gas for chemical conversion

Separate statistics 1

Manufacturers' identification codes (according to list in table 8)

Aliphatic hydrocarbons—Continued

Propylene

C4

Yes

COO, CNE, CSD, CSP, DA, DOW, DUP, EKX, ELP, ENJ, HKO, KHI, LYP, MCB, MOC, PLC, PPS, SHC, SIO, SM, SOC, SOG, SUN, TCR, TX, UCC, USI, UTP, VLR, VST.

Hydrocarbons: Butadiene and butylene fractions

Yes

1,3-Butadiene, grade for rubber (Elastomers)

Yes

n-Butane

Yes

1-Butene 2-Butene 1-Butene and 2-butene, mixed Hydrocarbons, C4, fraction Hydrocarbons, C4, mixtures isobutane (2-Methylpropane)

Yes No No No No Yes

Isobutylene (2-Methylpropene) All other hydrocarbons, C4 C5 Hydrocarbons: Hydrocarbons, C5 mixtures Isopentane (2-Methylbutane) Isoprene (2-Methyl-1,3-butadiene) n-Pentane 2-Pentene Pentenes, mixed Piperylene (1 ,3-Pentadiene) All other hydrocarbons, C5 All other aliphatic hydrocarbons, derivatives, and mixtures: Cs Hydrocarbons: Hexane 1-Hexene Hexenes, mixed Hydrocarbons, C5 -C8 , mixtures Hydrocarbons, C5 -C7 , mixtures Isohexane Neohexane (2,2-Dimethylbutane) All other hydrocarbons, Cs C7 Hydrocarbons: n-Heptane Heptenes, mixed Hydrocarbons, C6 -C7 , mixtures Isoheptanes All other hydrocarbons, C 7 C8 Hydrocarbons: DI-Isobutylene (DI-Isobutene) n-Octane Octenes, mixed 2,2,4-Trimethylpentane (Iso-octane) All other hydrocarbons, C8

AMO, ART, ASH, BAS, BFG, CCP,

Yes No

No No Yes Yes No Yes Yes No

Yes

BAS, DA, DOW, EKX, ELP, HKO, PLC, SOC, TUS, UCC, USI, UTP, VST. AMO, CNE, DOW, ELP, ENJ, LYP, SHC, SM, TPC, TUS. AMO, ASH, CSP, DA, KHI, LYP PLC, SHO, SM, SUN, TUS, USI. ENJ, SHC, SOC, TNA, TPC. TPC. DOW, LYP, SHC, SM, TNA. ART, KHI, TX. LYP, MCB, PPR, PPS, SOG. AMO, CSP, DA, ENJ, KHI, PLC, SHO, SUN, TUS, USI. AMO, ATR, ENJ, SHC, TPC, TUS. ENJ, SM, TPC TX, USI. GYR, HKO, LYP. PLC, SHO. DOW, ENJ, LYP, SHO, SOC. ASH, KHI, PLC, SHO. BFG, DOW. ART, CSP, CXI, PLC, SHO, TUS. CXI, DOW, LYP. DA, ENJ, PLC, SHC, TX.

No No No No No No No

ASH, ENJ, PLC, SHO, SOG, TX, UOC, VST. PLC. ENJ. PLC. ENJ. PLC. PLC. PLC, SHC, SM, TX.

Yes No No No No

ENJ, PLC, SOG, TX, UOC. ENJ, TX. PPR, TX. PLC. EKX, PPR.

No No No No No

EKT, TPC. PLC, SOG. ENJ, TX. CSP, LYP, PLC. SHC.

See footnotes at the end of table.

2-5

2-5

Section 2 Table 7—Continued Primary products from petroleum and natural gas for chemical conversion for which U.S. production and/or sales were reported, identified by manufacturer, 1987—continued

Primary products from petroleum and natural gas for chemical conversion

Separate statistics

Manufacturers' identification codes (according to list in table 8)

Aliphatic hydrocarbons—Continued C9 and above Hydrocarbons (except alpha olefins): Dodecene Eicosane Nonene (Tripropyiene) Alpha olefins: Alpha olefins, C6 -C 10 Alpha olefins, C 11 and higher N-Paraffins-Carbon chain length: n-Paraffins, C10-C14 n-Paraffins, C 10-C 16 n-Paraffins, C 12-C 19 n-Paraffins, C 9-C9 n-Paraffins, C6-C19 n-Paraffins, C 9-C 16 All other n-paraffins Polybutene Hydrocarbon derivatives: n-Butyl mercaptan (1-Butanethiol) sec-Butyl mercaptan (2-Butanethiol) tert-Butyl mercaptan (2-Methyl-2-propanethiol) Di-tert-butyl disulfide Diethyl sulfide (Ethyl sulfide) Dimethyl sulfide Ethyl mercaptan (Ethanethiol) Ethylthioethanol Isopropyl mercaptan (2-Propanethiol) Methyl ethyl sulfide Methyl mercaptan (Methanethiol) Octyl mercaptans n-Propyl mercaptan (1-Propanethiol) Thiophane (Tetrahydrothiophene) All other hydrocarbon derivatives All other hydrocarbons, Ce and above, including mixtures

Yes No Yes

ATR, ENJ, SOC, SUN, UOC. HMY. ATR, ENJ, TX, UOC.

Yes Yes Yes No No No No No No No No

SHC, SOC, TNA. ELP, SHC, SOC, TNA. ENJ, SHC, UOC. VST. VST. SOG, UOC. SOG. SHC, TX, UOC. ENJ, SOG, UOC. AMO, SOC.

No No No No No No No No No No No No No No No

PAS, PLC. HAP, PLC. HAP, PAS, PLC. PLC. HAP, PAS. PAS. HAP, PAS, PLC. HAP. HAP, PAS, PLC. CED, HAP, PAS. PAS. PAS. PAS, PLC. HAP. PAS, PLC.

No

CXI, NES, PLC, SHC, TNA.

Chemicals for which separate statistics are reported in this section are Indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are Indicated by "No". Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

2-6

2-6

Synthetic Organic Chemicals, 1987 Table 8 Primary products from petroleum and natural gas for chemical conversion: Directory of manufacturers, alphabetical by code, 1987

Code AMO ASH ART ATR BAS BFG BOR CCP CED CGO CNE CPS CSD CSP CXI DA DOW DUP

EKT EKX ELP ENJ EPC GRS GYR HAP HCL HEC HES HKO HMY KHI

Name of company Amoco Corp. Ashland Oil, Inc., Ashland Petroleum Co. Aristech Chemical Corp. Atlantic Richfield Co., Arco Chemical Co. BASF Corp. B. F. Goodrich Co. Borden, Inc., Borden Chemical Div. Crown Central Petroleum Corp. Cedar Chemical Co. Citgo Petroleum Corp. Cain Chemical, Inc. CPS Chemical Co., Inc. Fine Oil & Chemical Co., Cosden Chemical Div. Coastal Refining & Marketing, Inc. Chemical Exchange Industries, Inc. Diamond Shamrock Refining & Marketing Dow Chemical Co. E. I. duPont de Nemours & Co., Inc. Petrochemicals Dept. Eastman Kodak Co.: Tennessee Eastman Co. Div. Texas Eastman Co. Div. El Paso Products Co. Exxon Chemical Americas P/P Splitter Venture Champlin Petroleum Co. Goodyear Tire & Rubber Co. Helmerich & Payne, Inc. Natural Gas Odorizing, Inc. Hoechst Celanese Corp. Bayport works Hewchem Amerada Hess Corp. (Hess Oil Virgin Islands Corp) Occidental Chemical Corp., Olefins Div. Humphrey Chemical Co. Koch Refining Co.

Code KLM LYP MCB MER MNA MOC NES PAS PLC PPR RH SHC SHO SIO SM

SNO SOC SOG SUN SWR TCR TNA TOC TPC TU TUS TX UCC UOC UPM USI UTP VLR VST

Name of company Kalama Chemical, Inc. Lyondell Petrochemical Co. Borg-Warner Corp., Borg-Warner Chemicals Merichem Co. Monsanto Agriculture Co. Marathon Petroleum Co., Texas Refining Div. Ruetgers Nease Chemical Co. Pennwalt Corp. Phillips Petroleum Co. Phillips Puerto Rico Core, Inc. Rohm & Haas Co. Shell OH Co., Shell Chemical Co. Div. Shell Oil Co. Standard Oil Co. Mobil Oil Corp.: Gas Liquids Dept. Mobil Chemical Co., Petrochemicals Div. SunOlin Chemical Co. Chevron Corp., Chevron Chemical Co. Hill Petroleum Company Sun Company, Inc. Southwestern Refining Co., Inc. Texas City Refining, Inc. Ethyl Corp. Tenneco Oil Co. Texas Petrochemicals Corp. Tenn-USS Chemicals Co. Texaco Butadiene Co. Texaco Chemical Co. Union Carbide Corp. Union Oil Co. of California UOP, Inc. Quatum Chemical Corp., USI Div. Union Texas Petroleum Valero Refining Co. Vista Chemical Co.

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission

2-7

2-7

2-8

Synthetic Organic Chemicals, 1987

Section 3 Cyclic Intermediates Cyclic intermediates are synthetic organic chemicals derived principally from petroleum and natural gas and from coal-tar crudes produced by destructive distillation (pyrolysis) of coal. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic chemicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic rubber), pesticides, and plastics and resin materials. Some intermediates, however, are sold as end products without further processing. For example, refined naphthalene may be used as a raw material in the manufacture of 2-naphthol or of other more advanced intermediates, or may be packaged and sold as a moth repellant or as a deodorant. In 1987, about 42 percent of the total output of cyclic intermediates was sold; the rest was consumed chiefly in the producing plants in the manufacture of more advanced intermediates and finished products. The total annual production of cyclic intermediates during 1983-87 is shown in figure 4. Total production of cyclic intermediates in 1987

amounted to 55,196 million pounds, an increase of 10 percent compared with production reported to the Commission in 1986. Reported sales of cyclic intermediate chemicals in 1987 were 23,206 pounds, valued at $7,562 million, compared with 22,333 million pounds, valued at $7,150 million, in 1986. Intermediates that were produced in excess of 1 billion pounds in 1987 were ethylbenzene (9,346 million pounds), styrene (8,014 million pounds), terephthalic acid and terephthalic acid dimethyl ester (7,601 million pounds), p-xylene (5,155 million pounds), cumene (4,105 million pounds), phenol (3,841 million pounds), cyclohexane (2,276 million pounds), phthalic anhydride (1,035 million pounds), and bisphenol A (1,000 million pounds). These intermediate chemicals produced in excess of 1 billion pounds accounted for about 75 percent of the total output of cyclic intermediate chemicals produced in 1987. Table 10 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 11. Ed Matusik 202-252-1356

Figure 4 Cyclic Intermediates: U.S. production, 1983-87

Billions of pounds 60

50

40

30

20

10

0 1983

1984

1985

1986

1987

3-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

3-1

Section 3 Table 9 Cyclic Intermediates: U.S. production and sales, 1987

Cyclic intermediates

Production

Sales Quantity

Value

Average Unit value ,

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

55,196,139

23,205,872

7,562,427

$0.33

o-Acetoacetotoluidide p-[(p-Aminophenyflazo]benzenesulfonic acid Aniline (Aniline oil) Anilinomethanesulfonic acid and salt Benzoic acid, tech o-Chloroaniline Chlorobenzene, monoCresols and cresylic acid 3 Cumene Cyclohexane Cyclohexanone p-Dichlorobenzene Dicyclopentadiene (including cyclopentadiene) Ethylbenzene

2,259 140 859,037 393 94,619 1,221 246,445 73,276 4,104,961 2,276,060 930,376 103,346 99,255 9,346,119

2,009

2,941

1.46

(2)

(2)

430,182

127,929

.30

(2)

(2)

(2)

(2)

(2)

(2)

(2)

(2)

93,530 66,779 2,523,241 2,157,305 91,924 83,692 85,302 314,722

26,837 41,447 486,481 443,774 36,455 34,965 17,470 66,407

.29 .62 .19 .21 .40 .42 .20 .21

isocyanic acid derivatives, total

1,568,338

1,363,296

1,046,592

.77

Grand total

(2)

(2)

Polymethylene polyphenylisocyanate Toluene-2,4- and 2,6-dlisocyanate (80/20 mixture) All other isocyanic acid derivatives 4,4'-Isopropylidenediphenol (Bisphenol A) Nonylphenol

508,188

421,670

305,371

.72

713,008 347,142 1,000,351 539,441

645,998 295,628 409,387 98,190

526,938 214,283 199,393 36,642

.82 .72 .49 .37

Phenol, total

3,841,091

1,533,009

444,627

.29

From cumene All other phenol Phthalic anhydride Salicylic acid, tech Styrene Terephthalic acid, dimethyl ester 4 Tetrahydrofuran o-Xylene p-Xylene All other cyclic intermediates

3,132,211 708,880 1,035,187 25,131 8,014,020 7,601,418 142,903 939,969 5,155,219 7,195,564

1,381,150 151,859 454,933 (2) 2,175,680

400,387 44,240 113,240

.29 .29 .25

(2)

(2)

848,886

.39

(2)

(2)

(2)

71,394 807,604 3,166,728 7,276,965

59,272 119,032 556,347 2,853,690

.83 .15 .18 .39

Calculated from unrounded figures. Reported data were accepted in confidence and may not be published, or no data were reported. 3 Does not include data for coke oven and gas-retort ovens. 4 The figure for terephthalic acid, dimethyl ester (DMT) includes both the acid itself and the dimethyl ester without double counting. The acid production figure was multiplied by the factor 1.16 to convert it to equivalent DMT. 1

2

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

3-2

3-2

Synthetic Organic Chemicals, 1987 Table 10 Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Cyclic intermediates

Separate statistics

Manufacturers' identification codes (according to list in table 11)

No No No No No Yes No No No No No No No No No No

EKT. SAL. BKM. BRD, EKT, HCL. BRD, EKT, HCL. BRD, EKT, HCL. EKT, HCL. BRD. DIX. GIV. S. EK. RIL. DIX. SRL.

No

MON, PLC.

No No No No No No No No No No No No No No No

MON, VST. MON, SOC. RIL, ( 2 ). PHC. CGY. HCL. HCL, SDC. CGY. SDC. NSC. HCL. FMT. NSC, WYK. VPC. DAZ.

No No

VPC. BRS, TRD.

No No

CYH, DUP. WAY.

No No No No

UPJ. KF. CGY. SDC.

No

PSG, VPC, ( 2).

No

VPC.

No No No No No No

TCH. CHT. RIL. RIL. RIL. RIL.

No No No No

CGY. BUC. SOM SOM.

Cyclic 3- AcetamIdo - N-(2-succinimidoethyl)-N-ethylaniline Acetanilide, tech Acetic acid, phenyl ester Acetoacetanilide o-Acetoacetanisidide o-Acetoacetotoluidide 2' ,4'-Acetoacetoxylidide Acetoacet-m-xylidide Acetoguanamine l'-Acetonaphthone Acetophenone, tech p-Acetotoluidide 2-Acetylpyridine Adamantane Aldadiene Alkylbenzenes: Alkylbenzene straight-chain (except dodecyl and tridecyl) Dodecylbenzene (including Tridecylbenzene): Dodecylbenzene, straight-chain Dodecylbenzene, other Alkylpyridines, mixed Aluminum chlorohydroxyphthalocyanine blue 3'-Aminoacetanilide 4'-Aminoacetanilide (Acetyl-p-phenylenediamine) 3'-Amino-p-acetanisidide 2- (p- Aminoanilino)-5-nitrobenzenesulfonic acid 1-Aminoanthraquinone and salt p-AminobenzamIde 3'-Aminobenzanilide o-Amlnobenzenethlol p-Aminobenzoic acid, tech 2- Amino-6-benzothiazolesulfonic acid 3-Aminobenzotrifluorlde 1-Amino-4- bromo-9,10-dihydro-9,10-dioxo-2anthracenesulfonic acid and sodium salt 7-Aminocephalosporanic acid 6- Amino-5-chloro-m-toluenesulfonlc acid [SO 3 H=1 ] (2B Acid) 4-Amino-N, N-di (f3-hydroxyethyl) aniline sulfate 5-Amino-4,5 ' - dihydroxy-3,4'-[(2-methoxy-5-methyl-pphenylene)bls(azo)]-d1-2,7-naphthalenedisulfonic acid, 5'-benzenesulfonate 2-Amino-4, 6-dihydroxypyrimidine 5-Amino -2 , 3- dimethylbenzenesulfethanolamIde 3-Amino-9-ethylcarbazole 4-Amino-5- methoxy-2-methylbenzenesulfonic acid (5-methyl-o-anisidinesulfonic acid) m - [( 4-Amino-3- methoxyphenyl)azo]benzenesulfonic acid 4- [( 4-Amino -5- methoxy-o-tolyl)azo]-4-hydroxy-2,7naphthalenedisulfonic acid, benzenesulfonate 2-Amino-2-methylpropyl 8-bromotheophyllinate 2-Amino-3-methylpyrldine 2-Amino-4-methylpyridine 2-Amino-5-methylpyrldine 2-Amino-6-methylpyrldine 6- Amino-2-naphthalenesulfonic acid (Broenner's acid) 5(and 8)-Amino-2-naphthol 2- (4-Amino-2-nitroanilino) ethanol 2-Amino-4-nitrophenol

3-3

See footnotes at end of table.

3-3

Section 3 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic Intermediates

Separate statistics

Manufacturers' identification codes (according to list in table 11)

No No No

SOM. PCW. PCW.

No No Yes No

BRS, PFZ. MAL. ATL, CGY, VPC. VPC.

No No No No No No No Yes No Yes No No No No No No No No No No No

ACY. RIL. RIL. PCW. HCL. DUP. CYH, DUP. ART, DUP, FST, MAL, MOB, RUC, USR. TCH. ACY, ATL, CGY, VPC. CGY, VPC. CHF. SD. TX. PSG. CGY, SDC. KLM. EK. UPF. (2). UPF.

No No No No No No Yes No No No No No No No No

AMO. PD. EK. AMB. (2). HCF. KLM, PFZ, VEL. BFG, BKM, USR. PSG. EK. HK, VEL. HXL, KLM. HXL. PSG. EKT.

No No No No No No No

SD. SDW. HXL. HXL. KHI, MON, SOC, TCC. TX. (2).

No No No No No No

EK. GTL. (2). EK. TNA. DAZ, GTL.

Cyclic—Continued 2-[(2-AmIno-4-nitrophenyl)amlno]-2-hydroxymethyl - 1, 3-propanediol 2-Amino-5-nitrothiazole 2-Amino-4-nitrotoluene hydrochloride 5-Amino-2-[(2-oxo-5-benzImidazollnyl)amino]benzenesulfonic acid p-Aminophenol p-[(p-Aminophenyl)azo]benzenesulfonic acid 2-(4-Aminophenylazo)-4-methylphenol 7-[(4-Aminophenyl)azo]-1,3-naphthalenedisulfonic acid 2-Aminopyridine 3-Aminopyridine 2-Aminothiazoie nitrate 3-Amino-p-toluamide 4-Amino-m-toluenesulfonic acid [SO 3 H=1] 6-Amino-m-toiuenesulfonic acid [SO 3 H=1] Aniline (Aniline oil) 2-Anilinoethanol Anilinomethanesulfonic acid and salt o-Anisidinomethanesulfonic acid Anisole, tech Anisoyl chloride Anthracene, refined Anthranilic acid (o-Aminobenzoic acid) N,N'-(1,5-Anthraquinonylene)dianthranillc acid Benzaldehyde, tech Benzanilide Benzenesulfonic acid Benzenesulfonic acid, 2-formyl-, sodium salt Benzenesulfonyl chloride 1,2,4-Benzenetricarboxylic acid, 1,2-dianhydride (Trimellitic anhydride) Benzhydrol (Diphenyimethanol) Benzimidazole 1, 3-Benzodioxole Benzoic acid, 2-[4-(dimethyiamino)-benzoyl] Benzoic acid, methyl ester Benzoic acid, tech 2-Benzothiazolethiol, sodium salt 1H-Benzotriazole 2-Benzoxazolethiol Benzoyl chloride Benzylamine 2-(Benzylamino)ethanol Benzyldimethylamine 3- ( Benzylethylamino) acetanilide 2-Benzy1-2'-hydroxy-5,9-dimethy1-6,7-benzomorphanhydrobromide 1-Benzy1-4-phenyllsonipecotonitrile Benzyltrlethylammonium chloride Benzyltrimethylammonium hydroxide Biphenyl 1 ,4-Bis (3-aminopropyl)piperazine 2 , 6-Bis (p-azidobenzylidene) -4-methylcyclohexanone . . . . N,N-Bis((4-methylphenyl)sulfonyi)amine, potassium salt 1, 2-Bis (tribromophenoxy) ethane 3-Bromoacetophenone p-Bromoaniline Bromobenzaldehyde Bromobenzene,mono See footnotes at end of table.

3-4

3-4

Synthetic Organic Chemicals, 1987 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic intermediates

Separate statistics

Manufacturers' identification codes (according to list in table 11)

Cyclic—Continued

o-Bromobenzolc acid 4-Bromo-3,5-dihydroxybenzamide 4- Bromo-3,5-dihydroxybenzolc acid 2-Bromo-4, 6-dinitroaniline 1-Bromo-4-ethoxy-2-methylbenzene

p-Bromofiuorobenzene 2-Bromopyridine p-Butoxyphenol p-Butylanlline p-tert-Butylbenzaldehyde n-Butylbenzene 2-tert-Butyl-p-cresol 1-Tert-butyl-2,5-dimethoxybenzene 2- [( 1- Buty1- 2- methylindo1-3-ylicarbonylbenzoic acid o-sec-Butylphenol o-tert-Butylphenoi p-sec-Butyiphenol p-tert-Butyiphenol Butyiphenols, mixed p-tert-Butyitoluene 5-tert-Butyl-m-xylene 6-tert-Butyl-2,4-xylenol 4,4'-Carbonylbis[phthalic anhydride] N - Carboxy-N-methylanthranilic anhydride 4'-Chloroacetophenone o-Chloroanillne p-Chloroaniline Chlorobenzene, mono p- Chlorobenzenesulfonlc acid 2-Chloro-1 ,4-dibutoxybenzene 1-Chloro-2,5-dibutoxy-4-nitrobenzene 2-Chloro-1 ,4-diethoxybenzene 1-Chloro-2,5-dlethoxy-4-nitrobenzene 4'-Chloro-2' , 5 ' - dImethoxyacetoacetanilide 5-Chloro-2 ,4-dlmethoxyaniline 2- Chloro -10- [ 3- (dimethylarnino)propyl]phenothiazine 2-Chloro-4 , 6-dimethylaniline 1 - Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene) 3-Chlorodiphenylamlne N-(2-Chloroethyl)-N-ethylaniline p- [ (2-Chloroethyl) methylamino] benzaldehyde 2-Chloro-4-methylsulfonylaniline 2- [(Chloromethyl)thiol] benzothiazole 1-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene) 1-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene) 2-Chloro-4-nitrobenzolc acid 2-Chloro-4-nitrobenzoic acid, potassium salt a-Chloro-4-nitrotoluene 2-Chloro-4-nitrotoluene 2-Chiorophenothiazine N-(4-ChlorophenyI)-N'-(3,4-dichloropheny)urea 4-Chloro-o-phenylenediamine 4-Chlorophthalic acid 3-Chloropropy1-2,5-xyly1 ether 2-Chloropyridine 4-Chlororesorcinol 5-Chiorosalicylic acid o-Chlorotoluene m-Chlorotoluene p-Chlorotoluene a-Chlorotoluene (Benzyl chloride) 3-Chloro-p-toluldine [NH 2 =1]

No No No No No No No No No No No No No No No No No No Yes No No No No No No Yes No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

PD. PCW. PCW. HCL. (2) . (2) DAZ. ABB. TNA. GIV. PLC. PSG. EKT. (2) . SCN, TNA. TNA. SCN. SCN. SCN, TNA, ( 2 ). Cl. GIV. GAF. ACH. (2) . LIL. CWN, DUP, LAK, LMC. DUP. MON, PPG, SCC. UPF. ALL. ALL. ALL. ALL. HCL. ALL. SK. EKT. SDC. SK. TCH. VPC. EKT. BKM. DUP, MON. DUP, MON. SAL. SAL. EK. DUP, PCW. SK. VPC. FMT. PSG. PD. OMC. PCW. PCW. HK. HK. HK. MON. DUP.

3-5

See footnotes at end of table.

3-5

Section 3 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic intermediates

Separate statistics

Manufacturers' identification codes (according to list in table 11)

No No No No No No

CED. CED, ( 2 ). HK. PCW. ICI. FE R.

No Yes No No No No

(2).

GE, MER, NPC, PSG. MER, PSG.

No

MER, NPC.

No Yes

MER, NPC. ASH, BTL, GGC, GRS, KHI, SHC, SOC, TX. DUP.

Cyclic—Continued 5-[2-Chloro-4-(trifluoromethyflphenoxy]-2-nitrobenzoic acid 3-(2-Chloro-4-trifluoromethylphenoxy)toluene p-Chloro-a,a,a-trifluorotoluene 6-Chloro-a,a,a-trifluoro-m-toluidine p-Chloro-o-xylene 4-Chloro-3,5-xylenol Copper, [2,2' ,2" ,2" ' - [z9H,31H-phthalacyaninepentylpentakis (methylene) ] pentakis [1H-lsolndole-1,3 (2H)dionato]] Cresols: m-Cresol o-Cresol: o-Cresol, from petroleum p-Cresol Cresols, mixed: (M,P)-Cresol: (m,p)-Cresol, from petroleum Cresylic acid, refined: Cresylic acid, refined; from petroleum Cumene (Isopropyl benzene)

No

MER.

4-(Cyanoacetyl)morpholine N-Cyano-s-methyl-N-2 (4-methyl-5-Imidazolyi) methylthioethylisothiourea 2, 5-Cyclohexadiene-1 ,4-dlone , dioxime Cyclohexane

No No Yes

1,2-Cyclohexanedicarboxylic acid anhydride Cyclohexanol Cyclohexanone

No No Yes

Cyclohexanone oxime Cyclohexene 4-Cyclohexene-1,2-dicarboxylic anhydride Cyclohexene oxide 13-(1-Cyclohexenyl)ethylamine Cyclohexylamine Cyclohexyl isocyanate Cyclooctadiene Cyclopentene Cyclopropene carboxylic acid, 3-(2-chloro-3,3,3trifluoro-1-propenyl) -2 , 2-dimethyl- (2-methyl [1,1' biphenyl]-3-y1) methyl ester 2-Cyclopropylmethylamino-5-chlorobenzoPhenone 2-(N-Cyclopropylmethyl-N-phthalimIdoacety1)-amlno-5chlorobenzophenone p-Cymene 3-Diacetoxyethylaminobenzanilide Dialkylbenzene 2,4-Diaminobenzenesulfonic acid [SO 3 H=1] Diaminodiphenylamine sulfonic acid 2,6-Diaminopyridlne 2,5-Dianilinoterephthalic acid 1 ,3-Dibenzyiglycerol m-Dibromobenzene (1 ,2-Dibromoethyl) benzene p-Dibutoxybenzene (DBB) 2,5-Dibutoxy-4-morpholinobenzenediazonium sulfate salt (DBB Sulfate) 2,5-Dibutoxy-4-morpholinonitrobenzene 2,6-Di-sec-butylphenol

No No No No No No No No No

SK. SDC. GRS, PLC, PPR, SOC, SUN, TX,U0C. BCC. ACS, BAS, DUP, MON. ACS, BAS, CNP, DUP, MON, UCC. CNP. USR. DKA. USR. HXL. AIP, HCL. MOB. DUP. ALD.

No No

NES. PD.

No No No No No No No No No No No No

PD. HPC. HCL. VST. CGY. CGY. RIL. VPC. DIX. DAZ. DAZ. ALL.

No No No

ALL. ALL. TNA.

See footnotes at end of table.

3-6

3-6

Synthetic Organic Chemicals, 1987 Table 10—Continued Cyclic Intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic intermediates

Separate statistics

Manufacturers' identification codes (according to list in table 11)

Cyclic—Continued 2,6-Di-tert-butylphenol 2,6-DI-tert-4-sec-butylphenol 3,4-DIchloroaniline o(and p)-Dichlorobenzene m-Dichlorobenzene o-Dichlorobenzene p-Dichlorobenzene 3,3'-Dichlorobenzidine base and salts 3,4-Dichlorobenzotrifluoride 3,5-Dichlorobenzoyl chloride 4,6-Dichloro-1,3-dihydroxybenzene Dichlorodiphenylsilane 2,6-DIchloro-3-methylanIllne Dichloromethylphenylsilane 2,6-Dichloro-4-nitroaniline 1 , 2-Dichloro-4-nitrobenzene 2,4-Dichloro-5-nitrotrifluoromethylbenzene 3,4-Dichiorophenyl isocyanate p-u-Dichlorotoluene 2,5-Dichloro-p-xylene Dicyclohexylamine Dicyclohexylamine, nitrate salt Dicyclopentadiene (includes Cyclopentadiene) ot,a-Diethoxyacetophenone p-Diethoxybenzene 2,5-Diethoxy-4-morphollnonitrobenzene p-(Diethylamino)benzaldehyde 4- (Diethylamino)benzaldehyde, 1,1-diphenylhydrazone 2 [ 4- Diethylarnino-2-hydroxybenzyl]benzoic acid N,N-Diethylaniline 2,6-Diethylaniline Diethylbenzene N,N-Diethylcyclohexylarnine 3,5- Diethyl -1 , 2- dihydro-1-phenyl-2-propylpyrldlne N,N-Diethy1-4-methoxymetanliamide 3,5-Diethyltoluene 3,5-Diethyltoluene-2,4-diamine N,N-Diethyl-m-toluldine N,N-Diethyl-p-toluidine 6 , 11-Dihydrodibenz (b, e) oxepin-11-one 2,3-Dihydro-2,2-dimethy1-7-benzofuranol 2,3- Dihydro-2,2- dimethy1-7-benzofuranyl[(dibutylamino)thio]methylcarbamate 2- [ 2- ( 2,3- Dihydro -1 , 3- dioxo-1H-Inden-2y1)-(quinoliny1)] 6- methylbenzothlazole-7-sulfonic acid 2,3- Dihydro-2- [ 6- methy1-7-sulfo-2-benzothiazoly1]-2quInolinyl -1 ,3- dioxo-1H-indene-5-carboxylic acid Dihydrophenylglycine dane salt 1,2-Dihydro-2,2,4,7-tetramethylquinoline 1 ,4-Dihydroxyanthraquinone 2,4-Dihydroxybenzaldehyde 2,5- Dihydroxy-p-benzenedisulfonic acid, dipotasslum salt 3,4-Dihydroxybenzoic acid, methyl ester 2,4-Dihydroxybenzophenone 1,8-Dihydroxy-4,5-dinitroanthraquinone N,N-Di(p-hydroxyethyl)-m-chloroaniline 3,5-Dihydroxy-N-(2-hydroxyethyljbenzamide m-Dlisopropenylbenzene Dilsopropylaniline Diisopropylbenzene 2,5-Dimethoxybenzaldehyde

No No No No No No Yes No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No

TNA. CED. DUP. SCC. MON. MON, PPG, SCC, SOI. MON, PPG, SCC, SOI. CWN, LAK, LMC. HK, ( 2 ). HK. PCW. DCC. SDC. DCC. CWN DUP. DAZ. MOB. HK. COC. AIP, HCL. OMC. DOW, ENJ, LYP, SHC, VEL. CWN. ALL. ALL. VPC. EKT. (2). BCC, DUP. TNA. DOW, UPM. AIP. RIL. PCW. TNA. TNA. DUP. RSA. PFZ. FMN.

No

NES.

No

VPC.

No No No No No

VPC. SK. EKT. EKT. EK.

No No No No No No No No No No

PCW. ACY. EKT. MIL. PCW. EKT, HCL. TNA. EKT, GGC. CWN.

(2) .

3-7

See footnotes at end of table.

3-7

Section 3 Table 10—Continued Cyclic Intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic Intermediates

Separate statistics 1

Manufacturers' identification codes (according to list in table 11)

No No No No No No No

ACY. CHF. TNA. ATL. SDH. EK. ACY, BCC.

No No No No No No No No

PFZ. NEP. DUP. TNA. ARS, HXL. EKT. AI P. BRD.

No No

CGY UPM.

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

VPC. RSA. FST, RSA. DUP. SAL. EK. ALD. LMC. PSG. SDC. OMC. SAL. SAL. LC. CGY. DUP, RUC. MOB, RUC, ( 2). TX. SAL. (2).

Cyclic—Continued m-Dimethoxybenzene p-Dimethoxybenzene 3,4-Dimethoxytoluene p-(Dimethylamino)benzaldehyde m-(Dimethylamlno)benzoic acid 2-[4-(Dimethylamino)benzoyl]benzoic acid m-Dimethylaminophenol 11-[3(Dimethylamino)propy1]-6H-hydroxydibenz (b,e)oxepin 4-Dimethylaminopyridine N,N-Dimethylaniline 2,6-Dimethylaniline N,N-Dimethylbenzylamine Dimethy1-1,4-cyclohexanedicarboxylate N,N-Dimethylcyclohexylamine 5,5-DImethylhydantoin 2,5-Dimethy1-4(2)-morpholinylmethylphenol, hydrochloride 2,6-DImethylnaphthalene N,N'-Dimethy1-3,4,9,10-perylenetetracarboxylic acid 3, 4:9,10-diimide N, N-Dimethyl-o-toluidine N,N-Dimethyl-p-toluidine m-Dinitrobenzene Dlnitrobenzene-nitrobenzene mixture (30/70) 2,4-Dinitrobenzenesulfonic acid, sodium salt 3,5-Dinitrobenzoyl chloride 3,5-Dinitrochlorobenesulfonlc acid, potassium salt Dinitro-p-cresol 2,4-Dinitrophenol, tech 2,4-Dinitrophenoxyethanol 3,5-Dinitrosalicylic acid 3,5-Dinitrosalicylic acid, methyl ester p-Dinitrosobenzene 4,4'-Dinitrostilbene-2,2'-dIsulfonic acid 2,4-Dinitrotoluene 2,4(and 2,6)-Dinitrotoluene 3,5-DinItro-p-toluenesulfonic acid 3,5-Dinitro-o-toluic acid Dinonylhydroxybenzenesulfonic acid Dinonylphenol Di-para-benzoquinone dioxime 2,4-Di-tert-pentylphenol 1 ,4-Diphenoxybenzene Diphenylamine Diphenyldimethoxysllane Diphenyldisulfide 1 ,3-DI-4-piperidylpropane 2,5-DI-p-toluidinoterephthalic acid 1,5-Diureidonaphthalene Divinylbenzene 1,1-DI-3,4-xylylethane Dodecylaniline Dodecylmethylbenzyl chloride Dodecylnitrobenzene p-Dodecylphenol 2-Ethanolpyridine 5-Ethanoxy-3-trichloromethy1-1,2,4-thiadiazole Ethisterone 4-Ethoxy-3-methoxybenzaldehyde 1-Ethoxy-3-methylbenzene 4-Ethoxy-2-methyl-N-phenylaniline Ethyl-alpha-cyano-beta-methyl cinnamate See footnotes at end of table.

3-8

.

GAF. LC. PAS. TNA. ART, RUC, USR. KF. PAH. RIL. VPC. SO1. DOW, HCL. ACH. MON. RH. LMC. GAF, MON, SOC. RIL. OMC. SRL, UPJ. CGY. (2). (2). PD.

3-8

Synthetic Organic Chemicals, 1987 Table 10—Continued Cyclic Intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Separate statistics 1

Cyclic Intermediates

Manufacturers' identification codes (according to list in table 11)

Cyclic—Continued 3'-(Ethylamino)acetanllide o-Ethylaniline N-Ethylaniline, refined 2-(N-Ethylanilino)ethanol 3-(N-Ethylanilino)propionitrile a -(N-Ethylanilino)-m-toluenesulfonic acid Ethylbenzene 2 (N Ethyl N, p cyanoethyl) 4 acetaminoanisole N-Ethyl-N-(2,3-dihydroxypropy1)-m-toluidine N-Ethyl-N- (2-hydroxyethyl) -m-toluidine N-Ethylmaleimide 6-Ethyl-2-methylanlline 2-[Ethyl(3-methylphenyl)amino]ethanol 9-Ethyl-3-nitrocarbazole N-Ethyl-N-phenylbenzylamine 3-Ethylpyridine 5-Ethyl-2,3-pyridinedicarboxylic acid N-Ethyl-N-(3'-sulfobenzyl)aniline N-Ethyl-m-toluidine 3-(N-Ethyl-m-toluidino)propionitrile 9-Fluorenone o-Fluorobenzoyl chloride 1-Formylpiperldine Furan Furfuryl alcohol 1-(2-Furoyl)piperazine Hexachlorocyclopentadiene 1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride (Chlorendic anhydride) 1,1'-Hexamethylenebis-[5-(4-chlorophenyl)biguanide]diacetate Hydroquinone, tech p-Hydroxyanisole p-Hydroxybenzaldehyde p-Hydroxybenzenesulfonic acid p-Hydroxybenzoic acid 4-Hydroxy-2H-1,2-benzothiazine-3-carboxylic acid, methyl ester, 1,1-dioxide 4-Hydroxybenzylbenzene 2-Hydroxycineole 2'-Hydroxy-5,9-dimethy1-6,7-benzomorphan 2 ,2' - [[4-(2-Hydroxyethylamino)-3-nitrophenyi]imino]diethanol 3- [N- (2-Hydroxyethyl) anilino] proplonitrile N-(2-Hydroxyethyl)-o-chloroaniline N-p-Hydroxyethy1-2,4-dihydroxybenzamide 4-Hydroxymetanilamide 4- Hydroxy-2-methyl-2H-1,2-benzothiazine-3-carboxylic acid, methyl ester, 1,1-dioxide 2- Hydroxymethylene-17a-ethinylandrost-1713-01-4en-3-one 4(5)-Hydroxymethy1-5(4)-methylimidazole hydrochloride 3- Hydroxy-N-(3-N-morpholino-y-propyI)-2-naphthimide 7-Hydroxy-1,3-naphthalenedisulfonic acid, disodium salt 1-Hydroxy-2-naphthoic acid 3-Hydroxy-2-naphthoic acid (B.O.N.) 3-Hydroxy-2-naphthoic acid, diethylenetriamineamide 3-Hydroxy-2-naphthoic acid, ethanolamide -

-

-

-

-

-

No No No No No No No No No No No No No No No No No No No No No No No No No No No

EKT. TNA. BCC, FST. MIL, TCH. TCH. SDH. AMO, ATR, CSD, DOW, ELP, HCL, KHI, MCB, SC, SOC. TCH. EKT. EKT. REG. TNA. FST. SDC. SDH. RIL. NES. VPC. DUP, FST. TCH. MCK. OMC. RIL. QKO. QKO. PFZ. VEL.

No

VEL.

No No No No No No

NES. EKT, GYR. CHF. WES. UPF. LEM.

No No No No

PFZ. TNA. (2) . SD.

No No No No No

SOM. TCH. EKT. PCW. CGY.

No

PFZ.

No

SD.

No

SK.

No

PCW.

No No No No No

SDH. PCW. PCW. PCW. PCW.

3-9

See footnotes at end of table.

222 174 0 -

-

88

-

2 : 0L 3

3-9

Section 3 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic intermediates

Separate statistics 1

Manufacturers' identification codes (according to list in table 11)

No No No Yes No No No No Yes No Yes No No No No No No No

PCW. PCW. PLC, TNA.

No Yes No No No No No No No No No No No No No No No No No No No No No No No No

ARK. ART, DOW, GE, SHC. ICI. ICI. FMC, PSG. TNA. EK. PSG. RIL. RIL. ACY, MLC. ARZ, NCI. RIL. SDC. HEX. TCH. TCH. ACY. FMT. VPC. TLC. HXL. GRS. PSG. SK. PLC.

No No No No

FMN. CED, CPS. TNA. ACY.

No No No No No No No No

ACY. RUC, USR. MOB. KLM. RIL. EKT. EKT. HXL.

No No

SK. LAK.

Cyclic—Continued

1-Hydroxynaphthoic acid, methyl ester 3-Hydroxy-2-naphthoic acid, sodium salt Isobutylbenzene Isocyanic acid derivatives: Bitolylene diisocyanate (TODI) Diphenylmethane-4,4'-diisocyanate (MDI) Isophorone diisocyanate Methylenedicyclohexyl methane 1, 4-diisocyanate Polymethylene polyphenylisocyanate Toluene 2,4-diisocyanate Toluene 2,4-and 2,6-diisocyanate (80/20 mixture) Toluene 2,4-and 2,6-diisocyanate (65/35 mixture) p-Toluenesulfonyl isocyanate Isonicotinonitrile Isophthalic acid (Benzene-1 ,3-dicarboxylic acid) Isophthalonitrile Isophthaloyl chloride Isopropylblphenyl 5,5'-lsopropylidenebis(2-hydroxy-m-xylene-cx, 0e-diol) 4,4'-lsopropylidenediphenol (Bisphenol A) 4,4'-lsopropylidenediphenol, ethoxylated 4,4'-lsopropylidenediphenol, propoxylated o-lsopropylphenol Isopropylphenol, mixed Isothiocyanic acid, phenyl ester Isatoic anhydride 2,6-Lutldine 3,5-Lutidine Melamine dl-p-Mentha-1 ,8-diene (Limonene) 2-Methoxyethylpiperidine N-(4-Methoxy-3-nitrophenyl)acetamide (p-Methoxyphenyl)acetic acid 2-(N-Methylanilino)ethanol 3-(N-Methylanilino)propionitrile 2-Methylanthraquinone 2-Methylbenzothiazole 4-Methylbenzotriazole o-Methylbenzyl chloride N-Methylbenzylamine Methyl benzyl ether 2,2'-Methylenebis(4-methyl-6-nonyl-p-cresol) 1-Methyl-4-chloropropyl)piperazine hydrochloride Methylcyclohexane Methyl 3-(2,2-dichlorovinyI)-2,2-dimethylcyclopropane carboate 2-Methyl-4,6-dinitrophenol (4,6-Dinitro-o-cresol) 4,4-Methylenebis (2,6-di-tert-butylphenol) 4,4'-Methylenebis[N,N-diethylanilinej 4,4' -Methylenebis [N , N-dimethylaniline] (Methane-base) 4,4'-Methylenedianiline Methylene diphenylamine (polymeric) 5,5'-Methylenedisalicylic acid N-Methyl-2-ethanolpiperidine Methyl p-formylbenzoate Methylhydroquinone 2-Methylimidazole (2,4-Methyl-5-imidazoly1)methylthioethylamine dihydrochloride 4-Methyl-2-imino-1,3-dithiolane hydrochloride See footnotes at end of table.

3-10

CWN, MOB. BAS, DOW, MOB, RUC. MOB. MOB. BAS, MOB, RUC. MOB. BAS, DOW, MOB, OMC, RUC. MOB. CWN. RIL. AMO. DUP, PSG. DUP, TLC. TCC.

3-10

Synthetic Organic Chemicals, 1987 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic intermediates

Separate statistics 1

Manufacturers' identification codes (according to list in table 11)

No No No No No No No No Yes

EK. ACY, USR. PSG. SAL. BCC. EK. RIL. ART, GGC, TX. BTL, DOW, HCL.

No No No

WAY. PCW. GNW.

No No No

(2) . CGY. ACY.

No No No No No No

SDC. GNW. VPC. RDA. CGY. DUP.

No

SDC.

Cyclic—Continued 4-Methyl-N-( (4-methylphenyl)sulfonyl)benzenesulfonamide N-Methyl-p-nitroaniline 4-Methyl-2-nitroanisole 3-Methyl-2-nitrobenzoic acid 2-Methyl-5-norbornene-2,3-dicarboxylic anhydride 4-Methylphthalic acid 2-Methylpiperidine a-Methylstyrene ar-Methyistyrene (Vinyltoluene) Mono-,di-,and triesters of phenyl (2,3,4-trihydroxyphenyl) methanone with 6-diazo-5,6-dihydro-5-oxo-1naphthalenesulfonicacid Myristylbenzyldimethylammonium chloride2H 2O 1-Naphthaldehyde 1,5-Naphthalenedisulfonic acid, 2-amino-, monosodium salt 1-Naphthalenesulfonic acid 2-Naphthalenesulfonic acid 1-Napththalenesulfonic acid, 8-(phenylamino)-monosod'um salt 2-Naphthalenesulfonic acid, sodium salt Naphthalimide 1-Naphthol (a-Naphthol) Naphth [1,2-d] [1,2,3] oxadiazole-5-sulfonic acid 1-Naphthylamine (a-Naphthylamine) p- (2-Naphthylamino) phenol (N-(p-HydroxyphenyI)-2naphthylamlne) Nicotinic acid, 2-(4-isopropyl-4,5-oxo-2-imidazolin-2-y1)ester Nicotinonitrile (3-Cyanopyridine) 3-Niro-6-pyrrolodinyl toluene Nitrated dodecylbenzene 3'-Nitroacetanilide o-Nitroaniline p-Nitroaniline 1-Nitroanthraquinone p-Nitrobenzamide Nitrobenzene m-Nitrobenzenesulfonic acid, sodium salt m-Nitrobenzoic acid o-Nitrobenzoic acid p-Nitrobenzoic acid m-Nitrobenzolc acid, sodium salt 2-Nitro-N-benzoylaniiine 5-Nitrodimethyllsophthalate Nitrodiphenylamine 5-Nitroisophthalic acid 3-Nitro-4-methylacetophenone 4-Nitro-N-methylphthalimide 1-Nitronaphthalene p-Nitrophenethyl alcohol o-Nitrophenol p-Nitrophenol p-Nitrophenol, sodium salt 2-(o-Nitrophenylazo)-4,6-di-tert-pentylphenol (OH=1) 2-Nitro-N'-phenyl-p-phenyienediamine 5-Nitrosalicylaldehyde p-Nitrosophenol 4-Nitrosophenol, sodium salt 4-Nitro-4' - (5-suifo-2H-naphtho [1,2-d] triazol-2-y1) -2 ,2' stilbenedisulfonic acid

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

NES. NEP, RIL. ALL. LAK. EKT. BUC, DUP, MON. DUP, MON. SDC. PD. FST, MOB, RUC. USM. SAL, SDH. SAL. DUP. SAL. SAL. SAL. ACY, MON. SAL. TLI. LAK, LMC, SAL. DUP. PCW. MON. DUP, MON. DUP. CGY. SOM. EK. SDC. SDC.

No

HCL.

3-11

See footnotes at end of table.

3-11

Section 3 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987 Separate statistics'

Manufacturers' identification codes (according to list in table 11)

m-Nitrotoluene o-Nitrotoluene p-Nitrotoluene Nitrotoluene mixtures Nonyiphenol

No No No No Yes

Octylphenol Octylphenoxydiethoxy chloride 3-0xo-1,2-benzisothiazoline-2-acetic acid, methyl ester, 1,1-dioxide Oxyaluminum benzoate 4,4'-Oxydianiline Parahydroxyphenylglycine potassium methyl dane salt Pentabromoethylbenzene 1 , 1 ,3, 3 ,5-Pentamethylindan o-Pentylphenol (o-Amylphenol) p-tert-Pentylphenol Permethrin acid chloride 3,4,9,10-Peryienetetracarboxylic-3,4:9,10dianhydride 3,4,9,10-Peryienetetracarboxylic-3,4:9,10-dlimide 1,10-Phenanthroline cx-Phenethylamine 2-Phenethylamine p-Phenetidine Phenol: Natural: From petroleum: Phenol, natural, from petroleum, U.S.P All other phenol, natural, from petroleum Synthetic: Phenol, benzylated Phenol, styrenated Phenol, synthetic, from chlorobenzene by vapor-phase hydrolysis, U.S.P Phenol, synthetic, from cumene by oxidation, U.S.P

No No

DUP, FST. DUP, FST. DUP, FST. FST. GAF, KLM, MCB, MON, RH, SCN, TX. PSG, RH, SCN. RH.

No No No No No No No No No

PFZ. CHT. DOW, DUP. KAN. TNA. GIV. PAS, SCN, ( 2 ). PAS. CED.

No No No No No No Yes

VPC. VPC. VNC. HXL. HXL. HCL, MNA.

No No

MER. NPC.

No No

MIL. MIL.

No

TX.

Yes

ACS, ART, BTL, DOW, GCC, GE, SHC.

No No No No No No No No No No No No No No No No No No No No No No No

KLM. EK. SAL. SAL. NCC. TNA. TNA. TNA. TNA. PFZ. MER. EK. SAL. NES. DUP, FST. DUP. DUP. DOW, MON. HXL. EK. BCC, KAN. BCC, LIL. EKT.

No

MIL, TCH.

Cyclic intermediates Cyclic—Continued

Phenol, synthetic, from toluene by oxidation, U.S.P Phenolsulfonaphthalein, sodium salt Phenolsulfonic acid Phenolsulfonic acid, sodium salt Phenoxyacetic acid, sodium salt 3-Phenoxybenzaldehyde 3-Phenoxybenzaidehyde acetal 3-Phenoxybenzaldehyde cyanohydrin 3-Phenoxybenzenemethanol 2-(Phenoxymethyl)benzoic acid m-Phenoxytoluene 4-(Phenylazo)diphenylamine 2-Phenylbenzimide m-Phenylenebismaleimide m-Phenyienediamine o-Phenylenediamine p-Phenylenediamine Phenyl ether (Diphenyl oxide) d(+) ot-Phenylethylamine N-Phenylglycine Phenylglycine, potassium salt Phenylglycine, sodium salt Phenylhydroquinone 2,2'-[(Phenyl)imino]diethanol (N-Phenyldiethanolamine) See footnotes at end of table.

3-12

3-12

Synthetic Organic Chemicals, 1987 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic intermediates

Separate statistics 1

Manufacturers' identification codes (according to list in table 11)

No No No No No No No No No No No No Yes

TCH. COS. DOW. DOW. DOW. USR. ORT. RIL. PD. EKT. KF. EK. BAS, ENJ, KPT, MON, SC, STP, TU. PSG. PD. PHC. PHC. (2) .

Cyclic—Continued 2,2'-[(Phenyi)imino]diethanol, diacetate ester Phenylmercuric carboxylate o-Phenylphenol p-Phenylphenol o-Phenylphenol, sodium salt N-Phenyl-p-phenyienediamine 1-Phenyl-1,2-propanedione, 2-oxime 4-Phenylpropylpyridine dl-Phenylsuccinic acid 4-Phenyithiomorpholine-1,1-dioxide Phenyltriethoxysilane Phthalic acid Phthalic anhydride Phthalimide Phthalimidoacetic acid Phthalocyaninato(2-)copper [Phthalocyaninato(2-)]nickel [Phthalocyaninetetramethanaminato] copper Phthalocyaninetetrasulfonyl chloride, copper derivative Phthaloyl chloride (Phthalyl chloride) Picolines: Picoline (3,4-mixture) 2-Picoline (a-Picoline) 3-Picoline (13-Picoline) 4-Picoline (y-Picoline) 3-Picoline-N-oxide Picolinic acid Picolinonitrile (2-Cyanopyridine) 2-Picoly!amine 3-Picolyiamine Picric acid (Trinitrophenol) Pipecolic acid Piperidine Piperidine sulfate Polyethyibenzene (80 percent diethylbenzene) 3-Propanolpyridine Propiophenone 1,3,6,8-Pyrenetetrasulfonic acid Pyridine, refined: 2° Pyridine, refined Pyridine, refined all other grades Pyridine hydrochloride 3-Pyridinemethanol 2 Pyridinethiol-1-oxide, sodium salt 2 Pyridinethiol-1-oxide, zinc salt 4-Pyridylacetone 2-(4-Pyridyi)ethylsulfonic acid 2-Pyrimidinol Pyromellitic dianhydride 2-Pyrrolidinone (2-Pyrrolidone) Pyrvinium pamoate

No No No No No No No No No No No No

NEP, RIL. CGY, RIL. RSA. RIL. OMC. OMC. RIL. RIL. CGY. ACH. GAF. (2) . Quinole:

Quinoline-2,3-dicarboxyiic acid Quinoline, other grades Quinaldine 8-Quinolinol Quinone dioxime Resorcinol, dimethyl ether Resorcinol, tech, f3-Resorcylic acid, lead salt Salicylaldehyde

No No No No No No No No No

NES. ATL. ACY. SOM. LC. BAS. KPT. KPT. RDA.

No No No No No No No No No No No No No No No No No No No No No No No No

VPC. TLC. RIL. RIL. NEP, RIL. RIL. RIL. NEP. NEP. RIL. RIL. SDC. RIL. AIP, RIL. RIL. ELP. RIL. HEX, ORT. (2) .

3-13

See footnotes at end of table.

3-13

Section 3 Table 10—Continued Cyclic intermediates for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Cyclic intermediates

Separate statistics

Manufacturers' identification codes (according to list in table 11)

No

EK.

No Yes No No Yes No No

PCW. DOW, KLM, MON, SDH. SAL. UPF. AMO, ATR, CSD, DOW, ELP, HCL, MCB, PLC, SC, SHC, SOC. SAL. PCW.

No No No No No No No Yes No No No No No No No No

DUP. EKT, PCW. EKT, PCW. CRZ. CWN. PCW. AMO, HCF. DUP, EKT, HCF. DUP, TLC. PCW. MON. (2). EKT. TNA. MON. UCC.

No Yes No No No No No No No No No No No No No No No No No

NES. BAS, DUP, GAF, QKO. RDA. KHI. GAF. SDC. CRZ. RIL. ICI. OMC. RUC, ( 2). MOB, OMC. (2). NES. NES, TEN, UPF. NES. NES. UPF. WTC.

No No No No No No No No No No No No

NES HCF. DUP, FST. ALD, DUP, FST. DUP, FST. ATL. EKT. MIL. SOM. PGG. SK. HXL.

Cyclic—Continued

Salicylaldehyde oxime Salicylanilide Salicylic acid, tech Sodium p-sulfophenylmethallyl ether Sodium trichlorobenzenesulfate Styrene (Vinylbenzene) Sulfaguanidine 5-Sulfoisophthalic acid, 1,3-dimethyl ester 5-Sulfoisophthalic acid, 1,3-dimethyl ester, sodium salt 5-Sulfoisophthalic acid, lithium salt 5-Sulfolsophthalic acid, sodium salt 4,4'-Sulfonyidiphenol (4,4'-Dihydroxydiphenyl sulfone) 4-Sulfophthalic acid 5-Sulfosalicyclic acid, sodium salt Terephthalic acid Terephthalic acid, dlmethyl ester Terephthaloyl chloride Terephthaloyldiacetic acid, diethyl ester Terphenyl (Phenylbiphenyl) (m-,o-,and p-isomers) Terpinene-4-ol 1-Tert-butyl-2,5-dimethoxybenzene Tetrabromophthalic anhydride 1,2,4 ,5-Tetrachloro-3-nitrobenzene Tetrahydrobenzyl alcohol Tetrahydro-5 ,5-dimethy1-2 (1 H ) -pyrimidinone-3- [4(trifluoromethyl)phenyl]-1-[2-[4-(trifluoromethyl)phenyl] -2-propenylidene] hydrazone Tetrahydrofuran 1,2,3,4-Tetrahydronaphthalene 1,2,4,5-Tetramethylbenzene (Durene) p-(1,1,3,3-Tetramethylbutyl)phenol 1 ,3 , 6 ,8-Tetranitro-9H-carbazole Thiodiphenol Thionicotinamide Thiophenol Toluene-2,3-(and 3,4)-diamine (35/65 mixture) Toluene-2,4-diamine (4-m-Tolylenediamine) Toluene-2,4-(and 2,6)-dlamine (80/20 mixture) Toluene-3,4-diamine Toluenedimaleimide p-Toluenesulfonic acid p-Toluenesulfonic acid, aniline salt p-Toluenesulfonic acid, copper salt o-Toluenesulfonyl chloride m-Toluic acid m-Toluic acid, 6-(4-isopropyl-4-methyl-5-oxo-2imidazolin-2-y1)-, methyl ester and p-toluic acid, 2(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-y1)-, methyl ester p-Toluic acid, methyl ester m-Toluidine o-Toluidine p-Toluidine m-Toluidinomethanesuifonic acid p-Toluoyl chloride 2,2'-(m-Tolylimino)diethanol 1,2,4-Triacetoxybenzene Tolyltriazole 2,4,6-Triamino-5-nitrosopyrimidine N,N,N-Tribenzylamine See footnotes at end of table.

3-14

3-14

Synthetic Organic Chemicals, 1987 Table 10—Continued Cyclic Intermediates for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Cyclic Intermediates

Separate statistics I

Manufacturers' identification codes (according to list In table 11)

No No No No No No No No No No No No No No No No No No No No No No No No

GTL. PCW. PPG, SCC. SCC. CWN. OMC. PCW. DCC. HK, VEL. DGC. PEL.

Cyclic—Continued 2 , 4 ,6-Tribromophenol 3,4' ,5-Tribromosallcylanilide 1,2 , 3 (and 1,2 , 4) -Trichlorobenzene 1,2 ,4-Trichlorobenzene 1 , 1 , 1-Trichloro-2 ,2-diphenylethane 3-Trichloromethy1-1 , 2 ,4-thiadiazole 1,2 ,4-Trichloro-5-nitrobenzene Trichlorophenylsilane a,a,a-Trichlorotoluene (Benzotrichloride) 2,4,6-Trichloro-s-triazine (Cyanuric chloride) Tri (dimethylaminomethyl) phenol Trimellitic anhydride, acid chloride Trimellitic trichloride Trimesic acid 2,4,6-Trimethylaniline (Mesidine) 1,2,4-Trimethylbenzene (Pseudocumene) 1,3,5-Trimethylbenzene (Mesitylene) 1,3,3-Trimethyl-82 ,a -Indolineacetaldehyde Trimethylphenylammonium chloride Triphenylmethane Triphenyiphosphine Triphenylsulfonium chloride , a ' , " -Tris (dimethylamino) mesitol Tris(2-methyl-1-azirldinyl)phosphine oxide 7 , 7' -Ureylenebis [4-hydroxy-2-naphthalenesulfonic acid] (J-Acid urea) Veratraldehyde (3,4-Dimethoxybenzaldehyde) Vinylcyclohexene monoxide 2-Vinylpyridine 4-Vinylpyridine m-Xylene (90-100% of m-xylene isomer) o-Xylene (90-100% of o-xylene isomer) p-Xylene (90-100% of p-xylene Isomer) 2,4-Xylenesulfonic acid Xylenesulfonic acid, mixed isomers 2,6-Xylenol Xylenols: Xylenol, low boiling point Xylidines: Xylidine, original mixture All other cyclic Intermediates

No No No No No No Yes Yes

(2)

TLC. AMB. PLC. KHI. ABB, VPC. (2)



EK. (2) • SOM .

RH. ARS.

No No No

S. GIV. UCC. RIL. RIL. AMO, PLC. ENJ, KHI, LYP, PLC, PPR, TOC. AMO, ENJ, KHI, LYP, PLC, PPX, SOC, STX, TOC. UPF. NES. GE .

No

MER.

No No

DUP. ACY, ANG, ARA, CGY, DUP, FER, HCF, HCL, HEX, HK, HXL, LC, MCK, MIL, MRT, NES, NOD, OMC, PAH, PCW, PD, PFZ, PSG, RIL, SCH, SDC, SD, SDW, SFS, SOL, SRL, STC, TCH, TNA, UCC, UPJ, VPC, WTC, (2) , (2) , (2) (2) , (2) , (2) , (2) , (2) (2) , (2) , (2)

Chemicals for which separate statistics are reported in this section are indicat ed by "Yes." Chemicals for which data are accepted in confidence and may not be published by "No." 2 The manufacturer did not consent to his identification with the designated product. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

3-15

3-15

Section 3 Table 11 Cyclic intermediates:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ABB ACH ACY ACS

Abbott Laboratories AlIco Chemical Corp. American Cyanamid Co. Allied Signal Inc. Engineered Material Sector Air Products & Chemicals, Inc. Aldrich Chemical Co., Inc. Alliance Chemical, Inc American Bio-Synthetics Corp. Amoco Corp. Armstrong World Industries, Inc. Arsynco, Inc. Aristech Chemical Corp. Arizona Chemical Co. Ashland Oil, Inc., Ashland Petroleum Co. Atlantic Industries, Inc. Atlantic Richfield Co., Arco Chemical Co. BASF Corp. Buffalo Color Corp. B. F. Goodrich Co. Buckman Laboratories, Inc Lonza, Inc. Bristol-Myers Co. BTL Specialty Resin Corp. Synalloy Corp., Blackman Uhler Chemical Div. Cedar Chemical Co. Ciba-Geigy Corp. Firmenich, Inc. Kincaid Enterprises, Inc. Chattem, Inc. DSM Chemicals Augusta, Inc. Columbia Organic Chemical Corp. Cosan Chemical Corp. CPS Chemical Co., Inc. James River Corp. Fina Oil & Chemicals Co., Cosden Chemical Div. Upjohn Co., Fine Chemical Chemical Exchange Industries, Inc Cychem, Inc. Diaz Chemical Corp. Dow Corning Corp. Degussa Corp. Dixie Chemical Co., Inc. Denka Chemical Corp. Dow Chemical Co. E. I. duPont de Nemours & Co., Inc. Chemicals and Pigments Dept. Petrochemicals Dept. Eastman Kodak Co.: Tennessee Eastman Co. Div. El Paso Products Co.

ENJ FER FMC FMN FMT FST GE GGC

Exxon Chemical Americas Ferro Corp., Ferro Chemical Div. FMC Corp.: Agricultural Chemical Group Fairmount Chemical Co., Inc. First Chemical Corp. General ELectric Co. Georgia-Gulf Corp.: Boundbrook Div. Houston Div. Plaquemine Div. Givaudan Corp Greenwood Chemical Co. Champlin Petroleum Co. Great Lakes Chemical Corp. Goodyear Tire & Rubber Co. Cape Industries Hoechst Celanese Corp.: Bayport Works Rhode Island Works Sou-Tex Works Virginia Chemicals, Inc. Hexagon Laboratories, Inc. Occidental Chemical Corp., Specialty Chemical Div. Hercules, Inc. Hexcel Corp., Hexcel Chemical Products ICI Americas, Inc., Chemicals Div. Polyurethanes Group. Kanasco, Ltd Dynamit Nobel Chemicals, Inc. Koch Refining Co. Kalama Chemical, Inc. Koppers Co., Inc. Bofors Nobel, Inc. Lord Corp., Chemical Products Group Napp Chemicals, Inc. Eli Lilly & Co. Lomac, Inc. Lyondell Petrochemical Co. Mallinckrodt, Inc. Borg-Warner Corp., Borg-Warner Chemicals MacKenzie Chemical Works, Inc. Merichem Co. Milliken & Co., Milliken Chemical Co. Melamine Chemicals, Inc. Mobay Chemical Corp. Pittsburgh Div. Monsanto Co. Monsanto Agriculture Co. Morton-Thiokol, Inc., Morton Chemical Div. Niacet, Corp.

AIP ALD ALL AMB AMO ARK ARS ART ARZ ASH ATL ATR BAS . BCC BFG BKM BRD BRS BTL BUC CED CGY CI CHF CHT CNP COC COS CPS CRZ CSD CWN CXI CYH DAZ DCC DGC DIX DKA DOW DUP

EK EKT ELP

...

GIV GNW GRS GTL GYR HCF HCL

HEX HK HPC HXL ICI

KAN KF KHI KLM KPT LAK LC LEM LIL LMC LYP MAL MCB MCK MER MIL MLC MOB MON MNA MRT NCC

3-16

3-16

Synthetic Organic Chemicals, 1987 Table 11—Continued Cyclic intermediates:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

NCI

Union Camp Corp., Terpene & Aromatics Div. Nepera, Inc. Ruetgers-Nease Chemical Co. Nuodex, Inc. Northwest Petrochemical Corp. National Starch & Chemical Corp. Olin Corp. Roehr Chemicals, Inc., Div. of Aceto Corp. Parish Chemical Co. Pennwalt Corp. Pfister Chemical, Inc. Parke-Davis Div. of Warner-Lambert Co. Pelron Corp. Pfizer, Inc., & Pfizer Pharmaceuticals, Inc. Phthalchem, Inc. Phillips Petroleum Co. PPG Industries, Inc. Phillips Puerto Rico Core, Inc. Phillips Paraxylene, Inc. PMC Specialities Group Inc. Q0 Chemicals, Inc. ITT Rayonier, Inc. Rhone-Poulenc, Inc Regis Chemical Co. Rohm & Haas Co. Reilly Tar & Chemical Corp. R.S.A.Corp. Rubicon, Inc. Sandoz, Inc. Salsbury Laboratories, Inc. Sterling Chemicals Standard Chlorine of Delaware, Inc. The Schering Corp. Schenectady Chemicals, Inc. Sterling Drug, Inc., Sterling Pharmaceuticals, Inc.

SDC

Sandoz Chemicals Corp. Sterling Drug, Inc.: SDI Divestiture Corp. Sterling Organics Div. Shell Oil Co., Shell Chemical Co. Div. SmithKline Chemicals Chevron Corp., Chevron Chemical Co. Specialty Organics, Inc. Southland Corp. G. D. Searle & Co. Stepan Chemical Co. St. Croix Petrochemical Corp. Sun Company, Inc. Sybron Chemical, Inc. Quantum Chemical Corp., Emery Div. Tennessee Chemical Co. Twin Lake Chemical, Inc. Teledyne Industries Inc., Teledyne McCormick Se1ph Ethyl Corp. Tenneco Oil Co. Squibb Manufacturing, Inc. Tenn-USS Chemicals Co. Texaco Chemical Co. Union Carbide Corp. Union Oil Co., of California Jim Walter Resources, Inc., CIC Div. Upjohn Co UOP, Inc. Crown Metro, Inc. Uniroyal, Inc., Uniroyal Chemical Div. Velsicol Chemical Corp. Vanderbilt Chemical Corp. Mobay Chemical Corp., Dyes & Pigments Div. Vista Chemical Co. Olin Hunt Specialty Products, Inc. Wesley Industries Witco Chemical Corp. Wyckoff Chemical Co., Inc.

NEP NES NOD NPC NSC OMC ORT PAH PAS PCW PD PEL PFZ PHC PLC PPG PPR PPX PSG QKO RAY RDA REG RH RIL RSA RUC S SAL SC SCC SCH SCN SD

SDH SDW SHC SK SOC SOI SOM SRL STP STX SUN TCC TCH TEN TLC TLI TNA TOC TRD TU TX UCC UOC UPF UPJ UPM USM USR VEL VNC VPC VST WAY WES WTC WYK

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission

3-17

3-17

3-18

Synthetic Organic Chemicals, 1987

Section 4

Total domestic production of dyes in 1987 amounted to 255 million pounds, or 8.3 percent more than the 236 million pounds produced in 1986 (table 12). Sales of dyes in 1987 amounted to 230 million pounds, valued at $677 million, compared with 226 million pounds, valued at $652 million, in 1986. In terms of quantity, sales of dyes in 1987 was 2 percent higher, and in terms of value 4 percent higher. The average unit value of sales of all dyes in 1987 was $2.95 per pound, compared with $2.89 per pound in 1986.

Dyes Synthetic dyes are derived in whole or in part from cyclic intermediates. Approximately twothirds of the dyes consumed in the United States are used by the textile industry to dye natural and synthetic fibers or fabrics; about one-sixth is used for coloring paper; and the rest is used chiefly in the production of organic pigments and in dyeing leather and plastics. Of the several thousand different synthetic dyes that are known, more than one thousand are manufactured by domestic producers, collectively. The large number of dyes results from the many different types of materials to which dyes are applied, the different conditions of service for which dyes are required, and the cost that a particular use can bear. Commercial dyes are formulated products which are sold in a variety of physical forms (e.g.) granular, powders, liquids, and pastes) containing concentrations of colorant ranging from 6 percent (approximately) to 100 percent. In the statistical tables, production and sales quantities are expressed in terms of a standard strength of product (based on dyeing performance) and not in terms of the amount of actual colorant.

Production of five classes of dyes decreased in 1986, while the remaining five major classes increased their production. Fiber-reactive dyes and flourescent brightening agents registered significant increases in 1987 while mordant dyes registered a significant decline. Changes in U.S. production of synthetic dyes followed overall changes in U.S. economic activity during 1983-87 (see figure 5). Table 13 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 14.

Stephen Wanser 202-252-1363

Figure 5 Dyes: U.S. production, 1983-87

Millions of pounds

300 270 240 --: 210 -'t* 180 150 120

-

90 60 — 30 1983

1984

1985

1986

1987

4-1

Source: Compiled from data received In response to questionnaires of the U.S. International Trade Commission.

4-1

Section 4 Table 12 Dyes: U.S. production and sales, 1987

Dyes

Grand total

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

255,198

229,763

677,424

$2.95

18,002

16,860

81,713

4.85

3,121

2,579

9,748

3.78

90 139 2,892

75 118 2,386

534 510 8,704

7.09 4.33 3.65

4,994

3,586

8,266

2.31

68 153 4,773

55 131 3,400

151 400 7,715

2.76 3.06 2.27

2,806

3,590

22,956

6.39

241 50 635 1,880

258 43 386 2,903

700 342 2,227 19,687

2.71 7.91 5.77 6.78

77

77

674

8.87

4,683

5,036

30,431

6.04

1,499 3,184

1,681 3,355

9,139 21,292

5.44 6.35

268 421 1,632

211 360 1,421

1,991 1,840 5,807

9.44 5.11 4.09

12,771

11,906

66,549

5.59

3,231

2,926

11,184

3.82

159 3,072

136 2,790

754 10,430

5.53 3.74

860

758

2,800

3.69

538 322

474 284

1,207 1,593

2.55 5.61

1,789

1,554

7,480

4.81

246 451 1,092

282 379 893

1,497 1,209 4,774

5.31 3.19 5.34

Acid dyes Total Acid yellow dyes, total Acid Yellow 17 Acid Yellow 23 All other acid yellow dyes Acid orange dyes, total Acid Orange 7 Acid Orange 10 All other acid oranges dyes Acid red dyes, total Acid Red 1 Acid Red 137 Acid Red 182 All other acid red dyes Acid violet dyes Acid blue dyes total Acid Blue 324 All other acid blue dyes Acid green dyes Acid brown dyes Acid black dyes Basic dyes (classical and modified) Total Basic yellow dyes, total Basic Yellow 11 Basic yellow dyes, all other, modified Basic orange dyes, total Basic Orange 2 All other basic orange dyes Basic red dyes, total Basic Red 12 Basic Red 15 All other basic red dyes See footnotes at end of table.

4-2

4-2

Synthetic Organic Chemicals, 1987 Table 12-Continued Dyes:

U.S. production and sales, 1987

Dyes

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Basic dyes (classical and modified)-Continued

Basic violet dyes, total

3,441

3,258

12,066

$3.70

1,469 1,205 767

1,505 1,057 696

3,600 3,548 4,918

2.39 3.36 7.07

Basic blue dyes

1,957

1,869

11,981

6.41

All other basic dyes

1,493

1 , 541

21,038

13.65

36,856

35,746

84,438

2.36

14,393

13,989

27,660

1.98

1,369 1,288 11,736

1,327 1,130 11,532

2,120 2,349 23,191

1.60 2.08 2.01

1,564

1,397

3,553

2.54

90 576 898

59 600 738

279 1,763 1,511

4.70 2.94 2.05

6,012

5,296

16,822

3.18

1,544 1,430 3,038

1,463 1,107 2,726

3,259 2,137 11,426

2.23 1.93 4.19

267

195

926

4.75

7,367

8,301

20,551

2.48

703 758 832 1,594 3,480

323 783 894 1,373 4,928

1,416 2,500 2,208 4,393 10,034

4.39 3.19 2.47 3.20 2.04

466

421

805

1.91

6,787

6,147

14,121

2.30

535 6,252

485 5,662

1,376 12,745

2.83 2.25

26,262

20,847

80,131

3.84

Disperse yellow dyes

2,849

1,730

6,642

3.84

Disperse orange dyes, total

4,636

3,431

9,112

2.66

488 404 3,744

261 238 2,932

613 689 7,810

2.34 2.90 2.66

Basic Violet 1 Basic Violet 3 All other basic violet dyes

Direct dyes Total

Direct yellow dyes, total Direct Yellow 4 Direct Yellow 127 All other direct yellow dyes Direct orange dyes, total Direct Orange 39 Direct Orange 102 All other direct oranges dyes Direct red dyes, total Direct Red 236 Direct Red 254 All other direct red dyes Direct violet and green dyes Direct blue dyes, total Direct Blue 80 Direct Blue 86 Direct Blue 199 Direct Blue 218 All other direct blue dyes Direct brown dyes Direct black dyes, total Direct Black 80 All other direct black dyes Disperse dyes Total

Disperse Orange 37 Disperse Orange 44 and 44:1 All other disperse orange dyes

4-3

See footnotes at end of table

4-3

Section 4 Table 12-Continued Dyes: U.S. production and sales, 1987

Dyes

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Disperse dyes-Continued

Disperse red dyes, total Disperse Red 73 Disperse Red 167 and 167:1 Disperse Red 177 All other disperse red dyes Disperse violet dyes Disperse blue dyes Disperse black, brown and green dyes, total Disperse Brown 1 All other disperse black, brown, and green dyes

4,997

4,182

23,507

$5.62

596 736 456 3,209

415 637 423 2,707

1,424 2,137 1,976 17,970

3.43 3.36 4.67 6.64

152

198

1,504

7.56

11,361

9,811

32,344

3.30

2,267

1,495

7,022

4.70

645

581

1,756

3.02

1,622

914

5,266

5.76

23,253

15,598

87,529

5.61

65,424

61,353

79,819

1.30

5,623

6,099

51,881

8.51

5,327

5,794

45,446

7.84

443 1,618 1,153

366 1,461 1,132

4,731 7,057 5,062

12.91 4.83 4.47

2,113

2,835

28,596

10.09

296

305

6,435

20.68

7 84 205

8 71 226

249 2,148 4,038

35.13 30.09 17.21

73

68

295

4.32

9,416

5,990

34,019

5.68

1,163 323 2,190 3,286 2,454

1,011 263 1,885 484 2,347

8,117 2,179 11,508 5,271 6,944

8.03 8.29 6.11 10.89 3.02

Fiber-reactive dyes Total Fluorescent brightening agents Total Food, drug, and cosmetic colors Total Food, drug and cosmetic dyes, total FD&C Red No. 3 FD&C Yellow No. 5 FD&C Yellow No. 6 All other food, drug, and cosmetic, dyes Drug and cosmetic dyes, total D&C Red No. 33 D&C Yellow No. 10 All other drug and cosmetic dyes 2 Mordant dyes

Total Solvent dyes Total Solvent yellow dyes Solvent orange dyes Solvent red dyes Solvent blue dyes All other solvent dyes See footnotes at end of table.

4-4

4-4

Synthetic Organic Chemicals, 1987 Table 12—Continued Dyes: U.S. production and sales, 1987

Dyes

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Vat dyes Total Vat yellow dyes Vat orange dyes Vat red dyes Vat violet dyes Vat blue dyes Vat green dyes Vat brown dyes Vat black dyes All other dyes Total3

36,542

36,131

65,447

$1.81

12 126 284 222 34,884 423 381 210

14 108 286 297 34,517 352 455 102

157 894 2,270 2,079 53,927 1,860 2,525 1 ,735

11.21 8.28 7.94 7.00 1.56 5.28 5.55 17.01

20,976

19,165

45,603

2.38

Calculated from unrounded figures. The data Include external drug and cosmetic dyes. 3 The data include azoic compositions, azoic coupling components, azoic diazo components (bases and salts), sulfur dyes, and miscellaneous dyes. Statistics for those groups of dyes may not be published separately because publication would disclose Information received in confidence. 1

2

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

4-5

4-5

Section 4 Table 13 Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Acid dyes

Acid yellow dyes: Acid Yellow 3 Acid Yellow 17 Acid Yellow 23 Acid Yellow 34 Acid Yellow 36 Acid Yellow 49 Acid Yellow 59 Acid Yellow 65 Acid Yellow 73 Acid Yellow 87 Acid Yellow 99 Acid Yellow 119 Acid Yellow 127 Acid Yellow 129 Acid Yellow 135 Acid Yellow 151 Acid Yellow 159 Acid Yellow 198 Acid Yellow 200 Acid Yellow 219 Acid Yellow 226 Acid Yellow 239 All other acid yellow dyes Acid orange dyes: Acid Orange 7 Acid Orange 8 Acid Orange 10 Acid Orange 24 Acid Orange 60 Acid Orange 64 Acid Orange 89 Acid Orange 116 Acid Orange 128 Acid Orange 152 Acid Orange 156 Acid Orange 161 All other acid orange dyes Acid red dyes: Acid Red 1 Acid Red 4 Acid Red 14 Acid Red 18 Acid Red 57 Acid Red 73 Acid Red 85 Acid Red 87 Acid Red 88 Acid Red 97 Acid Red 114 Acid Red 119 Acid Red 137 Acid Red 151 Acid Red 182 Acid Red 186 Acid Red 226 Acid Red 266 Acid Red 296

Yes No Yes Yes No No No No No No No No No No No No No No No No No No No No Yes Yes No Yes No No No No No No No No No No Yes Yes No No No No No No No No No No No Yes No Yes No No No No

ACY. ATL, CK, SDH. BAS, CK, LVR, SDH, WJ. ATL. ATL, CGY. ATL, CK. BAS. ATL. SDH. CK. CK. BAS. CK. CK. ICI. CGY, CK. CK. CK. CK. CGY, CK, VPC. BAS. DGO. CK. ATL, BAS, CK. ATL, BAS, CK. ATL, CGY, CK. CK. CGY, CK. ATL. BAS. CGY, CK. CK. CK. CGY, CK, S. ATL. BAS, CK. ATL, BAS, CGY, CK, FAB. ATL. ATL, BAS. ATL. CK. ATL, CK, PSC, S. FAB. SDH. ATL, BAS. ATL. CGY, CK. CK. ATL, BAS, CK. ATL, CK. CGY, CK, VPC. CGY. BAS. CK, VPC. BAS.

See footnotes at end of table.

4-6

4-6

Synthetic Organic Chemicals, 1987 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Acid dyes—Continued

Acid red dyes—Continued Acid Red 299 Acid Red 337 Acid Red 364 Acid Red 384 Acid Red 396 Acid Red 410 All other acid red dyes Acid violet dyes: Acid Violet 3 Acid Violet 7 Acid Violet 12 Acid Violet 17 Acid Violet 49 Acid blue dyes: Acid Blue 9 Acid Blue 15 Acid Blue 25 Acid Blue 27 Acid Blue 29 Acid Blue 40 Acid Blue 41 Acid Blue 80 Acid Blue 104 Acid Blue 113 Acid Blue 118 Acid Blue 145 Acid Blue 231 Acid Blue 277 Acid Blue 283 Acid Blue 298 Acid Blue 321 Acid Blue 324 Acid Blue 330 All other acid blue dyes Acid green dyes: Acid Green 1 Acid Green 3 Acid Green 5 Acid Green 9 Acid Green 20 Acid Green 25 Acid Green 70 Acid brown dyes: Acid Brown 14 Acid Brown 19 Acid Brown 50 Acid Brown 97 Acid Brown 147 Acid Brown 159 Acid Brown 160 Acid Brown 161 Acid Brown 163 Acid Brown 165 Acid Brown 227 Acid Brown 239 Acid Brown 264 All other acid brown dyes

No No No No No No Yes Yes No No No No No Yes No No No No No No No No No No No No No No No No No Yes No No Yes No No No No No No No Yes No No No No No No No No No No No No No No

CK. ATL, CK, VPC(E). CK. CK. ICI. ATL. ATL, BAS, CG'f, CK, EKT. ATL, FAB. ATL, FAB. ATL. SDH. SDH. BAS, SDH, WJ. BAS. CGY, VPC. ATL. FAB. CK, VPC. ATL, CK. CGY. ATL. CK. ATL. ATL, CK. CK. CGY. S. CK. ATL. CK, S, VPC. ATL. BAS, CK, SDH. LVR. WJ. WJ. LVR. ATL. ATL, CK. CGY. CK, LVR. CK. BAS. BAS, FAB. CK. BAS. BAS. BAS. BAS. BAS. BAS. CK. BAS. BAS, FAB.

See footnotes at end of table.

4-7

4-7

Section 4 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Dyes

Separate statistics 1

Manufacturers' identification codes (according to list in table 14)

Acid dyes—Continued

Acid black dyes: Acid Black 1 Acid Black 52 Acid Black 60 Acid Black 63 Acid Black 107 Acid Black 112 Acid Black 172 Acid Black 194 Acid Black 210 All other acid black dyes

Yes No No No No No No No No No No

Azoic dyes and components:

No

Azoic compositions: Azoic yellow compositions: Azoic Yellow 1 Azoic orange composition: Azoic Orange 3 Azoic red compositions: Azoic Red 1 Azoic Red 2 Azoic Red 6 All other azoic red composition Azoic violet compositions: Azoic Violet 1 All other azoic violet compositions Azoic blue compositions: Azoic Blue 3 Azoic brown composition: Azoic Brown 7 Azoic Brown 9 All other azoic brown compositions Azoic black composition: Azoic Black 4 All other azoic black compostions Azoic diazo components, bases: Azoic Diazo Component 5, base Azoic Diazo Component 13, base Azoic Diazo Component 14, base Azoic Diazo Component 32, base All other azoic diazo components, base Azoic diazo components, salts: Azoic Diazo Component 1, salt Azoic Diazo Component 3, salt Azoic Diazo Component 5, salt Azoic Diazo Component 6, salt Azoic Diazo Component 8, salt Azoic Diazo Component 9, salt Azoic Diazo Component 10, salt Azoic Diazo Component 11, salt Azoic Diazo Component 12, salt Azoic Diazo Component 13, salt Azoic Diazo Component 14, salt Azoic Diazo Component 20, salt Azoic Diazo Component 32, salt Azoic Diazo Component 34, salt Azoic Diazo Component 35, salt

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

ATL, CK. ATL, CK, S. CK. BAS. CK. CK. ICI. BAS. BAS. CK.

BUC. BUC. BUC. BUC. BUC. BUC. BUC. BUC. BUC. BUC. BUC. BUC. BUC. BUC. ALL. ALL. ALL. ALL. ALL. ALL, BUC. ALL, BUC. ALL, BUC. ALL. ALL, BUC. ALL, BUC. ALL, BUC. ALL. ALL, BUC. ALL, BUC. ALL. ATL. ATL. ALL. ALL.

See footnotes at end of table.

4-8

4-8

Synthetic Organic Chemicals, 1987 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list In table 14)

Azoic dyes and components—Continued Azoic diazo components, salts—Continued Azoic Diazo Component 41, salt Azoic Diazo Component 42, salt Azoic Dlazo Component 44, salt Azoic Diazo Component 48, salt Azoic Diazo Component 49, salt All other azoic diazo components salts Azoic coupling components: Azoic Coupling Component 2 Azoic Coupling Component 3 Azoic Coupling Component 4 Azoic Coupling Component 7 Azoic Coupling Component 12 Azoic Coupling Component 14 Azoic Coupling Component 17 Azoic Coupling Component 18 Azoic Coupling Component 20 Azoic Coupling Component 21 Azoic Coupling Component 24 Azoic Coupling Component 34 Azoic Coupling Component 35 Azoic Coupling Component 43

No No No No No No No No No No No No No No No No No No No No No

ALL. ALL. ALL. ATL. ALL. ALL. ALL. PCW. ALL. PCW. PCW. ALL. ALL. ALL. PCW. PCW. PCW. ALL. PCW. ALL.

Basic dyes (Classical and modified) Basic yellow dyes: Basic Yellow 2 Basic Yellow 11 Basic Yellow 13 Basic Yellow 15 Basic Yellow 24 Basic Yellow 25 Basic Yellow 28 Basic Yellow 29 Basic Yellow 37 Basic Yellow 53 Basic Yellow 58 Basic Yellow 65 Basic Yellow 79 Basic Yellow 83 Basic Yellow 94 Basic Yellow 96 Basic Yellow 102 All other basic yellow dyes All other basic yellow dyes modified Basic orange dyes: Basic Orange 1 Basic Orange 2 Basic Orange 21 All other basic orange dyes Basic red dyes: Basic Red 12 Basic Red 14 Basic Red 15 Basic Red 17 Basic Red 29 Basic Red 46 Basic Red 49

Yes No Yes No No No No No No No No No No No No No No No No No Yes No Yes No No Yes Yes No Yes No No No No

ACY. ATL, CK, VPC. ATL. CK. BAS. BAS. BAS, VPC. BAS. ACY. CK. VPC. BAS. CK. CK. S. BAS. BAS. ACY, ( 2 ). CK. ATL, BAS, CK, PSC. ACY, ATL, CK, PSC. ATL, VPC. (2) . ACY, ATL, VPC. BAS, CK. ATL, BAS, CK. CK. BAS. CK. BAS, CK.

See footnotes at end of table.

4-9

4-9

Section 4 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Basic dyes (Classical and modified)—Continued

Basic red dyes—Continued Basic Red 51 Basic Red 54 Basic Red 73 Basic Red 104 Basic Red 111 All other basic red dyes Basic violet dyes: Basic Violet 1 Basic Violet 3 Basic Violet 4 Basic Violet 10 Basic Violet 16 Basic Violet 35 All other basic Violet dyes Basic blue dyes: Basic Blue 1 Basic Blue 3 Basic Blue 7 Basic Blue 21 Basic Blue 41 Basic Blue 54 Basic Blue 60 Basic Blue 77 Basic Blue 94 and 94:1 Basic Blue 140 All other basic blue dyes All other basic blue dyes, modified Basic green dyes: Basic Green I Basic Green 4 All other basic green dyes Basic brown dyes: Basic Brown 1 Basic Brown 4 All other basic brown dyes Basic black dyes: All other basic black dyes All other basic black dyes, modified

No No No No No No Yes Yes Yes No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No

BAS. BAS. BAS, CK. BAS, CK. S. (2). ACY, BAS, DSC. ACY, BAS, CK, DSC. ACY, DSC. ACY, BAS. ATL, BAS, VPC. BAS. BAS, ( 2 ). ACY, SDH. BAS, CK. DSC. CK. BAS. BAS. BAS. CK. CK. VPC. BAS, ( 2 ). CK. LVR. ACY, BAS (2) . PSC. ACY, ATL, PSC. BAS. ACY, BAS, ( 2 ). BAS, CK.

Direct dyes Direct yellow dyes: Direct Yellow 4 Direct Yellow 5 Direct Yellow 6 Direct Yellow 11 Direct Yellow 28 Direct Yellow 34 Direct Yellow 44 Direct Yellow 51 Direct Yellow 105 Direct Yellow 106 Direct Yellow 107 Direct Yellow 118 Direct Yellow 119 Direct Yellow 127 Direct Yellow 131

Yes Yes No No No No No No No No No No No No Yes No

ATL, BAS, CGY, CK, LVR, VPC. BAS. CGY, VPC. BAS, VPC. CK. CK. CK. S. CGY, CK. CK. CGY, CK. CK. VPC. BAS, CGY, CK, VPC. VPC.

See footnotes at end of table.

4-10

4 10 -

Synthetic Organic Chemicals, 1987 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics ,

Manufacturers' identification codes (according to list in table 14)

Direct dyes—Continued

Direct yellow dyes—Continued Direct Yellow 132 Direct Yellow 133 Direct Yellow 137 Direct Yellow 147 Direct Yellow 148 Direct Yellow 150 All other direct yellow dyes Direct orange dyes: Direct Orange 6 Direct Orange 15 Direct Orange 26 Direct Orange 29 Direct Orange 34 Direct Orange 39 Direct Orange 72 Direct Orange 80 Direct Orange 102 Direct Orange 118 All other direct orange dyes Direct red dyes: Direct Red 2 Direct Red 4 Direct Red 9 Direct Red 16 Direct Red 23 Direct Red 24 Direct Red 26 Direct Red 28 Direct Red 72 Direct Red 73 Direct Red 79 Direct Red 80 Direct Red 81 Direct Red 83 Direct Red 236 Direct Red 238 Direct Red 239 Direct Red 254 All other direct red dyes Direct violet dyes: Direct Violet 9 Direct Violet 66 Direct blue dyes: Direct Blue 1 Direct Blue 2 Direct Blue 8 Direct Blue 15 Direct Blue 22 Direct Blue 25 Direct Blue 71 Direct Blue 75 Direct Blue 80 Direct Blue 86 Direct Blue 98 Direct Blue 108 Direct Blue 160 Direct Blue 189

No No No No No No No Yes No No No No No Yes No No Yes No No Yes No No No No No No No No No No No No No No Yes No No Yes No No No No Yes No No No No No No No No Yes Yes No No No No

S. S. VPC. BAS, VPC. S. S. ATL, BAS, CK. ATL. BAS, VPC. CK. CGY. ATL. CGY, CK, FAB. CK. ATL. ATL, BAS, CGY, VPC. S. ATL, BAS. ATL. CK. CK. ATL, CGY. ATL. ATL, FAB. ATL. FAB. ATL, BAS, CGY, CK. ATL. CK. ATL, CK. ATL, CK, LVR, VPC. ATL, CK, FAB. BAS, CGY, CK, VPC. VPC. S. BAS, CGY, VPC. ACY, ATL, BAS, CK, VPC. ATL, CGY. ATL. ATL, LVR. FAB. ATL. S, VPC. CGY. ATL, CK. CK. CK, S. ATL, CGY, CK, FAB. CGY, CK, S, VPC. ATL, CK, FAB. ATL. CK. CK.

See footnotes at end of table.

4-11

4-11

Section 4 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Direct dyes—Continued Direct blue dyes—Continued Direct Blue 191 Direct Blue 199 Direct Blue 218 Direct Blue 269 Direct Blue 279 Direct Blue 281 Direct Blue 283 Direct Blue 285 Direct Blue 286 All other direct blue dyes Direct green dyes: Direct Green 1 Direct Green 6 Direct Green 92 All other direct green dyes Direct brown dyes: Direct Brown 31 Direct Brown 44 Direct Brown 230 Direct Brown 231 Direct Brown 232 Direct Brown 238 All other direct brown dyes Direct black dyes: Direct Black 1 Direct Black 4 Direct Black 22 Direct Black 80 Direct Black 165 Direct Black 170 Direct Black 190 All other direct black dyes

No Yes Yes No No No No No No Yes No No No No No Yes No No No No No No No Yes No No Yes Yes No No No No

CK, FAB. BAS, CGY, VPC. ATL, CGY, CK, FAB, VPC. VPC. VPC. CGY, CK, VPC. ATL. ATL. ATL. ATL, BAS, CK, VPC. FAB. FAB. ATL. FAB. FAB. FAB. ATL. ATL. ATL. ATL. BAS, CK, FAB, VPC. LVR. FAB. ATL, CK, FAB. ATL, CK, FAB. ATL. ATL. FAB. ATL, BAS, CK, FAB, VPC.

Disperse dyes Disperse yellow dyes: Disperse Yellow 3 Disperse Yellow 23 Disperse Yellow 34 Disperse Yellow 42 Disperse Yellow 54 Disperse Yellow 64 Disperse Yellow 77 Disperse Yellow 86 Disperse Yellow 88 Disperse Yellow 108 Disperse Yellow 125 Disperse Yellow 126 Disperse Yellow 198 Disperse Yellow 210 Disperse Yellow 219 Disperse Yellow 238 Disperse Yellow 239 All other disperse yellow dyes Disperse orange dyes: Disperse Orange 3 Disperse Orange 5

Yes No No No No No No No No No No No No No No No No No No No No No

CK. ATL, CK. EKT. CGY. BAS. BAS. VPC. EKT. EKT. EKT. SDC. ICI. BAS. S. S. CK. CK. BAS, CK, ICI, VPC. ATL, CK. ATL.

See footnotes at end of table.

4-12

4-12

Synthetic Organic Chemicals, 1987 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics

Manufacturers' identification codes (according to list in table 14)

Disperse dyes—Continued

Disperse orange dyes—Continued Disperse Orange 17 Disperse Orange 25 and 25:1 Disperse Orange 29 Disperse Orange 30 Disperse Orange 37 Disperse Orange 41 Disperse Orange 44 and 44:1 Disperse Orange 73 Disperse Orange 89 Disperse Orange 94 Disperse Orange 136 Disperse Orange 138 Disperse Orange 145 All other disperse orange dyes Disperse red dyes: Disperse Red 1 Disperse Red 5 Disperse Red 13 Disperse Red 17 Disperse Red 30 Disperse Red 35 Disperse Red 40 Disperse Red 50 Disperse Red 55 Disperse Red 60 Disperse Red 65 Disperse Red 73 Disperse Red 74 Disperse Red 88 Disperse Red 91 Disperse Red 112 Disperse Red 117 Disperse Red 133 Disperse Red 135 Disperse Red 136 Disperse Red 137 Disperse Red 145 Disperse Red 153 Disperse Red 159 Disperse Red 167 and 167:1 Disperse Red 177 Disperse Red 179 Disperse Red 195 Disperse Red 263 Disperse Red 274 Disperse Red 278 Disperse Red 305 Disperse Red 307 Disperse Red 309 Disperse Red 311 Disperse Red 313 Disperse Red 316 Disperse Red 325 Disperse Red 333 Disperse Red 338 Disperse Red 339

No No No No Yes No Yes No No No No No No No Yes No No No No No No No No No No No Yes No No No No No Yes No No No No No No Yes Yes No No No No No No No No No No No No No No No

ATL. ATL, CK, ICI, VPC. ATL, CK. ATL, BUC, CGY, CK, S. ATL, CK, EKT. CGY, S. ATL, CGY, CK, S, SDC. ATL, BAS. CK. S. EKT. EKT. EKT. CGY, CK. ATL, CK, EKT. ATL, CK. ATL. ATL, CK. EKT. EKT. VPC. CK. BAS, VPC. BAS. CK. ATL, CK, ICI,S. S. EKT. BAS. HCL. EKT. VPC. CK. EKT. EKT. CK. S, SDC. VPC. ATL, CGY, CK, S. CK, ICI, S, VPC(E). BAS, S. S. BAS. S. ICI. EKT. EKT. EKT. ICI. S. S. CK. S. EKT. EKT.

See footnotes at end of table.

4-13

4-13

Section 4 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Disperse dyes—Continued

Disperse red dyes—Continued Disperse Red 340 Disperse Red 345 All other disperse red dyes Disperse violet dyes: Disperse Violet 1 Disperse Violet 17 Disperse Violet 28 Disperse Violet 33 Disperse Violet 36 Disperse Violet 60 All other disperse violet dyes Disperse blue dyes: Disperse Blue 3 Disperse Blue 27 Disperse Blue 56 Disperse Blue 60 Disperse Blue 62 Disperse Blue 64 Disperse Blue 72 Disperse Blue 73 Disperse Blue 79 Disperse Blue 95 Disperse Blue 102 Disperse Blue 118 Disperse Blue 122 Disperse Blue 148 Disperse Blue 200 Disperse Blue 281 Disperse Blue 284 Disperse Blue 291 Disperse Blue 337 Disperse Blue 338 Disperse Blue 359 Disperse Blue 360 All other disperse blue dyes Disperse green dyes: Disperse Green 9 All other disperse green dyes Disperse brown dyes: Disperse Brown 1 Disperse Brown 18 Disperse Brown 22 Disperse Brown 26 Disperse Brown 27 Disperse black dyes Disperse Black 9 Disperse Black 33 All other disperse black dyes

No No No Yes No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No

EKT. CK. BAS CK, EKT, FAB, VPC.

No No No No No

ICI. HCL. HCL. ICI. HCL.

CK. CK. CK. ICI. S. S. CGY. CK, EKT, FAB. EKT. CK, S. BAS. EKT. EKT. BAS. S. BAS, CGY, CK, EKT, HCL, ICI, S. HCL. CK, EKT. EKT. ICI. BAS. ICI. CGY, S, SDC. ICI. S. EKT. EKT. CK. CK. ATL, BAS, BUC, CK, ICI, VPC(E). ICI. CK. ATL, BUC, CK, ICI, S. S. EKT. CK. CK. ATL, CGY, EKT. CGY. BAS, CK.

Fiber-reactive dyes Reactive yellow dyes: Reactive Yellow 7 Reactive Yellow 15 Reactive Yellow 17 Reactive Yellow 18 Reactive Yellow 37 See footnotes at end of table.

4-14

4-14

Synthetic Organic Chemicals, 1987 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Fiber-reactive dyes—Continued

Reactive yellow dyes—Continued Reactive Yellow 42 Reactive Yellow 57 Reactive Yellow 86 Reactive Yellow 125 Reactive Yellow 133 Reactive Yellow 135 Reactive Yellow 160 All other reactive yellow dyes Reactive orange dyes: Reactive Orange 1 Reactive Orange 4 Reactive Orange 12 Reactive Orange 13 Reactive Orange 14 Reactive Orange 16 Reactive Orange 20 Reactive Orange 78 Reactive Orange 84 Reactive Orange 86 All other reactive orange dyes Reactive red dyes: Reactive Red 2 Reactive Red 11 Reactive Red 21 Reactive Red 29 Reactive Red 31 Reactive Red 33 Reactive Red 35 Reactive Red 41 Reactive Red 43 Reactive Red 49 Reactive Red 94 Reactive Red 120 Reactive Red 141 Reactive Red 147 Reactive Red 180 All other reactive red dyes Reactive violet dyes: Reactive Violet 5 All other reactive violet dyes Reactive blue dyes: Reactive Blue 3 Reactive Blue 4 Reactive Blue 5 Reactive Blue 7 Reactive Blue 13 Reactive Blue 19 Reactive Blue 21 Reactive Blue 38 Reactive Blue 41 Reactive Blue 71 Reactive Blue 89 Reactive Blue 173 Reactive Blue 174 Reactive Blue 199 Reactive Blue 203 All other reactive blue dyes

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

HCL. HCL. ICI. S. ICI. ICI. HCL. HCL, ICI. ICI. ICI. ICI. ICI. ICI. ATL, CK, HCL. CK. HCL. ICI. ICI. HCL. CK, ICI. CK, ICI. HCL. ICI. ICI. ICI. HCL. HCL. CK, ICI. HCL. HCL. BAS, CK, ICI. ICI. S. ATL, HCL. CK, HCL, ICI. HCL. HCL, ICI. ICI. CK, ICI. ICI. CGY. ICI. HCL. HCL. HCL. S. ICI. HCL, ICI. ICI. ICI. ICI. HCL. HCL, ICI.

See footnotes at end of table.

4-15

4-15

Section 4 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Fiber reactive dyes—Continued Reactive green dyes: Reactive Green 12 Reactive Green, 19 All other reactive green dyes Reactive brown dyes: Reactive Brown I Reactive Brown 17 Reactive Brown 18 Reactive black dyes: Reactive Black 5 Reactive Black 9 All other reactive black dyes

No No No No No No No No No No No No

S. ICI. HCL. ICI. ICI. HCL. ATL, CK, HCL, S. ICI. HCL.

Fluorescent brighteners Fluorescent Brightener 22 Fluorescent Brightener 28 Fluorescent Brightener 46 Fluorescent Brightener 49 Fluorescent Brightener 52 Fluorescent Brightener 61 Fluorescent Brightener 71 Fluorescent Brightener 102 Fluorescent Brightener 128 Fluorescent Brightener 134 Fluorescent Brightener 205 Fluorescent Brightener 290 All other fluorescent brighteners

No No No No No No No No No No No No No

CGY. CGY, VPC. CGY. S. S. ACY. CGY. CGY. SDH. CGY. VPC. S. ACY, CGY, S, ( 2 ).

Food drug, and cosmetic colors Food, drug, and cosmetic dyes: Food, Drug, and Cosmetic Blue 1 Food, Drug, and Cosmetic Blue 2 Food, Drug, and Cosmetic Green 3 Food, Drug, and Cosmetic Red 3 Food, Drug, and Cosmetic Red 4 Food, Drug, and Cosmetic Red 40 Food, Drug, and Cosmetic Yellow 5 Food, Drug, and Cosmetic Yellow 6 Drug and cosmetic dyes Drug and Cosmetic Green 5 Drug and Cosmetic Green 8 Drug and Cosmetic Orange 4 Drug and Cosmetic Orange 5 Drug and Cosmetic Orange 17 Drug and Cosmetic Red 3 Drug and Cosmetic Red 6 Drug and Cosmetic Red 7 Drug and Cosmetic Red 9 Drug and Cosmetic Red 17 Drug and Cosmetic Red 19 Drug and Cosmetic Red 21 Drug and Cosmetic Red 22 Drug and Cosmetic Red 27 Drug and Cosmetic Red 28 Drug and Cosmetic Red 30 Drug and Cosmetic Red 33

Yes No No No Yes No No Yes Yes Yes No No No No No No No No No No No No No Yes No No Yes

KON, SDH, WJ. KON, SDH, WJ KON, WJ. SDH, STG, WJ. CK, WJ. KON, SDH, STG, WJ. CK, MAX, SDH, STG, WJ. CK, KON, MAX, SDH, STG, WJ. CK, KON. SDH. KON. SNA. SNA. KON. KON, SDH, SNA. KON, MAX, SDH, SNA. SNA. KON. SNA. SNA. SDH. KON, MAX, SDH, SNA. SDH. KON, MAX, SDH, SNA. CK, KON, SNA, WJ.

See footnotes at end of table.

4-16

4-16

Synthetic Organic Chemicals, 1987 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' Identification codes (according to list in table 14)

Food, drug, and cosmetic dyes—Continued Drug, and cosmetic dyes—Continued

Drug and Cosmetic Red 34 Drug and Cosmetic Red 36 Drug and Cosmetic Yellow 5 Drug and Cosmetic Yellow 6 Drug and Cosmetic Yellow 8 Drug and Cosmetic Yellow 10 Drug and cosmetic dyes, external: External Drug and Cosmetic Orange 3 External Drug and Cosmetic Yellow 7

No No No No No Yes

KON, SNA. KON, SDH. KON. KON. SDH. CK, KON, SDH, WJ.

No No

CK, KON. KON.

Mordant dyes Mordant yellow dyes: Mordant Yellow 1 Mordant Yellow 8 Mordant Yellow 20 Mordant orange dyes: Mordant Orange 1 Mordant Orange 6 Mordant red dyes: Mordant Red 7 Mordant Red 9 Mordant brown dyes: Mordant Brown 1 Mordant Brown 18 Mordant Brown 33 Mordant Brown 70 Mordant black dyes: Mordant Black 9 Mordant Black 11

No No No No No No No No No No No No No No No No No No

FAB. FAB. FAB. FAB. FAB. FAB. MAX. ATL, FAB. FAB. FAB. FAB. ATL. CGY.

Solvent dyes

Solvent yellow dyes: Solvent Yellow 3 Solvent Yellow 13 Solvent Yellow 14 Solvent Yellow 16 Solvent Yellow 33 Solvent Yellow 40 Solvent Yellow 42 Solvent Yellow 43 Solvent Yellow 44 Solvent Yellow 56 Solvent Yellow 72 Solvent Yellow 94 Solvent Yellow 107 Solvent Yellow 131 Solvent Yellow 135 Solvent Yellow 143 Solvent Yellow 160 Solvent Yellow 161 Solvent Yellow 163 All other solvent yellow dyes Solvent orange dyes: Solvent Orange 2 Solvent Orange 3

Yes No No No No No No No No No No No No No No No No No No No No Yes No No

PSC. BAS, FAB. ATL, PSC. PSC. ACY, CIC, MRT. CK. ATL, CK. DGO, HCL. DGO. PSC. CIC, MRT, PSC. SDH. MRT. DGO. (2) . MRT. (2) . MRT. MRT. ATL, CIC, FAB, MIL, MRT, PSC. PSC. ATL, PSC.

See footnotes at end of table.

4-17

4-17

Section 4 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Solvent dyes—Continued

Solvent orange dyes—Continued Solvent Orange 7 Solvent Orange 20 Solvent Orange 23 Solvent Orange 25 Solvent Orange 31 Solvent Orange 60 Solvent Orange 74 Solvent Orange 77 Solvent Orange 97 All other solvent orange dyes Solvent red dyes: Solvent Red 1 Solvent Red 22 Solvent Red 23 Solvent Red 24 Solvent Red 26 Solvent Red 27 Solvent Red 42 Solvent Red 49 Solvent Red 68 Solvent Red 74 Solvent Red 111 Solvent Red 164 Solvent Red 165 Solvent Red 166 Solvent Red 168 Solvent Red 169 Solvent Red 175 Solvent Red 207 Solvent Red 208 Solvent Red 210 Solvent Red 222 All other solvent red dyes Solvent violet dyes: Solvent Violet 8 Solvent Violet 9 Solvent Violet 13 Solvent Violet 14 Solvent Violet 38 All other solvent violet dyes Solvent blue dyes: Solvent Blue 3 Solvent Blue 5 Solvent Blue 35 Solvent Blue 36 Solvent Blue 38 Solvent Blue 58 Solvent Blue 59 Solvent Blue 98 Solvent Blue 99 Solvent Blue 100 Solvent Blue 102 Solvent Blue 128 Solvent Blue 129 All other solvent blue dyes Solvent green dyes: Solvent Green 3

No No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No No No No No No No No

ATL, PSC. BAS, FAB. ATL, CK. MRT. PSC. CIC. MRT. MRT. MRT. MIL. PSC. BAS. MRT, PSC. ATL, PSC. PSC. PSC. SDH. ACY, BAS. ATL, CK, MRT. ATL. MRT. MRT. MRT. MRT. MRT. MRT. MRT. MRT. MRT. MRT. CIC. CIC, MIL, MRT, PSC. DSC. DSC. CK. MRT. MRT. MIL. PSG. DSC. MRT. MRT. TNI. MRT, VPC. VPC. MRT. MRT. MRT. MRT. MRT. MRT. BAS, CK, MIL. MRT.

See footnotes at end of table.

4-18

4 18 -

Synthetic Organic Chemicals, 1987 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list In table 14)

Solvent dyes—Continued

Solvent brown dyes: Solvent Brown 12 Solvent Brown 20 Solvent Brown 22 Solvent Brown 52 Solvent black dyes: Solvent Black 7 Solvent Black 13 Solvent Black 26 Solvent Black 46 Solvent Black 47 Solvent Black 49

No No No No No No No No No No No No

PSC. ATL. PSC. MRT. OCC, PSC. ATL. ATL. MRT. MRT. MRT.

Sulfur dyes

Sulfur yellow dyes: Leuco Sulfur Yellow 22 All other sulfur yellow dyes Sulfur orange dyes: All other sulfur orange dyes Sulfur red dyes: Leuco Sulfur Red 14 Sulfur Red 10 Sulfur blue dyes: Leuco Sulfur Blue 7 Leuco Sulfur Blue 11 Sulfur green dyes: Leuco Sulfur Green 3 Leuco Sulfur Green 16 Leuco Sulfur Green 34 Leuco Sulfur Green 35 Leuco Sulfur Green 36 Sulfur brown dyes: Leuco Sulfur Brown 1, 1:1 Leuco Sulfur Brown 3 Leuco Sulfur Brown 10 Leuco Sulfur Brown 37 Leuco Sulfur Brown 52 Sulfur black dyes: Leuco Sulfur Black 1 Leuco Sulfur Black 2 Leuco Sulfur Black 18 Solubilized Sulfur Black 2 Sulfur Black 1 Sulfur Black 11, 11:1

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

SDC. SDC. SDC. SDC. SDC. SDC. SDC, VPC. SDC SDC. SDC. SDC. SDC. SDC. SDC. SDC. SDC. SDC. BRR, SDC. SDC. SDC. SDC. BRR. SDC.

Vat dyes

Vat yellow dyes• Vat Yellow 22, 10% Vat Yellow 51 Vat orange dyes: Vat Orange 2, 12% Vat Orange 7, 11% Vat red dyes: Vat Red 1, 13% Vat Red 10, 18% Vat Red 15, 10% Vat Red 32, 20% All other vat red dyes

Yes No No Yes No No Yes No No No No No

VPC(E). SDC. BAS. HCL. ACY. BAS. HCL. BAS. HCL, SDC.

4-19

See footnotes at end of table.

4-19

Section 4 Table 13—Continued Dyes for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Dyes

Separate statistics'

Manufacturers' identification codes (according to list in table 14)

Vat dyes—Continued Vat violet dyes: Vat Violet 13, 6-1/4% Vat blue dyes: Vat Blue 1, 20% Vat Blue 6, 8-1/3% Vat Blue 16, 16% Vat Blue 19 Vat Blue 29 Vat Blue 43 Vat Blue 66 Vat green dyes: Vat Green 1, 6% Vat Green 3, 10% Vat Green 7 Vat brown dyes: Vat Brown 57, 12.8% All other vat brown dyes Vat black dyes: Vat Black 16 Vat Black 25, 12-1/2%

No No Yes No No No No No No No Yes No No No No No No No No No

BAS, CGY. BCC, PSC. BAS, BRR. BAS. BAS. BAS. SDC. BAS. BAS. BAS, SDC. SDC. CGY, HCL. HCL. CGY. BAS, SDC.

Miscellaneous dyes All other dyes

Yes

DAN, MIL, MRT.

Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published by "No." 2 The manufacturer did not consent to his identification with the designated product. Source: Compiled from data received in response to questionnaire of the U.S. International Trade Commission.

4-20

4 20 -

Synthetic Organic Chemicals, 1987 Table 14 Dyes:

Code ACY ALL ATL BAS BCC BRR BUC CGY CIC CK DAN DGO DSC EKT FAB HCL

ICI KON

Directory of manufacturers, alphabetical by code, 1987

Name of company American Cyanamid Co. Alliance Chemical, Inc. Atlantic Industries, Inc. BASF Corp. Buffalo Color Corp. Burris Chemical Inc., Colors Div. Synalloy Corp., Blackman Uhler Chemical Div. Ciba-Geigy Corp. Color Chem International Corp. Crompton & Knowles Corp. Dan River, Inc., Chemical Products Div. Day-Glo Color Corp. Dye Specialties, Inc. Eastman Kodak Co., Tennessee Eastman Co. Div. Fabric°lor Manufacturing Corp. Hoechst Celanese Corp.: Rhode Island Works Sou-Tex Works ICI Americas, Inc., Chemical Div. H. Kohnstamm & Co., Inc.

Code

Name of company

LVR MAX MIL MRT

C. Lever Co., Inc. Max Marx Color Corp.

OCC PCW PSC PSG S SDC SDH SNA STG

TNI VPC WJ

Milliken & Co., Milliken Chemical Div. Morton-Thiokol, Inc., Morton Chemical Div. Orient Chemical Corp. Pfister Chemical, Inc. Passaic Color & Chemical Co. PMC Specialities Group, Inc. Sandoz, Inc.: Colors & Chemicals Div. Sandoz Chemical Corp. Sterling Drug Inc., SDI Divestiture Corp. Sun Chemical Corp., Pigments Div. McCormick & Co., Inc., McCormick/Strange Flavor Div. Gillette Co., Chemical Div. Mobay Chemical Corp., Dyes & Pigments Div. Warner-Jenkinson Co.

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaire of the U.S. International Trade Commission.

4-21

4-21

4-22

Synthetic Organic Chemicals, 1987

Section 5 Organic Pigments Organic pigments are toners and lakes 1 derivnwholpatfrmbenzoid chemicals and colors. Statistics on production and sales of all organic pigments in 1987 are given in table 15. Individual toners and lakes are identified in this report by the names used in the third edition of the Colour Index. Total production of organic pigments in 1987 was 93.9 million pounds, 6.1 percent more than the 88.5 million pounds produced in 1986. Total sales of organic pigments in 1987 amounted to 83.3 million pounds, valued at $586.3 million, compared with 76.7 million pounds, valued at $513.1 million, in 1986. In terms of quantity, sales of organic pigments in 1987 were 8.6 percent higher than in 1986; in terms of value, sales in 1987 were 14.2 percent higher than in 1986. Changes in U.S. production of pigment has followed overall changes in U.S. economic activity during 1983-87 (see figure 6). Production of toners in 1987 amounted to 93.1 million pounds, 6.0 percent more than the 87.8 million pounds reported in 1986. Sales in 1987 were 82.7 million pounds, valued at $582 million, compared with 76.7 million pounds valued at $509.1 million, in 1986. In terms of

quantity, sales of toners in 1987 were 8.6 percent higher than in 1986; in terms of value, sales in 1987 were 14.3 percent higher in 1987 than in 1986. The individual toners listed in the report which were produced in the largest quantities in 1987 were Pigment Yellow 12, Pigment Blue 15.3, beta form, Pigment Red 49:1 barium toner, Pigment Red 57:1 calcium toner, Pigment Red 53:1, barium toner, and Pigment Yellow 14. Production of lakes totaled 778,000 pounds in 1987, 12.1 percent higher than the 694,000 pounds reported for 1986. Sales of lakes in 1987 amounted to 571,000 pounds, valued at $4.2 million. In terms of quantity, sales of lakes in 1987 were 7.3 percent higher than in 1986; in terms of value, sales in 1987 were 5.2 percent higher than in 1986. Table 16 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 17. Stephen Wanser 202-252-1363 1 Toners and lakes are essentially the same in their final form; they differ in the method of preparation. A lake is an organic pigment produced by the interaction of a soluble dye, a precipitant, and an absorptive inorganic substrate. A toner is an insoluble dye produced as a powder; some toners are extended by the inclusion of a solid diluent.

Figure 6 Organic pigments: U.S. production, 1983-87

Millions of pounds 100 90 80

20

10

1983

1984

1985

1986

1987

5-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

222-174 0 - 88 - 3 : 0L 3

5-1

Section 5 Table 15 Organic pigments: U.S. production and sales, 1987

Organic pigments

Production

Sales Quantity

1,000 pounds dry basis3

1,000 pounds dry basis3

Value'

Average Unit value2

1,000 dollars

Per pound

Grand Total

93,915

83,302

586,254

$7.04

Toners Total

93,137

82,731

582,037

7.04

Yellow toners, total

24,474

20,660

114,230

5.53

149 133 163 368 670

140 143 155 448 655

949 836 1,206 2,231 5,090

6.79 5.85 7.80 4.98 7.71

16,173 434 4,395 573 960 456

12,633 425 4,131 547 912 471

63,548 2,677 20,485 3,762 8,553 4,893

5.03 6.30 4.96 6:88 9.38 10.37

2,884

2,700

17,981

6.66

1,014 171 727 740 232

887 160 716 714 223

4,323 1,585 4,957 3,556 3,560

4.87 9.93 6.92 4.98 15.92

33,475

29,872

219,100

7.33

1,679 43 38 160 125 1,313 855 282 177

1,596 54 14 145 111 1,272 775 293 151

17,103 667 157 1,383 1,389 13,507 4,774 1,519 1,697

10.72 12.30 11.07 9.52 12.46 10.62 6.16 5.19 11.25

2,249

2,263

13,198

5.83

1,715

1,606

9,453

5.89

188

218

1,718

7.58

5,681

3,962

15,133

3.82

888

888

4,400

4.96

814

786

5,293

6.74

252

291

1,725

5.94

3,778

3,571

14,750

4.13

11,870 427 2,620

10,596 395 2,481

52,409 6,125 69,803

4.95 15.50 5-228.14

Acetoacetarylide yellows: Pigment Yellow 1, C.I. 11 680 Pigment Yellow 3, C.I. 11 710 Pigment Yellow 65, C.I. 11 740 Pigment Yellow 73, C.I. 11 738 Pigment Yellow 74, C.I. 11 741 Diarylide yellows: Pigment Yellow 12, C.I. 21 090 Pigment Yellow 13, C.I. 21 100 Pigment Yellow 14, C.I. 21 095 Pigment Yellow 17, C.I. 21 105 Pigment Yellow 83, C.I. 21 108 All other yellow toners Orange toners, total Pigment Orange 5, C.I. 21 075 Pigment Orange 13, C.I. 21 110 Pigment Orange 16, C.I. 21 160 Pigment Orange 46, C.I. 15 602 All other orange toners

..

Red toners, total Naphthol reds, total Pigment Red 2, C.I. 12 120 Pigment Red 17, C.I. 12 390 Pigment Red 22, C.I. 12 315 Pigment Red 23, C.I. 12 355 All other naphthol reds Pigment Red 3, C.I. 12 120 Pigment Red 4, C.I. 12 085 Pigment Red 38, C.I. 12 120 Pigment Red 48:1, barium toner, C.I. 15 865 Pigment Red 48:2, calcium toner, C.I. 15 865 Pigment Red 48:4, manganese toner, C.I. 15 865 Pigment Red 49:1, barium toner, C.I. 15 630 Pigment Red 49:2, calcium toner, C.I. 15 630 Pigment Red 52:1, calcium toner, C.I. 15 860 Pigment Red 52.2, manganese toner, C.I. 15 860 Pigment Red 53:1, barium toner, C.I. 15 585 Pigment Red 57:1, calcium toner, C.I. 15 850 Pigment Red 81, PMA, C.I. 45 160 All other red toners See footnotes at end of table.

5 2 -

Synthetic Organic Chemicals, 1987 Table 15-Continued Organic pigments: U.S. production and sales, 1987

Organic pigments

Value'

Average Unit value2

1,000 dollars

Per pound

Production

Sales Quantity

1,000 pounds dry basis3

1,000 pounds dry basis3

3,532

3,521

66,498

$18.89

31 467 2,161 484 389

30 477 2,177 471 366

539 5,148 44,430 12,600 3,781

17.70 10.79 20.41 26.78 10.33

26,138

23,125

141,378

6.11

72

74

1,050

14.12

1,281

925

7,612

8.23

981

937

10,963

11.70

520

598

5,914

9.88

13,073 10,211

11,180 9,411

59,069 56,770

5.28 6.03

2,332

2,535

21,101

8.32

2,180 152

2,370 165

18,699 2,402

7.89 14.61

302

318

1,749

5.50

778

571

4,217

7.39

29 69 680

35 69 467

437 636 3,144

12.43 9.22 6.73

Toners-Continued Violet toners, total Pigment Violet 1, PTA, C.I. 45 170 Pigment Violet 3, (PMA), C.I. 45 535 Pigment Violet 19, C.I. 73 900 Pigment Violet 23, C.I. 51 319 All other violet toners Blue toners, total Pigment Blue 1, (PMA), C.I. 42 595 Pigment Blue 15, alpha form, C.I. 74 160 Pigment Blue 15:1, alpha form, C.I. 74 160 Pigment Blue 15:2, alpha form, C.I. 74 160 Pigment Blue 15:3, beta form, C.I. 74 160 All other blue toners Green toners, total Pigment Green 7, C.I. 74 260 All other green toners Brown and black toners, Lakes Total Pigment Red 83, C.I. 58 000 Pigment Violet 5:1, C.I. 58 055 All other lakes

1 The value of sales for toners is reported on a dry full-strength basis and the value of sales for lakes is reported on a dry form basis. All sales value data exclude the additional cost of processing or packaging in commercial forms other than the dry full-strength or dry form. 2 Calculated from unrounded figures. 3 Quantities for toners are reported as dry full-strength toner content, excluding the weight of any dispersing agent, vehicle, or extender. Quantities for lakes are reported as dry lake content, excluding the weight of any dispersing agent or vehicle. Note.-The C.I. (Colour Index) number shown in this report are the identifying number given in the third edition of the Colour Index. The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) acids, respectively.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

5-3

5-3

Section 5 Table 16 Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Organic pigments

Separate statistics

Manufacturers' Identification codes (according to list in table 17)

Toners

Yellow toners: Acetoacetarylide yellows: Pigment Yellow 1 Pigment Yellow 2 Pigment Yellow 3 Pigment Yellow 42 Pigment Yellow 60 Pigment Yellow 65 Pigment Yellow 73 Pigment Yellow 74 Pigment Yellow 97 Pigment Yellow 98 All others acetoacetarylide yellows Diarylide yellows: Pigment Yellow 12

No Yes No Yes No No Yes Yes Yes No No No No Yes

Pigment Yellow 13

Yes

Pigment Yellow 14

Yes

Pigment Yellow 17

Yes

Pigment Yellow 83

Yes

Pigment Yellow 124 Pigment Yellow 126 Pigment Yellow 152 Yellow pigments, other: (Basic Yellow 2), fugitive Pigment Yellow 110 Pigment Yellow 139 All other pigment yellow toners Orange toners: Pigment Orange 1 Pigment Orange 2 Pigment Orange 5 Pigment Orange 13 Pigment Orange 15 Pigment Orange 16

No No No Yes No No No No Yes No No Yes Yes No Yes

Pigment Orange 34 Pigment Orange 43 Pigment Orange 46 Pigment Orange 48 Pigment Orange 49 All other pigment orange toners Red toners: Naphthol reds: Pigment Red 2 Pigment Red 5 Pigment Red 13 Pigment Red 14 Pigment Red 17 Pigment Red 21 Pigment Red 22 Pigment Red 23

No No Yes No No No Yes Yes Yes No No No Yes No Yes Yes

See footnotes at end of table.

5-4

HSH, KCW, SNA, VPC. KCW. HCL, HEU, HSH, KCW, SNA, VPC. CGY, VPC. HSH. HEU, HSH, SNA, VPC. HCL, HSH, SNA, VPC. BAS, HCL, HEU, HSH, KCW, ROM, SDH, SNA, VPC. HCL. HCL. HCL, KCW. AMS, APO, BAS, GLX, HCL, HSH, IDC, IND, POP, ROM, SDH, SNA. APO, BAS, FAB, GLX, HCL, IDC, IND, SNA. AMS, BAS, BNS, FAB, GLX, HCL, HSH, IDC, IND, ROM, SNA. AMS, APO, BAS, CGY, FAB, GLX, HCL, HSH, IDC, IND, ROM, SNA, VPC. BAS, FAB, GLX, HCL, IDC, IND, ROM, SNA. GLX. HCL. HCL. MAX. CGY. COY. HSH. KCW. UHL. BAS, CGY, HCL, HSH, SDH, SNA. BAS, HSH, IND, ROM, SNA, VPC. BNS, CGY. BNS, CGY, FAB, GLX, HSH, IND, MGR, ROM, VPC. IND, ROM VPC. HCL, MGR. ALE, AMS, BAS, CMC, SNA UHL. CGY. CGY. GLX.

GLX, HCL, HSH. CGY, FAB, HSH. KCW. HCL. BNS, IND, ROM, SNA, UHL. BNS. GLX, HEU, IND, MAX, SNA. FAB, GLX, HEU, HSH, KCW, ROM, SNA, UHL. 5-4

Synthetic Organic Chemicals, 1987 Table 16—Continued Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Separate statistics I

Manufacturers' identification codes (according to list in table 17)

Naphthol reds—Continued Pigment Red 31 Pigment Red 66 Pigment Red 112 Pigment Red 146 Pigment Red 147 Pigment Red 170 All other naphthol reds

No No No No No No Yes

GLY, ROM, SDH. CGY. HCL, VPC. HCL. HSH. GLX, HCL. BUC, FAB, GLX, IND, ROM, SNA, (2) .

Red pigments, other: Pigment Red 1, (light) Pigment Red 3

No No Yes

Organic pigments Toners—Continued Red toners—Continued

Pigment Red 4

Yes

Pigment Red 6 Pigment Red 38 Pigment Red 41 Pigment Red 48 Pigment Red 48:1, (barium)

No Yes No No Yes

Pigment Red 48:2, (calcium)

Yes

Pigment Red 48:3, (strontium) Pigment Red 48:4, (manganese) Pigment Red 49:1, (barium)

No Yes Yes

Pigment Red 49:2, (calcium)

Yes

Pigment Red 52:1, (calcium) Pigment Red 52:2, (manganese) Pigment Red 53:1, (barium)

Yes Yes Yes

Pigment Red 57 Pigment Red 57:1, (calcium)

No Yes

Pigment Red 63 Pigment Red 81, (PMA) Pigment Red 81, (PTA) Pigment Red 88 Pigment Red 119 Pigment Red 122 Pigment Red 123 Pigment Red 168 Pigment Red 169 Pigment Red 179 Pigment Red 190 Pigment Red 200 Pigment Red 202 Pigment Red 206 Pigment Red 207 Pigment Red 209 Pigment Red 224 Pigment Red 245 Pigment Red 63:1, calcium All other pigment red toners

No Yes No No No No No No No No No No No No No No No No No No

HSH. BAS, CGY, HSH, KCW, MAX, SNA, UHL. ALE, BAS, CGY, HSH, KCW, MAX, SDH, UHL. SDH. HCL, HSH, SNA, VPC. UHL, VPC. CGY, HEU. AMS, APO, BAS, CGY, CMC, HEU, HSH, MGR, MAX, SNA, UHL. AMS, APO, BAS, CGY, HEU, HSH, MGR, MAX, SDH, SNA, UHL, VPC. BAS, CGY, HSH. CGY, HEU, HSH, SNA, VPC. AMS, BAS, BNS, CMC, IDC, MGR, SDH, SNA, UHL. AMS, BNS, CMC, IDC, MGR, SDH, SNA, UHL. BAS, HSH, MGR, SNA, UHL. BAS, CGY, HSH, UHL. ALE, AMS, APO, BAS, CMC, FAB, HSH, IDC, MGR, MAX, SDH, SNA, UHL. BNS. AMS, APO, BAS, BNS, CGY, CMC, FAB, HEU, HSH, IDC, KCW, MGR, POP, SDH, SNA, UHL. HSH. BAS, MGR, MAX, SNA, UHL. BAS, MGR, MAX, UHL. VPC. VPC. SNA, VPC. VPC. VPC. MAX. VPC. VPC. BAS, SNA. CGY, SNA, VPC. CGY. CGY. SNA. VPC. IND. SNA. BAS.

5-5

See footnotes at end of table.

5-5

Section 5 Table 16—Continued Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Organic pigments

Separate statistics

Manufacturers' identification codes (according to list in table 17)

Toners—Continued Violet toners: Pigment Violet 1, (fugitive) Pigment Violet 1, (PMA) Pigment Violet 1, (PTA) Pigment Violet 3, (fugitive) Pigment Violet 3, (PMA) Pigment Violet 3, (PTA) Pigment Violet 4, (fugitive) Pigment Violet 19 Pigment Violet 23 Pigment Violet 27 Pigment Violet 29 Pigment Violet 39, (PMA) Pigment Violet 42 All other pigment violet toners Blue toners: (Basic Blue 7) Pigment Blue 1, (PMA) Pigment Blue 2, (PMA) Pigment Blue 14, (PMA) Pigment Blue 15, (a form)

Yes No No Yes No Yes No No Yes Yes No No No No No Yes No Yes No No Yes

Pigment Blue 15:1, (ot form) Pigment Blue 15:2, (a form) Pigment Blue 15:3, (a form)

Yes Yes Yes

Pigment Blue 15:4, (13 form) Pigment Blue 19 Pigment Blue 25 Pigment Blue 61 Pigment Blue 62 All other pigment blue toners Green toners: Pigment Green 1, (PMA) Pigment Green 2, (PTA) Pigment Green 4, (fugitive) Pigment Green 4, (PMA) Pigment Green 7

No No No No No No Yes No No No No Yes

Pigment Green 8 Pigment Green 10 Pigment Green 36 All other pigment green toners Brown toners: Pigment Brown 5 All other pigment brown toners Black toners: Pigment Black 7 All other pigment black toners

No No No No No No No No No No

KCW, UHL. MGR, MAX, UHL. MGR, MAX, SNA, UHL. KCW, MGR, UHL. BAS, MGR, MAX, SDH, UHL. MGR, MAX, UHL. KCW. CGY, SNA, VPC. BUC, HCL, IPP, S, SNA, VPC. MRX. VPC. BAS, ( 2 ). CGY. BUC. KCW. BNS, MGR, MRX, SDH, UHL. UHL. BAS, UHL. BAS, CGY, HEU, HSH, SDH, SNA, TMS, VPC. CGY, SNA, VPC. CGY, HEU,SDH, SNA, UHL, VPC. AMS, APO, BAS, CGY, CIK, CMC, HEU, IDC, IPP, MGR, POP, ROM, SDH, SNA, VPC. CGY, HEU, POP, SNA, VPC. PSG. GLX. BAS. MRX. FAB. UHL. MAX, UHL. UHL. UHL. ALG, CGY, HEU, MGR, POP, SDH, SNA, VPC. KCW. HEU. SNA, VPC. UHL, ( 2 ). GLX, VPC. UHL. HCL, VPC. UHL.

Lakes Yellow lakes: (Acid Yellow 1) (Acid Yellow 23) Orange lakes: Pigment Orange 17

No No No No No

KCW. MAX. KCW.

See footnotes at end of table.

5-6

5-6

Synthetic Organic Chemicals, 1987 Table 16—Continued Organic pigments for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Organic pigments

Separate statistics I

Manufacturers' identification codes (according to list in table 17)

Lakes—Continued Red lakes: (Acid Red 26) (Basic Red 1) (Basic Red 81, PMA) Pigment Red 60:1 Pigment Red 83 Violet lakes: (Basic Violet 1) (Basic Violet 4) (Basic Violet 10) (Basic Violet 3, PMA) (Basic Violet 5:1) Blue lakes: (Basic Blue 1, PTA) (Basic Blue 14, (PMA) Green lakes: (Basic Green 1, (PMA)

No No No No No Yes No No No No Yes No No No No No

KCW. BNS. LVR. HSH, MAX, SNA. HSH, MAX, UHL. BNS. BNS. BNS. LVR. HSH, MAX, UHL, VPC. LVR. LVR. LVR.

1 Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No." 2 The manufacturer did not consent to his identification with the designated product.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

5-7

5-7

Section 5 Table 17 Organic pigments:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ALE ALG AMS APO BAS BNS BUC

Alex Chemical Co Allegheny Chemical Corp. Ridgway Color Co. Apollo Colors, Inc. BASF Corp., Chemicals Div. Binney and Smith, Inc. Synalloy Corp., Blackman Uhler Chemical Div. Ciba-Geigy Corp. Flint Ink Corp., Cal/Ink Div. Chromatic Color Corp. Customs Pigments Corp. Fabricolor Manufacturing Corp. Galaxie Chemical Corp. Hoechst Celanese Corp.: Rhode Island Works Sou-Tex Works Heubach, Inc. Harshaw/Filtrol Partnership

IDC IND IPP KCW LVR MGR MAX POP PSG ROM S SDH

Industrial Color, Inc. Indol Color Co., Inc. Spectrachem Corp. Keystone Color Works, Inc. C. Lever Co., Inc. Magruder Color Co., Inc. Max Marx Color Corp. Pope Chemical Corp. PMC Specialities Group, Inc. Roma Color, Inc. Sandoz Inc. Colors and Chemicals Div. Sterling Drug, Inc., SDI Divestiture Corp. Sun Chemical Corp., Pigment Div. Paul Uhlich & Co., Inc. Mobay Chemical Corp., Dyes & Pigments Div.

CGY CIK CMC CUS FAB GLX HCL

HEU HSH

SNA UHL VPC

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

5-8

5-8

Synthetic Organic Chemicals, 1987

Section 6 Medicinal Chemicals Medicinal chemicals include the medicinal and feed grades of all organic chemicals having therapeutic value, whether obtained by chemical synthesis, by fermentation, by extraction from naturally occurring plant or animal substances, or by refining a technical grade product. They include antibiotics and other anti-infective agents, antihistamines, autonomic drugs, cardiovascular agents, central nervous system depressants and stimulants, hormones and synthetic substitutes, vitamins, and other therapeutic agents for human or veterinary use, and for animal feed supplements. Data for the production of these products during 1983-87 are shown in figure 7. Table 18 shows statistics for production and sales of medicinal chemicals grouped by pharmacological class. The statistics shown are for bulk chemicals only. Finished pharmaceutical preparations and products put up in pills, capsules, tablets, or other measured doses are excluded. 1 The difference between production and sales reflects inventory changes, processing losses, and captive consumption of medicinal chemicals processed into ethical and proprietary pharmaceutical products by the primary manufacturer. In some instances, the difference may also include quantities for medicinal grade products used as intermediates; for example, penicillin V used as an intermediate in the manufacture of other antibiotics. All quantities are given in terms of 100 percent content of the pure bulk drug. Table 19 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 20. Total U.S. production of bulk medicinal chemicals in 1987 amounted to 260.6 million

pounds. Total sales of bulk medicinal chemicals in 1987 amounted to 166.5 million pounds, valued at $ 1,534.1 million. Beginning in 1980, methionine and most other amino acids and their salts are reported in the section on Miscellaneous End-Use Chemicals and Chemical Products. Section totals are not, therefore, comparable with years prior to 1980. Production of the larger groups of medicinal chemicals in 1987 was as follows (see table 18): Antibiotics, 35.5 million pounds, 20.0 percent lower than in 1986; anti-infective agents other than antibiotics, 21.3 million pounds, 24.7 percent lower than in 1986; central nervous system depressants and stimulants, 71.9 million pounds, 2.7 percent higher than in 1986; gastrointestinal agents and therapeutic nutrients, 64.2 million pounds, 11.4 percent higher than in 1986; and vitamins, 51.3 million pounds, 24.5 percent higher than in 1986. Production of some of the more important individual products in the table was as follows: Choline chloride, 59.1 million pounds, 15.4 percent more than in 1986; and aspirin, 24.1 million pounds, 21 percent less.

Elizabeth R. Nesbitt 202-252-1355 Complementary statistics on the dollar value of manufacturers' shipments of finished pharmaceutical preparations, except biologicals, are published annually by the U.S. Department of Commerce, Bureau of the Census, in Current Industrial Reports, Series MA-28G. Many pharmaceutical manufacturers that report to the Bureau of the Census are excluded from the U.S. International Trade Commission report because they are not primary producers of medicinal chemicals; that is, they do not themselves produce the bulk drugs which go Into their pharmaceutical products, but purchase their drug requirements from domestic or foreign producers.

Figure 7 Medicinal Chemicals: U.S. production, 1983-87

Millions of pounds 300 270 240 210 180 150 120 90 60 30 0

6-1

1983 1984 1985 1986 1987 Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

6-1

Section 6 Table 18 Medicinal chemicals:

U.S. production and sales, 1987

Medicinal chemicals

Grand total Acyclic Benzenoid3 Cyclic nonbenzenoid 4 Antibiotics, total Penicillins, totals All other antibiotics, total For medicinal use6 For nonmedicinal uses? Antihistamines, total Antinauseants All other antihistamines Anti-infective agents (except antibiotics), total Antheimintics All other anti-Infective agents (except antibiotics) 6 Autonomic drugs, total Sympathomimetic (adrenergic) agents All other autonomic drugs Central depressants and stimulants, total

Analgesics, antipyretics, and nonhormonal anti-Inflammatory agents, total Aspirin All other analgesics, antipyretics, and nonhormonal anti-Inflammatory agents 1° Antidepressants Antitussives All other central depressants and stimulants" Dermatological agents Expectorants and mucolytic agents Gastrointestinal agents and therapeutic nutrients, total' 3 Choline chloride, all grades All other gastrointestinal agents and therapeutic nutrients Vitamins' 3 Miscellaneous medicinal chemicals"

Production'

Sales Quantity

Value

Average Unit value2

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

260,617

166,501

1,534 ,126

$9.21

64,588 136,450 59,579

62,668 76,080 27,753

169,196 752,666 612,264

2.70 9.89 22.06

35,499

11,487

439,035

38.22

10,242 25,257 5,787 19,470

816 10,671 2,448 8,223

25,183 413,852 314,308 99,544

30.86 38.78 128.39 12.11

364

238

33,378

140.24

49 315

34 204

1,259 32,119

37.48 157.47

21,263

8,712

38,215

4.39

9,010

4,124

4,448

1.08

12,253

4,588

33,767

7.36

819

631

17,304

27.42

790 29

625 6

15,271 2,033

24.43 338.83

71,852

50,785

351,402

6.92

62,455 24,089

46,171 (9)

146,524 ( 9)

3.17 (9)

38,366 168 296

46,171 25 357

146,524 2,832 48,583

3.17 113.28 136.09

8,933 6,636 1,031

4,232 5,854 914

153,463 13,372 8,092

36.26 2.28 8.85

64,206

61,288

58,996

.96

59,149

57,739

25,794

.44

5,057

3,549

33,202

7.66

51,330 7,617

23,593 2,999

132,215 442,117

5.60 147.42

' The data on production and sales are for bulk medicinal chemicals only. Methionine and most other amino acids and their salts are now reported in the section on Miscellaneous End-Use Chemicals and Chemical Products. Section totals are not, therefore, comparable with years prior to 1980. 2 Calculated from rounded figures. 3 Benzenoid, as used in this report, describes any cyclic medicinal chemical whose molecule contains either a 6-membered carbocyclic ring with conjugated double bonds or a 6-membered heterocyclic ring with 1 or 2 6-2 hetero atoms and conjugated double bonds, except the pyrimidine ring. 4 Includes antibiotics of unknown structure. 5 Includes semisynthetic penicillins and all other penicillins.

6-2

Synthetic Organic Chemicals, 1987 Footnotes for table 18—Continued Includes production and sales of antifungal and antitubercular antibiotics, tetracyclines, and cephalosporins. Includes production and sales of tetracyclines. 8 Includes production and sales of antiprotozoan agents, sulfonamides, and urinary antiseptics; does not include production of sulfaguanidine used as an intermediate in the production of anti-infective sulfonamides. Reported data were accepted in confidence and may not be published, or no data were reported. 10 Includes sales quantity and value of aspirin; also production and sales of acetaminophen. 11 Includes production and sales of amphetamines; general anesthetics; respiratory and cerebral stimulants; skeletal muscle relaxants; tranquilizers; and anticonvulsants, hypnotics, and sedatives. 12 Methionine and its salts are reported in the section in Miscellaneous End-Use Chemicals and Chemical Products under amino acids. 13 Includes production and sales of vitamin A, vitamin B, vitamin C, vitamin D, vitamin E, and vitamin K. 14 Includes production and sales of antineoplastic agents, cardiovascular agents, diagnostic agents, hematological agents, renal-acting and edema-reducing agents, and unclassified medicinal chemicals. Also includes production and sales of local anesthetics, smooth muscle relaxants (including theophylline derivatives), and hormones and synthetic substitutes. 8

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

6-3

6-3

Section 6 Table 19 Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals Antibiotics: Cephalosporins: Cefaclor Cefamandole Cefazolin, sodium Cefoxitin Cephalexin Cephalothin, sodium Cephapirin, sodium Cephradine Penicillins: Penicillins, semisynthetic Amoxicillin: Amoxicillin (trihydrate) Amoxicillin (anhydrous) Ampicillin: Ampicillin (anhydrous) Ampicillin (trihydrate) Other semisynthetic peniciilins: Ampicillin, sodium Carbenicillin, sodium Cloxacillin, benzathine Cloxacillin, sodium Dicloxacillin, sodium Hetacillin, potassium Nafcillin, sodium Oxacillin, sodium Piperacillin Ticarcillin, disodium Penicillins (execpt semisynthetic): For medicinal use: Penicillin V Penicillin G, benzathine Penicillin G, potassium Penicillin V, potassium Penicillin G, procaine (medicinal grade) For nonmedicinal uses: Penicillin G, procaine (animal feed grade) Tetracyclines: For medicinal use: Chlortetracycline (medicinal grade) Minocycline Oxytetracycline (medicinal grade) Tetracycline For nonmedicinal uses: Chlortetracycline (animal feed grade) Oxytetracycline (animal feed grade) Other antibiotics: For medicinal use: Antifungal antibiotics: Amphotericin B Nystatin (medicinal grade) Tobramyctn Antitubercular antibiotics: Cycloserine Dihydrostreptomycin Other antibiotics for medicinal use: Apramycin Azetreonam Bacitracin (medicinal grade) Cefonicid

Separate statistics 1

Manufacturers' identification codes (according to list in table 20)

Yes No No No No No No No No Yes

LIL. LIL. LIL. MRK. LIL. LIL. BRS. TRD, SK.

No No

BEE, BOC, BRS, KAN. BEE.

No No

BRS. BOC, BRS, KAN.

No No No No No No No No No No

BEE, BRS, WYT. BEW. BEE. BEE, BOC. BEE, BOC, WYT. BRS. BEE, BRS, WYT. BEE, BOC. BRS. BEE.

No No No No No

PFZ. WYT. PFZ. BRS, LIL. PFZ, WYT.

No

PFZ.

No No No No

ACY. ACY. PFZ. ACY.

No No Yes Yes

ACY, PFZ. PFZ.

No No No

PEN, TRD. ACY, TRD. LIL.

No No

LIL. PFZ.

No No No No

LIL. TRD. IMC. SK.

See footnotes at end of table.

6-4

6-4

Synthetic Organic Chemicals, 1987 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals

Separate statistics

Antibiotics—Continued Other antibiotics—Continued For medicinal use—Continued Other antibiotics for medicinal use—Continued Cefuroxime Clindamycin Erythromycin Erythromycin estolate Erythromycin stearate Gentamycin lmipenem Kanamycin Lincomycin (medicinal grade) Moxalactam Neomycin (medicinal grade) Netilmicin Novoblocin, sodium Polymyxin B Sisomycin Spectinomycin (medicinal grade) Thiostrepton Vancomycin All other antibiotics, for medicinal use For nonmedicinal uses: Bacitracin (animal feed grade) CycloheximIde Hygromycin B Lasalocid Lincomycin (animal feed grade) Monesin Neomycin (animal feed grade) Streptomycin Tylosin

No No No No No No No No No No No No No No No No No No No Yes No No No No No No No No No

Antihistamines: Antinauseants: Dimenhydrinate Meclizine hydrochloride Metoclopramide hydrochloride Trimethobenzamide hydrochloride Other antihistamines: Brompheniramine maleate Chlorpheniramine maleate Chlorpheniramine tannate Cyproheptadine hydrochloride Dexbrompheniramine maleate Dexchlorpheniramine maleate Dimethindene maleate Diphenhydramine citrate Diphenhydramine hydrochloride Doxylamine succinate Laradine Phenindamine tartrate Phenyltoloxamine citrate Pyrilamine maleate Pyrilamine tannate Terfenadine Tripelennamine Tripelennamine citrate Tripelennamine hydrochloride Triprolidine hydrochloride

Yes Yes No No No No Yes No No No No No No No No No No No No No No No No No No No No

Manufacturers' Identification codes (according to list in table 20)

LIL ABB, UPJ. ABB, UPJ. LIL. UPJ. SCH. MRK. BRS. UPJ. LIL. UPJ. SCH. UPJ. PFZ. SCH. UPJ. TRD. ABB, ACY, LIL. RSA. IMC. UPJ. LIL. HOF. UPJ. LIL. PFZ, UPJ. PFZ. LIL.

GAN. PFZ. LLI. HOF. HEX, LLI. HEX, SK. HEX. MRK. HEX. SCH. CGY. WYK. PD. BKC, HOF. SCH. HOF. BRS, GAN, PD. HEX. HEX. DOW. CGY. CGY. CGY. CGY.

See footnotes at end of table.

6-5

6-5

Section 6 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals

Anti-infective agents (except antibiotics): Anthelmintics: Clorsulon Diethylcarbamazine citrate Ivermectin Piperazine Piperazine dihydrochloride Piperazine hexahydrate Piperazine hydrochloride Piperazine sulfate Pyrantel pamoate Thiabendazole Antiprotozoan agents: Arsenic and bismuth compounds: Arsanilic acid Bismuth subsalicylate Nitarsone Roxarsone Roxarsone, sodium Other antiprotozoan agents: Aklomide Amprolium Dinitolmide Ethopabate Hydroxychloroquine sulfate lodochlorhydroxyquin Ipronidazole Nitromide Sulfonamides Mafenide Mafenide acetate Sulfabenzamide Sulfacetamide, sodium Sulfadiazine Sulfadiazine, silver Sulfadimethoxine Sulfamethazine Sulfamethazine, sodium Sulfamethizole Sulfamethoxazole Sulfanitran Sulfasalazine Sulfathiazole, sodium Sulfisoxazole Sulfisoxazole, acetyl Urinary antiseptics: Methenamine Methenamine hippurate Methenamine mandelate Other anti-infective agents: Antifungal agents: Benzoic acid Calcium undecylenate Sodium caprylate Zinc undecylenate All other antifungal agents AntileprotIc and antitubercular agents: Aminosalicylic acid Sodium aminosalicylate Sulfoxone, sodium

Separate statistics

Yes Yes No No No No No No No No No No Yes

Manufacturers' identification codes (according to list in table 20)

MRK. SK. MRK. TX, UCC. FLM. BRS. DAN, FLM. FLM. PFZ. MRK.

No No No No No

FLM. NOR. SAL. SAL. SAL.

No No No No No No No No

SAL. MRK. SAL. MRK. SDW. CGY. HOF. SAL.

No No No No No No No No No No No No No No No No

SDW. SDW. ACY. SCH. ACY. BOT, LEM. HOF. SAL. SAL. ACY. HOF, LEM. SAL. SAL. SAL. HOF. HOF.

No No No Yes

ARN. RIK. ARN, PD.

No No No No No

KLM. WTL. LEM. WTL. ARN.

No No No

HXL. HXL. ABB.

See footnotes at end of table.

6-6

6-6

Synthetic Organic Chemicals, 1987 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, Identified by manufactures, 1987

Medicinal chemicals

Anti-infective agents (except antibiotics)—Continued Other anti-Infective agents—Continued Antiviral agents: Acyclovir Azidothymidine Rimantidine hydrochloride All other antiviral agents General antiseptics and antibacterial agents: Bromchlorenone Capreomycin Ceftazidime Cetylpyridinium chloride Cinoxacin m-Cresyl acetate 8-Hydroxy-5-quinolinesulfonic acid lodoform Ormetoprim Oxyquinoline benzoate (benoxiquine) Oxyquinoline sulfate Pentamidine isethionate Povidone - iodine Resorcinol Trimethoprim Autonomic drugs: Sympathomimetic agents: Dobutamine hydrochloride Methoxyphenamine hydrochloride Naphazoline hydrochloride Phenylephrine bitartrate Phenylephrine hydrochloride Phenylpropanolamine bitartrate Phenylpropanolamine hydrochloride Propylhexedrine Pseudoephedrine hydrochloride Pseudoephedrine sulfate Terbutaline sulfate All other sympathomimetic (adrenergic) agents Other autonomic drugs: Parasympatholytic quaternary ammonium compounds (except tropane derivatives): Glycopyrrolate Propantheline bromide Tridihexethyl chloride Parasympatholytic tertiary amines (except tropane derivatives): Oxybutynin chloride Oxyphencyclimine hydrochloride Trihexyphenidyl hydrochloride Parasympatholytic tropane derivatives: Benztropine mesylate Parasympathomimetic agents: Bethanechol chloride Neostigmine bromide Neostigmine methylsulfate Pyridostigmine bromide Sympatholytic agents: Timolol maleate Central depressants and stimulants: Analgesics, antipyretics, and nonhormonal antiinflammatory agents: Acetaminophen

Separate statistics

Manufacturers' identification codes (according to list In table 20)

No No No No

BUR. BUR. HOF. (2).

No No No No No No No No No No No No No No No

MHI. LIL. LIL, MRK, SK. HXL. LIL. ADC. MRK. DPW, MAL. HOF. LEM. LEM. MRX. GAF. KPT, LEM. BUR, LEM.

Yes Yes No No No No No No No No No No No No Yes

LIL. HXL. CGY. GAN. GAN, SDW. ARS. ARS, GAN, HEX, NEP, ORT. SK. BUR, GAN. GAN. CGY, PFZ. ARN, SCH.

No No No

LL1. SRL. ACY.

No No No

ABB. PFZ. ACY.

No

MRK, ( 2).

No No No No

GAN. HOF. HOF. HOF.

No

MRK.

Yes Yes No

MAL, MON, SWD.

See footnotes at end of table.

6-7

6-7

Section 6 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals Central depressants and stimulants—Continued Analgesics, antipyretics, and nonhormonal antiinflammatory agents—Continued Aspirin Aurothioglucose Choline magnesium salicylate Diflunisal Fenoprofen Fentanyl citrate Flunixin Ibuprofen lndomethacin Meclofenamate, sodium Meclofenamic acid Mefenamic acid Meperidine hydrochloride Methadone hydrochloride Morphine sulfate Oxycodone hydrochloride Pentazocine Pentazocine hydrochloride Piroxicam Potassium aminobenzoate Potassium salicylate Propoxyphene hydrochloride Propoxyphene napsylate Salsalate Sodium aminobenzoate Sodium salicylate Suiindac Anticonvulsants, hypnotics, and sedatives: Anticonvulsants (except barbiturates): Aminogiutethimide Ethosuximide Ethotoin Methsuximide Phenytoin Phenytoin, sodium Valproate, sodium Valproic acid Anticonvulsants, hypnotics, and sedatives: Barbiturates: Amobarbital Amobarbital, sodium Butabarbital Butalbital Pentobarbital Phenobarbital Phenobarbital, sodium Poly (oxy-1 ,2-ethanediy1)-a-carboxymethyl, omega (tridecyloxy), potassium salt Secobarbital, sodium Thiamylal, sodium Thiopental, sodium Hypnotics and sedatives (except barbiturates): Alprazolam Droperidol Ethchlorvynol Glutethimide Methyprylon

Separate statistics I

Manufacturers' identification codes (according to list in table 20)

Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No

DOW, MON, NOR, SD. SCH. LEM. MRK. LIL, WYK. MRX. SCH. TNA. MRK. PD, WYK. PD. PD. PEN, SDW. MAL. MAL, PEN. DUP, MAL, PEN. SD. SD. PFZ. GAN. KLM. GAN, LIL. GAN, LIL. RIK, WYK. GAN. KLM. MRK.

No No No No No No No No No

CGY. PD. ABB. PD. PD. PD. ABB. ABB.

No No No No No No No

GAN. GAN. GAN. GAN. GAN. GAN. GAN.

No No No No

GAN. GAN. ABB, PD. ABB.

No No No No No

UPJ. MRX. ABB. GAN. HOF.

See footnotes at end of table.

6-8

6-8

Synthetic Organic Chemicals, 1987 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals Central depressants and stimulants—Continued Antidepressants: Amitriptyline Amitriptyline hydrochloride Doxepin hydrochloride Fluoxetine hydrochloride Imipramine hydrochloride Maprotiline hydrochloride Nortriptyline hydrochloride Antitussives: Benzonatate Caramiphen edisylate Codeine Dextromethorphan hydrobromide Hydrocodone bitartrate Noscapine Thebaine Tranquilizers: Phenothiazine derivatives: Chlorpromazine hydrochloride Fluphenazine hydrochloride Perphenazine Prochlorperazine hydrochloride Trifluoperazine Trifluoperazine hydrochloride Other tranquilizers: Ciorazepate dipotassium Halazepam Haloperidol Hydroxyzine hydrochloride Hydroxyzine pamoate Prazepam Thiothixene hydrochloride Other central depressants and stimulants: Amphetamines: Amphetamine Amphetamine sulfate Dextroamphetamine Dextroamphetamine sulfate Methamphetamlne hydrochloride All other amphetamines General anesthetics: Enflurane Isoflurane Ketamine hydrochloride Respiratory and cerebral stimulants: Caffeine (natural and synthetic): Caffeine, natural Caffeine, synthetic Other respiratory and cerebral stimulants: Benzphetamine hydrochloride Diethylpropion hydrochloride Doxapram hydrochloride Methylphenidate hydrochloride Pemoline Phendimetrazine tartrate Phentermine Phentermine hydrochloride

Separate statistics

Yes No No No No No No No Yes No No No No No No No Yes

Manufacturers' identification codes (according to list in table 20)

MRK. GAN, MRK. PFZ. LIL. CGY. ABB, AMD, CGY. LIL. CGY. SK. MAL, PEN. AMD, HOF. MAL, PEN. PEN. MAL, PEN.

No No No No No No

SK. TRD. SCH. SK. SK. SK.

No No No No No No No

ABB. SCH. SRL. PFZ. LEM. PD. PFZ.

Yes No No No No No No

ARN. ARN. ARN. ARN. ARN. ARN.

No No No

OH. OH. BRS, PD.

No No

CPR, GNF. PFZ.

No No No No No No No No

UPJ. GAN. LLI, WYK. CGY. ABB. GAN. GAN, HEX, SWD. HEX.

See footnotes at end of table.

6-9

6-9

Section 6 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 20)

Central depressants and stimulants—Continued Other central depressants and stimulants—Continued Skeletal muscle relaxants: Chlorphenesin carbamate Cyclobenzaprine hydrochloride Methocarbamol Orphenadrine citrate Succinylcholine chloride

No No No No No

UPJ. MRK. HEX, LLI. ABB, RIK, WYK. ABB.

Tubocurarine

No

ABB, BUR.

Dermatological agents: Aluminum phenolsulfonate Ammonium phenolsulfonate Etretinate Padimate A Padimate 0 Salicylic acid Zinc phenolsulfonate

Yes No No No No No No No

SAL. SAL. HOF. VND. CWN, VND. DOW, KLM, MON. SAL.

Zinc salicylate

No

MAL, RSA.

Expectorants and mucolytic agents: Ethylenediamine dihydroiodide Guaifenesin Iodinated glycerol

Yes No No No

AJY, DPW. LLI. (2).

Gastrointestinal agents and therapeutic nutrients: Gastrointestinal agents: Choline chloride (all grades): Choline chloride (animal feed grade) Choline chloride (medicinal grade) Other gastrointestinal agents: Betaine hydrochloride Calcium polycarbophil All other choleretics and hydrocholeretics Choline bicarbonate Choline bitartrate Choline dihydrogen citrate Cimetidine Cimetidine hydrochloride Colestipol hydrochloride Dextrothyroxine, sodium Dihydroxyaluminum aminoacetate Diphenoxylate Docusate, calcium Docusate, potassium Docusate, sodium Gemfibrozil Methscopolamine bromide Nizatidine Probucol Therapeutic nutrients: Calcium gluceptate Copper giuconate Magnesium giuconate Manganese gluconate Potassium giuconate Zinc gluconate

Yes

Hormones and synthetic substitutes: Anabolic agents and androgens: Fiuoxymesterone Methyitestosterone Stanozoloi Testosterone Testosterone cypionate

No

See footnotes at end of table.

6-10

Yes No

CHO, HFT, NUT, TMH. HFT.

No No No No No No No No No No No No No No No No No No No

HFT. DAN, LLI. UPJ. HFT. HFT. HFT. SK. SK. UPJ. BOT. CHT. MAL. ACY, MAL. ACY. ACY. PD. UPJ. LIL. DOW.

No No No No No No

PFN. PFZ. PFZ. PFZ. PFZ. PFN, PFZ.

No No No No No

UPJ. (2). SD. (2). (2).

6-10

Synthetic Organic Chemicals, 1987 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals Hormones and synthetic substitutes—Continued Anabolic agents and androgens—Continued Testosterone enanthate Testosterone propionate Zeranol All other anabolic agents and androgens Corticosteroids: Beclomethasone Betamethasone Betamethasone dipropionate Betamethasone sodium phosphate Betamethasone valerate Cortisone acetate Dexamethasone Dexamethasone acetate Dexamethasone sodium phosphate Diflorasone diacetate Fludrocortisone acetate Fluorometholone Halcinonide Hydrocortisone Hydrocortisone acetate Isoflupredone, acetate Medrysone Methylprednisolone Prednisolone Prednisolone acetate Prednisone Triamcinolone Triamcinolone acetonide Triamcinolone diacetate All other corticosteroids Estrogens and progestogens: Estrogens: Estradiol cypionate Estrogens, conjugated Estrogens, esterified All other estrogens Progestogens: Carboprost Dinoprostone Hydroxyprogesterone caproate Medroxyprogesterone acetate Megestrol acetate Melengestrol acetate Progesterone Synthetic hypoglycemic agents: Acetohexamide Chlorpropamide Glipizide Tolazamide Thyroid hormone and antithyroid agents: Levothyroxine, sodium Methlmazole Thyroglobulin Thyroid Other hormones and synthetic substitutes: Calcitonin Corticotropin Danazol Humatrope

Separate statistics

Manufacturers' identification codes (according to list in table 20)

No No No No

(2). (2) . IMC. (2) .

No No No No No No No No No No No No No No No No No No No No No No No No No

SCH. SCH. SCH, ( 2). SCH. SCH, UPJ. MRK, UPJ. MRK, ( 2 ). MRK. MRK, ( 2 ). UPJ. UPJ. UPJ. TRD. UPJ. UPJ. (2) . UPJ. ABB, UPJ. UPJ. UPJ. UPJ. TRD, ( 2 ). TRD, ( 2). TRD, ( 2 ). (2) .

No No No No

UPJ. ORG. ORG. ORG.

No No No No No No No

UPJ. UPJ. UPJ. (2) . UPJ. UPJ. UPJ.

No No No No

LIL. PFZ. PFZ. (2) .

No No No No

BOT. LIL. NEP. ARP.

No No No No

ARP. ARP, ORG. SRL, SD. LIL.

See footnotes at end of table.

6-11

6-11

Section 6 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals

Separate statistics '

Manufacturers' identification codes (according to list in table 20)

Hormones and synthetic substitutes—Continued Other hormones and synthetic substitutes—Continued Insulin Oxytocin All other hormones and synthetic substitutes

No No No

LIL. PD. PD.

Local anesthetics: Benzocaine Butamben Dibucaine Dibucaine hydrochloride Lidocaine Lidocaine hydrochloride Pramoxine hydrochloride

No No No No No No No No

MAL, WYK. ABB, WYK. CGY. CGY. LEM, WYK. LEM, WYK. ABB.

Renal-acting and edema-reducing agents: Benzothiadiazine derivatives: Benzthiazide Chlorothiazide Hydrochlorothiazide Polythiazide Trichlormethiazide Other renal-acting and edema-reducing agents: Acetazolamide Amiloride hydrochloride Canrenoate, potassium Ethacrynic acid Probenecid Spironolactone Triamterene

No No No No No No

PFZ. MRK. ABB, MRK, SK. PFZ. SCH.

No No No No No No No

ACY. MRK. SRL. MRK. MRK, SAL. SRL. GAN, SK.

Smooth muscle relaxants: Atracurium besylate Flavoxate hydrochloride Oxtriphylline Theophylline sodium giycinate

No No No No No

BUR. SK. PD. CHT.

Vitamins: Vitamin A: Beta carotene (provitamin A) Retinoin (vitamin A acid) Vitamin A acetate (animal feed grade) Vitamin A acetate (medicinal grade) Vitamin A alcohol Vitamin A palmitate (medicinal grade) Vitamin A propionate All other vitamin A Vitamin 8-Complex: Niacin and derivatives: Niacin (medicinal grade) Niacinamide (medicinal grade) Niacinamide hydroiodide Pantothenic acid derivatives: Dexpanthenol Panthenol Other B-complex vitamins: Biotin Cyanocobalamin (animal feed grade) Cyanocobalamin (U.S.P. crystalline) Riboflavin (animal feed grade) Riboflavin (medicinal grade) Thiamine hydrochloride Thiamine mononitrate

Yes No No No No No No No No

HOF. EK. HOF. HOF. EK, HOF. HOF. HOF. EK.

No No No

RIL. NEP, RIL. DPW.

No No

HOF. HOF.

No No No No No No No

HOF. MRK. MRK. MRK. HOF. HOF. HOF.

See footnotes at end of table.

6-12

6-12

Synthetic Organic Chemicals, 1987 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals Vitamins—Continued Vitamin C: Ascorbic acid Sodium ascorbate Vitamin D: Calcifediol (Vitamin D 3) Cholecalciferol (vitamin D 3) Ergocalciferol (vitamin D) Vitamin E: dl-alpha Tocopheryl acetate (all grades): dl-a Tocopheryl acetate (animal feed grade) dl-a Tocopheryl acetate (medicinal grade) Other vitamin E: d-a Tocopherol dl-a Tocopherol d-a Tocopheryl acetate d-a Tocopheryl acid succinate Vitamin K: Menadione sodium bisulfite (anhydrous) Miscellaneous medicinal chemicals: Antineoplastic agents: Azathioprine Carboplatin Cisplatin Cytarabine Leuprolide acetate Methotrexate Procarbazine hydrochloride Streptozocin Thioguanine (hemihydrate) Vincristine sulfate All other antineoplastic agents Cardiovascular agents: Antihypertensive agents: Captopril Diazoxide Guanethidine sulfate Hydralazine hydrochloride Methyldopa Metoprolol tartrate Minoxidil Nadolol Prazosin hydrochloride Sodium nitroprusside Terazosin Enalapril maleate Vasodilators: Flecanide acetate Nifedipine Other cardiovascular agents: Disopyramide phosphate Lovastatin Procainamide hydrochloride Tocainide Diagnostic agents: Roentgenographic contrast media: Diatrizoate, sodium lohexol lothalamate, meglumine

Separate statistics

Manufacturers' Identification codes (according to list in table 20)

No No

HOF. HOF.

No No No No

UPJ. DUP, VTM. VTM.

No No

BAS, HOF. BAS, HOF.

No No No No

EKT, SCP. HOF. EKT, SCP. EKT, SCP.

No

ABB.

Yes No No No No No No No No No No No

BUR. MRX. MRX. PFN, UPJ. ABB. BRS. BRS, HOF. PFN, UPJ. BUR. L1L. (2) .

No No No No No No No No No No No No

TRD. SCH. CGY. CGY. MRK. CGY. UPJ. TRD. ABB, PFZ. ABB. ABB. MRK.

No No

RIK. PFZ.

No No No No

GAN, SRL. MRK. PD, WYK. MRK, SDW.

No No No

SDW. SD. MAL.

See footnotes at end of table.

6-13

6-13

Section 6 Table 19—Continued Medicinal chemicals for which U.S. production and/or sales were reported, identified by manufactures, 1987

Medicinal chemicals Miscellaneous medicinal chemicals—Continued Diagnostic agents other—Continued Other diagnostic agents: Albumin Edrophonium chloride Glutamyl-p-nitroaniline (liver function test) Metyrapone Xylose (intestinal malabsorption test) All other diagnostic agents, other than roentgenographic contrast media Hematological agents: Anticoagulants: Ammonium heparin Benzalkonium heparin Lithium heparin Potassium warfarin Sodium heparin Other hematological agents: Cellulose, oxidized Dextran Unclassified medicinal chemicals: Allopurinol Carbidopa Disulfuram Etidronate, disodium Levodopa All other medicinal chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 20)

No No No No No

SPR. MRX. REG. CGY. PFN.

No

PFZ.

No No No No No

SPR. RIK. SPR.

No No

EKT. PHR.

No No No No No No

BUR. MRK. ABB. NOR. MON, SRL. ABB, BIB, MRX.

(2) .

SPR.

1 Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No." 2 The manufacturer did not consent to his identification with the designated product.

Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

6-14

6-14

Synthetic Organic Chemicals, 1987 Table 20 Medicinal chemicals:

Code ABB ACY ADC AJY AMD ARN ARP ARS BAS BEW BEE BEW BIB BKC BOC BOT BRS BUR CGY CHO CHT CWN CPR DAN DOW DPW DUP EK EKT FLM GAF GAN GNF HEX HFT HOF HXL IMC KAN KLM KPT LEM

Directory of manufacturers, alphabetical by code, 1987

Name of company Abbott Laboratories American Cyanamid Co. Anderson Development Co. Ajay Chemicals, Inc. Cyclo Products, Inc. Arenol Chemical Corp. Armour Pharmaceutical Co. Arsynco, Inc. BASF Corp. Beecham, Inc.: Beecham Laboratries Div. Beecham Western Hemisphere Inc. Beckman Instruments, Inc., Spinco Div. J. T. Baker Chemical Co. Biocraft Laboratories, Inc. Boots Co. (USA), Inc. Bristol-Myers Co Burroughs Wellcome Co. Ciba-Geigy Corp. Ducon Chattem, Inc. UpJohn Co., Fine Chemicals Certified Processing Corp. Dan River, Inc., Chemical Products Div. Dow Chemical Co. Deepwater, Inc. E. I. duPont de Nemours & Co., Inc. Medical Products Dept. Eastman Kodak Co.: Tennessee Eastman Co. Div. Fleming Laboratories, Inc. GAF Corp., Chemical Group Gane's Chemicals, Inc. General Foods Manufacturing Corp., Maxwell House Coffee Div. Hexagon Laboratories, Inc. Syntex Agribusiness, Inc., Nutrition & Chemical Div. Hoffmann-LaRoche, Inc. Hexcel Corp., Hexcel Chemical Products Pitman-Moore, Inc., Kanasco, LTD Kalama Chemical, Inc. Koppers Co , Inc. Napp Chemicals, Inc.

Code LIL LLI MAL MHI MON MRK MRX NEP NOR NUT OH ORG ORT PD PEN PFN PFZ PHR REG RIK RIL RSA SAL SCH SCP SD SD SDW SK SPR SRL TMH TNA TRD TX UCC UPJ VND VTM WTL WYK WYT

Name of company Ell Lilly & Co., U.S. and Puerto Rico Lee Laboratories, Inc. Mallinckrodt, Inc. Morton-Thiokol, Inc., Ventron Div. Monsanto Co. Merck & Co., Inc. Johnson Matthey, Inc. Nepera Inc. Norwich Eaton Pharmaceutical, Inc. Nutrius, Inc. Anaquest Organics/LaGrange, Inc. Roehr Chemicals, Inc., Div. of Aceto Corp. Parke-Davis Div. of Warner-Lambert Co. CPC International, Inc., Penick Corp. Pfanstiehl Laboratories, Inc. Pfizer, Inc. & Pfizer Pharmaceuticals, Inc. Pharmachem Corp. Regis Chemical Co. Riker Laboratories, Inc. Sub of 3M Co. Reilly Tar & Chemical Corp. R.S.A. Corp. Salsbury Laboratories, Inc. The Schering Corp. Henkel Corp. Sterling Drug, Inc.: Sterling Pharmaceuticals, Inc. Sterling Organics Div. SmithKline Chemicals Scientific Protein Laboratories G.D. Searle & Co. Thompson-Hayward Chemical Co. Ethyl Corp. Squibb Manufacturing, Inc. Texaco Chemical Co. Union Carbide Corp. Upjohn Co. Van Dyk, Div. of Mallinckrodt, Inc. Vitamins, Inc. Pennwalt Corp., Lucidol Div. Wyckoff Chemical Co., Inc. Wyeth Laboratories, Inc., Wyeth Laboratories

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

6-15

6-15

6-16

Synthetic Organic Chemicals, 1987

Section 7 Flavor and Perfume Materials Flavor and perfume materials are organic chemicals used to impart flavors and aromas to foods, beverages, cosmetics, and soaps. These aroma chemicals are also utilized to neutralize or mask unpleasant odors in industrial processes and products, as well as in consumer products. Total domestic production of flavor and perfume materials in 1987 amounted to 126.2 million pounds (see figure 8). Sales of these materials in 1987 amounted to 81.5 million pounds, valued at $726.3 million, compared with 96.4 million pounds, valued at $623 4 million, in 1986. U.S. production of flavor and perfume materials in 1987 decreased by 8.7 percent from the level in 1986 while the value of sales increased by 16.5 percent. Production of cyclic flavor and perfume materials in 1987 amounted to 70.7 million

pounds; sales amounted to 56 2 million pounds, valued at $647.3 million. Individual publishable chemicals in the cyclic group produced in the greatest volume in 1987 were anethole (2.8 million pounds), and eugenol (452 thousand pounds) „ U.S. output of acyclic flavor and perfume materials in 1987 amounted to 55.4 million pounds; sales of these materials amounted to 25.2 million pounds, valued at $79.1 million. Individual publishable acyclic flavor and perfume chemicals produced in the greatest volume in 1987 were citronellol (1.9 million pounds), tetrahydrogeraniol (557 thousand pounds), and hydroxycitronellal (372 thousand pounds). Table 22 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 23.

Eric Land 202-252-1349

Figure 8 Flavor and perfume materials: U.S. production, 1983-87

Millions of pounds 200 180 160-: 140 120-, 100

80 60-4 40-5. 20

0 1983

1984

1985

1986

1987

7-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

7-1

Section 7 Table 21 Flavor and perfume materials: U.S. production and sales, 1987

Flavor and perfume materials

Grand total

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

126,154

81,464

726,336

$8.92

70,740

56,239

647,255

11.51

52,328

42,802

587,498

13.73

452 100 49 11 10 33 103 2,758

255

916

3.59

(2)

(2)

(2)

21

53

2.56

(2)

(2)

(2)

7 18 115 3,615

42 103 541 10,329

5.98 5.80 5.70 2.86

48,812

38,771

575,514

14.84

18,412

13,437

59,757

4.45

31 186 140 3,589 29

(2) 136 98 2,843 11

(2)

(2)

736 974 2,029 558

5.40 9.94 .71 48.54

14,437

10,349

55,460

4.89

55,414

25,225

79,081

3.13

76 31

66 15

292 159

4.46 10.35

10 557 1,850 24 332 154 9 9

23 182 1,817 20 291 134 11 6

117 608 5,432 85 583 658 88 180

5.08 3.35 2.99 4.37 2.00 4.92 8.21 30.19

372 101 51,889

(2)

(2)

(2)

114 22,546

275 70,604

2.42 3.13

Cyclic Total Benzenold and Naphthalenold Total 4-AllyI-2-methoxyphenol (Eugenol) Benzyl benzoate Benzyl propionate p-Methoxybenzyl alcohol Phenethyl isobutyrate 2-Phenethyl phenylacetate Phenylacetaldehyde, dimethyl acetal p-Propenylanisole (Anethole) All other benzenoid and naphthalenold materials Terpenoid, Heterocyclic, and Alicyclic Total B-Caryophyllene Cedryl acetate lonones ot-Terpineol Vetivenyl acetate All other terpenoid, heterocyclic, and alicyclic materials Acyclic Total Citronellyl acetate Citronelly1 formate 3,7-Dimethyl-cis-2,6-octadienol, acetate (Neryl acetate) 3,7-Dimethyloctano1-1 (Tetrahydrogeraniol) 3,7-Dimethy1-6-octen-1-ol (Citronellol) Ethyl hexanoate Ethyl propionate Geranyl acetate Geranyl formate cis-3-Hexen-1-y1 acetate 7-Hydroxy-3,7-dimethy1-1-octanal (Hydroxycitronelial) lsopentyl butyrate All other acyclic materials

Calculated from unrounded figures. Reported data are accepted in confidence and may not be published, or no data were reported. Source: Compiled from data received In response to questionnaires of the U.S. International Trade Commission.

2

7-2

7-2

Synthetic Organic Chemicals, 1987 Table 22 Flavor and perfume materials for which U.S. production and/or sales were reported identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics

Manufacturers' identification codes (according to list in table 23)

Cyclic Benzenoid and naphthalenold: Acetaldehyde, ethyl phenethyl acetal Acetaldehyde, phenethyl propyl acetal 2'-Acetonaphthone (3-Methyl naphthyl ketone) 1-Acetoxy-2-sec-butyl-1-ethylcyclohexane p-Allyianisole 4-Ally1-1,2-dimethoxybenzene (4-Allylveratrole) 4-AllyI-2-methoxyphenol (Eugenol) 4-Ally1-2-methoxyphenol acetate (Eugenol acetate) a-Amyl cinnamic aldehyde Amyl cinnamic aldehyse dimethyl acetal Amyl cinnamyl alcohol p-Anisaldehyde Anisyl acetate Aurantiol Benzaldehyde glyceryl acetal Benzophenone Benzyl acetate Benzyl benzoate Benzyl butyrate Benzyl cinnamate Benzyl formate Benzyl Isobutyrate Benzyl Isopentyl ether Benzyl isovalerate Benzyl laurate 1- (Benzyloxy)-2-methoxy-4-propenylbenzene (Benzyl isoeugenyl ether) Benzyl phenylacetate Benzyl propionate Benzyl salicylate p- tert-Butyl-a-methylhydrocinnamaidehyde N- ( 3- (p - tert-butylpheny1)-2-methylpropylidene)anthranilic acid, methyl ester 1- tert - Butyl-3,4,5-trimethyl-2,6-dinitrobenzene (Musk tibetene) Carvacrol Cineole (Eucalyptol) Cinnamaldehyde Cinnamic aldehyde dimethyl acetal Cinnamyl acetate Cinnamyl alcohol Cinnamyl butyrate Cinnamyl cinnamate Cinnamyl nitrile Cinnamyl propionate Coumarin Cuminyl acetate Cuminyl formate 2-4-Dibromo-6-nitro-m-cresyl methyl ether 1,2-Dimethoxy-4-propenyibenzene (4-Propenylveratrol)

13,4,Dimethy1-3-cyclohexene-1-propanal y ,4- Dimethy1-3-cyclohexene-l-propanol 3,7-Dimethy1-1,6-octadien-3-y1 formate 3,7-Dimethy1-2,6-octadienyl phenylacetate (Geranyl phenylacetate) a, a-Dimethylphenethyl acetate

No No No No No No Yes No No No No No No No No No No Yes No No No No No No No

IFF. IFF. GIV. GIV. SCM, ( 2 ). Cl. BDS, CI, ELN, GIV, IFF, UNG. CI, FB. FB. FB. IFF. FB. ELN, GIV. BDS, FB. GIV. CWN, PD. FB, MRF, TCH. HAR, KLM, MRF, TCH. ELN, FB. FB. ELN. ELN. GIV. ELN. GIV.

No No Yes No No

GIV. ELN, GIV. ELN, FB, IFF. FB, HAR, TCH. GIV.

No

GIV.

No No No No No No No No No No No No No No No No No No No

GIV. GIV. NCI, SCM. FB. Cl. ELN, FB. FB, IFF. FB. FB. IFF. ELN. RDA. IFF. IFF. GIV. Cl. Cl. Cl. GIV.

No No

GIV. IFF.

7-3 See footnotes at end of table.

7-3

Section 7 Table 22—Continued Flavor and perfume materials for which U.S. production and/or sales were reported Identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics '

Manufacturers' identification codes (according to list in table 23)

Cyclic—Continued Benzenold and naphthalenold—Continued Dimethyl phenylethyl carbinol p-Ethoxybenzaldehyde N-(p-Ethoxycarbonylpheny1)-N'-ethyl-N'phenylformamidlne 2-Ethoxynaphthalene Ethyl anthranilate Ethyl benzoate Ethyl cinnamate Ethyl-ot ,13-epoxy-fl-methylhydrocinnamate 2-Ethyl hexyl salicylate Ethyl phenylacetate Ethyl salicylate Heliotropyl acetate Heliotropyl acetone Hexahydro-5-methoxy-4,7-methano-1H-Indene cls-3-Hexenyl salicylate ot-Hexylcinnamaldehyde Hydratropaldehyde Hydratropaldehyde, dimethyl acetal Hydrocinnamic acid Hydrocoumarin Hydroxycitronellal methyl anthranilate 4-Hydroxy-3-ethoxybenzaldehyde (Ethylvanillin) 4-Hydroxy-3-methoxybenzaldehyde (Vanillin) 4-(4-Hydroxy-3-methoxyphenyI)-2-butanone (Vanillyacetone) p-Hydroxy-phenylbutanone soamyl phenylacetate sobutyl phenylacetate sobutylquinoline sobutyl salicylate sohexenyl tetrahydrobenzaldehyde (Myrac aldehyde) sopentyl benzoate sopentyl salicylate -Limonene Linatyl anthranilate Linalyl benzoate p-Mentha-1,8-diene (Llmonene) Methyl anthranilate o-Methoxycinnamic aldehyde p-Methoxybenzyl alcohol (Anisyl alcohol) 2-Methoxynaphthalene 1-p-Methoxyphenyl penten-1-one-3 ( a-Methylanisylacetone) 3-(2-Methoxypheny1)-2-propenal 2-Methoxy-4-propenylphenol (isoeugenol) 2-Methoxy-4-propenylphenol, acetate 2-Methoxy-propyiphenol 4' -Methylacetophenone p-Methylanlsole Methyl anthranilate 3- Methylbenzene propanal Methyl benzoate ce-Methylbenzyl acetate (Styralyl acetate) a-Methylcinnamaldehyde Methyl cinnamate 6-Methylcoumarin

See footnotes at end of table.

7-4

No No

IFF. GIV.

No No No No No No No No No No No No No No No No No No No No No

GIV. GIV. FB. ELN. ELN. ELN FEL, HAR. ELN, GIV. FB. IFF. AMB. Cl. BDS, GIV, IFF. Cl. GIV. GIV, IFF. ELN. ELN, GIV. GIV, IFF. RDA. RAY, RDA.

No No No No No No No No No No No No No No No Yes No

GIV. GIV. ELN. ELN, FB. IFF. FB. !FF. GIV. FB, HAR. SCM. BDS, FMT. GIV. IFF. HPC. Cl. ELN, FB, GIV. GIV.

No No No No No No No No No No No No No No

GIV. Cl. Cl. ELN. Cl. CWN. GIV. FB, PSG. Cl. KLM, MRF. CI, IFF. CI, FB. FB. GIV.

7-4

Synthetic Organic Chemicals, 1987 Table 22—Continued Flavor and perfume materials for which U.S. production and/or sales were reported identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics 1

Manufacturers' identification codes (according to list in table 23)

Cyclic—Continued Benzenold and naphthalenold—Continued 1,2-Methylenedloxy-4-propylene benzene (iso-Safrole) p-Methylhydrotropaldehyde 1-Methyl-lsohexyl-hexahydrobenzaldehyde Methyl-N-methylanthranilate ot-Methyl-3,4-methylene dioxyhydrocinnamaldehyde Methyl phenylacetate 3-Methyl-5-phenyl-1-pentanol Methyl salicylate Octahydro-5-methoxy-4,7-methano-1H-Indene, 2-carboxaldehyde 1 , 1 ,3,3 ,5-Pentamethy1-4 , 6-dinitroindan (Moskene ) ot-Pentylcinnamaldehyde Phenethyl acetate Phenethyl alcohol Phenethyl formate Phenethyl isobutyrate Phenethyl isovalerate 2-Phenethyl phenylacetat Phenethyl propionate Phenethyl salicylate 2-Phenoxyethyl isobutyrate Phenylacetaldehyde Phenylacetaldehyde, dimethyl acetal Phenylacetic acid Phenylacetic acid, isopentyl ester ot-Phenylanisole 4-Phenyl-3-buten-2-one Phenylethyl benzoate Phenylethyl tiglate 3-Phenyl-1-propanol (Hydrocinnamic alcohol) 3-Phenylpropyl acetate 3-Phenylpropyl cinnamate Piperonal (Heliotropin) p-Propenylanisole (Anethole) p-Propyianisol (Dihydroanethole) n-Propylidene phthalide Sweeteners, synthetic: Aspartame Cyclohexanesulfamic acid (Cyclamic acid) Cyclohexanesulfamic acid, calcium salt (Calcium cyclamate) Cyclohexanesulfamic acid, sodium salt (Sodium cyclamate) Saccharin (1 ,2-Benzisothiazolin-3-one , -1 , 1-dioxide) Saccharin, sodium salt Tetramethyl octahydro acetophenone Tetramethyl octahydro acetyl naphthalene p-Tolualdehyde p-Tolylacetaldehyde p-Toiylacetate p-Tolylisobutyrate p-Tolyl octanoate p-Tolylphenylacetate a-(Trichloromethyl)benzyl acetate (Rosetone)

No No No No No No No No

AMB. GIV. GIV. AMB. GIV. ELN. IFF. KLM, MON.

No No No No No No Yes No Yes No No No No Yes No No No No No No No No No No Yes No No

Cl. GIV. Cl. FB, IFF. FB. ELN, IFF. ELN, GIV, IFF. ELN, FB. BDS, ELN, GIV, IFF. ELN. GIV. FB. CI, GIV. CI, ELN, GIV. GIV. GIV. GIV. FB. IFF. FB. FB. ELN, GIV. FB. AMB. ARZ, FB, HPC, NCI, SCM. GIV. FB.

No No

NSW ABB.

No

ABB.

No No No No No No No No No No No No

ABB. PSG. PSG. IFF. IFF. FB, GIV. GIV. ELN. IFF. IFF. GIV. ARS.

See footnotes at end of table.

7-5

7-5

Section 7 Table 22—Continued Flavor and perfume materials for which U.S. production and/or sales were reported identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics 1

Manufacturers' identification codes (according to list in table 23)

Cyclic—Continued

Benzenoid and naphthalenold—Continued Trimethyl benzyl dioxane Trimethylcyclohexyl salicylate All other benzenoid or naphthalenoid chemicals Terpenoid, heterocyclic, and alicyclic: 4-Acetoxymethyl-4-nonene Acetyl-n-butyryl (2,3-Hexanedione) Acetyl cedrene (Vertoflex) Acetyl isovaleryl (5-Methyl-2,3-hexanedlone) N-Acetyl methyl anthranilate Acetyl propionyl (2,3-Pentanedione) Allo-ocimene Allyi cyclohexyl propionate Amyl cyclohexyl acetate Amyris acetate 3-methyl lonone coeur 2-tert-Butylcyclohexanol 2-sec-Butylcyclohexanone o-tert-Butylcyclohexyl acetate p-tert-Butylcyclohexyl acetate (Verbeniax) Cadinene a-Campholenic aldehyde Canrenoate, potassium I-Carvone f3-Caryophyllene Caryophyllene oxide ot-Cedrene epoxide (Andrane) Cedrenol Cedrol Cedryl acetate Cedryl formate Cyclohexyl salicylate Cyclopentanone Dihydro-cyclacet p-Cymene Dihydronordicyclopentadienyl acetate (Cyclacet) Dihydronordicyclopentadienyl propionate (Cyclaprop) (Verdyl propionate extra) Dihydro terpineol Dimethyl cyclohexane methanol 2,6-Dimethylheptan-2-ol Ethyl furoate 4-Ethyl gualacol Furfurylidene acetone Galaxolide (1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8hexamethyl-cyclopenta- q -2-benzopyran) Guaiacwood acetate Guaiene 2-Heptylcyclopentanone Hexadecanolide 2-Hexy1-2-cyclopenten-1-one 3-Hydroxy-2-ethyl-4-pyrone (Ethylmaltol) 4-(4-Hydroxy-4-methyl pentyI)-3-cyclohexene10-carboxaldehyde (Lyra!) 3-Hydroxy-2-methyl-4-pyrone (Maltol) 4-Hydroxynonanic acid, y-lactone (y-Nonalactone) 4-Hydroxyundecanoic acid, y-lactone (y-Undecalactone) See footnotes at end of table.

7-6

No No No

IFF. ARS. IFF.

No No No No No No No No No No No No No No No No No No No Yes No No No No Yes No No No No No No

FB. FB. BDS. FB. AMB. FB. SCM, ( 2 ). GIV. IFF. GIV. IFF. IFF. GIV. CI, IFF. CI, IFF. FB. SCM. IFF. SCM. BDS, FB, GIV. GIV. BDS, IFF. ELN, IFF. ELN. BDS, ELN, IFF. IFF. FB. FB. IFF. SCM. Cl.

No No No No No No No

Cl. SCM. IFF. GIV. IFF, SCM. STG. AMB.

No No No No No No No

IFF. ELN, FB. FB. IFF. IFF. FB. PFZ.

No No

IFF. PFZ.

No

ELN.

No

ELN.

7-6

Synthetic Organic Chemicals, 1987 Table 22—Continued Flavor and perfume materials for which U.S. production and/or sales were reported identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics

Manufacturers' identification codes (according to list in table 23)

Cyclic—Continued Terpenold, heterocyclic, and alicyclic—Continued lonone( a- and (3-) a-lonone Isobornyl acetate Isobornyl methyl ether Isobornyl propionate Isolongifolene epoxide Isomenthone 6-Isopropyldecalone Isopulegyl acetate p-Mentha-1 ,3-diene ( a-Terpinene) p-Mentha-1,4-diene (7-Terpinene) p-Mentha-6,8-dien-2-ol (Carveol) p-Mentha-6,8-dien-2-one (Carvone, Carvol) 1-p-Mentha-6,8-dien-2-yl acetate (Carvyl acetate) p-Menth-8-en-3-ol (Isopulegol) p-Menth-1-en-3-one (Piperitone) p-Menth-4-(8)-en-3-one (Pulegone) 1-1-p-Menthen-6-y1-1-propanone d,l-Menthol, synthetic I-Menthol, synthetic Menthyl acetate I-Menthyl acetate a-Methylcyclohexanemethanol Methylionone (a- and (3-) 7-Methylionone 6-Methyl-a-ionone Nopol Nopyl acetate 1 -Phenysal-1 ,2-propanidione Plinol Pliny) acetate Propyl furylacrylate Rose oxide a-Santalyi acetate Terpinene-ol Terpineol (a- and (3-) a-Terpineol a-Terpinyl acetate a-Terpinyl propionate 3,3,5-Trimethyl cyclohexanol (m-Homomenthol) Trimethyl cyclohexene carboxaldehyde Trimethyl cyclohexenyl butenone 1 - (2,6,6-Trimethy1-2-cyclohexen-1-y1)1,6-heptadlen-3-one (Allyl-a-lonone) 5- (2,2,3-Trimethylcyclopent-3-en-1-y1)3-methylpentan-2-ol Trimethyl norborane methanol a,a-5-Trimethyl-5-vinyl-furfuryl alcohol and tetrahydro-2,2,6-trimethy1-6-viny1-3-ol Vetivenol Vetivenyl acetate All other terpenoid, heterocyclic, or alicyclic flavor and perfume chemicals

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes No No No No No

BDS, GIV, NCI. BDS, FB, GIV, IFF. SCM. SCM. ELN. GIV. GIV. GIV. GIV. SCM SCM FB. FB. FB. GIV. GIV. GIV. GIV. GIV, HAR, NCI. HAR. GIV. SCM. Cl. GIV, IFF, NCI. BDS, FB, GIV, NCI. BDS, GIV. NCI. NCI, SCM. STG. SCM. SCM. AMB. FB. GIV. SCM. RBC. HPC, NCI, SCM. NCI, SCM. ELN. ARS. IFF. IFF.

No

IFF.

No No

GIV. IFF.

No No Yes

GIV. GIV. BDS, ELN, FB, GIV, IFF.

No

IFF, SCM.

See footnotes at end of table.

7-7

7-7

Section 7 Table 22—Continued Flavor and perfume materials for which U.S. production and/or sales were reported identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics

Manufacturers' identification codes (according to list in table 23)

Acyclic Allyl disulfide Allyl.heptanoate Allyl hexanoate Ammonium isovalerate Amyl vinyl carbinyl acetate Butanoic acid, 1-cyclohexylethyl ester Butyl butyryl lactate Butyraldehyde diethyl acetal Citral dimethyl acetal Citronellyl acetate

No No Yes No No No No No No Yes

Citronellyl butyrate Citronellyl formate Citronellyl isobutyrate Citronellyl propionate Crude acetate mixture (Linalyl, neryl, gerany acetates, main components) Decanal (Capraldehyde) Decyl acetate Diethyl acetal Diethyl sebacate Diethyl succinate Dihexyl fumarate Dihydrocarvone Dihydrolinalool Dihydromyrcenol Dihydropentamethyl indanone Dihydroterpinyl acetate 1,1-Dimethoxy octane 4-(1,1-Dimethylethyl)cyclohexanol 2,6-Dimethyl-5-hepten-1-al Dimethyl hexanediol 2,5-Dimethy1-3-hexyne-2,5-diol 3,7-Dimethyl-cis-2,6-octadienal (Citral B) (Neral) 3, 7-Dimethyl-trans-2 , 6-octadienal (Citral A, Geranial) 3,7-Dimethyl-2,6-octadienal (Citrals A & B) 3,7-Dimethy1-2,6-octadienenitrile 3,7-Dimethyl-2,6-octadiene oxime 3,7-Dimethyl-cis-2,6-octadien-1-ol (Nerol) 3,7-Dimethyl-trans-2,6-octadien-1-ol (Geraniol) 3,7-Dimethyl-1,6-octadien-3-ol (Linalool) (Linatyl alcohol) 3,7-Dimethyl-cis-2,6-octadienol, acetate (Neryl acetate) 3,7-Dimethyl-1,6-octadien-3-ol, acetate (Linalyl acetate) 3,7-Dimethy1-1,6-octadien-3-y1 isobutyrate (Linalyl isobutyrate) 3,7-Dimethy1-1,6-octadien-3-y1 propionate (Linalyl propionate) Dimethyloctanal 3,7-Dimethyloctanol-1 (Tetrahydogeraniol) 3,7-Dimethyl-3-octanol Dimethyloctanyl acetate 3,7-Dimethyl-6-octen-1-al (Citronella!) 3, 7-Dimethy-6-octenenitrile 3,7-Dimethyl-6-octen-1-ol (Citronellol) 3,7-Dimethyl-7-octenol 70%, 6-octenol isomer 30% Dimethyl succinate

No Yes No No

IFF. ELN, FB. ELN, FB. RSA. IFF. Cl. ELN. FB. FB, !FF. BDS, ELN, FB, GIV, IFF, NCI, SCM. IFF. BDS, ELN, GIV, IFF. ELN. IFF.

No No No No No No No No No No No No No No No No No

(2). Cl. GIV. FB. ELN. ELN, MRF. FB. SCM. SCM. SCM, ( 2 ). IFF. IFF. IFF. Cl. GIV. ( 2 ). (2).

No

SCM.

No No No No No No

BDS, SCM. NCI. Cl. Cl. ELN, GIV, IFF, NCI, SCM. ELN, FEL, GIV, IFF, NCI, SCM.

No

ELN, IFF, NCI, SCM.

Yes

ELN, GIV, IFF, SCM.

No

FB, GIV, NCI, SCM.

No

GIV.

No No Yes No No No No Yes No No

GIV. GIV, SCM. GIV, IFF, NCI, SCM. FB, SCM. GIV, IFF. GIV, SCM. Cl. ELN, FB, GIV, NCI, SCM. GIV. FB.

See footnotes at end of table.

7-8

7-8

Synthetic Organic Chemicals, 1987 Table 22—Continued Flavor and perfume materials for which U.S. production and/or sales were reported Identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics

Manufacturers' identification codes (according to list in table 23)

Acyclic—Continued Dodecane nitrile

No

Ethy butyrate Ethy caprate Ethy formate Ethy heptanoate Ethy hexanoate Ethy isovalerate Ethy laurate Ethy -2-methyl butyrate Ethy -2 methyl pentanoate Ethy myristate Ethy octanoate Ethy oxyhydrate Ethy propionate Ethy trimethyl cyclopentenyl buterol Ethy valerate 4-Formy1-4-nonene Gerany acetate

No No No No Yes No No No No No No No Yes No No No Yes

Gerany butyrate Gerany crotonate Gerany ethyl ether Gerany formate Gerany isobutyrate Gerany isovalerate Gerany nitrile (Citralva) Gerany propionate Gerany tiglate Heptyl acetate Heptyl butyrate N-Hexanal 2-Hexenal 2-Hexenol cis-3-Hexen-1-y1 acetate cis-3-Hexenyl butyrate cis-3-Hexenyl methyl carbonate cis-3-Hexenyl tiglate Hexoxyacetaldehyde dimethyl acetal Hexyl acetate Hexyl caproate Hydroxycitronellol 7-Hydroxy-3,7-dimethy1-1-octanal (Hydroxycitronellal) 7-Hydroxy-3,7-dimethyl octanal, dimethyl acetal (Hydroxycitronellal, dimethyl acetal) soamy caproate soamy caprylate soamy propionate sobuty acetate sobuty -2-butenoate sobuty butyrate sononyl acetate sopentyl acetate (Isoamyl acetate) sopentyl butyrate sopentyl formate sopentyl isovalerate Lauraldehyde 3-Methy butanol

No No No Yes No No No No No No No No No No Yes No No No No No No No

FB, HPC, NW. FB. FB. ELN, FEL. ELN, FB, NW. ELN, FB. ELN, FB. FB, HPC, SCM HPC. ELN. FB. FB. FB, MRF, NW. IFF. ELN. FB. BDS, CI, ELN, FB, FEL, GIV, HPC, FF, NCI, NW, SCM. ELN, GIV. FB. IFF. BDS, ELN, GIV. FB, IFF. FB. IFF. FB. FB. FB. SCM. Cl. FB, GIV. FB. BDS, GIV, IFF. IFF. IFF. BDS. FB. FB. FB. SCM.

Yes

GIV, IFF, SCM.

No No No No No No No No No Yes No No No No

GIV. FB. FB. FB. GIV. AMB. FB. IFF. ELN, FB, NW. FB, GIV, NW. ELN, FB. ELN, FB, HPC. GIV, SCM. FB.

IFF.

7-9 See footnotes at end of table.

222-174 0 - 88 - 4 : 0L 3

7-9

Section 7 Table 22—Continued Flavor and perfume materials for which U.S. production and/or sales were reported identified by manufacturer, 1987

Flavor and perfume materials

Separate statistics 1

Manufacturers' identification codes (according to list in table 23)

Acyclic—Continued 3-Methyl-2-butenyl acetate 3-Methyl butyl acetate 3-Methyl butyl butyrate Methyl butynol 2-Methyidecanai 2-Methylene undecanal Methyl isobutyrate Methyl isovalerate Methyl-2-methyl butyrate 3-Methyl-2-(and 3]nonene nitrite Methylol methyl hexyl ketone Methyl pentynol Methyl propionate Methyl thiobutyrate 2-Methylundecanal Myrcenyl acetate Myristaldehyde Nonanal 1,3-Nonanediol acetate Ocimene Ocimenyl acetate Octanal 3-Octanone (Ethyl amyl ketone) N-Octyl acetate Octyl formate Octyl isobutyrate Octyl isovalerate Pseudo linalyl acetate (Neobergamate) Rhodinol Rhodinyl acetate Tepyl acetate Tetrahydro-allocimerol (50/50 mixture of tetrahydrolinalool and tetrahydro-myrecenol) Tetralol Trimethyl-cyclododeca-trienyl ethanone 3,5,5-Trimethyl hexanal Undecanal 9-Undecenal All other acyclic flavor and perfume materials

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

FB. STG. CI, GIV. IFF. GIV. Cl. ELN, GIV, IFF. IFF. IFF. Cl. GIV. FB. FB. FB. GIV. IFF. GIV, IFF. IFF. ELN.

No No No No No No No

SCM. IFF. IFF. CI, GIV. GIV. FB, IFF, ( 2 ).

IFF. FB. FB. (2) .

IFF. Cl. HPC. FB. SCM. GIV. GIV. (2) .

(2) .

1 Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No." 2 The manufacturer did not consent to his identification with the designated product.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

7-10

7-10

Synthetic Organic Chemicals, 1987 Table 23 Flavor and perfume materials:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ABB AMB ARS ARZ BDS CI CWN ELN FB FEL FMT GIV HAR HPC IFF KLM MON MRF

Abbott Laboratories American Bio-Synthetics Corp. Arsynco, Inc. Arizona Chemical Co Biddle Sawyer Corp. Firmenich, Inc. Upjohn Co., Fine Chemical Div. Elan Chemical Co. Fritzsche Dodge & Olcott, Inc. Felton International, Inc. Fairmount Chemical Co., Inc. Givaudan Corp. Haarmann & Reimer Corp. Hercules, Inc. International Flavors & Fragrances, Inc. Kalama Chemical, Inc. Monsanto Co. Morflex Chemical Co., Inc.

NCI

Union Camp Corp., Terpene and Aromatics Div. Nutrasweet Co. Northwestern Chemical Co. Parke-Davis, Div. of Warner-Lambert Co. Pfizer, Inc. PMC Specialities Group, Inc. ITT Rayonier, Inc. Artel Chemical Corp. RSA Corp.

NSW NW PD PFZ PSG RAY RBC RSA RDA SCM STG TCH UNG

Rhone-Poulenc, Inc. SCM Glidco Organics McCormick & Co., Inc. McCormick-Stange Div. Quantum Chemical Corp., Emery Div. Ungerer & Co.

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

7-11

7-11

7-12

Synthetic Organic Chemicals, 1987

Section 8 Plastics and Resin Materials Plastics and resin materials are high molecular weight polymers which, at some stage in their manufacture, exist in such physical condition that they can be shaped or otherwise processed by the application of heat and pressure. The terms "plastics," "resin," and "polymers," can be (and often are) used interchangeably by the trade. Depending on the chemical composition, manufacturing process, or intended use, the commercial products may contain plasticizers, fillers, extenders, stabilizers, coloring agents, or other additives. There are about 40 to 50 basic plastics and resins which are available commercially. These basic materials are available in literally thousands of individual compounds each with its distinct properties depending on the molecular weight of the resin and the types and amounts of the additives present. Plastics materials may be molded, cast, or extruded into semifinished or finished solid forms. Resin materials may be in the form of solutions, pastes, or emulsions for applications such as protective coatings, adhesives, or paper and textile treatment. Statistics on U.S. production and sales of synthetic plastics and resin materials for 1987 are given in table 24. U.S. production of plastics and resin materials in 1987 totaled 59,481 million pounds, or 13.4 percent more than the 52,447 million pounds produced in 1986. From 1983-87, the production of plastics and resin materials increased steadily from 44,281 million pounds in 1983 to 59,481 million pounds in 1987, or at an average, annual rate of growth of 7.7 percent (see figure 9). Sales in 1987 totaled 51,170 million pounds, valued at $26,066 million,

compared with 45,144 million pounds, valued at $20,355 million, in 1986. Thermosetting materials are those which harden with a change in composition in the final treatment so that in their final state as finished articles they are substantially infusible and insoluble; that is, they cannot again be softened by heat or solvents. U.S. production of thermosetting materials totaled 8,923 million pounds in 1987, compared with 8,349 million pounds in 1986. Production of the most important products in 1987 included phenolic (1,697 million pounds), amino (urea and melamine) resins (2,214 million pounds), polyester resins, unsaturated (1,344 million pounds), and alkyd resins (752 million pounds). Thermoplastic materials are those which in their final state as finished articles can be repeatedly softened by heat and hardened by a decrease in temperature. U.S. production of thermoplastic materials totaled 50,558 million pounds in 1987 (or 85.0 percent of the total plastics and resin materials output for 1987), compared with 44,098 million pounds in 1986. Production of the most important products in 1987 included polyethylene (17,899 million pounds), polypropylene (6,977 million pounds), vinyl resins (9,931 million pounds), and styrene type materials (8,283 million pounds) . In 1987, production of saturated polyester resins reached 2,634 million pounds (polyethylene terephthalate alone reached 1,898 million pounds). Production of engineering plastics, in the aggregate, amounted to 1,494 million pounds in 1987. Table 25 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 26.

Edward J. Taylor 202-252-1362

Figure 9 Plastics and resin materials: U.S. production, 1983-87 Billions of pounds 60

50

40

30

20

10

0 1983 1984 1985 1986 1987 Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

8-1

8-1

Section 8 Table 24 Plastics and resin materials: U.S. Production and sales, 1987

Plastics and resin materials

Grand total

Value

Average Unit value'

1,000 dollars

Per pound

Production

Sales Quantity

1,000 pounds dry basis2

1,000 pounds dry basis2

59,480,710

51,170,043

26,066,138

$0.51

8,922,625

7,180,536

3,763,075

.52

752,252

502,048

298,862

.60

632,788 35,486 17,003 28,129 38,846

435,708 19,470 8,322 28,712 9,836

245,154 16,472 6,583 21,311 9,342

.56 .85 .79 .74 .95

2,534

2,245

2,763

1.23

514,598 (323,718) 19,234 20,096

353,678 (183,108) 19,428 15,616

391,396 (277,909) 13,667 13,879

1.11 (1.52) .70 .89

250,314 1,697,074 1,343,796

219,134 1,223,894 1,264,720

189,388 627,238 793,208

.86 .51 .63

1,974,645

1,593,065

830,149

.52

227,482

142,983

214,722

1.50

75,224 152,258

62,357 80,626

118,473 96,249

1.90 1.19

1,963,759 156,841

1,714,932 128,793

235,606 152,197

.14 1.18

50,558,085

43,989,507

22,303,063

.51

1,547,486

1,124,373

1,319,396

1.17

84,400

72,266

60,075

.83

107,979 596,588 81,822 676,697 1,493,630 347,758

21,591 383,022 30,842 616,652 1,253,689 312,179

19,303 395,209 28,176 816,633 1,983,840 151,698

.89 1.03 .93 1.32 1.58 .49

633,573

570,887

811,432

1.42

585,376 48,197

522,482 48,405

769,926 41,506

Thermosetting resins Total

Alkyd resins, total Phthalic anhydride type Polybasic acid type Styrenated-alkyds or copolymer alkyds Vinyl toluene alkyds All other alkyd resins Dicyandlamide resins (an amino resin) Epoxy resins: 3 4 Unmodified Advanced Furfuryl type resins Glyoxal-formaldehyde resins Melamine-formaldehyde resins (an amino resin) Phenolic and other tar acid resins Polyester resins, unsaturated 5 Polyether and polyester polyols for urethanes,' Polyurethane elastomers and plastics products, total Elastomers7 Plastics Urea-formaldehyde resins (an amino resin) All other thermosetting resins ,' Thermoplastic resins Total

Acrylic resins, total ,' Butyl acrylate-ethyl acrylate copolymers resins Homopolymer resins, except PMMA, of acrylic or methacrylic acid esters Polymethyl methacrylate (PMMA) resins Thermosetting acrylic resins All other acrylic resins Engineering plastics 10 Petroleum hydrocarbons resins Polyamide resins, total Nylon type° 11 Non-nylon type See footnotes at end of table.

8-2

8-2

1.47 .86

Synthetic Organic Chemicals, 1987 Table 24 Plastics and resin materials:

U.S. Production and sales, 1987

Plastics and resin materials

Production

Sales Quantity

1,000 pounds dry basis2

1,000 pounds dry basis2

Value

Average Unit value'

1,000 dollars

Per pound

Thermoplastics resins-Continued Polyester resins, saturated, totals 12 Polyethylene terephthalate (PET) All other saturated polyesters, including Poly-butylene terephthalate, (PBT) resins Polyethylene resins, total Ethylene-vinyl acetate and other copolymer resins Specific gravity 0.940 and below's Specific gravity over 0.940 Polypropylene resins Polyterpene resins Rosin modifications, total Modified rosin (unesterified) Modified rosin esters Rosin esters, unmodified (Ester gums) Styrene plastics materials, total Acrylonitrile-butadiene-styrene terpolymer (ABS) resins Methyl methacrylate-butadiene-styrene (MBS) resins and certain other styrenetype plastics materials Polystyrene homopoiymers, total Expandable polystyrene beads Rubber modified polystyrene Straight polystyrene Styrene-acrylonitrile copolymer (SAN) resins Sytrene latexes, total Styrene-butadiene latexes All other styrene latexes All other styrene plastics materials" Vinyl resins, total's Polyvinyl acetate's Polyvinyl chloride and copolymers Polyvinylidene chloride resins, latex type Vinyl acetate-acrylate copolymers All other vinyl and vinylidene resins 17 All other thermoplastic resins's

2,633,804

1,667,427

1,428,895

$0.86

1,897,698

1,205,963

899,438

.75

736,106

461,464

529,457

1.15

17,899,476

16,972,387

5,805,831

.34

524,841 9,467,960 7,906,675 6,977,334 38,538

463,891 8,606,631 7,901,865 5,644,015 38,669

225,803 2,970,976 2,609,052 2,153,717 31,321

.49 .35 .33 .38 .81

317,127

303,761

160,716

.53

150,111 129,743 37,273

140,571 125,508 37,682

51,038 86,913 22,765

.36 .69 .60

8,282,766

7,231,415

4,265,655

.59

1,260,608

1,243 , 086

983,772

.79

93,330 5,596,943 553,198 1,866,714 3,177,031

78,152 4,689,544 553,142 1,818,712 2,317,690

82,991 2,353,121 332,831 921,865 1,098,425

1.06 .50 .60 .51 .47

208,671 733,601 517,280 216,321 389,613

109,124 732,739 509,089 223,650 378,770

69,806 415,428 287,879 127,549 360,537

.64 .57 .57 .57 .95

9,930,691

8,580,486

3,594,987

.42

704,578 8,337,765 20,738 436,114 431,496

560,343 7,225,196 17,762 409,040 368,145

314,117 2,799,030 15,918 160,452 305,470

.56 .39 .90 .39 .83

455,902

290,219

595,575

2.05

Calculated from unrounded figures. Dry weight basis unless otherwise specified. Dry weight basis Is the total weight of the materials including resin and coloring agents, extenders, fillers, plasticizers, and other additives, but excluding water and other liquid diluents unless they are an integral part of the materials. 3 Includes reactive diluents which are an integral part of the resin. Excludes the weight of hardeners sold in association with the resin as part of a two-component system. 4 Data shown for advanced epoxy resins are that part of the unmodified epoxy resins which is further processed; therefore, the total in parentheses are not included in the grand total. 6 Polyester resins are unsaturated alkyd resins, later to be copolymerized with a monomer (Such as styrene or 8-3 methyl methacrylate), and polyallyl resins (such as diallyl phthalate and diglycol carbonate). Data are on an as sold" basis, including monomer if part of the resin system. 2

8-3

Section 8 Footnotes for table 24—Continued In addition to the polyols, the other principal starting materials used in the production of urethane products are the isocyanic acid derivatives, mainly the 80/20 mixture of toluene-2,4- and 2,6-diisocyanate. Statistics for the isocyanic acid derivatives are reported in the "Cyclic Intermediates" section of the Synthetic Organic Chemicals report. 7 The data on urethane elastomers are believed to be not fully representative of the total urethane market in view of the very large number of urethane elastomer producers. The commission has begun reporting statistics for urethane elastomers in two sections, section VIII, plastics and resin materials, and section X, elastomers (synthetic rubber). Henceforth those polyurethane products classified as "thermoplastic" urethane elastomers will be reported in SOC section X; all other urethane elastomers will remain in SOC section VIII. e Includes acetone-formaldehyde resins, polybutadiene resins, silicone resins, thiourea resins, and certain other thermosetting resins. • Does not include production or sales for fiber use. 10 Engineering plastics: Includes acetal, polycarbonate, polyimide and amide-imide polymers, polyphenylene oxide, polyphenylene sulfide and polysulfone. Engineering plastics are defined in Whittington's Dictionary of Plastics, as "All plastics, with or without fillers or reinforcements, which have mechanical, chemical and thermal properties suitable for use in construction, machine components and chemical processing equipment." The above list of plastics (all of which are thermoplastic) was selected from a larger group in this source. Certain other plastics named in Whittington's Dictionary as engineering plastics, such as ABS resins, acrylic resins, and nylon resins, are not included in the above list as they are published separately. 11 Statistics for nylon 6 and nylon 6/6 which are used in plastics applications (e.g., molding, etc.) are included here. 12 Statistics are included here for polyethylene terephthalate used in plastics applications (e.g., molding, etc.) Statistics also are included here for production only when the starting materials are converted directly to a finished product(i.e., "in situ" production); polyester film and tape are examples of such a conversion. 13 Combines conventional low density polyethylene (LDPE) resins with linear low density polyethylene (LLDPE) resins, because several of the leading producers of LLDPE still continue to aggregate these data with that of LDPE. See table 2 for a listing of those firms that reported production and/or sales data for LLDPE resins separately to the Commission in 1987. 14 Includes data for a-methyl styrene polymers, styrene-allyl alcohol copolymer resins, styrene-divinylbenzene copolymer resins, styrene-maleic anhydride copolymers resins and styrene-methyl methacrylate copolymers resins. 16 Data are on the basis of dry resin content, excluding the weight of plasticizers, extenders, fillers coloring agents, stabilizers, or impact modifiers, unless otherwise noted. 18 Data for polyvinyl acetate produced and sold in latex form includes the weight of any protective colloids which are used as emulsion stabilizers and form an Integral part of the resin system. Production and sales do not include polyvinyl acetate used as a reactive intermediate for polyvinyl alcohol or other vinyl resins. 17 Includes polyvinyl alcohol, polyvinyl butyral, polyvinyl formal, polyvinylidene chloride (solid type), and other vinyl resins. le Includes cellulose plastics, coumarone-indene resins, fluorocarbon resins, phenoxy resins, polybutylene type resins, polyphenyl aromatic ester resins, and certain other thermoplastic materials. 6

Note.—Data reported to the U.S. International Trade Commission do not necessarily coincide with that reported to the Society of the Plastics Industry (SPI) because of differences in both the reporting instructions and in the coverage of certain resins. Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

8-4

8-4

Synthetic Organic Chemicals, 1987 Table 25 Plastics and resin materials for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Plastics and resin materials

Separate statistics

Manufacturers' identification codes (according to list in table 26)

Thermosetting resins

Acetone-formaldehyde resins Alkyd resins: Acrylate alkyd copolymer resins

No

ACY, FJI, FLH, GP.

No

DRR, FJI, FRE, MNP, OBC, PPG, SW. (2) . ACO, ACY, ASH, AZS, BAL, BLC, BRU, CCC, CEI, CGL, CJO, CPV, DRC, DSO, DUP, EW, FOC, FRE, GEI, GLD,GRG, GRV, HAN, ICF, 10V, JOB, JSC, KMP, LIC, MCC, MNP, NCP, NTL, OBC, PER, PPG, PRT, QCP, RCI, REL, REZ, SDH, SRY, SW, TNA, UNO, ( 2 ), ( 2 ). ACY, CJO, CPV, DSO, FOC, GEI, GLD, HAN, ICF, 10y, JOB, MCC, NTL, PPG, RCI, REL, SCN, SW, ( 2 ). BLC, CJO, CPV, DSO, EW, FRE, GEI, GLD, HAN, JOB, MNP, MRT, NTL, REL, RUO, SW. BLC, CGL, CJO, FA FRE, GEI, GLD, GRV, JOB, MCC, MNP, PRT, REL, SW. CGL, GEI, MCC, MNP, PPG, SW, (2) , (2) •

Alkoyl phenol Phthalic anhydride type alkyd resins

No Yes

Polybasic acid type alkyd resins

Yes

Styrenated-alkyds, or copolymer alkyds

Yes

Vinyl toluene alkyds

Yes

Alkyd copolymers, all other

Yes

Amino resins: Melamine-formaldehyde resins

Yes

Thiourea-formaldehyde resins Urea-formaldehyde resins

No Yes

Dicyandiamide resins

Yes

Epoxy resins: Epoxy, resins advanced

Yes

Epoxy, resins unmodified

Yes

Furfuryl type resins

Yes

Glyoxal-formaldehyde resins

Yes

Phenolic and other tar acid resins

Yes

ACY, AUX, BOR, CBD, CGL, CPV, DGO, DRC, GP, GRG, HCL, JSC, MNP, MON, PLS, PMC, PPG, PPL, PST, RCI, REL, REZ, SQA, UTC, WPG, WRD. CMP. ACR, ACY, AUX, BOR, CBD, CGL, CMP, CPV, DAN, DSO, GAF, GP, GRV, JSC, MMM, MNP, MON, PKI, PMC, PST, REL, REZ, SAC, SOR, SQA, VAL, WPG. CMP, CMS, ECC, JSC, S, SNW, STC, WPG. CGL, CGY, CJO, CNI, CPV, DOW, DSO, DUP, EW, GE, GLD, GRG, GRV, HAN, HXL, ICF, MCC, MID, MNP, MRT, OCF, PPG, RCI, REZ, SCN, SMO. AGI, ASH, AZS, CGY,CLU, DOW, PRT, RCI, REZ, SHC, VCC, ( 2). ACR, CEI, CLU, DRR, HVG, NCP, UNO, WRD. AUX, CMP, HCL, RBI, RTC, SQA, VAL, WPG. ABS, ACR, ADC, ASH, BME, BOR, BSC, BTL, BUC, CBD, CEI, CLU, CPV, DRR, DSO, EW, GE, GEI, GP, HCL,HER, HKD, HPC, HVG, ICF, IRI, KPT, LII, MCA, MID, MMM, NCI, NCP, NTC, NTL, OCF, PKI, PLS, PPL, PSG, PSL, RAB, RCI, RH, RSN, SPL, SW, UCC, UNO, USR, VSV, WCA, WRD, ( 2 ), ( 2 ). 8-5

See footnotes at end of table.

8-5

Section 8 Table 25—Continued Plastics and resin materials for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Plastics and resin materials

Separate statistics

Manufacturers' Identification codes (according to list in table 26)

Thermosetting resins—Continued Polybutadiene resins Polyester resins, unsaturated, and ally) resins: Ally! resins Diallyl isophthalate Polyester resins, unsaturated

No Yes No No No

Polyether and polyester polyols for urethanes

Yes

Polyurethane elastomer and plastic products: Polyurethane elastomers

Yes

Polyurethane resins

Silicone resins All other thermosetting resins,

Yes

No Yes

Thermoplastic resins Acrylic resins: Copolymer resins of acrylic and/or methacrylic acid resins: Butyl acrylate-ethyl acrylate copolymer resins Butyl methacrylate-ethyl methylacrylate copolymer resins 2-Ethylhexyl acrylate-methy acrylate copolymer resins Lauryl methacrylate-stearyl methacryiate copolymer resins Other copolymer resins of acrylic and/or methacrylic acid esters

Homopolymer resins of acrylic and/or methacrylic acid resins: Homopolymer resins of acrylic or methacrylic acid esters, except PMMA Polymethyl methacrylate (PM MA) Thermosetting acrylate resins

CCS, CNI, CRS, LC, SCN. FMC, GEI, MCC. CMS, FMC, GEI. ACS, ACY, ADC, APH, ART, ASH, AZS, CGL, CPV, DSO, EW, FJI, FRE, GEI, GLD, GRG, ICF, ICI, IPC, KPT, LII, MCC, MRT, OCF, PPG, PPL, RCI, SIC, SLC, SW. ACR, ARK, BAS, BMC, BPT, CHC, CJO, CXI, DOW, DSO, FRE, GRG, ICF, ICI, JOB, MCC, MOB, MRT, NCP, NTL, OCF, OMC, PPG, RCI, RUO, TX, UCC, UNO, WM, WTC. ACY, ADC, ARO, BPT, CAS, CGY, CNI, DCC, DNS, EPI, GLC, GRD, ICF, INP, MRT, PLN, PPG, PRC, QUN, RUO, SBG, SLC, SMO. ARO, CGL, DSO, DUP, EW, FRE, GEI, GLD, HXL, HYC, INP, LC, MCC, MID, MMC, OMC, PEL, RBI, RCI, SCN, SIF, SLC, SW. CJO, DCC, MCC, PEL, SPD. ACY, BAS, FRE, GLD, MCC, MID, MIL, REL, UCC, WLN, ( 2 ).

Yes

Yes

BFG, DRB, DSO, FLH, ICI, RH, UOC, VAL.

No

UOC.

No

DSO, RH, UOC, VAL.

No

ICI.

No

ACO, AZS, BPT, CHP, CPV, DRB, DRC, DSO, GAF, GLD, ICF, ICI, JNS, JSC, KMP, MON, NSC, OBC, PPG, PRA, PYI, RH, SCP, SW, SYT, UCC, VAL, ( 2 ).

Yes

CPV, CYR, GRV, ICF, ICI, PYI, RH, SAR, SW, UOC, ( 2 ). ART, CTP, CYR, DUP, ICF, ICI, JOB, JSC, MRT, PKL, PTC, RH, SAR, SQA. ACY, CPV, DSO, DUP, FRE, GRV, HAN, ICF, LIC, MID, MNP, PRA, REZ, SM, SW.

Yes

Yes

See footnotes at end of table.

8-6

8-6

Synthetic Organic Chemicals, 1987 Table 25—Continued Plastics and resin materials for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Plastics and resin materials

Separate statistics

Manufacturers' Identification codes (according to list in table 26)

Thermoplastic resins—Continued

Cellulose plastics and resins: Cellulose acetate Cellulose acetate butyrate Cellulose acetate propionate Ethyl cellulose Coumarone-indene resins Engineering plastics: Acetal resins Polycarbonate resins Polyimides and amide-imide polymers Polyphenylene oxide type resins Polyphenylene sulfide resins Fluorocarbon resins: Polytetrafluoroethylene (PTFE) Polyvinylidene fluoride resin All other fluorocarbon resins Petroleum hydrocarbon resins Phenoxy resin (other than for coating and adhesives) Polyamide resins: Non-nylon type, polyamide resins

No No No No No Yes No No No No No

No

NEV, UCC.

Yes

COO, EFH, GP, HCL, HYA, LII, PAC, S, SCP, SQA, TNA, USM. ACS, AGI, BCM, CTR, DGO, DUP, GRG, HCL, MON, NCI, RSN, SCP, USM. ENJ, SHC.

Polybutylene type resins Polyester resins, saturated: Polybutylene terephthalate (PBT)

No No

Polyethylene terephthalate (PET)

Yes

All other polyester resins, saturated

Yes

AGI, GE, GEP, HCL, ICF, MOB, USM. AGI, DUP, EK, EKT, GEI, GEP, GYR, HCL, ICI, MOB, USM. BPT, COO, CPV, DUP, EKT, GLD, GRG, GYR, ICF, ICI, MNP, PPG, SW.

No Yes No

DOW. COO, ENJ, NSC, USI. EKT, EKX, ENJ, RH, SQA.

Yes

ACS, DOW, DUP, EKX, ELP, ENJ, NWP, SM, SOC, SQA, UCC, (2 ). ENJ, NWP, SM. ACS, AMO, CNE, DOW, DUP, ENJ, HCL, HIM, NWP, PLC, SLT, SOC, UCC. HPC. AMO, ART, CSD, EKX, ELP, ENJ, HIM, MIL, NWP, PLC, SHC, SLT. ARZ, CPV, HPC, RCI, SCN.

Yes Yes

Polyphenyl aromatic ester resins Polypropylene polymer and copolymer resins

No Yes

Polyterpene resins Rosin modifications: Modified rosin (unesterified) Modified rosin esters

Yes

Rosin esters, unmodified (ester gums)

CPU, DUP, HCL, MCC, PRT, RAS, REL. DOW, GE, GEP, MCC, MOB, SNW. AMO, DUP, EW, GE, GRG, PDI. GE , GEP. PLC. AUS, DUP, ICI. PAS. DUP. CFX, CXI, ENJ, GYR, HPC, ICF, LII, NEV, RCI, ( 2).

Yes

Specific gravity 0.940 and below (linear low density) Specific gravity over 0.940

CPU, EKX.

No No No Yes

Nylon type, polyamide resins

Polyethylene and copolymers resins: Ethylene-acrylic acid resins (EAA) Ethylene-vinyl acetate (EVA) copolymer resins Other ethylene copolymer resins Specific gravity 0.940 and below (conventional low density)

EKT. EKT. EKT. (2) .

Yes

Yes Yes

ARZ, CJO, HPC, NCI, SYL, WVA. AZS, EW, FJI, FRP, GP, GRV, HCL, HPC, ICF, LII, MCC, NCI, RCI, SW, SYL, WVA. ARZ, CPV, FRP, HPC, NCI, PRT, RCI, SYL.

8-7

See footnotes at end of table.

8-7

Section 8 Table 25—Continued Plastics and resin materials for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Plastics and resin materials

Separate statistics

Manufacturers' identification codes (according to list in table 26)

Thermoplastic resins—Continued Styrene type plastics materials:

Acrylonitrile-butadiene-styrene (ABS) terpolymer resins Methyl methacylate-butadiene styrene (MBS) resins and certain other styrene type plastics materials Polystyrene: Expandable polystyrene beads Rubber modified polystyrene Straight polystyrene

Yes

DOW, GRD, MCB, MON.

Yes

CYR, FER, GYR, ICI, MRT, RH.

Yes Yes

ATR, BAS, HMN, TXS. API, CSD, DOW, DPI, HMN, PLR, SM. AEP, AMO, API, ATR, CSD, DOW, DPI, GAF, HGC, HMN, HPC, KTP, PLR, SM, SOC, TXS. BFG, DOW, GE, ICI, MCB, MON.

Yes

Styrene-acrylonitrile copolymer resins (SAN) Styrene latexes: Styrene-butadiene latexes All other styrene latexes

Yes

Other styrene copolymers: a-Methyl styrene polymers Styrene-ally! alcohol copolymer resins Styrene-divinylbenzene copolymer resins Styrene-maleic anhydride copolymer resins Styrene-methyl methacrylate copolymer resins All other styrene copolymers

Yes No No No No No No

Vinyl resins: Polyvinyl acetate resins

Yes

AIP, CGL, DAN, DSO, FJI, FLH, FLN, GLD, GRD, JOB, JSC, MNP, MON, NCJ, NSC, PYI, RCI, SCO, SQA, UCC, UOC,

Polyvinyl alcohol resins Polyvinyl butyral resins Polyvinyl formal resin Vinyl acetate-acrylate copolymers

No No No Yes

AIP, AZS, DUP, MIL. MON. EW, GRG, MON. ACO, DAN, DSO, FLH, FLN, GLD, KMP, MCC, NCJ, NTC, PPG, RH, SPC, SQA UCC, UOC.

Polyvinyl chloride and copolymer resins: Polyvinyl chloride homopolymer resins

Yes No

Vinyl chloride-acetate copolymer resins All other polyvinyl chloride copolymer resins Polyvinylidine chloride resins: Latex type polyvinylidene chloride resins Solid type polyvinylidene chloride resins All other vinyl resins

No No

AIP, BFG, CNT, FOR, GGC, HKP, KYS, MIL, SHT, UCC, VST, VYN. KYS, MCC. BFG, BOR, CNI, HKP, VYN.

Yes No Yes

BFG, DOW, GRD, UOC. DOW. DUP, GLD, NTC, RH, UCC.

Yes

DUP, LII, MON, SW, UOC.

Yes Yes

DOW, GRD, GYR, PYI, UOC. ADC, CCS, CRS, FRS, GNT, GRD, MCC, SPO, UCC, UOC. AMO, CPV, VAL. HPC, MON. DOW, RH. ATR, MON. ADC, FLH, ICI, MCC, RCD. ARZ, CPV, DSO, DUP, GEP, HPC, JSC, MON, PLC, RCD, VAL.

(2)

All other thermoplastic resins



Chemicals for which separate statistics are reported in this section are indicat ed by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No. 2 The manufacturer did not consent to his identification with the designated prod uct. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

8-8

8-8

Synthetic Organic Chemicals, 1987 Table 26 Plastics and resin materials:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ABS

Abex Corp., Friction Products Div.U.S. CPC International, Inc., Acme Resin Corp. Adco Chemical Co. Allied Corp., Allied Signal Corp. Engineered Materials Sector. American Cyanamid Co. Anderson Development Co. A & E Plastics Corp. EMS-American Grilon, Inc. Air Products & Chemicals, Inc. Amoco Corp. Alpha Corporation of Tennessee American Polymers, Inc. Armstrong World Industries, Inc Arnco Aristech Chemical Div. Arizona Chemical Co. Ashland Oil, Inc. Atlantic Richfield Co., Arco Chemical Co. Auralux Corp. Sherwin-Williams Co., Consumers Div. BASF Corp. Belding Chemical Industries B. F. Goodrich Co. Ranbar Technology, Inc. Ball Chemical Co. Brin-Mont Chemicals, Inc. Allied Bendix Corp., Friction Materials Div. Borden, Inc., Borden Chemical Div. Permuthane Inc. M. A. Bruder & Sons, Inc. Cascade Resins, Inc. BTL Specialty Resin Corp. Synalloy Corp , Blackman Uhler Chemical Div. CasChem, Inc. Chembond Corp. C.N.C. International Inc. Colorado Chemical Specialties, Inc CastChem Inc. Chemfax, Inc. Cargill, Inc. Ciba-Geigy Corp. Carpenter Chemical Co. C. H. Patrick & Co., Inc. C. J. Osborn Chemicals, Inc. CL Industries, Inc. Commercial Products Co., Inc. Cosmic Plastics, Inc. Cain Chemical, Inc. Conap, Inc. Certainteed Corp. H.B. Fuller Cook Paint & Varnish Co. Colorado Resins, Inc.

CSD

Fina Oil & Chemical Co., Cosden Chemical Div. Continential Polymers, Inc. Custom Resins Div. of Bemis Co., Inc. CYRO industries Chemical Exchange Industries, Inc. Dan River, Inc., Chemical Products Div. Dow Corning Corp. Dennis Chemical Co. Dow Chemical Co. Dart Polymers, Inc. Sub of Dart Container Corp. The Derby Co., Inc. Dock Resins Corp. Delta Resins & Refractories DeSoto, Inc. E. I. duPont de Nemours & Co., Inc. Chemicals and Pigments Dept. Finishes and Fabricated Products Dept. Petrochemicals Dept. Photosystems and Electronics Products Dept. Polymer Products Dept. Eastern Color & Chemical Co. E. F. Houghton & Co. Eastman Kodak Co.: Tennessee Eastman Co. Div. Texas Eastman Co. Div. El Paso Products Co. Exxon Chemical Americas Ohio Rubber Eagle Pitcher Ind, Orthane Div. Westinghouse Electric Corp., Insulating Materials Div. Ferro Corp., Keil Chemical Div. Cincinnati Varnish Co. H. B. Fuller Co. Franklin International FMC Corp. Handschy Industries, Inc., Farac Varnishes & Chemicals Formosa Plastics Corp. - U.S.A. Freeman Chemical Corp. FRP Co. Firestone Tire & Rubber Co., Firestone Synthetic Rubber & Latex Co. Div. GAF Corp., Chemical Group General Electric Co.: Electromaterials Dept. Plastics Business Group. Insulting Materials Plastics Div. Georgia-Gulf Corp.,: PVC Compound Div. Plaquemine Div. General Latex & Chemical Corp. Glidden Co.

ACR ACO ACS ACY ADC AEP AGI AIP AMO APH API ARK ARO ART ARZ ASH ATR AUX BAL BAS BCM BFG BLC BMC BME BOR BPT BRU BSC BTL BUC CAS CBD CCC CCS CEI CFX CGL CGY CHC CHP CJO CLU CMP CMS CNE CNI CNT COO CPV CRS

CTP CTR CYR CXI DAN DCC DNS DOW DPI DRB DRC DRR DSO DUP

ECC EFH EK EKT EKX ELP ENJ EPI EW FER FJI FLH FLN FMC FOC FOR FRE FRP FRS

GAF GE

GEI GEP GGC

GLC GLD

8-9

8-9

Section 8 Table 26—Continued Plastics and resin materials:

Code GNT GP GRD GRG GRV GYR HAN HCL

HER HGC HIM HKD HKP HMN HPC HVG HXL HYA

HYC ICF ICI

INP lOy IPC IRI JNS JOB JSC KMP KPT KTP KYS LC LIC LII MCA MCB MCC

MID MIL MMC MMM MNP MOB

8-10

Directory of manufacturers, alphabetical by code, 1987

Name of company Gencorp Polymers Products Georgia-Pacific Corp.: Resins Operations W. R. Grace & Co., Polymers & Chemical Div. P. D. George Co. Guardsman Chemicals, Inc. Goodyear Tire & Rubber Co. Hanna Chemical Coatings Corp. Hoechst Celanese Corp: Bayport Works Engineering Plastics Div. Sou-Tex Works Heresite Protective Coatings Inc. Goodson Polymers, Inc. Himont U.S.A., Inc. Occidental Chemical Corp.: Durez Div. PVC Div. Huntsman Chemical Corp. Hercules, Inc. Ametek, Inc., Haveg Div. Hexcel Corp., Hexcel Chemical Products Dexter Corp: Hysol Aerospace & Industrial Products Div. Dexter Specialty Chemicals Group Hysol Electronic Chemicals Div., Dexter Specialty Chemicals Group BASF Corp., Inmont Div. ICI Americas, Inc. ICI Chemicals Div. ICI Resins Div. Synair Corp. lovite, Inc. Interplastic Corp. Ironsides Co. S. C. Johnson & Son, Inc. Jones-Blair Co. Sybron Chemicals, Inc. Kelly-Moore Paint Co., Inc. Koppers Co., Inc. Kent Polymers, Inc. Keysor Century Corp. Lord Corp., Chemical Products Group Lilly Industrial Coatings, Inc. Lawter International, Inc. Masonite Corp., Alpine Resin Div. Borg-Warner Corp., Borg Warner Chemicals McCloskey Corp.: McCloskey Varnish Co. McCloskey Varnish Co. of California McCloskey Varnish Co. of Oregon Dexter Corp., Midland Div. Milliken & Co., Milliken Chemical Co. EM Industries, Inc., EM Science Div. Minnesota Mining & Manufacturing Co. McWhorter, Inc. Mobay Chemical Corp., Pittsburgh Div.

Code MON MRT NCI NCJ NCP NCP NEV NSC NTC NTL OBC OCF OMC PAC PAS PDI

PEL PER PKI PKL PLC PLN PLR PLS PMC PPG PPL PRA PRC PRT PSG PSL PST PTC PYI QCP QUN RAB RAS RBI RCD RCI REL REZ RH RSN RTC RUO

S SAC SAR

Name of company Monsanto Co. Morton-Thiokol, Inc., Morton Chemical Co. Div. Union Camp Corp., Chemical Products Div. National Casein of New Jersey Niles Chemical Paint Co. Niles Chemical Paint Co. and Kordell Industries Div. Neville Chemical Co. National Starch & Chemical Corp. National Casein Co. NL Industries, Inc., NL Chemicals Div O'Brien Corp. Owens-Corning Fiberglas Corp. Olin Corp. Pacific Anchor Chemical Corp. Pennwalt Corp. Phelps Dodge Industries, Inc., Phelps Dodge Magnet Wire Co. Div. Pelron Corp. Perry & Derrick Co., Inc. Perkins Industries, Inc. Plaskolite, Inc. Phillips Petroleum Co. Disogrin Industries Corp. Polysar, Inc.: Plastic Div. Plastics Engineering Co. Plastics Manufacturing Co. PPG Industries, Inc. Sterling Engineered Products Para-Chem Southern Products Research & Chemical Corp. Pratt & Lambert, Inc., Paint Div. PMC Specialites Group Plasiok Corp. Perstorp Compounds, Inc. Polycast Technology Corp. Morton Thiokol, Inc. Morton Chemical Div. Quaker Chemical Corp. K. J. Quinn & Co., Inc. Raytech Corp. Surface Coatings, Inc. Reeves Brothers, Inc. Richardson Polymer Corp. Reichhold Chemicals, Inc. Reliance Universal, Inc., Louisville Resins Operations Interez, Inc. Rohm & Haas Co. Atochem, Inc., Polymers Div. Mount Vernon Mills, Inc. Ruco Polymer Corp. 8-10 Sandoz, Inc., Colors & Chemicals Div. Southeastern Adhesives Co. Esschem Inc.

Synthetic Organic Chemicals, 1987 Table 26—Continued Plastics and resin materials:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

SBG SC SCN SCO SCP SDH

Samuel Bingham Co. Sterling Chemical, Inc. Schenectady Chemicals, Inc. Scholler, Inc. Henkel Corp. Sterling Drug, Inc., SDI Divestiture Corp. Div. Shell Oil Co., Shell Chemical Co. Div. Shintech, Inc. Standard Oil Co., Silmar Div., Engineered Material Co. Standard Oil Co., Filon Div., Engineered Material Co. Soluol Chem Co., Inc. Soltex Polymer Corp. Mobil Oil Corp.: Mobil Chemical Co.: Chemical Div. Petrochemicals Div. Products Div. Smooth-On, Inc. Chevron Corp., Chevron Chemical Co. MW Manufacturers, Inc., Southern Resin Div. Insilco Corp., Sinclair Paint Co Div. General Electric Co., Silicone Products Dept. Spaulding Fibre Co., Inc., Industrial Plastics Div.

SPO

SHC SHT SIC SIF SLC SLT SM

SMO SOC SOR SPC SPD SPL

SQA SRY SW SYL SYT TNA TX TXS UCC UNO UOC USI USM USR UTC VAL VST VSV VYN WCA WLN WM WPG WRD WVA

Name of company Ameripol Synpol Co. Div. of Uniroyal GoodrichTire Co. Sequa Chemicals, Inc. Synray Corp. Sherwin-Williams Co. Sylvachem Corp. Synthron, Inc. Ethyl Corp. Texaco Chemical Co. Texstyrene Plastics, Inc. Union Carbide Corp. United-Erie, Inc. Union Oil Co. of California Quantum Chemical Corp., USI Division Emhart Corp., Bostik Div. Uniroyal, Inc., Uniroyal Chemical Div. Unitex Chemical Corp. United Merchants & Manufacturers, Inc., Vaichem Div. Vista Chemical Co. Valentine Sugars, Inc., Valite Div. Vygen, Inc. West Coast Adhesives Co. Wilmington Chemical Corp. Inolex Chemical Co. West Point-Pepperell, Inc., Grifftex Chemical Co. Sub. Weyerhaeuser Co. Westvaco Corp.

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

8-11

8-11

8-12

Synthetic Organic Chemicals, 1987

Section 9

pounds, or 19 percent more than the 297 million pounds produced in 1986. Sales of cyclic rubber-processing chemicals in 1987 totaled 263 million pounds, valued at $336 million, compared with 211 million pounds, valued at $273 million, in 1986. Of the total production of cyclic rubber-processing chemicals in 1987, antioxidants, antiozonants, and stabilizers accounted for 57 percent, and accelerators, activators, and vulcanizing agents for 24 percent. Production of antioxidants, antiozonants, and stabilizers, which amounted to 204 million pounds in 1987, included 123 million pounds of amino compounds and 81 million pounds of phenolic and phosphite compounds. Sales of amino antioxidants, antiozonants, and stabilizers in 1987 amounted to 89 million pounds, valued at $130 million; sales of phenolic and phosphite antioxidants, antiozonants, and stabilizers were 50 million pounds, valued at $74 million.

Rubber-Processing Chemicals Rubber-processing chemicals are organic compounds that are added to natural and synthetic rubber to give them qualities necessary for their conversion into finished rubber goods. In this report, statistics are given for cyclic and acyclic compounds by use—such as accelerators, antioxidants, and vulcanizing agents. Data on production and sales of rubber-processing chemicals in 1987 are given in table 27. Data on production of rubber-processing chemicals during 1983-87 is given in figure 10. Production of rubber-processing chemicals as a group in 1987 amounted to 382 million pounds, or 18 percent more than the 324 million pounds produced in 1986. Sales of rubber-processing chemicals in 1987 amounted to 289 million pounds, valued at $359 million, compared with 235 million pounds, valued at $297 million, in 1986. Table 28 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are indentified by company name in table 29. The production of cyclic rubber-processing chemicals in 1987 amounted to 354 million

Production of acyclic rubber-processing chemicals in 1987 amounted to 28 million pounds, or 1 percent more than the 27 million pounds produced in 1986. Sales in 1987 totaled 26 million pounds, valued at $23 million, compared with 25 million pounds, valued at $23 million, in 1986.

Cynthia Trainor 202-252-1354

Figure 10 Rubber-processing chemicals: U.S. production, 1983-87

Millions of pounds

400 360 320 280 240 200 160 120 80 40

1983

1984

1985

1986

1987

9-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

9-1

Section 9 Table 27 Rubber-processing chemicals:

U.S. production and sales, 1987

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

382,014

288,831

358,987

$1.24

354,372

262,853

336,204

1.28

85,133

61,057

94,583

1.55

80,943 11,960 68,983

56,997 12,518 44,479

79,985 12,160 67,825

1.40 .97 1.52

4,190

4,060

14,598

3.60

Antioxidants, antiozonants, and stabilizers, total

203,722

139,185

204,658

1.47

Amino compounds, total Substituted p-phenylenediamines All other amino compounds',

123,185 78,840 44,345

89,384 48,668 40,716

130,264 80,906 49,358

1.46 1.66 1.21

80,537 7,172 352

49,801 6,306 243

74,394 22,587 534

1.49 3.58 2.20

73,013

43,252

51,273

1.19

65,517

62,611

36,963

.59

27,642

25,978

22,783

.88

5,263

(7 )

( 7)

(7 )

22,379

( 7)

(7)

( 7)

Rubber-processing chemicals

Grand Total Cyclic Total Accelerators, activators, and vulcanizing agents total Thiazole derivatives, total 2,2'-Dithlobis[benzothiazole] All other thiazole derivatives All other accelerators, activators, and vulcanizing agents2 3

Phenolic and phosphite compounds, totals Polyphenolics Phenol, hindered All other phenolic and phosphite compounds All other cyclic rubber-processing chemicals6 Acyclic Total Accelerators, activators, and vulcanizing agents, total All other acyclic rubber-processing chemicalsa

, Calculated from unrounded figures. Includes aldehyde-amine reaction products, dithiocarbamates, guanidines, and other accelerators, activators, and vulcanizing agents. 3 Data on dithiocarbamates included In this table are for materials used chiefly In the processing of natural and synthetic rubber. Data on dithiocarbamates, which are used chiefly as fungicides, are included in the section on "Pesticides and Related Products." 4 Includes aldehyde- and acetone-amine reaction products and other amines. • Also includes other antioxidants, antiozonants, and stabilizers. • Includes phosphites, blowing agents, peptizers, and other cyclic rubber-processing chemicals. 7 Reported data were accepted in confidence and may not be published, or no data were reported. • Includes polymerization regulators, shortstops, and other acyclic rubber processing chemicals. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 2

9-2

9-2

Synthetic Organic Chemicals, 1987 Table 28 Rubber-processing chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Rubber-processing chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 29)

Cyclic

Accelerators, activators, and vulcanizing agnets: Yes Aldehyde-amine reaction products: Heptaldehyde-aniline condensate No Tetrahydro-3,5-dimethy1-4H-1,3,5-oxadiazine-4thione No Triethyltrimethylenetriamine No All other aldehyde-amine reaction products, cyclic .. No Dithiocarbamic acid derivatives: Dibenzyldithlocarbamic acid, sodium salt No Dibenzyldithiocarbamic acid, zinc salt No 2,4 Dinitrophenyl dimethyldithiocarbamate No Other cyclic dithiocarbamic acid derivatives No Guanidines: No Dicatechol borate, di-o-tolylguanidine salt No Thiazole derivatives: Yes 1 , 3-Bis (2-benzothiazolylmercaptomethyl) urea No N-tert-Butyl-2-benzothiazolesulfenamide No N-Cyclohexyl-2-benzothiazolesulfenamide No 2 ,5-Dimercapto-1 ,3,4-thiadiazole No 2 , 2 ' -Dithlobis [benzothiazole] Yes 2-Mercaptobenzothiazole No 2-Mercaptobenzothiazole, copper salt No 2-Mercaptobenzothiazole, zinc salt No N-Morpholinyl-2-benzothiazolyl disulfide No N-Oxydiethylene-2-benzothiazolesulfenamide No N - Oxydiethylenethlocarbamyl-N'-oxydiethylenesulfenamide No All other thiazole derivatives, cyclic No All other cyclic accelerators, activators, and vulcanizing agents: Yes Bis(morpholinothlocarbamoyl) disulfide No Dibenzylamine No 1,3-Dihydro-4(or 5)-methy1-2H-benzImidazole-2thione No Dimethylammonium hydrogen isophthalate No DI-N,N' -pentamethylenethiuram tetrasulfide No 4,4'-Dithiodimorpholine No 2-Imidazolidenethione (1, 3-ethylene-2-thiourea) No 2-Mercaptotoluoimidazole, zinc salt No m-Phenylenebismaleimide No Thiocarbanilide No All other accelerators, activators, and vulcanizing agents, cyclic No Antioxidants, antiozonants, and stabilizers: Yes Amino antioxidants, antiozonants, and stabilizers: Yes Aldehyde- and acetone-amine reaction products: No Butyraldehyde-aniline condensate No Diphenylamine-acetone aldehyde No Diphenylamine-acetone condensate No Substituted p-phenylenediamines: Yes Alkylaryl-p-phenylenediamines No N,N'-Bis(1,4-dimethylpenty1)-p-phenylenediamine No N , N' -Bis (1-ethyl-3-methylpentyl) -pphenylenediamine No N,N'-Bis(1-methylhepty1)-p-phenylenediamine No N-Cyclohexyl-N' -phenyl-p-phenylenediamine No Diarylenediamines, mixed No N-(1,3-DimethylbutyI)-N'-phenylp-phenylenediamine No N,N'-131-2-naphthyl-p-phenylenediamine No

USR. RBC. USR. DUP. USR. USR. USR. RBC. VNC. RBC. BFG, MON, USR. MON, USR. VNC. BFG, MON, USR. MON, USR. ACY. USR, VNC. GYR. BFG, USR. BFG. (2) .

ACY. HXL, USR. VNC. VNC. DUP, VNC. MON. RBC. VNC. DUP. RBC. DUP, USR.

DUP. USR. BFG, USR. MON. MON, UPM. UPM. UPM. USR. GYR. UPM, USR. BFG.

9-3

See footnotes at end of table.

9-3

Section 9 Table 28—Continued Rubber-processing chemicals for which U.S. production and/or sales were reported, Identified by manufacturer, 1987

Rubber-processing chemicals

Separate statistics 1

Manufacturers' identification codes (according to list in table 29)

Cyclic—Continued

Antioxidants, antiozonants, and stabilizers— Continued Amino antioxidants, antiozonants, and stabilizers— Continued Substituted p-phenylenediamines—Continued N,N'-Diphenyl-p-phenyienediamine N-Isopropyl-N'-phenyl-p-phenylenediamine N-(1-MethylheptyI)-N'-phenyl-p-phenyienediamine N-(1-MethylpentyI)-N'-phenyl-p-phenylenediamine All other p-phenyienediamines, substituted Other amines: p-Anilinophenol 1,2-Dihydro-6-ethoxy-2,2,4-Trimethylquinoline (Ethoxyquin) 1 ,2-Dihydro-2 9 2 ,4-trimethylquinoline Nonyldiphenylamine mixture (Mono-, di-, and VI) Octyldiphenylamine Octyldiphenylamine, alkylated p-(p-Toluenesulfonamido)diphenylamine Phenolic and phosphite antioxidants and stabilizers: Phosphites: Alkylaryl phosphites mixed Nonylphenyl phosphites, mixed Polymeric phosphites Polyphenolic phosphites, polyalkylated Triaryl phosphites Polyphenolics (Including bisphenols): Bisphenol, hindered 4,4'-Butylidenebis(6-tert-butyl-m-cresol) 2,5-Di-sec-butyldecylhydroquinone 2,5-D1-(1,1-dimethylpropyl)hydroquinone 2,2'-Methylenebis(6-tert-butyl-p-cresol) 2,2'-Methylenebis(6-tert-butyl-4-ethylphenol) 1 , 1 ,3-Tri(2-methy1-4-hydroxy-5-tert-butylphenyl) butane All other phenolic antioxidants and stabilizers: Phenol, alkylated Phenol, hindered Phenol, styrenated, mixtures N-Stearoyl-p-aminophenol All other phenolic antioxidants Blowing agents: p, p' -Oxybis (benzenesulfonhydrazide) 5-Phenyltetrazole p-Toluenesulfonylhydrazide p-Toluenesulfonylsemicarbazide All other acyclic blowing agents Peptizers: 2' , 2" ' -Dithiobis (benzanilide) All other cyclic rubber-processing chemicals: p-tert-Amylphenol sulfide (Tackifier) 4-Chloro-2,6-bis(2,4-dihydroxybenzyl)phenol N-(Cyclohexylthio)phthalimide Dipheny1-4,4'-diphenylmethylenedicarbamate All other rubber-processing chemicals, cyclic

Yes Yes Yes No No

BFG. USR.

No

UPM.

No No Yes No

USR. KPI, USR.

No No

MON. BFG, MON, USR.

No No No No No No No No No No No Yes No No No No No No

USR. BFG, USR. BFG. USR.

No

ICI.

No Yes No No No

ACY, BFG, GYR, NEV, RCI. FER, OMC, USR. NEV, USR. HXL. USR.

No No No No No

USR. OMC. USR. USR. OMC.

No Yes No No No No No

ACY.

BFG.

FER, MCB. MCB, USR. MCB. BFG, MCB. MCB. DUP, USR. MON. USR. MON. ACY, FER. ACY.

PAS. ICI. MON. USR. ACY, FER, WTC.

See footnotes at end of table.

9-4

9-4

Synthetic Organic Chemicals, 1987 Table 28—Continued Rubber-processing chemicals for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Rubber-processing chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 29)

Acyclic

Accelerators, activators, and vulcanizing agents: Dithiocarbamic acid derivatives: Dialkyldithiocarbamic acid derivative Dibutyldithiocarbamic acid, nickel salt Dibutyldithiocarbamic acid, sodium salt Dibutyldithiocarbamic acid, zinc salt Diethyldithiocarbamic acid, cadmium salt and bis(diethylthlocarbamoyl)disulfide, mixture Diethyldithiocarbamic acid, selenium salt Diethyldithiocarbamic acid, sodium salt Diethyldithiocarbamic acid, tellurium salt Diethyldithiocarbamic acid, zinc salt Dimethyldithiocarbamic acid, bismuth salt Dimethyldithiocarbamic acid, copper salt Dimethyldithiocarbamic acid, lead salt Dimethyldithiocarbamic acid, selenium salt Dimethyldithiocarbamic acid, sodium salt and sodium polysulfide Dimethyldithiocarbamic acid, zinc salt All other dithiocarbamic acid derivatives, acyclic Thiurams: Bis(dibutylthlocarbamoyl) disulfide N,N'-Dloctadecyl-N,N'-dlisopropyi thiuram disulfide Xanthates and sulfides: Di-n-butylxantho disulfide Zinc isopropyl xanthate All other acyclic accelerators, activators, and vulcanizing agents: n-Butyraldehyde-butylamine condensate Other, accelerators, activators and vulcanizing agents acyclic Polymerization regulators: n-Decyl mercaptan n-Dodecyl mercaptans tert-Nonyl mercaptan n-Octyi mercaptan Tetradecyl mercaptan All other polymerization regulators, acyclic Shortstops: Dimethyldithiocarbamic acid, potassium salt Dimethyldithiocarbamic acid, sodium salt All other acyclic rubber-processing chemicals: Waxes and paraffinic products Zinc laurate (Activator, physical property improver, and processing auxiliary)

Yes No No No No

VNC, ( 2 ). DUP, USR, VNC. DUP, USR, VNC. VNC.

No No No No No No No No No

VNC. VNC. EK, VNC. VNC. VNC. VNC. VNC. VNC. VNC.

No No No

BFG. VNC. DUP, ( 2 ).

No

VNC.

No

USR.

No No

USR. VNC.

No No

DUP.

No No No No No No No No No No No

USR. ALC, USR, VCC.

No

DUP, RCI.

No

USR.

DUP. PLC. PAS, PLC. PAS, PLC. PLC. PLC. PLC.

Chemicals for which separate statistics are reported In this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No." The manufacturer did not consent to his identification with the designated product. Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

2

9-5

9-5

Section 9 Table 29 Rubber-processing chemicals:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ACY ALC BFG DUP

American Cyanamid Co. Alco Chemical Corp. B. F. Goodrich Co. E. I. duPont de Nemours & Co., Inc. Chemicals and Pigments Dept. Polymer Products Dept. Eastman Kodak Co. Ferro Corp., Ferro Chemical Div. Goodyear Tire & Rubber Co. Hexcel Corp., Hexcel Chemical Products ICI Americas, Inc., Chemicals Div. Kenrich Petrochemicals, Inc. Borg-Warner Corp., Borg Warner Chemicals

MON NEV OMC PAS PLC RBC RCI UPM USR VCC VNC WTC

Monsanto Co. Neville Chemical Co. Olin Corp. Pennwalt Corp. Phillips Petroleum Co. Artel Chemical Corp. Reichhold Chemicals, Inc. UOP, Inc. Uniroyal, Inc., Uniroyal Chemical Div. Vinings Chemical Co. Vanderbilt Chemical Corp. Witco Chemical Corp.

EK FER GYR HXL ICI KPI MCB

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

9-6

9-6

Synthetic Organic Chemicals, 1987

Section 10 Elastomers Elastomers (synthetic rubber) are high polymeric materials with properties similar to those of natural rubber. The term "elastomers" as used in this report means substances, whether in bale, crumb, powder, latex, or other crude form, which can be vulcanized or similarly processed into a material that can be stretched to at least twice their original length; and, after having been so stretched and the stress removed, will return with force to approximately their original length. U.S. production and sales of elastomers in 1987 are shown in table 30. Table 31 lists the products reported in this section and indicates the manufacture(s) of each by code. These codes are identified by company names in table 32. Total U.S. production 1 of synthetic rubber in 1987 amounted to 4,690 million pounds, an increase of 14.9 percent from that produced in 1986. The production of synthetic rubber increased irregularly from 4,013 million pounds in 1983 to 4,690 million pounds in 1987, or by 16.9 percent. (see figure 11). Total sales of elastomers in 1987 amounted 3,109 million pounds, an increase of 25 percent from that sold in 1986. Styrene-butadiene rubber (SBR-type rubber) in 1987 continued to be the elastomer produced in the greatest quantity as it has been for more than 35 years. U.S. production of SBR-type rubber, including 21 million pounds of its vinylpyridine sub-type, amounted to 1,850 million pounds in 1987. Solution polymerized

polybutadiene rubber, a stereo type elastomer, was produced domestically in 1987 in the next largest amount-690 million pounds. Other principal types of synthetic elastomers for which U.S. production data are reported separately are ethylene-propylene rubber, production of which was 522 million pounds in 1987; butadiene-acrylonitrile (NBR-type) rubber, production of which was 142 million pounds; silicone (Q) type elastomers, production of which was 186 million pounds and thermoplastic elastomers (a family of products), production of which was 422 million pounds. Sales of SBR-type rubber, including 10 million pounds of its vinylpyridine sub-type, by U.S. producers in 1987 amounted to 1,003 million pounds. Sales of solution polymerized polybutadiene rubber amounted to 338 million pounds, and those of ethylene-propylene rubber to 442 million pounds. In 1987, sales of NBR-type rubber in 1987 amounted to 97 million pounds, silicone type elastomer sales amounted to 142 million pounds and sales of thermoplastic elastomers amounted to 364 million pounds in 1987. Edward J. Taylor 202-252--1362

Until now urethane type elastomers have been included in the section VIII "Plastics and Resin Materials." The commission has now begun reporting statistics for urethane elastomers in two sections, section VIII, plastics and resin materials, and section X, elastomers (synthetic rubber). Henceforth those polyurethane products classified as "thermoplastic" urethane elastomers will be reported in SOC section X; all other urethane elastomers will remain in SOC section VIII.

Figure 11 Elastomers: U.S. production, 1983-87 Billions of pounds 5

1983

1984

1985

1986

1987

10-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

10-1

Section 10 Table 30 Elastomers (synthetic rubber):' U.S. production and sales, 1987

Elastomers

Grand total Butadiene-acrylonitrile type (NBR-type) Ethylene-propylene type (EP-type) Polybutadiene (solution polymerized) type (BR-type) Silicone (Q) type elastomers Styrene-butadiene type (SBR-type) 4 Styrene-butadiene-vinylpyridine type Thermoplastic elastomers (such as styrene-block copolymers, thermoplastic olefin elastomers, thermoplastic polyurethane elastomers, and co-polyesters) All other elastomers 5

Production2

Sales Quantity2

Value

Average Unit value3

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

4,690,358

3,108,761

2,714,048

$.87

142,238 521.673

96,544 441,837

93,666 317,852

.97 .72

689,665 186,010 1,828,911 20,936

338,399 142,267 993,158 10,098

151,633 494,283 458,654 11,000

.45 3.47 .46 1.09

421,997 878,928

364,277 722,181

401,841 785,119

1.10 1.09

I The term "elastomers" is defined as substances In bale, crumb, powder, latex, and other crude forms which can be vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original length and, after having been stretched and the stress removed, will return with force to approximately their original length. 2 Includes oil content of oil-extended elastomers. 3 Calculated from unrounded figures. 4 More than four-fifth of SBR elastomer production is the dry type of product. 6 Includes butyl, chlorinated natural rubber, chlorinated polyethylene, epichlorohydrin, fluoroelastomers, polyacrylic ester type, polybutadiene type (emulsion), polychloroprene (neoprene) type, polyisoprenes (including cyclorubber), polysulfide, and miscellaneous elastomers. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

10-2

10-2

Synthetic Organic Chemicals, 1987 Table 31 Elastomers for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Elastomers

Separate statistics '

Manufacturers' Identification codes (according to list in table 32)

Cyclic elastomers: Cyclized polyisoprene (cyclorubber) Epichlorohydrin elastomers (CO, ECO) type Styrene-butadiene (S OR SBR) type: Styrene-butadiene, dry type Styrene-butadiene, latex type Styrene-butadiene-vinylpyridine Styrene-butadiene type elastomers, other Thermoplastic elastomers (such as styrene-block copolymers, thermoplastic olefin elastomers, thermoplastic urethane elastomers, and co-polyesters) Cyclic elastomers, all other All other cyclic elastomers Acyclic elastomers: Butadiene-acrylonitrile (nitrile) (NBR) type Butyl(isobutylene-isoprene) type Chlorinated rubber, natural and synthetic Ethylene-propylene (EP) type Fluorinated elastomers (CFM, FKM, FFKM) type Polyacrylate ester type: Polyacrylic (ACM) ester type elastomers Polyalkalene oxide Polybutadiene acrylic acid acrylonitrile terpolymer (PBAN) Polybutadiene (BR) type: Polybutadiene, emulsion-polymerized Polybutadiene, solution-polymerized Polychloroprene (Neoprene) (CR) type Polyisoprene (IR) type Polysulfide (T) type elastomers Silicone (Q) type elastomers Acyclic elastomers, all other: All other acyclic elastomers

No No Yes No No Yes No

WAY. DUP, SHC.

Yes

BFG, DOW, EEP, ENT, FRS, GEP, MON, QUN, SHC, USR.

No

HPC, TNA.

Yes No No Yes No

BFG, CPY, GYR, MMM, USR. ENJ. DOW, HPC. CPY, DUP, ENJ, PLR, USR. DUP, MMM, NES.

No No

ACY, BFG. PRC.

No

ASY.

No Yes No No No No

GYR, SPO. ASY, FRS, GYR, PLC. DKA, DUP, LC. GYR. MRT. DCC, DUP, SPD, SWS.

No

MRT.

CPY, FRS, GRD, GYR, SPO. BFG, GYR, MMM, PLR, RCI. BFG, FRS, GNT, GYR. LC.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

10-3

10-3

Section 10 Table 32 Elastomers (synthetic rubber):

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ACY ASY BFG CPY DCC DKA DOW DUP

American Cyanamid Co. American Synthetic Rubber Corp. B. F. Goodrich Co. Copolymer Rubber & Chemical Corp. Dow Corning Corp. Denka Chemical Corp. Dow Chemical Co. E. I. duPont de Nemours & Co., Inc • Polymer Products Dept. Fluorcarbon Company Exxon Chemical Americas: Firestone Tire & Rubber Co., Firestone Synthetic Rubber & Latex Co. Div. General Electric Co., Plastics Div. Gencorp Polymers Products W. R. Grace & Co., Polymers & Chemical Div. Goodyear Tire & Rubber Co. Hercules, Inc.

LC MMM MON MRT

Lord Corp., Chemical Products Group Minnesota Mining and Manufacturing Co. Monsanto Co. Morton-Thiokol, Inc., Morton Chemical Co. Div Ruetgers-Nease Chemical Co. Phillips Petroleum Co. Products Research & Chemical Corp. K.J. Quinn & Co., Inc. Reichold Chemicals, Inc. Shell 011 Co., Shell Chemical Co. Div. General Electric Co., Silicone Products Dept. Ameripol Co., Div. of Uniroyal Goodrich Tire Co. Wacker Silicones Ethyl Corp Uniroyal, Inc., Chemical Group Olin Hunt Speciality Products, Inc.

EEP ENJ FRS GEP GNT GRD GYR HPC

NES PLC PRC QUN RCI SHC SPD SPO SWS TNA USR WAY

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app A. Source: Compiled from data recleved in response to questionnaires of the U.S. International Trade Commission.

10-4

10-4

Synthetic Organic Chemicals, 1987

Section 11 Plasticizers Plasticizers are organic chemicals that are added to synthetic plastics and resin materials to (1) improve workability during fabrication, (2) extend or modify the natural properties of these materials, or (3) develop new improved properties not present in the original material. Table 33 presents statistics on U.S. production and sales of plasticizers in as great a detail as is possible without revealing the operations of individual producers. U.S. production of plasticizers totaled 1,998 million pounds in 1987, an increase of 16.0 percent from the 1,722 million pounds reported for 1986. The trend of production of these products is shown in the graph in figure 12 Sales of plasticizers totaled 1,876 million pounds, valued at $896 million, in 1987, compared with 1,624 million pounds, valued at $765 million, in 1986. Production of cyclic plasticizers in 1987, which consisted chiefly of the esters of phthalic anhydride, phosphoric acid, and trimellitic acid,

amounted to 1,455 million pounds, an increase of 10.9 percent from the 1,312 million pounds reported for 1986. Sales of cyclic plasticizers in 1987 totaled 1,452 million pounds, valued at $628 million, compared with 1,245 million pounds, valued at $517 million, in 1986. The most important cyclic plasticizers were the dioctyl phthalates, with production of 343 million pounds, in 1987. Production of acyclic plasticizers in 1987 totaled 543 million pounds, an increase of 32.5 percent from the 410 million pounds reported for 1986. Sales of acyclic plasticizers totaled 424 million pounds, valued at $268 million, in 1987, compared with 379 million pounds, valued at $248 million, in 1986. Epoxidized esters were the most important acyclic plasticizers in 1987 with production of 143 million pounds. Table 34 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 35.

Jesse Lawrence Johnson 202-252-1351

Figure 12 Plasticizers: U.S. production, 1983-87 Billions of pounds

2

1

0 1983

1984

1985

1986

1987

11-1

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

Section 11 Table 33 Plasticizers: U.S. production and sales, 1987

Average Unit value2

Production'

Sales Quantity

1,000 pounds

1,000 pounds

1,998,495

1,875,572

895,666

$0.48

1,697,652 300,843

1,609,728 265,844

731,478 164,188

.45 .99

1,455,074

1,451,905

627,675

.43

1,304,994

1,312,504

521,185

.40

25,167 18,972 161,510 203,612 12,792 343,138 30,954 508,849

22,614 14,535 162,573 195,898 12,743 353,863 28,812 521,466

10,045 23,773 58,570 69,140 7,656 124,897 15,998 211,106

.44 1.64 .36 .35 .60 .35 .57 .40

Trimellitic acid esters

57,366

65,193

45,748

.70

All other cyclic plasticizers 8

92,714

74,208

60,742

.82

543,421

423,667

267,991

.63

167,869

95,767

63,464

.66

49,006 (8) 6,342 112,521

48,486 922 6,156 40,203

24,662 580 5,240 32,982

.51 .63 .85 .82

83,185

61,708

46,481

.75

143,382

135,548

65,505

.48

120,648 22,734

117,864 17,684

49,243 16,262

.42 .92

2,614

2,499

3,014

1.22

11,638

10,958

6,144

.56

1,478 (8 ) 10,160

1,544 261 9,153

962 455 4,727

.62 1.74 .52

Dibutyl secabate Di(2-ethylhexyl) sebacate

813 3,127

869 2,518

1,484 3,828

1.71 1.52

Stearic acid esters, total

10,405

10,228

12,599

1.23

338 10,067

338 9,890

284 12,315

.73 1.25

120,388

103,572

65,472

.63

Plasticizers

Grand total Benzenold3 Nonbenzenoid

Value • 1,000 dollars

Per pound

Cyclic Total Phthalic anhydride esters, total Dibutyl phthalate' (including dilsobutyl phthalates) Diethyl phthalate Diisodecyl phthalate* Dlisononyl Phthalate Dimethyl phthalate Dioctyl phthalates* DI-tridecyl phthalate All other phthalic anhydride esters

Acyclic Total Adipic acid esters, total D1(2-ethylhexyl) adipate Diisooctyl adipate Ditridecyl adipate All other adipic acid esters Complex linear polyesters and polymeric plasticizers Epoxidized esters, total Epoxidized soya oil esters All other epoxidized esters Myristic Acid Esters Oleic acid esters, total Butyl oleate Decyl oleate All other oleic acid esters

n-Butyl stearate All other stearic acid esters All other acyclic plasticizers?

Includes data for compounds used principally (but not exclusively) as primary plasticizers. Does not include clearly 11-2 defined extenders or secondary plasticizers. 2 Calculated from unrounded figures. 3 Includes benzenoid products as defined in part 1, schedule 4, of the Tariff Schedules of the United States Annotated.

11-2

Synthetic Organic Chemicals, 1987 Footnotes for table 33—Continued The difference between the production reported here and that shown on the Preliminary Report on U.S. Production of Selected Organic Chemicals (including Synthetic Plastics and Resin Materials), 1987, results from a combination of incorrect reporting by some companies, end-of-year inventory adjustments, and rounding. 5 Includes data for cresyl diphenyl phosphate, dibutyl phenyl phosphate, diphenyi octyl phosphate, tricresyl phosphate, triphenyl phosphate, and other cyclic phosphoric acid esters, glycol dibenzoates, toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. Reported data were accepted in confidence and may not be published, or no data were reported. 7 includes data for azelaic acid esters, citric and acetyicitric acid esters, myristic acid esters, peiargonic acid esters, ricinoleic and acetylricinoleic acid esters, glyceryi and glycol esters, and other acyclic plasticizers. Source: Compiled from data received In response to questionnaires of the U.S. International Trade Commission.

11-3

11-3

Section 11 Table 34 Plasticizers for which U.S. production and/or sales were reported or estimated, Identified by manufacturer, 1987

Plasticizers

Separate statistics

Cyclic

Yes

N-n-Butyl benzenesulfonamide Diethylene glycol dibenzoate Dipropanedlol dibenzoate (Dipropylene glycol dibenzoate) N-ethyl-p-toluenesulfonamide Glyceryl trlbenzoate Phosphoric acid esters: Isodecyl diphenyl phosphate Tricresyl phosphate Triphenyl phosphate All other phosphoric acid esters Phthalic anhydride esters: Bls(2-ethylhexyl)terephthlate Butyl benzyl phthalate Butyl 2-ethylhexyl phthalate Butyl octyl phthalates Cyclohexyl isoctyl phthalates DI(2-butoxyethyl) phthalate Dibutyl phthalate (including Dlisobutyl phthalate)

No No No No No No No No No No Yes No No No No No No Yes

Dicyclohexyl phthalate Diethylene glycol phthalate Diethyl isophthalate Diethyl phthalate DI-(n-heptyl-n-nonyl) phthalate DI-(n-heptyl-n-nonyl) undecyl phthalate Diisodecyl phthalate

No No No Yes No No Yes

Diisohexyl phthalate Dilsononyl phthalate Di(2-methoxyethyl) phthalate Dlmethyl isophthalate Dlmethyl phthalate Dinonyl phthalate Ditridecyl phthalate Diundecyl phthalate Hexyl n-decyl phthalate n-Octyl n-decyl phthalate Phthalic acid, diallyl ester Dioctyl phthalates: DI(2-ethylhexyl) isophthalate Di(2-ethylhexyl) phthalate

No Yes No No Yes No Yes No No No No Yes No No

Dllsooctyl phthalate Di-n-octyl phthalate All other dloctyl phthalates Glycol phthalate esters: Butyl phthalyl butyl glycolate All other phthalic anhydride esters Polyethylene glycol dibenzoate Tetrahydrofurfuryl oleate Toluenesulfonamide o-, p-mixtures Trimellitic acid esters Tri(2-ethylhexyl) trimellitate Tri-n-hexyl trimellitate Triisodecyl trimellitate Trilsononyl trimellitate Triisooctyl trimellitate Trimethyl trimellitate

No No No No No No No No Yes No No No No No No

Manufacturers' identification codes (according to list in table 35)

TNA. KLM, VEL. KLM, VEL, UTC. NES. UTC, VEL. MON. FMC. FMC, MON. FMC, MON, SM. EKT. MON. BAS. ART, RCI. UTC. HAL. ART, BAS, EKT, HCC, MRF, NOD, UTC, WTH. UTC, ( 2 ). CMB. (2) . EKT, KF, MON, MRF. BAS. BAS, ENJ. ART, BAS, ENJ, HCC, MON, NOD, RCI, TEK. ENJ. ART, BAS, ENJ, TEK. EKT. UTC, ( 2 ). EKT, KF, MRF, WTC, UTC, ( 2 ). ENJ. ART, ENJ, HCC, NOD, SM, TEK. ART, TEK. VST. ART, RCI. TNA. MRF. ART, BAS, EKT, ENJ, HCC, RCI, TEK, VST. ENJ, HAL, NOD, RCI, TEK. EK. BAS, WTH. (2) . BAS, MON, NOD, TEK WTC. VEL. WTC. UTC. BAS, HCC, TEK. (2) (2) . ENJ, HCC. ART, TEK. ENJ, HAL, NOD, RCI, TEK. FER, ( 2 ).

See footnotes at end of table.

11-4

11 4 -

Synthetic Organic Chemicals, 1987 Table 34—Continued Plasticizers for which U.S. production and/or sales were reported or estimated, Identified by manufacturer, 1987

Plasticizers

Separate statistics

Manufacturers' identification codes (according to list In table 35)

Cyclic—Continued Trimellitic acid esters—Continued Tri-n-octyl n-decyl trimeilitate Trioctyl trimellitate All other trimellitic acid esters All other cyclic plasticizers Acyclic

No No No Yes Yes

Adipic acid esters: Butylene glycol adipate DI(2-(2-butoxyethoxy)ethyl) adipate Dibutoxyethyl adipate DI(2-ethylhexyl) adipate

Yes No No No No

Di-n-hexyl adipate Diisobutyl adipate Diisodecyl adipate Diisononyi adipate Dilsooctyl adipate Diisopropyl adipate Dimethyl adipate Di-n-octyl adipate Di-tridecyl adipate Ethylene glycol adipate Neopentyl glycol adipate n-Octyl n-decyl adipate All others adipic acid esters Azelaic acid esters: Bis(hydroxypropyl) azelate DI(2-ethylhexyl) azelate Citric and acetylcitric acid esters: Tributyl acetylcitrate Tributyl citrate Triethyl acetylcitrate Triethyl citrate All other citric and acetylcitric acid esters Complex linear polyesters and polymeric plasticizers: Adipic acid type complex linear polyesters and polymeric plasticizers

No No No No Yes No No No Yes No No No Yes No No No No No No No No No Yes

All other complex linear polyesters and polymeric plasticizers Epoxidized esters: Epoxidized linseed oils Epoxidized pentaerythritol tetraphthalate Epoxidized soya oils Epoxidized tall oils 2-Ethylhexyl epoxytallates All other epoxidized esters Glyceryl tripropionate Glutaric acid esters: Neopentyl glycol glutarate All other glutaric acid esters Myristic acid esters: Isopropyl myristate Myristyl ethoxy myristate All other myristic acid esters

HAL, RCI. ART, EKT, RCI, ( 2 ). ART, TEK, ( 2 ), ( 2 ). BAS, BOE, NEV, NOD, SBC.

HAL. HAL, MON, RCI. EKT, HAL. ART, BAS, CAS, EKT, ENJ, HAL, HCC, MON, NOD, RCI, TEK, WTH. EKT, MON. HAL, HCC, WTC. HAL, HCC, MRF, NOD. ART, ENJ, TEK. ENJ, HAL. HCC, RCI. VND, WTH. MRF, ( 2 ). WM, WTH. EMR, HCC, NOD, SM, WM. HAL. HAL. ART, HCC, RCI. HAL, HCC, MON, WTC. EMR. EMR, HAL, RCI. UTC. (2) • •(2) (2) • CCL, ( 2).

No

EMR, HAL, MRF, TEK, WTC, WTH.

No

ARZ, DIX, EKX, EMR, SM, VND, WTC.

Yes No No Yes No No Yes No No No No Yes No No No

UCC, VIK, WTC. UCC. FER, FMC, TEK, UCC, VIK, WTC. WTC. UCC. REZ, UCC, VIK. EKT. HAL. HAL. CAS, WM, WTH. SCP. WTH.

See footnotes at end of table.

11-5

11-5

Section 11 Table 34—Continued Plasticizers for which U.S. production and/or sales were reported or estimated, identified by manufacturer, 1987

Plasticizers

Separate statistics'

Manufacturers' identification codes (according to list in table 35)

Acyclic—Continued Octanoic acid esters: Palmityl octanoate All other octanoic acid esters Oleic acid esters: Butyl oleate Decyl oleate 2-Ethylhexyl oleate Glyceryl trioleate (Triolein) Isobutyl oleate Isooctyl oleate Methyl oleate Neopentyl glycol dioleate Oleyl oleate Propyl oleates: n-Propyl oleate All other oleic acid esters Palmitic acid esters: n-Butyl palmitate 2-Ethylhexyl palmitate Isobutyl palmitate Isopropyl palmitate Pelargonic acid esters: 2-Ethyhexyl pelargonate Glycol pelargonate Isodecyl pelargonate Triethylene glycol dipelargonate All other pelargonic acid esters Phosphoric acid esters: Tri(2-butoxyethyl) phosphate Triethyl phosphate Ricinoleic and acetylricinoleic acid esters: n-Butyl acetylricinoleate Butyl ricinoleate Ethylene glycol monoricinoleate Glyceryl monoricinoleate Glyceryl tri(acetylricinoleate) Methyl acetylricinoleate Methyl ricinoleate Propylene glycol monoricinoleate Sebacic acid esters: Dibutoxyethyl sebacate Dibutyl sebacate DI(2-ethylhexyl) sebacate Dlisopropyl sebacate Dimethyl sebacate Propylene glycol sebacate Stearic acid esters: n-Butyl stearate Diethylene glycol succinate 2-Ethylhexyl stearate Hexadecyl stearate Isobutyl stearate Isodecyl stearate Isopropyl stearate Myristyl stearate 2-Octyldecy1-12-stearoyl stearate Tridecyl stearate All other stearic acid esters

No No No Yes Yes Yes No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes No No No Yes Yes No No No No No No No No No No

(2). (2). CHL, EMR, HAL, WTC, WTH. SBC, SCP, VND. HAL, ( 2 ). EMR, WTC. SBC, WTH. HAL. EMR, TCH, WTC. HCC. CAS, SBC. EMR. HAL. EKT. VND, WM, WTH. WTH. WM, WTH. CAS, SBC. EMR. EMR. HAL. HCC, HCL, WM. FMC, MON. EKT. CAS. CAS. CAS. CAS. CAS. CAS. CAS. CAS. HAL. HAL, WM, ( 2 ). HAL, HCC, TEK, ( 2 ). SBC, ( 2 ). EMR, ( 2 ), ( 2 ). HAL. CHL, EMR, TCH, WM, WTC, WTH. CMB. CAS, STC, WM. HCL. EMR, WTH. WM. CAS. VND. VND. HCC, WM. SBC, WM, WTC.

See footnotes at end of table.

11-6

11-6

Synthetic Organic Chemicals, 1987 Table 34—Continued Plasticizers for which U.S. production and/or sales were reported or estimated, identified by manufacturer, 1987

Plasticizers

Separate statistics 1

Manufacturers' identification codes (according to list in table 35)

Acyclic—Continued Sucrose acetate Isobutyrate Tetraethylene glycol di(2-ethylhexanoate) Triethylene glycol dicaprylate Triethylene glycol di(caprylate-caprate) Triethylene glycol di(2-ethylbutyrate) Triethylene glycol di(2-ethylhexanoate) 2,2,4-Trimethy1-1 ,3-pentanediol dilsobutyrate All other acyclic plasticizers

No No No No No No No Yes

EKT. HAL, UCC, WM. WM. HAL. HAL, UCC. EKT, HAL. EKX. HCC, HPC, WM.

1 Chemicals for which separate statistics are reported in this section are Indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No. 2 The manufacturer did not consent to his identification with the designated product.

Source: Compiled from data received in response to questionnaires of the U.S International Trade Commission.

11-7

222-174 0 - 88 - 5 : QL 3

11-7

Section 11 Table 35 Plasticizers:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ART ARZ BAS BOE CAS CCL CHL CMB DIX EK EKT EKX EMR

Aristech Chemical Corp. Arizona Chemical Co. BASF Corp. Boehme Filatex, Inc CasChem, Inc Catawba-Chariab, Inc. Chemol Co. Cambridge Industries Co. Dixie Chemical Co., Inc. Eastman Kodak Co.: Tennessee Eastman Co Div. Texas Eastman Co. Div. Emery Chemicals Div. of National Distillers & Chemical Corp. Exxon Chemical Americas Ferro Corp.' Ferro Chemical Div. Grant Chemical Div. FMC Corp. C. P. Hall Co. Hatco Chemical Corp. Hoechst Celanese Corp., Sou-Tex Works Hercules, Inc. Dynamit Nobel Chemicals, Inc.

KLM MON MRF NES NEV NOD RCI REZ SBC SCP SM

Kalama Chemical, Inc. Monsanto Co. Morflex Chemical Co., Inc. Ruetgers-Nease Chemical Co. Neville Chemical Co. Nuodex, Inc. Reichhold Chemicals, Inc. Interez, Inc. Scher Chemicals, Inc. Henkel Corp. Mobil Oil Corp., Mobil Chemical Co., Chemical Products Div. Quantum Chemical Corp., Emery Div. Teknor Apex Co. Ethyl Corp. Union Carbide Corp. Unitex Chemical Corp. Van De Mark Chemical Co., Inc. Vesicol Chemical Corp. Viking Chemical Co. Van Dyk Div. of Mallinckrodt, Inc. Vista Chemical Co. Inolex Chemical Co. Witco Chemical Corp. Union Camp Corp.

ENJ FER

FMC HAL HCC HCL HPC KF

TCH TEK TNA UCC UTC VDM VEL VIK VND VST WM WTC WTH

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

11-8

11-8

Synthetic Organic Chemicals, 1987

Section 12 Surface-Active Agents The surface-active agents included in this report are organic chemicals that reduce the surface tension of water or other solvents and are used chiefly as detergents, dispersing agents, emulsifiers, foaming agents, or wetting agents in either aqueous or nonaqueous systems. Waxes and products used chiefly as plasticizers are excluded. Surface-active agents are produced from natural fats and oils, from silvichemicals such as lignin, rosin, and tall oil, and from chemical intermediates derived from coal tar and petroleum. A major part of the output of the bulk chemicals shown in this report is consumed in the form of packaged soaps and detergents for household and industrial use. The remainder is used in the processing of textiles and leather, in ore flotation and oil-drilling operations, and in the manufacture of agricultural sprays, cosmetics, elastomers, foods, lubricants, paint, pharmaceuticals, and many other products. The statistics for production and sales of surface-active agents (table 36) are grouped by ionic class and by chemical class and subclass. All quantities are reported in terms of 100-percent organic surface-active ingredients and thus exclude all inorganic salts, water, and other diluents. Sales statistics reflect sales of bulk surface-active agents only; sales of formulated products are excluded. Data for "all other" in each of the categories, which was published in previous editions, can be derived by subtracting from the totals of each category the sum of the enumerated items within that category. Data for the production of surface-active agents during 1983-87 are shown in figure 13. Total U.S. production of surface-active agents in 1987 amounted to 6,269 million pounds, or 6.3 percent more than the 5,895 million pounds reported for 1986. Sales of bulk surface-active

agents in 1987 amounted to 3,923 million pounds, valued at $1,713 million, compared with sales in 1986 of 3,567 million pounds, valued at $1,606 million. In terms of quantity, sales in 1987 were 10.0 percent more than in 1986. Production of anionic surface-active agents in 1987 amounted to 3,672 million pounds, or 58.6 percent of the total surfactant output reported for 1987. Sales of anionics in 1987 amounted to 1,788 million pounds, valued at $526 million. Production of cationic surface-active agents in 1987 amounted to 655 million pounds, 33.0 percent more than the 492 million pounds reported in 1986. Production of nonionic surface-active agents amounted to 1,909 million pounds in 1987, 11.2 percent more than the 1,717 million pounds reported in 1986. Sales of cationic surface-active agents in 1987 increased by 27.3 percent in terms of quantity, and by 13.8 percent in terms of value when compared with sales as reported in 1986. Sales of nonionics in 1987 increased by 12.4 percent in terms of quantity, and by 5.9 percent in terms of value when compared with sales as reported in 1986. The difference between production and sales reflects inventory changes and captive consumption of surface-active agents by synthetic rubber producers, and by manufacturers of cosmetics, packaged detergents, bar soaps, and other formulated consumer products. In some instances the difference may also reflect quantities of surface-active agents used as chemical intermediates, e.g., nonionic alcohol and alkylphenol ethoxylates, which may be converted to anionic surface-active agents by phosphation or sulfation. Table 37 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 38.

Eric Land 202-252-1349

12-1

12-1

Section 12 Figure 13 Surface-active agents: U.S. production, 1983-87

Millions of pounds 7

6

5

3

1983

1984

1985

1986

1987

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

12-2

12-2

Synthetic Organic Chemicals, 1987 Table 36 Surface-active agents: U.S. production and sales, 1987

Value

Average Unit value3

Sales2 Surface-active agents

Production'

Quantity

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Grand total

6,268,533

3,923,017

1,712,716

$0.44

Benzenoid4 Nonbenzenoid

1,460,055 4,808,478

840,263 3,082,754

386,270 1,326,446

.46 .43

33,129

30,007

28,818

.96

5,694

Amphoteric Total (Carboxymethyl)(3-(coconut oil amido) propyli dimethylammonium hydroxide, inner salt N-Dodecy1-3-iminodipropionic acid, disodium salt N-(Tallow alkyl)-3-iminodipropionic acid, disodium salt All other amphoteric.surface active agents

4,938

3,050

.62

194

203

288

1.42

240

227

287

1.26

27,001

24,639

25,193

1.03

3,672,111

1,787,551

525,968

.29

861,483

242,017

88,000

.36

3,484 409

1,927 81

1,548 81

.80 1.00

3,075 14,636 129,634 98,898 11,689 385,520

1,846 827 5,736 78,435 4,286 31,509

1,467 1,274 2,289 20,158 2,246 8,292

.79 1.54 .40 .26 .52 .26

217,622

119,297

52,193

.44

51,078

39,376

37,208

.94

33,754

28,468

25,477

.89

1,422

1,278

933

.73

1,154

1,138

1,035

.91

6,727

5,959

5,721

.96

6,392

5,400

4,737

.88

2,155 578

1,770 575

1,562 448

.88 .78

Anionic Total Carboxylic acids (and salts thereof), total Amine salts of fatty, rosin, and tall oil acids, total Stearic acid, triethanolamine salt All other amine salts of fatty, rosin, and tall oil acids Coconut oil acids, potassium salt Coconut oil acids, sodium salt Rosin acids, potassium salt Tall oil acids, potassium salt Tallow acids, sodium salt All other carboxylic acids (and salts thereof) Phosphoric and polyphosphoric acid esters (and salts thereof), total Alcohols and phenols, alkoxylated and phosphated, total Decyl alcohol, ethoxylated and phosphated Dinonylphenol, ethoxylated and phosphated Mixed linear alcohols, ethoxylated and phosphated Nonylphenol, ethoxylated and phosphated Octylphenol, ethoxylated and phosphated Phenol, ethoxylated and phosphated Tridecyl alcohol, ethoxylated and phosphated All other alcohols and phenols, alkoxylated and phosphated Decyl and octyl phosphate 2-Ethylhexyl phosphate 2-Ethylhexyl phosphate, sodium salt Mixed alkyl phosphate All other phosphoric and polyphosphoric acid esters (and salts thereof)

2,438

958

825

.86

12,888 1,418 711 (5) 3,872

11,390 1,370 565 1,940 2,923

10,216 1,150 543 1,202 3,231

.90 .84 .96 .62 1.11

11,323

4,110

5,605

1.36

See footnotes at end of table.

12-3

12-3

Section 12 Table 36-Continued Surface-active agents: U.S. production and sales, 1987

Surface-active agents

Production'

Sales2 Quantity

Value

Average Unit value3

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

1,963,385

1,284,575

274,361

$0.21

736,873 351,699

181,488 91,155

103,296 42,480

.57 .47

5,941

3,641

3,968

1.09

4,378

3,395

2,867

.84

Anionic-Continued Sulfonic acids (and salts thereof), total Alkylbenzenesulfonates, total Dodecylbenzenesulfonic acid Dodecylbenzenesulfonic acid, calcium salt Dodecylbenzenesulfonic acid, isopropylamine salt Dodecylbenzenesulfonic acid, (mixed alkyl) amine salt Docecylbenzenesulfonic acid, sodium salt Dodecylbenzenesulfonic acid, triethanolamine salt All other alkylbenzene suifonates Benzene-, cumene-, toluene-, and xylenesulfonates, total Xylenesulfonic acid, ammonium salt Xylenesulfonic acid, sodium salt All other benzene-, cumene-, toluene-, and xylenes sulfonates Ligninsulfonates and naphthalenesulfonates, total LignInsulfonic acid, ammonium salt Ligninsulfonic acid, calcium salt Ligninsulfonlc acid, sodium salt Ligninulfonic acid, zinc salt All other ligninsulfonates and naphthalene suifonates Sulfosuccinamic acid derivatives Taurine derivatives Sulfonic acids having ester or ether linkages, total Sulfosuccinic acid esters, total Sulfosuccinic acid, bis(2-ethyihexyi) ester, sodium salt Sulfosuccinic acid, diisooctyl ester, sodium salt All other sulfosuccinic acid esters All other sulfonic acids having ester or ether linkages All other sulfonic acids (and salts thereof) Sulfuric acid esters (and salts therof), total° Acids, amides, and esters, sulfated, total Butyl oleate, sulfated, sodium salt All other acids, amides, and esters, sulfated Alcohols, sulfated, total Decyl sulfate, sodium salt Dodecyl sulfate, ammonium salt Dodecyl sulfate, magnesium salt ..... Dodecyl sulfate, sodium salt Dodecyl sulfate, triethanolamine salt .. 2-Ethyihexyl sulfate sodium salt Mixed linear alcohols, sulfated, ammonium salt Mixed linear alcohols, sulfated, sodium salt All other alcohols, sulfated

212

(5)

(5)

(5)

239,988

70,095

46,213

.66

9,886 124,769

10,013 3,189

5,925 1,843

.59 .58

136,858 11,886 98,624

128,497 12,736 95,634

27,314 3,096 18,646

.21 .24 .19

26,348

20,127

5,572

.28

883,465 7,249 507,194 311,833 717

882,295 10,904 513,734 303,641 740

67,905 703 23,424 28,036 119

.08 .06 .05 .09 .16

56,472 3,795 5,734

53,276 3,714 3,467

15,623 2,442 3,725

.29 .66 1.07

160,436 31,437

52,100 26,697

48,662 26,162

.93 .98

23,272

19,856

20,487

1.03

(5) 8,165

135 6,706

116 5,559

.86 .83

128,999

25,403

22,500

.89

36,224

33,014

21,017

.64

796,165

221,583

126,399

.57

8,874 1, 864

5,606 1,617

3,788 758

.68 .47

7,010 221,105 1,102 22,497 469 25,956 10,056 2,056

3,989 61,778 ( 5) 10,247 86 24,873 7,543 2,005

3,030 52,189 (5) 7,341 110 20,399 5,159 2,413

.76 .84 ( 5) .72 1.27 .82 .68 1.20

52,735

4,171

4,069

.98

(5) 106,234

5,925 6,928

5,888 6,810

.99 .98

See footnotes at end of table.

12-4

12-4

Synthetic Organic Chemicals, 1987 Table 36-Continued Surface-active agents: U.S. production and sales, 1987

Surface-active agents

Production'

Sales2 Quantity

Value

Average Unit value3

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Anionic-Continued

Sulfuric acid esters (and salts thereof)Continued Ethers, sulfated, total ,' Dodecyi alcohol, ethoxylated and sulfated, sodium salt Mixed linear alcohols, ethoxylated and sulfated, sodium salt All other ethers, sulfated, Natural fats and oils, sulfated, total Castor oil, sulfated, sodium salt Tall oil, sulfated, sodium salt Tallow, sulfated, sodium salt All other natural fats and oils, sulfated .

537,856

130,964

54,274

$0.41

9,125

7,879

7,819

.99

( 5) 528,731 28,330 4,726 989 612

28,388 94,697 23,235 4,212 930 493

16,351 30,104 16,148 2,768 400 246

.58 .32 .70 .66 .43 .50

22,003

17,600

12,734

.72

Total

654,692

409,853

357,819

.87

Amine oxides and oxygen-containing amines (except those having amide linkages), total

180,413

63,190

47,037

.74

172,615 3,075

54,694 8,173

38,224 6,864

.70 .84

761 1,639 695 234 7,941 158,270

710 1,602 711 849 7,823 34,826

505 1,411 1,015 1,319 5,693 21,417

.71 .88 1.43 1.55 .73 .61

7,798

8,496

8,813

1.04

1,327

Cationic

Acyclic, total (Coconut oil alkyl)amine, ethoxylated (Hydrogenated tallow alkyl)amine, ethoxylated (9-Octadecenyl)amine, ethoxylated Octadecylamine, ethoxylated (Soybean oil alkyl)amine, ethoxylated (Tallow alkyl)amine, ethoxylated All other acyclic Cyclic (including imidazoline and oxazoline derivatives), total 1-(2-Hydroxyethyl)-2-nony1-2imidazoline 1-(2-Hydroxyethy1-2-nor(coconut oil alkyl)-2-imidazoline 1-(2-Hydroxyethyl)-2-nor(tall oil alkyl)2-imidazoline All other cyclic (including imidazoline and oxazoline derivatives) Amines and amine oxides having amide linkages, total Stearic acid-diethylenetriamine condensate Stearic acid-ethienediamine condensate, monoethoxylated All other amines and amine oxides having amide linkages Amines, not containing oxygen (and salts thereof), total Amine salts Diamines and polyamines, total N-(Coconut oil alkyl)trimethylenediamine N-(9-Octadecenyl)trimethylenediamine N-(Tallow alkyl)trimethylenediamine All other diamines and polyamines

1,325

1,693

1.28

272

(5)

(5)

(5)

1,607

577

1,784

3.09

4,592

6,594

5,336

.81

58,839

39,410

26,518

.67

1,328

584

712

1.22

401

359

233

.65

57,110

38,467

25,573

.66

207,132

99,609

79,616

.80

4,106 92,301

5,431 26,685

4,548 25,608

.84 .96

1,377

1,823

2,881

1.58

(6)

(5)

(5)

(5) 24,862

( 5) 22,727

(5) .91

650 7,182 83,092

See footnotes at end of table.

12-5

12-5

Section 12 Table 36-Continued Surface-active agents: U.S. production and sales, 1987

Surface-active agents

Cationic-Continued Amines, not containing oxygen (and salts thereof) -Continued Monoamines, total (Coconut oil alkyl)amine (Hydrogenated tallow alkyl)amine 9-Octadecenylamine Octadecylamine (Soybean oil alkyl)amine (Tallow alkyl)amine All other monoamines Quaternary ammonium salts, containing oxygen, total (Coconut oil alkyl)bis(2-hydroxyethyl, ethoxylated)-methylammonium chloride All other quaternary ammonium salts, containing oxygen Quaternary ammonium salts, not containing oxygen, total Acyclic, total Bis(coconut oil alkyl)dimethylammonium chloride Bis(hydrogenated tallow alkyl)dimethylammonium chloride Trimethyl(soybean oil alkyl) ammonium chloride Trimethyl(tallow alkyl)ammonium chloride All other acyclic Benzenoid, total', Benzyl (coconut oil alkyl) dimethylammonium chloride Benzyldimethyl(mixed alkyl)ammonium chloride Benzyltrimethylammonium chloride All other benzenoid All other cationic surface-active agents

Production'

Sales2 Quantity

Value

Average Unit value3

1,000 pounds

1,000 pounds

1,00 0 dollars

Per pound

110,725 2,174 3,319 12,033 2,013 4,628 8,419 78,139

67,493 991 4,733 6,146 1,561 3,226 10,312 40,524

49,460 1,050 3,576 4,857 1,517 1,506 7,491 29,463

$.73 .47 .76 .79 .97 .47 .73 .73

37,209

39,131

37,688

.96

346

346

388

1.12

36,863

38,785

37,300

.96

161,616

159,856

139,781

.87

134,848

144,041

124,406

.86

(5)

5,742

5,623

.98

75,008

72,926

48,410

.66

( 5)

502

1,053

2.10

818 59,022 26,768

2,974 61,897 15,815

2,622 66,698 15,375

.88 1.08 .97

972

(5)

(5)

( 5)

6,072 3,691 16,033

5,511 (5) 10,304

6,514 (5) 8,861

1.18 (5) .86

9,483

8,657

27,179

3.14

1,908,601

1,695,606

800,111

.47

178,392

133,722

53,791

.40

18,207 5,908 6,882 82 314 747 150 1,426 193

16,047 5,343 6,580 65 313 715 136 741 (5)

11,202 3,660 4,385 64 290 498 93 453 (5)

.70 .68 .67 .99 .93 .70 .69 .61 (5)

2,505

2,154

1,759

.82

160,185

117,675

42,589

.36

26,501

20,279

12,171

.60

3,103 3,436

(5) 2,264

(5) 2,010

(5) .89

1,616 396 121

1,686 384 (5)

1,325 332 (5)

Nonionic Total Carboxylic acid amides, total Diethanolamine codensates (amine/acid , Ratio = 2/1) total Coconut oil acids Coconut oil and tallow acids Lauric acid Lauric and myristic acids Oleic acid Stearic acid Tall oil acids Tallow acids All other diethanolamine condensates (amine/acid Ratio = 2/1) Diethanolamine condensates (other amine/ acid ratios), and other carboxylic acid amides, total Coconut oil acids (amine/acid Ratio = 1/1) Coconut oil acid-ethanolamine condensate (amine/acid Ratio = 1/1) Lauric acid (amine/acid Ratio = 1/1) Lauric and myristic acids (amine/acid Ratio = 1/1) Linoleic acid (amine/acid Ratio = 1/1) Oleic acid (amine/acid Ratio = 1/1 See footnotes at end of table.

12-6

12-6

.79 .86 (5)

Synthetic Organic Chemicals, 1987 Table 36-Continued Surface-active agents: U.S. production and sales, 1987

Surface-active agents

Nonionic-Continued

Diethanolamine condensates (other amine/ acid ratios), and other carboxylic acid amides-Continued Soybean oil acids (amine/acid Ratio = 1/1) Stearlc acid (amine/acid Ratio = 1/1) All other diethanolamine condensates (other amine/acidRatios), and other carboxylic acid amides Carboxylic acid esters, total Anhydrosorbitol esters, total Anhydrosorbitol monolaurate Anhydrosorbitol mono-oleate Anhydrosorbitol monostearate Anhydrosorbitol sesquioleate Anhydrosorbitol trioleate All other anhydrosorbitol esters Diethylene glycol monolaurate Diethylene glycol monostearate Ethoxylated sorbitol and anhydrosorbitol esters, total Ethoxylated anhydrosorbitol monolaurate Ethoxylated anhydrosorbitol monooleate Ethoxylated anhydrosorbitol monostearate Ethoxylated anhydrosorbitol trioleate Ethoxylated anhydrosorbitol tristearate All other ethoxylated sorbitol and anhydrosorbitol esters Ethylene glycol distearate Ethylene glycol monostearate Glycerol esters, total Glycerol mono-oleate Glycerol monoricinoleate Glycerol monostearate All other glycerol esters Natural fats and oils, ethoxylated, total . Castor oil, ethoxylated Hydrogenated castor oil, ethoxylated . Lanolin, ethoxylated All other natural fats and oils, ethoxylated Polyethylene glycol esters, total Polyethylene glyco diester of tall oil acids Polyethylene glyco dilaurate Polyethylene glyco dioleate Polyethylene glyco distearate Polyethylene glyco monoester of tall oil acids Polyethylene glyco monolaurate Polyethylene glyco mono-oleate Polyethylene glyco monopalmItate Polyethylene glyco monostearate Polyethylene glyco sesquiester of tall oil acids All other polyethylene glycol esters Polyglycerol esters, total Polyglycerol mono-oleate All other polyglycerol esters 1,2-Propanediol monostearate All other carboxylic acid esters See footnotes at end of table.

Production'

Sales2 Quantity

Value

Average Unit value3

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

1,097 135

1,084 66

1,734 48

$1.60 .73

123,780

91,912

24,969

.27

300,194

250,028

183,737

.73

36,174 6,002 6,645 17,865 1,017 2,081 2,564 266 70

36,462 5,510 6,294 19,454 919 1,872 2,413 266 73

26,105 3,864 5,083 12,972 787 1,453 1,946 143 77

.72 .70 .81 .67 .86 .78 .81 .54 1.06

35,217

34,075

26,040

.76

6,251

6,022

5,275

.88

8,066

8,101

5,049

.62

13,543

13,071

9,500

.73

2,362

2,219

1,804

.81

903

828

714

.86

4,092 3,268 2,203 66,145 7,263 53 13,346 45,483 38,451 16,843 2,507 1,849

3,834 3,312 2,110 64,480 6,510 54 12,448 45,468 27,844 13,141 1,829 1,558

3,698 1,975 1,347 52,222 4,992 81 10,117 37,032 20,372 8,646 1,289 1,368

.96 .60 .64 .81 .77 1.51 .81 .81 .73 .66 .70 .88

17,252 52,077

11,316 40,856

9,069 29,247

.80 .72

3,032 843 2,650 2,899

(5) 792 989 2,036

(5) 773 749 2,133

(5) .98 .76 1.05

2,978 6,172 4,529 988 8,254

2,534 5,949 3,952 784 6,171

1,555 3,846 2,937 468 4,815

.61 .65 .74 .60 .78

892 18,840 1,374 595 779 1,768 63,181

728 16,921 1,324 595 729 1,185 38,041

547 11,424 1,990 748 1,242 1,719 22,500

.75 .68 1.50 1.26 1.70 1.45 .59

12-7

12-7

Section 12 Table 36-Continued Surface-active agents:

U.S. production and sales, 1987

Surface-active agents

Production'

Sales2 Quantity

Value

Average Unit value3

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

1,408,092

1,304,210

547,886

$.42

501,317 3,589 12,135

466,760 2,648 10,894

199,382 2,420 4,972

.43 .91 .46

10,641 356,607

(6) 355,593

(6) 124,914

(6) .35

677 117,668 808,659

722 96,903 766,677

573 66,503 294,792

.79 .69 .38

25,127 13,472 3,266

21,547 11,170 2,470

17,616 6,504 2,140

.82 .58 .87

1,531 1,578

1,060 1 ,486

1,106 1,830

1.04 1.23

5,280

5,361

6,036

1.13

783,532 685,132

745,130 651,211

277,176 246,822

.43 .38

24,248 ( 6)

23,815 803

15,537 644

.65 .80

74,152 98,116 2,907

69,301 70,773 1,910

14,173 53,712 2,096

.20 .76 1.10

12,309 8,790 74,110

5,124 5,644 58,095

3,746 4,499 43,371

.73 .80 .75

21,923

7,646

14,697

1.92

Nonionic-Continued

Ethers, total Benzenold ethers, total' Dinonylphenol, ethoxylated Dodecylphenol, ethoxylated (Mixed alkyl)phenol-formaldehyde, alkoxylated Nonylphenol, ethoxylated Nonylphenol, ethoxylated and propoxylated All other benzenoid ethers Nonbenzenoid ethers, total Chemically-defined linear alcohols, ethoxylated, total Decyl alcohol, ethoxylated Dodecyl alcohol, ethoxylated 9-Octadecenyl alcohol, ethoxylated Oleyl alcohol, ethoxylated All other chemically-defined linear alcocols, ethoxylated Mixed linear alcohols, alkoxylated, total Mixed linear alcohols, ethoxylated Mixed linear alcohols, ethoxylated and propoxylated Tallow alcohol, ethoxylated All other mixed linear alcohols, alkoxylated Other ethers and thioethers, total Mixed alcohols, ethoxylated Poly(mixed ethylene, propylene) glycol Tridecyl alcohol, ethoxylated All other ethers and thioethers All other nonionic surface-active agents

All quantities are given in terms of 100 percent organic surface-active ingredient. Sales include products sold as bulk surface-active agents only. 3 Calculated from unrounded figures. 4 The term "benzenoid" used in this report, describes any surface-active agent, except lignin derivatives, whose molecular structure includes 1 or more 6-membered carbocyclic or heterocylic rings with conjugated double bonds (e.g., the benzene ring or the pyridine ring). 6 Reported data were accepted in confidence and may not be published, or no data were reported. 6 Includes all other anionic surface-active agents. 1

2

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

12-8

12 8 -

Synthetic Organic Chemicals, 1987 Table 37 Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' Identification codes (according to list in table 38)

Amphoteric

1,1-Bis(carboxymethyl)-2-undecy1-2-imidazolinium chloride, disodium salt Bis(2-hydroxyethyl)tallowammonium ethanoate 3- [Caprylamidoethylene-(2-hydroxyethyl)amino]propionic acid Caprylamphopropionate 1-Carboxyethy1-1-(2-hydroxyethyl)-2-heptyl-2imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxyethy1-1-(2-hydroxyethyl)-2-nonyl-2imiazolinium hydroxide, sodium derivative, sodium salt (1-Carboxyheptadecyl)trimethylammonium hydroxide, inner salt Carboxymethyl-3-cocoamidopropyldimethylammonium chloride, sodium salt (Carboxymethyl) [3-(coconut oil amIdo)propylldimethylammonium hydroxide, inner salt 1-Carboxymethyl-2-heptadecy1-1-(2-hydroxyethyl)-2imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxymethyl-1-(2-hydroxyethyl)-2-heptyl-2imidazolinium hydroxide, sodium derivative, sodium sal 1-Carboxymethyl-1-(2-hydroxyethyl)-2-imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxymethyl-1-(2-hydroxyethyl)-2-nonyl-2imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxymethyl-1-(2-hydroxyethyl)-2-undecyl-2imidazolinium hydroxide, sodium derivative, sodium salt 1-Carboxymethyl-1-(2-hydroxyethyl)-2-undecyl-2imidazolinium hydroxide, sodium derivative, sodium salt (Carboxymethyl)-3-laurylamidopropyldimethyl ammonium hydroxide, inner salt Cocoamidoamphoglycinate Cocoamidopropyl betaine N-Cocoamido-propyl-N,N-dimethylamine oxide 3- [3-(Cocoamidopropyl)dimethylammonio]-2hydroxypropane sulfonate 3-Cocoamidopropyl-2-hydroxy-3-sulfopropyldimethyl ammonium hydroxide, inner salt Cocoamphocarboxyglycinate Cocoamphocarboxypropionate Cocoamphopropionate N-(Coconut oil alkyl)-13-alanIne, partial sodium salt N-(Coconut oil alkyl)-13-alanine, sodium salt 3-(Coconut oil alkyl)amidoethylene-(2-hydroxyethyl)aminopropionic acid N-(Coconut oil alkypaminobutyric acid N,N-Di(hydroxyethyl)-N-carboxymethyl tallow ammonium quat, inner salt Dimethyloleylammonium ethanoate Dodecyl disodium banaline, N-(2-carboxyethyl), sodium salt

No No

BRD. MIR.

No No

MIR. MOA.

No

MIR.

No

MIR.

No

DUP.

No

ENJ.

Yes

AAC, CYL(E), ETC, MIR, MZC, SCP, SHX, WM, WTC, ( 2 ).

No

MIR.

tNo

MIR.

No

BRD.

No

AAC, BRD, MIR.

No

MIR.

No

MIR.

No No No No

MIR, MZC. MOA. MOA. MOA.

No

MIR.

No No No No No No

MZC, SCP, SHX. MOA. MOA. MOA. SCP. AAC, DUP.

No No

MIR. ARC.

No No

SHX. MIR.

No

GAF.

See footnotes at end of table.

12-9

12-9

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' Identification codes (according to list In table 38)

Amphoteric—Continued N-Dodecy1-3-iminodipropionic acid N-Dodecyl-3-iminodipropionic acid, disodium salt N-Dodecy1-3-iminodipropionic acid, monosodium salt HeptadecylmethylbenzImidazoline sulfonic acid, sodium salt 1-Hexadecanium-N-carboxymethyl-N-dimethyl, hydroxy salt Hexylisonanylamidocarboxylic acid, monoethanolamine salt 1-Hydroxyethy1-1-(2-hydroxy-3-sodium sulfonatopropy1)2-capry1-2-imidazolinium hydroxide 1-Hydroxyethy1-1-(2-hydroxy-3-sodium sulfonatopropyI)2-nor-(coconut oil fatty acids)-2-imidazolinium hydroxide 1-Hydroxyethy1-1-(2-hydroxy-3-sodium sulfonatopropy1-2oley1-2-imidazolinium hydroxide 1- (2-Hydroxyethyl) -1- (sodium carboxymethyleneoxyethylene)-2-nor-(coconut oil fatty acids)-2imidazolinium hydroxide Isodecyloxypropyliminopropionic acid, monosodium salt Isonanylamidocaproic acid, triethanolamine salt Isostearic amphopropionate Lauroamphocarboxyglycinate Laurylamidopropyl betaine Laurylamphoglycinate Mixed acyclic primary amines, ethoxylated and sulfated, sodium salt (Mixed alkyl)sulfobetaine Oleic acid-ethylenediamine condensate, propoxyiated and sulfated, sodium salt Oleyl betaine 1-(Sodium carboxyethylene)-1-(sodium carboxymethylene-oxyethylene) -2-nor- (tall oil fatty acids)-2-imidazolinium hydroxide 1-(Sodium carboxymethyl)-1-(sodium carboxymethylene-oxyethylene)-2-nor-(coconut oil fatty acids)-2-imidazolinium lauryl sulfate N-(Tallow alkyl)-3-iminodipropionic acid, disodium salt Tridecyloxypoly(ethyleneoxy)propionic acid, potassium salt All other amphoteric surface-active agents

No Yes No

MOA, SCP. AAC, MIR, MOA, SCP. MIR.

No

BRD.

No

GAF.

No

HCL.

No

MIR.

No

MIR.

No

MIR.

No No No No No No No

MIR. ENJ. SHX. MOA. MOA. MOA, MOA.

No No

RH. BRD, MOA, SHX, WM, ( 2 ).

No No

MOA. SCP.

No

MIR.

No Yes

MIR. MIR, MOA, SCP.

No No

MRV. SBC.

No No No No No No No No Yes

SHX. SBP. (2) .

CPC, ( 2 ). PCI. CPC.

No Yes

ICI. AAC, BRD, PCI, SBP, ( 2 ).

Anionic Carboxylic acids (and salts thereof): Amine salts of fatty, rosin, and tall oil acids: Coconut oil acids, diethanolamime salt Coconut oil acids, ethanolamine salt Isostearic acid, mixed isopropanolamines salt Isostearic acid, triethanolamine salt Oleic acid, mixed isopropanolamine salt Oleic acid, morpholine salt Oleic acid, triethanolamine salt 3-Propanoic acid, coco-amino, sodium salt Rosin acids, triethanolamine salt Stearic acid, N, N, N' ,N'-tetrakis(2-hydroxyethyl)ethylenediamine salt Stearic acid, triethanolamine salt

PCI. UTC, (2 ). (2) .

See footnotes at end of table.

12-10

12 10 -

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics'

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued

Carboxylic acids (and salts thereof):—Continued Amine salts of fatty, rosin, and tall oil acids—Continued Tall oil acids, diethanolamine salt (condensate) Tall oil acids, triethanolamine salt Tallow acids, triethanolamine salt All other amine salts of fatty, rosin,anti tall oil acids Carboxylic acids having amide, ester, or ether linkages: Butoxyethylene oxyacetic acid, sodium salt 5 (or 6 ) -Carboxy-4-hexy1-2-cyclohexene-1-octanoic acid, reaction products with castor oil N-(Coconut oil acyl)sarcosine, sodium salt N, N-Dimethyl capramide Dodecyloxypoly (ethyleneoxy ) acetic acid, sodium salt N-Lauroylsarcosine, sodium salt Maleic acid, monoalkyl ester Mixed(secondary linear alcohol) polyethylene propionic acid, sodium salt Poly (oxy-1 ,2-ethanediy1) (2-carboxyethoxy)-w' hydroxy-a , ' - (iminodi-2 , 1-ethanedlyi) bis-,N-(tallow alkyl derivs), potassium salt Poly(oxy-1,2-ethanedly1)-a-carboxy methyl, co(tri-decyloxy), potassium salt TrIdecyloxypoly (ethyleneoxy) acetic acid, sodium salt Carboxylic acids with amide, ester or ether linkage, other Potassium and sodium salts of fatty, rosin, and tall oil acids: Animal grease, sodium salt 5 (or 6) Carboxy-4-hexy1-2-cyclohexene-1-octanoic acid, potassium/sodium salts Castor oil acids, potassium salt Castor oil acids, sodium salt Citric acid, sodium salts (50%) In sodium phosphates (20%) Coconut oil acids, potassium salt

No No No

SHX. PNX. CPC, ENJ, SBP.

No

S, WVA, ( 2).

No

MIR.

No No No

(2) • ENJ, HMP. PEL.

No No No

MIR. HMP. (2) •

No

CHP.

No

MIR.

No

PCI.

No

FTX, HMP, S.

No

BRI, S.

No

NMC.

No No No

(2) • CAS. LUR.

No Yes

HCL. AGP, CON, ESS, HEW, HIP, HNT, NMC, PG, PNX. BSW, CON, CP, ENJ, HEW, LEV, NMC, NPR, PG, ( 2). HNT, NMC. UPF.

Coconut oil acids, sodium salt

Yes

Corn oil acids, potassium salt 2-Ethylhexanoic acid, potassium salt Gluconic acid, potassium and sodium salts with 20 percent mix of sodium bisuifite-formaldehyde Heptanoic acid, potassium salt isonanolc acid, sodium salt Lauric acid, potassium salt Mixed vegetable fatty acids, potassium salt Mixed vegetable fatty acids, sodium salt Naphthenic acid, potassium salt Oleic acid, potassium salt

No No No No No No No No No No

Oleic acid, sodium salt Olive oil acids, sodium salt Palm kernel oil acids, potassium salt Palm kernel oil acids, sodium salt

No No No No

HCL. (2) • HCL. PG . EFH, GRL. NMC. WBG. BSW, CPC, HAL, HNT, PG, WBG, (2) • BSW, WBG. HNT. PG . NMC, PG.

See footnotes at end of table.

12-11

12-11

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identifled by manufacturer, 1987

Surface-active agents

Separate statistics'

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued Carboxylic acids (and salts thereof)—Continued Potassium and sodium salts of fatty, rosin and tall oil acids—Continued Palm oil acids, sodium salt Rosin acids, potassium salt Rosin acids, sodium salt Stearic acid, ammonium salt Stearic acid, potassium salt Stearic acid, sodium salt Tall oil acids, mixed potassium/sodium salt Tall oil acids, potassium salt Tall oil acids, sodium salt Tallow acids, potassium salt Tallow acids, sodium salt All other potassium and sodium salts of fatty, rosin, and tall oil acids Other salts of fatty, rosin and tall oil acids: Alkoxy triacryl titanate Hexyl(lsonanoyi anide)carboxylic acid, mono- and triethanolamine salts Hexyl(lsonanoyl anide)carboxylic acid, di- and triethanolamine salts Isostearlc acid, isoproxy titanium salt Neoalkoxy, trineodecanoyl titanate Neoalkoxy, trineodecanoyl zirconate Oleic acid, ammonium salt Oleic acid, epoxidized, ammonium salt All other carboxylic acids Phosphoric and polyphosphoric acid esters (and salts thereof): Alcohols and phenols, alkoxylated and phosphated: Amyl alcohol, ethoxylated and phosphated Butyl alcohol, ethoxylated and phosphated Decyl alcohol, ethoxylated and phosphated Decyl alcohol, ethoxylated and phosphated, potassium salt C12 - C15 alcohol, ethoxylated, propoxylated and phosphated Decyl alcohol, ethoxylated and polyphosphated Dinonylphenoi, ethoxylated and phosphated Dodecyl alcohol, ethoxylated and phosphated Dodecylphenol, ethoxylated and phosphated 2-Ethylhexanol and ethoxylated nonylphenol, polyphosphated 2-Ethylhexanol and ethoxylated nonylphenol, polyphosphated, sodium salt 2-Ethylhexanol, ethoxylated and phosphated 2-Ethylhexanol, ethoxylated and phosphated, potassium salt Hexyl alcohol, ethoxylated and phosphated Meta, para-cresol, ethoxylated and polyphosphated, neutralized Mixed linear alcohols, ethoxylated and phosphated

No No No No No No No Yes No No Yes

BSW, HEW. ARZ, LEV, PG, WVA, ( 2 ) . ARZ, ( 2 ) . BSW. CON, HEW. CON, LEV, NOC. WVA. CCC, CON, DAN, ESS, FER, HIP, PNX, WVA, ( 2 ). HNT, CON, NMC, WVA, ( 2 ) . AGP, PG, PNX. BSW, CON, CP, HEW, LEV, NMC, NPR, PG, ( 2 ).

No

BRI, USR.

No

KPI.

No

HCL.

No No No No No No No

HCL. KPI. KPI. KPI. CCC. SCP. WVA.

No No Yes

GAF. FTX, GAF. BRI, FTX, GAF, MCP, RPC, TCH.

No

BRI, ETC.

No Yes No No

GAF. GAF. CPC, ETC, GAF, MZG, WTC. CPC, GAF, MZC, STC, WTC. DEX, GAF.

No

CCC.

No No

CCC. ETC, HCL, UTC.

No No

BRI, ETC. GAF.

No Yes

GAF. CRT, CTL, CYL, ENJ, ETC, FER, FTX, GAF, HCL, HIP, HRT, LUR, MOA, MRV, MZC, OC, RPC, TCH, WTC, ( 2 ) , ( 2 ) .

See footnotes at end of table.

12-12

12-12

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued Phosphoric and polyphosphoric acid esters (and salts thereof) —Continued: Alcohols and phenols, alkoxylated and phosphated—Cont Mixed linear alcohols, alkoxylated and phosphated, potassium salt No Mixed linear alcohols, ethoxylated and phosphated, sodium salt No Mixed tridecyl alcohol and 2-ethylhexanol, phosphated, potassium salt No Nonylphenol/diethylenetriamine blend No Nonylphenol, ethoxylated and phosphated Yes

Nonylphenol, ethoxylated and phosphated, diethanolamine salt Nonylphenol, ethoxylated and phosphated, partial sodium salt Nonylphenol, ethoxylated and phosphated sodium salt 9-Octadecenyl alcohol, ethoxylated and phosphated 9-Octadecyl alcohol, ethoxylated and phosphated Octylphenol, ethoxylated and phosphated Phenol, ethoxylated and phosphated Polyhydric alcohol, ethoxylated and phosphated Tridecyl alchol, ethoxylated and phosphated, polyalkylene polyamine salt Tridecyl alcohol, ethoxylated and phosphated Tridecyl alcohol, ethoxylated and phosphated, potassium salt All other alcohols and phenols, alkoxylated and phosphated or polyphosphated Alcohols, phosphated or polyphosphated: Butyl methyl pyrophosphate ethlenedioxy titanium salt/N,N-dimethylaminoethylmethacrylate salt Butyl methyl pyrophosphate isopropoxy titanium salt octyl phosphite adduct Butyl phosphate, potassium salt Decyl and octyl phosphate Decyl polyphosphate, sodium salt 2-Ethylhexyl phosphate 2-Ethylhexyl phosphate, potassium salt 2-Ethylhexyl phosphate, sodium salt 2-Ethylhexyl polyphosphate, sodium salt Hexadecyldiphosphate Hexadecylmonophosphate Hexyl phosphate Hexyl phosphate, potassium salt Isooctyl phosphate Isooctyl phosphate, potassium salt Lauryl alcohol, phosphated Methylbutyl pyrophosphate, ethylenedioxy titanium salt Mixed alkyl phosphate Mixed alkyl phosphate, alkylamine salt Mixed alkyl phosphate, diethanolamine salt Mixed alkyl phosphate, potassium salt Mixed alkyl phosphate, sodium salt

PCI. CHP. CHP. GAF. CPC, CRT, CTL, CYL, DEX, ESS, ETC, GAF, GDC, HCL, HIRT, LUR, MCP, MOA, MZC, OC, OMC, RPC, SCP, TCC, UTC, VKR, WTC.

No

OMC, WTC.

No

GAF.

No No No Yes Yes

WTC. GAF, HCL. GAF. MZC, RH, RPC, WTC. ETC, GAF, MOA, MZC, PEL, WTC. CYL, DEX, GAF.

No No Yes

(2) . DAN, DEX, ETC, GAF, HIP, MIL, VKR.

No

ETC.

No

DEX, SCP.

No

KPI.

No No Yes No Yes

KPI. DUP. APC, ENJ, ETC, HCL, MZC. CRD. APC, BRD, CHP, ETC, FTX, GAF, MCP, OMC, VKR. PCI. CHP, DAN, ENJ, PAT, S, SDC. DEX. ( 2 )• (2) .

No Yes No No No No No No No No

ETC, HCL, ICI. HCL, ICI. BOE, BRI, QCP BRI, QCP. HCL.

No Yes No No No No

KPI. CTL, DUP, ETC, HCL, WTC, ( 2 ). (2) . DUP, SCP. HCL, HYD, QCP. (2) .

12-13

See footnotes at end of table.

12-13

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued Phosphoric and polyphosphoric acid esters (and salts thereof) —Continued Alcohols and phenols, alkoxylated and phosphated—Cont Mixed alkyl phosphate, triethanolanine salt Neoalkoxy tris(dloctyl)phosphato zirconate Neoalkoxy tris(dloctyl)pyrophosphato zirconate Octy diphosphate, oxoethylene titanium salt Octy phosphate Octy phosphate, alkylamine salt Octy phosphate, isoproxy titanium salt Octy phosphate, neoalkoxy titanium salt Octy polyphosphate Octy pyrophosphate, ethylenedioxy titanium salt Octy pyrophosphate, ethylenedioxy titanium salt/dimethylaminomethacrylate salt Octyl pyrophosphate, isoproxy titanium salt Octyl pyrophosphate, neoalkoxy titanium salt Octyl pyrophosphate, oxoethylenedioxy titanium salt Pentaerythritol phosphate N-2(C5 to C 17 )alkylamido-N-carboxyethyl, N-2hydroxyethyl, 3-amino-2-hydroxypropyl phosphate, disodium salt All other phosphated and polyphosphated alcohols Other phosphoric and polyphosphoric acid esters: Blend of fatty and phosphate esters Glycerol, ethoxylated and phosphated Glycerol monoester of mixed fatty acids, phosphated Polyoxyalkylate(fatty alcohol), phosphate ester Stearyl amine polyphosphoric acid, ethoxylated All other phosphoric and polyphosphoric acid esters Sulfonic acids (and salts thereof): Alkylbenzenesulfonates: Dodecylbenzenesulfonates: Dodecylbenzenesulfonic acid

KPI. KPI. KPI. SCP. SCP, KPI. KPI. DEX. KPI.

No No No No No

KPI. KPI. KPI. KPI. MZC.

No No

MOA. BRI, HRT, OC.

No No

MIL. (2) .

No No No No

WTC. BAS. GDC. MOA, UTC, WTC.

Yes

Dodecylbenzenesulfonic acid, ammonium salt Dodecylbenzenesulfonic acid, calcium salt

No Yes

Dodecylbenzenesulfonic acid, diethanolamine salt Dodecylbenzenesulfonicacid, DMAP salt Dodecylbenzenesulfonic acid, isopropanolamine salt Dodecylbenzenesulfonic acid, isopropylamine salt Dodecylbenzenesulfonic acid, isoproxy titanium salt Dodecylbenzenesulfonic acid, (mixed alkyl)amine salt Dodecylbenzenesulfonic acid, monoethanolamine salt Dodecylbenzenesulfonic acid, oleyl amine, ethoxylated, salt Dodecylbenzenesulfonic acid, potassium salt Dodecylbenzenesulfonic acid, sodium salt

No No

CTL, ENJ, JLP, LAS, LEV, NLT, PIL, PLX, STP, TEN, VST, WTC, ( 2 ). CCC, LEV, ( 2 ). HCL, ICI, RH, STP, TMH, WTC, (2) • PCI. WTC.

No Yes

PIL. CIN, ICI, STP, WTC.

No

KPI.

Yes

ECC, FTX, HIP, ( 2 ).

No

PCI, RPC.

No No Yes

HCL. BRI, GDC, LEV. AAC, APC, BLA, BOE, BRI, CP, CPC, CRT, CTL, DOW, DUP, ECC, JLP, LEV, NMC, PCI, PG, PIL, PLX, PNX, RPC, STP, TEN, VST, WTC. AAC, BRD, BRI, CCC, CPC, CTL, ESS, FTX, PCI, PIL, STP, WTC. MRV, OC. 12-14

Dodecylbenzenesulfonic acid, triethanolamine salt .. Yes All other dodecylbenzenesulfonates See footnotes at end of table.

12 14 -

(2) .

No No No No No No No No No No

No

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics 1

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued

Sulfonlc acids (and salts thereof)—Continued Alkylbenzenesulfonates—Continued Benzenesulfonic acid Isopropyl-4- aminobenzenesulfonyi-di(dodecylbenzenesulfonyl)titanate Neoalkoxy, dodecylbenzene-sulfonyl titanate Pentadecylbenzenesulfonic acid, potassium salt Tridecylbenzenesuifonic acid Tridecylbenzenesulfonic acid, sodium salt Benzene-, cumene-, toluene-, and xylenesulfonates: Cumenesulfonic acid, ammonium salt Cumenesulfonic acid, sodium salt Toluenesulfonic acid, potassium salt Toluenesulfonic acid, sodium salt (Toluene-xylene)sulfonic acid Xylenesulfonic acid, ammonium salt Xylenesulfonic acid, sodium salt Ligninsulfonates: Ligninsulfonic acid, ammonium salt Ligninsulfonic acid, calcium salt Ligninsulfonic acid, chromium salt Ligninsulfonic acid, Iron salt Ligninsulfonic acid, magnesium salt Ligninsulfonic acid, manganese salt Ligninsulfonic acid, mixed chromium and iron salts Ligninsulfonic acid, potassium salt Ligninsulfonic acid, sodium salt Ligninsulfonic acid, zinc salt Naphthalenesulfonates: Butylnaphthalenesulfonic acid, sodium salt Butyl-o-phenylphenol sulfonic acid, sodium salt Di(C5-C6 alkyl)naphthalenesulfonic acid Dibutylnaphthalenesulfonic acid Dilsopropyinaphthalenesulfonic acid, sodium salt Isopropyinaphthalenesulfonic acid Methylnaphthalenesulfonic acid, sodium salt Methylnonylnaphthalenesulfonic acid, sodium salt Naphthalenesulfonic acid, sodium salt, formaldehyde condensate All other naphthalenesulfonates Sulfonic acids having amide linkages: Sulfosuccinamic acid derivatives: N-(Coconut oil alkyl)sulfosuccinamic acid, disodium salt N - ( 1 , 2- Dicarboxyethyl)-N-octadecylsulfosuccinamic acid, tetrasodium salt N-Octadecylsuifosuccinamic acid, disodium salt Oleamidosulfosuccinamic acid, disodium salt N- (01eoyloxyisopropyl)sulfosuccinamic acid All other sulfosuccinamic acid derivatives Taurine derivatives: N-(Coconut oil acy1)-N-rpethyltaurine, sodium salt N- Cyclohexyl-N-palmitoyltaurine, sodium salt N-Methyl-N-oleoyitaurine, sodium salt N-Methyl-N-paimitoyltaurine, sodium salt N-Methyl-N-(tall oil acyl)taurine, sodium salt All other sulfonic acids having amide linkages

No No No No No No

WTC. KPI. KPI. CP. PLX. BLA, CMT, CPC, NPR, PG.

No No No No No Yes Yes

NES. NES, STP, WTC. NES. NES, PG, VST. WTC. NES, PG, STP, WTC. ICI, NES, PIL, SDC, SHC, STP, WTC.

Yes Yes No No No No No No Yes Yes

MAR, PSP, RAY, SPA. FPC, LKY, MAR, PSP. MAR, PSP, RAY. MAR, PSP. MAR. MAR. PSP. PSP. MAR, PSP, RAY, WVA. ENJ, MAR, PSP.

No No No No No No No No

UDI. RBC. (2) • UDI. DUP, UDI. UDI. CPC, UDI. UDI.

No No

ICI. HAL.

No

SCP.

No No No No No

ACY, MOA. ACY. SBC. WTC. ACY.

No No No No No No

FTX, GAF. GAF. CPC, GAF, HCL. GAF. CCC, FTX, GAF, WVA. HCL.

See footnotes at end of table.

12-15

12-15

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

No

MOA.

No

MOA, NSC.

Yes

No No Yes No No No

ACC, ACY, AMU, APX, BRI, CCC, CHP, CRT, ECC, ENJ, FTX, HCL, HDG, MCP, MOA, RH, RPC, WTC. AAC, ACY, MOA. FTX. ARI, SHX, SOS, WTC. MOA. ACY. ACY, MOA, WTC.

No

MOA.

No

AAC.

No

SHX.

No

MIR, MOA.

No

SCP.

No

WTC.

No

MOA.

No No

MOA. MOA, WTC.

No

FTX, GAF, HDG, LEV, MZC.

No No

CTL. STP.

No

PG.

No

GAF, RH.

No No

AAC. WTC.

No

PG, (2),

No No No No No No

ARD. UPF. (2) • AAC, DUP, WTC, ( 2 ), ( 2 ). STP. (2)•

Anionic—Continued Sulfonic acids (and salts thereof)—Continued Su!forgo acids having ester or ether linkages: Sulfosuccinamic acid esters: Sulfosuccinic acid, bis(dilsobutyl)ester, amidodisodium salt Suifosuccinic acid, bis(2,6-dimethy1-4-hepty1)ester, sodium salt Sulfosuccinic acid, bis(2-ethylhexyl)ester, sodium salt

Sulfosuccinic acid, dihexyl ester, sodium salt Sulfosuccinic acid, diisobutyl ester, sodium salt Sulfosuccinic acid, dilsooctyl ester, sodium salt Sulfosuccinic acid, dioctyl ester, sodium salt Sulfosuccinic acid, dipentyl ester, sodium salt Sulfosuccinic acid, ditridecyl ester, sodium salt Sulfosuccinic acid, (coconut oil alkyl)Iminolsopropanol half-ester, sodium salt Sulfosuccinic acid, mixed linear alcohol ethoxylate ester, sodium salt Sulfosuccinic acid, (lauryl polyethylene glycol ether) ester, disodium salt Sulfosuccinic acid, monolaureth ester, disodium salt Sulfosuccinic acid, mono-oleamidopolyethyleneglycol ester, disodium salt Sulfosuccinic acid, myristyl ester, disodium monoethanolamine salt Sulfosuccinic acid, nonoxynyl-10 ester, disodium salt Sulfosuccinic acid, oleamidopolyethyleneglycol, disodium salt All other sulfosuccinic acid esters All other sulfonic acids having ester or ether linkages: Coconut oil acids, 2-sulfoethyl ester, sodium salt Dodecyldiphenyloxidedisulfonic acid, disodium salt Dodecyl sulfoacetate, sodium salt 2-Hydroxy, 3-(lauryl-myristyl)(oxy-1-propanesulfonic acid), sodium salt Iso-octylphenol, ethoxylated and sulfonated, sodium salt n-Octylphenol, ethoxylated and sulfonated, sodium sodium salt Petroleum sulfonic acid, calcium salt All other sulfonic acids with ester or ether linkages Other sulfonic acids: Allyl sulfonate, sodium salt Diphenylsulfone sulfonic acid, potassium salt (Mixed alkane)sulfonic acid (Mixed alkane)sulfonic acid, sodium salt Mixed linear olefin sulfonate n-Octanesuifonic acid, sodium salt See footnotes at end of table.

12 16 -

12-16

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics 1

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued

Sulfonic acids (and salts thereof)—Continued Other sulfonic acids—Continued Oleyloxyethyldiamide oxypropanol sulfonic acid Petroleumsulfonic acid, water soluble (acid layer), sodium salt All other sulfonic acids Sulfuric acid esters (and salts thereof): Acids, amides, and esters, sulfated: Carboxylic acid esters (except natural fats and oils), sulfated: Esters of sulfated oleic acid: Butyl oleate, sulfated, sodium salt Butyl and propyl oleate, sulfated, sodium salt Isopropyl oleate, sulfated, sodium salt Methyl oleate, sulfated, sodium salt Oleic acid, sulfated Oleic acid, sulfated, disodium salt Oleic acid, sulfated, sodium salt Propyl oleate, sulfated, sodium salt Other carboxylic acid esters: Coconut oil acids-ethanolamine salt, sulfated, potassium salt Glycerol monoester of coconut oil acids, sulfated, sodium salt Mixed alkyl phenol sulfate, ethoxylated, triethanolamine salt 9-Octadecenyl acetate, sulfated, sodium salt Tall oil acids, sulfated, sodium salt Alcohols, sulfated: Dodecylsu fate salts: Dodecy sulfate, ammonium salt

No

S.

No No

CLU, PIL. CGY, HAL, SLM, WVA.

Yes No No No No No No No

ARI, HIP, ICI, LUR, MCP, MRV, NSC. CRT. DEX. ICI. ACT. MCP. ACY, CIN. MRV.

No

ENJ.

No

CP.

No No No

MIL. DUP. ICI.

Yes

Dodecyl sulfate, triethanolamine salt Decyl and octyl sulfate, sodium salt Decyl sulfate, sodium salt 3,9-Diethyl-6-tridecyl sulfate, sodium salt 2-Ethylhexyl sulfate, sodium salt

Yes No Yes No Yes

7-Ethyl-2-methyl-4-undecyl sulfate, sodium salt Hexadecyl sulfate, sodium salt Hexyl sulfate, potassium salt Mixed linear alcohols, sulfated, ammonium salt

No No No Yes

Mixed linear alcohols, sulfated, diethanolamine salt Mixed linear alcohols, sulfated, magnesium salt Mixed linear alcohols, sulfated, mixed sodium/ cocodiethanolamine salts Mixed linear alcohols, sulfated, sodium salt Mixed linear alcohols, sulfated, triethanolamine salt Octyl sulfate, sodium salt

No No

AAC, BRD, CYL, LEV, STP, TCH, TNI, ( 2). BRD, DUP, JRG, TCH. DUP. JRG. AAC, BRD, CYL, PG, STP. PG. AAC, BRD, DUP, STP, TCH, WTC. AAC, BRD, CYL, STP, TCH, TNI. TCH. ARI, SCP, WTC. NCC. AAC, BRD, NCC, PCI, SCP, TCH, WTC. NCC. AAC. DEX. AAC, CP, NTL, PG, S, SCP, WTC, (2 )• SCP. WTC.

No Yes No No

AAC. AAC, DUP, PG, SCP, WTC. PG, SCP, WTC. AAC, DUP.

Dodecy sulfate, diethanolamine salt Dodecy sulfate, N,N-diethylcyclohexylamine salt Dodecy sulfate, isopropanolamine salt Dodecy sulfate, magnesium salt Dodecy sulfate, potassium salt Dodecy sulfate, sodium salt

No No No Yes No Yes

See footnotes at end of table.

12-17

12-17

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued Sulfuric acid esters (and salts thereof)—Continued Alcohols, sulfated—Continued °leyl sulfate, sodium salt Oxoalcohol bottoms, sulfated, sodium salt Tridecyl sulfate, sodium salt All other linear alcohols, sulfated Ethers, sulfated: Alkylphenols, ethoxylated and sulfated: (Mixed alkyl)phenol, ethoxylated and sulfated, sodium salt 1-Naphthol, ethoxylated and sulfated, free acid Nonylphenol, ethoxylated and sulfated, ammonium salt Nonylphenol, ethoxylated and sulfated, sodium salt Octylphenoxypolyethoxyethyl sulfate Dodecyl alcohol, ethoxylated and sulfated, ammonium salt Dodecyl alcohol, ethoxylated and sulfated, sodium salt Dodecyl and tetradecyl alcohols, ethoxylated and sulfated, ammonium salt Dodecyl and tetradecyl alcohols, ethoxylated and sulfated, magnesium salt Isobutanol, ethoxylated and sulfated, ammonium salt Mixed linear alcohols, ethoxylated and sulfated, ammonium salt Mixed linear alcohols, ethoxylated and sulfated, diethanolamine salt Mixed linear alcohols, ethoxylated and sulfated, sodium salt

Mixed linear alcohols ethoxylated, sulfated, mixed sodium and cocoamphocarboxyglycinate salts Tridecyl alcohol, ethoxylated and sulfated, ammonium salt Tridecyl alcohol, ethoxylated and sulfated, sodium salt Natural fats and oils, sulfated: Castor oil, sulfated, sodium salt

Coconut oil, sulfated, sodium salt Cod oil, sulfated, sodium salt Grease, other than wool, sulfated, sodium salt Herring oil, sulfated Herring oil, sulfated, sodium salt Lard, sulfated, sodium salt Mixed fish oils, sulfated, ammonium salt Mixed fish oils, sulfated, sodium salt Mixed vegetable oils, sulfated, sodium salt Neatsfoot oil, sulfated, sodium salt Peanut oil, sulfated, sodium salt Pecan oil, sulfated, sodium salt Soybean oil, sulfated, sodium salt Tall oil, sulfated, ammonium salt Tall oil, sulfated, sodium salt See footnotes at end of table.

12 18 -

No No No No

DUP. WVA. AAC. LEV.

'No No

(2). TCH.

No

GAF, OC, RPC, STP.

No No

GAF. RH.

No

AAC, MOA, STP.

Yes

AAC, CYL, SCP, STP, TCH.

No

PG, (2).

No

PG.

No

(2).

No

BRD, JTO, PG, SCP, SHC, STP, VST, WTC, ( 2 ) ( 2 ).

No

SCP.

Yes

AAC, BRD, DUP, PG, PIL, SCP, SHC, SHX, STP, TCH, VST, WTC, WVA.

No

AAC.

No

ARC.

No

AAC, BRD.

No

ACT, ACY, ARI, ARL, CRT, DEX, HIP, ICI, LEA, LUR, MRV, S, SCP, SLM, WHW. ACY. WHW. WHW. SLM ARI, SLM, WHW. CIN, CRT, WHW. CIN. CIN, SLM, WHW. CPC. ARI, WHW. ACY. CRT. ACT, WHW. CIN. ACT, ARI, CIN, WHW, WVA.

No No No No No No No Yes No No No No No No Yes

12-18

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Separate statistics

Surface-active agents

Manufacturers' identification codes (according to list in table 38)

Anionic—Continued Sulfuric acid esters (and salts thereof)—Continued Natural fats and oils, sulfated—Continued Tallow, sulfated, sodium salt

Yes

All other natural fats and oils, sulfated All other sulfuric acid esters Other anionic surface-active agents: Alkylalcohol ethoxylated and carbonated, sodium salt Lignin, sodium salt Mixed linear alcohols, ethoxylated and carbonated, sodium salt Nonylphenol, ethoxylated and carbonated, sodium salt Tridecyl alcohol, ethoxylated and carbonated, sodium salt All other anionic surface-active agents

No No

ACY, ARI, CCC, ECC, LUR, MCP, NSC, SOS, WHW. ARI, WVA. BFP, SLM.

No No

MIL. WVA.

No No

S. WTC.

No No

S. DUP, JTO, MOA, S, SLM, WVA.

No No No

ENJ. ENJ. ENJ.

No No No No No No No Yes

MZC. ENJ. ARC, SHX. ARC, ENJ, HCL, MZC, SHX. MZC. HXL. (2) .

Cationic Amine oxides and oxygen-containing amines except those having amide linkage): Acyclic: 3-(C 12-C 15 Alkyloxy)-1-propanamine 3-(C, 2-C 18 Alkyloxy)-1-propanamine N-(C 12-C 18 Alkyi)oxypropyl trimethylene diamine Bis-hydroxyethyl-cocoamine oxide, phosphated, potassium salt Bis-(2-hydroxyethyl)isodecyloxypropylamine oxide N , N-Bis (2-hydroxyethyl) octadecylamine N,N-Bis(2-hydroxyethyl) (tallow alkyl)amine N,N-Bis(2-hydroxyethyl) (tallow alkyl)amine acetate tert-Butylbenzylamine Cocoamidopropyl dimethyl amine (Coconut oil alkyl)amine, ethoxylated (Coconut oil alkyl)amine, ethoxylated, acetate (Coconut oil alkyl amine, propoxylated Cocoylamidopropyldimethylamine oxide N,N-Dimethyldodecylamine oxide N,N-Dimethylhexadecylamine oxide N,N-Dimethyl(mixed alkyl)amine oxide N,N-Dimethyloleylamine oxide Dimethyltetradecylamine oxide Di(pyrrolidonylethyl)imine Ethylenediamine, alkoxyiated Ethylenediamine, ethoxlated Ethylenediamine, propoxylated Hexyloxypropyl amine (Hydrogenated tallow alkyl)amine, ethoxylated N- (2-Hydroxyethyl)-N , N' , N' -tris (2-hydroxypropyl) ethylndiam Isodecyloxypropylamine Isodecyloxypropylamine, ethoxylated 3-(3-lsodecyloxy)propylaminopropyl amine N-Isodecyloxypropyl trimethylene diamine Isodicycloxypropyl amine propoxylated acetate Isononyloxypropylamine Isopropoxy-tris(2-ethylenediamino)ethyl titanate Isotridecyloxypropyiamine

AAC, ARC, ENJ, ETC, HCL, ICI, SHX, SVC, TCH, WTC, ( 2 ). MZC. SHX. SCP. BRD, MZC, PG, SHX, ( 2 ). ARC, BRD. PG, S. SCP. (2) .

No No No No No No No No No No No No No Yes

KPI. WTC. DUP, ENJ. ENJ, ETC, SHX, SVC, WTC.

No No No No No No No No No

ENJ. ENJ. SHX. ENJ. SHX. ENJ. KPI. ENJ.

PCI. (2) .

(2) .

See footnotes at end of table.

12-19

12-19

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

No No No No No No No Yes

No No No

ENJ. SHX. SHX. ICI, RH, SHX. KPI . KPI. KPI. ARC, ETC, GAF, HCL, SHX, TCH, (2) . ARC, ETC, TCH, WTC. JTO. HNT. ARC. RH. BAS. TCH. ARC, ENJ, ETC, GAF, JTO SHX, SVC, ( 2 ). ARC, BAS, DUP, ENJ, ETC, GAF, JTO, S, SHX, SVC, TCH, WTC, (2) ARC, ENJ, ETC, GAF, JTO. ETC, RPC. HCL, ( 2 ).

No

STC.

No

MZC

No No No No No

ARC, BAS, MZC. SHX. JTO. MIL, TCH. RSA.

No

BAS, BRD, SDH, TCH, WTC.

No No

MIL. MIL.

No No No Yes

BRD. BRD. MIR. BRD, MIR, MOA, MZC, SHX.

Yes

BRD, FTX, GAF, MOA, TCH.

No

MIR.

Yes

BRD, GAF, HDG, MIR, MOA,

No No No No

(2) • WVA. HPC. MIL.

No

ARC, ( 2 ).

Cationic Amine oxides and oxygen-containing amines (except those having amide linkages)—Contiuned Acylic—Continued N-Isotridecyloxypropyl trimethylene diamine 3-(Mixed alkoxy)propylamine, ethoxylated oxides 3-(3-Mixed alkoxy)propylaminopropyl amine (Mixed alkyl)amine, ethoxylated Neoalkoxy, trls(m-amino)-phenyl titanate Neoalkoxy, tris(m-amino)-phenyl zirconate Neoalkoxy, tris(ethylenediamino) zirconate (9-Octadecenyl)amine, ethoxylated Octadecylamine, ethoxylated Octyl/decy1-3-(trimethyleneamine)ether Octyldimethylamine oxide 3-Octyloxy and 3-decyloxy-propylamine Polyether amine, ethoxylated Polyethylenepolyamine, alkoxylated Polyimine, propoxylated (Soybean oil alkyl)amine, ethoxylated

Yes No No No No No No Yes

(Tallow alkyl)amine, ethoxylated

Yes

N-(Tallow alkyl) trimethylenediamine, ethoxylated Tallow ethyl alkylamine, ethoxylated, sulfate N,N,N',N'-TetrakIs(2-hydroxyethyl)ethylenediamine . N,N,N' ,N'-Tetrakis(2-hydroxyethyl)ethylenediamine, propoxylated N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylene diamine N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediamlne, propoxylated and ethoxylated 3-(3-Tridecyloxy)propylaminopropyl amine Tridecy1-3-(trimethyleneamine)ether Triethanolamine, ethoxylated Triethanolamine salicylate All other acyclic amine oxides and oxygen-containing amines (except those with amide linkages) Cyclic: Aniline, ethoxylated 2,5-Dimethoxyaniline, ethoxylated 2-Heptadecy1-1,4-hydroxymethy1-4-ethyl-2oxazoline N-Hexadecylmorpholine N-(2-Hydroxyethyl)-1 ,2-diphenylethylenediamine 1-(2-Hydroxyethyl)-2-nony1-2-imidazollne 1-(2-Hydroxyethyl)-2-nor(coconut oil alkyl)-2imidazoline 1-(2-Hydroxyethyl)-2-nor(soya oil alkyl)-21mIdazoline 1-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2Imidazoline 1-(2-Hydroxyethyl)-2-(tall oil alkyl) imidazoline, fatty acid salt Lignin amine Rosin amine, ethoxylated m-Toluidine, ethoxylated All other cyclic amine oxides and oxygen-containing amines (except those having amide linkages) See footnotes at end of table.

12-20

12-20

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Cationic—Continued Amines and amine oxides having amide linkages: Carboxylic acid-diamine and polyamine condensates: Acetic acid, amides with polyalkylene polyamines, salt Caprylic acid tetraethylene-pentamine condensate Coconut acids, dimethylpropylamine condensate, carboxylated Mixed fatty acids-polyalkylenepolyamine condensate Naphthenic acids-polyalkylene polyamine condensate Naphthenic acids-tall oil fatty acids-polyalkylene polyamine condensate 2-Nor tall oil alkyl-1-tall oil amidoethyl imidazoline Oleic acid-diethylenetriamine condensate Oleic acid-N,N-dimethyltrimethylenediamine condensate Pelargonic acid-tetraethylenepentamine condensate Stearic acid-diethylenetriamine condensate Stearic acid-diethylenetriamine condensate, ethyl sulfate Stearic acid, N,N-dimethylamino-propylamine condensate Stearic acid-ethylenediamine condensate Stearic acid-ethylenediamine condensate, monoethoxylated, ethyl sulfate Stearic acid mixed amine condensate Stearic acid-tetraethylenepentamine condensate Tall oil acids/aminoethylpiperazine condensate Tall oil acids-diethylenetriamine condensate Tall oil acids-mixed polyamine condensate Tall oil acids-polyalkylenepolyamine condensate Tall oil acids-polyalkylenepolyamine condensate salts, with dodecylbenzene sulfonic acid and/or tall oil fatty acids Tallow fatty acids-aminoethylethanoiamine condensates All other carboxylic acid-diamine and polyamine condensates Carboxylic acid-diamine and polyamine condensates, alkoxylated: Mixed fatty acids-alkylenediamine condensate, polyethoxylate Stearic acid-ethylenediamine condensate, monoethoxylated All other carboxylic acid-diamine and polyamine condensates, alkoxylated Other amines and amine oxides having amide linkages: 3-Cocoamido-N,N-dimethylpropylamine oxide Cocoamidopropyldimethylamine oxide 1-(2-Hydrogenated tallow amIdoethyl)-2nor(hydrogenated tallow)-2-imidazoline 3-Lauramido-N,N-dimethylpropylamine oxide Laurylamidopropyldimethyl amine Oleamidopropyldimethyl amine Palmitylamidopropyldimethyl amine Stearamidoethyldiethylamine Stearamidoethylethanolamine acetate

(2).

No No

ICI.

No

AAC.

No

JTO, TCH.

No

(2) .

No

(2) .

No No

SHX. LUR.

No No Yes

CCW. ETC, HCL, ICI, OC. CRT, MZC, OC, S.

No

GDC.

No No

MOA. CLD, SOS.

No No No No No No No

GDC. HCL. (2) . ENJ. WTC, WVA. WVA. FER, WVA, ( 2 )

No

(2) .

No

OC.

No

ARI.

No

SHX, WTC.

Yes

DEX, ICI, SLC, VKR.

No

VKR.

No No

MZC. PAT, SBC.

No No No No No No No

SHX. FTX, SQA. WM. WM. WM. S. S.

See footnotes at end of table.

12-21

12-21

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Cationic—Continued Amines and amine oxides having amide linkages—Continued Other amines and amine oxides having amide linkages— Continued Stearic acid, diethanolamine condensate, methyl sulfate Stearylamidopropyldimethyl amine Amines, not containing oxygen (and salts thereof): Amine salts: (Coconut oil alkyl)amine acetate , (Didecyl)amine acetate N,N-Dimethyl-N-alkylamine phosphate (Hydrogenated tallow alkyl)amine acetate Octadecylamine acetate (Tallow alkyl)amine acetate N-(Tallow alkyl)trimethylenediamine acetate N-(Tallow alkyl)trimethylenediamine oleate Diamines and polyamines: Imidazoline derivatives: 1-(2-Aminoethyl)-2-nor(tall oil alkyl)-2Imidazoline 2-Heptadecy1-2-imidazoline Polyamine/tall oil imidazoline Stearamidoethyl-2-heptadecyl Imidazoline N-(Coconut oil alkyl)trimethylenediamine N- (Dimeracidalkyl) trimethyenediamine Dimer diamine N-(Docosyl and eicosyl)tarimethylenediamine N-Dodecyldiethylenetriamine Jet amine D-20 (tall oil derivatives) N-(Mixed alkyl)polyethylenepolyamine N-(9-Octadecenyl)trimethylenediamine Polyalicyclene polyamines and salts and quats 1-Propanamine, 3-(C 12-C 15 alkoxy derivatives) N-(Soybean oil alkyl)trimethylenediamine Tall oil alkyl amines, dimers 3-(Tall oil amino)propyl amine N-(Tallow alkyl)dipropyienetriamine N-(Tallow alkyl)trimethylenediamine N-(Tallow alkyl)-N,N' ,N'-trimethy1-1 ,3propane diamine All other diamines and polyamines Primary monoamines: Alkyldimethylamine oxide Arachidylbehenylalkyl amine (Coconut oil alkyl)amine Dimeracidalkyl amine Dodecylamine (Erucyl alkyl)amine Hexadecylamine (Hydrogenated tallow alkyl)amine (Mixed alkyl)amine 9-Octadecenylamine Octadecylamine Pelargonyl amine (Soybean oil alkyl)amine (Tall oil alkyl)amine (Tallow alkyl)amine

No No

DUP. WM.

No No No No No No No No

ENJ. JTO. (2). ARC. ARC, HCL. ARC, JTO, ( 2 ). ARC. ARC.

No No No No Yes No No No No No No Yes No No No No No No Yes

WTC. CGY. WTC. ICI. ARC, JTO, SHX. ENO. SCP, SHX. ENO. SCO. JTO. CCW. ARC, JTO, SHX. (2). SHX. ENO. SHX. SHX. ARC, ENJ, JTO, SHX. ARC, ENJ, JTO.

No No

ARC. WTC, ( 2 ).

No No Yes No No No No Yes No Yes Yes No Yes No Yes

HCL. ENO, WTC. ARC, ENO, JTO, SHX. ENO, WTC. ARC, SHX. ENO. ARC. ARC, ENJ, ENO, JTO, SHX, WTC. SHX. ARC, ENO, JTO, SHX, WTC. ARC, ENO, SHX, WTC. JTO. ARC, ENO, JTO. ARC. ARC, ENJ, ENO, JTO, SHX, WTC.

See footnotes at end of table.

12-22

12 22 -

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics 1

Manufacturers' identification codes (according to list in table 38)

Cationic—Continued Amines, not containing oxygen (and salts thereof)— Continued Secondary and tertiary monoamines: Bis(coconut oil alkyl)amine Bis(hydrogenated tallow alkyl)amine 1-Decanamine, N,N-didodecyl N,N-Dimethyl(behenyi alkyl)amine N, N-Dimethylbehenylarachidylamine N,N-Dimethyl(coconut oil alkyl)amine N,N-Dimethyldodecylamine N,N-Dimethylerucyl amine N, N-Dimethylhexadecyiamine N,N-Dimethyl(hydrogenated tallow alkyl)amine N,N-Dimethyl(mixed alkyl)amine N,N-Dimethy1-9-octadecenylamine N,N-Dimethyloctadecylamine N,N-Dimethyl(soybean oil alkyl)amine N,N-Dimethyltetradecylamine N-Methylbis(coconut oil alkyl)amine N-Methylbis(hydrogenated tallow alkyl)amine Methyl didecylamine N-Methyldioctadecylamine Tri(hydrogenated tallow) amine Trilsodecylamine Trilaurylamine Tri(mixed alkyl) amine Trioctylamine Tri(tridecyl)amine Oxygen-containing quaternary ammonium salts: 13 - Alanine-N-(2-hydroxyethyl)-N-2,1-oxococoyl amino ethyl, sodium salt 2-(C 13-C 17 Alkyl)-1-(C 14-C 10 amidoethyl)(4,5-dihydro3-methyl)imidazolinium methyl sulfate (2-Aminoethyl)ethyl(hydrogenated tallow aikyi) (2hydroxetl)amniuhysfte Benzyl(coconut oil alkyl)bis(2-hydroxyethyl)ammonium chloride 1-Benzy1-1-(2-hydroxyethyl)-2-nor(tall oil alkyl)-2imidazoline Benzyl(polyoxyethylene-cocoamine)ammonium chloride with benzyl(polyoxyethylene, tallow amine) Benzyl(polyoxyethylene, octadecylamine)ammonium chloride with benzyl(polyoxyethylene,tallow amine) ammonium chloride Benzyl(tallow alkyl)bis(2-hydroxyethypammonium chloride Bis(N - amidopropy1)-N,N-dimethyl-N-ethylammonium ethyl sulfate, dimer acid Bis(N,N' - ethyl(stearic/arachidic/beherilc)amide)cyanoethyl ethylammonium ethosulfate Bis(2-hydroxyethyl, ethoxylated)-methyl-(9octadeceny1)-ammonium chloride Bis(2-hydroxyethyl, ethoxylated)methyloctadecylammonium chloride Bis-2-hydroxyethyl-(hydrogenated tallow)-ethyl sulfate Bis(2-hydroxyethyl)-methyl-(tallow aikyl)ammonium chloride

No No No No No No No No No No No No No No No No No No No No No No No No No

AMO, ARC, JTO. ARC, ENO, WTC. SHX. ENO. WTC. ARC, JTO, PG, S, WTC. ARC, TNA. ENO. ARC. ARC, CPC, SHX. BRD. ENO. ARC, ENO, WTC. ARC, ENO, JTO, WTC. ARC, BRD. ARC. ARC, ENO, SHX, WTC. TNA. ARC, SHX. SHX. SCP. SCP. TNA. ARC, SCP. SHX.

No

SHX.

No

DOW, SVC.

No

LUR.

No

(2) .

No

(2) .

No

S.

No

DUP.

No

SBC.

No

PCI.

No

ARC, SHX

No

ARC.

No

ICI.

No

ARC, MZC.

See footnotes at end of table.

12-23

12-23

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics'

Manufacturers' identification codes (according to list in table 38)

No

HXL.

Cationic—Continued Oxygen-containing quaternary ammonium salts—Continued Bis-2-hydroxyethyl-octyl-methyl-p-toluene sulfonate 1,3-Bis(stearyldimethylammonium chloride)-2propanol (Coconut oil alkyl)amine, ethoxylated, diethosulfate (Coconut oil alkyl)-bis-(2-hydroxyethyl, ethoxylated)methylammonium chloride Coconut oil fatty acid polyoxyethylene Dimethyldodecylethylammonium ether sulfate Distearyldimethylammonium methosulfate Ethanaminium, 2-hydroxy-N , N-bis (2-hydroxyethyl) -Nmethyl-, salt with silicic acid Ethoxylated(hydrogenated tallow amine), methyl ammonium chloride Ethoxyiated, quaternized(C 12-C 10 alkyl)-oxypropyltrimethylene diamine Ethoxylated, quaternized reaction product of formaldehyde and tallow diamine Ethoxylated tallow amine, potassium propionate derivative Ethoxylated tallow amine propionate, methyl sulfate, potassium salt N-Ethyl-N,N-bis(polyoxyethylene)tallow ammonium ethyl sulfate 1-Ethyl-2-(8-heptadeceny1)-1-(2-hydroxyethyl)-2imidazolinium ethyl sulfate N-Ethyl-N-hexadecylmorpholinium ethyl sulfate Ethyl(polyoxyethylene, cocoamine)ethylsulfate N-Ethyl-N-(soybean oil alkyl)morpholinium ethyl sulfate ra-Glyconamidopropyi dimethyl-2-hydroxyethyl ammonium ammonium chloride (Hydrogenated tallow alkyl)amlne, ethoxylated, diethosulfate (2-Hydroxyethyl) dimethyl (3-stearamidopropyl) amoniudhyrgeposat (2-Hydroxyethyl) dimethyl (3-stearamidopropyl) amoniutre Hydroxyethy1-2-undecy1-2,3-imidazoline N-2-Hydroxypropyl-N-methyl-N,N-bis(tallow amido ethyl)-ammonium ethyl sulfate Imidazolinium, 1-(carboxymethyl)-4,5-dihydro-1(hydroxyethyl)-2-nor(cocoalkyl), hydroxide, monosodium salts lmidazolinium, 1-(carboxymethyl)-2-hepty1-1-(2hydroxyethyl), hydroxide, sodium salt Isostearamidopropyldimethylamino glycolate isostearylamidopropyldimethylethylammonium ethyl sulfate (3-Lauramidopropyl)trimethylammonium methyl sulfate Methyl, bis-(2-hydroxyethyl)hydrogenated tallow alkylammonium chloride Methyl, bis-(2-hydroxyethyl)lsodecyloxypropylammonium chloride Methyl, bis-(2-hydroxyethyl)isotridecyloxypropylammonium chloride Methyl, bis-(2-hydroxyethyl)-(soya alkyl) ammonium chloride

No No

MZC. ETC.

Yes No No No

ENJ, GAF, JTO, SHX. S. PCI. HXL.

No

TCH.

No

ENJ.

No

ENJ.

No

ENJ.

No

SVC.

No

SVC.

No

SHX.

No No No

ICI, SHX. BRD, ICI, PCH. S.

No

ICI.

No

VND.

No

ETC.

No

ACY.

No No

ACY. MOA.

No

SHX.

No

SHX.

No No

SHX. SBC.

No

MZC.

No

ACY.

No

ENJ.

No

ENJ.

No

ENJ.

No

ENJ.

See footnotes at end of table.

12-24

12-24

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Cationic—Continued Oxygen-containing quaternary ammonium salts—Continued Methyldioleylethoxyammonlum methyl sulfate Methylditallowimidazolinium methosulfate 1-Methyl-2- (8-heptadecenyl) -1- (9-octadecenyl) amido ethyl 1-Methyl (hydrogenated tallow alkyl) diethyiamine condensate polyethoxylated, methyl sulfate 1 -Methy1-2-nor-tallow-1 -2-tallow amidoethylimidazolinium methyl sulfate N-Methyl-N-polyoxyethylene-N , N-bis (hydrogenated allow amidoethyl)ammonium N-Methyl-N-polyoxyethylene-N N-bis (tallow amidoethyl) Methyltallowdiethylenetriamine condensate, polyethoxylated, methyl sulfate Methyltallowdlethylenetriamine condensate, polypropoxylated, methyl sulfate Mixed alkyl imidazoline derivative, ethoxylated Mixed (coco and soya fatty acids), reaction products with chioromethane and diethylenetriamine, ethoxylated, quaternized Mixed fatty acid amide with diethylene triamine/ethyl sulfate N-Octadecyl-N N-di (2-hydroxyethyl) -Nmethylammonium chloride Polyethyleneimine methyl ammonium sulfate Polypropoxydiethylmethyl ammonium chloride 1 -Propanaminium , N-ethyl-N , N-dimethyl-3- ( 1 oxooctadecyl)amino-, ethyl sulfate Soya fatty acids, reaction products with chioromethane and diethylenetriamine, ethoxylated, quaternized Soya fatty acids, reaction products with chioromethane and diethylenetriamine, propoxylated, quaternized Stearamidopropyldimethylceterylammonium tosylate and propylene glycol Stearylamidopropyldimethylmyristyl acetate ammonium chloride (Tallow alkyl)amine, ethoxylated, diethosulfate (Tallow alkyl)-bis-(2-hydroxyethyl)methylammonlum chloride Tallow amine, ethoxylated, quaternary ammonium salt Trimethyl-p-methylbenzylammonium chloride All other oxygen-containing quaternary ammonium salts (except those having amide linkages) All other oxygen containing quaternary ammonium salts Quaternary ammonium salts, not containing oxygen: Acyclic: Bis(coconut oil alkyl)dimethylammonium chloride Bis(coconut oil alkyl)dimethylammonium nitrate Bis(hydrogenated tallow alkyl) dimethylammonium chloride Bis(hydrogenated tallow alkyl)dimethylammonium methyl sulfate Bis(tallow alkyl)dimethyl ammonium chloride Cocodimethylethylammonium ethyl sulfate N-(Coconut oil alkyl)aminobutyric acid, sodium salt Didecyldimethylammonium chloride

No No

SHX. SVC.

No

SHX.

No

SVC.

No

SHX.

No

SHX.

No

SHX.

No

SVC.

No No

SVC. MOA.

No

ENJ.

No

EFH.

No No No

SHX. HCL. WTC.

No

SBC.

No

ENJ.

No

ENJ.

No

VND.

No No

VND. ETC.

No No No

JTO. DUP, VND. PCI.

No

HYD, SBC, SHX, TCH, WTC, ( 2 ).

No

BRD, HYD.

Yes No

ARC, ENJ, JTO, SHX. ARC.

Yes

ARC, ENO, SHX, WTC.

No No No No No

ARC, SHX. SHX. MZC, SHX. ARC, BRD, JTO, SHX. HNT.

See footnotes at end of table.

12-25

12-25

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics 1

Manufacturers' Identification codes (according to list in table 38)

Cationic—Continued Quaternary ammonium salts, not containing oxygen— Continued Acyclic—Contiuned Dimethyldi(C 12-C18 )ammonium chloride (mixed straight and branched chains) Dimethyldioctadecylammonium choride Dimethyl(soya alkyl)ammonium ethyl sulfate N,N-Dioctyl-N,N-dimethylammonium chloride Di-tallow-amidoammonium sulfate Dodecyltrimethylammonium chloride Ethyldimethyl(mixed alkyl)ammonium ethyl sulfate Ethylhexadecyldimethylammonium bromide HexadecyltrImethylammonium bromide Hexadecyltrimethylammonium chloride Hexane-1 ,6-bis (tributylammonium bromide) (Hydrogenated tallow alkyl)trimethylammonium chloride Hydroxypropylammonium cyanoacetate Lauryl pyridinium chloride Methy1-1-tallow-amidoethy1-2-tallow-ImIdazoliummethyl sulfate Methyltri(C9 -C io )ammonium chloride Methyl(tri-hydrogenated tallow alkyl) ammonium chloride Methyltrioctylammonium chloride (Mixed alkyl)ammonium chloride (Mixed linear alkyl)dimethylammonium methyl sulfate Mixture of N-octyl, N-decyi, N,N-dimethyl ammonium chloride and benzyl, dimethyl, (mixed alkyl)ammonium chloride Octyl-decyi-dimethyl ammonium chloride N-Octyl, N-decyl, N,N-dimethyl ammonium chloride N,N,N' ,N' ,N'-Pentamethyl-N-(tallow alkyl)trimethylene-bis(ammonium chloride) (Stearic acid)-ethylenediamine methylammonium sulfate Stearyi pyridinium chloride Tallow alkyl-propylenediamine methylammonium sulfate Tetrabutylammonium bromide Tetradecy1-4-ethyl pyridinium chloride Tetraethylammonium bromide Tetraheptylammonium bromide Tetramethylammonium bromide Tetramethylammonium chloride Tributylmethylammonium chloride Trihydrogenated tallow ammonium chloride Trimethyl(mixed alkyl)ammonium chloride Trimethyloctadecylammonium chloride Trimethyl(soybean oil alkyl)ammonium chloride Trimethyl(tallow alkyl)ammonium chloride Trimethyltetradecylammonium bromide All other acyclic quaternary ammonium salts, not containing oxygen Cyclic: Benzyl (alkylpyridinium) chloride Benzyl(coconut oil alkyl)dimethylammonium chloride

No No No No No No No No No No No

SHX. ARC, SHX. SVC. BRD, HNT. CRD. ARC, SHX. DEX, JOR. HXL. HXL. ARC, BRD, SHX. HXL

No No No

SHX. (2) . WTC.

No No

CRD. SHX.

No No No

WTC. SCP. MIL.

No

HCL.

No No

BRD. HNT.

No

BRD.

Yes

ARC, SHX.

No No

HCL. WTC.

No No No No No No No No No No No Yes Yes No

HCL. HXL. HXL. EK. EK. RSA. RSA. TNA. ENO. WTC. ARC, SVC. ARC, JTO, SHX. ARC, ENO, JTO, SHX, WTC. HXL.

No

PCI, ( 2).

No Yes

(2) . ENO, GDC, HRT, TCC, WTC.

See footnotes at end of table.

12-26

12-26

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics '

Manufacturers' identification codes (according to list in table 38)

Cationic—Continued Quaternary ammonium salts, not containing oxygen— Continued Cyclic—Continued Benzyl-di(hydrogenated tallow alkyl)-methylammonium chloride Benzyldimethyierucylammonium chloride Benzyldimethyl(hydrogenated tallow alkyl)ammonium chloride Benzyldimethyl(mixed alkyl)ammonium chloride Benzyldimethyloctadecenylammonium chloride Benzyldimethyloctadecylammonium chloride Benzyldimethyl(tallow alkyl)ammonium chloride Benzylhexadecyldimethylammonium chloride Benzyl(hydrogenated tallow alkyl) dimethylammonium chloride Benzyl-methyl-bls(hydrogenated tallow) ammonium chloride Benzylpicolinium chloride 1-Benzylpyridinium chloride Benzyltriethylammonium chloride Benzyltrimethylammonium chloride Butylpicolinium bromide 2 ,4-Dichlorobenzyldimethyl (mixed alkyl) ammonium chloride 1-Dodecylpyridinium chloride (Ethylbenzyl) dimethyl (mixed alkyl) ammonium chloride (Mixed alkyl)dibenzyltrimethy1-1,3-propane diammonium chloride 1-Phenethy1-2-picolinium bromide Phenethylpyridinium bromide All other cyclic quaternary ammonium salts not containing oxygen All other cationic surface-active agents

No No

ARC. ENO.

No Yes No No No No

WTC. AAC, BKM, BRD, CRD, HNT, MZC, SDH, SHX, ( 2 ). MZC. MZC, SHX, TNI. BOE, ENO, WTC. BKM.

No

ARC, ENO, SHX.

No No No No Yes No

ENO, WTC. LUR. BRD. RSA. CRT, HIP, PAH, RSA, SHX, TCC. HXL.

No No

(2) . CCL, DAN.

No

HNT.

No No No

GDC. HXL. HXL.

No No

GDC, ICI, ( 2 ). BRI, CGY, DRC, DUP, JTO, MIR, MOA, RPC, TCH, WM, WTC.

No No Yes

SCP, TCH. CYL(E), FTX, NSC. ARD, BRD, BRI, CCC, CCL, CON, CTL, CYL, ECC, EFH, FTX, GAF, GDC, HNT, HRT, LEA, LUR, MCP, MOA, MRV, MZC, PNX, RPC, SBC, SCP, SHX, STP, TCH, VAL, WTC. BRD, CRT, CTL, ENJ, ESS, MOA, MZC, SBC, UNN. FER. CRD, MOA, MZC, SHX. CRD, MOA, MZC, SBC, STP. MOA. FER, RPC, SOS. CPC, CTL, CYL(E), EFH, FTX, GAF, MOA, MZC, STP.

Nonionic Carboxylic acid amides: Diethanolamine condensates (Amine/acid ratio = 2/1): Capric acid (Ratio = 2/1) Castor oil acids (Ratio = 2/1) Coconut oil acids (Ratio = 2/1)

Coconut oil and tallow acids (Ratio = 2/1)

Yes

Lard oil acids Lauric acid (Ratio = 2/1) Lauric and myristic acids (Ratio = 2/1) Linoleic acid (Ratio = 2/1) Mixed carboxylic acids Mixed fatty acids neuturalized Oleic acid (Ratio = 2/1)

No Yes Yes No No No Yes

See footnotes at end of table.

12-27

12-27

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics 1

Manufacturers' identification codes (according to list in table 38)

Nonionic—Continued Carboxylic acid amides—Contiuned Diethanolamine condensates (Amine/acid ratio = 2/1)— Continued Palmitic and stearic acids (Ratio = 2/1) Pelargonic acid (Ratio = 2/1) Soybean oil acids (Ratio = 2/1) Stearic acid (Ratio = 2/1) Tall oil acids (Ratio = 2/1) Tallow acids (Ratio = 2/1) All other diethanolamine condensates (Ratio = 2/1) Diethanolamine condensates (Other amine/acid ratios): Capric acid (Ratio = 1 /1) Coconut acids, modified Coconut oil acids (Ratio = 1/1)

No No No Yes Yes Yes No No No Yes

Lard oil acids (Ratio = 1 /1) Lauric acid (Ratio = 1/1)

No Yes

Lauric and myristic acids (Ratio = 1/1) Linoleic acid (Ratio = 1/1)

Yes Yes

Mixed carboxylic acids (Ratio = 1/1) Mixed fatty acids (Ratio = 1 /1) Myristic acid (Ratio = 1/1) Oleic acid (Ratio = 1/1) Palmitic and stearic acids (Ratio = 1/1) Palm kernel oil acids (Ratio = 1/1) Rapeseed acids (Ratio = 1/1) Soybean oil acids (Ratio = 1 /1) Stearic acid (Ratio = 1/1) Tall oil acids (Ratio = 1 /1) Tallow acids (Ratio = 1/1) All other diethanolamine condensates All other carboxylic acid amides: Coconut oil acids Coconut oil acids (Ratio = 1/1) Coconut oil acids (Ratio = 2/1) Coconut oil acids-dimethylaminopropylamine condensate (Ratio = 1/1) Coconut oil acids-ethanolamine condensate, ethoxylated Coconut oil dimethanolamine-propylamine Diethanolamine-stearic acid (Ratio = 1/2) Dimethylethanolamine-stearic acid (Ratio = 1/1) Dioieic acid (Ratio = 1/2) Glycol amide stearate (Ratio = 1 /1) Hydrogenated tallow acids (Ratio = 2/1) Hydrogenated tallow acids, aminoethylethanolamide, acetate salt Hydrogenated tallow glycerides diethylenetriamine condensate Isonanoic acid mono and triethanolamine salt Isostearic acid, aminoethylethanolamide, acetate salt See footnotes at end of table.

12-28

No No No Yes No No No Yes Yes No No No

RPC. TCH. MZC. CYL(E), EFH, OC, VAL. BRI, ECC, HCL, MOA, MZC, PNX, SBC, WVA. CYL(E), EFH, ICI, MOA. FTX, MOA. MOA. ETC. BRD, CTL, CYL(E), ETC, FTX, GAF, HNT, HRT, HTN, JRG, MIR, MOA, MZC, OC, PIL, QCP, SBC, SCP, SHX, STP, TCC, WTC, ( 2 ). QCP. CYL(E), GAF, MOA, SBC, TCH, TNI, WTC. BRD, CYL(E), HTN, MOA, SBC. ARD, CYL(E), MOA, MZC, SBC, VND. SOS, WTC. WTC. MOA. ETC, SBC, TMH. BRD, BRI. TMH. EFH. MOA, MZC, SBC. CHP, ECC, ENJ, HIP, MRV. CHP, WTC, WVA. MOA, QCP. BRD, MOA.

Yes

HTN, MOA, PAT, STP. AAC, FTX, MOA, MZC, PG, SCP, SOS. ENJ, MOA, STP.

No

JRG.

No No No No No No No

BRD, STP. GAF. VND. VND. CLD. VND. ARC.

No

PCI.

No No

HRT. HCL.

No

PCI.

No Yes

12-28

ayrurtetic urganic unerrucass,

1Y0/

Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics 1

Manufacturers' identification codes (according to list in table 38)

Nonionic—Continued Carboxylic acid amides—Continued All other carboxylic acid amines—Continued Lauric acid Lauric acid-ethanolamine condensate, ethoxylated Lauric and myristic acids Mink amidopropy dimethyl amine (Ratio = 1/1) Mixed fatty acids, diethanolamine condensate Myristic acid Oleic acid-ethanolamine condensate, ethoxylated Stearic acid (Ratio = 1/1) Stearic acid (Ratio = 2/1) Stearic acid aminoethanolamine (Ratio = 1.0/1.65) Stearic acid-aminoethylethanolamine (Ratio = 1.75/1.0) Stearic acid-N-aminoethylethanolamine condensate Stearic acid diethanolamine (Ratio = 1.0/11.6) Stearic acid-ethylenediamine condensate (Ratio = 1/2) Stearic acid monoethanolamine condensate Tall oil acids-dimethylamine condensate (Ratio = 1/1) Tall oil fatty acids (Ratio = 1/2) Tall oil fatty acids (Ratio = 2.7/1) Tall oil fatty acids (Ratio = 1.5/1) Tall oil fatty acids-triethanolamine condensate Tallow acids (Ratio = 1.00/1.65) Tallow, N-3-(dimethylamino)propyl (Ratio = 1/3) All other carboxylic acid amides Carboxylic acid esters: Anhydrosorbital esters: Anhydrosorbito dioleate Anhydrosorbito monoester of tall oil acids Anhydrosorbito monolaurate Anhydrosorbito mono-oleate Anhydrosorbito monopalmitate Anhydrosorbito monostearate Anhydrosorbito sesquioleate Anhydrosorbito sesquistearate Anhydrosorbito triester of tall oil acids Anhydrosorbito trioleate Anhydrosorblto tristearate All other anhydrosorbitol esters Diethylene glycol esters: Diethylene glyco distearate Diethylene glyco monoester of coconut oil acids Diethylene glyco monoester of tall oil acids Diethylene giyco monoester of tallow acids Diethylene glyco monolaurate Diethylene giyco mono-oleate Diethylene glyco monostearate Diethylene glyco sesqulester of tall oil acids Diethylene glyco sesquilaurate Diethylene glyco terephthalate Ethoxylated anhydrosorbitol esters: Ethoxylated anhydrosorbitol monolaurate Ethoxylated anhydrosorbitol mono-oleate Ethoxylated anhydrosorbitol monopalmitate Ethoxylated anhydrosorbitol monostearate

No No No No No No No No No No

CYL(E), HTN, MOA. MZC. GAF, MOA, TMH, VND. VND. WTC. UCC. SHX. GAF, MOA, VND. CYL(E), ECC. CHP.

No No No

SBC. APC, BOE. CHP.

No No

TCH. WTC,

No No No No No No No No

BKM. EFH. EFH. EFH. (2). PAT. PAT. ARC, CGY, EFH, SBC, SCP, ROB.

No No Yes Yes No Yes Yes No No Yes No No

ICI. HDG, MZC. BRD, ICI, MZC, TCH. BRD, HDG, ICI, MZC, TCH. ICI, TCH. BRD, HDG, ICI, MZC, TCH. BRD, HDG, TCH. TCH. ICI, MZC. BRD, ICI, TCH. ICI. BRD.

No No No No Yes No Yes No No No

BRD. BRD. BKM. ENJ. ECC, HDG, MZC. CTL, QCP. CYL(E), ECC, HDG, STP. ECC. BRD. UPF.

Yes Yes

ETC, HDG, ICI, MZC, SVC, TCH. BRD, ETC, HDG, ICI, MZC, SVC, TCH. ICI. BRD, HDG, ICI, MZC, TCH.

No Yes

See footnotes at end of table.

12-29 12-29

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Nonionic—Continued Carboxylic acid esters—Continued Ethoxylated anhydrosorbitol esters—Continued Ethoxylated anhydrosorbitol triester of tall oil acids Ethoxylated anhydrosorbitol trioleate Ethoxylated anhydrosorbitol tristearate All other ethoxylated anhydrosorbitol esters Ethoxylated sorbitol esters: Ethoxylated sorbito beeswax ester Ethoxylated sorbito hexaester of tall oil acids Ethoxylated sorbito hexaoleate Ethoxylated sorbito lanolin ester Ethoxylated sorbito mono-oleate Ethoxylated sorbito monostearate Ethoxylated sorbito oleate, acetylated Ethoxylated sorbito pentalaurate Ethoxylated sorbito tetraester of lauric and oleic acids Ethoxylated sorbito tetraester of tall oil acids Ethoxylated sorbito tetraoleate Ethoxylated sorbito tetrastearate Ethylene glycol esters: Ethylene glycol distearate Ethylene glycol monostearate Glycerol esters: Complex glycerol esters: Glycerol diacetyltartrate monostearate Glycerol mono- and dlesters of mixed fatty acids Glycerol monoester of mixed fatty acids, acetylated Glycerol monoester of mixed fatty acids, succinylated Glycerol mono-oleate, ethoxylated All other complex glycerol esters Glycerol esters of chemically defined acids: Glycerol dllaurate Glycerol dioleate Glycerol monolaurate Glycerol mono-oleate Glycerol monoricinoleate Glycerol monostearate

Glycerol trioctanoate/decanoate Glycerol trioleate Glycerol esters of mixed acids: Glycerol diester of coconut oil acids Glycerol mono-, di-, and triesters of hydrogenated tallow acids Glycerol monoester of C 8-C 10 acids Glycerol monoester of coconut oil acids Glycerol monoester of cottonseed oil acids Glycerol monoester of hydrogenated cottonseed oil acids

No Yes Yes No

ICI. ETC, HDG, ICI, MZC, TCH. BRD, ICI, MZC. BRD.

No No No No No No No No

ICI. MZC, TCH. ICI, TCH. ICI. CPC, ICI. TCH. ICI. ICI, MZC.

No No No No

ICI. AAC. ICI. ICI.

Yes Yes

CYL(E), EMR, ENJ, HDG, MZC, STP, WM, WTC. BRD, CYL, HDG, MZC, STP, VND, WM, WTC.

No No

EKT. ICI.

No

EKT.

No No No

EKT. SCP. BRD.

No No No Yes

No No

CAS, VND. STP, WTC. BRD. BRD, EFH, EMR, HAL, HDG, MZC, STP, TCH, WTC. BRD, HDG, MZC. BRD, CCC, CHL, CRT, CYL, EMR, HAL, HDG, HRT, LUR, MZC, SOS, SQA, STP, SVA, TCH, VND, WM, WTC, ( 2 ). WM. SVC.

No

WM.

No No No No

WPG. SVC. BRD, TCH EKT.

No

EKT, WM.

Yes Yes

See footnotes at end of table.

12-30

12-30

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

No

EKT.

Nonionic—Continued

Carboxylic acid esters—Continued Glycerol esters—Continued Glycerol esters of mixed acids—Contiuned Glycero monoester of hydrogenated lard acids Glycero monoester of hydrogenated soybean oil acids Glycero monoester of lard acids Glycero monoester of palm oil acids Glycero monoester of safflower oil acids Glycero monoester of tall oil acids Glycero monoester of tallow acids Glycero sesquiester of tall oil acids Glycero triester of mixed fatty acids Mixed ester of resin and rosin acids All other glycerol esters of mixed acids Natural fats and oils, ethoxylated: Castor oil, ethoxylated Coconut oil, ethoxylated Hydrogenated castor oil,, ethoxylated Lanolin, ethoxylated Mixed fatty acids, alkyl ether, ethoxylated Mixed tall oil and castor oil acids, ethoxylated Mixed tall oil and rosin acids, ethoxylated Oleic acid, ethoxylated and propoxylated Tall oil acids, ethoxylated Tall oil acids, ethoxylated and propoxylated Tall oil, refined, ethoxylated All other natural fats and oils, ethoxylated Polyethylene glycol esters: Polyethylene glycol esters of chemically-defined acids: Polyethylene glycol dilaurate

Yes

No Yes Yes No No No No No No No No

Yes

Polyethylene glycol dioleate

Yes

Polyethylene glycol distearate

Yes

Polyethylene glycol hydroxyacetate Polyethylene glycol monocaprylate Polyethylene glycol monoisostearate Polyethylene glycol monoiaurate

No No No Yes

Polyethylene glycol mono-monomerate Polyethylene glycol mono-oleate

No Yes

Polyethylene glycol mono-oleate, ethoxylated Polyethylene glycol monopalmitate Polyethylene glycol monopelargonate, methoxylated Polyethylene glycol monopelargonate Polyethylene glycol monoricinoleate Polyethylene glycol monostearate

No Yes

See footnotes at end of table.

222 174 0 -

No No No No No No No No No No

-

88

-

6 : 0L 3

No No No Yes

BFP, EKT. EKT, TCH. EKT. EKT. EFH, FER. CPC, EKT. PCI. SVC. WVA. BFP. CAS, ETC, GAF, GLY, HCL, HTN,ICI, MIL, S, SVC, TCH, TMH, ( 2 ). ETC, HCL. ETC, GAF, HCL, ICI, MIL, TCH. AAC, CRD, HCL, HDG, TCH, VCC. (2) . GAF. HCL. MIL . GAF, HCL. (2) . TCH, ( 2 ). GAF, MIL.

BRD, EFH, ETC, HDG, MZC, STP, TCH, WM. BRD, CCC, CLD, EFH, ETC, HAL, MIL, SOS, STP, TCH. BRD, CHP, MZC, QCP, SBC, STP, TCH. CCA. ECC. ETC. BRD, CCA, CGY, ECC, EFH, ETC, GAF, HAL, ICI, MZC, STP, SVC, TCH. ETC. APC, ARC, BOE, BRD, CCA, CCC, CLD, CRT, ECC, EFH, ETC, GAF, GDC, HAL, HCL, HDG, MRT, MRV, MZC, SHX, STP, SVC, TCH, WTC. ICI. BRD, ETC, HCL, ICI, SHX. TCH. ETC, SOS, TCH. ECC, S. APC, ARC, BRD, CCC, CPC, CRT, CYL, DEX, EFH, ETC, GAF, GDC, HCL, HDG, HRT, ICI, MZC, OC, SLC, SOS, STP, SVC, TCH, VND.

12-31

12-31

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics'

Manufacturers' identification codes (according to list in table 38)

Nonionic—Continued Carboxylic acid esters—Continued Polyethylene glycol esters—Continued Polyethylene glycol esters of chemically-defined acids—Continued Polyethylene glycol sesquinoleate Polyethylene glycol terephthalate All other polyethylene glycol esters of chemicallydefined acids Polyethylene glycol esters of mixed acids: Polyethylene glycol diester of coconut oil and oleic acids Polyethylene glycol diester of mixed linear acid/ oleic acid Polyethylene glycol diester of tall oil acids Polyethylene glycol ester of mixed fatty acids Polyethylene glycol monoester of coconut oil acids Polyethylene glycol monoester of soybean oil acids Polyethylene glycol monoester of tall oil acids Polyethylene glycol sesqulester of coconut oil acids Polyethylene glycol sesqulester of tall oil acids Polyethylene glycol sesquiester of tallow acids Polyglycerol esters: Hexaglycerol Mixed oleic, lauric, stearic, and paimitic hexaglycerol esters Polyglycerol decaoleate Polyglycerol distearate Polyglycerol mono-oleate Polyglycerol monostearate All other polyglycerol esters, Propanediol esters: 1,2-Propanedlol dioctanoate/decanoate 1 ,2-Propanediol dipelargonate 1 ,2-Propanedlol di-2-ethylhexanoate 1 ,2-Propanediol monolaurate 1 ,2-Propanedlol mono-oleate 1 ,2-Propanedlol monostearate Other carboxylic acid esters: Benzocaine, propoxylated Caprylic amphopropionate DI-Isobutylene maleate Ethoxylated 1,3-butylene glycol stearate Ethoxylated castor oil, ditridecylmaleate Ethoxylated glycerol mono- and diesters of hydrogenated tallow acids Ethoxylated glycerol and propylene glycol esters of coco fatty acids Ethoxylated nonylphenol esters of coconut oil acids Ethoxylated nonylphenol laurate Ethoxylated 1,2-propanediol monostearate Ethoxylated and propoxylated glycerol mono- and diesters of tallow acids Linoleic acid dimers, alkoxylated Maleic anhydride-dlisobutylene copolymer, sodium salt See footnotes at end of table.

12 32 -

No No

ETC, SOS, TCH. BOE, PCI.

No

BAS.

No

EFH.

No Yes No

PCI. CCC, EFH, ETC, MZC, PAT, QCP. SHX, SOS, ( 2 ).

No

ICI, WM.

No Yes

BRD, ETC. ARC, BKM, ETC, FER, GAF, MZC.

No Yes No

ENJ, LUR, MRT, MZC, PAT. ICI, LUR, QCP, SLM, WTC. PAT, RPC, SHX, TCH.

No

SVC.

No No No Yes No No

SVC. TCH. BRD, MZC. HDG, MZC, WTC. BRD, SVC. BRD.

No No No No No Yes

SVC, WM. WM. WM. SBC. EFH, TCH. BRD, EKT, HAL, MZC, SBC, TCH, WM.

No No No No No

UCC. MOA. RH. HCL UPF.

No

SVC.

No No No No

SVC. MZC. TCC. ICI.

No No

SVC. (2).

No

CPS.

12-32

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics 1

Manufacturers' Identification codes (according to list In table 38)

Nonionic—Continued Carboxylic acid esters—Continued Other carboxylic acid esters—Continued Maleic anhydride, polypropylene glycol copolymer Methylglucoside, ethoxylated Methylgiucoside laurate Methylgiucoside, propoxylated Methylgiucoside sesquistearate Mixed alkyl stearate Mixed di- and triethylene glycol monoesters of tall oil acids Nonylphenol ethoxylate, oieate Pentaerythritol distearate Pentaerythritol stearate Polyalkylene glycol oleate Polycarboxylic acid, alkyiate Polycarboxylic acid, alkylphenoxyalkoxylate Polypropylene glycol dioleate Propylene glycol esters of hydrogenated palm oil All other carboxylic acid esters

No No No No No No

PCI. UCC. HDG. UCC. UCC. SOS.

No No No No No No No No No No

WVA. EFH. ARC, GAF, VAL. SCP. SOS. (2) . (2) .

Ethers: Benzenoid ethers: Dinonylphenol, ethoxylated

Yes

CLD. PG, VND. ARI, CAS, CHP, GAF, HDG, ROB, SYL.

Yes No No No No

CPC, ETC, GAF, HTN MZC, RH, S, TCH. GAF, MON, TMH. (2). SVC. AAC, BAS, GAF, MZC, RH, TMH. (2) .

No No No Yes No

BAS, CPC, ( 2 ). MIL, NLT. RH. ENJ, ETC, GAF, HCL, WTC, ( 2 ). HCL.

No

OMC.

No

PCI.

No

PCI.

No Yes

PCI. ARC, BAS, CPC, ETC, GAF, HCL, HDG, HTN, ICI, JTO, MIL, MOA, MON, MZC, RH, S, SHX, STP, TCH, TMH, TX, UCC, WTC, (2) , (2) , OMC. GAF, HTN, RH, TMH, (2 ). SOS. WTC, ( 2). SOS. AAC, DUD, GAF, JTO, TCH. GAF. SDW. GAF, HCL, ICI, MIL.

Dodecylphenol, ethoxylated Epichlorohydrin bisphenol A, ethoxylated Furfuryl alcohol, ethoxylated Iso-octylphenol, ethoxylated (Mixed alkyl)phenol, alkoxylated (Mixed alkyl)phenol epichiorohydrin-formaldehyde, alkoxylated (Mixed alkyl)phenol, ethoxylated (Mixed alkyl)phenol, ethoxylated, butyl ether (Mixed alkyl)phenol-formaldehyde, alkoxylated (Mixed alkyl)phenol-formaldehyde, methoxylated (Mixed alkyl)phenoxypoly(ethyleneoxy)ethyl chloride Naphthalenesulfonic acid, polymer with formaldehyde and 4,4'-dihydroxydiphenyi sulfone Naphthalenesulfonic acid, polymer with formaldehyde and 4,4'-dihydroxydiphenyl sulfone, ammonium salt Naphthalenesulfonic acid, polymer with formaldehyde, sodium salt Nonylphenol, ethoxylated

Nonylphenol, ethoxylated, phosphate esters Nonylphenol, ethoxylated and propoxylated Nonylphenol, ethoxylated with mixed fatty acids Nonylphenol-formaidehyde, alkoxylated Nonylphenol oieate, ethoxylated n-Octylphenol, ethoxylated Octylphenol, ethoxylated and benzylated tert-Octylphenol-formaldehyde, ethoxylated Phenol, ethoxylated

No Yes No No No No No No No

See footnotes at end of table.

12-33

12-33

Section 12 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

No No No No No No

PSP. RH. HCL. SCP. CPC. BAS, GAF, ( 2 ).

Nonionic—Continued Ethers—Continued Benzenoid ethers—Continued Phenol-formaldehyde resin (with lignite) Phenol, propoxylated Phenylstyrene, ethoxylated Soya sterols, ethoxylated Tridecylphenol, ethoxylated All other benzenold ethers Nonbenzenoid ethers: Chemically-defined linear alcohols, alkoxylated: 2-Butanol, ethoxylated and propoxylated Butyl alcohol, propoxylated Decyl alcohol, ethoxylated

No No Yes

Decyl alcohol, ethoxylated and propoxylated Decyloxypoly(ethyleneoxy)ethyl chloride Dodecyl alcohol, ethoxylated Glycerol, ethoxylated Hexadecyl alcohol, ethoxylated N-Hexyl alcohol, ethoxylated Isodecyl alcohol, alkoxylated Isostearyl alcohol, ethoxylated Methyl alcohol, alkoxylated Mixed stearic/palmItic alcohol, ethoxylated Myristyl alcohol, propoxylated 9-Octadecenyl alcohol, ethoxylated Octadecyl alcohol, ethoxylated Coleyl alcohol, ethoxylated Pelargonic alcohol, ethoxylated Stearyl alcohol, propoxylated All other chemically defined linear alcohols, alkoxylated Coconut oil alcohol, ethoxylated Decyl and octyl alcohols, ethoxylated Developmental alcohol, ethoxylated Lanolin alcohol, propoxylated Mixed linear alcohols, alkoxylated Mixed linear alcohols, ethoxylated

No No No No No No Yes

Mixed linear alcohols, ethoxylated, benzyl ether Mixed linear alcohols, ethoxylated and propoxylated

No Yes

Mixed linear alkylpoly(ethyleneoxy)ethyl chloride Stearyl alcohol and ethoxylated ceteryl alcohol Tallow alcohol, ethoxylated Wool wax alcohols, ethoxylated All other nonbenzenoid ethers Other ethers and thioethers: Bis-cumylphenyl-oxoethylene titanate Butanediol, ethoxylated 1,3-Butylene glycol, ethoxylated Butynediol, ethoxylated tert-Dodecyl mercaptan, ethoxylated 2-Ethylhexanol, ethoxylated Glycerine, ethoxylated Isodecyl alcohol, ethoxylated

No No Yes No No No No No No No No Yes No Yes No No

(2 ). WTC. BAS, CPC, ENJ, GAF, HCL, ICI, MIL, S, TCH. GAF. GAF. AAC, CPC, ICI, MIL, ( 2 ). SVC. ICI, MZC, TCH. GAF. S, ( 2). SHX. (2) • GAF. WTC. AAC, GAF, ICI, S, TCH. CPC, GAF, HCL, ICI, UCC. CRD, ETC, HCL, HTN, MZC, SHX. GAF. SVC, WTC.

No No Yes No No

BAS, GAF, HDG. BRD, GAF, HCL, MZC, TX. GAF. SHC. UCC WTC, ( 2). AAC, BAS, DUP, ETC, GAF, HCL, HDG, ICI, MIL, RH, S, SHC, TCH, TMH, TNA, TX, UCC, VST, WTC. (2) • BAS, DUP, ETC, GAF, MIL, OMC, S, STP, SVC, TCH, UCC, ( 2 ). GAF. ETC. GAF, HCL, MZC, SHX, TX. CRD. BRD, RH, ( 2 ).

No No No No No No No No

KPI. ETC. HCL. GAF. AAC, GAF. ETC. ( 2 )• ETC.

See footnotes at end of table.

12-34

12 34 -

Synthetic Organic Chemicals, 1987 Table 37—Continued Surface-active agents for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Surface-active agents

Separate statistics

Manufacturers' identification codes (according to list in table 38)

Nonionic—Continued Ethers—Continued Other ethers and thioethers—Continued Isodecyl alcohol, ethoxylated and propoxylated Lignin, ethoxylated Mixed alcohols, ethoxylated Poly(epichlorhydrin) Polyether diols Polyether triols Poly(mixed ethylene, propylene)glycol

No No Yes No No No Yes

ETC. WVA. AAC, MIL, RH, SHX, TCH, UCC, WM, (2) . (2) .

WTC. WTC. AAC, GAF, MIL, S, UCC, WTC, (2) , (2) .

Poly(mixed ethylene/propylene glycol)capped with alkyl oxirone Poly (oxy-1,2-ethanedly1) , a-phenylmethyl-co-hydroxy,, C12 - C15 alkyl ethers Poly (oxy-1,2-ethanediy1) , ot-phenylmethyl-whydroxy, (ethoxylated nonylphenol) alkyl ether Polypropylene glycol, ethoxylated

No

(2) .

No

PCI.

No No

3-Propanonitrate methylphenyl ether Propoxylated corn starch Rosin alcohol, ethoxylated Thiodiglycol, ethoxylated Tridecyl alcohol, ethoxylated

No No No No Yes

No No No No

PCI. BAS, ETC, GAF, HCL, HDG, MZC, TCH, WTC, ( 2 ) . PCI. VAL. MZC. AAC. CPC, DUP, ETC, GAF, HCL, HTN, ICI, MIL, MZC, OMC, S, TCH, TMH, WTC, ( 2 ) . ETC, TX. UCC. BAS, GAF, WTC. GAF, HCL, OMC, RH, TX, ( 2 ) .

No

KPI.

No

PCI.

No No No

RPC. DUP.

Tridecyl alcohol, propoxylated and ethoxylated Trimethylnonyl alcohol, ethoxylated Trimethylolpropane, alkoxylated All other ethers and thioethers Other nonionic surface-active agents: Cumyl phenolate, isopropoxy titanium salt Formaldehyde, dicyandiamide, ethylene sulfate polymers (Mixed alkyl)phenol alkylenediaminealkanolamine formaldehyde Mixed fatty acid-ethoxylated nonylphenol ester Octyl phosphate, ethoxylated Tetra-(2,2-diallyloxymethylene)-1-butoxy titanium, bis-(ditridecyl) phosphite Tetra-isopropoxy titanium (bis-dioctyl) phosphite Tetra-octyloxy titanium (bis-tridecyl) phosphite Tri(castor oil alkyl)phosphate All other nonionic surface-active agents

No No No No No

(2) .

KPI. KPI. KPI. BRD. BRI, CGY, CLU, DUP, GAF, MIL, PG, WM, (2) , (2) .

Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No." The manufacturer did not consent to his identification with the designated product.

2

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

12-35

12-35

Section 12 Table 38 Surface-active agents:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

AAC ACT ACY AMU APO ARC

Alcolac, Inc. Southland Corp., Chemical Div. American Cyanamid Co. American Emulsion Apollo Chemicals Corp. Akzo Chemle America, Armak Chemicals Ardmore Chemical Co. Inc. Atlas Refinery, Inc. Arol Chemical Products Co. Arizona Chemical Co. BASF Corp. Breddo Corp. Buckman Laboratories, Inc. Astor Products, Inc., Blue Arrow Div. Lonza, Inc. Burlington Industries, Inc. Original Bradford Soap Works, Inc. Boehme Filatex, Inc. CasChem, Inc. lnterstab Chemicals, Inc. C.N.C. International, Inc. Catawba-Charlab, Inc. Morton-Thiokol, Inc., Carstab Div. Ciba-Geigy Corp. Chemol Co C. H. Patrick & Co., Inc. Stockhausen, Inc. Colloids, Inc. CL Industries, Inc. Chemithon Corp. Concord Chemicals Co., Inc. Colgate-Palmolive Co. Grant Industries, Inc. CPS Chemical Co., Inc. Croda, Inc. Chemos Corp. Continental Chemical Co. Dan River, Inc., Chemical Products Div. Dexter Chemical Corp. Dow Chemical Co. Dock Resins Corp. E. I. duPont de Nemours & Co., Inc. Chemicals & Pigments Dept. Eastern Color & Chemical Co. E. F. Houghton & Co. Eastman Kodak Co.: Tennessee Eastman Co Div. Emery Chemicals Div. of National Distillers & Chemical Corp. Exxon Chemical Americas Enenco, Inc. Essential Industries, Inc. Ethox Chemicals, Inc. Ferro Corp., Keil Chemical Div. Flambeau Paper Corp. Finetex, Inc. GAF Corp., Chemical Group Gresco, Inc. Calgon Vestal Laboratories, Inc

HAL HCL

ARD ARI ARL ARZ BAS BFP BKM BLA BRD BRI BSW BOE CAS CCA CCC CCL CCW CGY CHL CHP CIN CLD CLU CMT CON CP CPC CPS CRD CRT CTL DAN DEX DOW DRC DUP ECC EFH EK EKT EMR ENJ ENO ESS ETC FER FPC FTX GAF GDC GRL

12-36

HDG HEW HIP HMP HNT HPC HRT HTN HXL HYD ICI JLP JRG JTO KPI LAS LEA LEV LKY LUR MAR MCP MIL MIR MOA MON MRT MRV MZC NCC NES NLT NMC NOC NPR NSC OC OMC PAH PAT PCH PCI PEL PG PIL PLX PNX PSP QCP RAY RBC RH

Name of company C. P. Hall Co. Hoechst Celanese Corp., Sou-Tex Works Hodag Chemical Corp. Hewitt Soap Co., Inc. High Point Chemical Corp. W. R. Grace & Co., Hampshire Chemicals Div. Huntington Laboratories, Inc. Hercules, Inc. Hart Products Corp. Heterene Chemical Co. Hexcel Corp., Hexcel Chemical Products Hydrolabs Inc. ICI Americas, Inc., Chemicals Div. J. L. Prescott Co. Andrew Jergens Co. Jetco Chemicals, Inc. Kenrich Petrochemicals, Inc. Los Angeles Soap Co. Leatex Chemical Co. Lever Brothers Co. Lake States Div. of Rhinelander Paper Co. Laurel Products Corp. Reed Lignin, Inc. Moretex Chemical Products, Inc. Milliken & Co., Milliken Chemical Div. Miranol Chemical Co., Inc. Mona Industries, Inc. Monsanto Co. Morton-Thiokol, Inc., Morton Chemical Co. Div Marlowe-Van Loan Corp. Mazer Chemicals, Inc. Niacet Corp. Ruetgers-Nease Chemical Co. NL Treating Chemicals. National Milling & Chemical Co. Norac Co., Inc., Mathe Div. Safeway Stores, Inc. National Starch & Chemical Corp. Omega Chemicals, Inc. Olin Corp. Parish Chemical Co. PatChem Prochem Piedmont Chemical Industries, Inc. Pelron Corp. Procter & Gamble Co., Procter & Gamble Mfg. Co. Pilot Chemical Co. Desoto, Inc. Murphy-Phoenix Co. Georgia-Pacific Corp., Bellingham Div. Quaker Chemical Corp. ITT Rayonier, Inc. 12-36 Artel Chemical Corp. Rohm & Haas Co.

Synthetic Organic Chemicals, 1987 Table 38 Surface-active agents:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ROB RPC RSA S

Robeco Chemicals, Inc Hi-Tek Polymers, Inc., Lyndal Div. R.S.A. Corp. Sandoz, Inc., ColSherex Chemical Co., Inc. Soluol Chemical Co., Inc. Salem Oil & Grease Co SSC Industries, Inc. Scott Paper Co. Sequa Chemicals, Inc. Stepan Chemical Co. Capital City Products Co., Armstrong Chemical Plant Sylvachem Corp. Sybron Chemicals, Inc. Quantum Chemical Corp., Emery Div. Tennessee Chemical Co. Thompson Hayward Chemical Co. Ethyl Corp. Gillette Co., Chemical Div.

TX UCC UDI UNN UPF USR UTC VAL

Texaco Chemical Co. Union Carbide Corp. Desoto, Inc. United Aniline Co. Jim Walter Resources, Inc., CIC Div. Uniroyal, Inc., Uniroyal Chemical Div. Unitex Chemical Corp. United Merchants & Manufacturers, Inc. Valchem Div. Virkler Co. Van Dyk, Div. of Mallinckrodt, Inc. Vista Chemical Inc. White & Bagley Co. Whittemore-Wright Co., Inc. Inolex Chemical Co. West Point-Pepperell, Inc., Grifftex Chemical Co. Sub. Witco Chemical Corp. Westvaco Corp.

SLC SLM SOS SPA SQA STP SVC SYL TCC TCH TEN TMH TNA TNI

VKR VND VST WBG WHW WM WPG WTC WVA

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

12-37

12-37

12-38

Synthetic Organic Chemicals, 1987

Section 13 Pesticides and Related Products Pesticides and related products include fungicides, herbicides, insecticides, rodenticides, and related products such as plant growth regulators, seed disinfectants, soil conditioners, soil fumigants, and synergists. The data are given in terms of 100 percent active materials; they exclude such materials as diluents, emulsifiers, and wetting agents. U.S. production of pesticides and related products in 1987 amounted to 1,040 million pounds, 12 percent less than the 1,180 million pounds reported for 1986 (table 39). Sales in 1987 were 911 million pounds, a decline of 3 percent, as compared with 940 million pounds reported in 1986; the value of sales was $4,171 million in 1987, compared with $4,234 million in 1986—a decline of 2 percent. Data for production of pesticides and related products during 1983-87 are shown in figure 14.

The output of cyclic pesticides and related products amounted to 647 million pounds in 1987, 25 percent less than the 862 million pounds produced in 1986. Sales in 1987 were 593 million pounds, valued at $2,828 million, compared with 692 million pounds, valued at $2,964 million, in 1986. Production of acyclic pesticides and related products in 1987 amounted to 392 million pounds, compared with 318 million pounds reported for 1986. Sales in 1986 were 318 million pounds, compared with 248 million pounds reported for 1986; the value of sales were $1,342 million in 1987, compared with $1,270 million in 1986. Table 40 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 41.

Stephen Wanser 202-252-1363

Figure 14 Pesticides and related products: U.S. production, 1983-87

Billions of pounds 2

1983

1984

1985

1986

1987

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

13-1

Section 13 Table 39 Pesticides and related products: U.S. production and sales, 1987

Pesticides and related products

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

1,039,537

910,595

4,170,583

$4.58

Total

647,516

592,839

2,828,226

4.77

Fungicides, total

83,405

73,558

262,063

3.56

Naphthenic acid, copper salt All other cyclic fungicides 2 Herbicides and plant growth regulators, total

3,684 79,721

1 ,814 71,744

1,748 260,315

.96 3.63

449,639

417,898

1,837,179

4.40

3' ,4'-Dichloropropionanilide (Propanil) All other cyclic herbicides', Insecticides and rodenticides, total

14,266 435,373 114,472

( 3) 417,898 101,383

(3 ) 1,837,179 728,984

(3) 4.40 7.19

8,061 49,102

5,132 46,013

35,827 281,188

6.98 6.11

57,309

50,238

411,969

8.20

392,021

317,756

1,342,357

4.22

Fungicides? Herbicides and plant growth regulators 5

21,205 106,417

19,807 101,455

43,923 690,700

2.22 6.81

Insecticides, rodenticides, soli conditioners, and fumigants, total

264,399

196,494

607,734

3.09

85,975 17,603

47,384 9,265

257,261 7,748

5.43 .84

160,821

139,845

342,725

2.45

Grand total Cyclic

Chlorinated insecticides Organophosphorus insecticides 5 All other cyclic insecticides and rodenticides 5 Acyclic Total

Organophosphorus insecticides 5 Trichloronitromethane (chloropicrin) All other acyclic insecticides, rodenticides, soil conditioners, and fumigants 15

Calculated from unrounded figures. Includes benomyl, captafol, captan, chiorothalonil, DMTT, folpet, pipron, PMA, and others. 3 Reported data were accepted in confidence and may not be published, or no data were reported. 4 Includes alachlor, atrazine, benefin, bensulide, 2,4-D and other 2,4-D esters and salts, dicamba, dinitrophenol compounds, diuron, DNBP, Isopropyl phenylcarbamates (IPC and CIPC), maleic hydrazide, molinate, NPA, picloram, triazines, trifluralin, uracils, plant growth regulators, and others. 5 includes diazinon, methyl parathion, and other phosphorothioates and phosphorodithioates. • Includes carbaryl, chlorinated insecticides (chlordan, heptachlor, and others), insect attractants, DEET and other insect repellents, small amounts of rodenticides, and others. 7 Includes dithiocarbamates. • Includes butylate, dalapon, EPTC, methanearsonic acid salts, thiocarbamates, and organophosphorus herbicides, and others. • Includes acephate, disulfoton, ethion, malathion, phorate, and other organophosphorus Insecticides. 10 includes aldicarb, methomyl, methyl bromide, soil conditioners and fumigants, small quantities of rodenticides, and others. Note.-Does not include data for the insect fumigant, p-dichlorobenzene, nor the fungicide, o-phenyiphenol. These data are Included in the section on "Cyclic intermediates." it also does not include data for the fungicides, dimethyldithiocarbamic acid, sodium salt and dimethyldithiocarbamic acid, zinc salt (i.e., ziram). These data are included in the section on "Rubber-Processing Chemicals." The data for ethylene dibromide, a fumigant, are included in the "Miscellaneous End-Use Chemicals and Chemical Products" section. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 2

13-2

Synthetic Organic Chemicals, 1987 Table 40 Pesticides and related products for which U.S. production and/or sales were reported, Identified by manufacturer, 1987

Pesticides and related products

Separate statistics

Manufacturers' identification codes (according to list in table 41)

Cyclic

Fungicides: 2-Bromo-4'-hydroxyacetophenone 1- (4-Chlorophenoxy) -3, 3-dimethy1-1 - (1, 2 , 4-triazol-1 y1)-butan-2-one a-(2-Chloropheny1)-a-(4-chlorophenyl)-5pyrimidinemethanol a-(2-Chloropheny1)-a -(4-fluoropheny1)-5pyrimidinemethanol 2 , 4-Dichloro-6- (o-chloroanilino) -s-triazine 1,4-Dichloro-2,5-dimethoxybenzene (Chloroneb) Diphenylmercuricdocecenyl succinate Hexahydro-1 ,3 ,5-triethyl-s-triazine Hexahydro-1 , 3 , 5-tri (2-hydroxyethyl) -s-triazine 2-Mercaptobenzothiazole, sodium salt Methyl-1-(butylcarbamoy1)-2-benzimidazolecarbamate (Benomyl) 2 , 2' -Methylenebis (4-chlorophenol) (Dichlorophene) 3-(2-Methylpiperldino)propyl-3,4-dichlorobenzoate (Pipron) Naphthenic acid,copper salt 2-n-Octy1-4-isothiazolin-3-one Pentachlorophenol, sodium salt Phenylmercuric acetate (PMA) Phenylmercuric ammonium acetate Phenylmercuric oleate 8-Quinolinol, copper salt 8-Quinolinol, sulfate salt 2 , 4 , 5 , 6-Tetrachloroisophthalonitrile Tetrahydro-3, 5-dimethy1-2H-1 , 3, 5-thiadiazine-2-thione (DMTT) 2-(Thiocyanomethylthio)benzothiazole N-Trichloromethylthio-4-cyclohexene-1,2-dicarboximide (Captan) N-Trichloromethylthlophthalimide (Folpet) 1, 3 ,5-Tri (2-isopropanol) -s-triazine All other cyclic fungicides Herbicides and plant growth regulators: 3-Amino-2,5-dichlorobenzoic acid, ammonium salt (2,5-Dichloro-3-aminobenzoic acid, ammonium salt) 4-Amino-6-(1 , 1 -dimethylethyl) -3- (methylthio)-1 , 2 ,4triazin-5-(4H)-one 4-Amino-3,5,6-trichloropicolinic acid (Picloram) 2 ,4-Bis (isopropylamino) -6- (methylthio) -s-triazine (Prometryn) 5-Bromo-3-sec-butyl-6-methyluracil (Bromacil) 3-tert-Butyl-5-chloro-6-methyluracil N-Butyl-N-ethyl-a , a , a-trifluoro-2 , 6-dinitro-ptoluidine (Benefin) 2-Chloro-4,6-bis(ethylamino)-s-trlazine (Simazine) 2-Chloro-4, 6-bis (isopropylamino)-s-triazine (Propazine) 2 -Chi oro-2 ' , 6' -diethyl-N- ( n-b utoxymethyl) acetanilide (Butachlor) 2-Chloro-2 ' , 6' -diethyl-N- (methoxymethyl) acetanilide (Alachlor) 2-Chloro-N-ethoxymethyl-N- (2-ethyl-6-methylphenyl) acetamide (Acctochlor)

Yes No

BKM.

No

CHG.

No

LIL.

No No No No No No No

LIL. CHG. CHF. TRO. VNC. (2). NOD, ( 2 ).

No No

DUP, GTL. GIV.

No Yes No No No No No No No No

LIL, USR. CCA, MCI, NOD, TRO. FER, RH. FRO. COS. COS, TRO. COS, TRO. NOD, SOM. SOM. SDS, SOC.

No No

BKM, MRK, VCC. BKM.

No No No No

ICI, VNC. ICI. EFH. NOD.

No

RDA.

No No

CHG, DUP. DOW.

No No No

CGY. DUP. DUP.

No No

LIL, ( 2). CGY.

No

CGY.

No

MNA.

No

MNA.

No

MNA.

See footnotes at end of table.

13-3

Section 13 Table 40—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Pesticides and related products

Separate statistics 1

Manufacturers' identification codes (according to list in table 41)

Cyclic—Continued

Herbicides and plant growth regulators—Continued 2-Chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene (Oxyfluorfen) 2-Chloro-4- (ethylamino) -6- (isopropylamino) -striazine (Atrazine) 2- [4-Chloro-6-(ethylamino)-2-triazin-2-ylamino]-2methylpropionitrile(cyanazine) 2-Chloro-N-isopropylacetanilide (Propachior) 2-Chloro-N- [ (4-methoxy-6-methyl-1 ,3, 5-triazin-2-y1)aminocarbonyi]benzenesulfonamide 2-(4-Chloro-2-methylphenoxy)propionlc acid, dimethylamine salt 2-(2-Chlorophenyl)methy1-4,4-dimethyl-3Isoxazolinone 3-Cyclohexy1-6-(dimethylamino) -1 -methyl-1 ,3 ,5trlazine-2 ,4- (1 H , 3H ) -done 3,5-Dibromo-4-hydroxybenzonitrile (Bromoxynil) 3,6-Dichloro-2-anisic acid (Dicamba) 2,6-Dichlorobenzonitrile 2-(2,4-Dichlorophenoxy)proplonic acid dimethylamine salt 2-(2,4-Dichlorophenoxy)propionlc acid, isooctyl ester 3-(3,4-DIchloropheny1)-1,1-dimethylurea (Diuron) 3- (3 ,4-DIchlorophenyl ) -1 -methoxy-1 -methylurea (Linuron) 1- [- (2 ,4-Dichlorophenyl)4-propyl-1 , 3-dioxolan-2ylmethy1]-1H-1,2,4-triazole 3' ,4'-Dichloropropionanilide (Propanil) S-(0,0-Dlisopropyl phosphorodithioate) ester of N(a-mercaptoethyl)benzenesulfonamide (Bensulide) 1,1'-Dimethy1-4,4'-bipyrldinium dichloride N,N-Dimethy1-2,2-diphenylacetamide (Diphenamid) Dimethy1-2,3,5,6-tetrachloroterephthalate (DCPA) N-(1,1-Dimethy1-2-propyny1)-3,5-dlchlorobenzamide (Pronamide) Dimethy1-2 , 3 ,5 ,6-tetrachloroterephthalate (DCPA) N- [5-1 , 1 -Dimethyl) -1 ,3,4-thiadiazol-2-yi] -N , Ndimethylurea (Tebuthiuron) Dinitrobutylphenol (DNBP) Dinitrobutylphenol, triethanolamine salt 2,6-Dinitro-N,N-dipropyl cumidine 3,5-Dinitro-N4,N4-dipropylsulfanilamide 2- (Ethylamino) -4- (isopropylamino) -6- (methylthlo) -striazine (Ametryne) S-Ethyl cyclohexylethylthiocarbamate S-Ethyl-hexahydro-1H-azepine-1-carbothloate (Molinate) N- [3- (1 -Ethy1-1-methylpropy1)-5-isoxazolyl] -2 , 6dimethoxybenzamide (Flexidor) N-(1-Ethylpropy1)-3,4-dimethy1-2,6dinitrobenzenamine 3-Isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one 2,2dioxide Isopropyl N-(3-chlorophenyl)carbamate (CIPC) Isopropyl N-phenylcarbamate (IPC) 2-(2-Methyl-4-chlorophenoxy)propionic acid, diethanolamine salt 2-(2-Methyl-4-chlorophenoxy)propionic acid, isooctyl ester 1-(2-Methylcyclohexyl)-3-phenylurea (Siduron) Methyl 5-(2' ,4'-dIchlorophenoxy)-2-nitrobenzoate See footnotes at end of table.

13-4

No

RH.

No

CGY, DUP.

No No

DUP. MNA.

No

DUP.

No No

DAZ, FMN.

No No No No

DUP. RDA. ZOC. USR.

No No No

RIV. RIV. DUP.

No

DUP.

No Yes

ICI. CED, CYT, RH.

No No No No

ICI. (2). CWN. SDS.

No No

RH. SDS.

No No No No No

LIL. CED. CED. LIL. (2) , (2) .

No No

CGY. ICI.

No

ICI.

No

LIL.

No

ACY.

No No No

BAS. PPG. PPG.

No

RIV.

No No No

RIV. ADC, DUP. RDA.

Synthetic Organic Chemicals, 1987 Table 40—Continued Pesticides and related products for which U.S. production and/or sales were reported, Identified by manufacturer, 1987

Pesticides and related products

Separate statistics

Manufacturers' identification codes (according to list in table 41)

Cyclic—Continued

Herbicides and plant growth regulators—Continued: Methyl 2- [[[[ (4, 6-dimethyl-2-pyrimidinyl) amino] carbonyl] amino] sulfonyll benzoate 1-Methyl-3-phenyl-5-[3-(trifluoromethyl)phenyl] 4(1H)-pyridone (Fluridone) N-1-Naphthylphthalamic acid (NPA) 7-Oxablcyclo-[2.2.1]-heptane-2,3-dicarboxylic acid, disodium salt (Endothall) Phenoxyacetic acid derivatives: 4-Chloro-2-methylphenoxyacetic acid, dimethylamine salt 4-Chloro-2-methylphenoxyacetic acid, isooctyl ester 2,4-Dichlorophenoxyacetic acid, esters and salts: 2,4-Dichlorophenoxyacetic acid, dimethylamine salt 2,4-Dichlorophenoxyacetic acid, isopropyl ester All other 2,4-dichlorophenoxyacetic acid, esters and salts Phenoxyacetic acid derivatives, all other Plant growth regulators: N-[(Acetylamino)methy1]-2-chloro-N-(2,6diethylphenyl)acetamide 2-Chloro-N-(2 ,6-dinitro-4-(trifluoromethyl) phenyl) N-ethyl-6-fluorobenzenemethanamine

No

DUP.

No No

LIL. USR.

No

PAS.

No

RIV.

No

RIV.

No No

PBI, RIV. AMV.

No No

RDA. RDA.

No

MNA.

No

CGY.

No No

(2). DOW.

No

LIL.

No No

DRX, USR. BAS.

No No

MMM. ABB.

No

RH.

No

LIL.

No No

LIL. FRI, SOC, ZOC, ( 2 ).

(3-(4-Chlorophenyl)methyl-a-(1,1-dimethylethyl)-1,2,

4-triazole-1-ethanol 2-Chloro-6- (trichloromethyl) pyridine a-Cyclopropyl-a-(p-methoxypheny1)-5-pyrimidine methanol (Ancymidol) 1,2-Dihydro-3,6-pyrIdazinedione (Malefic hydrazide) (MH) 1,1-Dimethylpiperldinium chloride N-[2,4-dimethy1-5-[[trifluoromethyl]sulfonyl]amino]phenyl]acetamide, diethanolamine salt Gibberellic acid Sodium 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2nitrobenzoate a, a, a-Trifluoro-2 , 6-dinitro-N , N-dipropyl-ptoluidine (Trifluralin) a ,a, a-Trifluoro-2,6-dinitro-N-ethyl-N-(2-methy1-2propenyI)-p-toluidine (Ethylfluralin) All other cyclic herbicides Insect attractants and repellents: N,N-Diethyltoluamide (DEET) Insecticides: Bacillus thuringlensis Bis(pentachloro-2,4-dicyclopentadien-1-y1) 2,3,4,5-62-Butenylene-tetrahydrofurfural 2-(p-tert-Butylphenoxy)cyclohexyl-2-propynyl sulfite Cyan° (4-fluoro-3-phenoxyphenyl) methyl-3- (2 ,2-dIchloroethenyl)-2,2-dimethylcyclopropanecarboxylate Cyano-3-phenoxybenzyl-cis, trans-3-(2,2-dichloroviny1)2,2-dimethylcyclopropane carboxylate Cyano(3-phenoxyphenyl)methy1-4-chloro-a-(1-methylethyl)benzeneacetate Cypermethrin 0,0-Diethyl 0-(2-diethylamino-6-methy1-4-pyrimidinyl) phosphorothioate

No

HCL, MRF, TNA.

No No No No

ABB, ZOC. HK. PLC. ACY, USR.

No

FMN, ( 2 ).

No

(2) .

No No

DUP. CED, FMN.

No

(2).

See footnotes at end of table.

13-5

Section 13 Table 40—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Pesticides and related products

Separate statistics

Manufacturers' identification codes (according to list in table 41)

Cyclic—Continued

Insecticides—Continued 2 ,3-Dihydro-2 ,2-dimethy1-7-benzofuranyl [ (dibutylamino) thio]methylcarbamate 2,3-Dihydro-2,2-dimethy1-7-benzofuranyl methylcarbamate 2 ,3-Dihydroxy-2 ,2-dimethy1-7-benzofuranyl 2,2-Dimethy1-1,3-benzodioxol-4-y1 N-methylcarbamate Di-n-propylisocinchomeronate Distinnaxane, hexakis(2-methyl-2-phenylpropyl) Methyl 3- (2 , 2-dichloroethenyl) -2 ,2-dimethy1-3-cyano3-phenoxyphenylcyclopropanecarboxylate 1-Naphthyl-N-methylcarbamate (Carbaryl) 3-(Phenoxyphenyl)methyl-cis, trans-3-(2,2dichloroetheny1)-2,2-dimethyl cyclopropanecarboxylate Tetrahydro-5,5-dimethy1-2 (1 H ) -pyrimidinone [3[4-(trifluoromethyl)pheny1]-1- [2- [4- (trifluoromethyl) phenyl] ethenyl] -2-propenylidenel hydrozone Tricyclohexyltin hydroxide Chlorinated insecticides: 2-Chloro-N- [ [ [4- (trifluoromethoxy) phenyl] amino] carbonylibenzamide Ethyl 4,4'-dichlorobenzilate (Chlorobenzilate) Heptachloro-tetrahydro-endo-methanoindene (Heptachlor) Octachlorohexahydro-4 , 7-methanoindene (Chlordan) 1 , 1 , 1 -Trichloro-2 , 2-bis ( p-methoxyphenyl) ethane (Methoxychlor) All other chlorinated insecticides, cyclic Organophosphorus insecticides: 0-(2,4-Dichlorophenyi) 0-ethyl S-propylphosphorodithioate 2-(Diethoxyphosphinylimlno)-4-methyl-1,3dithiolane 0-(2-(Diethylamino)-6-methyl (4-pyrimidiny1)0,0dimethyl phosphrothioate 0,0-Diethyl 0-(2-isopropy1-4-methyl-6-pyrimidiny1)phosphorothioate (Diazinon) 0,0-Diethyl 0-[4-(methylsulfinyl)pheny1]phosphorothioate 0, 0-Diethyl 0-(p-nitrophenyl)phosphorothloate (Parathion) 0,0-Diethyl 0-3,5,6-trichloro-2-pyridylphosphorothioate 0,0-Dimethyl 0- [4-(methylthio)-m-toly11phosphorothioate (Fenthion) 0, 0-Dimethyl 0-(p-nitrophenyl)phosphorothioate (Methyl parathion) 0,0-Dimethyl S-[(4-oxo-1,2,3-benzotriazin-3(3H)yl)methyl]phosphorodithloate (Azinphos-methyl) 0-Ethyl 0-[4-(methylthio)phenyl] S-propylphosphorodithioate 0-Ethyl 0-(p-nitrophenyl)phenylphosphonothioate (EPN) N- (Mercaptomethyl) phthalimide S-(0,0-dimethylphosphorodithloate) 0,0' -(Thiod1-4,1-phenylene)bis(0,0-dimethyl phosphorothioate (Temphos) All other cyclic insecticides See footnotes at end of table.

13-6

No

FMN.

No No

FMN. DAZ.

No No No

FSN. MGK. DUP.

No No

FMN. RDA.

No

CED, FMN, ( 2).

No No

ACY, ( 2 ). DOW, ( 2 ), ( 2).

No No

CHG. CGY.

No

VEL.

No

VEL.

No No

CHF. DUP.

No

CHG.

No

ACY.

No

(2).

No

CGY.

No

CHG.

No

MNA.

No

DOW.

No

CHG.

No

DUP, MNA.

No

CHG, DUP.

No

CHG.

No

DUP.

No

ICI.

No Yes

ICI. FMN, RDA, ZOC, ( 2 ), ( 2 ).

Synthetic Organic Chemicals, 1987 Table 40—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Pesticides and related products

Separate statistics

Manufacturers' Identification codes (according to list in table 41)

Cyclic—Continued

Rodenticides: 3- (a-Acetonylbenzyl) -4-hydroxycoumarin (Warfarin) 3- [3- (4 ' -Bromo [1 , 1 ' -biphenyl] -4-y1) -1, 2 ,3 ,4-tetrahydro-1 -naphthalenyl] -4-hydroxy-2 H-1 benzopyran-2-one 2-Diphenylacety1-1,3-indandione and sodium salt 2-isovaleryl-1 ,3-indandione 2-Pivaloy1-1,3-indandione (Pindone) All other rodenticides, cyclic All other cyclic pesticides: Benzy1-2-chloro-4-(trifluoromethyl)-5-thlazolecarboxylate a- [2- (2-n-Butoxyethoxy ) ethoxy] -4, 5-methylenedioxy-2-propyltoluene (Piperonyl butoxide) N- (2-Ethylhexyl) bicyclo (2 .2 .1 ) -5-heptene-2 , 3dicarboximide 1-Methyl-3, 5, 7-triaza-1 -triaza-1 -azonia trIcyclodecane chloride

No

MOT.

No No No No No

LIL, ( 2). MOT. MOT. MOT. RBC.

No

MNA.

No

ALP, TNA.

No

MGK.

No

BKM.

No No No No No No No No

VIN. (2). TRO. MRK. BKM. ACY. MRK. MRK, VIN.

No No

BKM. (2).

No

ALC, BKM.

No

ALC, VCC.

No

DUP.

No No

RH. DUP.

No No

BKM. BKM.

No No No No No

DOW. VIN. ICI, PPG. ICI, PPG. VIN.

No No No No No No No No

VIN. SDS, VIN. BKM. MNA. ICI. ICI. BKM. CHG.

Acyclic Fungicides: Bis-1 ,4-bromoacetoxy-2-butene Bis(tributyltin) oxide Chloromethoxypropylmercuric acetate 1,2-Dibromo-2,4-dicyanobutane Disodium cyanodithiolmidocarbonate n-Dodecylguanidine acetate (Dodine) Dodecylguanidine hydrochloride Methylenebis (thiocyanate) Poly [oxyethylene (dimethylimino) ethylene(dimethylimino)ethylene dichloride] Tributyltin chloride Dithiocarbamic acid fungicides: Dimethyldithiocarbamic acid, potassium salt Ethylene bis(dithlocarbamic acid), disodium salt (Nabam) Ethylene bis(dIthiocarbamic acid), manganese salt with zinc Ions Ethylene bis(dithlocarbamic acid), zinc and manganese salts Ethylene bis(dithicarbamic acid), zinc salt (Zineb) Hydroxymethyl(methyl)dithlocarbamic acid, potassium salt N-Methyldithiocarbamic acid, potassium salt Herbicides and plant growth regulators: 2,2-Dichloropropionic acid, sodium salt (Dalapon) Dimethylarsinic acid (Cacodylic acid) S-Ethyl diisobutylthiocarbamate (Butylate) S-Ethyl dipropylthlocarbamate (EPTC) Methanearsonic acid, disodium salt (DSMA) Methanearsonic acid, dodecyl- and octylammonium salts Methanearsonic acid, monosodium salt (MSMA) Methylthiosulfonic acid, S-(2-hydroxypropyl) ester N-(Phosphonomethyl)glycine, isopropylamine salt S-Propyl butylethyithiocarbamate (Pebulate) S-Propyl dipropylthlocarbamate (Vernolate) Thiocyanic acid, methylene ester S,S,S-Tributyl phosphorotrithioate See footnotes at end of table.

13-7

Section 13 Table 40—Continued Pesticides and related products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Pesticides and related products

Separate statistics 1

Manufacturers' identification codes (according to list in table 41)

Acyclic—Continued

Herbicides and plant growth regulators—Continued Tributyl phosphorotrithioite (Merphos) S- ( 1 , 2 , 3-Trichloroallyl) diisopropylthiocarbamate (Triallate) Plant growth regulators: 6-Benzyladenine (BAP) 2-(Chloroethyl)phosphonic acid N-(Phosphonomethyl)glycine, sodium sesqui salt All other acyclic herbicides Insecticides: Ethyl 3,7,11-trimethyidodeca-2,4-dienoate Isopropyl-11 -methoxy-3 , 7 ,11-trimethyldodeca-2 , 4 dienoate Methyl N' ,N'-dimethyl-N-(methylcarbamoyl)oxy-1thiooxamidate S-Methyl-N- (methylcarbamoyl) oxythloacetimidate (Methomyl) 2-Methyl-2-(methylthlo)proplonaldehyde 0(methylcarbamoyl)oxime (Aldicarb) Organophosphorus insecticides: S-1, 2-Bis ( ethoxycarbonyl) ethyl 0 ,0-dimethyl phosphorodithioate (Malathion) 2-Carbomethoxy-1-propen-2-yl dimethyl phosphate 1,2-Dibromo-2,2-dichloroethyl dimethyl phosphate (Naled) O,O-Diethyl S- [2- (ethylthio) ethyl] phosphorodithioate (Disulfoton) 0 , 0-Diethyl S- [ ( ethylthlo) methyl] phosphorodithioate (Phorate) 0,S-Dimethylacetylphosphoramidothioate (Acephate) O,O-Dimethyl-0-2 ,2 -dichlorovinyl phosphate (DDVP) S- [ [ (1 , 1-Dimethylethyl)thio] methyl] O, 0-diethylphosphorodithioate (Turbufos) Dimethyl phosphate of 3-hydroxy-N-methyl-ciscrotonamide 0,S-Dimethyl phosphoramidothioate 0,0,0' ,0'-Tetraethyl S,S'-methylene-bisphosphorodithloate (Ethion) Rodenticides: 2-Hydroxyethyl n-octyl sulfide Sodium fluoroacetate All other rodenticides, acyclic Soil conditioners: Polyacrylonitrile, hydrolyzed, sodium salt Soil fumigants: 1,2-Dibromo-3-chloropropane (DBCP) 0-Ethyl S,S-dipropyl phosphorodithioate Methyl bromide (Bromomethane) N-Methyldithiocarbamic acid, sodium salt (Metham) Methyl isothlocyanate and 1,3-dichloropropene Trichloronitromethane (Chloropicrin) See footnotes at end of table.

13-8

No

RDA.

No

MNA.

No No No No

ABB. RDA. MNA. DUP VIN.

No

DOW, ZOC, ( 2).

No

(2).

No

DUP.

No

DUP, RDA.

No

RDA.

No No

ACY. AMV, DUP.

No

AMV.

No

CHG.

No

ACY.

No

SOC.

No

AMV.

No

ACY.

No No

DUP. CHG.

No

FMN.

No No No

PLC. RBC, TUL. RBC.

No

ACY.

No No No No No Yes

DOW. RDA. GTL. BKM, ICI. MRT. LCP, NLO, TNA.

Synthetic Organic Chemicals, 1987 Table 40—Continued Pesticides and related products for which U.S. production and/or sales were reported, Identified by manufacturer, 1987

Pesticides and related products

Separate statistics

Manufacturers' identification codes (according to list in table 41)

Acyclic—Continued All other acyclic pesticides: 3-Alkoxy-2-hydroxypropyl trimethyl ammonium chloride Ammonium oxydiethylenebis (alkyl dimethyl chloride) Alkyl-40% C12, 50% C14, 10% C15 Bromoacetic acid N-Cocoalky1-1,3-propylenediamine acetate 2- [(Hydroxymethyl)amino]-2-methylpropanol 2-(Hydroxymethyl)ethanol 3-lodo-2-propynyi butylcarbamate All other pesticides and related products, acyclic

No

(2).

No No No No No No No

BKM. VIN. (2).

TRO. TRO. TRO. CWN, DUP, USR, ZOC,

( 2 ).

1 Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are Indicated by "No." 2 The manufacturer did not consent to his identification with the designated product.

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

13-9

Section 13 Table 41 Pesticides and related products:

Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ABB ACY ADC ALC ALP AMV BAS BKM CCA CED CGY CHF CHG

Abbott Laboratories American Cyanamid Co. Anderson Development Co. Alco Chemical Corp. Alpha Laboratories, Inc. Amvac Chemical Corp. BASF Buckman Laboratories, Inc. Interstab Chemicals, Inc. Cedar Chemical Co. Ciba-Geigy Corp. Kincaid Enterprises, Inc. Mobay Chemical Crop., Agricultural Chemicals Div. Cosan Chemical Corp. Upjohn Co., Fine Chemicals Cumberland International Corp. Diaz Chemical Corp. Dow Chemical Co. Drexel Chemical Co. E. I. duPont de Nemours & Co., Inc. Agricultural Products E. F. Houghton & Co. Ferro Corp., Ferro Chemical Div. FMC Corp., Agricultural Chemical Group Farmland Industries, Inc. Vulcan Materials Co., Chemicals Div. Nor-Am Chemical Co. Givaudan Corp. Great Lakes Chemical Corp. Hoechst Celanese Corp., Virginia Chemicals, Inc. Occidental Chemical Corp., Speciality Chemical Div.

ICI LCP LIL MCI MGK MMM MNA MOT MRF MRK MRT

ICI Americas LCP Chemicals-Maine Eli Lilly & Co. Mooney Chemical, Inc. McLaughlin Gormley King Co. Minnesota Mining & Manufacturing Co. Monsanto Agriculture Co. Motomco, Ltd. Morfiex Chemical Co., Inc. Merck & Co., Inc. Morton-Thiokol, Inc., Morton Chemical Co. Div. Niklor Chemical Co., Inc. Nuodex, Inc. Pennwalt Corp. PBI-Gordon Corp. Phillips Petroleum Co. PPG Industries, Inc. Artel Chemical Corp. Rhone-Poulenc, Inc. Rohm & Haas Co. Riverdale Chemical Co. Fermenta Plant Proctection Chevron Corp., Chevron Chemical Co. Southland Corp. Ethyl Corp. Troy Chemical Corp. Tull Chemical Co., Inc. Uniroyal, Inc., Uniroyal Chemical Div. Vinings Chemical Co. Velsicol Chemical Corp. Vineland Chemical Co., Inc. Vanderbilt Chemical Corp. Sandoz Crop Protection

COS CWN CYT DAZ DOW DRX DUP EFH FER FMN FRI FRO FSN GIV GTL HCL HK

NLO NOD PAS PBI PLC PPG RBC RDA RH RIV SDS SOC SOM TNA TRO TUL USR VCC VEL VIN VNC ZOC

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

13 10 -

Synthetic Organic Chemicals, 1987

Section 14 Miscellaneous End-Use Chemicals and Chemical Products This section incorporates those end-use groups which are not readily classifiable within the prior sections of this report. Both cyclic and acyclic chemicals fall within this section. Production and sales of the end-use chemicals contained within this section continue to follow a general increase since 1983. In 1986, the production of miscellaneous end-use chemicals exceeded 25,223 million pounds, an increase of 9.5 percent from the more than 23,033 million pounds of production reported for 1986. Production of these chemicals remained nearly level but steadily increasing throughout 1983-87 (figure 15). Sales in 1987 totaled 21,010 million pounds, valued at $7,355 million (table 42). The sales quantity

increased 27 percent from that of 1986 with the value of sales decreasing by 16 percent. Polymers for fibers and urea collectively accounted for 72 percent of the 1987 production of these miscellaneous end-use chemicals. Urea accounted for 55 percent of the 1987 sales quantity of these chemicals. Production of end-use chemicals used in the auto and motor fuels market indicated continued upward trends. In 1987, the production of lubricating oil and grease additives totaled 724 million pounds, an increase of 11 percent, compared with 1986. Production of fuel additives for 1987 totaled 3,878 million pounds, an increase of 6 percent from the previous year. Table 43 lists the products reported in this section and indicates the manufacturer(s) of each by code. These codes are identified by company name in table 44.

David G. Michels 202-252-1352

Figure 15 Miscellaneous End-Use Chemicals and Chemical Products: U.S. production, 1983-87

Millions of pounds

30

25

20

15

10

5

0 1983

1984

1985

1986

1987

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

14-1

Section 14 Table 42 Miscellaneous end-use chemicals and chemical products: U.S. production and sales, 1987

Miscellaneous end-use chemicals and chemical product

Grand total Amino acids and their salts Chelating agents, nitriloacids and salts, total . (Diethylenetrinitrilo)pentaacetic acid, pentasodium salt (Ethylenedinitrilo)tetraacetic acid, calcium disodium salt (Ethylenedinitrilo)tetracetic acid, diammonium salt (Ethylenedinitrilo)tetraacetic acid, disodium copper salt, dihydrate (Ethylenedinitrilo)tetraacetic acid, disodium salt (Ethylenedinitrilo)tetraacetic acid, monosodium iron salt (Ethylenedinitrilo)tetraacetic acid, tetrasodium salt (N-Hydroxyethylethylenedinitrilo) triacetic acid, trisodium salt Nitrilo-tris-methylene triphosphonic acid All other chelating agents, nitriloacids and salts Chemical indicators Chemical reagents and fine chemicals Enzymes: Bacterial amylase Pectinase Proteases, total Rennin All other proteases Flotation reagents Fuel additives, total3 Methyl-t-butyl ether 4 All other fuel additives Lubricating oil and grease additives, total Oil soluble petroleum sulfonate, calcium salt Nonylphenol, barium salt All other lubricating oil and grease additives Paint driers, naphthenic acid salts, total' 6 Cobalt naphthenate All other paint driers, naphthenic acid salts Photographic chemicals Polymers for fibers, total Nylon 6 and 6/64 Polyacrylonitrile and acrylonitrile copolymers5 Polyethylene terephthalate 7 All other polymers for fibers

See footnotes at end of table.

14-2

. .

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

25,223,101

21,010,441

7,355,123

$0.35

(2)

(2)

162,637 255,336

209,488

127,794

.61

14,513

14,184

8,943

.63

743

647

1,701

2.63

2,657

1,572

949

.60

717

694

777

1.12

1,470

1,531

2,872

1.88

1,834

1,733

2,200

1 .27

82,740

51,604

32,262

.63

11,358

4,201

2,801

.67

2,637

2,758

2,234

.81

136,667 8 1,742

130,564 7 1,681

73,055 459 37,961

.56 64.53 22.58

19,070 1,521 32,247 16,606 15,641

( 2)

(2)

(2)

(2)

(2)

(2)

(2)

(2)

(2)

(2)

(2)

(2)

18,515

(2)

(2)

(2)

3,877,510

(2)

(2)

(2)

3,514,416 363,094

(2)

(2)

(2)

(2)

(2)

(2)

724,110

(2)

(2)

(2)

274,680 8,148

249,849

154,017

.62

(2)

(2)

(2)

441,282

(2)

(2)

(2)

7,731

(2)

(2)

(2)

3,167

2,715

6,846

2.52

4,564

(2)

(2)

(2)

16,027

7,762

47,347

6.10

6,558,683

3,360,072

3,947,881

1.17

2,222,185

1,538,153

2,474,266

1.61

564,122 2,014,931 1,757,445

455,980 1 ,228 ,409 137,530

384,101 999,186 90,328

.84 .81 .66

(2) (2)

(2) (2)

Synthetic Organic Chemicals, 1987 Table 42-Continued Miscellaneous end-use chemicals and chemical products: U.S. production and sales, 1987

Miscellaneous end-use chemicals and chemical product

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

573,047

476,392

545,201

$1.14

Cellulose esters and ethers: Hydroxethylcellulose Sodium carboxymethylcellulose Polyacrylamide Polyacrylic acid salts, total

52,614 47,040 52,219 172,898

56,072 49,485 39,793 130,188

120,172 61,169 44,446 112,874

2.14 1.24 1.12 .87

Sodium ammonium polyacrylate and copolymers All other polyacrylic acid salts All other water soluble polymers Poly-a-olefins Tanning materials synthetic

63,570 109,328 248,276 126,254 35,803

40,576 89,612 200,854 102,072 24,425

23,025 89,849 206,540 89,836 16,268

.57 1.00 1.03 .88 .67

61,780

59,708

34,714

.58

466

549

307

.56

61,314

59,159

34,407

.58

11 ,530 ,120

11,629,565

563,796

.05

321,611 1,939,381 669,875 8,599,253

326,171 1,843,764 762,240 8,697,390

19,043 115,607 36,761 392,385

.06 .06 .05 .05

1,273,798

4,886,705

1,730,165

.32

Polymers, water soluble, total

Textile chemicals, other than surface-active agents, total Urea polymers with formaldehyde and methanol All other textile chemicals, other than surface-active agents Urea in compounds or mixtures, total In feed compounds In liquid fertilizer In plastics In solid fertilizer All other miscellaneous end-use chemicals and chemical productse

Calculated from unrounded figures. Reported data were accepted in confidence an may not be published, or no data were reported. 3 Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given with the section on "Plasticizers." The difference between the production reported here and that shown on the Preliminary Report on U.S. Production of Selected Organic Chemicals (including Synthetic Plastics and Resins Materials, 1987, results from a combination of incorrect reporting by some companies, end-of-year inventory adjustment, and rounding. 5 Quantities are given on the basis of solid naphthenate. 6 Statistics exclude production and sales of copper naphthenate. Statistics for copper naphthenate are given in the section on Pesticides and Related Products." 7 Data for polyethylene terephthalate for fibers was misreported in 1986. The corrected production figure is 1,967,462 thousand pounds. 8 Includes all other items listed in table 43 which are not individually publishable as groups. 2

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

14-3

Section 14 Table 43 Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Miscellaneous end-use chemicals and chemical products Amino acids and their salts:

Aspartic acid N , N-Bis (2 , 2-acetamido) glycine N,N-Dimethylglycine N,N-Dimethylglycine hydrochloride Giutamic acid hydrochloride Glycine (Aminoacetic acid), non-medical Methionine and its salts: Methionine (animal feed grade) Methionine, hydroxy analogue, calcium salt Phenylalanine Potassium glutamate Protein hydrosylates Sarcosine All other amino acids and salts, cyclic Biological stains: Biological stains Chelating agents, nitriloacids and salts N-alkylamine bismethylenephosphonic acid N-alkylaminobismethylene phosphonic acid salts Aminotrimethyl phosphonic acid (Diethylenetriamine)pentamethylenephosphonic acid (Diethylenetriamine)pentamethylenephosphonic acid, sodium salt (Diethylenetrinitrilo)pentaacetic acid (Diethylenetrinitrilo)pentaacetic acid, monosodium hydrogen ferric salt (Diethylenetrinitrilo)pentaacetic acid, pentasodium salt N,N-Dihydroxyethylglycine, sodium salt Ethanoldiglycine, disodium salt (Ethylenedinitrilo)tetraacetic acid (Ethylenediaminetetraacetic acid) (EDTA) (Ethylenedinitrilo)tetraacetic acid, calcium disodium salt (Ethylenedinitrilo)tetraacetic acid, diammonium salt (Ethylenedinitrilo)tetraacetic acid, disodium copper salt, dihydrate (Ethylenedinitrilo)tetraacetic acid, disodium salt (Ethylenedinitrilo)tetraacetic acid, disodium zinc salt, dihydrate (Ethylenedinitrilo)tetraacetic acid, manganese salt (Ethylenedinitrilo)tetraacetic acid, monosodium iron salt (Ethylenedinitrilo)tetraacetic acid, tetraammonium salt (Ethylenedinitrilo)tetraacetic acid, tetrapotassium salt (Ethylenedinitrilo)tetraacetic acid, tetrasodium salt (Ethylenedinitrilo)tetraacetic acid, trisodium salt Glucoheptonic acid, 13-isomer, sodium salt Glucoheptonic acid, sodium salt Hexamethylenediaminetetra(methylenephosphonic acid), potassium salt Hydroxyethane-1-diphosphonic acid (N-Hydroxyethylethylenedinitrilo)triacetic acid, iron salt (N-Hydroxyethylethylenedinitrilo)triacetic acid, trisodium salt

See footnotes at end of table.

14 4 -

Separate statistics

Manufacturers' identification codes (according to list in table 44)

Yes No No No No No No

ESX, PFZ. PIC. MCK. MCK. LEM. CHT, HMP.

No No No No No No No

DGC. MNA. NSW. LEM. BRS. HMP. AJI.

No Yes No No No No

ALD, EK.

No No

MYO, OMC. CGY, HMP.

No

CGY.

Yes No No

CGY, DOW, HMP. HMP. HMP.

No

CGY, HMP.

Yes Yes

CGY, DAN, DOW. COY, DOW, HMP.

Yes Yes

CGY, DOW, HMP, PLC. CGY, DOW, HMP.

No No

CGY, DOW, HMP. DOW, HMP, CGY

No No No Yes No No No

DOW. COY, DOW. HMP, ( 2). CGY, DOW, HMP. CGY, TX. BLZ. BLZ, PFN.

No No

OMC. BKM, MYO.

No

CGY, DOW, HMP.

Yes

CGY, DOW, HMP.

DUP. (2). DOW, SCP. CCL, MYO.

Synthetic Organic Chemicals, 1987 Table 43—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Miscellaneous end-use chemicals and chemical products Chelating agents, nitriloacids and salts—Continued Hydroxyethylidene diphosphonic acid, potassium salt Hydroxyethylidene diphosphonic acid, sodium salt Nitriloacetic acid, zinc salt Nitrilotriacetic acid Nitrilotriacetic acid, trisodium salt Nitrilo-tris-methylene triphosphonic acid Nitrilo-tris-methylene triphosphonic acid, potassium salt Nitrilo-tris-methylene triphosphonic acid, sodium salt 2-Phosphonobutane-1,2,4-tricarboxylic acid, sodium salt Polyamine polymethane phosphonic acid Polyamine polymethane phosphonic acid, magnesium salt All other chelating agents, nitriloacids and salts Chemical Indicators: Chemical indicators Chemical reagents and fine chemicals: Chemical reagents and fine chemicals Enzymes: Hydrolytic enzymes: Amylases: Bacterial amylase Glucoamylase Maltase All other amylases Proteases: Papain Pepsin Protease (bacterial) Rennin All other proteases Other hydrolytic enzymes: Cholesterol esterase Glucose isomerase Hydrolytic enzyme mixtures Lipase Pectinase All other hydrolytic enzymes Non-hydrolytic enzymes: Cholesterol oxidase Glucose oxidase Glucose-6-phosphate dehydrogenase Glycerol kinase Uricase Flotation reagents: Allyl n-butyl trithiocarbonate Phosphorodithioates, used as flotation reagents: Dicresylphosphorodithloic acid Dicresylphosphorodithloic acid, ammonium salt Dicresylphosphorodithloic acid, sodium salt All other phosphorodithloates used as flotation reagents Rosin amines Thiocarbanilide (Diphenyithiourea) Xanthates and sulfides, used as flotation reagents: Sodium n-butylxanthate Xanthates and sulfides All other flotation reagents

Separate statistics

Manufacturers' identification codes (according to list in table 44)

No No No No No Yes

(2). MYO, ( 2). HMP. HMP, MON. HMP. BKM, OMC, MYO, ( 2 ).

No No

(2). MYO, OMC, ( 2 ).

No No

(2). SCP, ( 2 ), ( 2 ).

No No Yes Yes Yes Yes

RPC. BKM, CCL, CGY, HMP, OMC ( 2). ALD, EK, GFS. ABB, ALD, EK, ESA, GFS, HEX, HMY, PAH, PFN, PIC, PLB, REG, RSA, UPJ, UPM, ( 2 ).

No Yes No No No Yes No No No Yes No

GBF, GNR, MLS, NBI, PMP. GBF, MLS, NBI. PFZ, TX. GBF, TX.

No No No No Yes No

BCK. MLS. JFR. CHH, GNR. GBF, GNR, MLS. GNR, MLS, PMP, ( 2).

No No No No No Yes No

BCK, UPJ. BCK. BCK. BCK. BCK. PLC.

No No No

ACY. ACY. KCU.

No No No No No No No

ELC. HPC. ACY.

GBF, PFZ. CHH. PMP. CHH, MLS, PFZ. GBF, GNR, MLS, SPR.

USR. PLC. DOW, PLC, SHX.

See footnotes at end of table.

14-5

Section 14 Table 43—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Miscellaneous end-use chemicals and chemical products

Separate statistics

Fuel additives: Diesel fuel additives: Hexyl nitrate All other diesel fuel additives acyclic All other diesel fuel additives cyclic Fuel oil additives: Adlpic acid-diethylenetriamine-epichlorophydrin polymer N-sec-Butyl-N-phenylphenylenediamine Methyl-t-amyl ether N,N-Dimethy1-1,3-propanediamine polymer with epichlorohydrin, sulfate N,N' -Disalicylidene-1 ,2-propanediamine Formaldehyde polymer with ethylenediamine and nonyl phenol derivatives Imidazoline from tall oil fatty acids and diethylenetriamine Mixed aryl dilmides Phenyl acid phosphate Polybutylether carbamate Poly(dimethylimino(2-hydroxytrimethylene)chloride) Polyethylenepolyamine polymer with 1 ,4-dihyroxy-2butyne Rust preventing additives Tetrahydropyrimidine from tall oil fatty acids and propylenediamine All other fuel oil additives, acyclic All other fuel oil additives, cyclic Gasoline additives: N,N'-Dl-sec-butyl-p-phenylenediamine N,N'-Dlisopropyl-p-phenylenediamine Ethylene dibromide 4,4'-Di-sec-butylamino diphenyl methane Methyl-t-butyl ether Methylcyclopentadienylmanganese tricarbonyl Tetraethyl lead Tetra(methyl-ethyl)lead, (Tel-tml,reacted) Tetramethyl lead All other gasoline additives, acyclic Lubricating oil and grease additives: Chlorosulfurized and sulfurized compounds: Chlorosulfurized sperm oil Sulfurized lard oil Sulfurized sperm oil substitutes Hydrocarbon carboxylic acid derivatives Hydrocarbon phosphorous acid, barium salt Hydrocarbon phosphoryl derivatives Oil-soluble petroleum sulfonates: Oil-soluble petroleum sulfonate, ammonium salt Oil-soluble petroleum sulfonate, barium salt Oil-soluble petroleum sulfonate, calcium salt Oil-soluble petroleum sulfonate, magnesium salt Oil-soluble petroleum sulfonate, sodium salt All other oil-soluble petroleum sulfonates

No No Yes No No No

Phenol salts: Alkyl phenols Dodecylphenol, sulfurized, calcium salt Nonylphenol, barium salt Phenol, salts, all other

No No No Yes No

See footnotes at end of table.

14 6 -

Manufacturers' identification codes (according to list in table 44)

Yes No No No No

DUP, TNA. TNA. PAH.

No No No

(2). UPM. CXI.

No No

(2). DUP, FER, SM, TNA.

No

(2).

No No No No No

(2). SM. HDG. SOC. (2).

No No

(2). ALX.

No No No

(2). DUP, SM, UPM. DUP, PAH.

No No No No Yes No No Yes No No Yes No No No No No No No

DUP, TNA, UPM. DUP, TNA. GTL, TNA. UPM. ATR, ENJ, LYP, TPC, TUS, VLR. TNA, TX. DUP, ( 2 ). DUP. SHC. BRD. ELC. CCW, WBG. CCW, ELC. EMR, QCP, ( 2 ), ( 2 ). (2). (2). NLT. TNA, WTC, ( 2). SOC, TNA, TX, WTC, ( 2). WTC, ( 2). PAR. DAN, DUP, MON, SOC, TNA, WTC. (2). SOC. CCA, FER, WTC. TNA.

Synthetic Organic Chemicals, 1987 Table 43—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Miscellaneous end-use chemicals and chemical products Lubricating oil and grease additives—Continued Phosphorodithioates (Dithiophosphates): Alkene thiophosphonate Alkyl imidazoline Alkyl succinic anhydride Alkyl terephthalamate Bornyl phenylamine DI-2-ethylhexylphosphorodithloic acid DI-N-propylphosphorodithioic acid Zinc dialkyldithlophosphate Zinc diaikylphenol dithiophosphate Zinc dibutyl phosphorodithioate Zinc dilsodecyl phosphorodithioate Zinc hydrocarbon dithiophosphate All other phosphorodithioates used as lubricating oil and grease additives Succinimides: Aikenyl succinimide Dodecenyl-acetic succinimide Sulfur compounds: Aliphatic hydrocarbon sulfides Di-tertiary nonylpolysulfide Triisobutylene polysuifide All other sulfur compounds All other lubricating oil and grease additives: DI-2-ethylhexylphosphorodithloic acid Diisopropyl hydrogen phosphite Dimer acid esters and polyesters Dodecenyl succinic acid, benzotriazole salt Dodecylphenyl-a-naphthylamine Dodecylphenyl-a-naphthylamine, dioctyl diphenylamine co-polymer Fatty acid polyamine condensate Mixed polyesters Pentaerythritol esters 1 ,3 ,4-Thiadiazole , 2 ,5-bis (dIalkyldlthio) derivatives Very high weight ( 1000) hydrocarbons All other lubricating oil and grease additives, acyclic All other lubricating oil and grease additives, cyclic Paint driers, naphthenic acid salts: Barum naphthenate Cadmium naphthenate Calcium naphthenate Chromium naphthenate Cobalt naphthenate Copper naphthenate Iron naphthenate Lead naphthenate Lithium naphthenate Manganese naphthenate Naphthenate driers, mixed salts Rare earths naphthenate Strontium naphthenate Vanadyl naphthenate Zinc naphthenate All other paint dryers, naphthenic acid salts

Separate statistics

No No No No No No No No No No No No No

Manufacturers' Identification codes (according to list in table 44)

TX. QCP. SM, TNA. SOC. SOC. ELC. ELC. ELC, SOC, TNA, ( 2 ). SOC. ELC. ELC. (2).

No No No No No No No No No No No No No No No

TX, ( 2 ).

No No No No

SM. SOC. HCC. HCC.

No No

ELC. (2).

No

DUP, ELC, QCP, SM, TNA, ( 2).

No Yes No No No No Yes No Yes No No No No No No No No No

COY, ENJ, SM, TNA, ( 2 ).

SOC, TNA, TX, ( 2). SM. ELC, FER, ( 2 ). PAS. TX. FER, QCP, TNA ( 2 ). ELC. ALW. EMR. SM. SM.

QCP. CCA, VNC. CCA, MCI, NOD, TRO. MCI. CCA, MCI, NOD, SHP, TRO. NOD. CCA, MCI, NOD. CCA, MCI, NOD, SHP, TRO. CCA. CCA, MCI, NOD, SHP. MCI. CCA, NOD. CCA. SHP. CCA, MCI, NOD, SHP, TRO. SHP, NOP.

See footnotes at end of table.

14-7

Section 14 Table 43—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Miscellaneous end-use chemicals and chemical products Photographic chemicals: N-2-(4-Amino-n-ethyl-m-toluidino)ethyl methane sulfonamide Aryl alkyl polyether alcohol 5-Chlorobenzotriazole 3-Chloro-4-diethylaminobenzenediazonium chloride (p-Diazo-2-chloro-N,N-diethylaniline zinc choride) Chlorohydroquinone 4-Diazo-2 , 5-diethoxymorpholinobenzene 2,5-Diethoxy-4-morpholinobenzenediazonium chloride p-Diethylaminobenzenediazonium chloride (p-Diazo-N,Ndiethylaniline zinc chloride) p-Dimethylaminobenzenediazonium chloride] (p-Diazo-N, N-dimethylaniline zinc chloride) p-Diphenylaminediazonium sulfate p-(N-Ethylbenzimido)benzenediazonium chloride (p-Diazo-N-benzyl-N-ethylaniline)-zinc chloride p- [Ethyl (2-hydroxyethyl) amino] benzenediazonium chloride (p-Diazo-N-hydroxyethylaniline zinc chloride) (N-Ethyl-N- (2-hydroxyethyl) -3-methyldehydrogen sulfate)p-phenylenediamine N-Ethyl-N-hydroxyethyl-p-phenylenediamine sulfate Hydroquinone (Hydroquinol) p-[(2-Hydroxyethyl)methylamino]benzenediazonium chloride (p-Diazo-N-hydroxyethyl-N-methylaniline)zinc chloride 4-Hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidone 2-Hydroxynaphthoic ethylamide 4-Methoxy-1-naphthol p-Methylaminophenol sulfate (Metol) 5-Methyl-1 ,7-dihydroxy-1 ,3,4-triazaindolizine . . . . 4 ,4-Methylidene-bis-1 (p-sulfophenyl) 3-methylpyrazolone 3-methyl-N- [2 (methyl sulfonamido ethyl)-N-ethyl-pphenylenediamine]sesquisulfate monohydrate 4-methyl-1-phenyl-3-pyrazolidenone p-Morphollny1-2,5-dibutoxybenzene diazonium chloride 6-Nitrobenzimidazole 5-Nitrobenzimidazole nitrate 1-Phenyl-3-pyrazolidone Poly (vinyl-O-sulfobenzal) 4-N-(1-Pyrrolidyl)-m-toluenediazonium chloride All other photographic chemicals Polymers for fibers: Cellulose acetate Copolyurethane urea Linear saturated polyester Nylon 6 and 6/6: Nylon 6 (Polymer for fiber, only) Nylon 6/6 Polyacrylonitrile and acrylonitrile copolymers Polyethylene terephthalate Poly-m-phenylene isophthalamide Poly-p-phenylene terephthalamide All other polymers for fibers See footnotes at end of table.

14-8

Separate statistics

Manufacturers' identification codes (according to list in table 44)

Yes No No No

WAY. DIX. FMT.

No No No No

ESA. ESA. ALL. ALL, ESA.

No

ALL, ESA, FMT.

No No

ALL, ESA. ALL.

No

ESA.

No

ALL, ESA.

No No No

(2). WAY. EKT.

No No No No No No

ESA. (2). FMT. (2). EK. FMT.

No

FMT.

No No

(2). CWN.

No No No No No No No

ALL FMT. EK. CWN. DUP. ALL, ESA. ALL, DUP, ESA, FMT, WAY, ( 2 ), (2) .

No No No No Yes No No Yes Yes No No No

CEL, EKT, MIL. DUP. EKT. ACS, SKP, ( 2). DUP, MON, SKP. ACY, BKM, DUP, MON. CEL, DUP, EKT, FRF, GYR. DUP. DUP. HCL, ( 2 ).

Synthetic Organic Chemicals, 1987 Table 43—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1987

Miscellaneous end-use chemicals and chemical products

Separate statistics '

No Polymers, water soluble: No Acrylamide polymers and co-polymers: No Acrylamide-2-acrylamido-2-methylpropanesulfonic No acid, sodium salt polymer No Acrylamide-acrylic acid copolymer No Acrylamide-acrylic acid copolymer potassium salt No Acrylamide-acrylic acid copolymer, sodium salt Acrylamide N-dimethylaminomethylacrylamide No copolymer No Acrylamide-trimethylamino ethyl acrylate chloride Acrylamide-trimethylamino ethyl methacrylate chloride No No Adipic acid-crosslinked polycrylamide Yes Polyacrylamide No All other polyacrylamide copolymers Yes Cellulose esters and ethers: No Cationic cellulosic ether Yes Hydroxyethylcellulose No Methylceliulose Sodium carboxymethylcellulose (100%) Yes All other cellulose ethers and esters No Dimethylamine epichlorohydrin ethylenediamine No copolymer Ethyl acrylate methacrylic acid copolymer No Hydroxypropyl guar gum No Poly(acrylic acid) ethyl ester No Poly(acyclic acid, methyl ester/ethylene/ 1,1dIchlorosucclnlo acid, methylene-) with ethyl acrylate No Polyacrylic acid salts: Yes Ammonium polyacrylate No Polyacrylate methacrylate copolymers No Sodium ammonium polyacrylate and copolymers Yes Sodium polyacrylate No All other polyacrylic acid salts No Polyacrylonitrile, hydrolyzed No Polyacrylonitrile, starch hydrolized polymer No Polyamines No Polydextrose No Poly(diallyldimethylammonium) chloride No Polymethacrylic acid, sodium salt No Poly (1 ,1'- (methylimino) bis (3-chloro-2-propanoi) teramhylndie No Sodium carboxymethyl amylose No Sodium carboxymethyl starch No Vinyl acetate maleic copolymer, sodium salt No 1-Vinyl-2-pyrrolidinone, polymers No Xanthan gum No All other polymers, water soluble No Poly-a-olefins: Poly-a-olefins Poly-a-olefins, sulfurized Rare sugars: I-Arabinose D-Galactose D-Maltose Silicone greases: Silicone greases

Yes No No No No No No No No

Manufacturers' identification codes (according to list in table 44)

ENJ, ( 2). CHP. (2) . BKM, ( 2 ). BKM. (2) . (2) . BKM, ENJ, HCL, ( 2 ). ACY, DOW, ENJ, MRK, SQA, ( 2). HCL, ( 2 ). UCC. AQU, DOW, UCC, ( 2 ). DOW. AQU, CBC, LCS, MAK, ( 2 ). S, ( 2 ). CPS, ( 2 ). ALC. RPC. DUP. DUP. ENJ, RH, ( 2 ), ( 2 ). BFG, RH, ( 2 ). ALC, BAS, BFG, RH, ( 2), ( 2 ). BKM, DOW, ENJ, SYT, ( 2), ( 2). ACY, MYO, S, ( 2 ), ( 2 ). BKM, DIX, RH. GPC. ENJ, ( 2 ). PFZ. CPS, MRK, ALC, CPS. BKM. CCL. (2) • ( 2 ). CCL, DAN, GAF, ( 2 ). PFZ. BKM, EFH, RH, RPC, SYT, ( 2), (2) , (2) . (2) . CO, SM, SOC. SM. PFN. PFN. PFN. DCC, SPD, SWS.

See footnotes at end of table.

14-9

Section 14 Table 43—Continued Miscellaneous end-use chemicals and chemical products for which U.S. production and/or sales were reported, identified by manufacturer, 1987 Miscellaneous end-use chemicals and chemical products Tanning materials, synthetic: 1-naphthalene sulfonic acid, formaldehyde condensate and salt 2-naphthalenesulfonic acid, formaldehyde condensate and salt 1-phenol-2-sulfonic acid, formaldehyde condensate Polyoxyalkylated cyclic amines Tanning materials synthetic, all other Textile chemicals, other than surface-active agents: N , N-bis- (2-Hydroxyethyl) octadecanamide N,N-Dibenzylhydroxylamine Dicyanodiamide formaldehyde ammonium chloride polymer Diethylenetriamine,triethylphosphate, urea polymer, stearate Dimethyloldihydroxyethylene urea Formaldehyde polymer with carbamate esters Hydrogenated tallow fatty acid aminoethylethanolamine condensation products Lauryl alkyl dimethylamine acetate Laurly alkyl dimethylamine phosphate Melamine formaldehyde copolymer Melamine formaldehyde methanol polymer Melamine formaldehyde triethanolamine mixed fatty alcohols polymer Melamine stearyl alcohol polymer Propoxylated starches 2,2' ,4,4'-tetrahydroxybenzophenone Urea, 2-(2-aminoethyl)aminoethanol polymer, stearate Urea polymers with formaldehyde and methanol Urea, polymer with tetrakishydroxymethyiphosphonium sulfate All other textile chemicals, other than surface active agents Urea, by end-use markets: Urea, primary solution (Report on 100% urea-content basis)

Urea in compounds or mixtures (100% Basis): Urea in feed compounds (100% Basis)

Separate statistics

Manufacturers' identification codes (according to list in table 44)

Yes No

RH.

No No No No

GRD. BAS, RH. MIL. BAS.

Yes No No

CCC. CCC.

No

CCC, CRT, DAN.

No No No

CCC. ACY, CCC, CHP, DAN. SYT.

No No No No No

CCC. ENT. ACY, CCC, CRT.

No No No No No Yes

RPC. SYT. SYT. BAS. CCC. ACY, BAS, CCC, CRT, SYT.

No

CHP.

No

BAS, CCC, DAN, ENJ, GAF, JSC, PAT, RPC, S.

(2)



(2)

No Yes

Yes Yes

Urea in liquid fertilizer (100% Basis)

Yes

Urea in plastics (100% Basis) Urea in solid fertilizer (100% Basis)

Yes Yes

APD, ARM, BNP, BOR, CAC, CFI, CHN, CNC, FRI, GCC, HKY, MSC, OMC, SMP, SOC, SOH, TER, TRI, TVA, UOC, WLC, WYC, ( 2 ). APD, BNP, CAC, SOH, TER, TRI, WYC. ARM, BNP, CFI, CHN, CNC, FRI, HKY, MSC, SMP, SOC, SOH, TER, TRI, TVA, UOC, ( 2). BOR, OMC, SOH, TRI. APD, CAC, CFI, CNC, FRI, GCC, MSC, OMC, SOH, TER, TRI, TVA, UOC, WLC, WYC.

Chemicals for which separate statistics are reported in this section are indicat ed by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No. 2 The manufacturer did not consent to his identification with the designated prod uct. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

14-10

Synthetic Organic Chemicals, 1987 Table 44 Miscellaneous end-use chemicals and chemical products: Directory of manufacturers, alphabetical by code, 1987

Code

Name of company

Code

Name of company

ABB ACS

Abbott Laboratories Allied Signal, Inc. Engineered Materials Sector American Cyanamid Co. Ajinomoto USA, Inc. Alco Chemical Corp. Aldrich Chemical Co , Inc. Alliance Chemical, Inc. Albright & Wilson, Inc. Alox Corp. Atlas Powder Co. Sub. of Tyler Corp. Aqualon LaRoche Industries Inc. Atlantic Richfield Co., Arco Chemical Co. BASF Corp. Beckman Instruments, Inc. B. F. Goodrich Co. Buckman Laboratories, Inc. Belzak Corp. Borden, Inc., Borden Chemical Div. Bison Nitrogen Products Co. Lonza, Inc. Bristol-Myers Co. Cominco Fertilizers Inc. Carbose Corp. Interstab Chemicals, Inc. C.N.C. International, Inc. Catawba-Charlab, Inc Morton-Thiokol, Inc., Carstab Div. Cedar Chemical Co. CF industries, Inc. Ciba-Geigy Corp. CHR. Hansen's Laboratory, Inc. Wil-Gro Fertilizer, Inc. C. H. Patrick & Co , Inc. Chattem, Inc. Columbia Nitrogen Corp. Conoco Specialty Products, Inc CPS Chemical Co., Inc. Chemos Corp. James River Corp. Upjohn Co., Fine Chemicals Chemical Exchange Industries, Inc Dan River, Inc., Chemical Products Div. Dow Corning Corp Degussa Corp. Dixie Chemical Co., Inc. Dow Chemical Co. E. I. duPont de Nemours & Co., Inc. Chemicals and Pigments Dept. Textile Fibers Dept. Photosystems and Electronics Dept. E.F. Houghton Co. Eastman Kodak Co.: Tennessee Eastman Co. Div. Eico Corp. Sub, of Detrex Chemical Industries, Inc.

EMR

Emery Chemicals Div. of National Distillers & Chemical Corp. Exxon Chemical Americas East Shore Chemical Co. Essex Chemical Corp., Essex Industrial Chemicals, Inc. Ferro Corp.: Ferro Chemical Div. Keil Chemical Div. Fairmount Chemical Co., Inc. Firestone Tire & Rubber Co., Firestone Fibers & Textiles Co. Farmland Industries, Inc. GAF Corp., Chemical Group. Gist-Brocades U.S.A Inc. W. R. Grace & Co., Agricultural Chemicals Group. G. Frederick Smith Chemical Co. Genencor, Inc. Grain Processing Corp. W. R. Grace & Co., Polymers & Chemical Div. Great Lakes Chemical Corp. Goodyear Tire & Rubber Co. Hatco Chemical Corp. Hoechst Celanese Corp: Hoechst Celanese Fibers. Sou-Tex Works. Hodag Chemical Corp. Hexagon Laboratories, Inc. Hawkeye Chemical Co. W. R. Grace & Co., HampshireChemical Div. Humphrey Chemical Co. Hercules, Inc. Hexcel Corp., Hexcel Chemical Products. George A. Jeffreys & Co., Inc. Sybron Chemicals, Inc. Kennecott Minerals Co., Utah Copper Div. Louisiana Chemical Polymers, Inc. Napp Chemicals, Inc. Lyondell Petrochemical Co. MAK Chemical Corp. Mooney Chemicals, Inc. MacKenzie Chemical Works, Inc. Milliken & Co., Milliken Chemical Co. Miles Laboratories, Inc., Biotechnology Group. Monsanto Agricultural Co. Monsanto Co. Merck & Co., Inc. Mississippi Chemical Corp. Mayo Chemical Co. Novo Biochemical Industries, Inc. Nuodex, Inc. NutraSweet Co.

ACY AJI ALC ALD ALL ALW ALX APD AQU ARM ATR BAS BCK BFG BKM BLZ BOR BNP BRD BRS CAC CBC CCA CCC CCL CCW CED CFI CGY CHH CHN CHP CHT CNC CO CPS CRT CRZ CWN CXI DAN DCC DGC DIX DOW DUP

EFH EK EKT ELC

.

ENJ ESA ESX FER

FMT FRF FRI GAF GBF GCC GFS GNR GPC GRD GTL GYR HCC HCL

HDG HEX HKY HMP HMY HPC HXL JFR JSC KCU LCS LEM LYP MAK MCI MCK MIL MLS MNA MON MRK MSC MVO NBI NOD NSW

14-11

Section 14 Table 44—Continued Miscellaneous end-use chemicals and chemical products: code, 1987

Directory of manufacturers, alphabetical by

Code

Name of company

Code

Name of company

NTL

NL Industries, Inc. Olin Corp. Parish Chemical Co. Pennzoil Co , Penreco Div. Pat-Chem Inc. Pennwalt Corp. Pfanstiehl Laboratories, Inc. Pfizer, Inc. Pierce Chemical Co. Pharmacia P-L Biochemicals, Inc. Phillips Petroleum Co. PMP Fermentation Products, Inc. Quaker Chemical Corp. Regis Chemical Co. Rohm & Haas Co HI-TEK Polymers, Inc., Lyndal Div. R.S.A. Corp. Sandoz, Inc., Colors & Chemicals Div. Henkel Corp. Shell Oil Co., Shell Chemical Co. Shepherd Chemical Co. Sherex Chemical Co., Inc. Shakespeare Co , Monofilament Div. Mobil Oil Corp., Mobil Chemical Co., Chemical Products Div. J. R. Simplot Co. Chevron Corp., Chevron Chemical Co.

SOH SPD

Standard Oil Chemical Co. General Electric Co., Silicone Products Dept. Scientific Protein Laboratories Segua Chemicals, Inc. Wacker Silicone Synthron, Inc. Terra International, Inc. Ethyl Corp. Texas Petrochemical Corp. Triad Chemical Troy Chemical Corp. Texaco Butadiene Co. Tennessee Valley Authority Texaco Chemical Co. Union Carbide Corp. Union Oil Co. of California Upjohn Co. U.O.P. Inc. Uniroyal, Inc., Uniroyal Chemical Div. Valero Refining Company Vanderbilt Chemical Corp. Olin Hunt Specialty Products, Inc. White & Bagley Co. Freeport-McMoran Resource Partners Witco Chemical Corp. Wycon Chemical Co.

OMC PAH PAR PAT PAS PFN PFZ PIC PLB PLC PMP QCP REG RH RPC RSA S SCP SHC SHP SHX SKP SM SMP SOC

SPR SQA SWS SYT TER TNA TPC TRI TRO TUS TVA TX UCC UOC UPJ UPM USR VLR VNC WAY WBG WLC WTC WYC

Note.—Complete names, telephone numbers, and addresses of the above reporting companies are listed in table 1 of the appendix. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

14 12 -

Synthetic Organic Chemicals, 1987

Section 15 Miscellaneous Cyclic and Acyclic Chemicals The term "miscellaneous chemicals" as it is used here comprises those synthetic organic products that are not included in the use groups covered by sections I-XIV of this report. They include products that are employed in a great variety of applications. The number of chemicals used extensively for only one purpose is not large. Among the products covered in this section are those used for refrigerants, aerosols, solvents, catalysts, additives in plastics and food products, and, especially, a wide range of acyclic chemical intermediates. Figure 16 shows the trend of production of miscellaneous chemicals during 1983-87, and shows there has been a steady rate of increase since 1984. However, the 1987 production of 98.0 billion pounds did not surpass the all-time peak of 98.8 billion pounds produced in 1979. U.S. production of miscellaneous cyclic and acyclic chemicals in 1987 amounted to 98.0 billion pounds, an increase of 2.5 percent compared with production in 1986 (Table 45). Production of miscellaneous cyclic chemicals comprised only 2.9 percent of this section's total production. Because most of the production of miscellaneous chemicals is used internally by their producers to make more advanced intermediates and other chemical products, their sales are much smaller than their production. In 1987, sales of miscellaneous chemicals were 40.3 billion pounds, valued at $12.0 billion, compared with 37.9 billion pounds, valued at $10.8 billion, in 1986. The increase in sales quantity in 1987 was 6.3 percent. Moreover, with increases in prices which compensated for their fall in 1986 when total value of sales declined 3.3 percent though sales quantity increased 4.1 percent, the value of sales in 1987 was 11.3 percent greater than in 1986. Oxygenated hydrocarbons accounted for 62 percent of the production of all acyclic miscellaneous chemicals. Production of oxygenated hydrocarbons, which include organic acids, alcohols (the largest group), ketones, esters, ethers, aldehydes, epoxides, and other chemicals, increased from 55.6 billion pounds in 1986 to 58.9 billion pounds in 1987, or by 5.9 percent. Slightly larger in volume than the alcohols in miscellaneous acyclic chemicals is the halogenated hydrocarbons group, the largest production of halogenated hydrocarbons was almost 26 billion pounds in 1987, about 1 billion pounds less than in 1986. Production of chlorinated hydrocarbons, by far the largest segment of this group, was 24.7 billion pounds in 1987, compared with

25.7 billion pounds in 1986. The small overall decrease in this group in 1986-87 hides larger changes in many of its constituent chemicals: There was decreased production of methyl chloride (down 38.3 percent), methylene chloride (down 9 percent), and ethylene dichloride (down 5.7 percent); somewhat balanced by increased production of chloroform (up 9.3 percent), perchloroethylene (up 14 percent), and 1,1,1-trichloroethane (up 6.5 percent). (One year earlier, this situation was almost reversed; the latter two chemicals were the major "down" chemicals and methylene chloride and ethylene dichloride had increased by 940 million pounds). Fluorinated hydrocarbons production was 1.16 billion pounds in 1987, up 1.9 percent compared with production in 1986. Production of brominated chemicals, on the other hand, was less than half of what it had been in 1986-10.4 versus 21.1 million pounds. The second largest individual group of miscellaneous acyclic chemicals is monohydric alcohols (with double the production of polyhydric alchols), production of which was 15.3 billion pounds in 1987, an increase of 13.5 percent over 1986, which followed an increase of similar magnitide the year before. Compared with 1986, the increase of 512 million pounds of "mixtures of C11 and lower alcohols" in 1987 outweighed less spectacular increases in production of most of the other alcohols. Virtually in a tie for third place among miscellaneous acyclic chemicals, each with production close to 9 billion pounds in 1987, are nitrogenous compounds, acids and anhydrides, and aldehydes. Led by increases in acetic and acrylic acids, production of acids and anhydrides was 10.6 percent greater than in 1986. Production of aldehydes was 5.9 percent greater than in 1986, led by an increase for butyraldehyde of nearly 20 percent. Production of nitrogenous chemicals was 3.5 percent greater than in 1986. Almost all identified groups of nitrogenous chemicals grew more than 10 percent in 1987 but production of the large "all other" group dropped by 32 percent. There were a few other large increases in 1987 of major chemicals; namely, the increase of 30.4 percent in production of propylene glycol to 747 million pounds, and increases of about 12 percent for methyl ethyl ketone and butyl acetate. The apparent doubling of production of acyclic peroxides, to 96 million pounds, is overstated since some of the peroxides has been grouped in the "all other" category in earlier years. Table 46 lists the products in this section individually identified by manufacturer(s) codes. Table 47 lists those codes alphabetically and identifies the manufacturer by name. Aimison Jonnard 202-252-1350 15-1

Section 15 Figure 16 Miscellaneous cyclic and acyclic chemicals: U.S. production, 1983-87

1983

1984

1985

1986

1987

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

15-2

Synthetic Organic Chemicals, 1987 Table 45 Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1987

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

98,040,259

40,317,300

12,032,151

$0.30

2,887,467

1,305,231

1,397,386

1.07

Benzoic acid esters, total

1,465

(2)

(2)

(2)

Butyl benzoate All other Benzoic acid salts: Potassium benzoate Sodium benzoate Benzoyl peroxide tert-Butyl peroxybenzoate Caprolactam Hexamethylenetetramine, tech. grade Lactones Maleic anhydride

1,146 319

1,391 (2)

783 (2)

.56 (2)

4,808 20,060 8,602 4,157 1,156,336 86,808 69,964 382,289

4,210 16,841 8,677 4,165 276,871 (2) 14,103 312,548

3,479 10,744 21,573 7,313 170,252 (2) 14,312 133,570

.83 .64 2.49 1.76 .62 (2) 1.01 .43

Pinene and derivatives, total

337,298

48,273

18,569

.38

Pinene, sulfate Pine oil, natural sulfate All other Succlnic anhydride derivatives Tall oil salts (Linoleic-rosin acid salts) All other

156,294 5,285 175,719 18,697 2,934 794,049

(2) 6,044 42,229 16,984 (2) 601,168

(2) 2,036 16,533 14,855 (2) 1 ,001 ,936

(2) .34 .39 .87 (2) 1.67

95,152,792

39,012,069

10,634,765

.27

8,789,514

3,218,896

1,403,203

.44

296,529

137,872

116,400

.84

(2) 51,845 (2) 889 243,795

2,583 33,149 4,996 (2) 97,144

2,423 21,037 5,586 (2) 87,354

.94 .63 1.12 (2) .90

Amines, total3

1,740,451

527,566

360,148

.68

Butylamines, total Di-n-butylamine All other Ethylenediamlne Isopropylamine, monoMethylamines, total Dimethylamine Methylamine, monoTrimethylamine All other Dimethylaminoethyl methacrylate-methyl chloride, quaternary salt

15,806 3,250 12,556 78,775 (2) 155,731 73,935 51,997 29,799 1,490,139

25,843 5,046 20,797 66,680 47,391 (2) 62,758 (2) 27,912 296,982

19,857 3,423 16,434 46,348 17,164 (2) 21,600 (2) 9,164 246,015

.77 .68 .79 .70 .36 (2) .34 (2) .33 .83

(2)

4,912

6,916

1.41

Miscellaneous cyclic and acyclic chemicals

Grand total

Cyclic Total

Acyclic Total Nitrogenous compounds Total Amides, total N,N'-Ethylenebis-oleamide N,N'-Ethylenebis-stearamide Oleamide (Octadecene amide) Stearamide (Octadecane amide) All other

See footnotes at end of table.

15 -3 222-174 0 - 88 - 7 : QL 3

Section 15 Table 45-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1987

Miscellaneous cyclic and acyclic chemicals

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Acyclic-Continued Nitrogenous compounds-Continued Ethanolamines, total

626,774

547,810

135,422

$0.25

2,2'-Aminodiethanol (Diethanolamine) 2-Aminoethanol (Monoethanolamine) 2,2' ,2"-Nitrilotriethanol (Triethanolamine) Methyl diethanolamine (2,2'-(Methylimino) diethanol)

194,406 231,835 200,533

183,584 163,344 200,882

44,424 38,571 52,427

.24 .24 .26

18,632

15,307

13,821

.90

Nitrites, total

5,053,994

1,764,648

513,562

.29

Acetonitrile Acrylonitrile 2-Methyllactonitrile (Acetone cyanohydrin) All other All other

27,760 2,451,829 1,163,879 1,410,526 1,053,134

(2)

(2)

(2)

1,453,973 (2)

421,140 (2)

310,675 220,781

92,422 256,934

.29 (2) .30 1.16

9,295,102

2,691,447

908,051

.34

3,245,948 1,100,894 31,481 287,790 1,631 (2)

1,102 ,599 204,500 24,752 233,458 (2)

140,337 75,257 12,088 65,912 (2)

.13 .37 .49 .28 (2)

4,627,358

83,388 1,042,750

18,535 595,922

.22 .57

448,429

327,453

233,345

.71

Acetic acid salts, total

54,949

22,405

15,343

.68

Sodium acetate Zinc acetate All other Calcium neodecanoate

47,182 448 7,319 104

(2)

(2)

(2)

416 21,989 99

798 14,545 103

1.92 .66 1.03

2-Ethylhexanolc acid (a-Ethylcaproic acid) salts, total

16,117

12,392

18,300

1.48

55 262 2,496 7,904 722 914 708 5,239

1.15 .88 1.02 2.02 .84 .94 .98 1.67

Acids, acyl halides and anhydrides Total Acetic acid, synthetic, 100% 4 Acrylic acid4 Dimer acid (C 36 dibasic acid) Fatty acids, hydrogenated Pivaloyl chloride Propionic acid All other Salts of organic acids Total

Barium 2-ethylhexanoate Cadmium 2-ethylhexanoate Calcium 2-ethylhexanoate Cobalt 2-ethylhexanoate Lead 2-ethylhexanoate Manganese 2-ethylhexanoate Zinc 2-ethylhexanoate Zirconium 2-ethylhexanoate

110 891 2,514 5,040 846 957 1,461 4,298

48 . 298 2,450 3,917 864 968 719 3,128

Oleic acid salts, total

237

(2)

(2)

(2)

Oxalic acid salts: Ammonium oxalate Potassium oxalate

(2)

42 31

119 79

2.82 2.53

See footnotes at end of table.

15-4

33

Synthetic Organic Chemicals, 1987 Table 45-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1987

Miscellaneous cyclic and acyclic chemicals

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Acyclic-Continued

Salts of organic acids-Continued Propionic acid salts, total

29,616

32,751

13,084

$0.40

Calcium propionate Sodium propionate

26,527 3,089

29,612 3,139

11,661 1,423

.39 .45

Stearic acid salts, totals

139,895

128,853

76,627

.59

Aluminum tristearate Barium stearate Cadmium stearate Calcium stearate Magnesium stearate Zinc stearate All other

1,835 1,672 197 77,172 25,604 33,415 207,478

1,734 1,190 119 76,497 17,561 31,752 130,880

2,325 919 274 36,057 12,626 24,426 109,690

1.34 .77 2.30 .47 .47 .72 .84

8,929,774

2,110,428

213,018

.10

1,758,934 5,733,238 (2) 1,437,602

(2) 1,691,080 10,869 408,479

(2) 107,114 2,400 103,504

(2) .06 .22 .25

2,807,716

2,165,222

447,568

.21

Acetone, total

1,845,586

(2)

(2)

(2)

From cumene All other Methyl ethyl ketone (2-Butanone) 4-Methyl-2-pentanone (Methyl isobutyl ketone) All other

1,360,155 485,431 671,859

1,182,797 (2) 549,374

175,923 (2) 123,887

.15 (2) .23

151,241 139,030

155,490 277,561

51,201 96,557

.33 .35

15,322,198

7,189,725

1,220,022

.17

13,821,457

6,473,181

885,147

2,731,359

814,124

164,029

.20

1,154,867

583,726

127,594

.22

165,806 1,410,686 573,687 662,153 1,370,877 7,536,766 186,190 760,425

147,684 82,714 714,202 228,342 1,107,330 3,182,754 107,641 318,788

25,074 11,361 168,832 60,681 188,412 150,069 33,187 119,937

.17 .14 .24 .27 .17 .05 .31 .38

Aldehydes Total Butyraldehyde Formaldehyde (37% by weight) Propionaldehyde All other Ketones Total

Alcohols, monohydric, unsubstituted Total Alcohols, C I , or lower, unmixed, total Butyl alcohols, total n-Butyl alcohol (n-Propylcarbinol) 4 Isobutyl alcohol (isopropylcarbino1) 4 All other Ethyl alcohol, synthetic', 6 2-Ethyl-1-hexanol Isopropyl alcohol3 Methanol, synthetic 3 Propyl alcohol (Propanol) All other

.14

See footnotes at end of table.

15-5

Section 15 Table 45-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1987

Miscellaneous cyclic and acyclic chemicals

Production

Sales Quantity

Value

Average Unit valuer

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Acyclic-Continued Alcohols,

and higher, unmixed, total

172,562

63,056

35,619

$0.56

(2)

172,562

6,361 56,695

3,711 31,908

.58 .56

1,328,179

653,488

299,256

.46

620,230 600,589 107,360

193,702 413,835 45,951

88,319 197,443 13,494

.46 .48 .29

4,992,098

3,184,468

1,026,267

.32

1,268 201,853 88,247 515,059 3,076 2,508 2,721 2,664 84,863 214,003 324,368

1,238 168,868 70,095 236,392

1,679 48,919 17,802 104,571

1.36 .29 .25 .44

(2)

(2)

(2)

2,553 85,251 162,370 144,982

4,154 31,137 34,097 54,358

1.63 .37 .21 .37

11,727

8,783

5,602

.64

(2)

440 469 7,874 36,527

679 411 4,512 13,409

1.54 .88 .57 .37

(2)

(2)

(2)

144,125 70,540 1,813,313 442,737

88,715 63,954 1,641,242 471,069

96,315 25,372 326,265 258,710

1.09 .40 .20 .55

Total

7,097,429

5,041,909

1,189,384

.24

1 ,4-Butanediol Ethylene glycol', Pentaerythritol4 Propylene glycol All other

402,105 5,183,229 747,209 764,886

112,031 3,778,031 130,416 663,740 357,691

69,490 669,635 63,287 182,214 204,758

.62 .18 .49 .27 .57

Polyhydric alcohol esters, total

235,140

244,276

162,013

.66

2-Butyoxyethyl acetate All other

(2)

235,140

16,487 227,789

9,827 152,186

.60 .67

C12

Stearyl alcohol All other Mixtures of alcohols, total Containing C 11 or lower only Containing C12 through C18 Other mixtures Esters of monohydric alcohols Total Allyi methacrylate n-Butyl acetate Isobutyl acetate Butyl acrylate Di-2-ethylhexyl maleate Dilaury1-3,3'-thiodipropionate Dloctyl maleate Disteary1-3,3'-thiodipropionate 2-Ethoxyethyl acetate Ethyl acetate (100% basis) Ethyl acrylate Fatty acid esters, not included with plasticizers or surface-active agents, total Myristyl myristate Tridecyl stearate All other Isopropyl acetate Methyl methacrylate 4 Phosphorus acid esters, not elsewhere specified Propyl acetate Vinyl acetate All other

(2)

11,727 40,237 1,028,789

(2)

(2)

(2)

2,429

3,877

1.60

Polyhydric alcohols?

See footnotes at end of table.

15-6

(2)

Synthetic Organic Chemicals, 1987 Table 45-Continued Miscellaneous cyclic and acyclic chemicals: U.S. production and sales, 1987

Miscellaneous cyclic and acyclic chemicals

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Acyclic-Continued

Polyhydric alcohol ethers Total 2-Butoxyethanol (Ethylene glycol monobutyl ether) 2-(2-Butoxyethoxy)ethanol (Diethylene glycol mono-butyl ether) 2-[2-(2-Butoxyethoxy)ethoxy] ethanol (Triethylene glycol monobutyl ether) Diethylene glycol Dipropylene glycol 2-(2-Ethoxyethoxy)ethanol (Diethylene glycol mono-ethyl ether) 2-Methoxyethanol (Ethylene glycol monomethyl ether) 2-(2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl ether) 2-[2-(2-Methoxyethoxy)ethoxy]ethanol (Triethylene glycol monomethyl ether) Polyethylene glycol Tetraethylene glycol Triethylene glycol All other

1,919,618

1,661,341

582,497

$0.35

406,082

370,043

98,904

.27

85,219

76,964

29,887

.39

(2) 435,986 71,192

10,128 393,808 (2)

3,416 63,562 (2)

.34 .16 (2)

29,551

27,491

10,491

.38

71,888

41,220

13,545

.33

36,170

58,230

20,601

.35

34,946 120,288 21,741 118,056 488,499

17,068 114,867 20,577 115,078 415,867

4,368 65,509 6,985 32,963 232,266

.26 .57 .34 .29 .56

25,866,572

9,077,592

2,120,319

.23

10,396

9,156

13,705

1.50

24,694,479

8,110,665

1,357,953

.17

Brominated, chlorinated, and fluorinated hydrocarbons Total Brominated (including bromochlorinated) hydrocarbons Chlorinated hydrocarbons, total Carbon tetrachloride Chlorinated paraffins (C10-Cm): 35%-64% chlorine 65% or more chlorine Chloroform', Chloromethane (Methyl chloride) Dichloromethane (Methylene chloride) 4 Ethyl chloride (Chloroethane) 4 Ethylene dichloride (1,2-Dichloroethane) Tetrachloroethylene (Perchloroethylene) 1,1,1-Trichloroethane (Methyl chloroform) . Vinyl chloride, monomer (Chioroethylene) . All other

672,151

717,822

102,068

.14

76,615 19,537 461,819 373,258 516,132 154,505 12,196,585 473,410 694,296 8,401,595 654,576

78,444 22,973 446,377 (2) 473,111 (2) 1,296,930 574,354 584,535 3,458,777 457,342

28,831 8,966 53,535 (2) 83,122 (2) 103,816 96,782 186,267 598,725 95,841

.37 .39 .12 (2) .18 (2) .08 .17 .32 .17 .21

Fluorinated (including other fluorohalogenated) hydrocarbons, total

1,161,697

957,771

748,661

.78

274,903 334,885 197,769 354,140

197,016 332,673 197,551 230,531

189,629 219,445 85,255 254,332

.96 .66 .43 1.10

Chlorodifluoromethane (F22) Dichlorodifluoromethane (F12) Trichlorofluoromethane (F11) All other See footnotes at end of table..

15-7

Section 15 Table 45-Continued Miscellaneous cyclic and acyclic chemicals:

Miscellaneous cyclic and acyclic chemicals

U.S. production and sales, 1987

Production

Sales Quantity

Value

Average Unit value'

1,000 pounds

1,000 pounds

1,000 dollars

Per pound

Acyclic-Continued All other miscellaneous acyclic chemicals 9,274,471

1,936,803

1,106,149

$0.57

96,311

56,106

84,384

1.50

3,106 13,509 2,694 77,002

3,090 14,175 2,517 36,324

8,391 24,191 3,616 48,186

2.72 1.71 1.44 1.33

Expoxides, ethers, and acetals, total

7,673,001

1,512,518

474,860

.31

Ethylene oxide' Glycidyl ethers, total 1-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) All other All other Fats and oils, chemically modified Hydrocarbons Organo-aluminum compounds

4,785,307 7,692

670,810 7,389

135,125 11,373

.20 1.54

778 6,914 2,880,002 45,429 26,077 124,883

634 6,755 834,319 42,294 16,158 36,921

1,073 10,300 328,362 18,318 12,896 63,135

1.69 1.52 .41 .43 .80 1.71

Organo-silicon compounds, totals

295,703

120,365

275,834

.29

Chloropropyltrimethoxysilane Silicone fluids All other Organo-tin compounds Phosgene (Carbonyl chloride) Sodium methoxide (Sodium methylate) All other

2,311 141,902 151,490

Total Acyclic peroxides, total tert-Butyl peroxypivalate 2-Butanone peroxide (MEK peroxide) Di-tert-butyl peroxide All other

(2)

(2)

(2)

(2)

85,100 35,265 27,174

166,285 109,549 77,626

1.95 3.11 2.86

842,843 5,107 165,117

(2)

(2)

(2)

5,467 119,800

5,731 93,365

1.05 .78

174,731

162,509

22,929

.14

Mixtures not specifically itemized Total

Calculated from unrounded figures. Reported data are accepted in confidence and may not be published, or no data were reported. 3 Statistics exclude production and sales of fatty amines. Statistics on fatty amines are included in the section "Surface-Active Agents." 4 The difference between the production reported here and that shown on the Preliminary Report on U.S. Production of Selected Organic Chemicals (including Synthetic Plastics and Resin Materials), 1987, results from a combination of incorrect reporting by some companies, end-of-year inventory adjustments, and rounding. 6 Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are Included In the section "Surface-Active Agents." • Synthetic ethyl alcohol is conventionally defined as that portion made from ethylene. Bureau of Alcohol, Tobacco, and Firearms statistics for calendar year 1987 show that 138 million proof gallons of ethyl alcohol were made from ethylene whereas 663 million proof gallons were made mostly from grain, molasses, cellulose, and other "natural" raw materials. Most of the latter material was blended with gasoline for fuel use. • Some polyols which are used as intermediates for urethanes have been included in the section "Plastics and Resin Materials." e Statistics exclude production and sales of silicone resins (see Plastics and Resin Materials section), silicone elastomers (see Elastomers section), and silicone greases (see Miscellaneous End-Use Chemicals and Chemical Products section). Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission. 2

15-8

Synthetic Organic Chemicals, 1987 Table 46 Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Cyclic

GIV. (2). UCC. DOW. TX. FER. FER.

6-Acetoxy-2 ,4-dimethy1-1 ,3-dioxane Alkylphenol formaldehyde condensate, alkoxylated 1-(2-Aminoethyl)piperazine 1-(2-Aminoethyl)piperazine, technical 1- (3-Aminopropyl) morpholine Benzenephosphinic acid Benzene phosphonous dichloride Benzoic acid esters: Benzoic acid, isodecyl ester 2-Butoxyethyl benzoate Butyl benzoate 2-Ethylhexyl benzoate Lauryl benzoate Sucrose benzoate Benzoic acid salts: Ammonium benzoate Barium benzoate Cadmium benzoate Potassium benzoate Sodium benzoate, U.S.P Sodium benzoate, tech Benzothiazole Benzotriazole, substituted Benzoyl peroxide

No No No No No No No Yes No No Yes No No No Yes No No No Yes Yes No No No Yes

Benzyl alcohol Benzyl chloroformate Bis (p-chiorobenzoyl) peroxide 1,2-Bis(3,5-di-tert-buty1-4-hydroxyhydrocinnamoyl) hydrazine Bis(2,4-dichlorobenzoyl) peroxide Bis(ce,a-dimethylbenzyl)peroxide 2 ,2-Bis(ferrocenyl) propane Bis(hydroxymethyl)oley1 oxazoline 2,2-Bis(4-hydroxypheny1)4-methylpentane Bis(triphenylsilyl)chromate Boron fluoride-phenol complex 13-Bromo-p-nitrostyrene 4-tert-Butylcyclohexyl peroxydicarbonate tert-Butylhydroquinone Butyl and isopropyl pthalimides 2(and 3)-tert-Butyl-4-methoxyphenol (BHA) Butyl morpholine tert-Butyl peroxybenzoate p-tert-Butylphenyl glycidyl ether tert-Butylphenyl glycidyl ether Camphene Campholenic aldehyde Caprolactam (2-0xohexamethylenelmine) Caprolactam magnesium bromide Cellulose acetate hexahydrophthalate Cellulose acetate phthalate 1-(3-Chloroally1)-3,5,7-triazo-1-azonlaadamantane chloride Chlorothiaxanthone Cresolsulfonic acid, formaldehyde condensate Cresyl glycidyl ether Cumene hydroperoxide

No No No

WTK. FER, WTC. VNC, WTC. KLM, PFZ, SOL. HCP, JRC, KLM, PFZ, SOL. PFZ. RCI. CGY, ( 2 ). AZT, CAD, NOC, PLC, WTC, WTL. KLM. ESX, VCM. CAD.

No No No No No No No No No No No No No No Yes No No No No Yes No No No

ASL CAD. WTL. (2). ANG. ASL. (2). ACS. GIV. CAD. EKT. RPC. EKT, UPM. TX. AZT, FRE, WTC, WTL. WLN. REZ SCM. VIK. ACS, BAS, CNP. (2). (2). EK.

No No No No No

DOW. PSG. HCL. REZ, WLN. BTL, FRE.

VEL (2). MRF, PCI, TCC, UTC. TCC APC. VEL.

See footnotes at end of table.

15-9

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' Identification codes (according to list in table 47)

Cyclic—Continued oi-Cumyl peroxyneodecanoate Cyanuric acid Cyclic silizane Cyclohexane dimethanol diglycidyl ether Cyclohexanethiol 2-Cyclohexene-1-octanoic acid, 5 (and 6)-carboxy-4hexyl, C21 H38 0 4 1 ,4-Cyclohexylenedimethanol Cyclohexyl methacrylate N-Cyciohexyl pyrrolidone Cyclopropane Decabromodiphenyi ether (DBDP) Decahydronaphthalene (Decalin) Diamino cyclohexane 4,4-Diaminodiphenyl ether 1,8-Diazabicyclo (5.4.0)undecane 1 ,4-Diazobicyclo (2 .2 .2 ) octane Diazodinitrophenol 2,5-Di(benzoyl peroxy)-2,5-dimethylhexane Dibutoxy acetophenone Di-t-butyl diperoxyphthaiate 2, 5-Di-tert-butylhydroquinone 1,1-DI (t-butyl peroxy) cyclohexane 1,1-D1(t-butyl peroxy)-3,3,5-trimethyl cyclohexane 2,4-DI-t-butyl phenyl 3,5-di-t-butyl hydroxybenzoate 1 ,3-Dichloro-5,5-dimethylhydantoin Dicumyl peroxide Dicyclohexylammonium nitrite Dicyclopentadienyi chromium Diethoxyphenyl acetophenone (Chromocene) N,N'-Diethyl-N,N'-diphenylurea DI(2-ethylhexyl)chlorendate o,o-Diethyl-o-phenyl phosphorothioate 1 ,5-Dlethyl-2-thio-4 ,6-pyrimidinedione 2,5-DIhydrothlophene-1,1-dioxide (Suifolene) 2,4-Dihydroxybenzophenone 2,2'-Dihydroxy-4,4'-dimethoxybenzophenone Dihydroxydimethyl benzophenone 3, 5-D1hydroxy-3 ,5, dimethyl-1 ,2-peroxycyclopentane . . . 2,3-DIhydroxynaphthalene-6-sulfonic acid, sodium salt Dilodomethyl-p-tolyl sulphone Diisopropylbenzene hydroperoxide p-Dimethoxybenzene (Dimethyl ether of hydroquinone) 4,4-Dimethyl oxazolidene 4,4-Dimethyl oxazoline Dimethyl piperazine Dimorphoiine diethyl ether Di-tert-octyl hydroquinone Dioxane (1,4-Dlethylene oxide) 1 ,3-Dioxolane Di-para-xylene 1 ,2-Dlphenoxyethane Dipheny1-2-ethylhexyl phosphite Diphenyllsodecyl phosphite Diphenyllsooctyl phosphite Dipropyiene glycol salicylate See footnotes at end of table.

15-10

No No No No No

WTC, WTL. MON. SCM. WLN. PAS.

No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No

WVA. EKT. CPS. GAF. DOW. GTL, TNA. DUP. CXI. MAL. AIP. (2) .

HPC. AZT, WTL. CWN. WTL. EKT. WTL. WTL. FER. BRD. FRE. SHC. (2) .

CWN. VCM. VEL. ICI. TNI. PLC. BAS. BAS CWN. WTL. CCC. ABB. HPC. ASL. EFH. ANG. TX. TX. EKT. FER. FER. WCC. ASL. WTC. WTC. WTC. SBC.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics 1

Manufacturers' identification codes (according to list in table 47)

Cyclic—Continued 2,6-DI-tert-butyl-p-cresol (BHT): 2,6-Di-tert-butyl-p-cresol, (BHT), food grade 2,6-Di-tert-butyl-p-cresol, (BHT), technical grade 4-(Dodecyloxy)-2-hydroxybenzophenone Dodecyl pyridinium chloride 6-Ethoxy-1,2-dihydro-2,2,4-trimethyl quinoline 5-Ethyl-1-aza-3, 7-dioxabicyclo [3.3.0] octane Ethyl-2-cyano-3,3-diphenyi acrylate Ethyl cyclohexylamine 2-Ethylhexyl-2-cyano-3,3-diphenyl acrylate Ethyl hydroxymethyl oleyl oxazoline Ethylidine norbornene 4-Ethylmorpholine N-Ethyl pyrrolidone Furan derivatives: 2-Furaldehyde (Furfural) Tetrahydrofurfuryl alcohol Furan derivatives, all other Glyceryl p-aminobenzoate Hexabromocyclodecane Hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triazine Hexamethylenetetramine, tech Hydrindantin Hydroquinone, di(3-hydroxyethyl) ether p-Hydroxybenzoic acid, butyl ester p-Hydroxybenzoic acid, ethyl ester p-Hydroxybenzoic acid, methyl ester p-Hydroxybenzoic acid, propyl ester N-(Hydroxyethyl)piperazine 2-Hydroxy-4-methoxybenzophenone 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid Hydroxymethy1-5,5-hydantoin 2-Hydroxy-4-N-octoxybenzophenone a-D-p-Hydroxyphenylglycine methyl ester K 4-Hydroxy-2,2,6,6-tetramethy1-1-piperldinyloxy 1,2,3-Indantrione monohydrate (Ninhydrin) Lactones: Butyrolactone Caprolactone Diketene Glucono-S-lactone Lanolin acid Lanolin acid, isopropyl ester Lanolin alcohol acetate Lanolin, hydroxylated Lanolin oil Lanolin wax Maleic anhydride Methoxyethyl morpholine 4-Methoxyphenol Methylaziridine Methylbenzene sulfonate Methyl-p-benzoquinone 2-Methylcyclohexylamine 2,2'-Methylenebis(3,4,6-trichlorophenol) (Hexachlorophene) 4-Methylmorpholine 4-Methylphthalic anhydride

No No No No No No No No No No No No No

USR. USR. EKT. TLC. MNA, MON. ANG. BAS. AIP. BAS. ANG. UCC. TX. GAF.

No No No No No No Yes No No No No No N.0 No No No No No No No No Yes No No No No No No No No No No Yes No No No •No No No

HPC, QKO. QKO. BRD. VND. TNA. ANG. BOR, HMP, PLS, WCL. PIC. EKT. KLM. KLM. KLM, LEM. KLM, LEM. TCH, UCC. BRD, VND. BAS. BRD. BAS. BOC. EK. PIC. BAS, GAF. UCC. EKT. PFZ. UCC. UCC. UCC. UCC. UCC. UCC. AMO, ART, ASH, DKA, MON. TX. ASL, EKT. ARS. EK. EK. AIP.

No No No

VEL, ZOC. TX. ICI.

See footnotes at end of table.

15-11

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Cyclic—Continued 1-Methyl-2-pyrolidone, monomer Morpholine Morpholine salt of p-toluene sulfonic acid N-Nitrosophenylhydroxylamine salt Nonylphenol glycidyl ether Octabromodiphenyl oxide Octadecy1-3-(3,5-di-tert-buty1-4-hydroxypheny1)propionate Oxalyl bis(benzylidene hydrazide) Pentaerythritol tribenzoate Phenethyl bromide 2-Phenoxyethanol (Ethylene glycol monophenyl ether) Phenyl acid phosphate Phenyldilsodecyl phosphite Phenylglycidyl ether a-D-Phenyiglycine methyl ester K 1-Phenyl-2-hydroxy-2-methyl-propanone-1 p-Phenylphenoxypolyethylene glycol Phenylxylyl ethane Phthalic acid, lead salt (dibasic) Picramic acid, sodium salt Pinene and derivatives: Pinane Pinane hydroperoxide 2-Pinanol (cis and trans) a-Pinene 13-Pinene cy-Pinene epoxide Oi Pinene oxide Pinene, sulfate Pinene, wood Pine oil, natural sulfate Pine oil, synthetic Polyglycols-toluene diisocyanate reaction product Propylene glycol dibenzoate Propyl gallate 2 ,4 (1 H ,3H ) Pyrimidinedione p-Quinone Resorcinol diglycidyl ether Resorcinol monobenzoate Rosin acid salts: Sodium/potassium rosin acid salts Salicylic acid, ammonium salt Salicylic acid, lead salt Salicylic acid, magnesium salt Stannous octyl phthalate Styrene oxide Succinic anhydride Succinic anhydride derivatives: Dodecenylsuccinic anhydride Dodecylsuccinic anhydride n-Hexadecenylsuccinic anhydride Hexenylsuccinic anhydride Iso-Hexadecenyl succinic anhydride Iso-Octadecenyl succinic anhydride Nonenylsuccinic anhydride -

See footnotes at end of table.

15-12

No No No No No No

BAS, GAF. AIP, DOW, TX. AMB. MAL. WLN. TNA.

No No No No No No No No No No No No No No Yes No No No No Yes No No Yes No Yes No No No No No No No No

CGY, TNA. EKT. VEL. WCC. TCH, UCC. ALW. WTC. REZ. BOC. CWN. UCC. HCC, TCC. ALI. SDC.

No No No No No No No Yes No No No No No No No

GP. WTK. SHP. KLM, WTK. (2). UCC. BCC, MIL.

NCI, SCM. SCM. SCM. ARZ. ARZ, NCI. SCM. VIK. ARZ, HPC, NCI, SCM. HPC. ARZ, NCI, SCM. ARZ, SCM. (2). VEL. EKT. SCM. EKT. WLN. EKT.

BCC, DIX, HMY. HMY, MIL. DIX, HMY. HMY. HMY. DIX, HMY. HMY.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Cyclic—Continued

Succinic anhydride derivatives—Continued Octenyl succinic anhydride All other succinic anhydride derivatives Tall oil acyl chloride Tall oil, chemically modified Tall oil fatty acids, polymerized Tall oil salts (Linoleic-rosin acid salts): Cadmium tallate Calcium manganese tallate Calcium tallate Cobalt manganese tallate Cobalt tallate Lead tallate Manganese tallate Zinc tallate All other tall oil salts (Linoleic-rosin acid salts) Tannic acid, N.F Terpene hydrocarbons, monocyclic (Solvenol) Tetrabromobisphenol A 1 ,2,3,4-Tetrahydronaphthalene (Tetralin) Tetrahydrothiophene Tetrahydrothiophene-1 , 1-dioxide (Sulfoiane) Tetraphenyitin chloride Thiophene Tributyltin benzoate 3,4,4'-Trichlorocarbanilide 1, 3, 5-Trichloro-s-triazine-2 ,4 , 6- ( 1 H , 3H , 5H) trione (Trichloroisocyanuric acid) Tri (2 ,4-ditertiarybutylphenyi) phosphite Tri(methoxymethyl) tri(stearoxymethyl) melamine Trimethy1-1-cyclohexane 3,3,5-Trimethyicyclohexanol (m-Homomenthol) 3,5,5-Trimethy1-2-cyclohexene-1-one (Isophorone) s-Trioxane Triphenyl phosphite Triphenyltin hydroxide 1-Vinyl-2-pyrrolidinone - other copolymers 1-Vinyl-2-pyrrolidinone-maleic anhydride copolymer 1-Vinyl-2-pyrrolidinone-methylacrylic acid, dimethylamine ethyl ester, copolymer 1-Vinyl-2-pyrrolidinone, monomer 1-Vinyl-2-pyrroildinone-vinyl acetate copolymer All other cyclic chemicals

No No No No No Yes No No No No No No No No No No No No No No No No No No No

WTC. MCI, SHP. CCA. MCI, SHP. MCI, SHP. MCI. MCI, SHP. MCI. CCA, CIN, GAF, SHP, ( 2 ). MAL. NCI, SCM, WTK. GTL, TNA, ( 2 ). DUP. PAS. PLC. ALW. PAS. COS. MON.

No No No No No No No No No No No

MON, OMC. WTC. WPG. ENJ. ARS. UCC. ALW. WTC. (2) . GAF. GAF.

No No No No

GAF. GAF. GAF. ALW, BAS, CED, COC, CWN, EK, EKT, FTX, HCL, HK, HMY, HXL, ORT, PAC, PCI, PD, PIC, PLC, RBC, REG, REM, RH, RSA, S, SHP, TNA TX, UCC, VIK, WTC, WTL, ( 2), ( 2 ), ( 2 ), ( 2 )•

No No No No

DIX. SBC. EFH. COS.

HMY, MIL. HMY. CCC. EFH, FOC, WVA, ( 2 ), ( 2). WVA.

Acyclic Nitrogenous compounds: Acetaldehyde dimethylhydrazone Acetamidoethanol (N-Acetyl-ethanoiamine) Adipic acid-diethyiene triamine condensate Alkyl C12-C 14 amine hydrochloride See footnotes at end of table.

15-13

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics 1

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Nitrogenous compounds—Continued Amides: AcetamIde Acrylamide monomer Acrylamide polymer with N,N-Dlethyl-N-methyl-2 (1-oxo-2-propenyloxy)ethanimlnium sulfate Amides, C14-18 , N-[2-(C 13-C 17 -alkyl-4, 5-dihydro-1-h'-imldozol-lyl) ethyl Amido amine salts as curing agents 1,1'-Azobisformamide Behenamide Bis [2- (octadecylamido) ethyl] -N- (2-cyanoethyl) N-ethyl ammonium ethyl sulfate Coconut oil amide 2,2-Dibromo-3-nitrilopropionamide N, N-Diethyldodecanamide N,N-Dimethylacetamide N,N-Dimethylacetoacetamide Dimethylaminopropyl methacrylamide Dimethyl caprylamide capramide N,N-Dimethylformamide Erucamide Erucamide-stearamide mix N,N'-Ethylenebis-oleamide (Oleic acidethylenediamine condensate (Amine/acid ratio = 1/2)) N,N'-Ethylenebis(stearamide) Fatty acid amide mixtures Formaldehyde adduct condensation Methacrylamide Monomethylacetoacetamide Oleamide (Octadecene amide) Oleoylpalmitamide Oxamide Stearamide (Octadecane amide) Stearylerucamide Stearyl stearamide Tallow amide, hydrogenated Triethylene diamide All other amides Amines: t-Alkylamines, primary, mixed Allylamines Bis-hexamethylenetriamine amine Butylamines: n-Butylamine, mono sec-Butylamine, mono tert-Butylamine, mono Di-n-butylamine Dilsobutylamine Tri-n-butylamine n-Butylethylamine DI-tert-butylethyldiamine Diethylenetriamine Dilsopropylamine Dimethylamine sulfate Dimethylaminopropylamine See footnotes at end of table.

15 14 -

Yes No No

WTK. ACY ( 2 ) .

No

( 2).

No No No No

SHX. PAC, REZ, FMT, USR. WTC.

No No No No No No No No No No No

SBC. ARC, CAD. DOW. EK. DUP, MON. BRD, EKT. TX. HAL. AIP, DUP, HAL. ARC, SYP, WTC. WTC.

Yes Yes No No No No Yes No No Yes No No No No No Yes No No No Yes No No No Yes No No No No No No No No

BRD, CCW, DOW, WTC. BRD, CCW, WTC. GAF. COS. DUP. EKT. ARC, SYP, WTC. HXL, WTC. HML, ( 2 ) . ARC, SYP, WTC. HXL, WTC. WTC. ARC. CAD. ARC, ARS, COC, RBC, WTC.

(2 ) .

RH. HCL, SHC. MON. AIP, HCL, PAS. FER, PAS. MON. AIP, HCL, PAS. AIP, HCL. AIP, PAS. AIP, DOW. HCL. UCC. AIP, HCL, PAS, UCC. ALW. AIP, TX.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics 1

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Nitrogenous compounds—Continued Amines—Continued N,N-Dimethylbutylamine Ethylamines: Diethylamine Ethylamine, mono Triethylamine Ethylenediamine (2-Ethylhexyl)amine, mono N-Ethyl-2-methylallylamine Fatty amines 1,6-Hexanediamlne (Hexamethylenediamine) n-Hexyiamine Isopropylamine, mono Methylamines: Dimethylamine Methylamine, mono Trimethyl amine tert-Octylamine n-Octylamine, mono Pentaethyienehexamine Pentylamines (Amy!amines): Dipentylamine Pentylamine, mono Tripentylamine Poly (oxypropylene) diamine Propylamines: Dipropylamine Propylamine, mono Tripropylamine Tetraethyienepentamine N ,N ,N' ,N'-Tetramethy1-1,3-butanediamine Tetramethylethylenediamine Triethylenediamine Triethylenepentamine Triethylenetetramine All other amines 2-Aminoethanol hydrochloride 2-Aminoethanol (Monoethanol amine) sulfite Aminoethoxyethanol 2- (2-Aminoethylamino) ethanol (Aminoethylethanolamine) 2-Aminoethyl mercaptoacetate (Monoethanolamine thioglycolate) 2-Amino-2-ethyl-1 ,3-propanediol Aminoguanidine hydrochloride 2-Amino-2-(hydroxymethyl)-1,3-propanediol (Tris ( hydroxymethyl) aminomethane ) 2-Amino-2-methyl-1 ,3-propanediol 2-Amino-2-methyl-1-propanol 2-Amino-2-methyl-1-propanol hydrochloride Bis (dimethylaminoethyl) ether tert-Butylaminoethyl methacrylate tert-Butyldiethanolamine tert-Butyl ethanolamine tert-Butyl urea 2-Chloro-N , N-dimethylethylamine (Dimethylamino ethyl chloride) hydrochloride Choline

No

HCL.

No No No Yes No No No No No Yes Yes Yes Yes Yes No No No

AIP, HCL, PAS, UCC. AIP, HCL, PAS, UCC. AIP, HCL, PAS, UCC. DOW, TX, UCC. HCL, PAS. HCL. NCI. DUP, MON. PAS. AIP, HCL, PAS, UCC.

No No No No

HCL, PAS. PAS. PAS. TX.

No No No No No No No No No No No No No

AIP, HCL, PAS. AIP, PAS. AIP, PAS. DOW, UCC. MON, UCC. BKM. TX. CXI. CXI, DOW, UCC. EK, MON, PAC, VEL, ( 2 ). OMC, ( 2). EVN. TX.

No

DOW, UCC.

No No No

EVN. ANG. REM.

No No No No No No No No No

ANG, WTK. ANG. ANG. CCC. TX. AAC, CPS. PAS, UCC. UCC. ADC, PAS.

No No

SOM. RH.

AIP, DUP, GAF, IMC, UCC. AIP, DUP, GAF, IMC. AIP, DUP, IMC. RH. HCL. DOW, UCC.

See footnotes at end of table.

15-15

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list In table 47)

Acyclic—Continued Nitrogenous compounds—Continued Diallyidimethyl ammonium chloride DI-amine derivatives of dimer acids 2-Dibutylaminoethanol Dibutylaminomethanol 1 ,3-Dibuty1-3-thiourea 2-Diethylaminoethanol (N,N-Dlethylethanolamine) 2-(2-Diethylaminoethoxy)ethanol Diethylaminoethylacrylate, dimethyl sulfate, quaternary salt 2-Diethylaminoethyl methacrylate Diethylglycolamine (DEGA) Diethylhydroxylamine 1 ,3-Diethyl-2-thiourea 2-Dlisopropylaminoethanol (N,N-Dilsopropylethanolamine 2-Dlisopropylaminoethyl methacrylate Diisopropylammonium nitrite 2-DImethylaminoethanethiol hydrochloride 2-Dimethylaminoethanol (N,N-Dimethylethanolamine) Dimethylaminoethylacrylate, methyl chloride, quaternary salt Dimethylaminoethyl methacrylate Dimethylaminomethylmethacrylate, dimethyl sulfate, quaternary salt Dimethylaminoethylmethacrylate, methyl chloride, quaternary salt 2-Dimethylamino-2-methyl-1-propanol hydrochloride 1-(Dimethylamino)-2-propanol Dimethylaminopropylamine, propoxylated Dimethyl dilsocyanate 2,5-Dithloblurea Ethanolamines: Diethanolamine (2,2'-Aminodiethanol) Monoethanolamine (2-Aminoethanol) Triethanolamine (2,2' ,2"-Nitrilotriethanol) 2-Ethylaminoethanol (Ethylmonoethanolamine) N,N-Ethylenebis(12-hydroxystearamide) 1,1-Ethylenediurea N-Ethyl-N-hydroxyethyl-1 ,4-pentanediamine 2-Ethyl-2-nitro-1,3-propanediol Hexamethylenediamine adipate (Nylon salt) Hexamethylene-1 ,6-diisocyanate (HDI) Hexamethylene- a,6-dilsocyanate, biurets (HDI biurets) Hexamethylene-1,6-diisocyanate trimers (HDI trimers) Hexylamine ethoxylate N-(2-Hydroxyethyl)-12-hydroxystearamide 2- ( Hydroxymethyl) -2-nitro-1 ,3-propanediol (Tris(hydroxymethyl) nitromethane) Iminodiacetic acid Isopropanolamines: Diisopropanolamine Monoisopropanolamine Triisopropanolamine 2-Isopropylaminoethanol Ketimine, tetrafunctional 3-Methoxypropylamine 2-Methylaminoethanol (N-Methylethanolamine) See footnotes at end of table.

15 16 -

No No No No No No No

( 2). TX. PAS. (2). RBC. PAS, UCC. PAS, UCC.

No No No No No

CPS. AAC, CPS, DUP. AIP, GAF. PAS. PAS, RBC.

No No No No

PAS, UCC. DUP. RBC. EVN.

No

PAS, PEL, TX, UCC, ( 2 ).

No No

AAC, CPS. AAC, CPS.

No

AAC, CPS.

Yes

AAC, CPS, UCC.

No No No No No Yes Yes Yes Yes No No No No No No No

WPG. ANG, PAS, PEL. TX. MOB. FMT, GAF.

No

MOB.

No No No

MOB. CXI. CAS.

No No

ANG. HMP.

No No No No No No No

DOW. DOW. DOW. PAS, UCC. PAC, SM. TX. PAS, UCC.

CNE, DOW, ICI, OMC, TX, UCC. CNE, DOW, ICI, OMC, TX, UCC. CNE, DOW, ICI, OMC, TX, UCC. PAS. CAS. EK. SDW. ANG. DUP, MON. MOB.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics'

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Nitrogenous compounds—Continued Methyl hydrazine 2,2'-(Methylimino)diethanol (Methyldiethanolamine) Methyl lsocyanate 2-Methyl-2-nitro-1-propanol Mixed higher glycolamines (MHGA) Nitrated lard oil Nitriles: Acetonitrile Acrylonitrile, monomer Adiponitrile Aminodimethyl butyronitrile 2 , 2' -Azobis [2-methylpropionitrilej (Azobisisobutyronitrile) n-ButyronitrIle Coconitrile Crotononitrile Cyanoacetic acid (Malonic Mae) 1-(2-Cyanoethyl)ethyl urea Dicyandiamide (Cyanoguanidine) Dicyanoethyldiethylene triamine 3-Ethoxyproplonitrile Ethyl cyanoacetate Isobutyronitrile 3-Methoxypropionitrile Methyl cyanoacetate Methylisobutyl ketone aminonitrile 2-Methyllactonitrile (Acetone cyanohydrin) Nitrilotriacetonitrile Oleonitrile (Octodecene nitrite) Pentenenitrile Propionitrile Stearonitrile (Octadecane Mlle) Tallow nitrite 3, 3' -Thiodipropionitrile Trichloroacetonitrile Vinylacetonitrile All other nitriles

No Yes No No No No Yes Yes Yes No No

OMC. DOW, PAS, TX, UCC. RDA. ANG. AIP. SM.

No No No No No No No No No No No No No No Yes No No No No No No No No No No

DUP. EKX. ARC. RBC. KF. GAF. FER. HXL. DIX. KF. EKX. (2) . KF. HMP. CYR, DUP, RH, SOH. HMP. ARC. DUP. MON. ARC. ARC, SHX. EVN. OMC. RBC. ARC, COC, DUP, EK, EKT, HXL, NES, ( 2 ). ANG. ANG. ANG. ANG. MOB (2) ESA. OMC. WM. RSA. FMT. HXL. (2) . ADC, COC, EK, HCL, NES, OMC, PAH, PIC, RBC, RSA, SOM, UCC, (2) , (2) , (2) .

Nitroethane Nitromethane 1-Nltropropane 2-Nitropropane Octadecyl diisocyanate N-n-Octyl glucamine Polyvinyl octadecyl carbamate Semicarbazide hydrochloride Stearylamidopropyl dimethylamine lactate Tetraethyl ammonium bromide Thlosemicarbazide Triethylenetetramine, propoxylated Trimethylamine hydrochloride All other nitrogenous compounds, acyclic

No No No No No No No No No No No No No No

Acids, acid anhydrides, and acyl halides: Acetic acid, synthetic (100%)

Yes Yes

BKC, DUP, SOH, ( 2 ). ACY, DUP, MON, SC, SOH. DUP, MON. KF.

AIP, EKT, HCL, MON, NWP, RDA, SC, UCC.

See footnotes at end of table.

15-17

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Acids, acid anhydrides, and acyl halides—Continued Acetic anhydride, 100%: Acetic anhydride from acetaldehyde, 100% Acetic anhydride from acetic acid, other than recovered, by the vapor-phase process, 100% Acetic anhydride from acetic acid, recovered, by vapor-phase process Acetyl chloride Acrylic acid Adipic acid Azelaic acid 2,2-bis(Hydroxy-methyl)-propionic acid Bromoacetic acid Bromobutyric acid 2-Bromohexanoic acid tert-Butylperoxy maleic acid Butyric acid Butyric anhydride Butyryl chloride Castor oil fatty acids, dehydrated Chloroacetic acid, mono Citric acid Crotonic acid (2-Butenoic acid) Decanoyl chloride 2,2-dichloroacetyl chloride Dimer acid (C36 Aliphatic dibasic acid) Dimethylpropionic acid (Neopentanoic acid) Di-n-propyl phosphorodithloic acid Dithiodiglycolic acid Dithiodipropionic acid Dodecanedioic acid 1,2-Ethanedisulfonic acid 2-Ethylbutyric acid (Diethylacetic acid) 2-Ethyihexanoic acid ((x-Ethylcaproic acid) 2-Ethylhexanoyl chloride Fatty acids, hydrogenated Fatty acids, non-hydrogenated Fatty acids, partially hydrogenated Formic acid, 90% Fumaric acid Gluconic acid, technical Glutaric acid Giutaric anhydride Glycolic acid (Hydroxyacetic acid) Heptafluorobutyric anhydride Heptanoic acid Isoascorbic acid (Erythorbic acid) Isobutyric acid Isobutyric anhydride Isobutyryl chloride Isononanoyl chloride itaconic acid (Methylenesuccinic acid) Lactic acid, edible, 100% Lauroyl chloride Malic acid Mercaptoacetic acid (Thloglycolic acid) 3-Mercaptopropionic acid See footnotes at end of table.

15-18

No No No No Yes No No No No No No No No No No No No No No No No Yes No No No No No No No No No Yes No No No No No No No No No No No No No No No No No No No No No

EKT. HCL, UCC. HCL, PFZ. WCC. BAS, HCL, RH, UCC. DUP, MON. EMR. IMC. WCC. EKT. EKT. WTC, WTL. EKT, HCL ,PEN. EKT. WCC. CAS. PFZ. MLS, PFZ. EKT. WCC, WTL. RDA. EMR, SYL, WTC. PCI. ICI. EVN. EVN. DUP. SK. PCI. EKT, PCI, UCC. PPG, WTC, WTL. BRD, CAS, DRL, SHX, SYP, WTC. DRL, WTC. SYP, WTC. HCL. DKA, MON, PFZ. PFZ, PMP. EK. UCC. DUP. PIC. ENJ, HCL. PFZ. EKX. EKT. SYL. HCL. PFZ. MON. WTL. DKA. EVN. EVN, WTC.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued

Acids, acid anhydrides, and acyl halides—Continued Mercaptosuccinic acid (Thlomalic acid) Methacrylic acid Methanesuifonic acid Methanesulfonyl chloride Neo-C9-C 12 acids Neodecanoic acid Neodecanoyl chloride Neoheptanoyl chloride Nonanoic acid (Pelargonic acid) Nonanoyl chloride Octanoyl chloride Oleic acid Oxidized Fischer Tropsch wax Paimitoyl chloride Perfluoropropionic anhydride Pivaloyl chloride Polyacrylic acid Propionic acid Propionic anhydride Propionyl chloride Sebacic acid Sebacoyl chloride Sorbic acid (2,4-Hexadienoic acid) 3,3'-Thiodipropionic acid Thiodisuccinic acid Thiolactic acid Trifluoroacetic acid Trifluoroacetic anhydride Trimerdibasic acids Valerie acid Valeroyi chloride All other acids, acid anhydrides, and acyl halides

No No No No No No No No No No No No No No No Yes No Yes No No No No No No No No No No No No No No

Salts of organic acids: Acetic acid salts: Aluminum acetate Ammonium acetate Calcium acetate Chromium acetate Cobalt acetate Cobalt manganese acetate Copper acetate Hydrazine acetate Lead acetate Lead subacetate Magnesium acetate Manganese acetate Nickel acetate Potassium acetate Sodium acetate

Yes Yes No No No No No No No No No No No No No No Yes

Sodium diacetate Zinc acetate Zirconium acetate All other acetic acid salts Adipic acid, ammonium salt Adipic acid, sodium salt Adipic dihydrazide

No Yes No No No No No

EVN. DUP, RH. PAS. PAS. ENJ. ENJ. PPG, WTC. WTC. EMR, HCL. WCC. WCC. BRD, DRL, WTC. SQA. HCL. PIC. PPG, TLC, WCC, WTC. BFG, BKM, RH. EKT, HCL, UCC. EKT. WCC. WTH. ALD, EK. MON. EVN. EVN. EVN. HOC. HOC. WTC. UCC. WCC. EK, ENJ, HMY, NES, PG, UCC, WTL. NCC. BKC, WTK. HFT, NCC. SHP. SHP. SHP. BKC. FMT. BKC. BKC. BKC, SHP. SHP. SHP. BKC, HCP, JRC, NCC. ATL, BKC, BRI, DAN, HCP, JRC, MAL, NCC, UCC, ( 2). HCP, JRC, NCC. BKC, DIX, SHP, WTK. TZC. RSA. ACS. RSA. FMT.

See footnotes at end of table.

15-19

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics I

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued

Salts of organic acids—Continued Sodium di-2-ethylhexyl sulfosuccinate Sodium formaldehyde bisulfite Sodium-N-methyl-N-oleyl taurate Stearic acid salts: Aluminum stearates: Aluminum distearate Aluminum monostearate Aluminum tristearate Ammonium stearate Barium stearate Cadmium stearate Calcium stearate Cobalt stearate Lead stearate Lead stearate, dibasic Lithium stearate Magnesium stearate Potassium stearate Sodium stearate Strontium stearate Zinc stearate Tartaric acid salts: Potassium sodium tartrate All other salts of organic acids Aldehydes: Acetaldehyde Acroiein (Acrylaidehyde) Butyraidehyde Crotonaldehyde 2-Ethyihexanal (a-Ethylcaproaldehyde Formaldehyde (37% HCHO by weight)

No No No Yes

WPG. EK. WPG.

Yes No Yes No Yes Yes Yes

MAL, NOC, NOD, SYP. MAL, NOD, SYP. MAL, NOC, NOD, SYP, WTC, ( 2 ). WPG. ALI, NOC, NOD, SYP, VNC, WTC. SYP, VNC, WTC. FER, MAL, NOC, NOD, SQA, SYP, WTC. MCI, SHP. ALI. ALI. NOC, WTC. ALI, MAL, NOD, SYP, WTC. WTC. WTC. WTC. CCC, MAL, NOC, NOD, PLS, SYP, WTC.

No No No No Yes No No No Yes

No No Yes No No Yes No No Yes

Glutaraidehyde No Glyoxal No Isobutyraldehyde No Isopentaldehyde, mixed isomers No Propionaidehyde Yes Succinaldehyde-sodium bisulfite complex No Valeraldehyde (Pentanal) No All other aldehydes, acyclic No Ketones: Yes Acetone: Acetone from cumene Yes Acetone from isopropyl alcohol No Acetone, crude No 5-Chloro-2-pentanone No 1-Chloropinacolone No Chloro-2-propanone (Chioroacetone) No Diisopropyl ketone (2,4-Dimethy1-3-pentanone) No 2-Heptanone (Methyl amyl ketone) No 3-Heptanone (Ethyl butyl ketone) No 4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) No Isovalerone (Dilsobutyl ketone) No Methyl ethyl ketone Yes 5-Methyl-2-hexanone (Methyl isoamyl ketone) No Methylhexyl ketone No Methyl isobutyl ketone (4-Methyl-2-pentanone) Yes See footnotes at end of table.

15 22 -

PFZ. EK, EKX, FER, PFN, TCH. EKX, HCL, UCC. UCC. BAS, EKX, HCL, UCC. EKT. EKX, UCC. BOR, CBD, DUP, GAF, GP, HCL, HPC, IMC, MON, PKI, RCI, WCL. UCC. ACY. BAS, EKX, HCL, TU, UCC. UCC. EKX, HCL, UCC. EK. UCC. UCC. ACS, ART, BTL, GGC, SHC. GE, SHC, UCC. ATR. SDW. CHG. MRK. EKX. EKT. UCC. HCL, SHC, UCC. EKT, UCC. ATR, ENJ, HCL, LYP, SHC. EKT. UPM. EKT, ENJ, SHC, UCC.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued

Ketones—Continued 4-Methyl-3-penten-2-one (Mesityl oxide) Methylpseudoionone 2-Octanone (Hexyl methyl ketone) 2,4-Pentanedione (Acetylacetone) 3-Pentanone (Diethyl ketone) Pseudoionone 2,6,8-Trimethyl-4-nonanone (Isobutyl heptyl ketone) All other ketones Alcohols, monohydric, unsubstituted: Alcohols, C I , or lower, unmixed (95% or more pure): Ally, alcohol Amyl alcohols: Amyl alcohol, primary 2-Methyl-1-butanol 3-Methyl-1-butanol 1-Pentanol Butyl alcohols n-Butyl alcohol (n-Propylcarbinol)

No No No No No No No No Yes Yes No No No No No Yes Yes

FMC. UCC. UCC. CPS. UCC.

No No No No No Yes No No No

BAS, CXI, EKX, GAF, HCL, SHC, UCC, VST. ENJ, GAF, SHC. ATR, CXI. BAS, CPS, EKX, HCL, SHC, UCC. TNA, VST. UCC. ENJ. DOW, EKX, HCL, NWP, SHC, UCC. BAS, EKX, SHC, TU, UCC. EKX. TNA, VST. ENJ. ENJ. ENJ, SHC. SHX. ENJ. ATR, CXI, ENJ, LYP, SHC, UCC. AIP, BOR, DUP, EKT, GGC, HCL, LYP, TX. UCC. UCC. UCC. TNA, VST. WTH. EKX, HCL, UCC. GAF. BAS, ENJ. SHC, UCC.

Yes No No No Yes No No No No No

TNA, VST. PG, UCC, VST. SCP. PG, TNA, UCC, VST. SHX. VST. ENJ. UCC. ENJ.

sec-Butyl alcohol (Methylethylcarbinol) tert-Butyl alcohol (Trimethylcarbinol) Isobutyl alcohol (Isopropylcarbinol) 1-Decanol Diisobutyl alcohol 2,2-Dimethylbutanol (Isohexyl alcohol) Ethyl alcohol, synthetic only

No No Yes No No No Yes

2-Ethyl-1-hexanol n-Heptyl alcohol n-Hexyl alcohol sodecyl alcohol soheptyl alcohol sononyl alcohol so-octadecyl alcohol so-octyl alcohol sopropyl alcohol Methanol, synthetic only

Yes No No No No No No No Yes Yes

Methyl amyl alcohol 2-Methyl-1-pentanol 4-Methyl-2-pentanol (1-Methyllsobutylcarbinol) 1-Octanol 2-Octanol (sec-Capryl alcohol) Propyl alcohol (Propanol) 2-Propyl-1-ol (Propargyl alcohol) Undecanol (Linear C,, alcohol) All other alcohols, C I , or lower, unmixed Alcohols C12 or higher, unmixed (95% or more pure): Dodecyl alcohol (Lauryl alcohol) 1-Hexadecanol (Cetyl alcohol) 2-Hexyl-1-decanol 1-Octadecanol (Stearyl alcohol) cis-9-Octadecen-1-ol (Oleyl alcohol) 1-Tetradecanol (Myristyl alcohol) 1-Tridecanol 2,6,8-Trimethy1-4-nonanol All other alcohols, C12 or higher, unmixed

UCC. NCI. WTH. UCC. EKT, HEX, ORT, UCC. NCI, SCM. UCC. COC.

See footnotes at end of table.

15-23

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, Identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics 1

Manufacturers' Identification codes (according to list in table 47)

Acyclic—Continued

Alcohols, monohydric, unsubstituted—Continued Mixtures of alcohols: Alcohol mixtures, C 11 or lower only Alcohol mixtures, C12 through Cie only Alcohol mixtures, C19 and C20 only All other mixtures of alcohols Esters of monohydric alcohols: C12-C 15 Alcohol esters of lactic acid Ally' methacrylate Amyl acetates: Amyl acetate (n-Pentyl acetate) All other amyl acetates Butyl acetates: n-Butyl acetate Isobutyl acetate Butyl acrylate n-Butyl chlorocrotonate sec-Butyl chloroformate Buty lactate Buty levulinate Buty maleate Buty mercaptopropionate Buty methacrylate Buty oleate Cetyleicosyl methacrylate Cetyl lactate Diallyl maleate Dibutyl fumarate Dibutyl maleate Diethyl carbonate (Ethyl carbonate) DI(2-ethyl-1-hexyl) maleate Di (2-ethyl- 1 -hexyl) peroxydicarbonate Diethyl maleate Diethyl oxalate (Ethyl oxalate) Dilaury1-3 , 3' -thiodipropionate Dimethyl carbonate Dimethyl maleate Dimyristy1-3, 3' -thiodiproplonate Dioctyl maleate Disteary1-3,3'-thiodipropionate Dithiobis(stearyl propionate) Ditridecyl maleate Di (tridecyI)-3 , 3' -thiodipropionate Dodecylpentadecyl methacrylate Dodecyl succinic lactate 2-Ethoxyethyl acetate Ethyl acetate Ethyl acetoacetate Ethyl acrylate Ethyl chloroformate Ethyl chlorothiolformate Ethylene carbonate Ethyl-3-ethoxy propionate 2-Ethyl-1-hexyl acetate 2-Ethyl-1-hexyl acrylate 2-Ethylhexyl chloroformate 2-Ethyl-1-hexyl methacrylate See foonotes at end of table.

15-24

Yes Yes

BAS, EKX, ENJ, NCI, PG, SHC, TNA, UCC, VST. PG, SHC, SHX, TNA, VST. TNA. ENJ, SCP, VST, WTK.

Yes No No Yes No Yes

VND. AAC, BRD, CPS.

No No

UCC. WTL.

Yes Yes Yes No No No No No No No No No No No No No No Yes No No No Yes No No No Yes Yes No No No No No Yes Yes No Yes No No No No No No No No

BAS, EKT, HCL, UCC. BAS, EKT, EKX, HCL, UCC. BAS, HCL, RH, UCC. MAL. PPG, VCM. CPS. SOM. TCH. EVN. DUP, RH. ELC. RH. VND. AAC, FMC. RCI. ART, NOD, RCI. PPG. CCC, CHP, FTX, RPC. WTL. ACY. TLI, ( 2 ) . CCW, EVN, WTC. PPG. AAC. CCW. ART, NOD, RCI. CCW, EVN, WTC. EVN. EFH. EVN, WTC. RH. SM. EKT, ICI, UCC. EKT, EKX, HCL, MON. EKT. HCL, RH, UCC. ESX, PPG. ICI. TX. UCC. EKT, MRF. BAS, HCL. PPG, UCC, VCM. DUP.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

No

UCC.

Yes No No No No No No No No No No No No No No Yes Yes

CAS, UCC. WTC. WTC. SBC. SCP, VND. VND. UCC. UCC. FER. CHL, FER. CAS, WTH. SYL. HRT. CHL, WTC. CAS, CYL(E), SBC, VND. HCL, RPC, SCP.

Acyclic—Continued Esters of monohydric alcohols—Continued Ethyl sulfate (Diethyl sulfate) Fatty acid esters, not included with plasticizers or surface active agents: Butyl myristate Diglycol dimerate Dioctyl dimerate Docosanyl docosenoate Isocetyl stearate Isopropyl linoleate Isopropyl myristate Isopropyl palmitate Methyl esters of lard Methyl esters of tallow Methyl 12-hydroxystearate Methyl iso-octadecenoate Methyl linoleate Methyl stearate Myristyl myristate Tridecyl stearate All other fatty acid esters, not included with plasticizers surface-active agents Hexyl acetate Hexyl acrylate sobutyl acrylate sobutyl chloroformate sobutyl isobutyrate sobutyl methacrylate sodecyl acrylate sodecyl mercaptoacetate sodecyl methacrylate so-octyl mercaptoacetate so-octyl-3-mercaptopropionate sopropyl acetate sopropyl chloroformate sostearyl neopentanoate Lauryl acrylate Lauryl lactate Lauryl methacrylate 2-Methoxyethyl acrylate Methy acetoacetate Methy acrylate, monomer Methy chloroformate Methy formate Methy isodehydroacetate Methy methacrylate, monomer Methy sulfate (Dimethyl sulfate) Myristyl lactate Octadecyl-3-mercaptopropionate Phosphorus acid esters: Amyl hydrogen phosphate Bis (2-Chloroethyl)-2-chloroethylphosphonate Bis(2-ethylhexyl) hydrogen phosphate Butyl acid phosphate Chloroalkyl diphosphate ester, neutral Dibutyl butylphosphonate Dibutyl hydrogen phosphite Dibutyl pyrophosphate

No No No No No No No No No No No No Yes No No No No No No No No No No No Yes No No No Yes No No No No No No No No

HDG, HPC, SBC. ENJ. CPS. BAS. VCM. EKX. RH. AAC, CPS. EVN. RH. CCW, EVN. EVN. EKT, HCL, UCC. PPG, VCM. SBC, VND. CPS. VND. AAC, CPS, RH. CPS. EKT. HCL. PPG. HCL. EKT. CYR, DUP, RH. DUP. VND. EVN. HK. ALW. ALW. ALW, HK. ALW. ALW, HDG. ALW. ALW.

See footnotes at end of table.

15-25

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued

Esters of monohydric alcohols—Continued Phosphorus acid esters—Continued Diethylhexyl phosphoric acid Diethyl hydrogen phosphite Diethyl phosphenothlonic dichloride Diethyl phosphorochloridothionate Dimethyl hydrogen phosphite Dimethyl methylphosphonate Dimethyl phosphoridothionate 2-Ethylhexyl hydrogen phosphate lso-octyl hydrogen phosphate Methyl dihydrogen phosphate Mixed dialkyl hydrogen phosphates, amine salts Stearyl acid phosphate Tetrakis(2-chloroethyl)ethylene diphosphate Tetrakis(2-chlorolsopropyl)ethylene diphosphate (T-RDT) Trialkyl phosphite Triakyl thiophosphite Tributyl phosphate Triethyl phosphite Trilso-octyl phosphite Tr'isopropyl phosphite Trimethyl phosphite Tris (2-chloroethyl ) phosphite Tris(chlorolsopropyl)thionophosphate Tris(2-ethylhexyl) phosphite All other phosphorus acid esters Propyl acetate n-Propyl chioroformate Stearyl methacryiate Tetraethyl orthosilicate (Tetraethyl silicate) Tetraethyl silicate, condensed Tetrapropyl silicate Titanic acid esters: Bis (2- [bis (2-hydroxyethyl) amino] ethyl) diisopropyl titanate DI(hydroxy)bis(ammoniumlactato)titanium Diisopropyltitanate bis(ethy1-3-oxobutanoate) Tetrabutyl titanate Tetraisopropyl titanate Tetrakis (2-ethylhexyl) titanate Triethanolamine titanate All other titanic acid esters Triethyl citrate Triethyl orthoacetate Triethyl orthoformate Triethyl orthopropionate Trifluoroethyl methacryiate Trimethyl orthoformate Tristearyl citrate Vinyl acetate, monomer All other monohydric alcohol esters Polyhydric alcohols: 2 ,2-Bis (bromomethyl) -1, 3-propanediol 1 ,2 (and 1 ,3)-Butanediol 1,4-Butanediol

Yes No No Yes

See footnotes at end of table.

15-26

No No No No No No No No No No No No No

ALW. ALW. TNA. ICI, TNA. ALW. ALW, HDG. ICI. ALW. ALW. HK. ELC. HK. OMC.

No No No No No No No No No No No No Yes No No No No No

OMC. MCB. MCB. FMC. ALW, ICI. ALW, MCB. ALW. ALW, ICI. ALW. GAF. ALW. ALW, AZT, COC, PAH, ( 2). BAS, EKT, HCL, UCC. VCM. CPS, RH, TX. KF, UCC. UCC. KF.

No No No No No No No No No No No No No No No Yes No

DUP. DUP. DUP. DUP. DUP. DUP. KF. BUC, DUP. (2). KF. KF. KF. (2). KF. CYL(E). DUP, FER, HCL, NWP, PLC, UCC. COC, EK, EKT, ENJ, MON, PIC, REZ ( 2). DOW. HCL. BAS, DUP, GAF, ( 2).

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

No No

GAF. BAS, GAF.

No

No

DIX, EVN. BAS, EKX. BAS, CNE, CXI, DOW, EKX, HCF, HCL, ICI, NWP, OMC, PDG, PLC, PPG, SHC, TX, UCC. UCC.

No No No

HCL. DOW, SYP. BAS, CXI.

No No No No Yes No Yes No No No

IMC. ICI. EVN. SHC, UCC. DOW, HCL, HPC, IMC, PST. BAS. ATR, CXI, DOW, OMC, TX, UCC. EHC, ICI, PFZ. EKX. ICI, PAH, VIK, ( 2).

Yes No Yes No

EKT, ICI, UCC. EKT, ICI, UCC. USB.

No No No No No No No No No No No No No No No No No No No No No No No No No No No No

USB. CMB, HAL. OMC. PPG. CPS. EKT. EKT. CPS, WTC. EVN. CPS. CCA. REZ. HAL. HAL. EVN, WTC. EKT. REZ. DOW, RH. AAC, RH. DOW, RH. AAC, REZ, RH. UCC. EKX. BRD. REZ. EVN. SQA. REZ.

Acyclic—Continued

Polyhydric alcohols—Continued 2-Butene-1 ,4-diol 2-Butyne-1 ,4-diol 3-Chloro-1,2-propanediol (Glycerol a-chlorohydrin) 2, 2-Dimethy1-1 ,3-propanediol (Neopentyl glycol) Ethylene glycol 2-Ethyl-1 ,3-hexanediol 2-Ethyl-2-(hydroxymethyl) -1 ,3-propanediol (Trimethylolpropane) Glycerol, synthetic only 1 ,6-Hexanediol 2-(Hydroxymethyl)-2-methy1-1,3-propanediol (Trimethylolethane) Mannitol 3-Mercapto-1,2-propanediol (Thloglycerol) 2-Methyl-2,4-pentanediol (Hexylene glycol) Pentaerythritol 1,5-Pentanediol Propylene glycol (1,2-Propanediol) Sorbitol (70% by weight) 2 ,2 ,4-TrImethyl-1 ,3-pentanediol All other polyhydric alcohols Esters and ethers of polyhydric alcohols: Polyhydric alcohol esters: 2-(2-Butoxyethoxy)ethyl acetate 2-Butoxyethyl acetate 1,3-Butylene glycol diborate 1,3-Butylene glycol diborate/hexylene glycol boric anhydride Diethylene glycol adipate Diethylene glycol, borated Diethylene glycol chloroformate Diethylene glycol dimethacrylate 2-(2-Ethoxyethoxy)ethyl acetate Ethylene glycol diacetate Ethylene glycol diacrylate Ethylene glycol dimercaptoacetate Ethylene glycol dimethacrylate Ethylene glycol hydroxyacetate Glycerol propoxylate trlacrylate Glyceryl diacetate (Diacetin) Glyceryl monoacetate (Monacetin) Glyceryl monothioglycolate Glyceryl triacetate (Triacetin) 1,6-Hexanediol diacrylate Hydroxyethyl acrylate Hydroxyethyl methacrylate Hydroxypropyl acrylate Hydroxypropyl methacrylate 2-Methoxyethyl acetate 1-Methoxy-2-propyi acetate Pentaerythritol stearate Pentaerythritol tetraacrylate Pentaerythritol tetrakls(3-Mercaptoproplonate) Polyol aluminum chelate Tetraethylene glycol diacrylate

No Yes

See footnotes at end of table.

15-27

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Esters and ethers of polyhydric alcohols—Continued Polyhydric alcohol esters—Continued Trimethylolpropane ethoxylate triacrylate No Trimethylolpropane triacrylate No Trimethylolpropane tri(2-mercaptopropionate) No Trimethylolpropane trioleate (TMP trioleate) No 2,2,3-Trimethy1-1,3-pentanediol monoisobutyrate No Tripropylene glycol diacrylate No All other polyhydric alcohol esters No Polyhydric alcohol ethers: Yes Bis(2-butoxyethyl)ether (Diethylene glycol di-nbutyl ether) No Bis(2-ethoxyethyl)ether (Diethylene glycol diethyl ether) No Bis[2-(2-methoxyethoxy)ethyll ether (Tetraethylene glycol dimethyl ether) No Bis(2-methoxyethyl)ether (Diethylene glycol dimethyl ether) No 2-Butoxyethanol (Ethylene glycol monobutyl ether) Yes 2-(2-Butoxyethoxy)ethanol (Diethylene glycol monobutyl ether) 2- [2- (2-Butoxyethoxy) ethoxy] ethanol (Triethylene glycol monobutyl ether) 1-Butoxyethoxy-2-propanol Butyl ethers of tetra- and higher ethylene glycols (high boiling) i-Butyraldehyde trimer Diethylene glycol

15 28 -

ASL, FER. ASL, FER. ASL, FER. ASL, FER. CNE, DOW, EKX, ICI, OMC, SHC, UCC.

Yes

DOW, EKX, ICI, OMC, SHC, UCC.

Yes No

CXI, DOW, OMC, UCC. UCC.

No No Yes

EKX, ICI. HTM. BAS, CNE, CXI, EKX, HCL, ICI, NWP, OMC, PDG, PPG, SHC, TX, UCC. GAF. EKX.

Diethylene glycol divinyl ether No Diethylene glycol mono-n-propyl ether No Dimethoxyethane (Ethylene glycol dimethyl ether) No Dipropylene glycol Yes Dipropylene glycol monomethyl ether No 2-Ethoxyethanol (Ethylene glycol monoethyl ether) No 2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl ether) Yes 2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol monoethyl ether) No Ethylene glycol di-tributyl ether No Ethylene glycol di-tri-ethyl ether No Ethyl ethers of tetra- and higher ethylene glycols (high boiling) No 2-[2-(Hexyloxy)ethoxy]ethanol No 2-Methoxyethanol (Ethylene glycol monomethyl ether) Yes 2-(2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl ether) Yes 2- (2- (2-Methoxyethoxy) ethoxy] ethanol. (Triethylene glycol monomethyl ether) Yes 2-(2-Methoxyethoxy)ethy1-2-methoxyethyl ether (Triethylene glycol dimethyl ether) No Methoxypolyethylene glycol No 1-Methoxy-2-propanol No Methoxypropyl acetate No Paraformaldehyde No Polyethoxy propoxydiethylene glycol ether No See footnotes at end of table.

AAC, REZ. AAC, REZ, SM. EVN. EFH. EKX. AAC, REZ. BRD, SHX, SQA, UCC, ( 2 ).

ASL, FER. ATR, DOW, UCC. OMC. EKX, ICI, OMC, UCC. DOW, EKX, ICI, OMC, UCC. DOW, OMC, UCC. EKX. EKX. EKX, ICI, OMC. UCC. ICI, OMC, UCC. DOW, ICI, OMC, UCC. DOW, OMC, UCC. ASL, FER, OMC. HCL, ICI, UCC. OMC. HTM. HCL. TX.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

No Yes

(2) . ABB, CNE, DOW, GAF, HCL, HDG, ICI, OMC, UCC, ( 2 ), ( 2 ). ICI. FER, SHX, ( 2 ).

Acyclic—Continued

Esters and ethers of polyhydric alcohols—Continued Polyhydric alcohol ethers—Continued Poly(ethylene-butylene) glycol Polyethylene glycol Polyethylene glycol butyl ether, propoxylated Polyethylene glycol dimethyl ether Polyglycols, ethylene glycol, and glycol ether, mixed Polymethylvinyl ether monoethylmaleate Polyoxyalkylene glycol Polyoxypropylene polyoxyethylene glycol, mixed Poly(propoxy)butyl ether, ethoxylated Polypropylene glycol Polytetramethylene glycol ether Propoxyethanol (Ethylene glycol monopropyl ether) Propylene glycol, mixed ethers Sorbitol, alkoxylated Sorbitol, ethoxylated Sorbitol monooleate Sorbitol monostearate Sorbitol, propoxylated Tetraethylene glycol 2,2'-Thlodiethanol (Thiodiglycol) Triethylene glycol Tripropylene glycol Tripropylene glycol monomethyl ether Trl- and tetraethylene glycol monoethyl ethers, borate esters All other polyhydric alcohol ethers Brominated, chlorinated, and fluorinated hydrocarbons: Brominated (including bromochlorinated) hydrocarbons: 1-Bromobutane (n-Butyl bromide) Bromochloromethane Bromoethane (Ethyl bromide) 1-Bromohexadecane 1-Bromohexane (n-Hexyl bromide) 1-Bromo-2-methyl-2-butene 1-Bromo-octadecane 1-Bromopentane (n-Amyl bromide) 2-Bromopropane (Isopropyl bromide) Ethylene bis tetrabrom 1, 1,2 ,2-Tetrabromoethane (Acetylene tetrabromide) Vinyl bromide (Bromoethylene) All other brominated (including bromochlorinated) hydrocarbons Chlorinated (Not otherwise halogenated) hydrocarbons: Carbon tetrachloride Chlorinated paraffins (C10 -C30): Chlorinated paraffins, 35-64% chlorine Chlorinated paraffins, less than 35% chlorine Chlorinated paraffins, 65% or more chlorine 1-Chlorobutane (n-Butyl chloride) Chloroform Chloromethane (Methyl chloride)

No No No No No No No No No No No No No No No No Yes No Yes No No No No Yes

CXI, HCL, UCC, ( 2). TNI. OMC. UCC. TX. CXI, DOW, GAF, HCL, HDG, OMC, TX, ( 2 ). DUP, GAF, QKO. EKX. UCC. (2) . BRD, ICI. WTC. WTC. ICI. CNE, CXI, DOW, EKX, ICI, UCC. AAC, PLC. CNE, CXI, DOW, EKX, HCL, ICI, OMC, PDG, PPG, SHC, TX, UCC. DOW. OMC, UCC. OMC. CXI, DUP, MIL, OMC, UCC.

Yes No No No No No No No No No No

DAZ. DOW. DOW, GTL. HMY. WCC. SD. HMY. WCC. WCC. TNA.

No No

DOW. TNA.

No

COC, FER, HMY, TNA, WTC.

Yes Yes

DOW, FRO, HK, LCP, SFI.

Yes No Yes No Yes Yes

DVC, FER, HK, NEV, WTC. DVC, FER, SHC. DVC, FER, HK, NEV. UCC. DOW, FRO, HK, LCP. DCC, DOW, LCP, SPD, TNA, VST.

See footnotes at end of table.

15-29

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Brominated, chlorinated, and fluorinated hydrocarbons— Continued Chlorinated (Not otherwise halogenated) hydrocarbons—Continued 3-Chloro-2-methyl-1-propene (Methallyl chloride) 3-Chloropropene (Ally! chloride) 1,2-Dichloroethane (Ethylene dichloride) 1,2-Dichloropropane (Propylene dichloride) 2,3-Dichloropropene Ethyl chloride (Chloroethane) Hexyl chloride Lauryl chlorides Methylene chloride (Dichloromethane) Neophyl chloride t-Octyl chloride Octyl chloride Paraffin oils, chlorinated Perchloroethylene (Tetrachloroethylene) 1,1,1-Trichloroethane (Methyl chloroform) 1, 1,2-TrIchloroethane (Vinyl trichloride) Trichloroethylene 1 ,2 ,3-Trichloropropene Vinyl chloride, monomer (Chloroethylene) Vinylidene chloride, monomer (1,1-Dichloroethylene) All other chlorinated (not otherwise halogenated) hydrocarbons Fluorinated (Including other fluorohalogenated) hydrocarbons: Bromochlorodifluoromethane 2-Bromo-2-chloro-1,1,1-trifluoroethane Bromotrifluoromethane 1-Chloro-1,1-difluoroethane Chlorodifluoromethane (F22) Chlorotrifluoroethylene (Trifluorovinyi chloride) Chlorotrifluoromethane Dibromodifluoromethane Dichiorodifluoromethane (F12) Dichlorotetrafluoroethane 1,1-Difluoroethane Hexafluoropropylene, monomer 1-lodoperfiuorohexane Polyhexafluoropropylene oxide Polytetrafluoroethylene ethyl iodide Tetrafluoroethylene, monomer Tetrafluoromethane Trichiorofluoromethane (F11) Trichlorotrifluoroethane Trifluoropropene Vinyl fluoride, monomer Vinylidene fluoride, monomer All other fluorinated (including other fluorohalogenated) hydrocarbons Other miscellaneous acyclic chemicals: Iodinated (not otherwise halogenated) hydrocarbons: Diiodomethane (Methylene Iodide) lodobutane See footnotes at end of table.

15-30

No No Yes No No Yes No No Yes No No No No Yes Yes No No No Yes

FMC. SHC. BFG, DOW, FOR, FRO, GGC, HK, LYP, OMC, PPG, SHC, VST. DOW, OMC. DOW. DUP, PPG, TNA. TNA. SHC, TNA. DOW, FRO, HK, LCP. TNA. RBC. TNA. BAS. DOW, FRO, HK, PPG. DOW, FRO, PPG. DOW. DOW, PPG. DOW. BFG, BOR, DOW, FOR, GGC, PPG, SHC, VST.

No

DOW, PPG.

No

COC, WTC, (2 ).

Yes No No No No Yes No No No Yes No No No No No No No No Yes No No No No

ICI. HOC. DUP, GTL. PAS. ACS, DUP, PAS, RCN. ACS. DUP. GTL. ACS, DUP, PAS, RCN. ACS, DUP. DUP, PAS. DUP. DUP. DUP. (2). DUP, ICI. DUP. ACS, DUP, PAS, RCN. ACS, DUP, PAS. HOC. DUP. PAS.

No Yes No No No

DUP, HOC, OH, REG.

DPW, ( 2). RSA.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics 1

Manufacturers' identification codes (according to list in table 47)

No No

DPW, RSA. DPW, RSA.

No

COC, DPW, EK, RSA.

No No No No

EK. SHP. KF. SHP.

No No No No Yes No No No Yes No No Yes No No No No No No Yes No No No No No No

MCK. MCK. MCK. MCK.

Acyctic—Continued

Other miscellaneous acyclic chemicals—Continued Iodinated (not otherwise halogenated) halogenated)— Continued lodoethane (Ethyl iodide), non-medical lodomethane (Methyl iodide) All other iodinated (not otherwise halogenated) hydrocarbons Acetylacetonates: Acetone sodium bisulfite Cobaltic acetylacetonate Titanium acetylacetonate All other acetylacetonates Acetylacetonates complex: Chromium acetylacetonate complex Iron acetylacetonate complex Manganese acetylacetonate complex Zirconium acetylacetonate complex Acyclic peroxides: Acetylacetone peroxide Acetyl peroxide tert-Amyl hydroperoxIde 2-Butanone peroxide n-Butyl-4,4-bis[t-butylperoxy]valerate tert-Buty hydroperoxide tert-Buty peroxide (Di-tert-butyl peroxide) tert-Buty peroxyacetate tert-Buty peroxy-2-ethylhexanoate tert-Buty peroxylsobutyrate tert-Buty peroxylsopropylcarbonate tert-Buty peroxyneodecanoate tert-Buty peroxyneoheptanoate tert-Buty peroxypivalate Decanoyi peroxide DI-(2-ethylhexyl)peroxydicarbonate Dilsononanoyi peroxide 2,5-Dimethy1-2,5-di(tert-butylperoxy)hexane 2,5-Dimethy1-2,5-di(tert-butylperoxy)hexyne-3 2,5-Dimethy1-2,5-dihydroperoxy) hexane 2,5-Dimethy1-2,5-di(2-ethylhexanoyl peroxy) hexane Diperoxydodecanedioic acid Di-n-propyl peroxydicarbonate Ethyl 3,3-di(t-butyl peroxy) butyrate Lauroyl peroxide Peroxyacetic acid (Peracetic acid) Succinyl peroxide Tertiary amyl per-2-ethylhexanoate All other acyclic peroxides 1-Butanesulfonyl chloride 2-Butenedioic acid(e)-linoleic acid, reaction product Carbon disulfide 2,3-Dibromopropanol Epoxides, ethers, and acetals: Bis(2-chloroethyl)ether (Dichiorodiethyl ether) Butylene oxide Butyl vinyl ether Chioromethyl methyl ether 2,2-Dichloro-1,1-difluoroethyl methyl ether Diethoxyethane

No No No No No No No No No No No No No Yes No No No No No No

CAD. WTL. WTC. CAD, FRE, NOC, RCI, WTC, WTL. WTL. ATR, AZT, FRE, WTL. AZT, WTC, WTL. AZT, WTL. WTC, WTL. WTL. PPG, WTL. WTC, WTL. WTC. AZT, WTC, WTL. WTL. WTC, WTL. WLT. WTL. WTL. WTC. WTC, WTL. MMC. WTL. WTL. WTL. FMB, FMC, UCC. WTL. WTC. PLC, WTC. EKT. WVA. PAS. GTL. BKM. DOW. ATR, GAF. RH. OH. FER, WPG.

See footnotes at end of table.

15-31

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acycllc chemicals

Separate statistics

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Other miscellaneous acylic chemicals—Continued Epoxides, ethers, and acetals—Continued Dimethyl sulfone Epichlorohydrin 1 ,2-Ethanedithiol Ethylene oxide Ethyl ether, absolute 2-(Ethylmercapto)ethanol Ethyl vinyl ether Glycidol (2,3-Epoxy-1-propanol) Glycidyl ethers: Alkyl glycidyl ethers, Ce-Clo Alkyl glycidyl ethers, C12 -C14 Allyl glycidyl ether (Allyloxy-2,3-epoxy propane) 1,4-Butanediol diglycidyl ether 1-Butoxy-2,3-epoxypropane (Butyl glycidyi ether) tert-Butyl glycidyi ether Castor oil triglycidyl ether 2-Ethylhexyl glycidyl ether neoPentyl glycol diglycidyl ether Polyol glycidyl ether All other glycidyl ethers Isopropyl ether Malonaldehyde bis(dimethyl) acetal Methylal (Dimethoxymethane) Methyl ether (Dimethyl ether) Methyl vinyl ether Propylene oxide All other epoxides, ethers, acetals Fats and oils, chemically modified: Castor oil, hydrogenated Castor oil, polymerized Chlorinated fatty materials Hydrogenated menhaden fish oil Hydrogenated tallow glycerides Linseed oil, oxygenated Sulfurized corn oil Vegetable glycerides, hydrogenated All other fats and oils, chemically modified Glutaraldehyde bis(sodium blsulfite) Hexadecylsulfonyl chloride Hydrocarbons: n-Decane 3,3-DImethylbutene n-Dodecane Hexadecane Myrcene n-Nonane n-Octadecane n-Octane n-Tetradecane All other hydrocarbons 2-Mercaptoethanol Methyl sulfide (Dimethyl sulfide) Methyl sulfone (Dimethyl sulfone) Methyl sulfoxide (Dimethyl sulfoxide) See footnotes at end of table.

15-32

No No No Yes

CRZ. DOW, SHC. RBC. BAS, CNE, DOW, EKX, HCL, ICI, NWP, PPG, SHC, SNO, TX, UCC. EKX, NWP. DOM. GAF. DIX.

No No No No Yes No No

AZS, WLN. REZ, WLN.

No No

AAC, CPS. ALD, REZ, WLN.

Yes No No No No No No No No No No No No No Yes No No No No No No No No No No No Yes No No No No No No No No No No No No No No

AAC, CPS, REZ, WLN. AAC. WLN. WLN. WLN. REZ, WLN. REZ. ENJ, SHC. KF. HCL. AIP, DUP. GAF, UCC. ATR, DOW. UCC, VIK. CAS. CAS. FER. CHL, WTC. CHL, WTC. CJO. SM. BRD, WTC. CAS, UCC. EK, FMT. EKT. HMY, PLC. PLC. HMY. HMY. SCM, ( 2 ). HMY, PLC. HMY. HMY, PLC. HMY. DUP, WTK. AAC, PLC. GAY. GAY. GAY.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics 1

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued

Other miscellaneous acylic chemicals—Continued Octadecanoic acid, 2-(1-carboxyethoxy)1-methy1-2-oxoethyl ester, sodium salt Organo-aluminum compounds: Aluminum acetylacetonate complex Aluminum di-sec-butoxide acetoacetic ester chelate Aluminum diisopropoxide acetoacetic ester chelate Aluminum ethyl-3-oxobutanoato-0 1 , 03 -dihydroxy T-4 Aluminum Isopropoxide Aluminum, oxo(2-propanolato) Aluminum tri-sec-butoxide Diethylaluminum chloride Dlethylaiuminum ethoxide Diethylaiuminum iodide Dlisobutylaluminum chloride Dilsobutylaluminum hydride Ethylaluminum dichloride Ethylaluminum sesquichlorlde Isobutylaluminum chloride Isopropenylaluminum Oxy-aluminum octanoate Sodium dihydrobis(2-methoxyethoxy)aluminum hydride Tri-n-butyl aluminum Triethylaluminum Tri-n-hexyl aluminum Trilsobutylaluminum Trimethylaluminum Tri-n-octylaluminum Tri-oxyaluminum tri-isopropoxide All other organo-aluminum compounds Organo-boron compounds: N-Methyl-methanamine with borane (1:1) 2-Methyl-2-propanamine with borane (1:1) Mixed alcohol borates Triethylborane Triethyl borate Triethyl boron Trimethoxyboroxine N,N,N-Trimethyl methanaminium octahydrotriborate All other organo-boron compounds Organo-lithium compounds: n-Butyllithium sec-Butyllithium Lithium hydroxystearate Organo-magnesium compounds: Butyl ethyl magnesium Di-n-butyl magnesium Di-n-hexyl magnesium Ethylmagnesium bromide Magnesium methylate Methylmagnesium bromide Methylmagnesium chloride Organo-silicon compounds: N-Aminoethylaminopropyl trimethoxysilane a-Chloropropyltrichlorosilane Chloropropyltrimethoxysilane Chlorotrimethylsilane Cyclohexylmethyl dimethoxy silane

No

WTC.

Yes No

MCK.

No

CHT.

No

CHT, KCH.

No No No No No No No No No No No No No No

CHT. CHT, KCH. KCH. CHT. TNA, TSA. TSA. TNA, TSA. TNA, TSA. TNA, TSA. TNA, TSA. TNA, TSA. TSA. TSA. CHT, KCH.

No No No No No No No No No No No No No No No No No

HXL. TNA, TSA. TNA, TSA. TNA, TSA. TNA, TSA. TNA. TNA, TSA. CHT. KCH, MCB, TNA, TSA,

( 2 ). (2). (2). ADC. TSA. ( 2 ).

No No

( 2). HCL, MHI.

No No No

FTE. FTE. WTC.

No No No No No No No Yes No No Yes No No

TSA. TSA. TSA. ARA. SOI. ARA. ARA.

(2).

KF. DCC. DCC, KF, UCC. DCC, UCC. (2).

See footnotes at end of table.

15-33

Section 15 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics 1

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued

Other miscellaneous acylic chemicals—Continued Organo-silicon compounds—Continued DIchlorodimethylsilane Dichloromethylsilane DichloromethylvInylsilane Dichlorooctamethyl tetraslioxane Divinyl tetramethyidisiloxane a-Glycidoxypropyltrimethoxysilane Hexamethyldisilazane Isobutyltrimethoxysilane Mercaptopropyltrimethoxysilane a-Methacryloxypropyltrimethoxysilane Methyltrimethoxysilane and polymethyltrislioxane Polyoxyalkene silicones Silicone fluids Silicone resins for mold release agents TrIchloromethylsilane Trichloropropylsilane Trichlorovinyisilane (Trimethoxysilyl propyl) didecyl methylammonium chloride Tris(2-methoxyethoxy)vinyl silane Tris (pentamethyldisiloxanyl) -3-methacrylatopropyl silane Vinyltriethoxysilane Vinyltrimethoxy silane All other organo-silicone compounds Organo-tin compounds: Dibutyltin bis(butylmaleate) Dibutyltin bis(isooctylmercaptoacetate) Dibutyltin bis(mercaptolaurate) Dibutyltin dichloride Dibutyltin-1 OTG Dibutyltin oxide Ester tin mercaptoesters Monomethyl tin Octyltin Tin carboxylate Tributyltin fluoride Tributyltin propylene glycol maleate All other organo-tin compounds Organo-zinc compounds: Diethylzinc Zinc acetylacetonate complex Perchloromethanethiol (Perchloromethyl mercaptan) Phosgene (Carbonyl chloride) Pine oil, synthetic Potassium 2-methyl-2-butanol Potassium 2-methyl-2-propanol Sodium ethoxide Sodium methoxide (Sodium methylate) Thioethanol, sodium salt Trifluoroethanol Trimethylsulfonium iodide All other miscellaneous acylic chemicals

See footnotes at end of table.

15-34

No No No No No No No No No No No No Yes No No No No

DCC. DCC, UCC. DCC, UCC. PIC. KF. UCC. KF, SCM. KF. KF, UCC. UCC. DCC, KF, UCC. UCC. DCC, SPD, SWS, UCC. CNI. DCC. DCC. UCC.

No No

(2). KF.

No No No No Yes No No No No No No No No No No No No No

(2). KF, UCC. KF. ARO, KF, SCM, UCC, ( 2 ),( 2). CCA. WTC, ( 2). (2). WTC. WTC. (2). CCA. WTC. CCA, ( 2 ). FER. (2). CCA. CCW, COS, SCM.

No No

TSA. MCK.

No Yes No No No No Yes No No No No

ICI, ( 2). DUP, ICI, MOB, OMC, PPG, VDM. NCI. (2). (2). RBC. HK, OMC, RBC. BAS. HOC. DPW. ABB, AIP, AMD, ANG, ASL, CGY, COC, DPW, DUP, EKT, HPC, NES, NOD, PAH, PIC, RBC, SHX, TCC, TLI, USR, ( 2 ), ( 2 ).

.

Synthetic Organic Chemicals, 1987 Table 46—Continued Miscellaneous chemicals for which U.S. production and/or sales were either reported or estimated, identified by manufacturer, 1987

Miscellaneous cyclic and acyclic chemicals

Separate statistics '

Manufacturers' identification codes (according to list in table 47)

Acyclic—Continued Mixtures not specifically itemized: Alcohols, monohydric, and their esters, Ce and higher, mixed Butyl formcel Celtone Fatty acid residues Gluconic acid and salts, mixed Glycol residues Lanolin alcohol mixtures Methyl formcel Morpholine residue stream Oxidate light ends Oxo process bottoms All other mixtures of miscellaneous chemicals not specifically itemized

Yes No No No No No No No No No No No

EKX, HCL. HCL. DRL, SHX, SYP. PMP. ICI, OMC. UCC. HCL. TX. HCF. CXI.

No

BAS, CGY, CXI, EKT, JSC, MON, NES, PCI, UCC, WAY.

(2 ) .

Chemicals for which separate statistics are reported in this section are indicated by "Yes." Chemicals for which data are accepted in confidence and may not be published are indicated by "No." 2 The manufacturer did not consent to his identification with the designated product. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

15-35 222-174 0 - 88 - 8 : QL 3

Section 15 Table 47 Miscellaneous cyclic and acyclic chemicals:

Code AAC ABB ACS ACY ADC AIP ALD ALI ALW AMB AMD AMO ANG APC ARA ARC ARQ ARS ART ARZ ASH ASL ATL ATR AZS AZT BAS BCC BFG BKC BKM BOC BOR BRD BRI BTL BUC CAD CAS CBD CCA CCC CCW CED CGY CHG CHL CHP CHT CIN CJO CNE CMB CNI CNP

15-36

Directory of manufacturers, alphabetical by code, 1987

Name of company Alcoiac, Inc. Abbott Laboratories Allied Signal Inc., Engineered Material Sector American Cyanamid Co. Anderson Development Co. Air Products & Chemicals, Inc. Aldrich Chemical Co., Inc. Anzon, Inc. Albright & Wilson, Inc. American Bio-Synthetics Corp. Cyclo Products Inc. Amoco Corp. Angus Chemical Co. Apollo Chemicals Corp. Syntex Chemicals, Inc. Akzo Chemie America, Armak Chemicals Arnco Arsynco, Inc. Aristech Chemical Corp. Arizona Chemical Co. Ashland Oil, Inc. Specialtychem Products Corp. Atlantic Industries, Inc. Atlantic Richfield Co., Arco Chemical Co. AZS Corp. Catalyst Resources, Inc. BASF Corp. Buffalo Color Corp. B. F. Goodrich Co. J. T. Baker Chemical Co. Buckman Laboratories, Inc. Biocraft Laboratories, Inc. Borden Inc., Borden Chemical Div. Lonza, Inc. Burlington Industries, Inc. BTL Specialty Resin Corp. Synalloy Corp., Blackman Uhler Chemical Div. Akzo Chemie America, Noury Chemicals Caschem, Inc. Chembond Corp. Interstab Chemicals, Inc. C.N.C. International Inc. Morton-Thiokol, Inc., Carstab Div. Cedar Chemical Co. Ciba-Geigy Corp. Mobay Chemical Corp., Agricultural Chemicals Div. Chemol, Inc. C. H. Patrick & Co., Inc. Chattem, Inc. Stockhausen, Inc. C. J. Osborn Chemicals, Inc. Cain Chemical, Inc. Cambridge Industries Co. Conap, Inc. DSM Chemicals Augusta, Inc.

Code COC COS CPS CRZ CWN CXI CYL CYR DAN DAZ DCC DIX DKA DOM DOW DPW DRL DUP

DVC EFH EHC EK EKT EKX ELC EMR ENJ ESA ESX EVN

FER

FMB FMC FMT FOC

FOR FRE FRO FTE FTX GAF GAY GE GGC

GIV

Name of company Columbia Organic Chemicals Co., Inc. Cosan Chemical Corp. CPS Chemical Co., Inc. James River Corp. Upjohn Co., Fine Chemicals Chemical Exchange Industries, Inc. Cyclo Chemicals Corp. CYRO Industries Dan River Inc., Chemical Products Div. Diaz Chemical Corp. Dow Corning Corp. Dixie Chemical Co., Inc. Denka Chemical Corp. Dominion Products, Inc. Dow Chemical Co. Deepwater, Inc. Unichema Chemicals, Inc. E. I. duPont de Nemours & Co., Inc. Chemicals & Pigments Dept. Polymer Products Dept. Dover Chemical Corp. Sub. of ICC Industries, Inc. E. F. Houghton & Co. Ethichem Corp. Eastman Kodak Co.: Tennessee Eastman Co. Div. Texas Eastman Co. Div. Elco Corp. Sub. of Detrex Chemical Industries, Inc. Quantum Chemical Corp. Exxon Chemical Americas East Shore Chemical Co. Essex Chemical Corp., Essex Industrial Chemicals, Inc. W. R. Grace & Co., Organic Chemicals Div. Evans Chemetics Ferro Corp.: Ferro Chemical Div. Grant Chemical Div. Kell Chemical Div. FMC Corp., Peroxygen Chemicals Div. FMC Corp. Fairmount Chemical Co., Inc. Handschy Industries, Inc., Farac Varnishes Chemicals Formosa Plastics Corporation Louisiana Freeman Chemical Corp. Vulcan Materials Co., Chemicals Div. Foote Mineral Co. Finetex, Inc. GAF Corp., Chemical Group Gaylord Container General Electric Co. Georgia-Gulf Corp.: Boundbrook Div. Plaquemine Div. Givaudan Corp.

Synthetic Organic Chemicals, 1987 Table 47—Continued Miscellaneous cyclic and acyclic chemicals:

Code GP GTL HAL HCC HCF HCL

HCP HDG HEX HFT HK HML HMP HMY HOC HPC HRT HTM HXL ICI

IFF IMC JRC JSC KCH KF KLM KMI LCP LEM LIL LYP MAL MCB MCI MCK MHI MIL MLS MMC MNA MOB MON MRF MRK NCC

Directory of manufacturers, alphabetical by code, 1987

Name of company Georgia-Pacific Corp., Resins Operations Great Lakes Chemical Corp. C. P. Hall Co. Hatco Chemical Corp. Cape Industries Hoechst Celanese Corp: Chemical Group Div. Fibers Div. Sou-Tex Works Honig Chemical & Processing Corp. Hodag Chemical Corp. Hexagon Laboratories, Inc. Syntex Agribusiness, Inc., Nutrition & Chemical Div. Occidential Chemical Corp., & Specialty Chemical Div. Hummel Chemical Co. W. R. Grace & Co., Hampshire Chemicals Div. Humphrey Chemical Co. Halocarbon Products Corp. Hercules, Inc. Hart Products Corp. Haltermann Ltd. Co. Hexcel Corp., Hexcel Chemical Products ICI Americas, Inc • Chemicals Div. Rubicon Inc. International Flavors & Fragrances, Inc. Pitman-Moore Industrial Chemicals Div. Jarchem Industries, Inc. Sybron Chemicals, Inc. Joseph Ayers, Inc. Dynamit Nobel Chemical Div. Kalama Chemical, Inc. Kemin Industries, Inc. LCP Chemicals - West Virginia, Inc. Napp Chemicals, Inc. Eli Lilly & Co. Lyondeli Petrochemical Co. Mallinckrodt, Inc. Borg-Warner Corp., Borg-Warner Chemicals Mooney Chemicals, Inc MacKenzie Chemical Works, Inc. Morton-Thiokol, Inc., Ventron Div. Milliken & Co., Milliken Chemical Co. Miles Laboratories, Inc., Biotechnology Group EM Industries, Inc., EM Science Div. Monsanto Agricultural Co Mobay Chemical Corp., Pittsburgh Div. Monsanto Co. Morfiex Corp. Merck & Co., Inc. Niacet Corp.

Code NCI NCI NES NEV NOC NOD NWP OH OMC ORT PAC PD PAH PAS PCI PDG PEL PEN PFN PFZ PG PIC PKI PLC PLS PMP PPG PSG PST QKO RBC RCI RCN RDA REG REM REZ RH RPC RSA S SBC SCM SCP SD SDC SDW SHP SHC SHX

Name of company Union Camp Corp., Terpene & Aromatics Div. Union Camp Corp., Chemical Products Div. Ruetgers-Nease Chemical Co. Neville Chemical Co. Norac Co., Inc. Mathe Div. Nuodex, Inc. USI Chemicals Co. Inc. Anaquest Olin Corp. Roehr Chemicals, Inc. Pacific Anchor Chemical Corp. Parke-Davis, Div. of Warner-Lambert Co. Parish Chemical Co. Pennwalt Corp. Piedmont Chemical Industries, Inc. P.D. Glycol Pelron Corp. CPC International, Inc., Penick Corp. Pfanstiehl Laboratories, Inc. Pfizer, Inc. and Pfizer Pharmaceuticals, Inc. Procter & Gamble Co., Procter & Gamble Mfg. Co. Pierce Chemical Co. Perkins Industries, Inc. Phillips Petroleum Co. Plastics Engineering Co. PMP Fermentation Products, Inc. PPG Industries, Inc. PMC Specialities Group, Inc. Perstorp Polyols, Inc. Q0 Chemicals, Inc. Artel Chemical Corp. Reichhold Chemicals, Inc. Racon, Inc. Rhone-Poulenc, Inc. Regis Chemical Co. Remington Arms Co., Inc. Interez, Inc. Rohm & Haas Co. Hi-Tek Polymers, Inc., Lynda! Div. R.S.A. Corp. Sandoz, Inc. Scher Chemicals, Inc. SCM Corp.: Glidco Organic. Henkel Corp. Sterling Drug, Inc.: Sterling Pharmaceuticals, Inc. Sandoz Chemicals Corp. Sterling Drug, Inc. Sterling Organics Div. Shepherd Chemical Co. Shell Oil Co., Shell Chemical Co. Div. Sherex Chemical Co., Inc.

15-37

Section 15 Table 47—Continued Miscellaneous cyclic and acyclic chemicals:

Code SK SM SNO SOH 501 SOL SOM SPD SQA SWS SYL SYP

TCC TCH TLC TLI TNA TNI TRO TSA TU TX TZC UCC

Directory of manufacturers, alphabetical by code, 1987

Name of company SmithKline Chemicals. Mobil Oil Corp.: Chemical Products Div. SunOlin Chemical Co. Standard Oil Chemical Co. Speciality Organics, Inc. Southland Corp., Fine Chemical Div. Southland Corp. General Electric Co., Silicone Products Dept. Sequa Chemicals, Inc. Wacker Silicones Syivachem Corp. Synthetic Products Co., Division of Plastic Specialties & Technology, Inc. Sybron Chemicals, Inc. Quantum Chemical Corp., Trylon Div. Twin Lake Chemical, Inc. Teledyne Industries, Inc., Teledyne McCormick Se1ph Ethyl Corp. Gillette Co., Chemical Div. Troy Chemical Corp. Texas Alkyls, Inc. Tenn-USS Chemicals Co. Texaco Chemical Co. Magnesium Elektron, Inc. Union Carbide Corp.

Code UPM USB USI USR UTC VCM VDM VEL VIK VNC VND VST WAY WCC WCL WLN WM WPG WTC WTH WTK WTL WVA ZOC

Name of company UOP. Inc. U. S. Borax & Chemical Corp., U.S. Borax Research Corp. Quantum Chemical Corp., USI Div. Uniroyal, Inc., Uniroyal Chemical Div. Unitex Chemical Corp. Vanchem, Inc. Van De Mark Chemical Co., Inc. Velsicol Chemical Corp. Viking Chemical Co. Vanderbilt Chemical Corp. Van Dyk, Div. of Mallinckrodt, Inc. Vista Chemical Co. Olin Hunt Specialty Products, Inc. White Chemical Corp. Wright Chemical Corp. Wilmington Chemical Corp. inolex Chemical Co. West Point-Pepperell, Inc., Grifftex Chemical Co. Sub. Witco Chemical Corp. Union Camp Corp. Whittaker Corp., Heico Chemicals Div. Pennwalt Corp., Lucidol Div. Westvaco Corp., Sandoz Corp. Protection

Note.—Complete names, telephone number, and addresses of the above reporting companies are listed in app. A. Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

15-38

APPENDIX A DIRECTORY OF MANUFACTURERS

A-1

Appendix A Table A-1 Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

AEP

A & E Plastic Inc

818-968-3801

AZS

AZS Corp

404-859-0536

ABB

Abbott Laboratories

312-937-7262

ABS ILI

Abex Corp Acme Steel Company

703-662-3871 312-849-2500

ACO AIP AJY

Adco Chemical Co Air Products & Chemicals, Inc Ajay Chemicals, Inc

201-589-0880 215-481-4911 404-943-6202

AJI ARC

Ajinomoto U.S.A., Inc Akzo Chemie America, Armak Chemicals

201-488-1212

Office address

14505 Proctor Ave. Industry, CA 91749. 762 Marietta Blvd., N.W., Atlanta, GA 30318. 14th St. & Sheridan Rd., N. Chicago, IL 60064. P. 0. Box 3250, Winchester, VA 22601. 13500 S. Perry Avenue Riverdale, IL. 60627 129 Rutherford St., Newark, NJ 07105. P. 0. Box 538, Allentown, PA 18105. P. 0. Box 127, Powder Springs, GA 30073. 4020 Ajinomoto Dr., Raleigh, NC 27610.

312-906-7500

300 S. Riverside, Plaza Chicago, IL 60606.

Akzo Chemle America, Noury Chemicals

716-778-8554

ALW ALC AAC

Albright & Wilson, Inc Alco Chemical Corp Alcolac, Inc

804-752-6100 615-629-1405 301-355-2600

ALD

Aldrich Chemical Co., Inc

414-273-3850

ALE

Alex Chemical Co

717-462-3500

ACH ALG ALL ACS

316-783-1321 814-772-3965 201-945-5400 201-455-5000

ALX

Alico Chemical Corp Allegheny Chemical Corp Alliance Chemical, Inc Allied Signal Inc Allied Corp. Engineered Materials Sector Allied Signal-Bendix, Friction Materials Div. Alox Corp

2153 Lockport-Olcott Rd., Burt,' NY 14028 P. 0. Box 26229, Richmond, VA 23260. 909 Mueller Dr., Chattanooga, TN 37406. 3440 Fairfield Rd., Baltimore, MD 21226, and 190 Wintersen Rd., Linthicum, MD 21090. 940 W. St. Paul Ave., Milwaukee, WI 53233. 119 N. Union St., Shenandoah, PA 17976. P.O. Box 247, Galena, KS 66739 Gillis Ave., Ridgway, PA 15853. Linden Ave., Ridgefield, NJ 07657. Columbia Rd.& Park Ave., Morristown, NJ 07960.

APH

Alpha Corporation of Tennessee

901-853-2450

ALP HES

Alpha Laboratories, Inc Amerada Hess Corp. (Hess Oil Virgin Island Corp.) American Bio-Synthetics Corp

303-756-1338 201-750-6000

CAD

BME

AMB ACY AMU API ASY SPO

518-783-0537

P. 0. Box 238 Troy, NY 12180.

716-282-1295

3943 Buffalo Ave., Niagara Falls, NY 14303. P. 0. Drawer A, Hwy. 57 E, Collierville, TN 38017. P. 0. Box 22223, Denver, CO 80222. 1 Hess Plaza, Woodbridge, NJ 07095-0961. 710 W. National Ave., Milwaukee, WI 53204. One Cyanamid Plaza, Wayne, NJ 07470. 1202 Dozier St., Dalton, GA 30721. Old Webster Rd., Oxford, MA 01540. P. 0. Box 32960, Louisville, KY 40232. 146 South High St. Akron, OH 44308-1493. 900 Greenbank Rd., Wilmington, DE 19808. P. 0. Box 87703 Mail Code 1201, Chicago, IL 60680-0703. 4100 E. Washington Blvd., Los Angeles, CA 90023. 2005 W. Beltline Hwy., Madison, A-2 WI 53713. 1415 E. Michigan St., Adrian, MI 49221. 2211 Sanders Rd., Northbrook, IL 60062.

414-384-7017 201-831-2768 404-226-7028 617-987-0144 502-448-2761 216-762-4442

HVG

American Cyanamid Co American Emulsions, Inc American Polymers, Inc American Synthetic Rubber Corp Ameripol Synpol Co. Div. of Uniroyal Goodrich Tire Co Ametek, Inc., Haveg Div

AMO

Amoco Corporation

312-856-6111

AMV

Amvac Chemical Corp

213-264-3910

OH

Anaquest

608-273-0019

ADC ANG

Anderson Development Co Angus Chemical Co

517-263-2121 312-498-6700

A-2

302-995-0400

Synthetic Organic Chemicals, 1987 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

ALI

Anzon, Inc

215-427-3000

APX

Apex Chemical Co

201-354-5420

APC

Appollo Chemical Corp

919-226-1161

APO AQU

Apollo Colors, Inc Aqualon

312-564-9190 302-996-2030

ARD ART

Ardmore Chemical Co Aristech Chemical Corp.: Chemical Div

201-481-2406 412-433-2747

Clairton Plant

412-675-1752

Gary Works

219-888-4797

ARN

Arenol Chemical Corp

718-784-0948

ARZ

Arizona Chemical Co

904-785-6700

ALS

Armco, Inc

513-425-500

ARP ARK

Eastern Steel Div Armour Pharmaceutical Co Armstrong World Industries, Inc

513-425-2744 815-932-6771 717-397-0611

ARO

ARNCO

714-739-7900

ARL ARS

Arol Chemical Products Co Arsynco, Inc., Sub Div. of Aceto Corp

201-344-1510 718-898-2300

RBC ASH

Artel Chemical Corp Ashland Oil, Inc Ashland Petroleum Co Astor Products, Inc., Blue Arrow Div

304-755-3336 614-889-3333 606-329-3333 904-783-5000

Atlantic Industries, Inc Atlantic Richfield Co., Arco Chemical Co Atlas Powder Co., sub. of Tyler Corp Atlas Refinery, Inc Atochem Inc. Polymers Div

201-235-1800 215-359-2000

Auralux Corp Joseph Ayers, Inc BP America: Filon Div., Engineering Materials Co

203-886-2616 215-837-1808

213-757-1801

BAS

Silmar Div., Engineering Materials Co BASF Corp

ICF

Inmont Div

201-365-3400 201-263-4050

BTL BKC

BTL Specialities Corp J. T. Baker Chemical Co

419-244-5856 201-859-2151

BLA ATL ATR APD ARI RSN AUX KCH SIF SIC

214-387-2400 201-589-2002 201-447-3300

213-757-5141

616-392-2391 201-316-2937

Office address

2545 Aramingo Ave., Philadelphia, PA 19125. 200 S. First St., Elizabethport, NJ 07206-0254. 1105 Southerland St., Graham, NC 27253. 899 Skokie Blvd., Northbrook, IL 60062. 2711 Centerville Rd., Wilmington, DE 19850-5417. 29 Riverside Ave., Newark, NJ 07104. 600 Grant St., Pittsburgh, PA 15230-0250. 600 Grant St., Pittsburgh, PA 15230-0250. 600 Grant Dt., Pittsburgh, PA 15230-0250. 40-33 - 23d St., Long Island City, NY 11101. 200 Caller Box 2447, Panama City, FL 32401. P. 0. Box 191, Ashland, KY 41105, and 1801 Crawford St., Middletown, OH 45043. 703 Curtis St., Middletown, OH 45043. P. O. Box 511, Kankakee, IL 60901. Liberty & Charlotte Sts., Lancaster, PA 17604. One Centerpointe Dr., LaPalma, CA 90623-1094. 649 Ferry St., Newark, NJ 07105. 126-02 Northern Blvd., Flushing, NY 11368. P. 0. Box 550 Nitro, W.VA. 25143. P. 0. Box 2219, Columbus, OH 43216. P. O. Box 391, Ashland, KY 41101. 5244 Edgewood Ct., Jacksonville, FL 32205. 10 Kingsland Rd., Nutley, NJ 07110. 3801 Westchester Pike. Newtown Square, PA 19073. P. 0. Box 87, Joplin, MO 64802. 142 Lockwood St„ Newark, NJ 07105. 266 Harristown Rd. Glen Rock, N.J. 07452. 29 Scott Ave., Norwich, CT 06360. 275 Keystone Dr., Bethlehem, PA 18017. 12333 South Van Ness Ave., Hawthorne, CA 90250. 12333 South Van Ness Ave., Hawthorne, CA 90250. 491 Columbia Ave., Holland, MI 49423. and 100 Cherry Hill Rd., Parsippany, NJ 07054. 1255 Broad St., Clifton, NJ 07015 and 100 Cherry Hill Rd., Parsippany, NJ 07054. 2112 Sylvon Ave., Toledo, Oh. 43606. 222 Red School Lane, Phillipsburg, A-3 NJ 08865.

A-3

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Telephone Code Name of company number Office address BCK

619-993-8740

2470 Faraday Ave. Carlsbad, CA 92008.

714-871-4848

1050 Page Mill Rd., Palo Alto, CA 94304.

BEE

Beckman Instruments, Inc Diagnostic Systems Group Spinco Div Beecham, Inc.: Beecham Laboratories.Div

201-469-5200

BEW

Beecham Western Hemisphere, Inc

201-881-3000

BCM BLZ BTS

Belding Chemical Industries Belzak Corp Bethlehem Steel Corp

212-944-6040 201-773-0602 215-694-4522

BDS

Biddle Sawyer Corp.

212-736-1580

BNS

Binney and Smith, Inc

215-253-6271

BOC BNP

Biocraft Laboratories, Inc Bison Nitrogen Products Co

201-796-3434 712-277-1340

BOE LAK

Boehme Fllatex, Inc Bofors Nobel, Inc

919-342-1051 616-788-2341

101 Possumtown Rd., Piscataway, NJ 08854. 3 Garret Mountain Plaza, West Paterson, NJ 07424. 1430 Broadway, New York, NY 10018. 850 Bloomfield Ave., Clifton, NJ 07012. 866 Martin Tower - 8th Fl., Bethlehem, PA 18016. 2 Penn Plaza - Suite 2439, New York, NY 10121. 1100 Church Lane, Easton PA 18044-0431. 12 Industrial Park, Waldwick, NJ 07463. Terra Centre, 600 4th St., Sioux City, IA 51101. Rt. 11 Box 5 Reidsville, N.C. 27320 5025 Evanston Ave., Muskegon, MI 49443.

BOR

614-225-4000 304-424-5411

BFP

Borden, Inc.: Borden Chemical Div Borg-Warner Corp., Borg-Warner. Chemicals Breddo Inc

913-321-5300

BMC

Brin-Mont Chemicals, Inc

919-292-0566

BRS BRU

Bristol-Myers Co M. A. Bruder & Sons, Inc

212-546-4220 215-353-5100

BKM

Buckman Laboratories, Inc

901-278-0330

BCC BRI

Buffalo Color Corp Burlington Industries Inc

716-827-4500 919-379-2000

BRR BUR

Burris Chemical, Inc., Color Div Burroughs Wellcome Co

803-554-7511 919-248-3000

CFI CLU CCC CPC ACR

CF Industries, Inc CL Industries, Inc C.N.C. International, Inc International, Inc.: Acme Resin Corp

312-438-9500 217-662-2136 401-769-6100

BIB

MCB

PEN CPS CYR CNE GRL

Penick Corp

312-343-1900 201-621-2804

CMB HCF SVC

CPS Chemical Co., Inc CYRO Industries Cain Chemical, Inc Calgon Corp., Calgon Vestal Laboratories Div Cambridge Industries Co Cape Industries Capital City Products Co

617-924-0026 919-341-5500 614-299-3131

CBC CGL

Carbose Corp Cargill, Inc

814-443-1611 612-475-7646

A 4 -

201-727-3100 201-930-2000 713-623-2246 314-862-2000

180 E. Broad St., Columbus. OH 43215. International Center, Parkersburg, WV 26101. 18th & Kansas Ave., Kansas City, KS 66105. 3921 Spring Garden St., Greensboro, NC 27407. 345 Park Ave., New York, NY 10154 52nd & Grays Ave., Philadelphia, PA 19143 1256 N. McLean Blvd., Memphis, TN 38122. 100 Lee St., Buffalo, NY 14210. 3330 W. Friendly Ave. Greensboro, N.C. 27406 175 Eschelon Rd., Greenville, SC 29605. 3030 Cornwallis Rd., Research Triangle Park, NC 27709. Salem Lake Dr., Long Grove, IL 60047. P. 0. Box 218 Georgetown, IL 61846. 20 Priv!ledge St., Woonsocket, RI 02895. 10330 W. Roosevelt Rd. Westchester, IL 60153 158 Mount Olivet Ave., Newark, NJ 07114. P. 0. Box 162, Old Bridge, NJ 08857. 100 Valley Rd., Mr. Arlington, NJ 07856. 5 Greenway Plaza, Houston, TX 77046. 5035 Manchester Ave., St. Louis, MO 63110. 440 Arsenal St., Watertown, MA 02172. P. 0. Box 327 Wilmington, NC 28402. 1530 S. Jackson St., Janesville, WI 53545. 100 Maple St., Somerset, PA 15501. P. 0. Box 5630, Minneapolis, MN A-4 55420.

Synthetic Organic Chemicals, 1987 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

CDT

Carondelet Coke Corp

314-638-2400

CHC BSC CAS CE1 AZT

Carpenter Chemical Co Cascade Resins, Inc Caschem, Inc CastChem, Inc Catalyst Resources, Inc

804-359-0800 503-343-2111 201-858-7900 412-344-7500 713-957-6818

CCL

Catawba-Charlab, Inc

704-523-4242

CED

Cedar Chemical Co

501-572-3701 901-685-5348

CNT CPR GRS

Certainteed Corp Certified Processing Corp Champlin Petroleum Co

215-341-7000 201-923-5200 512-882-8871

CHH CHT

Chr. Hansen's Laboratory, Inc Chattem, Inc

414-476-3630 615-821-4571

CBD

Chembond Corp

503-687-8840

CFX CXI

Chemfax, Inc Chemical Exchange Industries, Inc

601-863-6511 713-526-8291

CMT

Chemithon Corp

206-937-9954

CHL

Chemol Co

919-272-3121

CRT SOC

Chemos Corp Chevron Corp., Chevron Chemical Co

201-623-3334 415-842-5500

CMC CGY

Chromatic Color Corp Ciba-Geigy Corp

502-737-1700 914-478-3131

FJI CGO

Cincinnati Varnish Co Citgo Petroleum Corp

513-631-4270 318-491-6488

CGU

Citizens Gas & Coke Utility

317-631-2181

CSP

Coastal Refining & Marketing Inc

713-877-1400

CP CLD

Colgate-Palmolive Co Colloids, Inc

212-310-2000 201-926-6100

CIC CCS

Color Chem International Corp Colorado Chemical Specialties, Inc

201-444-8563 303-245-8148

CRS

Colorado Resins, Inc

303-245-8148

CNC

Columbia Nitrogen Corp

404-823-4300

COC CAC

Columbia Organic Chemical Co., Inc Cominco Fertilizers Inc

803-425-1786 509-747-6111

CMP CNI CON CO

Commercial Products Co., Inc Conap, Inc Concord Chemical Co. Inc Conoco Specialty Products, Inc

201-427-6887 716-372-9650 609-966-1526 713-293-1764

Office address

526 E. Catalan Street St. Louis, MO. 63111 P. 0. Box 27205, Richmond, VA 23261. P. 0. Box 1989, Eugene, OR 97440. 40 Avenue A, Bayonne, NJ 07002. P.O. Box 457 Muse, PA., 15350 2190 North Loop West, Suite 400, Houston, TX 77018. 5046 Old Pineville Rd., Charlotte, NC 28217. Highway 242 South, West Helena, AR 72390 and P. 0. Box 3, Vicksburg, MS 39180. P. 0. Box 860, Valley Forge, PA 19482. U.S. Highway #22, Hillside, NJ 07205. P. 0. Box 9176, Corpus Christi, TX 78469. 9015 W. Maple St., West Allis, WI 53214. 1715 W. 38th St., Chattanooga, TN 37409. 1600 Valley River Dr., Suite 390, Eugene, OR 97401. Three Rivers Rd., Gulfport, MS 39503. 3813 Buffalo Speedway, Houston, TX 77098. 5430 W. Marginal Way, SW., Seattle, WA 98106. 2410 Randolph Ave., Greensboro, NC 27406. 225-235 Emmet St., Newark, NJ 07114. 6001 Bollinger Canyon Rd., San Ramon, 94583. 305 Ring Rd., Elizabethtown KY, 42701. 444 Saw Mill River Rd., Ardsley, NY 10502. 1776 Mentor Ave., Cincinnati, OH 45212. P. 0. Box 1562, Lake Charles, LA 70602. 3133 Southeastern Ave., Indianpolis, IN 46203 Nine Greenway Plaza, Houston, TX 77046. 300 Park Ave., New York, NY 10022. 394 Frelinghuysen Ave., Newark, NJ 07114. 7 Plymouth Rd., Glen Rock, NJ 07452. 569 24-1/4 Rd., Grand Junction, CO 81501. 569 24-1/4 Rd., Grand Junction, CO 81501. #23 Columbia Nitrogen Road, Augusta, GA 30903. 1424 Mt. Zion Road, Cassatt SC 29032 W. 818 Riverside Ave., Spokane, WA 99201. 117 Ethel Ave., Hawthorne, NJ 07506. 1405 Buffalo St., Olean, NY 14760. 17th & Federal Sts., Camden, NJ 08105. 600 N. Dairy Ashford Rd. Houston, TX 77079.

A-5

A-5

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Telephone Code Name of company number Office address

CTP

Continental Polymers, Inc

213-637-2103

CPV

Cook Paint & Varnish Co

816-391-6000

COP

Coopers Creek Chemical Corp

215-828-0375

CPY COS CMS

Copolymer Rubber & Chemical Corp Cosan Chemical Corp Cosmic Plastics, Inc

504-355-5655 201-460-9300 818-365-3249

CRD CK CCP USM CYT

Croda, Inc Crompton & Knowles Corp Crown Central Petroleum Corp Crown Metro, Inc Cumberland International Corp

212-683-3089 215-775-8000 301-539-7400 803-299-1331 713-682-1221

CTR

Customs Resins Div. of Bemis Co., Inc

502-826-7641

CYH

Cychem, Inc

513-681-0099

CYL AMD

Cyclo Chemical Corp Cyclo Products, Inc

305-592-6700 213-582-6411

CTL CNP DAN

201-472-5000 404-823-4240 804-799-7000 517-676-3800

432 Hogsback Rd., Mason. MI 48854.

DGO

Continental Chemical Co DSM Chemicals Augusta, Inc Dan River, Inc., Chemical Products Div. Dart Polymers, Inc., Sub. of Dart Container Corp. Day-Glo Color Corp

2225 E. Del Amo Blvd., Compton, CA 90220. P. 0. Box 419389, Kansas City, MO 64141. River Rd., West Conshohocken, PA 19428. P. 0. Box 2591, Baton Rouge, LA 70821. 400 - 14th St., Carlstadt, NJ 07072. 12314 Gladstone Ave., San Francisco, CA 91342. 183 Madison Ave., New York, NY 10016. P. O. Box 341, Reading, PA 19603. 1 N. Charles St., Baltimore, MD 21203. P. 0. Box 5695, Greenville, SC 29606. 1523 N. Post Oak Rd., Houston, TX 77055. Highway 136 West, Henderson, KY 42420. 266 W. Mitchell Ave., Cincinnati, OH 45216. 7500 N.W. 66th St., Miami, FL 33166. 1922 E. 64th St., Los Angeles, CA 90001. 270 Clifton Blvd., Clifton, NJ 7011-3686 P. O. Box 2451, Augusta, GA 30903. P. 0. Box 261, Danville, VA 24543.

216-391-7070

DPW DGC

Deepwater, Inc Degussa Corp

714-751-3522 201-641-6100

DRR

Delta Resins & Refractories, Inc

414-462-1200

DKA

713-477-8821

DNS DRB DSO & PLX UDI

Denka Chemical Corp TX 77017. Dennis Chemical Co Derby Co., Inc DeSoto, Inc

4515 St. Clair Ave., Cleveland, OH 44103. P. 0. Box 17599, Irvine, CA 92713. 65 Chassenger Rd., Ridgefield Park, NJ 07660. 6263 N. Teutonia Ave., Milwaukee, WI 53209. 8701 Park Place Blvd., Houston,

314-771-1800 617-342-5831 312-391-9000

DeSoto, Inc

312-391-9000

DTR

Detroit Coke Corp

312-842-6222

DEX HYA

212-542-7700 415-687-4201

818-968-6511

15051 E. Don Julian Rd., Industry, CA 91749.

MID AGP

Dexter Chemical Corp Dexter Corp, Hysol Aerospace & Industrial Products Div., Dexter Specialty Chemical Group. Dexter Corp., Hysol Electronic Chemical Div., Dexter Specialty Chemical Group Midland Div Dial Corp

312-623-4200 312-892-4381

DA

Diamond Shamrock Refining & Marketin

512-641-6800

DAZ

Diaz Chemical Corp

716-638-6321

E. Water St., Waukegan, IL 60085. 2000 Aucutt Rd., Montgomery, AL 60538. P. 0. Box 696000, San Antonio, TX 78269-6000. 40 Jackson St., Holley, NY 14470.

DPI

HYC

A-6

2700 Papin St., St. Louis, MO 63103. 119 Authority Dr., Fitchburg, MA 01420. 1700 S. Mt. Prospect Rd., Des Plaines, IL 60018. 1220 N. Main Place, Fort Worth, TX 76106. 7819 West Jefferson Ave., Detroit, MI. 48209 845 Edgewater Rd., Bronx, NY 10474. 2850 Willow Pass Road, Pittsburgh, CA. 94565.

A-6

Synthetic Organic Chemicals, 1987

Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

PLN

Disogrin Industries Corp

603-669-4050

DIX

Dixie Chemical Co., Inc

713-526-2604

DRC

Dock Resins Corp

201-862-2351

DOM DVC DOW

Dominion Products, Inc Dover Chemical Corp. Sub. of ICC Dow Chemical Co

718-499-3050 216-343-7711 517-636-6125

DCC

Dow Corning Corp

517-496-4000

DRX

Drexel Chemical Corp

901-774-4370

ABP CHO DUP DSC KF MMC

Drummond Company, Inc Ducon E. I. duPont de Nemours & Co., Inc Dye Specialties, Inc Dynamit Nobel Chemicals, Inc EM Industries, Inc., EM Science Div

205-945-6301 618-654-2070 302-774-1000 201-866-9504 201-784-0200 609-354-9200

AGI ECC EK EKT EKX ESA

EMS-American Grilon, Inc Eastern Color & Chemical Co Eastman Kodak Co Tennessee Eastman Co. Div Texas Eastman Co. Div East Shore Chemical Co,

803-481-9173 401-331-9000 716-724-4000 615-229-2000 214-236-5000 616-726-3106

ELN ELC

Elan Chemical Co Elco Corp. Sub. of Detrex Chemical

201-344-8014 216-749-2605

ELP EMR

915-333-7200 212-949-5000

USM EKO

El Paso Products Co Emery Chemicals, Division of National Distillers & Chemical Corp Emhart Corp., Bostik Div Empire Coke Co

ENO

Enenco, Inc

901-320-5800

SAR ESS ESX

215-521-3800 414-691-3000 201-773-6300

EHC

Esschem, Inc Essential Industries, Inc Essex Chemical Corp., Essex Industrial Chemicals, Inc Ethichem Corp

ETC

Ethox Chemicals, Inc.

803-277-1620

TNA ENJ

Ethyl Corp Exxon Chemical Americas

804-788-5000 713-870-6000

FMC FMN FMB

FMC Corp Agricultural Chemical Group Peroxygen Chemicals Div

215-299-6000 215-299-6000 716-876-8300

FRP FAB

FRP Co Fabricolor Manufacturing Corp

912-367-3616 201-742-3900

FMT FRI

Fairmount Chemical Co., Inc Farmland Industries, Inc Farmland industries, Inc

201-344-5790 913-459-6000 816-238-8111

617-777-0100 205-323-2400

201-933-7880

Office address Grenier Industrial Airpark, Manchester, NH 03103. 3635 W. Dallas Ave., Houston, TX 77019. 1512 W. Elizabeth Ave., Linden, NJ 07036. 882 - 3rd Ave., Brooklyn, NY 11232. W. 15th & Davis Sts., Dover, OH 44622. 2020 Willard H. Dow Center, Midland, MI 48674. 2200 W. Salzburg Rd., Midland, MI 48686-0994. 2487 Pennsylvania St., Memphis, TN 38109. P. 0. Box 10246, Birmingham, AL 35209. P. 0. Box 219, Highland, IL 62249. 1007 Market St., Wilmington, DE 19898. 100 Plaza Center, Secaucus, NJ 07094. 10 Link Dr., Rockleigh, NJ 07647. 2909 Highland Ave., Cincinnati, OH 45212. P. 0. Box 1948, Sumter, SC 29151. 35 Livingston St., Providence, RI 02904. 343 State St., Rochester, NY 14650. P. 0. Box 1974, Kingsport, TN 37662. P. 0. Box 1974, Kingsport, TN 37662. 1221 E. Barney Ave., Muskegon, MI 49443. 268 Doremus Ave., Newark, NJ 07105. 1000 Beltline Rd. Cleveland OH 44109. Industries, Inc. 619 N. Grant, Odessa, TX 79761. 11501 North Lake Dr., Cincinnati, OH 45249. Boston St., Middleton, MA 01949. 1927 1st Ave., N., Birmingham, AL 35203. 755 Crossover Lane, Memphis, TN 38117. P. 0. Box 56, Essington, PA 19029. 28391 Essential Rd., Merton, WI 53056. 1135 Broad St., Clifton, NJ 07015. 150 Grand St., Carlstadt, NJ 07072. South Carolina 29606 P.O. Box 5094, Station B, Greenville, SC 29606. 330 S. 4th St., Richmond, VA 23219. P.O. Box 3272, Houston, TX 77253-3272. 2000 Market St., Philadelphia, PA 19103. 2000 Market St., Philadelphia, PA 19103. Sawyer Ave. & River Rd., Town of Tonawanda, NY 14150. P. 0. Box 349, Baxley, GA 31513. 24-1/2 Van Houten St., Paterson, NJ 07509. 117 Blanchard St., Newark, NJ 07105. P.O. Box 308, Lawrence KS 66044. A-7 1417 Lower Lake Rd., St. Joseph, Mo 64502.

A-7

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

FEL SDS

Felton International, Inc Fermenta Plant Protection

718-497-4664 216-357-4100

FER

Ferro Corp. Ferro Chemical Div Grant Chemical Div Kell Chemical Div

599 Johnson Ave., Brooklyn, NY 11237. 5966 Heisley Rd., Mentor, OH 44061-8000.

216-641-8580 504-654-6801 219-931-2630

7050 Krick Rd., Bedford, OH 44146. P. 0. Box 263, Baton Rouge, LA 70821. 3000 Sheffield Ave., Hammond, IN 46320. 8350 N. Central, Dallas, TX 75206.

CSD FTX

Fina Oil & Chemical Co., Cosden Chemical Div Finetex, Inc

214-750-2400 201-797-4686

418 Falmouth Ave., Elmwood Park, NJ 07407.

804-541-2000 216-379-7495

P. 0. Box 450, Hopewell, VA 23860. P.O. Box 26611, Akron, OH 44319-0006.

Firestone Tire & Rubber Co.: Firestone Fibers & Textile Co Firestone Synthetic Rubber & Latex Co. Div Firmenich, Inc First Chemical Corp Flambeau Paper Corp Fleming Laboratories, Inc Flint Ink Corp., Cal/Ink Div Fluorocarbon Co Foote Mineral Co Formosa Plastics Corp-Louisiana Formosa Plastics Corp-USA

609-452-1000 601-762-0870 715-762-3231 704-372-5613 415-525-1188 216-274-3171 215-363-6500 504-356-3341 201-966-6980

FLN FRE

Franklin International Freeman Chemical Corp

614-443-0241 414-284-5541

WLC

Freeport McMoran Resource Partners

504-582-4000

FB FLH

Fritzsche Dodge & Olcott, Inc H.B. Fuller Co

212-929-4100 612-645-3401

COO GAF GLX GAN GAY GNT

H.B. Fuller Co GAF Corp., Chemical Group Galxie Chemical Corp Ganes Chemicals, Inc Gaylord Chemical Corp Gencorp Polymers Products

617-658-3351 201-628-3000 201-279-0558 212-391-2580 206-254-0922 216-869-4444

GNR

Genencor, Inc

415-742-7500

GE

General Electric Co.: Electromaterials

614-622-5310

FRF FRS CI FST FPC FLM CIK EEP FTE FOR

GEP GEI SPD GNF GLC GRG GGC

Plastics Business Group Plastics Div Insulating Materials Silicone Products Div

413-494-4793 413-448-4656 518-233-3757 518-237-3330

P.O. Box 5880, Princeton, NJ 08543. P. 0. Box 1427, Pascagoula, MS 39567. 200 N. First Ave., Park Falls, WI 54552. 2215 Thrift Rd., Charlotte, NC 28234. 1404 - 4th St., Berkeley, CA 94710. Main & Orchard Sts. Mantua, OH 44255. Route 100, Exton, PA 19341. P. 0. Box 271, Baton Rouge, LA 70821. 66 Hanover Rd., Florham Park, NJ 07932. 2020 Bruck St., Columbus, OH 43207. 217 Freeman Dr. Port Washington, WI 53074. 1615 Poydras St. New Orleans, LA 70112. 76 - 9th Ave., New York, NY 10011. 1200 W. County Rd. E., St. Paul, MN 55112. 820 Woburn St. Wilmington, MA 01887 P. 0. Box 12, Linden, NJ 07036. 26 Piercy St., Paterson, NJ 07524. 1114 6th Avenue, New York, NY 10036. P.O. Box 1209, Slidell, LA 70459-1209 165 S. Cleveland Ave. Mogadore, OH 44260. 180 Kimball Way, S. San Francisco, CA 94080. 1350 S. Second St., Coshocton, OH 43812 1 Plastics Ave., Pittsfield, MA 01201. 1 Plastics Ave., Pittsfield, MA 01201. 1 Campbell Rd., Schenectady, NY 12345. 260 Hudson River Rd., Waterford, NY 12188. 1125 Hudson St., Hoboken, NJ 07030.

General Foods Manufacturing Corp. Maxwell House Coffee Co General Latex and Chemical Corp P.D. George Co

617-576-8000 314-621-5700

Georgia Gulf Corp: Bound Brook Div

P.O. Box 498, Ashland, OH 44805. 5200 N. Second St., St. Louis, MO 63147.

404-395-4549

400 Perimeter Ctr., Terr. Suite 595, A-8 Atlanta, GA 30346. 400 Perimeter Ctr., Terr. Suite 595, Atlanta, GA 30346.

Houston Div

A-8

Office address

201-420-3432

404-395-4549

Synthetic Organic Chemicals, 1987 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

Office address

404-521-4000 404-395-4500

P.O. Box 105197, Atlanta, GA 30348. Evergreen Rd., Plaquemine, LA 70765.

206-733-4410 404-521-4000

PSP GP

Georgia Gulf Corp-Continued: Plaquemine Div PVC Compound Div Georgia-Pacific Corp.: Bellingham Div Resins Inc

TNI GBF

Gillette Co Gist-Brocades, USA, Inc

617-421-7000 704-527-9000

GIV GLD BFG

Givaudan Corp Glidden Company B. F. Goodrich Co

201-365-8000 216-344-8000 216-447-6000

HGC GYR

513-339-0591 216-796-2121 212-819-5500 617-861-6600 617-861-6600

P. 0. Box 27147, Memphis, TN 38127. 55 Hayden Ave., Lexington, MA 02173. 90 Tokeneke Rd., Darien, CT 06820.

GRD GPC CPC GTL GNW

Goodson Polymers, Inc Goodyear Tire & Rubber Co W. R. Grace & Co.: Agricultural Chemicals Group Hampshire Chemicals Div Organic Chemicals Div., Evans Chemetics. Organic Chemicals & Polymers Div Grain Processing Corp Grant Industries, Inc Great Lakes Chemical Corp Greenwood Chemical Co

P. 0. Box 1236, Bellingham, WA 98227. 133 Peachtree St. NE., Atlanta, GA 30303 3500 W. 16th St., N. Chicago, IL 60064. 5550 - 77 Center Dr., Charlotte, NC 28224-1068. 100 Delawanna Ave., Clifton, NJ 07014. 925 Euclid Ave., Cleveland OH 44115 6100 Oak Tree Blvd., Cleveland, OH 44131. 1250 South Union St., Troy, OH 45373 1144 E. Market St., Akron, OH 44316.

617-801-6600 319-264-4211 201-791-6700 317-497-6100 703-456-6832

GDC

Gresco, Inc

919-475-8101

GRV

Guardsman Chemicals, Inc

616-452-5181

GSS

Gulf States Steel, Inc

205-543-6201

55 Hayden Ave., Lexington, MA 02173. P. 0. Box 349, Muscatine, IA 52761. P. 0. Box 360, Elmwood Park, NJ 07407. Hwy. 52 N.W., Lafayette, IN 47906. State Hwy. #690, Greenwood, VA 22943. 216 E. Holly Hill Rd., Thomasville, NC 27360. 1350 Steele Ave., S.W., Grand Rapids, MI 49507. 174 South 26th Street Gadsden AL 35904.

HAR HAL

Haarmann & Reimer Corp C. P. Hall Co

201-686-3132 312-767-4600

HOC HTM

Haiocarbon Products Corp Haltermann Ltd. Co

201-343-8703 713-452-5951

FOC

Handschy Industries, Inc., Farac Varnishes & Chemicals Hanna Chemical Coatings Corp

312-597-7990

216-292-9200 201-433-6662 201-738-1000 319-243-5800 713-424-5568

SCP

Harshaw/Filtrol Partnership Hart Products Corp Hatco Chemical Co Hawkeye Chemical Co Helmerich & Payne, Inc., Natural Gas Odorizing Div Henkel Corp

HPC HER HTN HEU HEC HEW HEX HXL

Hercules, Inc Heresite Protective Coating, Inc Heterene Chemical Corp Heubach Inc Hewchem Hewitt Soap Co., Inc Hexagon Laboratories, Inc Hexcel Corp, Hexcel Chemical Products:

302-594-5000 414-684-6646 201-278-2000 201-242-1800 601-863-6600 513-253-1151 212-324-7550

70 Diamond Rd., Springfield, NJ 07081. 7300 S. Central Ave., Chicago, IL 60638. 82 Burlews Ct., Hackensack, NJ 07601. 16717 Jacintoport Blvd., Houston, TX 77015. 13601 S. Ashland Ave., Riverdale, IL 60627-1099. 1313 Windsor Ave., P.O. Box 147, Columbus, OH 43216. 3400 Band St., Louisville, KY 40212. 173 Sussex St., Jersey City, NJ 07302. King George Post Rd., Fords, NJ 08863. P.O. Box 899, Clinton, IA 52732. 3601 Decker Dr., P.O. Box 1429, Baytown, TX 77520. 7900 W. 78th St., Minneapolis, MN 55435. Hercules Plaza, Wilmington, DE 19894. 822 S. 14th St., Manitowoc, WI 54220. 790-21st Ave., Paterson, NJ 07513. Heubach Ave., Newark, NJ 07114. P.O. Box 188 Gulfport, MS 39501. 333 Linden Ave., Dayton, OH 45403. 4166 Boston Rd., Bronx, NY 10475.

818-882-3022 616-772-2193

A-9 20701 Nordhoff, Chatsworth, CA 91311. 215 N. Centennial, Zeeland, MI 49464.

GGC

GCC HMP EVN

HAN HSH HRT HCC HKY HAP

614-294-3361

612-828-8000

A-9

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

HIP SDG HIM RPC HDG

HCL

Name of company

Telephone number

Fine Organics Corp High Point Chemical Corp Hill Petroleum Company Himont, U.S.A., Inc Hi-Tek Oplymers, Inc., Lynda! Div Hodag Chemical Corp

201-472-6800 919-884-2214 713-923-3563 302-594-5500 404-259-4831 312-675-3950

Hoechst Celanese Corp: Bayport Works Chemical Group Div

205 Main St. Lodi, NJ 07644. 601 Taylor Ave., High Point, NC 27261. P.O. Box 5038 Houston, TX 77262-5038 1313 N. Market St., 1338 Coronet Dr., Dalton, GA 30720. 7247 N. Central Park Ave., Skokie, IL 60076. Wilmington, DE 19894.

201-231-2000 214-689-4000

12212 Port Rd., Pasadena, TX 77507. 1250 W. Mockingbird Lane, Dallas, TX 75247. 26 Main St., Chatham, NJ 07928. P.O. Box 32414, Charlotte, NC 28232. Frontage Rd., Spartanburg, SC 29304-5887. 129 Quidnick St., Coventry, RI 02816. P.O. Box 866, Mt. Holly, NC 28120. 801 Water St., Portsmouth, VA 23704. 340 Kingsland St., Nutley, NJ 07110. 414 Wilson Ave., Newark, NJ 07105. P.O. Box 930, Valley Forge, PA 19482. 10 Harmich Rd., S. Plainfield, NJ 07080. 45 Divine St., N. Haven, CT 06473-0325. 970 E. Tipton St., Huntington, IN 46750. 2000 Eagle Gate Tower, Salt City, UT 84111. 27 East 33rd St., Paterson, NJ 07514. Concord Pike & Murphy Rd., Wilmington, DE 19897. Concord Pike & Murphy Rd., Wilmington, DE 19897. Mantua Grove Rd., W. Deptford, NJ 08066. 730 Main St., Wilmington, DE 19897. Concord Pike & Murphy Rd., Wilmington, DE 19897. 1177 Summer St., Stamford, CT 06904. 1341 Hulman St., Terre Haute, IN 47808. 1029 Newark Ave., Elizabeth, NJ 07201. 50 Industry Ave., Joliet, IL 60435. 3210 Watling, St., E. Chicago, IL 46312. Jackson & Swanson Sts., Philadelphia, PA 19148. 6100 South Garfield Ave., Los Angeles, CA 90040. 9814 Bluegrass Parkway, KY 40299. 1515 Highway #36, Union Beach, NJ 07735. 2015 NE Broadway, Minneapolis, MN 55413. 500 Jersey Ave., New Brunswick, NJ 08903. 21625 Oak St., Matteson, IL 60443. 7575 Plaza Court, Willowbrook IL 60521. 4th & Adams Sts., Camas, WA 98607.

Engineering Plastics Div Fibers Div Fibers Industrial Div

201-635-2600 704-554-2000 803-579-5522

HOF HCP EFH HML HMY HNT HMN

Rhode Island Works Sou-Tex Virginia Chemicals, Inc Hoffmann-LaRoche, Inc Honig Chemical & Processing Corp E. F. Houghton & Co Hummel Chemical Co., Inc Humphrey Chemical Co Huntington Laboratories, Inc Huntsman Chemical Corp

201-231-2000 704-827-7531 804-393-3100 201-235-5000 201-344-0881 215-666-4000 201-754-1800 203-281-0012 219-356-8100 801-532-5200

HYD ICI

Hydrolabs, Inc ICI Americas, Inc

201-345-5100 302-575-3000

Films Group Div

302-575-3000

Polyurethanes Group

609-423-7400

Resin Div Speciality Chemicals Control

617-658-6600 302-575-3000

RAY IGC IND IDC INL WM

ITT Rayonier, Inc Indiana Gas & Chemical Corp Indol Color Co., Inc Industrial Color, Inc Inland Steel Co 'nolex Chemical Co

203-348-7000 812-232-0231 201-541-4159 815-722-7402 219-399-5385 215-271-0800

SPC

Insilco Corp., Sinclair Paint Co. Div .....

213-268-2511

REZ IFF

Interez, Inc International Flavor & Fragrances Inc

502-499-4011 212-765-5500

IPC

Interplastic Corp

612-331-6850

CCA

Interstab Chemicals, Inc

201-247-2202

10V IRI CRZ

312-481-8900 312-655-4595 206-834-8134

JRC JFR JRG

lovite, Inc Ironsides Co James River Corp., Speciality Chemicals Div Jarchem Industries, Inc George A. Jeffreys & Co., Inc Andrew Jergens Co

201-344-0600 703-389-8220 513-421-1400

JTO

Jetco Chemicals, Inc

214-872-3011

A-10

Office address

40 Ball St., Newark, NJ 07105. P. 0. Box 909, Salem, VA 24153. A-10 2535 Spring Grove Ave., Cincinnati, OH 45214. P. 0. Box 1898, Corsicana, TX 75110.

Synthetic Organic Chemicals, 1987 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

UPF MRX JNS JOB KLM

Jim Walter Resources, Inc Johnson Matthey, Inc.. S. C. Johnson & Son, Inc Jones-Blair Co Kalama Chemical, Inc

205-254-7835 215-971-3000 414-631-2000 214-353-1600 206-682-7890

KAN

Kanasco, Ltd

301-789-7800

KMP

Kelly-Moore Paint Co., Inc

415-592-8337

KM! KCU

515-266-2111 801-569-6000

KPI

Kemin Industries, Inc Kennecott Minerals Co., Utah Copper Div Kenrich Petrochemicals, Inc

KTP KYS KCW CHF KHI KON

Kent Polymers, Inc Keysor Century Corp Keystone Color Works, Inc Kincaid Enterprises, Inc Koch Refining Co H. Kohnstamm & Co., Inc

717-455-2021 805-259-2360 717-854-9541 304-755-3377 316-832-5500 212-620-4800

KPT

Koppers Co., Inc

412-227-2000

LCP

LCP Chemicals: Maine West Virginia, Inc LTV Steel Co., Inc

201-225-4840 304-843-1310 216-622-5000

201-823-9000

Office address P. 0. Box 5327, Birmingham, AL 35207. 2002 Nolte Dr., W. Deptford, NJ 08066. 1525 Howe St., Racine, WI 53403. 2728 Empire Central, Dallas, TX 75045. Suite 1110, Bank of California Center, Seattle, WA 98164. 6118 Robinwood Road, Baltimore, MD 21125. 987 Commercial St., San Carlos, CA 94070. 2100 Maury St., Des Moines, IA 50301. 8362 West 10200 South, Bingham Canyon, UT 84006-0525 140 E. 22nd St., Bayonne, NJ 07002-0032. 666 Dietrich Ave., Hazelton, PA 18201. P. 0. Box 308, Saugus, CA 91350. 151 W. Gay Ave., York, PA 17403. P. 0. Box 549, Nitro, WV 25143. P. O. Box 2302, Wichita, KS 67201. 161 Avenue of the Americas, New York, NY 10013. Koppers Bldg., K 601, Pittsburgh PA 15217.

LIC LMC

Lilly Industrial Coatings, Inc Lomac, Inc

317-634-8512 616-788-2341

BRD LC

Lonza, Inc Lord Corp., Chemical Products Group

201-794-2400 814-868-3611

LAS LCS

Los Angeles Soap Co Louisiana Chemical Polymers

213-627-5011 504-775-1801

LYP

Lyondell Petrochemical Co

713-652-7200

MCK MCC

MacKenzie Chemical Works, Inc McCloskey Corp. McCloskey Varnish Co.: McCloskey Corp. McCloskey Varnish Co.:

516-234-8600

P. 0. Box 149, Orrington, ME 04474. P. 0. Box Box J, Moundsville, WV 26041. LTV Steel Bldg., 25 W. Prospect Ave., Cleveland, OH 44115. 515 W. Davenport St., Rhinelander, WI 54501. 1100 Johnson Ferry Rd., Alanta GA 30342. 2600 E. Tioga St., Philadelphia, PA 19134. 990 Skokie Blvd., Northbrook, IL 60062. 2722 N. Hancock St., Philadelphia, PA 19133 P. 0. Box 1658, Petersburg, VA 23805. 390 Park Ave., New York, NY 10022. 736 Dunks Ferry Rd., Bensalem, PA 19020. 307 E. McCarty St., Indianapolis, IN 46285. Call Box 1198 - Pueblo Station, Carolina, PR 00630-1198. P. 0. Box 946, Indianapolis, IN 46206. 5025 Evanston Ave., Muskegon, MI 49443. 17-17 Route 208, Fair Lawn, NJ 07410. 2000 W. Grandview Blvd., Erie, PA 16514-0038. 617 E. 1st St., Los Angeles, CA 90051. 12537 Scenic Hwy., Baton Rouge, LA 70807. 1221 McKinney, Suite 1600, Houston, TX 77253-3646. 55 G Brook Ave., Deer Park, NY 11729.

215-624-4400

7600 State Rd., Philadelphia, PA 19136. A-11

215-624-4400

7600 State Rd., Philadelphia, PA 19136.

LTV

715-369-4356

ARM

Lake States Div. of Rhinelander Paper Co LaRoche Industries Inc.

LUR

Laurel Products Corp

215-423-5300

LII LEA

Lawter International, Inc Leatex Chemical Co

312-498-4700 215-739-6324

LLI LEV LVR

Lee Laboratories, Inc Lever Brothers Co C. Lever Co., Inc

804-862-2534 212-688-6000 215-639-8640

LIL

Ell Lilly & Co

317-261-2000

LKY

Eli Lilly Industries, Inc

MCC

404-851-0407

809-757-4000

A-11

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their Identification codes as used in each of the 15 individual sections of this report) Identification Code

MCC

Name of company

Telephone number

McCloskey Corp. McCloskey Varnish Co. -Continued: McCloskey Varnish Co., Oregon

503-226-3751

McCloskey Varnish Co., California

213-726-7272 301-667-7401

MGK

McCormick & Co., Inc., McCormickStange, Flavor Div McLaughlin Gormley King Co

MNP

McWhorter, Inc

312-428-2657

MAK

MAK Chemical Corp

317-288-4464

SOR

MW Manufacturers, Inc., Southern Resin Div. Magnesium Elektron, Inc

919-475-1348

STG

TZC MGR MAL MOC MRV MCA MAX MVO MZC MLC MRK MER MLS MIL MMM MIR MSC CHG VPC MOB SM

MOA MON MNA

612-544-0341

201-782-5800

500 Point Breeze Road, Flemington, NJ 08822 1029 Newark Ave., Elizabeth, NJ 07201. 3600 N. Second St., St. Louis MO 63147 539 S. Main St., Findlay, OH 45840.

201-242-1300 314-895-2000 419-422-2121

Masonite Corp., Alpine Resin Div Max Marx Color Corp Mayo Chemical Co Mazer Chemicals, Inc Melamine Chemicals, Inc Merck & Co., Inc Merichem Co Miles Laboratories, Inc: Biotechnology Group Milliken & Co., Milliken Chemical Div Minnesota Mining & Manufacturing Co Miranol Chemical Co., Inc Mississippi Chemical Corp Mobay Chemical Corp.: Agricultural Chemicals Div Dye & Pigment Div Pittsburgh Div Mobil Oil Corp.: Gas Liquids Dept Mobil Chemical Co Chemical Products Div Petrochemicals Div

312-750-0900 201-373-7801 404-696-6711 312-244-3410 504-473-3121 201-574-4000 713-455-1311 219-262-7445

1511 Joshua Circle, High Point, NC 27261. P.O. Box 1048, Laurel, MS 39441. 1200 Grove St., Irvington, NJ 07111. 5544 Oakdale Rd., Smyrna, GA 30081. 3938 Porett Dr., Gurnee, IL 60031. P. 0. Box 748, Donaldsonville, LA 70346. P. 0. Box 2000, Rahway, NJ 07065. 1914 Haden Rd., Houston, TX 77015. 1127 Myrtle St., Elkhart, IN 46515.

803-472-9041 612-733-3647 201-329-3900 601-746-4131

P. 0. Box 817, Inman, SC 29349. 3M Center 224-6S, St. Paul, MN 55144. P. 0. Box 436, Dayton, NJ 08810. P. 0. Box 388, Yazoo City, MS 39194.

816-242-2345 201-686-3700 412-777-2000

Hawthorne Rd., Kansas City, MO 64120. Mobay Road, Pittsburgh, PA 15205. Mobay Road, Pittsburgh, PA 15205.

703-849-3000 201-321-6000 201-321-6000 713-590-7700

Mona industries, Inc Monsanto Co

201-345-8220 314-694-1000

P. O. Box 900, Dallas, TX 75221. P. 0. Box 240, Edison, NJ 08818. P. 0. Box 250, Edison, NJ 08818. World Towers One, 15600 Drummet Blvd., Houston, TX 77032. 76 E. 24th St., Paterson, NJ 07544. 800 N. Lindbergh Blvd., St. Louis, MO 63167. 800 N. Lindbergh Blvd., St. Louis, MO 63167. 2301 Scranton Rd., Cleveland, OH 44113. 314 W. Henry St., Spartanburg, SC 29304. 2110 High Point Road, Greensboro, NC 27403. A-12

Monsanto Agricultural Co

919-886-7126

314-694-1000

Mooney Chemicals, Inc

216-781-8383

MCP

Moretex Chemical Products, Inc

803-583-8441

MRF

Morflex Chemical Co., Inc

919-292-1781

CCW MRT

Morton Thiokol, Inc.: Carstab Div Morton Chemical Div

513-733-2100 312-807-2000

-

4155 N.W. Yeon Ave., Portland, OR 97210. 5501 E. Slanson Avenue, Los Angeles, CA 90040. 230 Schilling Circle S., Hunt Valley, MD 21031. 8810 - 10th Ave., N., Minneapolis, MN 55427. 400 E. Cottage Place, Carpentersville, IL 60110. 1200 Rochester Ave., Muncie, IN 47307-0423. P.O. Box 68, Thomasville, NC 27360.

Magruder Color Co., Inc Mallinckrodt, Inc Marathon Petroleum Co., Texas Refining Div Marlowe-Van Loan Corp

MCI

A 12

Office address

2000 West St., Reading, OH 45215. 333 W. Wacker Dr. Chicago, IL 60606.

Synthetic Organic Chemicals, 1987 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of

the 15 individual sections of this report) Identification Code

Name of company

Telephone number

PYI

Morton Thiokol, Inc.-Continued: Morton Chemical Div

312-807-2000

MHI MOT RTC PNX

Ventron Div Motomco, Ltd Mount Vernon Mills, Inc The Murphy-Phoenix Co

617-774-3100 608-244-2904 803-233-4151 216-831-0404

NTL NLT LEM NTC NCJ NMC

NL Chemicals Div NL Treating Chemicals Napp Chemicals, Inc National Casein Co National Casein of New Jersey National Milling & Chemical Co., Inc

609-443-2000 713-870-6000 201-773-3900 312-846-7300 312-846-7300 215-482-6600

NSC

National Starch & Chemical Corp

201-685-5000

NTS

313-297-3000

NEP NEV

National Steel Corp., Great Lakes Plant Nepera, Inc Neville Chemical Co

914-782-1200 412-331-4200

NBC NCC NLO

New Boston Coke Corp Niacet Corp Niklor Chemical Co., Inc

614-456-4154 716-285-1474 213-830-2253

NCP

FSN

Niles Chemical Paint Co Mishawaka Div The Norac Co., Inc Mathe Div NOR-AM Chemical Co

616-683-3377 219-255-9678 818-334-2908 201-779-4981 302-575-2000

NPC

Northwest Petrochemical Corp

206-293-3176

NW

Northwestern Chemical Co

312-231-6111

NOR NBI NOD NSW NUT

Norwich Eaton Pharmaceutical, Inc Novo Biochemical Industries, Inc Nuodex, Inc The Nutrasweet Co Nutrius, Inc

607-335-2111 919-494-2014 201-981-5000 312-940-9800 216-526-5522

OBC

The O'Brien Corp

415-761-2300

HKD HKO

Occidential Chemical Corp.: Durez Div Olefins Div

716-696-6000 318-437-8100

NOC

HKP HK EPI OMC

PVC Div Specialty Chemical DivOhio Rubber Eagle Pitcher Ind Orthane Div Olin Corp

203-356-2000

WAY OC ORG OCC BSW

Olin Hunt Speciality Products, Inc. Omega Chemicals, Inc Organics/LaGrange, Inc Orient Chemical Corp Original Bradford Soap Works, Inc

201-977-6000 803-582-5346 312-764-6700 201-465-0714 401-821-2141

214-251-1000 214-404-3300 817-387-0585

Office address

Mountain Creek Church Rd., Greenville, SC 29602. 150 Andover St., Danvers, MA 01923. P. 0. Box 8422, Madison, WI 53708. One Shelter Place, Greenville, SC 29602. 23811 Chagrin Blvd., Beachwood, OH 44122. P. 0. Box 700, Hightstown, NJ 08520. 17402 Wallisville Rd., Houston, TX 77049. 199 Main St., Lodi, NJ 07644. 601 W. 80th St., Chicago, IL 60620. 601 W. 80th St., Chicago, IL 60620. 4601 Flat Rock Rd., Philadelphia, PA 19127. 10 Finderne Ave., Bridgewater, NJ 08807. 1 Quality Dr., Ecorse, MI 48229. Route #17, Harriman, NY 10926. 2800 Grand Avenue, Pittsburgh, PA 15225. P.O. Box 3128 New Boston, OH 45662. 400 - 47th St., Niagara Falls, NY 14304. 2060 E. 220th St., Long Beach, CA 90810. P. 0. Box 307, Niles, MI 49120. 1413 Clover Rd., Mishawaka, IN 46544. 405 S. Motor Ave., Azusa, CA 91702. 169 Kennedy Dr., Lodi, NJ 07644-0230. 3509 Silverside Road, Wilmington, DE 19803. 708 N. Texas Rd. - March Point, Anacortes, WA 98221. 120 N. Aurora St., West Chicago, IL 60185. 17 Eaton Ave., Norwich, NY 13815. State Road 1003, Franklinton, NC 27525. Turner Place, Piscataway, NJ 08854. 1751 Cook Road, Deerfield, IL 60015. 8221 Brecksville Rd., Brecksville, OH 44141. 450 E. Grand Ave., S. San Francisco, CA 94080. Walck Rd., N. Tonawanda, NY 14120. One Lakeshore Dr., Suite 1895 Lake Charles, LA 70629. P. 0. Box 1772, Berwyn, PA 19312. 505 LBJ Freeway, Dallas, TX 75244. 1500 I 35-W, Denton, TX 76202. 120 Long Ridge Rd., Stamford, CT 06904. One Wellington Rd., Lincoln, RI 02865. P.O. Box 1723, Spartanburg, SC 29304. 7125 N. Clark St., Chicago, IL 60626. 121 Tyler St., Port Newark, NJ 07114. 200 Providence St., W. Warwick, RI 02893. A-13

A-13

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

CJO

C. J. Osborn Chemicals, Inc

609-662-0128

OCF PBI

Owens-Corning Fiberglas Corp PBI-Gordon Corp

419-248-8000 816-421-4070

PDG PSG

P.D. Glycol PMC Specialities Group, Inc

409-838-4521 216-356-0700

PMP

PMP Fermentation Products, Inc

414-352-3001

PPG PPS

PPG Industries, Inc P/P Splitter Venture

412-434-3131 713-972-1307

PAC

Pacific Anchor Chemical Corp

213-725-1800

PRA PAH PD

803-967-7691 801-226-2018 201-540-2000

PSC PAT CHP PEL PAS WTL PAR PKI

Para-Chem. Southern Parish Chemical Co Parke-Davis Div., of Warner Lambert, Inc Passaic Color & Chemical Co Pat-Chem, Inc C. H. Patrick & Co., Inc Pelron Corp Pennwalt Corp Lucidol Div Penreco, Pennzoil Products Co., Div Perkins Industries, Inc

BPT PER

Permuthane Coating, Inc Perry & Derrick Co

617-531-1880 513-351-5800

PST PST PFN

Perstorp Compounds, Inc Perstorp Polyols, Inc Pfanstiehl Laboratories, Inc

413-584-2472 419-729-5448 312-623-0370

PCW PFZ PHR

Pfister Chemical, Inc Pfizer, Inc Pfizer Pharmaceuticals, Inc Pharmachem Corp

201-945-5400 212-573-2323 809-846-4300 215-867-4654

PLB

Pharmacia P-L Biochemicals, Inc

414-225-2600

PDI

Phelps Dodge Industries, Inc.

219-456-4444

PPX PLC PPR PHC

Phelps Dodge Magnet Wire Co. Div. Phillips Paraxylene, Inc Phillips Petroleum Co Phillips Puerto Rico Core, Inc Phthalchem, Inc

809-864-1515 918-661-6600 809-864-1515 513-681-0099

PCI PIC

Piedmont Chemical Industries, Inc Pierce Chemical Co

919-885-5131 815-968-0747

PIL

Pilot Chemical Co

213-723-0036

IMC

Pitman-Moore, Inc Industrial Chemicals, Div Plaskolite, Inc Plaslok Corp Plastics Engineering Co

812-232-0121 312-566-2600 614-294-3281 716-681-7755 414-458-2121

PKL PSL PLS

A 14 -

.

201-279-0400 803-233-3941 803-244-4831 312-442-9100 215-587-7000 716-877-1740 713-337-1534 913-677-5831

Office address

820 Sherman Ave., Pennsauken, NJ 08110. Fiberglas Tower, Toledo, OH 43659. 1217 W. 12th St., Kansas City, MO 64101-9984. P.O. Box 3785, Beaumont, TX 77704. 20525 Center Ridge Rd, Rocky River, OH 44116. 7670 N. Port Washington Rd., Milwaukee, WI 53217. One PPG Place, Pittsburgh, PA 15272. 6161 Savoy Dr. Suite 222, Houston, TX 77036. 5701 S. Eastern Ave. Suite 530, Los Angeles, CA 90040. P.O. Box 127, Simpsonville, SC 29681. 145 N. Geneva Rd., Orem, UT 84057. 188 Howard Ave., Holland, MI 49424. 28-36 Paterson St., Paterson, NJ 07501. 11 Worley Rd., Greenville SC 29602. P. 0. Box 2526, Greenville, SC 29602. 7847 W. 47th St., Lyons, IL 60534. Three Parkway, Philadelphia, PA 19102. 1740 Military Rd., Buffalo, NY 14240. 4401 Park Ave., Dickinson, TX 77539. 10453 W. 84th Terrace, Lenexa, KS 66214. 13 Corwin St., Peabody, MA 01960. 2510 Highland Ave., Cincinnati, OH 45212. 238 Nonotuck St., Florence, MA 01060. 600 Matzinger Rd., Toledo, OH 43612. 1219 Glen Rock Ave., Waukegan, IL 60085. Linden Ave., Ridgefield, NJ 07657. 235 E. 42nd St., New York, NY 10017. P. 0. Box 628, Barceloneta, PR 00617. 719 Stefko Blvd., P.O. Box 1035 Bethlehem, PA 18016. 2202 N. Bartlett Ave., Milwaukee, WI 53202. 4300 New Haven Ave., Fort Wayne, IN 46803. P. 0. Box 1166, Guayama, PR 00655. Phillips Bldg., Bartlesville, OK 74006. P. 0. Box 1166, Guayama, PR 00655. 266 W. Mitchell Ave., Cincinnati, OH 45232. 331 Burton Ave., High Point, NC 27261. 3747 N. Meridan Rd., Rockford, IL 61103. 11756 Burke St., Santa Fe Springs, CA 90670. P.O. Box 207, Terre Haute, IN 47808. 421 E. Hawley St., Mundelein, IL 60060. A-14 P. 0. Box 1497, Columbus, OH 43216. 3155 Broadway, Buffalo, NY 14227. 3518 Lakeshore Rd., Sheboygan, WI 53081.

Synthetic Organic Chemicals, 1987 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

PMC

Plastics Manufacturing Co

214-330-8671

PTC PLR POP PRT JLP PCH

Polycast Technology Corp Polysar, Inc Plastics Div Pope Chemical Corp Pratt & Lambert, Inc J. L. Prescott Co Prochem, Inc

203-327-6010 671-537-9901 201-279-2702 716-873-6000 201-777-4200 215-436-4812

PG

513-627-5194 818-240-2060

5430 San Fernando Rd., Glendale,

QKO

Procter & Gamble Co., Procter & Gamble Mfg. Co. Products Research & Chemical Corp CA 91209. Q0 Chemicals, Inc

2700 S. Westmoreland, Dallas, TX 75233. 69 Southfield Ave., Stamford, CT 06902. 29 Fuller St., Leominster, MA 01453. 33 - 6th Ave., Paterson, NJ 07524. P.O. Box 22, Buffalo, NY 14240. 27 8th St., Passaic, NJ 07055. 116 Concord MTG. Road, Glen Mills, PA 19342. P. 0. Box 599, Cincinnati, OH 45201.

312-572-2330

QCP

Quaker Chemical Corp

215-828-4250

823 Commerce Dr., Suite 200, Oak Brook, IL 60521. Elm & Lee Sts., Conshohocken, PA 19428-0809.

TCH USI

Quantum Chemical Corp.: Emery Div USI Div

803-963-4031 513-530-6580

QUN RSA

K. J. Quinn & Co., Inc. R.S.A. Corp

617-321-3200 914-693-1818

RCN BLC

316-524-3245 412-486-1111

RAB

Racon, Inc Ranbar Technology, Inc., Ball Chemical Co Raytech Corp

MAR RBI REG

Reed Lignin, Inc Reeves Brothers, Inc Regis Chemical Co

203-625-0701 803-576-1210 312-967-6000

RCI

Reichhold Chemicals, Inc

914-682-5700

RIL

Reilly Tar & Chemical Corp

317-247-8141

REL

502-459-9110

REM

Reliance Universal, Inc., Louisville Resins Div Remington Arms Co., Inc

302-774-1000

RDA

Rhone-Poulenc, Inc

201-821-2034

RCD AMS RIK

Richardson Polymer Corp Ridgway Color Co Riker Laboratories, Inc. Sub. of 3M Co

203-245-0441 513-771-1900 818-341-1300

RIV

Riverdale Chemical Co

312-754-3330

ROB ORT

Robeco Chemicals, Inc. Roehr Chemicals, Inc, Div. of Aceto

212-986-6410 718-784-8473

RH

Rohm & Haas Co

215-592-3000

ROM

Roma Color, Inc

617-676-3481

RUC RUO NES

Rubicon, Inc Ruco Polymer Corp Ruetgers-Nease Chemical Co

504-673-6141 516-931-8104 814-238-2424

SBP

SBS Products Inc

517-799-4941

PRC

203-371-0101

Office address

P.O. Box 628, Mauldin, SC 29662. 11500 Northlake Dr., Cincinnati, OH 45249. 195 Canal St., Malden, MA 02148. 690 Saw Mill River Rd., Ardsley, NY 10502. 6040 S. Ridge Rd., Wichita, KS 67201. 1114 William Flinn Highway, Glenshaw, PA 15116. 1204 Darlington Ave., Crawfordsville, IN 47933. 81 Holly Hill Lane, Greenwich, CT 06830. P. 0. Box 1898, Spartanburg, SC 29304. 8210 Austin Ave., Morton Grove, IL 60053. 525 N. Broadway, White Plains, NY 10603. 151 N. Delaware St., 1510 Market Square Center, Indianapolis, IN 46204. 4730 Crittenden Dr., Louisville, KY 40232. 615 Asylum St., Bridgeport, CT 06601-2190. P.O. Box 125, Princeton, NJ 08543-5266. 17 Woodland Rd., Madison, CT 06443. 75 Front St., Ridgway, PA 15853. 19901 Nordhoff St., Northridge, CA 91324. 220 E. 17th St., Chicago Heights, IL 60411. 99 Park Ave., New York, NY 10016. 52-20 37th St., Long Island City, NY 11101. Independence Mall West., Philadelphia, PA 19105. 749 Quequechan St., Fall River, MA 02723. P. 0. Box 517, Geismar, LA 70734. New South Rd., Hicksville, NY 11802. 201 Struble Rd., State College, A-15 PA 16801. 302 Wailer St., Saginaw, MI 48605.

A-15

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Telephone Code Name of company number Office address SCM

SOS

SCM Corp.: Glidco Organics PCR, Inc SSC Industries, Inc

904-768-5800 904-376-8246 404-762-9651

NPR

Safeway Stores, Inc

415-944-4478

STX

St. Croix Petrochemical Corp

809-778-6450

SLM SAL

Salem Oil & Grease Co Salsbury Laboratories, Inc

508-745-0585 515-257-2422

SBG

Samuel Bingham Co

312-298-6777

SCM ZOC ZOC

Sandoz Corp.: Sandoz Chemical Corp Sandoz Corp. Protection Sandoz Corp. Protection

704-331-7016 312-699-1616 312-699-1616

SCN

Schenectady Chemicals, Inc

518-370-4200

SBC SCH SCO SPR SPA SRL SQA SKP

Scher Chemicals, Inc Schering Corp Scholler, Inc Scientific Protein Laboratories Scott Paper Co G. D. Searle & Co Sequa Chemicals, Inc Shakespeare Monofilament Div

201-471-1300 201-298-4000 215-739-0900 608-849-5944 215-521-5000 312-982-7000 803-385-5181 803-754-7011

SHO SHC SGO

Shell Oil Co Shell Chemical Co Shenango, Inc

713-241-1242 713-241-1242 412-771-4400

SHP SHX

513-731-1110 614-764-6500

SW SW BAL

Shepherd Chemical Co Sherex Chemical Co., Inc The Sherwin-Williams Co.: Sherwin-Williams Co Sherwin-Williams Co Consumer Div

216-566-2000 216-566-2000 301-625-8247

SHT

Shintech, Inc

713-965-0713

SMP GFS SK SMO SIO SLT SLC

J. R. Simplot Co G. Frederick Smith Chemical Co SmithKline Chemicals Smooth-On, Inc Sohio Oil Co Soitex Polymer Corp Soluol Chemical Co., Inc

208-336-2110 614-881-5501 215-751-4000 201-647-5800 419-226-2300 713-522-1781 401-821-8100

SAC

Southeastern Adhesives Co

704-754-3493

ACT SOL SOM SWR

Southland Corp.: Chemical Div Fine Chemical Div Great Meadows Div Southwestern Refining Co., Inc

214-333-2151 214-333-2151 214-828-7011 512-884-8863

SPL

A-16

Spaulding Composites Co. Industrial Plastics Div

716-692-2000

P.O. Box 389, Jacksonville, FL 32201 P.O. Box 1466, Gainesville, FL 32609. 1550 E. Taylor Ave., East Point, GA 30344. 2800 Ygnacio Valley Rd., Walnut Creek, CA 94598. P. 0. Box 6801, Christiansted, St. Croix, U.S. VI 00820. 60 Grove St., Salem, MA 01970. 2000 Rockford Rd., Charles City, IA 50616. 479 Business Center Dr., Suite 109, Franklin Park, IL 60131. 4000 Monroe Rd., Charlotte, NC 28205. P.O. Box 220, Wasco, CA 93280. 1300 E. Touity Ave., Des Plaines, II 60018. P. 0. Box 1046, Schenectady, NY 12306. Industrial West, Clifton, NJ 07012. 1011 Morris Ave., Union, NJ 07083. P. 0. Box 26968, Philadelphia, PA 19134. 700 E. Main St., Waunakee, WI 53597. P. 0. Box 925, Everett, WA 98206. 5200 Old Orchard Rd., Skokie, IL 60077. P.O. Box 70, Chester, SC 29706. 6111 Shakespeare Rd., Columbia, SC 29240. P. 0. Box 3105, Houston, TX 77002. P. 0. Box 3105, Houston, TX 77002. 200 Neville Rd., Pittsburgh, PA 15225-1690. 4900 Beech St., Cincinnati, OH 45212. 5777 Frantz Rd., Dublin, OH 43017. 11541 S. Champlain, Chicago, IL 60628. 2802 W. Miller Rd., Garland TX 75040. 2325 Hollins Ferry Rd., Baltimore, MD 21230. 24 Greenway Plaza, Suite 811, Houston, TX 77046. P.O. Box 912 Pocatello, ID 83204. P. 0. Box 23214, Columbus, OH 43223. 900 River Rd., Conshohocken, PA 19428. 1000 Valley Rd., Gillette, NJ 07933. 1150 S. Metcalf St., Lima, OH 45804. P. 0. Box 1000, Deer Park, TX 77536. Green Hill & Market Sts., W. Warwick, RI 02893. 815 D Virginia St., SW., Lenoir, NC 28645. 7666 W. 63d St., Summit, IL 60501. 2841 Pierce St. Dallas, TX 75233. Alphano Rd., Great Meadows, NJ 07838. P. 0. Box 9217, Corpus Christi, TX 78469. 310 Wheeler St., Tonawanda, NY 14150.

A-16

Synthetic Organic Chemicals, 1987 Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report) Identification Code

Name of company

Telephone number

ASL SOI IPP TRD SCC

SpecialtyChem Products Corp Specialty Organics, Inc Spectrachem Corp Squibb Manufacturing, Inc Standard Chlorine of Delaware, Inc

715-735-9033 818-962-2008 201-595-8181 809-852-1255 201-997-1700

SOH

Standard Oil Chemical Co

216-586-4141

STP

Stepan Co

312-446-7500

SC

Sterling Chemicals, Inc

409-945-4431

SD SDH

Sterling Drug, Inc SDI Divestiture Cprp.

212-907-2000 513-841-4000

SDW SD PPL CIN SNA SUN SNO RAS JSC & TCC SYL INP

Sterling Organics Div Sterling Pharmaceuticals, Inc Sterling Engineered Products Stockhausen, Inc Sun Chemical Corp., Pigments Div Sun Company, Inc SunOlin Chemical Co Surface Coatings, Inc Sybron Chemical, Inc

212-907-2000 212-907-2000 207-784-9111 919-378-9393 212-986-5500 215-977-6358 215-977-6358 617-933-4200 609-893-1100

Sylvachem Corp Synair Corp

904-785-6700 615-698-8801

Synalloy Corp., Blackman Uhler Chemical Div Synray Corp

803-585-3661

BUC SRY HFT ARA SYP SYT TEK TLI TU TOC TEN TVA

TER TER

Syntex Agribusiness, Inc., Nutrition & Chemical Div Syntex Chemicals, Inc Synthetic Products Co., Div of Plastic Specialties & Technology Synthron, Inc Teknor Apex Co Teledyne industries, Inc., Teledyne McCormick Seiph Tenn-USS Chemicals Co Tenneco Oil Co Tennessee Chemical Co Tennessee Valley Authority, NFDC, TVA, OACD, Div. of Developmental Production Terra international, Inc Terra Nitrogen, Inc

201-245-2600 417-866-7291 303-442-1926 216-531-6010 704-437-8611 401-725-8000 408-637-3731 713-884-4400 713-757-3373 615-496-3331 205-386-3522

712-277-1340 712-277-1340

TX TUS TSA TCR TPC

Texaco Chemical Co Texaco Butadiene Co Texas Alkyls, Inc Texas City Refining, Inc Texas Petrochemicals Corp

713-432-3734 713-666-8000 713-479-8411 409-945-4451 713-477-9211

TXS

Texstyrene Plastics, Inc

817-831-3541

Office address 2 Stanton St., Marinette, WI 54143. 5623 N. 4th St., Irwindale, CA 91706. 200 Sheridan Ave., Paterson, NJ 07512. P. 0. Box 609, Humacao, PR 00661. 1035 Belleville Turnpike, Kearny, NJ 07032. 200 Public Square, (31-41505-N) Cleveland, OH 44114-2375. RR #1, Elwood, IL 60421 and 100 W. Henter Ave., Maywood, NJ 07607. 201 Bay St. South, Texas City, TX 77592-1311. 2144 E. State St., Trenton, NJ 08619. 2335 Langdon Farm Rd., Cincinnati, OH 45237. 90 Park Ave., New York, NY 10016. P. 0. Box 11247, Barcelonita, PR 00617. 1 Pionite Road, Auburn, ME 04210. 2408 Doyle St., Greensboro, NC 27406. 411 Sun Ave., Cincinnati, OH 45232. 1801 Market St., Philadelphia, PA 19103. 1801 Market St., Philadelphia, PA 19103. 100 Eames St., Wilmingon, MA 01887. Birmingham Rd., Birmingham, NJ 08011. P. 0. Box 947, Port St. Joe, FL 32456. 2003 Amnicola Hwy., Chattanooga, TN 37406. P. 0. Box 5627, Spartanburg, SC 29304. 209 N. Michigan Ave., Kenilworth, NJ 07033. P. 0. Box 1246 S.S.S., Springfield, MO 65805. 2075 N. 55th St., Boulder, CO 80301. 1000 Wayside Rd., Cleveland, OH 44110. P. 0. Box 1111, Morganton, NC 28655. 505 Central Ave., Pawtucket, RI 02861. 3601 Union Rd., Hollister, CA 95024-0006. P. O. Box 600, Pasadena, TX 77501. P. O. Box 2511, Houston, TX 77001. 1 Ocoee St., Copperhili, TN 37317. Muscle Shoals, AL 35660.

Terra Centre, 600 - 4th St., Sioux City, IA 51101. Terra Centre, 600 - 4th St., Sioux City, IA 51101. 4800 Fournace Place, Bellaire, TX 77401. P. 0. Box 430, Bellaire, TX 77401. P. 0. Box 600, Deer Park, TX 77536. P. 0. Box 1271, Texas City, TX 77592. 8600 Park Place Blvd., Houston, TX 77017. 3607 N. Sylvania Ave., Fort Worth, TX 76111.

A-17

A-17

Appendix A Table A-1-Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in each of the 15 individual sections of this report)

Identification Code

Name of company

Telephone number

TMH

Thompson Hayward Chemical Co

913-321-3131

TWD TRI TRO TUL TLC UPM

Tonawanda Coke Corp Triad Chemical Troy Chemical Co Tull Chemical Co., Inc Twin Lake Chemical, Inc UOP, Inc

716-876-6222 504-473-9231 201-589-2500 205-831-1154 716-433-3824 312-391-2000

UHL

Paul Uhlich & Co., Inc

914-478-2000

UNG

Ungerer & Co

201-628-0600

DRL WTH NCI NCI UCC

Unichema Chemical, Inc Union Camp Corp Chemical Products Div Terpene & Aromatics Div Union Carbide Corp

201-327-6100 201-628-2000 201-628-2000 201-628-2000 203-794-3113

UOC

Union Oil Co. of California

213-977-7746

UTP

Union Texas Petroleum Corp

713-968-2366

USR

Uniroyal, Inc., Uniroyal Chemical Div

203-573-3886

UNN UNO VAL

617-762-4057 814-456-7561 201-837-1700

USB

United Aniline Co United Erie, Inc United Merchants & Manufacturers, Inc., Valchem Div U.S. Borax & Chemical Corp., U.S

UTC UPJ CWN

Borax Research Corp Unitex Chemical Corp The Upjohn Co Fine Chemicals

VSV VLR VCM VDM VNC

Valentine Sugars, Inc Valero Refining Co Vanchem, Inc Van De Mark Chemical Co., Inc Vanderbilt Chemical Corp

VND VEL VIK VIN VCC

Van Dyk, Div. of Mallinckrodt, Inc Velsicol Chemical Corp Viking Chemical Co Vineland Chemical Co., Inc Vinings Industries, Inc

504-532-2541 512-246-2000 716-434-2624 716-433-6764 203-744-3900 203-853-1400 201-759-3225 312-698-9700 612-333-0394 609-691-3535 404-436-1542

VKR VST

Virkler Co Vista Chemical Co

704-527-2350 713-531-3200

VTM FRO VYN SWS WJ WES WCA

Vitamins, Inc Vulcan Materials Co., Chemicals Div Vygen Corporation Wacker Silicones Corp Warner-Jenkinson Wesley Industries, Inc West Coast Adhesives Co

312-861-0700 205-877-3000 216-998-1120 517-263-5711 314-889-7600 205-626-2040 503-286-3515

Office address 5200 Speaker Rd., Kansas City, KS 66110. P.O. Box A-500 Tonawanda, NY 14151 P. 0. Box 310, Donaldsonville, LA 70346. One Avenue L, Newark, NJ 07105. P. 0. Box 3246, Oxford, AL 36203. 520 Mill St., Lockport, NY 14094. 25 E. Algonguin Road, Des Plaines, IL 60017-5017. 1 Railroad Ave., Hastings-on-Hudson, NY 10706. 4 Bridgewater Lane, Lincoln Park, NJ 07035. 4650 S. Racine Ave., Chicago, IL 60609. 875 Harger Street Dover, OH 44622. 1600 Valley Rd., Wayne, NJ 07470. P. 0. Box 37617, Jacksonville, FL 32236. P.O. Box 8361, S. Charleston, WVA 25303. 1201 W. Fifth St., Los Angeles, CA 90017. 1330 Post Oak Blvd. Houston TX 77252-2120. World Headquarters, Middlebury, CT 06749 Endicott St., Norwood, MA 02062. 438 Huron St., Erie, PA 16502. 1650 Palisades Ave., Teaneck, NJ 07666.

213-251-5600

3075 Wilshire Blvd., Los Angeles, CA 90010.

919-378-0965 616-323-4000 203-281-2722

520 Broome Rd. Greensboro, N.0 27406. 7000 Portage Rd., Kalamazoo, MI 49001 410 Sackett Point Rd., North Haven, CT 06473. Rt 2, Box 625, Lockport, LA 70374. 530 McCullough, San Antonio, TX 78215. 1 N. Transit Rd., Lockport, NY 14094. 1 N. Transit Rd., Lockport, NY 14094. 31 Taylor Ave., Bethel, CT 06801 and Rt. #2, Box 54, Murray, KY 42071. Main & William Sts., Belleville, NJ 07109. 5600 N. River Rd., Rosemont, IL 60018. 838 Baker Bldg., Minneapolis, MN 55402. W. Wheat Rd., Vineland, NJ 08360. 3950 Cumberland Pkwy., Atlanta, GA 30339. 1022 Pressley Rd., Charlotte, NC 28210. 15990 N. Barker's Landing Rd., Houston, TX 77224. 200 E. Randolph Dr., Chicago, IL 60601. P. 0. Box 7689, Birmingham, AL 35233. Middle Road, Ashtabula, OH 44004. 3301 Sutton Rd., Adrian, MI 49221. 2526 Baldwin St., St. Louis, MO 63106. P.O. Box 490, Montrose, AL 36559. 11104 NW Front Ave., Portland, OR 97231.

A-18

A-18

Synthetic Organic Chemicals, 1987 Table A-1—Continued Synthetic organic chemicals alphabetical directory of manufacturers, by company, 1987 (Names of synthetic organic chemicals manufacturers that reported production and/or sales to the U.S. International Trade Commission for 1987 are listed below alphabetically, together with their identification codes as used in table 2 of the 15 individual sections of this report) Identification Code EW

Name of company

Telephone number

Office address

412-864-7960

Route 993, Manor, PA 15665.

404-645-4753

1900 Cunningham Dr., Opelika, AL 36801. P. 0. Box 70848, Charleston Heights, SC 29415. 118 S. Palmetto Ave., Marshfield, WI 54449. 1134 Market Square Wheeling, W VA 26003. P. 0. Box 706, Worcester, MA 01613. 660 Frelinghuysen Ave., Newark, NJ 07114. Rt. 611, Delaware Water Gap, PA 18327. 62 Alford St., Boston, MA 02129. P.O. Box 429, Pryor, OK 74362. Pyles Lane, Wilmington, DE 19899. 155 Tice Blvd., Woodcliff Lake, NJ 07675. 102 Orange, Wilmington, NC 28403. 1421 Kalamazoo St., S. Haven, MI 49090. P. 0. Box 1287, Cheyenne, WY 82003. P.O. Box 13745, Philadelphia, PA 19101-3745.

WPG

Westinghouse Electric Corp., Insulating Materials Div WestPoint Pepperell, Inc

WVA

Grifftex Chemical Co. Sub. Westvaco Corp

212-688-5000

WRD

Weyerhauser Co

715-384-2141

WPS

Wheeling-Pittsburgh Steel Corp

304-234-2439

WBG WCC

White & Bagley Co White Chemical Corp

617-791-3201 201-621-4100

WTK WHW CHN WLM WTC

Whittaker Corp., Heico Chemicals Div Whittmore-Wright Co., Inc Wil-Gro Fertilizer, Inc Wilmington Chemical Corp Witco Corp

717-476-0353 617-242-1180 918-825-3383 302-658-3515 201-573-2800

WCL WYK

Wright Corp Wyckoff Chemical Co., Inc

919-251-0234 616-637-8474

WYC WYT

Wycon Chemical Co Wyeth Laboratories, Inc., Wyeth Laboratories Div. of American Home Products Corp

307-637-2700 215-341-3867

Source: Compiled from data received in response to questionnaires of the U.S. International Trade Commission.

A-19

A-19

A-20

APPENDIX B CYCLIC INTERMEDIATES; GLOSSARY OF SYNONYMOUS NAMES

B-1

• Appendix B Table B-1 Cyclic Intermediates: Glossary of synonymous names Common name

Standard (chemical abstracts) name

A acid Acetyl-p-phenylenediamine 1,2,4-acid

Aminoepsilon acid Amino G acid Amino J acid Amino R sal Aniline oil Anthraflavic acid Anthrarufin Armstrong & Wynne's acid

3,5-Dihydroxy-2,7-naphthalenedisulfonic acid. 4'-Aminoacetanilide. 4-Amino-3-hydroxy-1-naphthalenesulfonic acid (1-Amino-2-naphthol-4-sulfonic acid). 6-Amino-3,4'-azodibenzenesulfonic acid. Sulfanilic acid and salt. 4-Hydroxy-7- (m-aminobenzamido) 2-naphtlesufoicd. 8-Amino-1,6-naphthalenedisulfonic acid. 7-Amino-1 ,3-naphthalenedisulfonic acid. 6-Amino-1 ,3-naphthalenedisulfonic acid. 3-Amino-2,7-naphthalenedisulfonic acid. Aniline. 2,6-Dihydroxyanthraquinone. 1,5-Dihydroxyanthraquinone. 4-Hydroxy-2-naphthalenesulfonic acid.

B acid 2B acid 4B acid Benzal chloride Benzanthrone Benzotrichloride Bisphenol A B.O.N Broenner's acid Bromamine acid Bromobenzanthrone

5-Amino-4-hydroxy-1 ,7-naphthalenedisulfonic acid. 6-Amino-4-chloro-m-toluenesulfonic acid. 6-Amino-m-toluenesulfonic acid. , a-Dichlorotoluene 7H-Benz [de] anthracen-7-one. , a, a-Trichlorotoluene. 4,4'-lsopropylidenediphenol. 3-Hydroxy-2-naphthoic acid. 6-Amino-2-naphthalenesulfonic acid. 1-Amino-4-bromo-2-anthraquinonesulfonic aci d. 3-Bromo-7H-benz [de] anthracen-7-one.

C acid C.A. acid C-Amine (Lake Red C acid) Cassella acid Chicago Acid (SS acid Chlorobenzanthrone Chromotropic acid Chrysazin 1 , 6-Cleve' s acid 1,7-Cleve's acid Crocein acid 2-Cyanopyridine 3-Cyanopyridine Cyanuric chloride

3-Amino-1,5-naphthalenedisulfonic acid. 3-Amino-6-chloro-4-sulfobenzoic acid. 2-Amino-5-chloro-p-toluenesulfonic acid. 5-Hydroxy-1-naphthalenesulfonic acid. 4-Amino-5-hydroxy-1 ,3-naphthalenedisulfonic acid. Chloro-7H-benz [de] anthracen-7-one. 4,5-Dihydroxy-2,7-naphthalenedisulfonic acid. 1 ,8-Dihydroxyanthraquinone 5-Amino-2-naphthalenesulfonic acid. 8-Amino-2-naphthalenesulfonic acid. 7-Hydroxy-1-naphthalenesulfonic acid. Picolinonitrile. Nicotinonitrile. 2,4,6-Trichloro-s-triazine.

D acid DADI DDB Decacyclene Dehydrothio-p-toluidine Developer Z o-Dianisidine 1,1'-Dianthrimide Dibenzanthrone Dichlone 4,4'-Dihydrocydiphenylsulfone Dimethyl POPO 4,5-Dinitrochrysazin Dioxy S acid Diphenyl epsilon aci Durene

6-Amino-1-naphthalenesulfonic acid. Dianisidine diisocyanate. p-Dibutoxybenzene. Diacenaphtho [1 ,2-j:1' ,2' -I ]fluoranthene. 2- (p-Aminophenyl) -6-methylbenzothiazole. 3-Methyl-1-phenyl-2-pyrazolin-5-one . 3,3'-Dimethoxybenzidine. 1,1'-lminodianthraquinone. Violanthrone. 2,3-Dichloro-1,4-naphthoquinone. 4,4'-Sulfonyldiphenol. 1,4-Bis[2-(4-methy1-5-phenyloxazoly1)]benzene. 1,8-Dihydroxy-4,5-dinitroanthraquinone. 4,5-Dihydroxy-1-naphthalenesulfonic acid. 6,8-Dianilino-1-naphthalenesulfonic acid. 1, 2 , 4 , 5-Tetramethylbenzene.

Epsilon acid (Andresen's acid)

8-Hydroxy-1,6-naphthalenedisulfonic acid.

F acid Fast Red G base Fast Scarlet R base Fischer's aldehyd Fischer's base Freund's acid

7-Hydroxy-2-naphthalenesulfonic acid. 2-Nitro-p-toluidine [NH 2=1]. 5-Nitro-o-anisidine [NH 2=1]. 1 ,3, 3-Trimethyl-w 2 , a-indolineacetaldehyde 1,3,3-Trimethy1-2-methyleneindoline. 4-Amino-2,7-naphthalenedisulfonic acid.

Acid yellow 9 p-Aminobenzenesulfonic acid m-Aminobenzoyl J acid

B-2

B-2

Synthetic Organic Chemicals, 1987 Table BA—Continued Cyclic Intermediates: Glossary of synonymous names Common name

Standard (chemical abstracts) name

G salt Gamma acid Gold salt

7-Hydroxy-1,3-naphthalenesulfonic acid, sodium salt. 6-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodium salt. 9,10-Dihydro-9,10-dioxo-1-anthracenesulfonic acid and salt.

H acid Hellimellitene

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid, (8-Amino-1-naphthol-3,6-disulfonic acid). 1,2,3-Trimethylbenzene.

Indoxyl Isodurene

3(2H)-Indolone. 1 ,2 , 3 , 5-Tetramethylbenzene .

J acid J acid urea

7-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodium salt. 7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid]

K acid Koch's acid

4-Amino-5-hydroxy-1,7-naphthalenedisulfonic acid. 8-Amino-1,3,6-naphthalenetrisulfonic acid.

L acid Lake Red C amine Laurent's acid

5-Hydroxy-1-naphthalenesulfonic acid. 2-Amino-5-chloro-p-toluenesulfonic acid. 5-Amino-1-naphthalenesulfonic acid.

M acid MEP Mesitylene Methane base Michler's hydro! Michler's ketone MOCA MVP

8-Amino-4-hydroxy-2-naphthalenesulfonic acid. 5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine). 1,3,5-Trimethylbenzene. 4,4' -Methylenebis [N, N-dimethylaniline] . 4,4' -Bis [dimethylamino] benzhydrol. 4 , 4' -Bis [dimethylamino] benzophenone. 3,3'Dichloro-4,4'-diaminodiphenylmethane. 5-Vinyl-2-picoline.

Naphthionic acid o-Naphthionic acid [3-Naphthol Naphthol AS oz-Napthylamine Neville & Winther's acid. m-Nitrobenzoyl J acid

4-Amino-1-naphthalenesulfonic acid. 1-Amino-2-naphthalenesulfonic acid. 2-Naphthol, tech 3-Hydroxy-2-naphthanilide. 1-Naphthylamine. 4-Hydroxy-1-naphthalenesulfonic acid. 4-Hydroxy-7-(m-nitrobenzamido)-2-naphthalenesulfonic acid.

Oxy Koch's acid

1-Naphthol-3,6,8-trisulfonic acid.

Pentaanthrimide Peri acid Phenyibiphenyl N-Phenyidiethanolamine Phenyl gamma acid Phenyl J acid Phenyl pert acid Picric acid POPO Pseudocumene Pyrazoleanthrone Pyrazoleanthrone yellow Pyrazolone T

1, 4 ,5,8-Tetrakis(1-anthraquinonylamino)anthraquinone . 8-Amino-1-naphthalenesulfonic acid. Terphenyl. 2,2'-[(Phenyl)imino]diethanol. 6-Anilino-4-hydroxy-2-naphthalenesulfonic acid. 7-Anliino-4-hydroxy-2-naphthalenesulfonic acid. 8-Anilino-1-naphthalenesulfonic acid. 2,4,6-Trinitrophenol. 1 ,4-Bis [2- (5-phenyloxazolyl) ] benzene. 1, 2 ,4-Trimethylbenzene Anthra [1 , 9-cd] pyrazol-6 (2H) -one. [3,3' -Bianthral [1 ,9-cd]pyrazole] -6, 6' - (2H ,2 ' H) dione . 5-0xo-1-(p-sulfopheny1)-2-pyrazoline-3-carboxylic acid.

Quinizarin 2-Quinizarinsulfonic acid Quinoline yellow base

1,4-Dihydroxyanthraquinone. 9,10-Dihydro-1,4-dihydroxy-9,10-dioxo-2anthracenesulfonic acid. Quinophthalone.

R salt RG acid (Violet acid) Rhoduline acid (J Acid Imide) RR acid

3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt. 4-Hydroxy-2,7-naphthalenedisulfonic acid. 7,7'-lminobis[4-hydroxy-2-naphthalenesulfonic acid]. 3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid.

S acid Schaffer's acid Silver salt Solvent Yellow 1 Solvent Yellow 3 SS acid (Chicago acid Sulfanilic acid o-Sulfobenzaldehyde

4-Amino-5-hydroxy-1-naphthalenesulfonic acid. 6-Hydroxy-2-naphthalenesulfonic acid. 9,10-Dihydro-9,10-dioxo-2-anthrazenesulfonic acid and salt. p-Phenylazoaniline and hydrochloride. 4-(o-Tolylazo)-o-toluidine. 4-Amino-5-hydroxy-1,3-naphthalenedisulfonic acid. p-Aminobenzenesulfonic acid. o-Formyibenzenesulfonic acid.

B-3

B-3

Appendix B Table B-1—Continued Cyclic Intermediates: Glossary of synonymous names

Common name

Standard (chemical abstracts) name

Tetralin Thiolindoxyl Thiosalicylic Tobias acid TODI o-Tolidine a-Toluic acid a-Tolunitrile 4-m-Tolylenediamine Trimellitic anhydride Trimethyl base Trinitrophenol

1 ,2 , 3 ,4-Tetrahydronaphthalene . 3(2H)-Thianaphthenone. o-Mercaptobenzoic acid. 2-Amino-1-naphthalenesulfonic acid. Bitolylene diisocyanate. 3,3'-Dimethylbenzidine. Phenylacetic acid. Phenylacetonitrile. Toluene-2,4-diamine. 1,2,4-Benzenetricarboxylic acid, 1,2-anhydride. 1,3,3-Trimethyl-2-methyleneindoline. Picric acid.

Urea J acid (J acid urea)

7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid].

Veratraldehyde Veratrole Vinyltoluene Violet acid (RG acid)

3,4-Dimethoxybenzaldehyde. o-Dimethoxybenzene. ar-Methyistyrene. 4-Hydroxy-2,7-naphthalenedisulfonic acid.

B-4

B-4

APPENDIX C SYNTHETIC ORGANIC CHEMICALS, U.S. PRODUCTION AND SALES, 1987

C-1

Appendix C

Synthetic Organic Chemicals, U.S. Production And Sales, 1987, Harmonized System Basis The following table contains 1987 U.S. production and sales data for synthetic organic chemicals in the 6-digit Harmonized System (HS) format. The Commission decided to compile such data in this format in response to the decision by the U.S. Bureau of the Census to publish Standard Industrial Classification (SIC) data which will be convertible to the HS beginning with the 1987 Census of Manufactures. The U.S. Bureau of the Census has historically referred to the Synthetic Organic Chemicals, United States Production and Sales (SOC) report in the chemicals section of the Census of Manufactures, which permits them to omit collecting synthetic organic chemicals production and shipments data from its respondents. Because of this situation, the SOC data will now also be compiled on an HS basis to provide comparablility with the new SIC format. The table provides production and sales data on a 6-digit HS basis only where publication would not violate the statutory provisions relating to unlawful disclosure of information accepted in confidence by the Commission. It includes only the 6-digit item numbers with publishable data from a number of HS chapters in which these chemicals are classified, but does not provide totals by chapter or overall total figures.

C-2

C-2

Table C-1 Synthetic organic chemicals: U.S. production and sales, 1987, harmonized system basis

HS number 151800 220720 271113 271114 271119 271129 290110 290121 290122 290123 290124 290129 290211 290220 290230 290250 290260 290270 290311 290312 290313 290314 290315 290319 290321 290329 290340 290410 290514 290531 290532 290539 290542 290549 290550 290711 290723 290919 290941 290942 290943 290949 290960

Description Chemically modified fats and oils and their fractions (except those of heading 1516) Ethyl alcohol and other spirits, denatured, of any strength Butanes, liquefied Ethylene, propylene, butylene and butadiene, liquefied Other petroleum gases and other gaseous hydrocarbons nspf, liquefied Other petroleum gases and other gaseous hydrocarbons nspf, In gaseous state Acyclic hydrocarbons, saturated Ethylene Propene (Propylene) Butene (Butylene) and isomers thereof Buta-1,3-diene and isoprene Unsaturated acyclic hydrocarbons nspf Cyclohexane Benzene Toluene Styrene Ethylbenzene Cumene Chloromethane (Methyl chloride) and chloroethane (Ethyl chloride) Dichloromethane (Methylene chloride) Chloroform (Trichioromethane) Carbon tetrachloride 1 ,2-Dichioroethane (Ethylene dichloride) Other saturated chlorinated derivs of acyclic hydrocarbons nspf Vinyl chloride (Chloroethylene) Other unsaturated chlorinated derivs of acyclic hydrocarbons nspf Halogenated derivs of acyclic hydrocarbons containing two or more different halogens Hydrocarbon derivs containing only sulfo groups, their salts and ethyl esters 1Butan-1-01 (n-Butyl alcohol) Other butanols nspf Ethylene glycol (Ethanediol) Propylene glycol (Propane-1,2-diol) Other acyclic diols nspf Pentaerythritol Other acyclic polyhydric alcohols nspf Halogenated, sulfonated, nitrated or nitrosated derivs of acyclic alcohols Phenol (Hydroxybenzene) and its salts 4,4'-lsopropylidenediphenol (Bisphenol A, Diphenyloipropane) and its salts Other acyclic ethers, and their halo, sulfo, nitro or nitroso derivs 2,2'-Oxydiethanol (Diethylene glycol, Digol) Monomethyl ethers of ethylene glycol or of diethylene glycol Monobutyl ethers of ethylene glycol or of diethylene glycol Other ether-alcohols and their halo, sulfo, nitro or nitroso derivs nspf Alcohol-, ether- and ketone peroxides and their halo sulfo, nitro or nitroso derivs

Production

Sales

Quantity

Quantity

Value

Pounds

Pounds

Dollars

161,141,359

149,406,233

76,088,594

573,687,392 3,195,922,145

714,202,268 1,393,993,183

168,831,509 114,758,406

3,995,808,542

1,946,498,320

225,251,391

6,474,130,636

2,085,680,649

90,005,759

11,123,859,953

8,208,243,577 1,143,833,735 11,075,508,887 9,870,188,768 598,206,209 2,870,894,854 1,641,406,113 2,157,305,353

489,568,525 154,073,194 1,590,662,227 1,411,357,394 103,830,766 664,649,482 385,166,389 443,773,693

2,175,680,000 314,721,969 2,523,241,403

848,886,000 66,406,688 486,480,918

527,762,604 516,132,000 461,819,000 672,151,000 12,196,585,000

473,110,640 446,377,320 717,822,000 1,296,930,000

83,121,870 53,535,015 102,068,000 103,816,000

1,461,377,093 8,401,595,436

1,344,679,877 3,458,777,093

347,277,679 598,724,547

46,841,000

18,333,665

1,161,114,328

997,475,880

759,661,031

1,154,866,663 1,576,491,000 5,183,229,147 747,208,900 2,740,957,003

583,726,351 230,398,000 3,778,030,872 663,739,982 1,838,210,135 130,416,000 880,055,754

127,593,593 36,435,000 669,634,831 182,214,072 955,268,897 63,286,555 65,898,319

3,841,091,000

6,278,374 1,533,009,072

10,517,819 444,626,924

1,000,351,000

409,386,700

199,393,400

3,672,392,832 435,986,000

393,807,673

63,562,299

108,057,891

99,449,996

34,145,687

491,301,000

447,007,000

128,791,000

557,025,536

466,357,912

260,611,178

79,389,321

50,366,734

C-3 59,178,559

3,813,500,638 34,950,791,770 19,019,302,251 1,496,719,753 3,037,797,552 2,497,779,132 2,276,060,246 11,532,819,013 6,969,852,001 8,014,020,000 9,346,118,724 4,104,961,173

C-3

Appendix C Table C-1— Continued Synthetic organic chemicals: U.S. production and sales, 1987, harmonized system basis HS number Description

291010 Oxirane (Ethylene oxide) 291211 Methanal (Formaldehyde) 291213 Butanal (Butyraldehyde, normal Isomer) 291230 Aldehyde-alcohols 201411 Acetone 291412 Butanone (Methyl ethyl ketone) 291413 4-Methylpentan-2-one (Methyl isobutyl ketone) 291422 Cyclohexanone and methylcyclohexanones 291423 lonones and methylionones 291430 Aromatic ketones without other oxygen function 291521 Acetic acid 291522 Sodium acetate 291531 Ethyl acetate 291532 Vinyl acetate 291533 n-Butyl acetate 291534 Isobutyl acetate 291535 2-Ethoxyethyl acetate (Ethylene glycol, monoethyl ether acetate) 291539 Other esters of acetic acid nspf 291550 Propionic acid, its salts and esters 291570 Palmitic acid, stearic acid, their salts and esters 291590 Other saturated acyc monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids; halo, sulfa, nitro, nitroso derivs nspf 291611 Acrylic acid and its salts 291615 Oleic, linoleic or linolenic acids, their salts and esters 291619 Other unsaturated acyc monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids nspf; halo, sulfa, nitro, nitroso deny 291620 Cyclanic, cyclenic or cycloterpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivs 291631 Benzoic acid, Its salt and esters 291639 Other aromatic monocarboxylic acids, their anhydrides halides, peroxides, peroxyacids and their derivs nspf 291719 Other acyc. polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids nspf; halo, sulfo, nitro or nitroso derivs 291731 Dibutyl orthophthalates 291732 Dioctyl orthophthalates 291735 Phthalic anhydride 291739 Other aromatic polycarboxylic acids, their anhydrides halides, peroxides, peroxyacids nspf and their derivs 291819 Other carbox. acids w/add alcohol function only, anhydrides, halides, peroxides, peroxyacids nspf; halo, sulfo, nitro, nitroso derivs 291821 Salicylic acid and Its salts 291822 0-Acetylsalicylic acid (Aspirin), its salts and esters 291829 Other carboxylic acids w/ add phenol funct only, anhydrides, halides, peroxides, peroxyacids nspf; halo, sulfa, nitro, nitroso derivs 291830 Other carboxylic acids with add aldehyde or ketone function only, anhydrides, halides, peroxides, peroxyacids nspf; halo, etc. derivs

C-4

Production

Sales

Quantity

Quantity

Value

Pounds

Pounds

Dollars

4,785,306,886 5,733,238,007 1,758,934,440 4,609,285 1,845,586,000 671,858,630 151,241,000 930,376,161 2,021,046 5,253,070 3,245,948,000 47,182,128 214,002,936 1,813,312,848 201,853,236 88,246,804

670,809,847 1,691,080,439

135,125,043 107,114,319

2,341,693

11,328,850

549,373,600 155,490,000 91,923,913 1,275,538 3,616,227 1,102,599,000

123,887,164 51,201,000 36,455,375 10,332,936 8,620,113 140,337,000

162,370,127 1,641,242,171 168,867,767 70,094,770

34,096,618 326,265,093 48,919,152 17,802,082

84,863,000 227,221,345 256,185,205

85,250,588 217,827,209 132,329,794

31,137,051 126,424,014 57,505,874

208,367,199

189,966,472

131,480,615

423,766,286 1,100,893,500

200,814,199 204,499,824

162,707,570 75,256,983

88,046,587

77,603,213

41,760,506

44,474,607

46,636,485

64,037,571

26,986,077

20,684,063

65,111,895

574,098,367 25,167,407 343,138,087 1,035,187,000

464,824,111 22,614,292 353,863,174 454,932,644

266,319,489 10,044,971 124,896,867 113,240,346

4,608,340,080

1,137,168,785

436,148,802

34,708,151 25,131,000

20,973,804

24,365,423

4,811,163

15,524,708

101,026,723 94,619,000

24,088,861

4,909,055

C-4 853,295,009

26,440,754

14,774,062

Synthetic Organic Chemicals, 1987 Table C-1—Continued Synthetic organic chemicals: U.S. production and sales, 1987, harmonized system basis Production HS number Description

291890 Other carboxylic acids w/ add oxygen function, anhydrides, halides, peroxides, peroyacids nspf; halo sulfo, nitro, nitroso derivs Phosphoric esters and their salts, incl. 291900 lactophosphates; their halo, sulfo, nitro, nitroso derivs 292010 Thiophosphoric esters (phosphorothioates), their salts; their halo, sulfo, nitro, nitroso derivs 292090 Other esters of inorg. acids (excl. esters of hydrogen halides) nspf, their salts; halo, sulfo, nitro, nitroso derivs Methylamine, di- or trimethylamine, 292111 and their salts 292119 Other acyclic monoamines and their derivs nspf; salts thereof 292129 Other acyclic polyamines and their derivs nspf; salts thereof 292130 Cyclanic, cyclenic, cycioterpenic monoor polyamines and their derivs; salts thereof 292141 Aniline and its salts 292211 Monoethanolamine and its salts 292212 Diethanolamine and its salts 292213 Triethanolamine and its salts 292219 Other amino-alcohols nspf, their ethers and esters, containing only one kind of oxygen function; salts thereof 292229 Other amino-naphthols and amino-phenols nspf, their ethers, esters, containing only one kind of oxygen function; salts thereof 292230 Amino-aldehydes, amino-ketones and amino-quinones, containing only one kind of oxygen function; salts thereof 292249 Other amino-acids nspf and their esters, containing only one kind of oxygen function; salts thereof 292250 Amino-alcohol-phenols, amino-acidphenols and other amino-compounds with oxygen function 292390 Other quaternary ammonium salts and hydroxides nspf 292410 Acyclic amides (including acyclic carbamates), and their derivs; salts thereof 292421 Ureines and their derivs; salts thereof 292429 Other cyclic amides nspf (including cyclic carbamates) and their derivs; salts thereof 292519 Other imides nspf and their derivs; salts thereof 292520 (mines and their derivs; salts thereof 292690 Other nitrile-function compounds nspf 292700 Diazo-, azo-, or azoxy-compounds 292800 Organic derivs of hydrazine or of hydroxylamine 292910 Isocyanates 292990 Other compounds nspf with other nitrogen functions 293020 Thiocarbamates and dithiocarbamates 293090 Other organo-sulfur compounds nspf 293100 Other organo-inorganic compounds 293211 Tetrahydrofuran 293229 Other lactones nspf with oxygen heteroatom(s) only 293339 Other heterocyclic cmpds with nitrogen hetero-atom(s) only nspf, with unfused pyridine ring (hydrogenated or not) in structure

222-174 0 - 88 - 9 : QL 3

Sales

Quantity

Quantity

Value

Pounds

Pounds

Dollars

83,063,111

73,312,024

193,685,965

184,904,360

131,566,545

140,320,496

118,495,728

62,646,465

140,279,110

175,705,485

134,429,248

121,475,790

155,884,696

130,505,979

43,618,142

273,438,817

233,881,719

151,582,455

98,318,465

108,629,833

18,914,037 859,074,674 231,835,000 194,406,000 216,241,155

21,282,469 430,181,762 163,344,000 183,584,000 212,010,630

81,310,798 127,929,172 38,571,000 44,424,000 62,185,055

134,887,256

107,414,776

110,367,675

12,624,189

8,948,590

12,617,847

68,346,896

36,186,623

80,843,347

71,942,531

26,634,874

52,732,919

51,218,886

43,435,152

54,236,009

336,363,893 30,397,090

138,544,396 22,675,948

137,620,177 64,238,677

147,203,104

148,444,469

444,902,660

11,923,482 179,647,399 4,728,449,245 21,048,307 3,567,075 1,568,338,000

9,492,366 140,559,346 1,644,779,079 16,727,086 4,078,775 1,363,296,000

25,967,760 100,532,276 737,547,506 58,875,585 14,596,542 1,046,592,000

54,321,519 88,170,302 369,292,884 293,740,683 142,902,550

40,498,205 78,206,918 255,607,039 172,765,197 71,394,370

29,330,882 188,308,625 416,477,902 990,851,079 59,271,674

77,167,399

17,857,916

63,614,786

153,209

C-5 106,270,348

74,202,798

420,868,676

C-5

Appendix C Table C-1 —Continued Synthetic organic chemicals: U.S. production and sales, 1987, harmonized system basis HS number Description

293359 Heterocyc cmpds w/ nitrogen heteroatom(s) only, pyrimidine (hydrogenated or not) or piperazine ring in struct; nucleic acids, salts 293369 Other heterocyc cmpds w/nitrogen heteroatom(s) only nspf, with unfused triazine ring (hydrogenated or not) in the structure 293371 6-Hexanelactam (epsilon-Caprolactam) 293390 Other heterocyclic compounds with nitrogen hetero atom(s) only nspf 293420 Heterocyclic compounds containing a benzothlazole ring-system (hydrogenated or not), not further fused 293490 Other heterocyclic compounds nspf 294190 Other antibiotics nspf 294200 Organic compounds nspf 310210 Urea, whether or not In aqueous solution 320411 Disperse dyes and preparations based thereon 320412 Acid dyes, premetallized or not, mordant dyes and preparations based thereon 320413 Basic dyes and preparations based thereon 320414 Direct dyes and preparations based thereon 320417 Pigments and preparations based thereon 320419 Other synth. organic coloring matter nspf and preparations based thereon, incl mixtures of items of subheadings 3204.11 thru 3204.19 320420 Fluorescent brightening agents 380610 Rosin 380630 Ester gums 380991 Other finishing agents, dye carriers, like products nspf, for textile industry use 380999 Other finishing agents, dye carriers, like products nspf, for leather industry use 381121 Lubricating oil additives containing petroleum oils or oils obtained from bituminous minerals 381230 Antioxidizing preps and compound stabilizers for rubber or plastics 381590 Reaction initiators, reaction accelerators, and catalytic preps, nspf 382320 Naphthenic acids, their water-Insoluble salts and their esters 382390 Other chemical products, preparations, and residual products of the chemical or allied industries nspf 390110 Polyethylene having a specific gravity of less than 0.94 390120 Polyethylene having a specific gravity of 0.94 or more 390210 Polypropylene 390311 Polystyrene, expandable .......... 390319 Polystyrene, other than expandable 390320 Styrene-acrylonitrile (SAN) copolymers 390330 Acrylonitrile-butadiene-styrene (ABS) copolymers 390390 Other polymers of styrene nspf, in primary forms 390511 Polymers of vinyl acetate In aqueous dispersion 390590 Polymers of vinyl esters nspf, in primary forms; other vinyl polymers nspf, in primary forms 390610 Polymethyl methacrylate 390690 Other acrylic polymers nspf In primary forms 390730 Epoxide resins

C-6

Production

Sales

Quantity

Quantity

Value

Pounds

Pounds

Dollars

36,722,206

25,728,639

122,623,959

348,393,956 1,156,336,310

254,728,564 276,870,986

530,823,893 170,252,204

177,606,592

107,148,903

496,560,540

101,193,018 99,469,522 11,986,831 228,770,076 11,530,120,118 26,137,386

61,084,112 70,284,505 3,002,220 187,084,219 11,529,565,380 20,801,105

141,233,260 266,669,654 245,529,688 197,612,367 563,796,493 79,664,389

17,927,818 12,718,804 36,856,147 100,465,908

16,811,810 11,861,428 35,745,493 89,915,398

81,554,999 66,385,641 84,436,333 598,053,128

36,088,406 65,424,147 150,110,704 167,015,914

31,322,278

131,800,727

140,570,971 163,190,271

51,038,216 109,678,283

61,617,130

59,544,995

34,383,718

35,965,640

24,588,343

16,598,763

1,891,692,078

1,289,324,846

939,429,354

101,117,304

83,185,422

52,941,852

12,916,346

31,959,755

11,496,943,715

5,656,933,143

900,396,282

9,467,960,065

8,606,631,233

2,970,975,563

7,906,674,788 6,977,333,991 553,197,950 5,043,745,000 208,670,515

7,901,864,749 5,644,014,860 553,141,950 4,136,402,000 109,124,290

2,609,051,954 2,153,716,511 332,831,343 2,020,290,000 69,805,806

1,260,608,009

1,243,086,228

983,771,907

1,216,544,000

1,189,661,000

858,956,000

704,577,712

560,342,633

314,116,880

642,549,924 596,587,782 1,901,393,716 838,316,528

562,609,187 383,021,937 1,441,496,613 536,786,157

315,940,456 C-6 395,209,266 1,556,196,421 669,304,510

66,546,905

Synthetic Organic Chemicals, 1987 Table C-1—Continued Synthetic organic chemicals: U.S. production and sales, 1987, harmonized system basis HS number

Description

Production

Sales

Quantity

Quantity

Value

Pounds

Dollars

Pounds

390750 390760 390791 390799 390810 390910 390920 390940 390950 391231 400299

Alkyd resins Polyethylene terephthalate Other polyesters nspf, unsaturated, in primary forms Other polyesters nspf, saturated, in primary forms Polyamide-6, -11, -12, -6,6, -6,9, -6,10 or -6,12 (nylon type) Urea resins; thiourea resins Melamine resins Phenolic resins Polyurethanes Carboxymethylcellulose and its salts Other synthetic rubber nspf

752,251,342 3,912,629,000

502,047,438 2,434,372,000

298,862,505 1,898,624,000

1,343,796,000

1,264,020,000

793,208,000

736,106,000

461,464,000

529,457,000

2,807,561,000 1,963,759,000 250,314,269 1,697,074,000 227,481,921 99,654,240 1,064,171,159

2,060,635,000 1,714,932,000 219,133,537 1,223,894,000 142,983,244 105,556,966 554,509,298

3,244,192,000 235,606,000 189,387,811 627,238,000 214,722,195 181,340,969 824,872,703

C-7

C-7

C-8

APPENDIX D ALPHABETICAL CHEMICAL INDEX

D-1

Appendix D

Alphabetical Chemical Index The alphabetical index of chemicals contained in this appendix table is an outgrowth of the processing of data by the U.S. International Trade Commission for its annual report, Synthetic Organic Chemicals, United States Production and Sales. This index will aid those who have an interest in the report, either as users of the published data or as suppliers of individual company data to the Commission, principally by showing the section number and line item number of specific chemicals. This information can be used to assist in locating a chemical in the report and to provide respondents to the Commission's questionnaire with information on where to list their production and sales data. The index shows only those chemicals for which production or sales were reported to the Commission for this edition of the report. The index, initially designed for Commission use in computer processing of data for the annual report, has certain characteristics that should be noted to increase its usefulness. For example, superior headings for individual entries are not shown in the index. Thus, understanding the contents of the first item in the index, "accelerators, activators, and vulcanizing agents, acyclic, other," necessitates that the index user turn to the individual section (in the report) and item number (in the questionnaire) to find those acyclic accelerators, activators, and vulcanizing agents already specified. Similarly, the index entry "specific gravity 0.940 and below" does not by itself identify the chemical product. The index user will need to turn to the indicated section number and item number to determine the chemical referred to—in this case, polyethylene. The chemical names used in this report and in the questionnaires sent to U.S. producers to obtain the data aggregated in the report are listed alphabetically in the first column of each listing in the index. The second column refers to the section in the report and questionnaire containing the chemical, and the third column shows the appropriate item number in that section in the questionnaire.

D-2

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D-11

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Appendix D

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D-13





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Appendix D

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▪•

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• Appendix D

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D-43





Appendix D

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D-48



▪▪



Synthetic Organic Chemicals, 1987

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D-49



• Appendix D

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▪•



••

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